JP4010935B2 - Polymer electrolyte fuel cell - Google Patents
Polymer electrolyte fuel cell Download PDFInfo
- Publication number
- JP4010935B2 JP4010935B2 JP2002350544A JP2002350544A JP4010935B2 JP 4010935 B2 JP4010935 B2 JP 4010935B2 JP 2002350544 A JP2002350544 A JP 2002350544A JP 2002350544 A JP2002350544 A JP 2002350544A JP 4010935 B2 JP4010935 B2 JP 4010935B2
- Authority
- JP
- Japan
- Prior art keywords
- mea
- separator
- fuel cell
- polymer electrolyte
- electrolyte fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Description
【0001】
【発明の属する技術分野】
本発明は、燃料電池を構成する固体高分子形燃料電池用セルに関する。
【0002】
【従来の技術】
従来の一般的な燃料電池用セルの構造は、図1に示すように、電解質膜の両側に、燃料極触媒層と多孔質支持層とによる燃料極と、空気極触媒層と多孔質支持層とによる空気極とが接合し、MEAとして一体化され、さらにMEAの外側に配設された水素や酸素の反応ガスの供給通路をかねたセパレータによって挟持されているものがある(例えば、参考文献1参照)。
【0003】
【特許文献1】
池田宏之助編,「燃料電池のすべて」,第3版,株式会社日本実業出版社,2002年4月20日,p.126−127
【0004】
【発明が解決しようとする課題】
上記、従来の一般的な燃料電池用セルを構成するセパレータは、反応ガスの供給通路と電極との役割を果たすために、炭素系や金属系等の材料のブロック状の基材に多数の溝を設けた構造になっている。従って以下のような問題点が指摘される。
(1)セパレータの基材がブロック状であるため重量が重い。
(2)セパレータに溝を設けるための設計、金型の製造などに係わる工数が必要
となりコストが高くなる。
(3)セパレータの強度を確保するための厚みが発電に寄与しない部分となり、組上げたセルの単位体積当たりの発電効率が低下する要因となる。
そこで、本発明は、上記課題に鑑みて創案なされたものであり、軽量、低コストで単位体積当たりの発電効率を向上させ、その上フレキシブルな固体高分子形燃料電池用セルを提供することにある。
【0005】
【課題を解決するための手段】
本発明の請求項1記載の固体高分子形燃料電池用セルは、電解質膜の両面に酸素極と水素極とを接合してMEAを構成し、前記MEAを挟むようにセパレータが配設された固体高分子形燃料電池用セルであって、前記セパレータは平板で柔軟性を有し、且つ、前記セパレータで挟まれたMEAは波状に変形されており、前記セルを巻回したことを特徴とする。
【0006】
本発明の請求項2記載の固体高分子形燃料電池用セルは、電解質膜の両面に酸素極と水素極とを接合してMEAを構成し、前記MEAを挟むようにセパレータが配設された固体 高分子形燃料電池用セルであって、前記セパレータは平板で柔軟性を有し、且つ、前記セパレータで挟まれたMEAは波状に変形されており、前記セルを折曲して積重したことを特徴とする。
【0007】
【発明の実施の形態】
以下、この発明の好適な実施形態を図2乃至図5を参照しながら、詳細に説明する。尚、以下に述べる実施形態は、本発明の好適な具体例であるから、技術的に好ましい種々の限定が付されているが、本発明の範囲は、以下の説明において特に本発明を限定する旨の記載がない限り、これらの態様に限られるものではない。
【0008】
図2は、本発明に係る固体高分子形燃料電池用セルの実施例を示す部分断面図である。従来の一般的な燃料電池用セルを構成するMEAと同様に、電解質膜1の両面に酸素極2と水素極3とを接合してMEA7を構成している。MEA7の厚みは約40乃至100μm程度で、人の力で加圧すれば変形させることができるほどの柔軟性を有するものである。これを、波状に保持し、両面に柔軟性のある平板のセパレータ4で挟んだ構造になっている。セパレータ4は、例えば、ステンレスの薄い平板に金メッキを施した構成など、導電性の良い柔軟性を持った部材を適宜使用すればよい。そして、上述の構造に組上がったセル10も柔軟性をもったものとなる。また、このセル10においては、セパレータ4とセパレータ4に挟まれたMEA7の酸素極2及び水素極3との間に空間ができるので、この空間をそれぞれ空気流路5、水素流路6として、酸素及び水素を供給することにより起電反応を起こさせ、セパレータ4を電極にして起電力を外部に取り出すものである。なお、空気流路5及び水素流路6は中空でも良いし、カーボンなどの導電繊維を満たしても良い。導電繊維を満たすと、MEA7とセパレータが接触していなくてもMEA7で発生した起電力は導電繊維を介してセパレータに伝達される。
【0009】
