JP4050676B2 - Cleaning fee - Google Patents

Description

  The present invention relates to a cleaning agent that has good foaming at the time of shampooing, has a fine and soft foam quality, has good smoothness of hair at the time of rinsing, and maintains that smoothness.

  Hair is always affected by sunlight, ultraviolet rays, heat, drying, and the like, and tends to be pricked by daily hair washing, brushing, the heat of a dryer, and the like. Furthermore, in recent years, it has become common to enjoy changing the hair color and hairstyle of each person freely, and the frequency of performing coloring and perm is increasing. Along with this, the hair is damaged, gloss, elasticity, and smoothness are lost, it becomes easy to dry, and it tends to be difficult to organize by styling. In particular, the degree to which the smoothness of the hair is impaired during shampooing is large, and the feeling of use is increasing, such as tingling or catching during rinsing.

  On the other hand, in order to improve the smoothness at the time of shampooing and the like, it has been generally performed to add various cationic polymers into the hair cleaning agent. For example, a shampoo composition (Patent Document 1) excellent in conditioning effect using a combination of a cationic polymer and a silicone derivative, a specific anionic surfactant, an amphoteric surfactant and a cationic polymer, and a smooth feel in a certain pH range Shampoo compositions (Patent Document 2), shampoo compositions (Patent Document 3) and the like that have a good feel and a good conditioning effect using a copolymer of dialkyl diallylammonium salt and cationized cellulose have been proposed.

JP-A-56-72095 Japanese Patent Laid-Open No. 10-182368 Japanese Unexamined Patent Publication No. 1-128914

  However, the conventional techniques have not been able to adequately cope with the problems of hair that tends to be excessively damaged in recent years, such as the smoothness of hair at the time of shampooing and the stagnation of rinsing. Accordingly, the present invention provides a cleansing agent that has good foaming at the time of shampooing, has a fine and soft foam quality, and has good smoothness at the time of rinsing and maintains the smoothness even for excessively damaged hair. The purpose is to provide.

  The present inventors have found that the above requirement is satisfied by using a low pH detergent containing an anionic surfactant, a specific cationic polymer and a specific nonionic surfactant.

That is, the present invention includes the following components (A) to (C):
(A) Anionic surfactant
(B) Dialkyldiallylammonium salt / acrylamide copolymer
(C) A detergent containing a fatty acid alkanolamide and / or polyoxyethylene alkyl ether and having a pH of 2 to 4.5 at 25 ° C. when diluted 20 times by weight with water.

  The cleaning material of the present invention has good foaming at the time of shampooing, has a fine and soft foam quality, has particularly good smoothness during rinsing, and maintains the smoothness.

  Examples of the anionic surfactant of component (A) include those having a sulfuric acid residue, a sulfonic acid residue or a carboxylic acid residue, such as polyoxyethylene alkyl ether sulfate, polyoxyethylene alkenyl ether sulfate, alkyl Examples thereof include sulfates, polyoxyalkylene alkylphenyl ether sulfates, sulfosuccinic acid alkyl ester salts, polyoxyalkylene sulfosuccinic acid alkyl ester salts, higher fatty acid salts, alkane sulfonates, and the like. Particularly preferred are those represented by the following general formula (1) or (2).

R ¹ O (CH ₂ CH ₂ O) _m SO ₃ M (1)
R ² OSO ₃ M (2)

[Wherein, R ¹ represents an alkyl group or alkenyl group having 10 to 18 carbon atoms, R ² represents an alkyl group having 10 to 18 carbon atoms, and M represents an alkali metal, alkaline earth metal, ammonium, alkanolamine or A basic amino acid is shown, m shows the number of 1-5 on a weight average. ]

  Two or more of these components (A) may be used in combination, and the content thereof is preferably 1 to 50% by weight in the cleaning material of the present invention from the viewpoints of foaming, liquid properties at the time of use, and cleaning properties. Further, 5 to 30% by weight, particularly 8 to 25% by weight is preferable.

