JP4046882B2 - Copy form - Google Patents

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Publication number
JP4046882B2
JP4046882B2 JP02328099A JP2328099A JP4046882B2 JP 4046882 B2 JP4046882 B2 JP 4046882B2 JP 02328099 A JP02328099 A JP 02328099A JP 2328099 A JP2328099 A JP 2328099A JP 4046882 B2 JP4046882 B2 JP 4046882B2
Authority
JP
Japan
Prior art keywords
layer
developer
dye
upper sheet
copy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP02328099A
Other languages
Japanese (ja)
Other versions
JP2000218936A (en
Inventor
好則 越智
学 藤井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Forms Co Ltd
Original Assignee
Toppan Forms Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Forms Co Ltd filed Critical Toppan Forms Co Ltd
Priority to JP02328099A priority Critical patent/JP4046882B2/en
Publication of JP2000218936A publication Critical patent/JP2000218936A/en
Application granted granted Critical
Publication of JP4046882B2 publication Critical patent/JP4046882B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【0001】
【発明の属する技術分野】
本発明は、上位シートに記入することによって下位シートに複写記入する複写帳票に関し、特に、控えとなる上位シートの裏面にも複写記入されることによって記入事項の改ざんを防止し得る複写帳票に関する。
【0002】
【従来の技術】
従来のこの種複写帳票は、上位シートの裏面側に染料内包マイクロカプセル剤を設ける一方、下位シートの表面側には、顕色剤層を設けるとともに、この顕色剤層の表面に転移性顕色剤層を設けている。
【0003】
【発明が解決しようとする課題】
この従来例によると、下位シートの表面への複写は、その表面に設けた顕色剤層と、上位シートの裏面に設けた染料内包マイクロカプセル剤層との反応によってなされるが、顕色剤層の表面には転移性顕色剤層が存在するので、複写像が不鮮明であるという不都合がある。本発明は、この不都合を解消した複写帳票を提供することを目的とする。
【0004】
【課題を解決するための手段】
この目的を達成するために本願の請求項1に記載した複写帳票は、裏面側に染料内包マイクロカプセル剤層を設けた上位シートの下位に下位シートを重ね合わせてなり、この下位シートの表面側には、染料内包マイクロカプセル剤と顕色剤とからなる自己発色剤層を設けるとともに、この自己発色剤層の表面に、顕色剤、流動性油分、ワックスを主成分とする転移性顕色剤層を設けたものである。
【0005】
【発明の実施の形態】
以下、本発明を複写領収証に適用した場合の好適な実施形態を添付図面に基づいて詳細に説明する。ここにおいて、図1は平面図、図2は図1のA−A線断面図である。
【0006】
図1及び図2に示すように、複写領収証1は、一端側を接着力の弱い弱接着剤2で分離可能に綴じ合わせた控えとなる上位シート3と発行先に渡す下位シート4からなる。前記上位シート3の表面には、図1に示すように、「領収証」なる標題5の下に、領収年月日記入欄6、発行先記入欄7、領収金額記入欄8、領収内容記入欄9の各記入欄を設けるとともに、発行者表示10をあらかじめ印刷している。
【0007】
図2に示すように、上位シート3の裏面側には、領収年月日記入欄6、発行先記入欄7、領収金額記入欄8、領収内容記入欄9の各記入欄に対応する部分に、染料内包マイクロカプセル剤層11を設けている。この染料内包マイクロカプセル剤層11を構成するマイクロカプセルとしては、公知のものを使用することができるが、スポット的に塗布でき、加熱せずとも速やかに乾燥できる紫外線硬化型インキ化したものが好適である。
【0008】
一方、下位シート4の表面側には、図示していないが、各記入欄6,7,8,9の下位に対応する位置に、それぞれ同一の記入欄を設け、また、図2に示すように、上位シート3の染料内包マイクロカプセル剤層11に対向する部分に、公知の染料内包マイクロカプセル剤と顕色剤とからなる自己発色剤層12を設けるとともに、この自己発色剤層12の表面に転移性顕色剤層13を設けている。
【0009】
この転移性顕色剤層13は、非水系の転移性顕色剤インキとして調製され、顕色剤、流動性油分、ワックスを主成分とするもので、その他必要に応じて、バインダー、紫外線吸収剤、光重合開始剤、増粘度剤、ゲル化剤等の公知の補助剤を添加して調製するものである。
【0010】
顕色剤としては、例えば、粘度類、フェノール樹脂、芳香族カルボン酸の多価金属塩等やこれらの混合物を使用でき、特に、印字の良好な保存性から2,2−ビスフェノールスルホン化合物の亜鉛塩等が好適である。また、流動性油分としては、無色であって、発色剤と顕色剤との反応を阻害するような不飽和二重結合を有さないもので、かつ、粘度が低く、コーティング適正が良好なものがよく、例えば芳香族を含まない潤滑油や、ノルマルパラフィンが好適である。さらに、ワックスとしては、無色で、融点が55〜85℃、ワックスの針入度が5(25℃)程度の比較的硬めのものをベースワックスとして用い、かつ、転写性と汚染性を制御する目的で、これに軟質ワックスを添加して硬度を低く調製して用いるもので、例えばカルナバワックス、木ロウ、パラフィンワックス、ココナッツワックス等がある。
【0011】
なお、転移性顕色剤インキには、エチレン−酢酸ビニル共重合体を添加するのがよく、これは、この共重合体はワックスとの相溶性が高く、インキの粘度を上昇させる作用を有し、上位シート3の裏面側に塗布した染料内包マイクロカプセル剤層11への接着特性を高める作用を奏するからである。
【0012】
続いて、上述のように構成した複写領収証1の使用方法について説明する。上位シート3の各記入欄6,7,8,9にボールペン等の適宜な筆記用具で所定事項を記入すると、筆圧がかかることによって、上位シート3の裏面には、転移性顕色剤層13の転移性顕色剤インキが転移し、染料内包マイクロカプセル剤層11の染料と反応して発色し、同一内容が複写される。これと同時に、下位シート4の表面には、自己発色剤層12の顕色剤が前記染料内包マイクロカプセル剤層11の染料と反応して発色するとともに、前記自己発色剤層12の顕色剤と染料とが反応して発色することにより、筆記事項と同一内容が鮮明に複写される。
【0013】
ここで、上位シート3と下位シート4とを分離し、複写記入された下位シート4を発行先に手渡す一方、上位シート3を発行元の控えとして保管するものである。この際、複写領収証1の発行担当者や経理担当者が上位シート3の記載内容を改ざんしても、前記上位シート3の裏面には正規の記載内容が複写記入されているので、前記上位シート3の表裏面の記載内容を比較すれば、表面側の記載内容が正規のものであるか、改ざんされたものであるかを、一目で判別することができる。
【0014】
なお、本発明は上述した実施形態に限定されるものではなく、例えば、上位シート3に設ける染料内包マイクロカプセル剤層11と、下位シート4に設ける転移性顕色剤層13及び自己発色剤層12を、各記入欄6,7,8,9対応部分だけでなく、各シート3,4の全面に設けてもよい。また、本発明を複写領収証1以外の改ざん防止が必要な複写帳票にも適用可能なことはもちろんである。さらに、上位シート3と下位シート4とを接着力の強い強接着剤で線綴じし、線綴じ部分の内側に切り用ミシン目を設けてもよい。
【0015】
【発明の効果】
以上説明したところで明らかなように、本発明の請求項1に記載した複写帳票によれば、下位シートへの複写記入を鮮明に行うことができるほか、上位シートの裏面には下位シートへの複写記入内容と同一の正規の記入内容が複写されるので、上位シートの表裏面の記載内容を比較することで、上位シート表面側の記載内容が正規のものか否かが一目で判別可能であり、改ざん防止に有効であるという効果を奏する。
【図面の簡単な説明】
【図1】 複写領収証の平面図。
【図2】 図1のA−A線断面図。
【符号の説明】
1 複写領収証
3 上位シート
4 下位シート
6 領収年月日記入欄
7 発行先記入欄
8 領収金額記入欄
9 領収内容記入欄
11 染料内包マイクロカプセル剤層
12 自己発色剤層
13 転移性顕色剤層
