JP4012761B2 - Coke oven carbonization chamber furnace wall adhering carbon removal device operation method - Google Patents

Coke oven carbonization chamber furnace wall adhering carbon removal device operation method Download PDF

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Publication number
JP4012761B2
JP4012761B2 JP2002101762A JP2002101762A JP4012761B2 JP 4012761 B2 JP4012761 B2 JP 4012761B2 JP 2002101762 A JP2002101762 A JP 2002101762A JP 2002101762 A JP2002101762 A JP 2002101762A JP 4012761 B2 JP4012761 B2 JP 4012761B2
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Prior art keywords
blowing
lance
air
carbonization chamber
blown
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JP2003292963A (en
Inventor
貴史 小川
康彦 大谷
正弘 土岐
久典 加来
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Nippon Steel Corp
Nippon Steel Chemical and Materials Co Ltd
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Nippon Steel Corp
Nippon Steel Chemical Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、コークス炉炭化室内炉壁に付着したカーボンを、エア吹き込みにより燃焼除去することを目的としたカーボン除去方法に関するものである。
【0002】
室炉式コークス炉の炭化室内炉壁には、石炭の乾留時に発生するコークス炉ガスの熱分解によって生じるカーボンが付着する。この炉壁付着カーボンは炉壁レンガの目地を緻密に閉塞し、炭化室から燃焼室へのガスリークを防止するという有効な働きがある一方、そのまま放置しておくと成長して炭化室の有効容積を減少させて炉の生産性を低下させるばかりでなく、押し出し機の押詰りに繋がる原因となる。従って、上記の弊害を防止する為、定期的に付着カーボンを除去する必要がある。この炉壁付着カーボン除去方法としては、特開昭62−161884号公報では噴出ノズルを設けたランスを進退自在に設けて気体を噴出させる方法や、特開平6−248272号公報では噴出ノズルを設けたランスを炭化室内で傾動させ気体を炉壁に吹き付ける方法が開示されている。
【0003】
【発明が解決しようとする課題】
一般的に炭化室内に付着するカーボンの成長速度は、炉温などの影響を受けるため場所によって異なる。また通常、ランスの位置や本数を固定してエアを吹き込む方法では炭化室内に一定の流動パターンが形成されるため、定常的に流速が遅い領域(以下淀み)や、渦等により換気が行われない領域では相対的に付着カーボンの成長速度が大きくなる。従って、炭化室全体に付着するカーボンを均一に除去しつつ、局所的なカーボンの成長を防止することが重要である。
【0004】
しかし、特開昭62−161884号公報の方法では、操業方法が明確化されていないため、任意の位置での操業を継続すると、上記のような局所的なカーボンの成長が起こり押詰りに繋がる。また、特開平6−248272号公報の方法であるランスを傾動させるという操業では、実際にエアの吹き付けが可能な位置が限定されるため、局所的な成長は避けられない。
【0005】
本発明においては、炭化室全体に付着するカーボンを均一に除去しつつ、局所的なカーボンの成長を防止できるコークス炉炭化室内炉壁付着カーボン除去方法を提供することを目的とする。
【0006】
【課題を解決するための手段】
本発明者は局所的なカーボン付着を防止するため、炭化室内に一定の流動パターンが形成されない操業を見出すべく研究した。その研究の結果、本発明は、コークス炉炭化室内の炉壁に付着したカーボンをエア吹き込みによって燃焼させることを目的としたカーボン除去方法であって、ランスの本数と挿入位置、吹き込み流量の異なる2種類以上のパターンを定期的あるいは不定期に変更させることを特徴とするカーボン除去装置の操業方法である。
【0007】
ここで、エアの吹き込みパターンとして、以下に示す吹き込みパターンの組合せが採用できる。
