JP3958118B2 - Scroll type fluid machine, scroll member and method of manufacturing the member - Google Patents

Scroll type fluid machine, scroll member and method of manufacturing the member Download PDF

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JP3958118B2
JP3958118B2 JP2002160882A JP2002160882A JP3958118B2 JP 3958118 B2 JP3958118 B2 JP 3958118B2 JP 2002160882 A JP2002160882 A JP 2002160882A JP 2002160882 A JP2002160882 A JP 2002160882A JP 3958118 B2 JP3958118 B2 JP 3958118B2
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pore
tin
scroll
film
scroll member
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JP2004003402A (en
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和彦 井野口
真実 竹内
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Mitsubishi Heavy Industries Ltd
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Mitsubishi Heavy Industries Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、アルミニウム合金で形成する旋回スクロール部材、および、または固定スクロール部材の表面処理方法、およびその表面処理を施したスクロール部材およびそのスクロール部材を用いたスクロール型流体機械、特にスクロール型圧縮機に関する。
【0002】
【従来の技術】
スクロール型流体機械、例えば冷媒のスクロールコンプレッサの冷媒圧縮部は、固定および旋回のそれぞれのスクロールによって構成され、それらが噛み合って圧縮機構を形成している。図7は一般的なスクロールコンプレッサの固定または旋回スクロール部材の形状の説明図であり、(a)はスクロール部材の平面図、(b)は(a)中A−A矢視断面図である。
【0003】
図7において、スクロール部材10はラップ11と呼ばれる渦巻き状の歯と、それを保持する端板12によって形作られており、固定スクロールと旋回スクロールの両スクロール部材10の歯(ラップ11)の側面(ラップ面11a)同士の接触部と、端板12と相手側のスクロール部材10の歯先(ラップ頂面11b)との接触部とで囲まれた部屋が、旋回スクロールの旋回運動によって吸入、圧縮を繰り返す構造となっている。このためラップ面11a同士の接触、摺動、ラップ頂面11bと相手側のスクロール部材10の端板12の面(端板面12a)との接触、摺動が発生することになり摩耗対策が必要となっている。
【0004】
一般に、スクロールコンプレッサを自動車エアコン用コンプレッサとして使用する場合、軽量化を要求されることからアルミニウム合金を採用する場合が多い。しかし、スクロールコンプレッサにおいて,お互いに噛み合って設けられ、接触、摺動する固定スクロール、旋回スクロールともにアルミニウム合金を用いた場合、両者ともに裸材ではお互いの摩耗が大きく、また凝着が生じることが多い。
【0005】
スクロールコンプレッサの動作においては、固定スクロールに噛み合った旋回スクロールの旋回運動によって圧縮動作が行われるのであるが、旋回スクロールが旋回運動をする時、相手部材である固定スクロールの端板面12aには旋回スクロールのラップ頂面11bが接触、摺動する。そこで、旋回スクロールのラップ頂面11bには溝11cが設けられ、その溝11cに樹脂で形成されたチップシール13と呼ばれる摺動性の良い部材が取り付けられて、ラップ頂面11bと相手側の端板面12aとが直接接することが無いように配慮されている。
【0006】
【発明が解決しようとする課題】
前述のようなスクロールコンプレッサにおいては、従来から固定スクロールあるいは旋回スクロールのどちらか一方のラップ11および端板12の表面に硬質皮膜を形成する表面処理を行い、裸材と硬質皮膜の摺動として、耐摩耗性を大幅に向上させ、また凝着も生じなくなるようにしているが、チップシール13も旋回スクロールが傾斜せず旋回する場合には効果があるが、傾斜して旋回運動をした場合には固定スクロールの端板面12aとラップ頂面11bとが直接接することとなる。この場合にも、潤滑油が存在すれば問題なく稼動するが、スクロールコンプレッサの停止状況によっては潤滑油が途切れる場合があり、この時の摺動により凝着を生じやすいことが明らかになっている。
【0007】
そこで本発明の出願人は、上記の対策として図6に示すスクロール部材、スクロール部材の製造方法、この部材を用いたスクロール型流体機械を提案し、特許出願も了している。次に、この先行技術の内容を説明する。
【0008】
図6はスクロール部材の表面部断面拡大図であり、前述のように、スクロール型流体機械、例えばスクロールコンプレッサにおいて、アルミニウム合金製の固定スクロールあるいは旋回スクロールのどちらか一方のラップ11および端板12の表面に硬質皮膜を形成する場合、硬質陽極酸化処理が利用されるが、図6に示すように、硬質陽極酸化処理の特徴として、アルミニウム合金母材1の表面に形成された硬質陽極酸化処理皮膜(以下、単に「陽極酸化皮膜」という)2中には、ポア3と呼ばれる微小孔が存在する。この例では、図6に示すように、スクロール部材10のアルミニウム合金母材1の陽極酸化皮膜2のポア3中に潤滑材としてすず5を含浸し、潤滑油が枯渇した場合でも潤滑性能を発揮できる自己潤滑性表面処理皮膜を形成したものである。
【0009】
ポア3の底部(アルミニウム合金母材1側)にバリヤ層6と呼ばれる層が存在する陽極酸化皮膜2の構造から、バリヤ層6の通電可能な性質を利用し、硬質陽極酸化処理されたスクロール部材10を、すずイオンを含む電解液中において陰極にセットし電解することで、バリヤ層6を介して通電が行なわれ、陽極酸化皮膜2のポア3中にすず5が析出し充填される。すず5は軟質の材料で自己潤滑作用を持つ材料の一つである。
【0010】
陽極酸化皮膜2中にすず5の含浸物を形成することで、すず5の持つ自己潤滑作用により、潤滑油が枯渇した場合でも陽極酸化皮膜2表面に潤滑作用を保持し凝着に至らないスクロール部材、スクロールコンプレッサの製品を得ることができる。
【0011】
そこで本発明は上記に説明した先行技術に係るスクロール部材、この部材の製造方法を改良し、更に性能を向上させ、チップすきまを減少させ性能的な問題を解消し、初期なじみ性を向上し、潤滑油が枯渇した場合でも潤滑性能を発揮できる皮膜を有するアルミニウム合金製のスクロールを備えるスクロール型流体機械、および、そのスクロール部材とスクロール部材の製造方法を提供することを課題とするものである。
【0012】
【課題を解決するための手段】
本発明は前述の課題を解決するために次の手段を提供する。
【0013】
(1)アルミニウム合金製の一対の固定スクロールと旋回スクロールとを備えるスクロール型流体機械であって、前記固定スクロールまたは旋回スクロールのどちらか一方のスクロールの表面に、硬質陽極酸化処理皮膜を形成させ、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、水酸化ナトリウムのエッチングによるポア開口処理を行うことで、前記皮膜中に生ずるポアの表層部のみに同ポアの径より拡大させた拡大開口部を設け、同ポア内にすずを含浸させた自己潤滑性表面処理皮膜を形成してなることを特徴とするスクロール型流体機械。
【0014】
(2)スクロール型流体機械のアルミニウム合金製のスクロール部材であって、同スクロール部材の表面に、硬質陽極酸化処理皮膜を形成させ、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、水酸化ナトリウムのエッチングによるポア開口処理を行うことで、前記皮膜中に生ずるポアの表層部のみに同ポアの径より拡大させた拡大開口部を設け、同ポア内にすずを含浸させた自己潤滑性表面処理皮膜を形成してなることを特徴とするスクロール部材。
