JP3973287B2 - トナーの調製方法 - Google Patents
トナーの調製方法 Download PDFInfo
- Publication number
- JP3973287B2 JP3973287B2 JP7443298A JP7443298A JP3973287B2 JP 3973287 B2 JP3973287 B2 JP 3973287B2 JP 7443298 A JP7443298 A JP 7443298A JP 7443298 A JP7443298 A JP 7443298A JP 3973287 B2 JP3973287 B2 JP 3973287B2
- Authority
- JP
- Japan
- Prior art keywords
- poly
- styrene
- toner
- isoprene
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims description 14
- 229920000126 latex Polymers 0.000 claims description 60
- 239000004816 latex Substances 0.000 claims description 57
- 239000000049 pigment Substances 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 53
- 239000002245 particle Substances 0.000 claims description 53
- 239000000203 mixture Substances 0.000 claims description 46
- 229920000642 polymer Polymers 0.000 claims description 45
- 229920006037 cross link polymer Polymers 0.000 claims description 36
- 239000006185 dispersion Substances 0.000 claims description 24
- 239000002563 ionic surfactant Substances 0.000 claims description 17
- -1 poly (ethylene Acrylate-isoprene Chemical compound 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000002174 Styrene-butadiene Substances 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 7
- 239000011115 styrene butadiene Substances 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- DCUTVXHHLQVRRA-UHFFFAOYSA-N 2-methylbuta-1,3-diene;prop-2-enoic acid;styrene Chemical compound CC(=C)C=C.OC(=O)C=C.C=CC1=CC=CC=C1 DCUTVXHHLQVRRA-UHFFFAOYSA-N 0.000 claims description 3
- PLOYJEGLPVCRAJ-UHFFFAOYSA-N buta-1,3-diene;prop-2-enoic acid;styrene Chemical compound C=CC=C.OC(=O)C=C.C=CC1=CC=CC=C1 PLOYJEGLPVCRAJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 3
- LONCJFPVKZBTLG-UHFFFAOYSA-N 2-methylbuta-1,3-diene prop-1-enylbenzene Chemical compound CC(=C)C=C.CC=CC1=CC=CC=C1 LONCJFPVKZBTLG-UHFFFAOYSA-N 0.000 claims description 2
- KLWOORLBKQYYQC-UHFFFAOYSA-N 2-methylbuta-1,3-diene propyl prop-2-enoate Chemical compound CC(=C)C=C.CCCOC(=O)C=C KLWOORLBKQYYQC-UHFFFAOYSA-N 0.000 claims description 2
- NRDDLSFHZLETFD-UHFFFAOYSA-N 2-methylbuta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound CC(=C)C=C.COC(=O)C(C)=C NRDDLSFHZLETFD-UHFFFAOYSA-N 0.000 claims description 2
- XXEJNJYARCWPGC-UHFFFAOYSA-N 2-methylbuta-1,3-diene;propyl 2-methylprop-2-enoate Chemical compound CC(=C)C=C.CCCOC(=O)C(C)=C XXEJNJYARCWPGC-UHFFFAOYSA-N 0.000 claims description 2
- WOYXYXOSUAZDIA-UHFFFAOYSA-N buta-1,3-diene;butyl 2-methylprop-2-enoate Chemical compound C=CC=C.CCCCOC(=O)C(C)=C WOYXYXOSUAZDIA-UHFFFAOYSA-N 0.000 claims description 2
- YIEXROAWVNRRMJ-UHFFFAOYSA-N buta-1,3-diene;butyl prop-2-enoate Chemical compound C=CC=C.CCCCOC(=O)C=C YIEXROAWVNRRMJ-UHFFFAOYSA-N 0.000 claims description 2
- UWWYTVDAXIVRAJ-UHFFFAOYSA-N buta-1,3-diene;ethyl 2-methylprop-2-enoate Chemical compound C=CC=C.CCOC(=O)C(C)=C UWWYTVDAXIVRAJ-UHFFFAOYSA-N 0.000 claims description 2
- UCPLVEOTDDIMJD-UHFFFAOYSA-N buta-1,3-diene;ethyl prop-2-enoate Chemical compound C=CC=C.CCOC(=O)C=C UCPLVEOTDDIMJD-UHFFFAOYSA-N 0.000 claims description 2
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 claims description 2
- LRTQWXGNPCHTFW-UHFFFAOYSA-N buta-1,3-diene;methyl prop-2-enoate Chemical compound C=CC=C.COC(=O)C=C LRTQWXGNPCHTFW-UHFFFAOYSA-N 0.000 claims description 2
- NACNINIZJRIDPK-UHFFFAOYSA-N buta-1,3-diene;propyl 2-methylprop-2-enoate Chemical compound C=CC=C.CCCOC(=O)C(C)=C NACNINIZJRIDPK-UHFFFAOYSA-N 0.000 claims description 2
