JP4046894B2 - Permanent wave treatment agent - Google Patents
Permanent wave treatment agent Download PDFInfo
- Publication number
- JP4046894B2 JP4046894B2 JP15136499A JP15136499A JP4046894B2 JP 4046894 B2 JP4046894 B2 JP 4046894B2 JP 15136499 A JP15136499 A JP 15136499A JP 15136499 A JP15136499 A JP 15136499A JP 4046894 B2 JP4046894 B2 JP 4046894B2
- Authority
- JP
- Japan
- Prior art keywords
- permanent wave
- agent
- wave
- wave treatment
- treatment agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 14
- 239000004202 carbamide Substances 0.000 claims description 7
- CNWSQCLBDWYLAN-UHFFFAOYSA-N butylurea Chemical compound CCCCNC(N)=O CNWSQCLBDWYLAN-UHFFFAOYSA-N 0.000 claims description 6
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 claims description 6
- JUVJQIPDVWOVNP-UHFFFAOYSA-N hexylurea Chemical compound CCCCCCNC(N)=O JUVJQIPDVWOVNP-UHFFFAOYSA-N 0.000 claims description 6
- MONRWRVYLOHUFA-UHFFFAOYSA-N pentylurea Chemical compound CCCCCNC(N)=O MONRWRVYLOHUFA-UHFFFAOYSA-N 0.000 claims description 6
- -1 phosphate compound Chemical class 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 2
- 235000019838 diammonium phosphate Nutrition 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Hair Curling (AREA)
Description
【０００１】
【発明の属する技術分野】
この発明は毛髪にパーマネントウェーブを与えるパーマネントウェーブ処理剤に関する。
【０００２】
【従来の技術】
一般に、毛髪のパーマネントウェーブは、毛髪に存在するＳ−Ｓ結合（ジスルフィド結合）をパーマネントウェーブ処理剤第１剤により一旦化学的に切断し、同第２剤により再びＳ−Ｓ結合が再形成される間、円筒形のロッドに巻き付けるなどカールした状態を保持することによって行われている。
しかしながら、従来のパーマネントウェーブ処理剤では、ウェーブ処理するのに、少なくとも１剤塗布後、２剤塗布後各１５分の計３０分の長時間カールした状態を保つ必要があった。また、ウェーブ処理をした毛髪が洗髪によって形崩れしやすく、ウェーブの保持力が十分ではなかった。
そのため、チオ尿素、チオ乳酸などの還元剤、ベンジルオキシエタノールなどの浸透剤の添加、あるいは、アニオン界面活性剤、両性界面活性剤とカチオン化セルロースを含有したパーマネントウェーブ処理剤（特公平４−２４３２２号公報）等が提案されているが、未だ十分に満足できる結果は得られていない。
【０００３】
【発明が解決しようとする課題】
そこで、本発明では、ウェーブ処理する際の放置時間が短く且つ保持力の大きなパーマネントウェーブ処理剤を提供することを目的としている。
【０００４】
【課題を解決するための手段】
本発明者は鋭意研究を重ねた結果、（Ａ）炭酸グアニジン、（Ｂ）尿素、Ｎ−ブチル尿素、Ｎ−ペンチル尿素、Ｎ−ヘキシル尿素より選ばれる１種または２種以上および（Ｃ）りん酸塩化合物を組み合わせることにより、パーマネントウェーブ処理時の放置時間の短縮とウェーブの保持にすぐれた効果があることを見い出し本発明を完成するに至った。
【０００５】
以下、本発明において記述する。この発明に係わるパーマネントウェーブ処理剤は、（Ａ）炭酸グアニジン、（Ｂ）尿素、Ｎ−ブチル尿素、Ｎ−ペンチル尿素、Ｎ−ヘキシル尿素より選ばれる１種または２種以上および（Ｃ）りん酸塩化合物が必須成分として含有される。
【０００６】
第一の必須成分である炭酸グアニジンは、Ｃ２Ｈ１０Ｎ６・Ｈ２ＣＯ３で表される化合物であり、第二の必須成分として、尿素、Ｎ−ブチル尿素、Ｎ−ペンチル尿素、Ｎ−ヘキシル尿素より選ばれる１種又は２種以上を用いることができる。特に尿素は使用性の面から好適に使用することができる。第３の必須成分であるリン酸塩化合物としては、りん酸一水素アンモニウム、りん酸二水素アンモニウム、りん酸一水素ナトリウム、りん酸二水素ナトリウムなどを用いることができ、中でもりん酸一水素アンモニウムが効果、使用性の面から好適に使用することができる。
【０００７】
本発明のパーマネントウェーブ処理剤における（Ａ）炭酸グアニジンおよび（Ｂ）尿素、Ｎ−ブチル尿素、Ｎ−ペンチル尿素、Ｎ−ヘキシル尿素の配合量は、各々０．０１〜７．０重量％とする。０．０１％未満では、充分な効果が得られない。また、７．０重量％を越えるとコストアップおよび安定性の問題が起こる。０．０１〜７．０重量％が効果・コストの点から望ましく、特に０．１〜４．０重量％が効果、安定性の点からより好ましい。
【０００８】
パーマネントウェーブ処理剤の形態としては、透明な液状の他、乳液状、クリーム状、泡状、ジェル状、粉末等が挙げられる。
【００１０】
さらに、（Ａ）炭酸グアニジン、（Ｂ）尿素、Ｎ−ブチル尿素、Ｎ−ペンチル尿素、Ｎ−ヘキシル尿素より選ばれる１種または２種以上および（Ｃ）りん酸塩化合物を必須成分とするこの発明に係わるパーマネントウェーブ用処理剤では、前記必須成分以外に通常のパーマネントウェーブ用処理剤に用いられる通常の成分、すなわち、香料、界面活性剤、精製水、多価アルコール、保湿剤、金属イオン封鎖剤、アルカリ剤、毛髪保護剤、還元剤、酸化剤等を必要に応じて配合することができる。