なお、上述のフレキシブルなセル10を使用すると、セル10を配置するスペースに制約があっても、図3に示すように螺旋状に巻きつけて乾電池のような形に形成したり、図4に示すように葛折のように折り重ねるなど、いろいろな形状にして対応することができる。また、要求される電力によって図5のように大判のセル10を適宜、切断部8で切断して使用することも可能である。
【0010】
【発明の効果】
以上説明したように、本発明の固体高分子形燃料電池用セルは、従来の一般的な燃料電池用セルと比較して、セパレータを平板にしたので、薄くて軽いセルができる。また、MEAを波形に保持することによって流路を流れる各反応ガスとMEAとの接触面積が増大し、その結果、反応面積が大きくなること及びセルが薄くなることで、単位体積当たりの発電効率が向上する。また、応用面では、セパレータに柔軟性のある材質を採用することによって実現されたセルのフレキシブルな特性を生かして、螺旋状にしたり、折り重ねたり、切断するなどして制約のある配置スペースや、要求される電力に対して適宜対応することができる。さらに、コスト面では、セパレータが平板であるため設計、製造に係わる工数が低減され、低コスト化が実現できる、といった効果を奏するものである。
【図面の簡単な説明】
【図1】 参考文献1のP.126に記載された図である。
【図2】 本発明に係わる固体高分子形燃料電池用セルの実施例を示す部分断面図である。
【図3】 本発明に係わる固体高分子形燃料電池用セルを使用した第1の応用例を示す概念図である。
【図4】 本発明に係わる固体高分子形燃料電池用セルを使用した第2の応用例を示す概念図である。
【図5】 本発明に係わる固体高分子形燃料電池用セルを使用した第3の応用例を示す概念図である。
【符号の説明】
1 電解質膜
2 酸素極
3 水素極
4 セパレータ
5 空気流路
6 水素流路
7 MEA
8 切断部
10 セル[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a polymer electrolyte fuel cell for constituting a fuel cell .
[0002]
[Prior art]
As shown in FIG. 1, the conventional general fuel cell structure has a fuel electrode composed of a fuel electrode catalyst layer and a porous support layer on both sides of an electrolyte membrane, an air electrode catalyst layer, and a porous support layer. Are joined by an air electrode, and are integrated as an MEA, and are sandwiched by a separator that also serves as a hydrogen or oxygen reactive gas supply passage disposed outside the MEA (for example, References) 1).
[0003]
[Patent Document 1]
Ikeda Hironosuke, “All about Fuel Cells”, 3rd edition, Nippon Jitsugyo Publishing Co., Ltd., April 20, 2002, p.126-127
[0004]
[Problems to be solved by the invention]
The separator constituting the conventional general fuel cell has a large number of grooves in a block-like base material made of carbon-based material or metal-based material in order to serve as a reaction gas supply passage and an electrode. The structure is provided. Therefore, the following problems are pointed out.
(1) Since the base material of a separator is a block shape, weight is heavy.
(2) Man-hours related to the design for providing grooves in the separator and the manufacture of molds are required, resulting in high costs.
(3) The thickness for securing the strength of the separator is a portion that does not contribute to power generation, which causes a decrease in power generation efficiency per unit volume of the assembled cell.