- XPRLOFXIQNKWMK-UHFFFAOYSA-N buta-1,3-diene;propyl prop-2-enoate Chemical compound C=CC=C.CCCOC(=O)C=C XPRLOFXIQNKWMK-UHFFFAOYSA-N 0.000 claims description 2
- QQIMXPLXJVRMNX-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;2-methylbuta-1,3-diene Chemical compound CC(=C)C=C.CCCCOC(=O)C(C)=C QQIMXPLXJVRMNX-UHFFFAOYSA-N 0.000 claims description 2
- VMRHCZNACCBXEJ-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;butyl prop-2-enoate Chemical compound CCCCOC(=O)C=C.CCCCOC(=O)C(C)=C VMRHCZNACCBXEJ-UHFFFAOYSA-N 0.000 claims description 2
- KGVITRZHZPHLOI-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCOC(=O)C(C)=C KGVITRZHZPHLOI-UHFFFAOYSA-N 0.000 claims description 2
- PSJCFABZBPCBNQ-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CCCCOC(=O)C(C)=C PSJCFABZBPCBNQ-UHFFFAOYSA-N 0.000 claims description 2
- DFYKHEXCUQCPEB-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C(C)=C DFYKHEXCUQCPEB-UHFFFAOYSA-N 0.000 claims description 2
- HOIWWOKSBHULCU-UHFFFAOYSA-N butyl prop-2-enoate;2-methylbuta-1,3-diene Chemical compound CC(=C)C=C.CCCCOC(=O)C=C HOIWWOKSBHULCU-UHFFFAOYSA-N 0.000 claims description 2
- IYCOKCJDXXJIIM-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CCCCOC(=O)C=C IYCOKCJDXXJIIM-UHFFFAOYSA-N 0.000 claims description 2
- TUZBYYLVVXPEMA-UHFFFAOYSA-N butyl prop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C=C TUZBYYLVVXPEMA-UHFFFAOYSA-N 0.000 claims description 2
- RXQXUXZUWNFWJV-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate;2-methylbuta-1,3-diene Chemical compound CC(=C)C=C.CCOC(=O)C(C)=C RXQXUXZUWNFWJV-UHFFFAOYSA-N 0.000 claims description 2
- HNJKLOSHGNUTBM-UHFFFAOYSA-N 2-methylbuta-1,3-diene;methyl prop-2-enoate Chemical compound CC(=C)C=C.COC(=O)C=C HNJKLOSHGNUTBM-UHFFFAOYSA-N 0.000 claims 1
- QSMOHLASMMAGIB-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enenitrile Chemical compound C=CC#N.CCCCOC(=O)C=C QSMOHLASMMAGIB-UHFFFAOYSA-N 0.000 claims 1
- WWPXOMXUMORZKI-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1.CCCCOC(=O)C=C WWPXOMXUMORZKI-UHFFFAOYSA-N 0.000 claims 1
- 230000004927 fusion Effects 0.000 claims 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
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- 239000002736 nonionic surfactant Substances 0.000 description 11
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 8
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 7
- 238000010008 shearing Methods 0.000 description 7
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- 238000001035 drying Methods 0.000 description 4
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- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 4
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- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 3
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- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 2
- PIKJWNAIKAKPQW-UHFFFAOYSA-N 1-dodecylnaphthalene;sulfuric acid Chemical compound OS(O)(=O)=O.C1=CC=C2C(CCCCCCCCCCCC)=CC=CC2=C1 PIKJWNAIKAKPQW-UHFFFAOYSA-N 0.000 description 2
- VEBJYBIQIYFEFN-UHFFFAOYSA-N 2-[2-[2-[2-[2-(4-octylphenoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCO)C=C1 VEBJYBIQIYFEFN-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- G03G9/08708—Copolymers of styrene
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- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08726—Polymers of unsaturated acids or derivatives thereof
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- G—PHYSICS