(吹き込みパターンA) 炭化室が最前方(炉の排気口を後方、反対側を前方とする。以下、同じ)から順次第1〜第5装炭口を有し、前記第2〜第4装炭口にエアを吹き込む第1〜第3ランスを前方より順次挿入し、前記ランスのエア吐出孔がランス下端寄りに位置し、第1ランスは吹き込み方向が前方のみであり、第2ランスは吹き込み方向が前方、及び前方斜め下方向であり、第3ランスは吹き込み方向が前方、後方、及び前方斜め下方向であり、これら全てのランスの吹き込み位置を炭化室の中央の高さとし、エアを吹き込むことを特徴とする吹き込みパターン。
(吹き込みパターンB)炭化室が最前方(炉の排気口を後方、反対側を前方とする。以下、同じ)から順次第1〜第5装炭口を有し、前記第2及び第3装炭口にエアを吹き込む第1及び第2ランスを前方より順次挿入し、前記ランスのエア吐出孔がランス下端寄りに位置し、第1ランスは吹き込み方向が前方のみで、吹き込み位置は炭化室室頂直下とし、かつ、第2ランスは吹き込み方向が前方、及び前方斜め下方向で、吹き込み位置は炭化室高さの1/4とし、エアを吹き込むことを特徴とする吹き込みパターン。
【0008】
また、別のエアの吹き込みパターンとして、ランス本数を2本とし、前方のランスは、吹き込み方向が前方のみで、吹き込み位置は炭化室室頂直下とし、かつ、後方のランスは、吹き込み方向が前方、及び前方斜め下方向で、吹き込み位置は炭化室高さの1/4程度とし、エアを吹き込むと、渦流の発生が少なく、CO2の滞留する領域がミニマムに抑えられ、やはり効率よくカーボン除去ができる。
そして、この両パターンのいずれかあるいは両方を採用して前記のようにエアの吹き込みパターンを定期あるいは不定期に変更すると更に効率よくカーボン除去ができる。
【0009】
【発明の実施の形態】
上記した本発明は本発明者らの以下に記す実験結果に基づくものである。上記前者の吹き込みパターンは、図1(a)に示すように3本のランス1a、1b、1cを装炭口2a、2b、2cより炭化室4に挿入する。最前方のランス1aは、吹き込み方向(エア吐出口3aの位置)が前方のみであり、真中のランス1bは、吹き込み方向が前方、及び前方斜め下方向であり、最後方のランス1cは、吹き込み方向が前方、後方、及び前方斜め下方向である。各ランスの挿入位置Hを炭化室中央の高さまでとし、ランスの吐出孔3a、3b、3cよりエアを吐出すると同図(b)に示すようなエア流れを形成する。このエア流れの特徴は淀み部が少ないということである。淀み部が少ないということは、炉内に満遍なくエアが行き渡り炉全体のカーボンの除去が可能となる。
しかし、この吹き込みパターンでは、数カ所に渦が発生する。この様に渦となっている領域は、ランスから供給されるエアとは換気がなされず、局所的にCO2が滞留し、付着カーボンが成長する原因になる。
【0010】
そこで次に、図2(a)に示す前記後者の吹き込みパターンを説明する。前方にのみ吐出孔3aを有するランス1aの挿入位置rを炭化室炉頂直下とし、なおかつ前方及び前方斜め下方向に吐出孔3bを有するランス1bの挿入位置hを炭化室高さの1/4程度とする。ランスの吐出孔3よりエアを吐出すると、同図(b)に示すようなエア流れを形成する。このエア流れの特徴は炉内全体に行き渡る大きな渦を形成することである。大きな一つの渦なので、炉内全体が順次新しいエアを供給され、そして、順次排気側から排気されて換気がなされる。
【0011】
このような渦流の少ない、あるいは、淀みの少ない吹き込みパターンを固定化してもある程度の効率的なカーボン除去の効果はあるが、これら図1(b)と図2(b)はそれぞれ全く異なるエア流れを形成するので、これらの吹き込みパターンのいずれか一つあるいは両方を採用して定期的あるいは不定期にに吹き込みパターンを変更すれば、更に効率的なカーボン除去が可能である。
【0012】
【実施例】
コークス炉実炉において本発明を実施した。まず図1の(a)に示すように本発明請求項2に相当するランス構成で、炭化室4へランス1を挿入位置Hを2500mmとして、風量は8700Nm3/hとした。押し出し電流の上昇が認められた上で本発明請求項3に相当する図2(a)に示すランス配置に変更した。挿入位置rを200mmとし、挿入位置hを1000mmとした。風量は5800Nm3/hとし、操業を継続した結果押し詰りは認められなかった。
【0013】
【発明の効果】
以上のように本発明によれば、エアの吹き込み方向と吹き込み位置を規定し、あるいは、更に異なる2種類以上のパターンを定期的あるいは不定期に変更することで、エア吹き込みによってカーボン付着を効果的に燃焼除去することが可能である。
【図面の簡単な説明】
【図1】(a)は本発明方法を実施するためのカーボン除去装置の縦断側面図である、(b)はこのカーボン除去装置を使用した場合におけるエア流れを示した図である。
【図2】(a)は本発明方法を実施するためのカーボン除去装置の他の例の縦断側面図である、(b)はこのカーボン除去装置を使用した場合におけるエア流れを示した図である。
【符号の説明】
1a、1b、1c ランス
2a、2b、2c 装炭口
3a、3b、3c エア吐出孔
4 炭化室
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a carbon removal method for the purpose of burning and removing carbon adhering to a coke oven carbonization chamber furnace wall by air blowing.