The dialkyl diallylammonium salt / acrylamide copolymer of component (B) is preferably a dimethyl diallylammonium halide / acrylamide copolymer. The weight ratio of the dialkyl diallylammonium salt and acrylamide is preferably 10:90 to 90:10, particularly 40:60 to 60:40. The weight average molecular weight is preferably 0.5 × 10 ^{6 to} 3 × 10 ⁶ , particularly preferably 1 × 10 ⁶ to 2 × 10 ⁶ . Specific examples include Marcote 550, Marcote S, Marcote 2200 (above, ONDEO NALCO).

Two or more kinds of these components (B) may be used in combination, and the content thereof is foaming, fine and soft foam quality, smoothness during rinsing and the maintenance of the smoothness. The content is preferably 0.01 to 1.0% by weight, more preferably 0.03 to 0.5% by weight, and particularly preferably 0.05 to 0.3% by weight.

  Among the components (C), the fatty acid alkanolamide preferably has an acyl group having 8 to 22 carbon atoms, particularly 10 to 16 carbon atoms. The fatty acid alkanolamide may be either a monoalkanolamide or a dialkanolamide, and preferably has a hydroxyalkyl group having 2 to 3 carbon atoms, such as oleic acid diethanolamide, palm kernel oil fatty acid diethanolamide, coconut oil fatty acid diethanolamide. And lauric acid diethanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, coconut oil fatty acid monoethanolamide, lauric acid isopropanolamide, and lauric acid monoethanolamide. Of these, fatty acid monoalkanolamides are preferred, and coconut oil fatty acid monoethanolamide is preferred.

  Among the components (C), as the polyoxyalkylene alkyl ethers, those having a linear or branched alkyl group having 8 to 22 carbon atoms, particularly 10 to 18 carbon atoms are preferable. The number of added moles of alkylene oxide is preferably 1 to 30 on a weight average. The nonionic surfactant of component (C) preferably has an HLB (griffin method) of 7 to 18, particularly 9 to 15.

  Two or more kinds of these components (C) may be used in combination, and the content thereof is foaming, fine and soft foam quality, smoothness during rinsing and the sustainability of the smoothness of the present invention. The content is preferably 0.1 to 10% by weight, more preferably 0.3 to 5% by weight, and particularly preferably 0.5 to 4% by weight. Further, in relation to the content of the component (B), the weight ratio of the component (B): the component (C) is 1:50 to 1: 5, particularly 1:40 to 1: 6. It is preferable from the point of smoothness of time.

  The cleaning material of the present invention preferably further contains a cationic polymer other than component (B) as component (D). Specifically, for example, cationized cellulose derivatives, cationic starch, cationized guar gum derivatives, diallyl quaternary ammonium salt homopolymers, quaternized polyvinyl pyrrolidone derivatives, polyglycol polyamine condensates, vinyl imidazolium trichloride / vinyl pyrrolidone. Copolymer, hydroxyethylcellulose / dimethyldiallylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer Polymer, vinylpyrrolidone / methacrylamidopropyl trimethylammonium chloride copolymer, alkylacrylamide / acrylate / alkyl Described in minoalkylacrylamide / polyethylene glycol methacrylate copolymer, adipic acid / dimethylaminohydroxypropylethylenetriamine copolymer (Cartaretin manufactured by Sandos, USA), JP-A-53-139734, JP-A-60-36407 The cationic polymer etc. currently mentioned are mentioned, A cationized cellulose derivative and a cationized guar gum derivative are especially preferable.

  The content of component (D) is to provide smoothness from the time of foaming of the cleaning agent to the time of rinsing, to unite the hair after drying, the fine and soft foam quality, and the active ingredient to the hair From the viewpoint of improvement in adsorption, the content is preferably 0.1 to 2% by weight, more preferably 0.2 to 1.5% by weight, and particularly preferably 0.3 to 1% by weight in the cleaning material of the present invention. In relation to the content of component (B), the weight ratio of component (B): component (D) is preferably 1: 1 to 1:10, particularly 1: 4 to 1: 6.

  In order to improve the finish after drying, the cleaning agent of the present invention may further contain a conditioning component selected from cationic surfactants, silicones and oils as component (E).