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- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
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- G03G9/087—Binders for toner particles
- G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08726—Polymers of unsaturated acids or derivatives thereof
- G03G9/08731—Polymers of nitriles
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- G—PHYSICS
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- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08726—Polymers of unsaturated acids or derivatives thereof
- G03G9/08733—Polymers of unsaturated polycarboxylic acids
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Developing Agents For Electrophotography (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/825,451 US5763133A (en) | 1997-03-28 | 1997-03-28 | Toner compositions and processes |
| US825451 | 2001-04-02 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH10282717A JPH10282717A (ja) | 1998-10-23 |
| JPH10282717A5 JPH10282717A5 (https=) | 2005-09-02 |
| JP3973287B2 true JP3973287B2 (ja) | 2007-09-12 |
Family
ID=25244031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7443298A Expired - Fee Related JP3973287B2 (ja) | 1997-03-28 | 1998-03-23 | トナーの調製方法 |
Country Status (2)
| Country | Link |
|---|---|
| US (2) | US5763133A (https=) |
| JP (1) | JP3973287B2 (https=) |
Families Citing this family (147)
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|---|---|---|---|---|
| DE3571355D1 (en) * | 1984-04-17 | 1989-08-10 | Hitachi Chemical Co Ltd | Process for producing toner for electrophotography |
| JPH0740142B2 (ja) * | 1985-11-05 | 1995-05-01 | 日本カーバイド工業株式会社 | 静電荷像現像用トナ− |
| EP0302939B1 (en) * | 1987-01-29 | 1997-06-11 | Nippon Carbide Kogyo Kabushiki Kaisha | Toner for developing electrostatically charged image |
| US5290654A (en) * | 1992-07-29 | 1994-03-01 | Xerox Corporation | Microsuspension processes for toner compositions |
| US5278020A (en) * | 1992-08-28 | 1994-01-11 | Xerox Corporation | Toner composition and processes thereof |
| US5308734A (en) * | 1992-12-14 | 1994-05-03 | Xerox Corporation | Toner processes |
| US5346797A (en) * | 1993-02-25 | 1994-09-13 | Xerox Corporation | Toner processes |
| US5364729A (en) * | 1993-06-25 | 1994-11-15 | Xerox Corporation | Toner aggregation processes |
| US5344738A (en) * | 1993-06-25 | 1994-09-06 | Xerox Corporation | Process of making toner compositions |
| US5418108A (en) * | 1993-06-25 | 1995-05-23 | Xerox Corporation | Toner emulsion aggregation process |
| US5370963A (en) * | 1993-06-25 | 1994-12-06 | Xerox Corporation | Toner emulsion aggregation processes |
| US5403693A (en) * | 1993-06-25 | 1995-04-04 | Xerox Corporation | Toner aggregation and coalescence processes |
| US5585215A (en) * | 1996-06-13 | 1996-12-17 | Xerox Corporation | Toner compositions |
| US5650252A (en) * | 1996-06-24 | 1997-07-22 | Xerox Corporation | Toner grafting processes |
| US5650256A (en) * | 1996-10-02 | 1997-07-22 | Xerox Corporation | Toner processes |
| US5645968A (en) * | 1996-10-07 | 1997-07-08 | Xerox Corporation | Cationic Toner processes |
-
1997
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- 1997-04-29 US US08/841,300 patent/US5747215A/en not_active Expired - Lifetime
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1998
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|---|---|
| US5747215A (en) | 1998-05-05 |
| JPH10282717A (ja) | 1998-10-23 |
| US5763133A (en) | 1998-06-09 |
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