【0015】
(3)スクロール型流体機械のアルミニウム合金製のスクロール部材の表面に硬質陽極酸化処理皮膜を形成し、次に、同スクロール部材を硫酸第1すずイオンを含む水溶液中で陰極側として電解し、前記硬質陽極酸化処理皮膜中に生じたポアにすずを析出せしめた状態で、前記硬質陽極酸化処理皮膜の表層部を水酸化ナトリウム水溶液中に所定時間浸漬して前記ポアの表層部をエッチングすることにより同ポアの径よりも拡大した拡大開口部を、前記ポアの表層部のみに形成し、次に、前記電解を施して同硬質陽極酸化処理皮膜中にすずを含浸させた自己潤滑性表面処理皮膜を形成することを特徴とするスクロール部材の製造方法。
【0016】
(4)スクロール型流体機械のアルミニウム合金製のスクロール部材の表面に硬質陽極酸化処理皮膜を形成し、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、前記硬質陽極酸化処理皮膜の表層部を水酸化ナトリウム水溶液中に所定時間浸漬し同硬質陽極酸化処理皮膜に生じたポアの表層部をエッチングすることにより同ポアの径よりも拡大した拡大開口部を、前記ポアの表層部のみに形成し、次に、同スクロール部材を硫酸第1すずイオンを含む水溶液中で陰極側として電解し、前記ポア内にすずを析出せしめ、同硬質陽極酸化処理皮膜中にすずを含浸させた自己潤滑性表面処理皮膜を形成することを特徴とするスクロール部材の製造方法。
【0017】
(5)前記エッチングとその後の電解は複数回行うことを特徴とする(3)又は(4)記載のスクロール部材の製造方法。
【0018】
(6)前記ポアの拡大した径は、同ポアの拡大してない部分の径よりも大きく、最大2倍であって2倍以下の範囲であり、拡大部の形状は底部に向って徐々に減少する漏斗状であって、その深さは、ポア全体の深さをポア拡大開口部の深さで除算した値が1.25以上5以下であることを特徴とする(1)記載のスクロール型流体機械。
【0019】
(7)前記ポアの拡大した径は、同ポアの拡大してない部分の径よりも大きく、最大2倍であって2倍以下の範囲であり、拡大部の形状は底部に向って徐々に減少する漏斗状であって、その深さは、ポア全体の深さをポア拡大開口部の深さで除算した値が1.25以上5以下であることを特徴とする(2)記載のスクロール部材。
【0020】
(8)前記ポアの拡大した径は、同ポアの拡大してない部分の径よりも大きく、最大2倍であって2倍以下の範囲であり、拡大部の形状は底部に向って徐々に減少する漏斗状であって、その深さは、ポア全体の深さをポア拡大開口部の深さで除算した値が1.25以上5以下であることを特徴とする(3)から(5)のいずれかに記載のスクロール部材の製造方法。
【0021】
本発明の(1)のスクロール型流体機械においては、ポアの径が表層部で拡大しており、この部分では比較的高度が低くすず濃度の高い皮膜によりなじみ性とすずの持つ自己潤滑作用により、固定スクロールと旋回スクロールとの間に潤滑油が枯渇した場合でも両スクロール間の潤滑作用を保持し凝着に至らないスクロール型流体機械を得ることができる。
【0022】
本発明の(2)のスクロール部材においては、部材におけるポアの径が表層部で拡大しており、すず濃度の高い皮膜によりなじみ性とすずの持つ自己潤滑作用を有するスクロール部材が得られ、このスクロール部材をスクロール機械に用いた場合、潤滑性が枯渇した場合でも固定、旋回スクロール間の潤滑作用を保持し凝着に至ることがない。
【0023】
本発明の(3)製造方法においては、すずのなじみ性と自己潤滑作用を有するスクロール部材が容易に製造できる製造方法が実現でき、硫酸第1すずを含む水溶液中での電解と、水酸化ナトリウム水溶液中の浸漬によるエッチングとの工程により、複雑な工程がなく、スクロール部材の一貫製造ラインでの製造を可能とするものである。
【0024】
本発明の(4)の製造方法においては、硬質陽極酸化処理皮膜の形成した後に、すずを析出する電解を行うことなく水酸化ナトリウムによる表層部のエッチングを行いポア開口部を拡大させ、その後電解を行うので、最初の電解の工程がなく、上記(3)の発明よりも工程を簡略化できる。
【0025】
本発明の(5)の製造方法では、エッチングと電解を行う工程を複数回繰り返して行うので、エッチングによりポア開口の拡大を充分に行うと共に、すずのポア内への充填が表層部まで完全になされ、スクロール部材の品質を一層向上させることができる。
【0026】
本発明の(6),(7),(8)では、水酸化ナトリウムによるエッチングで形成される部材表層部におけるポア開口の拡大部の径が、もともとのポアの径よりも大きく、最大2倍まで拡大され、かつその深さも、ポア全長/深さが5〜5/4の範囲、即ち、全長に対して20%〜80%の範囲で充分に開口しており、このような処理により、比較的高度が低くすず濃度の高い皮膜によりなじみ性とすずの持つ自己潤滑作用により、固定スクロールと旋回スクロールとの間に潤滑油が枯渇した場合でも両スクロール間の潤滑作用を保持し凝着に至らないスクロール型流体機械が得られ、それに使用されるスクロール部材が容易に得られるスクロール部材の製造方法が実現されるものである。なお、拡大開口部は概略漏斗状であれば良いもので、本発明は漏斗状に限らず半球状や、放物線回転体状、等の形状であっても同様の効果があり、本発明の範囲に入ることは言うまでもない。
【0027】
【発明の実施の形態】
以下、本発明の実施の形態について図面に基いて具体的に説明する。図1は、本発明の実施の一形態に係るスクロール部材の表面部断面拡大図である。図において、符号1〜3,5,6は図6で示した従来例と同じであるので、そのまま引用して説明する。
【0028】
まず、硬質陽極酸化処理皮膜について説明する。このスクロール部材10について、硬質陽極酸化処理として、硫酸300g/L(Lはリットルであり、以下“L”と表示する)、溶存アルミ5g/Lの液組成の水溶液中で、液温5℃、電流密度2A/dm2、20分の電解(被処理物としてスクロール部材10を陽極にセット)を行い、約20μmの陽極酸化皮膜2を形成される。
【0029】
硬質陽極酸化処理の特徴として、アルミニウム合金母材1の表面に形成された硬質陽極酸化処理皮膜2(以下、単に「陽極酸化皮膜」という)中には、ポアと呼ばれる微小孔が存在する。本実施の形態は、図1に示すように、スクロール部材10のアルミニウム合金母材1の陽極酸化皮膜2のポア3の開口部に拡大開口部20を形成し、このポア3中に潤滑材としてすず5を含浸し、潤滑油が枯渇した場合でも潤滑性能を発揮できる自己潤滑性表面処理皮膜を形成したものである。
【0030】
すずの含浸については、図6の先行技術でも説明したように、陽極酸化皮膜のポア底部のバリヤ層6を介して電解することにより、ポア3中にすず5を析出させ充填するものである。ここで表層部の陽極酸化皮膜2をアルカリエッチングすることで皮膜表層部はポーラス状になり、図1の拡大開口部20が形成され、この部分の皮膜の硬度は通常より低くなる。ただしこの時皮膜の中央部より底部にかけては通常の硬度が維持できる。この状態ですずを電解することで表層部にすず濃度を高めた皮膜を得ることができる。すず5は軟質の材料で自己潤滑作用を持つ材料の一つである。
【0031】
陽極酸化皮膜2中にすず5の含浸物を形成することで、すず5の持つ自己潤滑作用により、図6で示した先行技術のものよりも拡大開口部20を有するので、潤滑油が枯渇した場合でも陽極酸化皮膜2表面に、先行技術のものよりもより効果的に潤滑作用を保持し、凝着に至らないスクロール部材、スクロールコンプレッサの製品を得ることができる。
【0032】
次に上記に説明したスクロール部材の製造工程について説明する。まず、スクロール部材10を陽極酸化皮膜2を形成し、最初のすず電解を行う。この時のすず電解液は硫酸第1すずを主として他に硫酸、クレゾールスルホン酸で構成された水溶液で、その中に被処理物であるスクロール部材10を陰極にセットして電解を行った。処理条件は、液温5℃、電流密度100mA/dm2で20分実施した。
【0033】
その後陽極酸化皮膜2の表層部をポーラス化するため、水酸化ナトリウムを1g/L含んだ25〜30℃の水溶液中に240〜360秒間浸漬した。その後2回目のすず電解を30分実施(液組成、温度は初回と同じ)、その後上記エッチング処理をし、さらに3回目のすず電解を40分(液組成、温度は初回と同じ)行った。
【0034】
その結果、陽極酸化皮膜2の表層部はポーラス状になり図1の拡大開口部20を有するポアとなり、この部位の硬度は150〜200HV程度となった。また、ポア3中にすず5の含浸物が形成され、特に表層部にすず濃度を高めることができた。なお施工範囲は、ラップ面と端板面全面である。