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a copy form for copying and filling in a lower sheet by filling in an upper sheet, and more particularly, to a copy form that can prevent falsification of entry items by being copied and written on the back side of the upper sheet as a copy.
[0002]
[Prior art]
In this conventional copy form, a dye-encapsulating microcapsule is provided on the back side of the upper sheet, while a developer layer is provided on the front side of the lower sheet, and a transferable developer is formed on the surface of the developer layer. A colorant layer is provided.
[0003]
[Problems to be solved by the invention]
According to this conventional example, copying on the surface of the lower sheet is performed by a reaction between the developer layer provided on the surface and the dye-encapsulating microcapsule layer provided on the back surface of the upper sheet. Since there is a transferable developer layer on the surface of the layer, there is a disadvantage that the copied image is unclear. It is an object of the present invention to provide a copy form that eliminates this inconvenience.
[0004]
[Means for Solving the Problems]
In order to achieve this object, the copy form according to claim 1 of the present application is formed by superposing a lower sheet on the lower side of an upper sheet provided with a dye-encapsulating microcapsule layer on the back side. the, provided with a self-color former layer comprising a dye containing microcapsules and a developer, the surface of the self-coloring agent layer, a developer, metastatic color appearance mainly fluidity oil, wax An agent layer is provided.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, a preferred embodiment in the case where the present invention is applied to a copy receipt will be described in detail with reference to the accompanying drawings. Here, FIG. 1 is a plan view, and FIG. 2 is a cross-sectional view taken along line AA of FIG.
[0006]
As shown in FIGS. 1 and 2, the copy receipt 1 is composed of an upper sheet 3 serving as a copy of one end side separably bound with a weak adhesive 2 having a weak adhesive force and a lower sheet 4 delivered to an issue destination. As shown in FIG. 1, the upper sheet 3 has a receipt date entry column 6, an issuer entry entry column 7, a receipt amount entry entry column 8, a receipt content entry entry column, under the title 5 “Receipt”. Each entry field 9 is provided and an issuer display 10 is printed in advance.
[0007]
As shown in FIG. 2, on the back side of the upper sheet 3, there are portions corresponding to the entry fields of the receipt date entry field 6, the issuer entry entry field 7, the receipt amount entry field 8, and the receipt content entry field 9. The dye-encapsulating microcapsule layer 11 is provided. As the microcapsules constituting the dye-encapsulating microcapsule layer 11, known ones can be used, but those made into ultraviolet curable inks that can be applied in a spot manner and can be dried quickly without heating are preferable. It is.
[0008]
On the other hand, although not shown, on the front side of the lower sheet 4, the same entry fields are provided at positions corresponding to the lower positions of the entry fields 6, 7, 8 and 9, respectively, as shown in FIG. In addition, a self-coloring agent layer 12 composed of a known dye-encapsulating microcapsule agent and a developer is provided on a portion of the upper sheet 3 facing the dye-encapsulating microcapsule layer 11, and the surface of the self-coloring agent layer 12 is provided. Is provided with a transferable developer layer 13.
[0009]
This transferable developer layer 13 is prepared as a non-aqueous transferable developer ink, and is mainly composed of a developer, fluid oil, and wax. It is prepared by adding a known auxiliary agent such as an agent, a photopolymerization initiator, a thickener, and a gelling agent.
[0010]