[0002]
Carbon generated by pyrolysis of coke oven gas generated during the dry distillation of coal adheres to the carbonization chamber furnace wall of the chamber type coke oven. This carbon adhering to the furnace wall closes the joints of the furnace wall bricks finely and has an effective function of preventing gas leakage from the carbonization chamber to the combustion chamber. Not only lowers the productivity of the furnace but also leads to clogging of the extruder. Therefore, in order to prevent the above-described adverse effects, it is necessary to periodically remove the attached carbon. As a method for removing the carbon adhering to the furnace wall, JP-A-62-161884 discloses a method in which a lance provided with an ejection nozzle is provided so as to freely advance and retract, and JP-A-6-248272 provides an ejection nozzle. A method is disclosed in which a lance is tilted in a carbonization chamber and gas is blown onto a furnace wall.
[0003]
[Problems to be solved by the invention]
In general, the growth rate of carbon deposited in the carbonization chamber varies depending on the location because it is affected by the furnace temperature and the like. In general, in the method in which air is blown with the position and number of lances fixed, a constant flow pattern is formed in the carbonization chamber, and therefore ventilation is performed by a region where the flow velocity is constantly low (hereinafter referred to as stagnation) or vortices. In a region where there is not, the growth rate of attached carbon is relatively increased. Therefore, it is important to prevent local carbon growth while uniformly removing carbon adhering to the entire carbonization chamber.
[0004]
However, in the method of JP-A-62-161884, the operation method is not clarified. Therefore, if the operation at an arbitrary position is continued, the above-mentioned local carbon growth occurs and leads to clogging. . Further, in the operation of tilting the lance, which is the method disclosed in Japanese Patent Laid-Open No. 6-248272, the position where air can be actually blown is limited, so local growth is inevitable.
[0005]
An object of the present invention is to provide a coke oven carbonization chamber furnace wall adhering carbon removal method capable of preventing local carbon growth while uniformly removing carbon adhering to the entire carbonization chamber.
[0006]
[Means for Solving the Problems]
In order to prevent local carbon adhesion, the present inventor studied to find an operation in which a constant flow pattern was not formed in the carbonization chamber. As a result of the research, the present invention is a carbon removal method for the purpose of burning carbon adhering to the furnace wall in the coke oven carbonization chamber by air blowing, wherein the number of lances, the insertion position, and the blowing flow rate are different. The operation method of the carbon removing apparatus is characterized in that patterns of more than one kind are changed regularly or irregularly.
[0007]
Here, the following combinations of blowing patterns can be employed as the air blowing pattern .
(Blowing pattern A) The carbonization chamber has first to fifth charcoal ports sequentially from the forefront (the furnace exhaust port is the rear and the opposite side is the front; hereinafter the same), and the second to fourth devices The first to third lances for blowing air into the coal spout are sequentially inserted from the front, the air discharge hole of the lance is located near the lower end of the lance, the first lance is blown only in the forward direction, and the second lance is blown The direction is forward and obliquely downward, and the third lance is blown forward, backward, and forward obliquely downward. All these lances are blown at the center height of the coking chamber and blown in air. Blowing pattern characterized by that.
(Blowing pattern B) The carbonization chamber has first to fifth charcoal ports sequentially from the forefront (the furnace exhaust port is the rear and the opposite side is the front; hereinafter the same), and the second and third devices First and second lances for injecting air into the coal spout are sequentially inserted from the front, the air discharge hole of the lance is located near the lower end of the lance, the first lance is blown only in the forward direction, and the blowing position is the coking chamber chamber A blowing pattern in which the second lance is blown in the forward and obliquely downward directions, the blowing position is 1/4 of the height of the carbonization chamber, and blows air.