【0035】
上記によって製造したスクロール部材10をスクロールコンプレッサ実機に組み込み、チップすきまを従来の設定より狭く設定し、潤滑油が枯渇する条件を設定し稼動試験を行った。その結果、従来の硬質陽極酸化処理皮膜と裸材の組み合わせでは短時間で凝着が生じていた状況に比べ、本実施の形態によるスクロール部材10では凝着が無く問題は発生しなかった。
【0036】
これは陽極酸化皮膜2と皮膜中に存在するすず5との効果である。すず5が陽極酸化皮膜2中に存在することで、自己潤滑性表面処理皮膜が形成され、潤滑油が皆無になった場合でもスクロールコンプレッサシステム内の潤滑油が循環し、同部に到達するまで凝着を生じず稼動を続けることができ、さらにチップすきまを従来に比べ狭く設定したが、表層部での陽極酸化皮膜のポーラス部とすず濃度の高い状態によってなじみがよく潤滑性も良いため、このような状況が頻発した場合においても損傷が生じない。
【0037】
次に、上記の工程によって製造したスクロール部材10のポアの形状について図2により説明する。図2は図1における部分拡大図であり、ポア3の全長をa、拡大開口部の直径をb、拡大開口部の深さをcとし、ポア3の径をdとすると、(a対c)=(100対20)〜(100対80)の範囲とし、望ましくは、(a対c)=(100対25)〜(100対50)の範囲とする。また、b>dであって、望ましくは、1.1d≦b≦2d,さらに望ましくは、1.4d≦b≦2d、より望ましくは、b=2dが好ましい。ここで(a対c)=(100対20)〜(100対80)の範囲であれば拡大開口部の効果が充分に得られる。この比が(100対20)を下回ると拡大開口部の効果は得られにくく、逆に(100対80)を上回ると陽極酸化皮膜2の強度が下がってしまう。拡大開口部の効果を発揮しつつ陽極酸化皮膜2の強度低下を実害のない程度に抑えられる範囲は(100対25)から(100対50)である。また、1.1d>bでは開口部拡大の効果が充分に得られないか、あるいは加工精度的に問題があるが、1.1d≦bであればこのような問題はなく、1.4d≦bであれば開口部拡大の効果が大きく得られ、さらにb=2dとすると、さらに効果が大きくなることから、このような範囲が決まるものである。ただし、b>2dとなると、拡大開口部20が大きすぎて陽極酸化皮膜2の強度を不必要に下げるおそれがあるので範囲の極限はb=2dとなる。このことは、図1を見るとわかりやすい。
【0038】
図3は上記のスクロール部材10の処理工程を示すブロック図であり、まず、上記に説明した硬質陽極酸化処理P1を行い、P2において、まずポア3にすず電解を行ってSn含浸処理P2を行う。その後、P3において、水酸化ナトリウム水溶液に浸漬してエッチング処理によりポア開口処理S1を行い、続いてSn含浸処理S2を行う、処理P3を行う。又、必要に応じて、S1,S2による処理P4を繰り返し行い終了する。
【0039】
上記の工程においてはP1,P2,P3,P4により処理を行う方法と、P2をなくし、P1,P3,P4により処理を行う方法があり、後者の方が工程が少くて好ましいが、製造条件により必要に応じて両方法のうち適した方法を選ぶことができる。
【0040】
図4は本発明の実施の形態におけるスクロール部材の製造工程を図示した説明図であり、上記に説明したようにまず、P1において硬質陽極酸化処理を行い、アルミニウム合金母材1に陽極酸化皮膜2を形成する。この陽極酸化皮膜2には前述のように微小孔のポア3が形成されている。 次にP2においてSn含浸処理が行なわれ、ポア3の内部の底面にすず5が電解により徐々に形成されてゆく。次に、P3において、まずS1で水酸化ナトリウムのエッチングによりポア3の表層部に拡大開口部20が形成され、次いてS2において電解によりポア3内にすず5を析出させて充填させ、処理を完了する。このS1,S2を含む処理P3は必要に応じてP4,P5と実施しても良いものである。
【0041】
図5はスクロール部材の各種形態に対する比較を説明する図であり、(A)は本発明のものであり、アルミニウム合金母材に陽極酸化皮膜2を形成し、ポア3に拡大開口部20を形成してすず5を充填したものである。(B)は(A)の形態において拡大開口部20がないもの、(C)はポア3の径を拡大してd’>dとしたもの、(D)はポア3内にすず5を充填しないもので、かつ拡大開口部のないものである。
【0042】
上記の各形態のものを比較すると、潤滑性については、拡大開口部20を有する(A),d’>dとした(C)のものが大であって最も良好であり、被膜硬さについては(A)〜(D)についてあまり大差がない。これらを総合判定すると、本発明の(A)のものが潤滑性も良好で、皮膜の硬さも有しており、これら形態のうち最良のスクロール部材であることがわかる。図5において、記号の二重丸は適、三角は可、斜め十字は不適を示す。本発明の範囲に入るものは二重丸で示すものである。
【0043】
以上説明したように、本発明の実施の形態においては、ポア3に拡大開口部20を設け、すず5を充填したことにより、潤滑油が枯渇した場合でも潤滑性能を発揮でき、また圧縮機の性能を向上できる自己潤滑性表面処理皮膜を有するスクロール部材10を備えたスクロールおよび、そのスクロール部材10とスクロール部材10の製造方法を提供するものであり、又、本発明の範囲内で、上記実施の形態に限定されるものではなくその具体的構成、構造に種々の変更を加えてもよいことは言うまでもない。
【0044】
なお、以上説明した実施の形態において、拡大開口部20が漏斗状、すなわち略円錐形である場合についての説明を行ったが、しかし、本発明なこれに限らず、半球形や、放物線回転体状などの形状であっても範囲に入ることは言うまでもない。
【0045】
【発明の効果】
本発明のスクロール型流体機械は、(1)アルミニウム合金製の一対の固定スクロールと旋回スクロールとを備えるスクロール型流体機械であって、前記固定スクロールまたは旋回スクロールのどちらか一方のスクロールの表面に、硬質陽極酸化処理皮膜を形成させ、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、水酸化ナトリウムのエッチングによるポア開口処理を行うことで、前記皮膜中に生ずるポアの表層部のみに同ポアの径より拡大させた拡大開口部を設け、同ポア内にすずを含浸させた自己潤滑性表面処理皮膜を形成してなることを特徴としている。
【0046】
上記の構成により、ポアの径が表層部で拡大しており、この部分では比較的高度が低くすず濃度の高い皮膜によりなじみ性とすずの持つ自己潤滑作用により、固定スクロールと旋回スクロールとの間に潤滑油が枯渇した場合でも両スクロール間の潤滑作用を保持し凝着に至らないスクロール型流体機械を得ることができる。
【0047】
本発明のスクロール部材は、(2)スクロール型流体機械のアルミニウム合金製のスクロール部材であって、同スクロール部材の表面に、硬質陽極酸化処理皮膜を形成させ、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、水酸化ナトリウムのエッチングによるポア開口処理を行うことで、前記皮膜中に生ずるポアの表層部のみに同ポアの径より拡大させた拡大開口部を設け、同ポア内にすずを含浸させた自己潤滑性表面処理皮膜を形成してなることを特徴としている。
【0048】
上記スクロール部材によれば、ポアの径が表層部で拡大しており、すず濃度の高い皮膜によりなじみ性とすずの持つ自己潤滑作用を有するスクロール部材が得られ、このスクロール部材をスクロール機械に用いた場合、潤滑性が枯渇した場合でも固定、旋回スクロール間の潤滑作用を保持し凝着に至ることがない。
【0049】
本発明のスクロール部材の製造方法は、(3)スクロール型流体機械のアルミニウム合金製のスクロール部材の表面に硬質陽極酸化処理皮膜を形成し、次に、同スクロール部材を硫酸第1すずイオンを含む水溶液中で陰極側として電解し、前記硬質陽極酸化処理皮膜中に生じたポアにすずを析出せしめた状態で、前記硬質陽極酸化処理皮膜の表層部を水酸化ナトリウム水溶液中に所定時間浸漬して前記ポアの表層部をエッチングすることにより同ポアの径よりも拡大した拡大開口部を、前記ポアの表層部のみに形成し、次に、前記電解を施して同硬質陽極酸化処理皮膜中にすずを含浸させた自己潤滑性表面処理皮膜を形成することを特徴としている。
【0050】
上記の方法では、すずのなじみ性と自己潤滑作用を有するスクロール部材が容易に製造できる製造方法が実現でき、硫酸第1すずを含む水溶液中での電解と、水酸化ナトリウム水溶液中の浸漬によるエッチングとの工程により、複雑な工程がなく、スクロール部材の一貫製造ラインでの製造を可能とするものである。