As the developer, for example, viscosity, phenol resin, polyvalent metal salt of aromatic carboxylic acid, or a mixture thereof can be used. In particular, zinc of 2,2-bisphenolsulfone compound is used because of good storage stability of printing. Salts and the like are preferred. The fluid oil is colorless and does not have an unsaturated double bond that inhibits the reaction between the color former and the developer, and has a low viscosity and good coating suitability. For example, lubricating oil not containing aromatics and normal paraffin are preferable. Further, as the wax, a relatively hard wax having a colorless melting point of 55 to 85 ° C. and a penetration of the wax of about 5 (25 ° C.) is used as the base wax, and the transferability and contamination are controlled. For the purpose, a soft wax is added to prepare a low hardness, and examples thereof include carnauba wax, wood wax, paraffin wax, and coconut wax.
[0011]
It should be noted that an ethylene-vinyl acetate copolymer is preferably added to the transfer developer ink, and this copolymer is highly compatible with wax and has an action of increasing the viscosity of the ink. This is because the adhesive property to the dye-encapsulating microcapsule layer 11 applied to the back side of the upper sheet 3 is enhanced.
[0012]
Next, a method of using the copy receipt 1 configured as described above will be described. When a predetermined item is entered in each entry column 6, 7, 8, 9 of the upper sheet 3 with an appropriate writing tool such as a ballpoint pen, the transfer pressure developer layer is formed on the back surface of the upper sheet 3 by applying writing pressure. Thirteen transferable developer inks transfer, react with the dye in the dye-encapsulated microcapsule layer 11 to develop a color, and the same content is copied. At the same time, the developer of the self-color-developing layer 12 reacts with the dye of the dye-encapsulating microcapsule layer 11 to develop color on the surface of the lower sheet 4 and the developer of the self-color-developing layer 12 As the color reacts with the dye, the same content as the written item is clearly copied.
[0013]
Here, the upper sheet 3 and the lower sheet 4 are separated, and the copied lower sheet 4 is handed over to the issue destination, while the upper sheet 3 is stored as a copy of the issuer. At this time, even if the person in charge of issuing the copy receipt 1 or the person in charge of accounting falsifies the contents of the upper sheet 3, since the regular contents of the upper sheet 3 are copied and entered, the upper sheet 3 3 is compared, it can be discriminated at a glance whether the description on the front side is regular or has been tampered with.
[0014]
The present invention is not limited to the above-described embodiment. For example, the dye-encapsulating microcapsule layer 11 provided in the upper sheet 3, the transferable developer layer 13 and the self-coloring agent layer provided in the lower sheet 4. 12 may be provided on the entire surface of each sheet 3, 4 as well as the corresponding part of each entry column 6, 7, 8, 9. Of course, the present invention can be applied to copy forms other than the copy receipt 1 that need to be prevented from being falsified. Furthermore, the upper sheet 3 and the lower sheet 4 may be line-bound with a strong adhesive having a strong adhesive force, and a cut perforation may be provided inside the line-bound portion.
[0015]
【The invention's effect】
As is apparent from the above description, according to the copy form described in claim 1 of the present invention, it is possible to clearly carry out copy entry on the lower sheet, and to copy the lower sheet on the lower surface of the upper sheet. Since the same regular entry contents as the entry contents are copied, it is possible to determine at a glance whether the description contents on the upper sheet front side are genuine by comparing the description contents on the front and back surfaces of the upper sheet. It is effective in preventing falsification.
[Brief description of the drawings]
FIG. 1 is a plan view of a copy receipt.
FIG. 2 is a cross-sectional view taken along line AA in FIG.
[Explanation of symbols]
1 Copy receipt 3 Upper sheet 4 Lower sheet 6 Receipt date entry column 7 Issuance destination entry column 8 Receipt amount entry column 9 Receipt content entry column 11 Dye-encapsulated microcapsule layer 12 Self-coloring agent layer 13 Transferable developer layer