【００１１】
【実施例】
以下、この発明に係わるパーマネントウェーブ処理剤の効果を実施例、比較例を挙げることにより、一層明確にする。但し、この発明は以下の実施例により限定されるものではない。
【００１２】
実施例１及び比較例３〜７
表１に示す組成のパーマネントウェーブ処理剤第１剤を調製した。また、表２に示す組成のパーマネントウェーブ処理剤第２剤を調製した。これらの組成物を用いて、各パーマネントウェーブ処理剤のウェーブ形成能、ウェーブ保持能を評価した。
【００１３】
【表１】
【００１４】
【表３】
【００１５】
試験例１
各パーマネントウェーブ処理剤第１剤と、第２剤の放置時間によるウェーブ効率、及びその後のウェーブ保持率について、ｋｉｒｂｙ法（日本パーマネントウェーブ工業組合，‘ＳＣＩＥＮＣＥ
ｏｆ ＷＡＶＥ’，新美容出版）による結果を表３に示す。
【００１６】
【表３】
【００１７】
表３に示す結果から明らかなように、実施例１のパーマネントウェーブ処理剤は、比較例３〜７のパーマネントウェーブ処理剤に比べて、放置時間が短時間でもウェーブ効率が充分で、それ以上の放置時間は必要ないことがわかる。また、ウェーブ保持力も優れていることがわかる。
【００１８】
【発明の効果】
本発明のパーマネントウェーブ処理剤は、放置時間が短時間で済み、また、形成したウェーブを長期的に保持することができるパーマネントウェーブ処理剤である。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a permanent wave treating agent for imparting permanent wave to hair.
[0002]
[Prior art]
In general, in permanent wave of hair, SS bonds (disulfide bonds) existing in hair are chemically cut once by the first agent of the permanent wave treatment agent, and SS bonds are re-formed by the second agent. In the meantime, it is carried out by holding a curled state such as winding around a cylindrical rod.
However, with the conventional permanent wave treating agent, it was necessary to keep the curled state for a total of 30 minutes for a total of 15 minutes after applying at least one agent and 15 minutes after applying the agent for wave treatment. Moreover, the wave-treated hair was easily deformed by washing the hair, and the wave holding power was not sufficient.
Therefore, a reducing agent such as thiourea or thiolactic acid, a penetrating agent such as benzyloxyethanol, or a permanent wave treatment agent containing an anionic surfactant, an amphoteric surfactant and a cationized cellulose (Japanese Patent Publication No. 4-24322). However, satisfactory results have not been obtained yet.
[0003]
[Problems to be solved by the invention]
Therefore, an object of the present invention is to provide a permanent wave treatment agent having a short standing time during wave treatment and a large holding power.
[0004]
[Means for Solving the Problems]
As a result of extensive research, the present inventor has found that (A) guanidine carbonate, (B) urea, N-butylurea, N-pentylurea, N-hexylurea, or one or more selected from (C) phosphorus By combining the acid salt compound, the inventors have found that there are excellent effects in shortening the standing time during permanent wave treatment and maintaining the wave, and have completed the present invention.
[0005]
Hereinafter, it describes in this invention. The permanent wave treating agent according to the present invention comprises (A) one or more selected from (A) guanidine carbonate, (B) urea, N-butylurea, N-pentylurea, N-hexylurea, and (C) phosphoric acid. A salt compound is contained as an essential component.