【0051】
本発明の更なるスクロール部材の製造方法は、(4)スクロール型流体機械のアルミニウム合金製のスクロール部材の表面に硬質陽極酸化処理皮膜を形成し、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、前記硬質陽極酸化処理皮膜の表層部を水酸化ナトリウム水溶液中に所定時間浸漬し同硬質陽極酸化処理皮膜に生じたポアの表層部をエッチングすることにより同ポアの径よりも拡大した拡大開口部を、前記ポアの表層部のみに形成し、次に、同スクロール部材を硫酸第1すずイオンを含む水溶液中で陰極側として電解し、前記ポア内にすずを析出せしめ、同硬質陽極酸化処理皮膜中にすずを含浸させた自己潤滑性表面処理皮膜を形成することを特徴としている。
【0052】
上記の方法によれば、硬質陽極酸化処理皮膜の形成した後に、すずを析出する電解を行うことなく、水酸化ナトリウムによる表層部のエッチングを行いポア開口部を拡大させ、その後電解を行うので、最初の電解の工程がなく、工程が上記(3)の発明よりも工程が簡略化できる。
【0053】
本発明の(5)の製造方法では、エッチングと電解を行う工程を複数回繰り返して行うので、エッチングによりポア開口の拡大を充分に行うと共に、すずのポア内への充填が表層部まで完全になされ、スクロール部材の品質を一層向上させることができる。
【0054】
本発明の(6),(7),(8)では、水酸化ナトリウムによるエッチングで形成される部材表層部におけるポア開口の拡大部の径が、もともとのポアの径よりも大きく、最大2倍まで拡大され、かつその深さも、ポア全長/深さが5〜5/4の範囲、即ち、全長に対して20%〜80%の範囲で充分に開口しており、このような処理により、比較的高度が低くすず濃度の高い皮膜によりなじみ性とすずの持つ自己潤滑作用により、固定スクロールと旋回スクロールとの間に潤滑油が枯渇した場合でも両スクロール間の潤滑作用を保持し凝着に至らないスクロール型流体機械が得られ、それに使用されるスクロール部材が容易に得られるスクロール部材の製造方法が実現されるものである。
【図面の簡単な説明】
【図1】本発明の実施の一形態に係るスクロール部材の表面部断面拡大図である。
【図2】図1における部分拡大図である。
【図3】本発明の実施の一形態に係るスクロール部材の処理工程を示すブロック図である。
【図4】本発明の実施の一形態に係る製造工程を示す説明図である。
【図5】本発明を含むスクロール部材の各種形態の比較を示す説明図である。
【図6】本発明の先行技術に係るスクロール部材の表面部断面拡大図である。
【図7】一般的なスクロール部材の形状の説明図であり、(a)はスクロール部材の平面図、(b)は(a)におけるA−A矢視断面図である。
【符号の説明】
1 アルミニウム合金母材
2 陽極酸化皮膜
3 ポア
5 すず
6 バリア層
10 スクロール部材
11 ラップ
20 拡大開口部
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an orbiting scroll member formed of an aluminum alloy and / or a surface treatment method of a fixed scroll member, a scroll member subjected to the surface treatment, and a scroll fluid machine using the scroll member, in particular, a scroll compressor. About.
[0002]
[Prior art]
A refrigerant compression part of a scroll type fluid machine, for example, a refrigerant scroll compressor, is constituted by a fixed scroll and a revolving scroll, which are engaged with each other to form a compression mechanism. 7A and 7B are explanatory views of the shape of a fixed scroll scroll member or a general scroll compressor. FIG. 7A is a plan view of the scroll member, and FIG. 7B is a cross-sectional view taken along line AA in FIG.
[0003]
In FIG. 7, the scroll member 10 is formed by spiral teeth called a wrap 11 and an end plate 12 that holds the wrap 11, and the side surfaces (wrap 11) of the scroll members 10 of both the fixed scroll and the orbiting scroll (wrap 11). The room surrounded by the contact portion between the wrap surfaces 11a) and the contact portion between the end plate 12 and the tooth tip (wrap top surface 11b) of the other scroll member 10 is sucked and compressed by the orbiting scroll. It has a structure that repeats. For this reason, contact and sliding between the wrap surfaces 11a, contact between the wrap top surface 11b and the surface of the end plate 12 of the mating scroll member 10 (end plate surface 12a), and sliding occur, which is a countermeasure against wear. It is necessary.
[0004]
In general, when a scroll compressor is used as a compressor for an automobile air conditioner, an aluminum alloy is often used because weight reduction is required. However, in scroll compressors, both fixed and sliding scrolls, which are in mesh with each other, and aluminum scrolls are both made of aluminum alloy. .
[0005]
In the operation of the scroll compressor, the compression operation is performed by the orbiting motion of the orbiting scroll meshed with the fixed scroll. The scroll top surface 11b contacts and slides. Therefore, a groove 11c is provided in the lap top surface 11b of the orbiting scroll, and a member having good sliding property called a chip seal 13 formed of resin is attached to the groove 11c, so that the lap top surface 11b and the mating side Consideration is made so that the end plate surface 12a is not in direct contact.