[0008]
As another air blowing pattern, the number of lances is two, the front lance is blown only in the front direction, the blowing position is just below the top of the coking chamber, and the rear lance is blown in the blowing direction. In addition, the blowing position is about 1/4 of the height of the carbonization chamber in the diagonally downward direction of the front. When air is blown in, there is little vortex generation, the area where CO 2 stays is suppressed to a minimum, and carbon removal is also efficient. Can do.
If either or both of these patterns are employed and the air blowing pattern is changed regularly or irregularly as described above, carbon can be removed more efficiently.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
The above-described present invention is based on the following experimental results of the present inventors. In the former blowing pattern, as shown in FIG. 1A, three lances 1a, 1b, and 1c are inserted into the carbonization chamber 4 through the charring ports 2a, 2b, and 2c. The foremost lance 1a has only the front blowing direction (the position of the air discharge port 3a), the middle lance 1b has the blowing direction forward and obliquely downward, and the rearmost lance 1c blows. The directions are forward, backward, and forward diagonally downward. When the insertion position H of each lance is set to the height of the center of the carbonizing chamber and air is discharged from the discharge holes 3a, 3b, 3c of the lance, an air flow as shown in FIG. The feature of this air flow is that there are few stagnation parts. The fact that there are few stagnation parts means that air is evenly distributed in the furnace and carbon can be removed from the entire furnace.
However, in this blowing pattern, vortices are generated in several places. In this vortex region, the air supplied from the lance is not ventilated, and CO 2 stays locally, causing the attached carbon to grow.
[0010]
Therefore, the latter blowing pattern shown in FIG. The insertion position r of the lance 1a having the discharge hole 3a only in the front is directly below the top of the carbonization chamber furnace, and the insertion position h of the lance 1b having the discharge hole 3b in the forward and front obliquely downward directions is 1/4 of the height of the carbonization chamber. To the extent. When air is discharged from the discharge hole 3 of the lance, an air flow as shown in FIG. This air flow is characterized by the formation of large vortices throughout the furnace. Since it is one large vortex, the whole furnace is sequentially supplied with new air and then exhausted from the exhaust side in order to be ventilated.
[0011]
Even if such a blowing pattern with little swirl or little stagnation is fixed, there is a certain degree of efficient carbon removal effect, but these FIG. 1 (b) and FIG. 2 (b) have completely different air flows. Therefore, if one or both of these blowing patterns are adopted and the blowing pattern is changed regularly or irregularly, more efficient carbon removal is possible.
[0012]
【Example】
The present invention was implemented in an actual coke oven. First, as shown in FIG. 1A, in the lance structure corresponding to claim 2 of the present invention, the insertion position H of the lance 1 into the carbonization chamber 4 is 2500 mm, and the air flow is 8700 Nm 3 / h. After an increase in the pushing current was recognized, the lance arrangement shown in FIG. 2 (a) corresponding to claim 3 of the present invention was changed. The insertion position r was 200 mm, and the insertion position h was 1000 mm. The air volume was 5800 Nm 3 / h, and as a result of continuing the operation, no clogging was observed.
[0013]
【The invention's effect】
As described above, according to the present invention, the air blowing direction and the blowing position are regulated, or two or more different patterns are changed periodically or irregularly, so that carbon adhesion is effectively performed by blowing air. It is possible to burn and remove.
[Brief description of the drawings]
FIG. 1 (a) is a longitudinal side view of a carbon removing device for carrying out the method of the present invention, and FIG. 1 (b) is a view showing an air flow when this carbon removing device is used.
FIG. 2A is a longitudinal side view of another example of a carbon removing device for carrying out the method of the present invention, and FIG. 2B is a diagram showing an air flow when this carbon removing device is used. is there.