Examples of the cationic surfactant include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, lauryl trimethyl ammonium bromide, dialkyldimethyl ammonium chloride, dicetyl chloride. Dimethylammonium, distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, myristyldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, ethyl sulfate lanolin fatty acid aminoethyltriethylammonium, ethyl lanolin sulfate fatty acid Aminoethyldiethylmethylammo Um, ethyl lanolin fatty aminoethyl trimethylammonium sulfate, ethyl lanolin fatty acid aminopropyl triethylammonium sulfate, methyl sulfate lanolin fatty acid aminoethyl trimethylammonium, lanolin fatty acid aminopropyl ethyl dimethyl ammonium methyl sulfate, ethyl sulfate isoalkanes acid (C ₁₄ ~C ₂₀₎ mentioned aminopropyl dimethylammonium, ethyl isoalkanes acid (C ₁₈ ~C ₂₂₎ aminopropyl dimethylammonium sulfate, ethyl isostearate aminopropyl dimethylammonium sulfate, ethyl sulfate, isononanoic acid aminopropyl ethyl dimethyl ammonium and alkyl trimethyl ammonium saccharine It is done. Two or more of these cationic surfactants may be used in combination, and the content thereof is determined from the point of smoothness of the hair from washing to rinsing, the goodness of the fingers after drying, and the unity of the present invention. Is preferably 0.01 to 5% by weight, more preferably 0.05 to 3% by weight, and particularly preferably 0.1 to 1% by weight.

  Examples of silicones include the following.

(Silicones-1) Dimethylpolysiloxane Examples include those represented by the following general formula.

(Me) ₃ SiO-[(Me) ₂ SiO] _d -Si (Me) ₃
[In formula, Me shows a methyl group and d shows the number of 3-20000. ]

(Silicones-2) Amino-modified silicones Various amino-modified silicones can be used, but in the CTFA dictionary (USA, Cosmetic Ingredient Dictionary) 3rd edition, especially with an average molecular weight of about 3000 to 100,000 under the name Amodimethicone What is described is preferred. This amino-modified silicone is preferably used as an aqueous emulsion. Examples of commercially available products include SM 8704C (Toray Dow Corning Silicone) and DC 929 (Dow Corning).

(Silicones-3) Other silicones Besides the above, polyether modified silicone, methylphenylpolysiloxane, fatty acid modified silicone, alcohol modified silicone, alkoxy modified silicone, epoxy modified silicone, fluorine modified silicone, cyclic silicone, alkyl modified silicone Etc. Two or more kinds of these silicones may be used in combination, and the content of the silicones is determined from the point of smoothness of hair from shampooing to rinsing, good fingering of dried hair, and consistency. The content is preferably 0.1 to 7% by weight, more preferably 0.2 to 6% by weight, and particularly preferably 0.3 to 5% by weight.

  Oils include hydrocarbons such as squalene, squalane, liquid paraffin, liquid isoparaffin, cycloparaffin; glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil; beeswax, whale wax, lanolin, carnauba wax, etc. Waxes; alcohols such as myristyl alcohol, cetyl alcohol, oleyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, glycerin; isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, hexyl laurate, cetyl lactate , Esters such as propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, isononyl isononanoate, tridecyl isononanoate; capric acid, Examples thereof include higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil fatty acid, isostearyl acid and isopalmitic acid, isostearyl glyceryl ether, polyoxypropylene butyl ether and the like. Of these, esters are preferable, and hexadecyl 2-ethylhexanoate, isononyl isononanoate, isopropyl palmitate, and the like are particularly preferable. Two or more of these oils may be used in combination, and the content thereof is determined according to the present invention from the viewpoint of smoothness of hair from shampooing to rinsing, ease of fingering after drying, and consistency. The content is preferably 0.1 to 7% by weight, more preferably 0.2 to 6% by weight, and particularly preferably 0.5 to 5% by weight.