[0006]
[Problems to be solved by the invention]
In the scroll compressor as described above, conventionally, a surface treatment is performed to form a hard film on the surface of one of the wrap 11 and the end plate 12 of the fixed scroll or the orbiting scroll. The wear resistance is greatly improved and adhesion is prevented from occurring, but the tip seal 13 is also effective when the orbiting scroll does not incline, but when the inclining orbiting is performed. The end plate surface 12a of the fixed scroll and the lap top surface 11b are in direct contact with each other. In this case as well, if there is lubricating oil, it will operate without problems, but depending on the stop condition of the scroll compressor, the lubricating oil may be interrupted, and it has become clear that adhesion is likely to occur due to sliding at this time. .
[0007]
Therefore, the applicant of the present invention has proposed the scroll member shown in FIG. 6, a method for manufacturing the scroll member, and a scroll type fluid machine using this member as a countermeasure, and has also filed a patent application. Next, the contents of this prior art will be described.
[0008]
FIG. 6 is an enlarged cross-sectional view of the surface of the scroll member. As described above, in a scroll type fluid machine, for example, a scroll compressor, one of the wrap 11 and the end plate 12 of either an aluminum alloy fixed scroll or an orbiting scroll. When forming a hard film on the surface, a hard anodizing treatment is used. As shown in FIG. 6, as a feature of the hard anodizing treatment, a hard anodized film formed on the surface of the aluminum alloy base material 1 is used. (Hereinafter simply referred to as “anodized film”) 2 has micropores called pores 3. In this example, as shown in FIG. 6, the pores 3 of the anodized film 2 of the aluminum alloy base material 1 of the scroll member 10 are impregnated with tin 5 as a lubricant, and even when the lubricating oil is exhausted, the lubricating performance is exhibited. A self-lubricating surface treatment film that can be formed is formed.
[0009]
From the structure of the anodized film 2 in which a layer called a barrier layer 6 is present at the bottom (the aluminum alloy base material 1 side) of the pore 3, a scroll member that has been hard anodized using the property of the barrier layer 6 that can be energized. 10 is set on the cathode in an electrolytic solution containing tin ions, and electrolysis is performed through the barrier layer 6, and tin 5 is deposited and filled in the pores 3 of the anodized film 2. Tin 5 is one of soft materials having a self-lubricating action.
[0010]
By forming an impregnated material of tin 5 in the anodic oxide film 2, the self-lubricating action of the tin 5 keeps the lubricating action on the surface of the anodic oxide film 2 even when the lubricating oil is depleted and does not lead to adhesion. Members and scroll compressor products can be obtained.
[0011]
Therefore, the present invention improves the scroll member according to the prior art described above, the manufacturing method of this member, further improves the performance, reduces the chip clearance, eliminates the performance problem, improves the initial conformability, It is an object of the present invention to provide a scroll type fluid machine including an aluminum alloy scroll having a film that can exhibit lubricating performance even when the lubricating oil is depleted, and a method for manufacturing the scroll member and the scroll member.
[0012]
[Means for Solving the Problems]
The present invention provides the following means in order to solve the aforementioned problems.
[0013]
(1) A scroll type fluid machine comprising a pair of aluminum alloy fixed scroll and orbiting scroll, wherein a hard anodized film is formed on the surface of either the fixed scroll or the orbiting scroll, Next, tin impregnation treatment was performed, and in the state where tin was deposited on the pore bottom in the film, pore opening treatment by etching with sodium hydroxide was performed, A scroll characterized in that only a surface portion of a pore generated in the film is provided with an enlarged opening that is larger than the diameter of the pore, and a self-lubricating surface-treated film impregnated with tin is formed in the pore. Type fluid machine.
[0014]
(2) A scroll member made of an aluminum alloy of a scroll type fluid machine, wherein a hard anodized film is formed on the surface of the scroll member; Next, tin impregnation treatment was performed, and in the state where tin was deposited on the pore bottom in the film, pore opening treatment by etching with sodium hydroxide was performed, A scroll characterized in that only a surface portion of a pore generated in the film is provided with an enlarged opening that is larger than the diameter of the pore, and a self-lubricating surface-treated film impregnated with tin is formed in the pore. Element.
[0015]
(3) A hard anodized film is formed on the surface of the scroll member made of an aluminum alloy of the scroll type fluid machine, and then the scroll member is electrolyzed as a cathode side in an aqueous solution containing sulfuric acid first tin ions, Pore formed in hard anodized film bottom To deposit tin In the state An enlarged opening that is larger than the diameter of the pore by immersing the surface layer portion of the hard anodized film in an aqueous sodium hydroxide solution for a predetermined time and etching the surface layer portion of the pore; And forming a self-lubricating surface-treated film in which tin is impregnated in the hard anodized film.
[0016]
(4) forming a hard anodized film on the surface of the scroll member made of aluminum alloy of the scroll type fluid machine; In a state where tin was impregnated and tin was deposited on the pore bottom in the film, An enlarged opening that is larger than the diameter of the pore is obtained by immersing the surface layer of the hard anodized film in an aqueous solution of sodium hydroxide for a predetermined time and etching the surface layer of the pore formed in the hard anodized film. The scroll member is formed only on the surface layer of the pore, and then the scroll member is electrolyzed as a cathode side in an aqueous solution containing sulfuric acid first tin ions to deposit tin in the pore, A method for producing a scroll member, comprising forming a self-lubricating surface-treated film impregnated with tin.
[0017]
(5) The method for manufacturing a scroll member according to (3) or (4), wherein the etching and the subsequent electrolysis are performed a plurality of times.
[0018]
(6) The enlarged diameter of the pore is larger than the diameter of the non-expanded portion of the pore, and is a maximum of twice and not more than twice, and the shape of the enlarged portion gradually increases toward the bottom. The scroll according to (1), wherein the scroll has a decreasing funnel shape, and the depth is a value obtained by dividing the depth of the entire pore by the depth of the pore enlargement opening and is 1.25 or more and 5 or less. Type fluid machine.
[0019]
(7) The enlarged diameter of the pore is larger than the diameter of the non-expanded portion of the pore, and is a maximum of twice and not more than twice, and the shape of the enlarged portion gradually increases toward the bottom. The scroll according to (2), wherein the depth is a decreasing funnel shape, and the depth is a value obtained by dividing the depth of the entire pore by the depth of the pore enlargement opening and is 1.25 or more and 5 or less. Element.
[0020]
(8) The diameter of the enlarged pore is larger than the diameter of the non-expanded portion of the pore and is a maximum of twice and not more than twice, and the shape of the enlarged portion gradually increases toward the bottom. The depth of the funnel is reduced, and the depth is obtained by dividing the depth of the entire pore by the depth of the pore expansion opening and is from 1.25 to 5 (5) to (5) ). The manufacturing method of the scroll member in any one of.
[0021]
In the scroll type fluid machine of (1) of the present invention, the diameter of the pore is enlarged in the surface layer portion, and in this portion, the relatively high altitude and the coating with high tin concentration are compatible with the self-lubricating action of tin and Even when the lubricating oil is depleted between the fixed scroll and the orbiting scroll, it is possible to obtain a scroll type fluid machine that maintains the lubricating action between the two scrolls and does not cause adhesion.
[0022]
In the scroll member of (2) of the present invention, the diameter of the pores in the member is enlarged in the surface layer portion, and a scroll member having a self-lubricating action possessed by the tin and having a conformability and a tin is obtained. When the member is used in a scroll machine, even when the lubricity is depleted, the lubrication action between the fixed and orbiting scroll is maintained and adhesion does not occur.
[0023]
In the production method (3) of the present invention, a production method capable of easily producing a scroll member having tin conformability and self-lubricating action can be realized, and electrolysis in an aqueous solution containing sulfuric acid first tin and aqueous sodium hydroxide solution There is no complicated process by the process of etching by immersion in the inside, and the scroll member can be manufactured on the integrated production line.
