JP3988153B2 - Deodorants - Google Patents

Deodorants Download PDF

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Publication number
JP3988153B2
JP3988153B2 JP09663695A JP9663695A JP3988153B2 JP 3988153 B2 JP3988153 B2 JP 3988153B2 JP 09663695 A JP09663695 A JP 09663695A JP 9663695 A JP9663695 A JP 9663695A JP 3988153 B2 JP3988153 B2 JP 3988153B2
Authority
JP
Japan
Prior art keywords
deodorant
benzisothiazolin
composition
deodorizing
deodorizing effect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP09663695A
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Japanese (ja)
Other versions
JPH08289924A (en
Inventor
昇 山本
直美 川村
努 粟田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobayashi Pharmaceutical Co Ltd
Original Assignee
Kobayashi Pharmaceutical Co Ltd
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Filing date
Publication date
Application filed by Kobayashi Pharmaceutical Co Ltd filed Critical Kobayashi Pharmaceutical Co Ltd
Priority to JP09663695A priority Critical patent/JP3988153B2/en
Publication of JPH08289924A publication Critical patent/JPH08289924A/en
Application granted granted Critical
Publication of JP3988153B2 publication Critical patent/JP3988153B2/en
Anticipated expiration legal-status Critical
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Description

【0001】
【産業上の利用分野】
この発明は、新規な消臭剤に関するものである。
【0002】
【従来の技術】
従来より、屋内や車内などの嫌な匂いを除去するために消臭剤が用いられている。この消臭剤は例えばゲル基剤等に消臭剤組成物が配合されて成り、前記消臭剤組成物として銅イオン系のものや植物抽出物系のもの等が用いられている。
【0003】
確かに、この従来の消臭剤は消臭効果があり実用的にも優れたものである。
【0004】
しかし、消臭剤というものに対しては基本的には常により高い消臭効果が求められているのである。
【0005】
【発明が解決しようとする課題】
そこで、この発明は、従来よりもその消臭効果が高い消臭剤を提供しようとするものである。
【0006】
【課題を解決するための手段】
前記課題を解決すべく鋭意検討した結果、1,2−ベンズイソチアゾリン−3−オン(1,2−Benzisothiazolin−3−one)を消臭助剤組成物として他の消臭剤組成物とともに消臭剤に含有せしめることにより、従来よりも高い消臭効果を得ることができることを見出しこの発明を完成するに到った。
【0007】
すなわち、この発明の消臭剤は、1,2−ベンズイソチアゾリン−3−オン(1,2−Benzisothiazolin−3−one)を消臭助剤組成物として銅イオン系の消臭剤組成物とともに含有せしめることを特徴とし、1,2−ベンズイソチアゾリン−3−オン(1,2−Benzisothiazolin−3−one)を消臭助剤組成物として植物抽出物系の消臭剤組成物とともに含有せしめることを特徴とする。この1,2−ベンズイソチアゾリン−3−オンは、従来は防腐剤・殺菌剤としての機能を有するものとして知られていたものである。
【0008】
1,2−ベンズイソチアゾリン−3−オンは、消臭助剤組成物として例えばゲル基剤などに配合して実施することもできる。
【0009】
【発明の効果】
この発明は上述のような構成であり、次の効果を有する。
【0010】
従来よりもその消臭効果が高い消臭剤を提供することができる。
【0011】
【実施例】
以下、この発明の構成を実施例により説明する。
(実施例1、2)
1,2−ベンズイソチアゾリン−3−オン、銅イオン系の消臭剤組成物、及び植物抽出物系の消臭剤組成物、ゲル基剤としてマレイン酸系樹脂(クラレケミカル社製、商品名アクアビーズ)、イオン交換水とを表1に示す配合比率で混合することにより製造した。この実施例1、2は1,2−ベンズイソチアゾリン−3−オンを消臭助剤組成物として用いている。
【0012】
一方、比較例1として茶抽出物を消臭剤として用い、比較例2として蒸留水を消臭剤として用いた。これら比較例の消臭剤はいずれも消臭効果があるものとして知られている。比較例3,4として、1,2−ベンズイソチアゾリン−3−オン以外の消臭剤組成物を用い、表2に示す比率で配合することにより形成した。なお、表中1,2−ベンズイソチアゾリン−3−オンはB.I.Tと示す。
【0013】
(評価試験)
得られた消臭剤の消臭効果の評価試験を、次のようにして行った。
【0014】
10mlビーカーに消臭剤の試料1gを入れたもの及び悪臭源を一定量入れたものを、ともに300mlのコニカルビーカーに入れて密栓した。そして、1時間経過後の悪臭の濃度を、検知管(ガステック社製)を用いて測定した。悪臭源としてアンモニア、トリメチルアミン、硫化水素、メチルメルカプタンの4種類を用いた。これらは代表的な悪臭として知られているものである。
【0015】
一方、悪臭源を一定量入れたもののみを300mlのコニカルビーカーに入れて密栓し、1時間経過後に検知管を用いて悪臭の濃度を測定した。この悪臭の濃度を100%とし、これに対しての消臭した比率により、消臭剤の試料の消臭率(%)を算出した。消臭率の数値が大きい方が、消臭効果が高い。結果を、表3に示す。
【0016】
表3に示されるように、各実施例の消臭剤は各比較例のものに対して消臭効果が高く、特にメチルメルカプタンの消臭効果が非常に高い。すなわち、この実施例の消臭剤はゲル基剤などの防腐作用を有すると共に、高い消臭効果が得られるという利点を有する。
【0017】
【表1】