In order to improve the stability of the cleaning material, the cleaning material of the present invention may contain a nonionic surfactant other than the component (C) as the component (F). Examples of such nonionic surfactants include polyoxyalkylene sorbitan fatty acid esters, polyoxyalkylene sorbit fatty acid esters, polyoxyalkylene glycerin fatty acid esters, polyoxyalkylene fatty acid esters, polyoxyalkylene alkyl phenyl ethers, Examples include polyoxyalkylene (cured) castor oils, sucrose fatty acid esters, polyglycerin alkyl ethers, polyglycerin fatty acid esters, alkylglycosides and the like. Of these, alkyl glycosides, polyoxyalkylene (C ₈ -C ₂₀ ) fatty acid esters, polyoxyethylene sorbitan fatty acid esters, and polyoxyethylene hydrogenated castor oil are preferred.

  Two or more kinds of these nonionic surfactants may be used in combination, and the content thereof is the stability of the cleaning material, the liquid property during use, the ease of foaming, the ease of washing during hair washing, the fine and soft foam From the viewpoint of quality, it is preferably 0.1 to 30% by weight, more preferably 0.5 to 20% by weight, and particularly preferably 1.0 to 10% by weight in the cleaning material of the present invention.

  The detergent of the present invention may contain an amphoteric surfactant as component (G) in order to improve the stability of the detergent. Examples of amphoteric surfactants include betaine surfactants. Of these, betaine surfactants such as alkyldimethylaminoacetic acid betaine and fatty acid amidopropyl betaine are more preferred, and fatty acid amidopropyl betaine is particularly preferred. The fatty acid amidopropyl betaine is preferably one having an acyl group having 8 to 18 carbon atoms, particularly 10 to 16 carbon atoms, and in particular, lauric acid amidopropyl betaine, palm kernel oil fatty acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine and the like. preferable.

  The content of the amphoteric surfactant is preferably from 0.1 to 10% by weight, more preferably from 0.2 to 8% by weight, particularly preferably from 2 to 6% by weight, in the cleaning material of the present invention, from the viewpoint of obtaining a good foam increasing effect. .

  Furthermore, the cleaning material of the present invention can contain a hair-penetrating solvent as component (H) in order to improve the gloss and cohesiveness of the hair. Examples of the hair-penetrating solvent include aromatic alcohol, N-alkylpyrrolidone, alkylene carbonate, polypropylene glycol, lactone, and cyclic ketone. Examples of the aromatic alcohol include benzyl alcohol, cinnamyl alcohol, phenethyl alcohol, p-anisyl alcohol, p-methylbenzyl alcohol, phenoxyethanol, 2-benzyloxyethanol and the like. Examples of N-alkylpyrrolidone include N-methylpyrrolidone, N-octylpyrrolidone, N-laurylpyrrolidone and the like. Examples of the alkylene carbonate include ethylene carbonate and propylene carbonate. As the polypropylene glycol, those having a molecular weight of 300 to 600, particularly those having a polymerization degree of 2 to 5 are preferable. As the lactone, a linear or branched alkyl group having 1 to 6 carbon atoms in the γ position in the case of γ-lactone, or in the δ position in the case of δ-lactone (that is, methylene adjacent to the hetero oxygen atom), for example, Those substituted with a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group or the like are preferable. In order to increase the water solubility of the lactone, it is preferable to have an acidic group such as a sulfonic acid group, a phosphoric acid group, or a carboxy group, or an alkyl group substituted with these. Specific examples include γ-butyrolactone, γ-caprolactone, γ-valerolactone, δ-valerolactone, δ-caprolactone, and δ-heptanolactone. From the viewpoint of lactone stability, γ-lactone, In particular, γ-butyrolactone and γ-caprolactone are preferable. Examples of the cyclic ketone include cyclopentanone, cyclohexanone, cycloheptanone, 4-methylcycloheptanone and the like.

  Component (H) may be used in combination of two or more, and the content thereof is preferably 0.1 to 20% by weight in the cleaning agent of the present invention from the viewpoint of smoothness from washing to rinsing. Is preferably 0.2 to 10% by weight, more preferably 0.7 to 7% by weight.