[0024]
In the manufacturing method of (4) of the present invention, after the formation of the hard anodized film, etching of the surface layer portion with sodium hydroxide is performed without performing electrolysis to precipitate tin, and then the pore opening is enlarged, and then electrolysis is performed. Therefore, there is no initial electrolysis step, and the process can be simplified as compared with the above invention (3).
[0025]
In the manufacturing method of (5) of the present invention, the etching and electrolysis steps are repeated a plurality of times, so that the pore opening is sufficiently expanded by etching, and the tin is completely filled into the surface layer. The quality of the scroll member can be further improved.
[0026]
In (6), (7) and (8) of the present invention, the diameter of the enlarged portion of the pore opening in the member surface layer portion formed by etching with sodium hydroxide is larger than the original pore diameter, and is twice as much as the maximum. And the depth of the pore is sufficiently open in the range of 5 to 5/4 of the total pore length / depth, that is, in the range of 20% to 80% of the total length. Due to the relatively low altitude and high tin concentration coating, the self-lubricating action of tin and tin maintains the lubricating action between the scrolls even when the lubricant is depleted between the fixed scroll and the orbiting scroll, leading to adhesion. Thus, a scroll member manufacturing method can be realized in which a scroll type fluid machine can be obtained and a scroll member used in the fluid machine can be easily obtained. Note that the enlarged opening may have a substantially funnel shape, and the present invention is not limited to the funnel shape, and the same effect can be obtained even in a hemispherical shape, a parabolic rotating body shape, and the like. It goes without saying that it enters.
[0027]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings. FIG. 1 is an enlarged cross-sectional view of a surface portion of a scroll member according to an embodiment of the present invention. In the figure, reference numerals 1 to 3, 5 and 6 are the same as those of the conventional example shown in FIG.
[0028]
First, the hard anodized film will be described. About this scroll member 10, as hard anodizing treatment, sulfuric acid 300 g / L (L is liter, hereinafter referred to as “L”), dissolved aluminum 5 g / L in an aqueous solution having a liquid composition of 5 ° C., Current density 2A / dm 2 , Electrolysis for 20 minutes (the scroll member 10 is set as an object to be processed on the anode), and an anodic oxide film 2 of about 20 μm is formed.
[0029]
As a feature of the hard anodizing treatment, there are micropores called pores in the hard anodized film 2 (hereinafter simply referred to as “anodized film”) formed on the surface of the aluminum alloy base material 1. In the present embodiment, as shown in FIG. 1, an enlarged opening 20 is formed in the opening of the pore 3 of the anodized film 2 of the aluminum alloy base material 1 of the scroll member 10, and as a lubricant in the pore 3. A self-lubricating surface treatment film is formed which is impregnated with tin 5 and can exhibit lubricating performance even when the lubricating oil is depleted.
[0030]
As described in the prior art of FIG. 6, tin impregnation is performed by depositing and filling tin 5 in the pore 3 by electrolysis through the barrier layer 6 at the bottom of the pore of the anodized film. Here, by subjecting the anodic oxide film 2 of the surface layer portion to alkali etching, the surface layer portion of the film becomes porous, and the enlarged opening 20 of FIG. 1 is formed, and the hardness of the film of this portion becomes lower than usual. However, normal hardness can be maintained from the center to the bottom of the film. By electrolyzing the tin in this state, a film with an increased tin concentration can be obtained on the surface layer portion. Tin 5 is one of soft materials having a self-lubricating action.
[0031]
By forming the impregnated material of tin 5 in the anodized film 2, the self-lubricating action of tin 5 has an enlarged opening 20 than that of the prior art shown in FIG. Even in this case, it is possible to obtain a scroll member and a scroll compressor product that retains the lubricating action more effectively than the prior art on the surface of the anodized film 2 and does not lead to adhesion.
[0032]
Next, the manufacturing process of the scroll member described above will be described. First, the scroll member 10 is formed with the anodic oxide film 2, and the first tin electrolysis is performed. At this time, the tin electrolyte was an aqueous solution mainly composed of sulfuric acid and cresol sulfonic acid in addition to the first tin sulfate, and the scroll member 10 as the object to be processed was set in the cathode and electrolysis was performed. Processing conditions are liquid temperature 5 ° C, current density 100mA / dm. 2 For 20 minutes.
[0033]
Thereafter, in order to make the surface layer portion of the anodized film 2 porous, it was immersed in an aqueous solution at 25 to 30 ° C. containing 1 g / L of sodium hydroxide for 240 to 360 seconds. Thereafter, the second tin electrolysis was carried out for 30 minutes (liquid composition and temperature were the same as the first time), and then the etching treatment was performed, and the third tin electrolysis was carried out for 40 minutes (liquid composition and temperature were the same as the first time).
[0034]
As a result, the surface layer portion of the anodic oxide film 2 became porous and became a pore having the enlarged opening portion 20 of FIG. 1, and the hardness of this portion was about 150 to 200 HV. Further, an impregnated material of tin 5 was formed in the pore 3, and the tin concentration could be increased particularly in the surface layer portion. The construction range is the entire surface of the lapping surface and the end plate surface.
[0035]
The scroll member 10 manufactured as described above was incorporated into an actual scroll compressor, the chip clearance was set narrower than the conventional setting, and the conditions under which the lubricating oil was exhausted were set, and an operation test was performed. As a result, the scroll member 10 according to the present embodiment has no adhesion and no problem has occurred as compared with the situation in which the conventional hard anodized film and the bare material are adhered in a short time.
[0036]
This is the effect of the anodized film 2 and the tin 5 present in the film. By the presence of tin 5 in the anodic oxide film 2, a self-lubricating surface treatment film is formed, and even when there is no lubricating oil, the lubricating oil in the scroll compressor system circulates until it reaches the same part. The operation can be continued without causing adhesion, and the chip clearance is set narrower than before, but because the familiarity is good and the lubricity is good due to the high concentration of tin in the porous part of the anodized film on the surface layer part, Even when such a situation occurs frequently, no damage occurs.
[0037]
Next, the shape of the pores of the scroll member 10 manufactured by the above process will be described with reference to FIG. FIG. 2 is a partially enlarged view of FIG. 1, where the total length of the pore 3 is a, the diameter of the enlarged opening is b, the depth of the enlarged opening is c, and the diameter of the pore 3 is d. ) = (100 to 20) to (100 to 80), preferably (a to c) = (100 to 25) to (100 to 50). Also, b> d, preferably 1.1d ≦ b ≦ 2d, more preferably 1.4d ≦ b ≦ 2d, and more preferably b = 2d. Here, if it is in the range of (a vs. c) = (100 vs. 20) to (100 vs. 80), the effect of the enlarged opening can be sufficiently obtained. When this ratio is less than (100: 20), the effect of the enlarged opening is difficult to obtain, and conversely, when it exceeds (100: 80), the strength of the anodized film 2 is lowered. The range in which the strength reduction of the anodic oxide film 2 can be suppressed to the extent that there is no actual harm while exhibiting the effect of the enlarged opening is from (100 to 25) to (100 to 50). Further, if 1.1d> b, the effect of expanding the opening cannot be sufficiently obtained, or there is a problem in processing accuracy, but if 1.1d ≦ b, there is no such problem, and 1.4d ≦ If b, the effect of enlarging the opening is greatly obtained, and if b = 2d, the effect is further enhanced, and thus such a range is determined. However, when b> 2d, since the enlarged opening 20 is too large and the strength of the anodized film 2 may be unnecessarily lowered, the limit of the range is b = 2d. This can be easily seen from FIG.