[0006]
The first essential component guanidine carbonate is a compound represented by C2H10N6.H2CO3, and the second essential component is selected from urea, N-butylurea, N-pentylurea, and N-hexylurea. Or 2 or more types can be used. In particular, urea can be preferably used from the viewpoint of usability. As the phosphate compound as the third essential component, ammonium monohydrogen phosphate, ammonium dihydrogen phosphate, sodium monohydrogen phosphate, sodium dihydrogen phosphate and the like can be used, among which ammonium monohydrogen phosphate. However, it can be used suitably from the surface of an effect and usability.
[0007]
The blending amount of (A) guanidine carbonate and (B) urea, N- butylurea , N- pentylurea and N- hexylurea in the permanent wave treating agent of the present invention is 0.01 to 7.0% by weight, respectively. . If it is less than 0.01%, a sufficient effect cannot be obtained. On the other hand, if it exceeds 7.0% by weight, there are problems of cost increase and stability. 0.01 to 7.0% by weight is desirable from the viewpoint of effect and cost, and 0.1 to 4.0% by weight is more preferable from the viewpoint of effect and stability.
[0008]
Examples of the form of the permanent wave treating agent include a transparent liquid, an emulsion, a cream, a foam, a gel, and a powder.
[0010]
Further, (A) one or more selected from guanidine carbonate, (B) urea, N-butylurea, N-pentylurea, N-hexylurea and (C) a phosphate compound as essential components In the permanent wave treating agent according to the invention, in addition to the essential components, usual components used in ordinary permanent wave treating agents, that is, perfume, surfactant, purified water, polyhydric alcohol, humectant, sequestering metal ion. An agent, an alkaline agent, a hair protecting agent, a reducing agent, an oxidizing agent, etc. can be blended as necessary.
[0011]
【Example】
Hereinafter, the effects of the permanent wave treating agent according to the present invention will be further clarified by giving examples and comparative examples. However, the present invention is not limited to the following examples.
[0012]
Example 1 and Comparative Examples 3-7
A permanent wave treating agent first agent having the composition shown in Table 1 was prepared. Moreover, the permanent wave processing agent 2nd agent of the composition shown in Table 2 was prepared. Using these compositions, the wave forming ability and wave retention ability of each permanent wave treating agent were evaluated.
[0013]
[Table 1]
[0014]
[Table 3]
[0015]
Test example 1
About the wave efficiency by the standing time of each permanent wave processing agent 1st agent and the 2nd agent, and the subsequent wave retention, Kirby method (Japan Permanent Wave Industrial Association, 'SCIENCE
of WAVE ', result of the new beauty publication) are shown in Table 3.
[0016]
[Table 3]
[0017]
As is clear from the results shown in Table 3 , the permanent wave treatment agent of Example 1 has sufficient wave efficiency even if the standing time is short compared with the permanent wave treatment agents of Comparative Examples 3 to 7, and more than that. It can be seen that no waiting time is required. Moreover, it turns out that the wave holding power is also excellent.
[0018]
【The invention's effect】
The permanent wave treatment agent of the present invention is a permanent wave treatment agent that can be left for a short time and can retain the formed wave for a long period of time.
Claims (1)
（Ａ）炭酸グアニジン
（Ｂ）尿素、Ｎ−ブチル尿素、Ｎ−ペンチル尿素、Ｎ−ヘキシル尿素より選ばれる１種または２種以上
（Ｃ）りん酸塩化合物
とを含有することを特徴とするパーマネントウェーブ処理剤組成物。 The following components (A), (B) and (C):
(A) Guanidine carbonate
(B) One or more selected from urea, N-butylurea, N-pentylurea, N-hexylurea
(C) A permanent wave treating agent composition comprising a phosphate compound .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15136499A JP4046894B2 (en) | 1999-05-31 | 1999-05-31 | Permanent wave treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15136499A JP4046894B2 (en) | 1999-05-31 | 1999-05-31 | Permanent wave treatment agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000344634A JP2000344634A (en) | 2000-12-12 |
| JP4046894B2 true JP4046894B2 (en) | 2008-02-13 |
Family
ID=15516936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15136499A Expired - Lifetime JP4046894B2 (en) | 1999-05-31 | 1999-05-31 | Permanent wave treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4046894B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4905478B2 (en) * | 2009-01-27 | 2012-03-28 | 有限会社湘南ハーベスト | Mainly the muzzle, the permutation correction perm |
| JP2014189528A (en) * | 2013-03-28 | 2014-10-06 | Milbon Co Ltd | Hair cosmetic |
-
1999
- 1999-05-31 JP JP15136499A patent/JP4046894B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000344634A (en) | 2000-12-12 |
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