  The cleaning material of the present invention must have a pH of 2 to 4.5 at 25 ° C. when diluted 20 times by weight with water from the viewpoint of smoothness during rinsing, fingering, and good touch after finishing. Furthermore, it is preferable that it is 3-3.9. For adjusting the pH, it is preferable to use an organic acid having 8 or less carbon atoms.

  As the organic acid having 8 or less carbon atoms, dicarboxylic acid, tricarboxylic acid, and hydroxycarboxylic acid are preferable. Specifically, as the dicarboxylic acid, malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, etc., and as the tricarboxylic acid, citric acid etc. Examples of hydroxycarboxylic acid include glycolic acid, lactic acid, malic acid, tartaric acid, and citric acid. Of these, glycolic acid, lactic acid, malonic acid, maleic acid, and malic acid are preferable. Examples of these organic acid salts include salts with alkali metals, alkaline earth metals, ammonia, and organic amine compounds.

  Two or more of these organic acids may be used in combination, and the content thereof is determined under the condition that the pH is within the above range from the viewpoint of improving the finish of the hair such as gloss and unity. 0.1 to 5.0% by weight in the cleaning material is preferable, 0.2 to 3.0% by weight, more preferably 0.5 to 2.0% by weight.

  In addition to the above-described components, the cleaning agent of the present invention can be appropriately mixed with components used in ordinary hair cleaning agents depending on the purpose. Such components include, for example, anti-dandruff agents; vitamins; bactericides; anti-inflammatory agents, antiseptics; chelating agents; moisturizers such as sorbitol and panthenol; colorants such as dyes and pigments; Viscosity modifiers such as glycols and clay minerals; pH adjusters such as potassium hydroxide; plant extracts; pearling agents; fragrances; dyes; ultraviolet absorbers; antioxidants and other encyclopedias of shampoos Ingredients [ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS)] are listed.

  In addition, the cleaning agent of the present invention is preferably a shampoo composition, a shampoo composition, a rinse-in shampoo, or the like used in the bathroom.

  The pH in the following Examples and Comparative Examples is a value at 25 ° C. when diluted 20 times by weight with water.

Examples 1-3 and Comparative Examples 1-3
The shampoo composition shown in Table 1 was prepared and the sensory evaluation was performed.

(Evaluation methods)
10 panelists applied each sample solution to the hair bundle using a hair bundle (20 g of female hair that had been subjected to a hair bleaching process once, about 30 cm), rinsed well after lathering (15 seconds). The average of the points evaluated based on was ranked. The gloss was evaluated by comparison with an untreated hair bundle (reference hair) after drying.

(Evaluation criteria)
・ Bubbling 4: Very bubbling 3: Bubbling is good 2: Slight bubbling is good 1: Not very bubbling 0: Bubbling is not good

・ Fine fineness 4: Very fine 3: Fine fine 2: Slightly fine 1: Not very fine 0: Not fine

・ Softness of foam 4: Very soft 3: Soft 2: Slightly soft 1: Not very soft 0: Not soft

-Smoothness at the start of rinsing 4: Very smooth 3: Smooth 2: Slightly smooth 1: Not very smooth 0: Not smooth

-Smoothness at the end of rinsing 4: Very smooth 3: Smooth 2: Slightly smooth 1: Not very smooth 0: Not smooth

・ Gloss 4: The gloss of the treated hair is slightly glossy 3: The gloss of the treated hair is slightly glossy 2: Neither can be said 1: The standard hair is slightly glossy 0: The standard hair Is more glossy

(Rank)
A: Average evaluation score is 3.1 to 4.0
○: Average evaluation score is 2.1 to 3.0
Δ: Average evaluation score is 1.1 to 2.0
X: Average evaluation score is 0 to 1.0