Figure 0003988153
【0018】
【表2】
Figure 0003988153
【0019】
【表3】
Figure 0003988153
[0001]
[Industrial application fields]
The present invention relates to a novel deodorant.
[0002]
[Prior art]
Conventionally, deodorizers have been used to remove unpleasant odors such as indoors and cars. This deodorant is formed, for example, by blending a deodorant composition into a gel base or the like, and a copper ion type or plant extract type is used as the deodorant composition.
[0003]
Certainly, this conventional deodorant has a deodorizing effect and is practically excellent.
[0004]
However, a deodorant is basically required to have a higher deodorizing effect.
[0005]
[Problems to be solved by the invention]
Therefore, the present invention intends to provide a deodorant having a higher deodorizing effect than before.
[0006]
[Means for Solving the Problems]
As a result of intensive studies to solve the above problems, 1,2-benzisothiazolin-3-one (1,2-Benzisothiazolin-3-one) is used as a deodorizing aid composition together with other deodorant compositions. The present inventors have found that a deodorizing effect higher than that in the prior art can be obtained by incorporating the compound into an agent, and the present invention has been completed.
[0007]
That is, the deodorant of this invention contains 1,2-benzisothiazolin-3-one (1,2-Benzisothiazolin-3-one) as a deodorizing aid composition together with a copper ion-based deodorant composition. And including 1,2-benzisothiazolin-3-one as a deodorizing aid composition together with a plant extract-based deodorant composition. Features. This 1,2-benzisothiazolin-3-one has been conventionally known as having a function as an antiseptic / bactericidal agent.
[0008]
1,2-benzisothiazolin-3-one can also be carried out as a deodorizing aid composition, for example, in a gel base.
[0009]
【The invention's effect】
The present invention is configured as described above and has the following effects.
[0010]
It is possible to provide a deodorant having a higher deodorizing effect than before.
[0011]
【Example】
The configuration of the present invention will be described below with reference to examples.
(Examples 1 and 2)
1,2-benzisothiazolin-3-one, copper ion-based deodorant composition, and plant extract-based deodorant composition, maleic resin as a gel base (trade name Aqua, manufactured by Kuraray Chemical Co., Ltd.) Beads) and ion-exchanged water at a blending ratio shown in Table 1. In Examples 1 and 2, 1,2-benzisothiazolin-3-one is used as a deodorizing aid composition.
[0012]
On the other hand, as Comparative Example 1, a tea extract was used as a deodorant, and as Comparative Example 2, distilled water was used as a deodorant. All of these comparative deodorants are known to have a deodorizing effect. As Comparative Examples 3 and 4, a deodorant composition other than 1,2-benzisothiazolin-3-one was used and blended at a ratio shown in Table 2. In the table, 1,2-benzisothiazolin-3-one is B.I. I. T.
[0013]
(Evaluation test)
The evaluation test of the deodorizing effect of the obtained deodorant was performed as follows.
[0014]
A 10 ml beaker containing 1 g of the deodorant sample and a certain amount of malodorous source were placed in a 300 ml conical beaker and sealed. And the density | concentration of the malodor after 1 hour passage was measured using the detection tube (made by Gastec). Four types of ammonia, trimethylamine, hydrogen sulfide, and methyl mercaptan were used as bad odor sources. These are known as typical malodors.
[0015]
On the other hand, only a certain amount of malodor source was put in a 300 ml conical beaker and sealed, and after 1 hour, the concentration of malodor was measured using a detector tube. The concentration of this malodor was set to 100%, and the deodorization rate (%) of the sample of the deodorant was calculated based on the ratio of deodorization with respect to this concentration. The larger the deodorization rate, the higher the deodorization effect. The results are shown in Table 3.
[0016]
As shown in Table 3, the deodorant of each example has a higher deodorizing effect than that of each comparative example, and in particular, the deodorizing effect of methyl mercaptan is very high. That is, the deodorant of this example has an advantage that a high deodorizing effect can be obtained while having an antiseptic action such as a gel base.
[0017]
[Table 1]
Figure 0003988153
[0018]
[Table 2]
Figure 0003988153
[0019]
[Table 3]
Figure 0003988153