Therefore, the present invention has been made in view of the above problems, and provides a cell for a solid polymer electrolyte fuel cell that is light and low in cost, improves power generation efficiency per unit volume, and is flexible. is there.
[0005]
[Means for Solving the Problems]
Polymer electrolyte fuel cell according to claim 1 of the present invention constitutes an MEA by bonding and the oxygen electrode and the hydrogen electrode to both surfaces of the electrolyte membrane, the separator is disposed so as to sandwich the MEA A polymer electrolyte fuel cell, wherein the separator is flat and flexible , and the MEA sandwiched between the separators is deformed into a wave shape, and the cell is wound. To do .
[0006]
In the polymer electrolyte fuel cell according to
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to FIGS. The embodiments described below are preferable specific examples of the present invention, and thus various technically preferable limitations are given. However, the scope of the present invention particularly limits the present invention in the following description. As long as there is no description of the effect, it is not restricted to these aspects.
[0008]
FIG. 2 is a partial sectional view showing an example of a polymer electrolyte fuel cell according to the present invention. Like the MEA that constitutes a conventional general fuel cell, the
[0009]
In addition, when the above-described
[0010]
【The invention's effect】
As described above, since the polymer electrolyte fuel cell of the present invention has a flat separator as compared with a conventional general fuel cell, a thin and light cell can be formed. Further, by maintaining the MEA in a waveform, the contact area between each reaction gas flowing through the flow path and the MEA is increased. As a result, the reaction area is increased and the cell is thinned, thereby generating power generation efficiency per unit volume. Will improve. In addition, in terms of application, it is possible to take advantage of the flexible characteristics of the cells realized by adopting a flexible material for the separator, such as spiraling, folding, cutting, etc. Therefore, it is possible to appropriately cope with the required power. Furthermore, in terms of cost, since the separator is a flat plate, man-hours related to design and manufacture are reduced, and the cost can be reduced.
[Brief description of the drawings]
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 126 is a diagram described in FIG.
FIG. 2 is a partial cross-sectional view showing an embodiment of a polymer electrolyte fuel cell according to the present invention.
FIG. 3 is a conceptual diagram showing a first application example using a polymer electrolyte fuel cell according to the present invention.
FIG. 4 is a conceptual diagram showing a second application example using the polymer electrolyte fuel cell according to the present invention.
FIG. 5 is a conceptual diagram showing a third application example using the polymer electrolyte fuel cell according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1
8 Cutting
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2002350544A JP4010935B2 (en) | 2002-12-02 | 2002-12-02 | Polymer electrolyte fuel cell |
Applications Claiming Priority (1)
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JP2002350544A JP4010935B2 (en) | 2002-12-02 | 2002-12-02 | Polymer electrolyte fuel cell |
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JP2004185937A JP2004185937A (en) | 2004-07-02 |
JP4010935B2 true JP4010935B2 (en) | 2007-11-21 |
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JP2002350544A Expired - Fee Related JP4010935B2 (en) | 2002-12-02 | 2002-12-02 | Polymer electrolyte fuel cell |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7201986B2 (en) | 2004-05-04 | 2007-04-10 | Angstrom Power Incorporated | Electrochemical cells formed on pleated substrates |
FR2870388B1 (en) * | 2004-05-12 | 2006-08-25 | Peugeot Citroen Automobiles Sa | SOLID ELECTROLYTE FUEL CELL CELL |
KR101030044B1 (en) | 2004-08-30 | 2011-04-20 | 삼성에스디아이 주식회사 | Fuel cell system, stack and separator used thereto |
EP2352193A4 (en) * | 2008-11-28 | 2014-06-18 | Nissan Motor | Solid state polymer fuel cell |
US20140141286A1 (en) * | 2012-08-16 | 2014-05-22 | J. Craig Venter Institute | Pleated cathode electrode: high surface area, light-weight, modified packed-bed electrode for oxygen reduction |
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2002
- 2002-12-02 JP JP2002350544A patent/JP4010935B2/en not_active Expired - Fee Related
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