[0038]
FIG. 3 is a block diagram showing the processing steps of the scroll member 10. First, the hard anodizing process P1 described above is performed, and in P2, tin electrolysis is first performed on the pore 3 to perform the Sn impregnation process P2. . Thereafter, in P3, a pore opening process S1 is performed by immersion in an aqueous sodium hydroxide solution and an etching process, and then a Sn impregnation process S2 is performed. If necessary, the process P4 by S1 and S2 is repeated and the process ends.
[0039]
In the above steps, there are a method of performing treatment with P1, P2, P3, and P4 and a method of eliminating P2 and performing treatment with P1, P3, and P4. The latter is preferable because it requires fewer steps, but depending on the manufacturing conditions. A suitable method can be selected from both methods as required.
[0040]
FIG. 4 is an explanatory diagram illustrating the manufacturing process of the scroll member according to the embodiment of the present invention. As described above, first, the hard anodizing treatment is performed at P1, and the aluminum alloy base material 1 is subjected to the anodized film 2. Form. The anodic oxide film 2 is formed with micropores 3 as described above. Next, Sn impregnation is performed at P2, and tin 5 is gradually formed on the bottom surface inside the pore 3 by electrolysis. Next, in P3, first, an enlarged opening 20 is formed in the surface layer portion of the pore 3 by etching with sodium hydroxide in S1, and then tin 5 is deposited and filled in the pore 3 by electrolysis in S2, and the treatment is performed. Complete. The process P3 including S1 and S2 may be performed as P4 and P5 as necessary.
[0041]
FIG. 5 is a diagram for explaining a comparison with respect to various forms of scroll members. FIG. 5A shows the present invention, in which an anodized film 2 is formed on an aluminum alloy base material, and an enlarged opening 20 is formed in a pore 3. Thus, tin 5 is filled. (B) is the one with no enlarged opening 20 in the form of (A), (C) is one in which the diameter of the pore 3 is enlarged to satisfy d ′> d, and (D) is filled with tin 5 in the pore 3. It does not have, and there is no expansion opening part.
[0042]
Comparing each of the above-mentioned forms, the lubricity is most favorable with (A) having an enlarged opening 20 and (C) where d ′> d, and the film hardness is the best. There is not much difference between (A) to (D). When these are comprehensively judged, the material of (A) of the present invention has good lubricity and has a coating hardness, and it is understood that these are the best scroll members among these forms. In FIG. 5, double circles of symbols indicate appropriate, triangles indicate acceptable, and oblique crosses indicate inappropriate. Those within the scope of the present invention are indicated by double circles.
[0043]
As described above, in the embodiment of the present invention, the enlarged opening 20 is provided in the pore 3 and the tin 5 is filled, so that the lubricating performance can be exhibited even when the lubricating oil is depleted. A scroll provided with a scroll member 10 having a self-lubricating surface treatment film capable of improving performance, and a method of manufacturing the scroll member 10 and the scroll member 10 are also provided. It goes without saying that the present invention is not limited to this embodiment, and various modifications may be made to its specific configuration and structure.
[0044]
In the embodiment described above, the case where the enlarged opening 20 has a funnel shape, that is, a substantially conical shape has been described. However, the present invention is not limited to this, but a hemispherical shape or a parabolic rotator is provided. Needless to say, even a shape such as a shape falls within the range.
[0045]
【The invention's effect】
The scroll type fluid machine of the present invention is (1) a scroll type fluid machine comprising a pair of fixed scrolls made of aluminum alloy and a turning scroll, on the surface of either the fixed scroll or the turning scroll. Forming a hard anodized film, Next, tin impregnation treatment was performed, and in the state where tin was deposited on the pore bottom in the film, pore opening treatment by etching with sodium hydroxide was performed, Only the surface layer portion of the pore generated in the coating is provided with an enlarged opening that is larger than the diameter of the pore, and a self-lubricating surface treatment coating impregnated with tin is formed in the pore.
[0046]
With the above configuration, the pore diameter has been enlarged in the surface layer, and in this part, the relatively high altitude tin film and the self-lubricating action of tin are compatible with the fixed scroll and the orbiting scroll. Even when the lubricating oil is depleted, it is possible to obtain a scroll type fluid machine that maintains the lubricating action between both scrolls and does not lead to adhesion.
[0047]
The scroll member of the present invention is (2) a scroll member made of an aluminum alloy of a scroll type fluid machine, wherein a hard anodized film is formed on the surface of the scroll member, Next, tin impregnation treatment was performed, and in the state where tin was deposited on the pore bottom in the film, pore opening treatment by etching with sodium hydroxide was performed, Only the surface layer portion of the pore generated in the coating is provided with an enlarged opening that is larger than the diameter of the pore, and a self-lubricating surface treatment coating impregnated with tin is formed in the pore.
[0048]
According to the scroll member, the diameter of the pore is enlarged in the surface layer portion, and a scroll member having a self-lubricating action with a conformability and tin is obtained by a film having a high tin concentration, and this scroll member was used in a scroll machine. In this case, even when the lubricity is depleted, the lubrication action between the fixed and orbiting scrolls is maintained and adhesion does not occur.
[0049]
The method of manufacturing a scroll member according to the present invention includes (3) forming a hard anodized film on the surface of an aluminum alloy scroll member of a scroll type fluid machine, and the scroll member contains first tin ions. Pore generated in the hard anodized film by electrolysis as cathode side in aqueous solution bottom To deposit tin In the state An enlarged opening that is larger than the diameter of the pore by immersing the surface layer portion of the hard anodized film in an aqueous sodium hydroxide solution for a predetermined time and etching the surface layer portion of the pore; The self-lubricating surface treatment film in which tin is impregnated in the hard anodized film is then formed by performing the electrolysis.
[0050]
In the above method, it is possible to realize a manufacturing method capable of easily manufacturing a scroll member having a conformability of tin and a self-lubricating action, and electrolysis in an aqueous solution containing sulfuric acid first tin and etching by immersion in an aqueous sodium hydroxide solution. With this process, there is no complicated process, and it is possible to manufacture the scroll member on the integrated production line.
[0051]
A further method for manufacturing a scroll member according to the present invention includes (4) forming a hard anodized film on the surface of the scroll member made of an aluminum alloy of the scroll type fluid machine, In a state where tin was impregnated and tin was deposited on the pore bottom in the film, An enlarged opening that is larger than the diameter of the pore is obtained by immersing the surface layer of the hard anodized film in an aqueous sodium hydroxide solution for a predetermined time and etching the surface layer of the pore formed in the hard anodized film. The scroll member is formed only on the surface layer of the pore, and then the scroll member is electrolyzed as a cathode side in an aqueous solution containing sulfuric acid first tin ions to deposit tin in the pore, and in the hard anodized film It is characterized by forming a self-lubricating surface treatment film impregnated with tin.
[0052]
According to the above method, after the formation of the hard anodized film, without performing electrolysis for depositing tin, the surface layer portion is etched with sodium hydroxide to enlarge the pore opening, and then electrolysis is performed. There is no first electrolysis process, and the process can be simplified compared to the invention of (3) above.
[0053]
In the manufacturing method of (5) of the present invention, the etching and electrolysis steps are repeated a plurality of times, so that the pore opening is sufficiently expanded by etching, and the tin is completely filled into the surface layer. The quality of the scroll member can be further improved.
[0054]
In (6), (7) and (8) of the present invention, the diameter of the enlarged portion of the pore opening in the member surface layer portion formed by etching with sodium hydroxide is larger than the original pore diameter, and is twice as much as the maximum. And the depth of the pore is sufficiently open in the range of 5 to 5/4 of the total pore length / depth, that is, in the range of 20% to 80% of the total length. Due to the relatively low altitude and high tin concentration coating, the self-lubricating action of tin and tin maintains the lubricating action between the scrolls even when the lubricant is depleted between the fixed scroll and the orbiting scroll, leading to adhesion. Thus, a scroll member manufacturing method can be realized in which a scroll type fluid machine can be obtained and a scroll member used in the fluid machine can be easily obtained.