Claims (3)

1,2−ベンズイソチアゾリン−3−オン(1,2−Benzisothiazolin−3−one)を消臭助剤組成物として銅イオン系の消臭剤組成物とともに含有せしめることを特徴とする消臭剤。 A deodorant comprising 1,2-benzisothiazolin-3-one as a deodorizing aid composition together with a copper ion-based deodorant composition . 1,2−ベンズイソチアゾリン−3−オン(1,2−Benzisothiazolin−3−one)を消臭助剤組成物として植物抽出物系の消臭剤組成物とともに含有せしめることを特徴とする消臭剤。A deodorant characterized by containing 1,2-benzisothiazolin-3-one as a deodorizing aid composition together with a plant extract-based deodorant composition . 前記1,2−ベンズイソチアゾリン−3−オンを、ゲル基剤に配合して成る請求項1又は2記載の消臭剤。  The deodorizer according to claim 1 or 2, wherein the 1,2-benzisothiazolin-3-one is blended with a gel base.
JP09663695A 1995-04-21 1995-04-21 Deodorants Expired - Fee Related JP3988153B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP09663695A JP3988153B2 (en) 1995-04-21 1995-04-21 Deodorants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP09663695A JP3988153B2 (en) 1995-04-21 1995-04-21 Deodorants

Publications (2)

Publication Number Publication Date
JPH08289924A JPH08289924A (en) 1996-11-05
JP3988153B2 true JP3988153B2 (en) 2007-10-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP09663695A Expired - Fee Related JP3988153B2 (en) 1995-04-21 1995-04-21 Deodorants

Country Status (1)

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JP (1) JP3988153B2 (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02268900A (en) * 1989-04-11 1990-11-02 Kurita Seizosho:Kk Deodorant composition
JPH06104236B2 (en) * 1992-03-18 1994-12-21 興南化学工業株式会社 Deodorant for dehydrated sludge cake and method for producing the same
JPH06154794A (en) * 1992-11-17 1994-06-03 Nippon Soda Co Ltd Vomit treating agent and treatment thereof
JPH06327585A (en) * 1993-05-24 1994-11-29 Funayama Kk Excrement storage bag of sprinkled deodorant type

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Publication number Publication date
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