Example 4 Transparent shampoo
(weight%)
Polyoxyethylene (2) sodium lauryl ether sulfate 15.0
Palm oil fatty acid monoethanolamide 0.4
Amidopropyl betaine laurate 1.5
Polyoxyethylene (16) lauryl ether 2.0
Polypropylene glycol (Mw = 400) 0.5
Benzyl alcohol 0.2
Cationized cellulose 0.5
Dimethyldiallylammonium chloride / acrylamide copolymer solution ^* 1.0
Malic acid 0.8
48 wt% sodium hydroxide appropriate amount edetate disodium 0.4
Fragrance Trace amount Purified water Balance *: Marquat 550 (effective 8% by weight, ONDEO NALCO)

  The above shampoo (pH = 3.7) is excellent in foam volume and fineness / softness / smoothness of foam, smoothness in rinsing, glossiness of hair after drying, elasticity, suppleness and cohesion. It was excellent in stability.

Example 5 Pearl appearance shampoo
(weight%)
Polyoxyethylene (2) sodium lauryl ether sulfate 10.0
Sodium lauryl sulfate 5.0
Palm oil fatty acid monoethanolamide 0.8
Myristyl alcohol 1.0
Amidopropyl betaine laurate 1.0
Polyoxyethylene (16) lauryl ether 2.0
Ethylene glycol distearate 2.0
Polypropylene glycol (Mw = 400) 1.0
Cationized cellulose 0.5
High molecular weight dimethylpolysiloxane (d = 1000-2700) 1.0
Dimethylpolysiloxane (d = 50-300) 1.4
Dimethyldiallylammonium chloride / acrylamide copolymer solution ^* 1.5
Malic acid 0.8
48 wt% sodium hydroxide appropriate amount Eucalyptus extract (dry weight 0.2 wt%) 0.05
Hydrolyzed conchiolin solution (dry weight 3% by weight) 0.05
Soybean extract (0.4% dry matter) 0.05
Panax ginseng extract (dry weight 3%) 0.05
Rice germ oil 0.05
Edetate disodium 0.4
Sodium chloride 0.2
Fragrance Trace amount Purified water Balance *: Marquat 550 (effective 8% by weight, ONDEO NALCO)

  The above shampoo (pH = 3.7) is excellent in foam volume and fineness / softness / smoothness of foam, smoothness in rinsing, glossiness of hair after drying, elasticity, suppleness and cohesion. It was excellent in stability.

Example 6 Anti-dandruff shampoo
(weight%)
Polyoxyethylene (2) sodium lauryl ether sulfate 15.0
Palm oil fatty acid monoethanolamide 0.4
Amidopropyl betaine laurate 1.0
Polyoxyethylene (16) lauryl ether 2.0
Ethylene glycol distearate 2.0
Polypropylene glycol (Mw = 400) 0.5
Cationized cellulose 0.5
High molecular weight dimethylpolysiloxane (d = 1000-2700) 1.0
Dimethylpolysiloxane (d = 50-300) 1.4
Dimethyldiallylammonium chloride / acrylamide copolymer solution ^* 1.5
Malic acid 0.8
48 wt% sodium hydroxide appropriate amount Cocoyl benzalkonium chloride 0.5
Edetate disodium 0.4
Fragrance Trace amount Purified water Balance *: Marquat 550 (effective 8% by weight, ONDEO NALCO)

  The above shampoo (pH = 3.7) is excellent in foam volume and fineness / softness / smoothness of foam, smoothness in rinsing, glossiness of hair after drying, elasticity, suppleness and cohesion. It was excellent in stability.

Claims (3)

Next ingredient (A) ~ (C)
(A) Anionic surfactant 1 to 50% by weight
(B) Dialkyl diallylammonium salt / acrylamide copolymer 0.01 to 1% by weight
(C) Fatty acid alkanolamide and polyoxyethylene alkyl ether Total 0.1 to 10% by weight
Containing weight ratio of component (B) and component (C) is 1: 50 to 1: 5, hair wash pH at 25 ° C. when diluted 20 times the weight with water is 2 to 4.5. Furthermore, the hair washing agent of Claim 1 which contains cationic polymers other than a component (B) as a component (D). Furthermore, the hair washing agent of Claim 1 or 2 containing the conditioning component chosen from a cationic surfactant, silicones, and an oil agent as a component (E).