[Explanation of symbols]
1a, 1b, 1c Lance 2a, 2b, 2c Charging port 3a, 3b, 3c Air discharge hole 4 Carbonization chamber

Claims (2)

コークス炉炭化室内の炉壁に付着したカーボンを、エアあるいは酸素付加エア(以下、エアという)を吹き込むことによって燃焼させることを目的としたカーボンの除去方法であって、前記エアを吹き込むランスの本数、吹き込み位置、吹き込み流量によって決まる吹き込みパターンを2種類以上あらかじめ決めておき、定期あるいは不定期に前記吹き込みパターンを変更することを特徴とするコークス炉炭化室内炉壁付着カーボン除去装置の操業方法。A carbon removal method for burning carbon adhering to a furnace wall in a coke oven carbonization chamber by blowing air or oxygen-added air (hereinafter referred to as air), the number of lances blowing the air blowing position, keep predetermined blowing flow amount thus determined blowing pattern of two or more, operating method of the coke oven carbonization chamber furnace wall attached decoking apparatus characterized by changing the blowing pattern regularly or irregularly . 請求項1における吹込みパターンが、以下に示す吹き込みパターンA及びBの組合せであることを特徴とするコークス炉炭化室内炉壁付着カーボン除去装置の操業方法。The operation method of the coke oven carbonization chamber furnace wall adhesion carbon removal apparatus, wherein the injection pattern in claim 1 is a combination of the following injection patterns A and B.
(吹き込みパターンA) 炭化室が最前方(炉の排気口を後方、反対側を前方とする。以下、同じ)から順次第1〜第5装炭口を有し、前記第2〜第4装炭口にエアを吹き込む第1〜第3ランスを前方より順次挿入し、前記ランスのエア吐出孔がランス下端寄りに位置し、第1ランスは吹き込み方向が前方のみであり、第2ランスは吹き込み方向が前方、及び前方斜め下方向であり、第3ランスは吹き込み方向が前方、後方、及び前方斜め下方向であり、これら全てのランスの吹き込み位置を炭化室の中央の高さとし、エアを吹き込むことを特徴とする吹き込みパターン。(Blowing pattern A) The carbonization chamber has first to fifth charcoal ports sequentially from the forefront (the furnace exhaust port is the rear and the opposite side is the front; hereinafter the same), and the second to fourth devices The first to third lances for blowing air into the coal spout are sequentially inserted from the front, the air discharge hole of the lance is located near the lower end of the lance, the first lance is blown only in the forward direction, and the second lance is blown The direction is forward and obliquely downward, and the third lance is blown forward, backward, and forward obliquely downward. All these lances are blown at the center height of the coking chamber and blown in air. Blowing pattern characterized by that.
(吹き込みパターンB)炭化室が最前方(炉の排気口を後方、反対側を前方とする。以下、同じ)から順次第1〜第5装炭口を有し、前記第2及び第3装炭口にエアを吹き込む第1及び第2ランスを前方より順次挿入し、前記ランスのエア吐出孔がランス下端寄りに位置し、第1ランスは吹き込み方向が前方のみで、吹き込み位置は炭化室室頂直下とし、かつ、第2ランスは吹き込み方向が前方、及び前方斜め下方向で、吹き込み位置は炭化室高さの1/4とし、エアを吹き込むことを特徴とする吹き込みパターン。(Blowing pattern B) The carbonization chamber has first to fifth charcoal ports sequentially from the forefront (the furnace exhaust port is the rear and the opposite side is the front; hereinafter the same), and the second and third devices First and second lances for injecting air into the coal spout are sequentially inserted from the front, the air discharge hole of the lance is located near the lower end of the lance, the first lance is blown only in the forward direction, and the blowing position is the coking chamber chamber A blowing pattern in which the second lance is blown in the forward and obliquely downward directions, the blowing position is 1/4 of the height of the carbonization chamber, and blows air.
JP2002101762A 2002-04-03 2002-04-03 Coke oven carbonization chamber furnace wall adhering carbon removal device operation method Expired - Fee Related JP4012761B2 (en)

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JP2007119577A (en) * 2005-10-27 2007-05-17 Nippon Steel Corp Method for removing deposited carbon of carbonization chamber of coke oven
CN101852557B (en) * 2010-06-12 2013-03-13 沈阳石蜡化工有限公司 Decoking method of tubular heater of urea dewaxing device
GB2502115B (en) 2012-05-15 2015-04-01 Chinook End Stage Recycling Ltd Improvements in waste processing
KR101560886B1 (en) * 2013-11-07 2015-10-16 주식회사 포스코 Coke oven and method for injection of reaction gas in coke oven using the same

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