Claims (1)

裏面側に染料内包マイクロカプセル剤層を設けた上位シートの下位に下位シートを重ね合わせてなり、この下位シートの表面側には、染料内包マイクロカプセル剤と顕色剤とからなる自己発色剤層を設けるとともに、この自己発色剤層の表面に、顕色剤、流動性油分、ワックスを主成分とする転移性顕色剤層を設けたことを特徴とする複写帳票。The lower sheet is superimposed on the lower side of the upper sheet provided with the dye-encapsulated microcapsule layer on the back side, and the self-coloring agent layer comprising the dye-encapsulated microcapsule and the developer is formed on the surface side of the lower sheet. And a transferable developer layer mainly composed of a developer, fluid oil, and wax, on the surface of the self-coloring agent layer.
JP02328099A 1999-01-29 1999-01-29 Copy form Expired - Fee Related JP4046882B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP02328099A JP4046882B2 (en) 1999-01-29 1999-01-29 Copy form

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP02328099A JP4046882B2 (en) 1999-01-29 1999-01-29 Copy form

Publications (2)

Publication Number Publication Date
JP2000218936A JP2000218936A (en) 2000-08-08
JP4046882B2 true JP4046882B2 (en) 2008-02-13

Family

ID=12106201

Family Applications (1)

Application Number Title Priority Date Filing Date
JP02328099A Expired - Fee Related JP4046882B2 (en) 1999-01-29 1999-01-29 Copy form

Country Status (1)

Country Link
JP (1) JP4046882B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4503815B2 (en) * 2000-11-28 2010-07-14 トッパン・フォームズ株式会社 Pressure-sensitive copy sheet for preventing falsification

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