[Brief description of the drawings]
FIG. 1 is an enlarged cross-sectional view of a surface portion of a scroll member according to an embodiment of the present invention.
FIG. 2 is a partially enlarged view of FIG.
FIG. 3 is a block diagram showing processing steps for a scroll member according to an embodiment of the present invention.
FIG. 4 is an explanatory diagram showing a manufacturing process according to an embodiment of the present invention.
FIG. 5 is an explanatory view showing a comparison of various forms of scroll members including the present invention.
FIG. 6 is an enlarged cross-sectional view of a surface portion of a scroll member according to the prior art of the present invention.
7A and 7B are explanatory views of the shape of a general scroll member, where FIG. 7A is a plan view of the scroll member, and FIG. 7B is a cross-sectional view taken along line AA in FIG.
[Explanation of symbols]
1 Aluminum alloy base material
2 Anodized film
3 pores
5 Tin
6 Barrier layer
10 Scroll member
11 laps
20 Enlarged opening

Claims (8)

アルミニウム合金製の一対の固定スクロールと旋回スクロールとを備えるスクロール型流体機械であって、前記固定スクロールまたは旋回スクロールのどちらか一方のスクロールの表面に、硬質陽極酸化処理皮膜を形成させ、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、水酸化ナトリウムのエッチングによるポア開口処理を行うことで、前記皮膜中に生ずるポアの表層部のみに同ポアの径より拡大させた拡大開口部を設け、同ポア内にすずを含浸させた自己潤滑性表面処理皮膜を形成してなることを特徴とするスクロール型流体機械。A scroll type fluid machine comprising a pair of fixed scrolls and orbiting scrolls made of an aluminum alloy, wherein a hard anodized film is formed on the surface of either the fixed scroll or the orbiting scroll , In the state in which tin impregnation treatment was performed and tin was deposited on the pore bottom in the film, pore opening treatment by etching with sodium hydroxide was performed, so that the diameter of the pore was formed only on the surface layer portion of the pore generated in the film. A scroll type fluid machine comprising a further enlarged opening and a self-lubricating surface-treated film impregnated with tin in the pore. スクロール型流体機械のアルミニウム合金製のスクロール部材であって、同スクロール部材の表面に、硬質陽極酸化処理皮膜を形成させ、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、水酸化ナトリウムのエッチングによるポア開口処理を行うことで、前記皮膜中に生ずるポアの表層部のみに同ポアの径より拡大させた拡大開口部を設け、同ポア内にすずを含浸させた自己潤滑性表面処理皮膜を形成してなることを特徴とするスクロール部材。A scroll member made of an aluminum alloy for a scroll type fluid machine, wherein a hard anodized film is formed on the surface of the scroll member, and then tin impregnation is performed to deposit tin on the pore bottom in the film. In the caulked state, by performing pore opening treatment by etching sodium hydroxide , an enlarged opening that is larger than the diameter of the pore is provided only in the surface layer portion of the pore generated in the film, and the tin is placed in the pore. A scroll member comprising an impregnated self-lubricating surface treatment film. スクロール型流体機械のアルミニウム合金製のスクロール部材の表面に硬質陽極酸化処理皮膜を形成し、次に、同スクロール部材を硫酸第1すずイオンを含む水溶液中で陰極側として電解し、前記硬質陽極酸化処理皮膜中に生じたポアにすずを析出せしめた状態で、前記硬質陽極酸化処理皮膜の表層部を水酸化ナトリウム水溶液中に所定時間浸漬して前記ポアの表層部をエッチングすることにより同ポアの径よりも拡大した拡大開口部を、前記ポアの表層部のみに形成し、次に、前記電解を施して同硬質陽極酸化処理皮膜中にすずを含浸させた自己潤滑性表面処理皮膜を形成することを特徴とするスクロール部材の製造方法。A hard anodizing film is formed on the surface of an aluminum alloy scroll member of a scroll type fluid machine, and then the scroll member is electrolyzed as an anode side in an aqueous solution containing sulfuric acid first tin ions, in a state in which allowed precipitation of pore bottom NiSuzu occurring during treatment film, the pores by by immersing a predetermined time of the surface layer portion of the hard anodized film in an aqueous solution of sodium hydroxide to etch the surface portion of the pore An enlarged opening that is larger than the diameter of the pore is formed only on the surface layer of the pore, and then the electrolysis is performed to form a self-lubricating surface-treated film in which tin is impregnated in the hard anodized film. A method for manufacturing a scroll member. スクロール型流体機械のアルミニウム合金製のスクロール部材の表面に硬質陽極酸化処理皮膜を形成し、次に、すず含浸処理を行い、前記皮膜中のポア底にすずを析出せしめた状態で、前記硬質陽極酸化処理皮膜の表層部を水酸化ナトリウム水溶液中に所定時間浸漬し同硬質陽極酸化処理皮膜に生じたポアの表層部をエッチングすることにより同ポアの径よりも拡大した拡大開口部を、前記ポアの表層部のみに形成し、次に、同スクロール部材を硫酸第1すずイオンを含む水溶液中で陰極側として電解し、前記ポア内にすずを析出せしめ、同硬質陽極酸化処理皮膜中にすずを含浸させた自己潤滑性表面処理皮膜を形成することを特徴とするスクロール部材の製造方法。A hard anodizing film is formed on the surface of an aluminum alloy scroll member of a scroll type fluid machine, and then tin impregnation is performed, and tin is deposited on the pore bottom in the film. An enlarged opening that is larger than the diameter of the pore is formed by immersing the surface layer portion of the oxidation treatment film in a sodium hydroxide aqueous solution for a predetermined time and etching the surface layer portion of the pore generated in the hard anodization treatment film. Next, the scroll member is electrolyzed as a cathode side in an aqueous solution containing sulfuric acid first tin ions, tin is deposited in the pores, and tin is deposited in the hard anodized film. A method for producing a scroll member, comprising forming an impregnated self-lubricating surface treatment film. 前記エッチングとその後の電解は複数回行うことを特徴とする請求項3又は4記載のスクロール部材の製造方法。  The method for manufacturing a scroll member according to claim 3 or 4, wherein the etching and the subsequent electrolysis are performed a plurality of times. 前記ポアの拡大した径は、同ポアの拡大してない部分の径よりも大きく、最大2倍であって2倍以下の範囲であり、拡大部の形状は底部に向って徐々に減少する漏斗状であって、その深さは、ポア全体の深さをポア拡大開口部の深さで除算した値が1.25以上5以下であることを特徴とする請求項1記載のスクロール型流体機械。  The enlarged diameter of the pore is larger than the diameter of the non-expanded portion of the pore and is in the range of up to 2 times and less than 2 times, and the shape of the enlarged portion gradually decreases toward the bottom. 2. The scroll type fluid machine according to claim 1, wherein the depth is a value obtained by dividing the depth of the entire pore by the depth of the enlarged pore opening and is 1.25 or more and 5 or less. . 前記ポアの拡大した径は、同ポアの拡大してない部分の径よりも大きく、最大2倍であって2倍以下の範囲であり、拡大部の形状は底部に向って除々に減少する漏斗状であって、その深さは、ポア全体の深さをポア拡大開口部の深さで除算した値が1.25以上5以下であることを特徴とする請求項2記載のスクロール部材。  The enlarged diameter of the pore is larger than the diameter of the non-expanded portion of the pore and is in the range of up to 2 times and less than 2 times, and the shape of the enlarged portion gradually decreases toward the bottom. 3. The scroll member according to claim 2, wherein the depth is a value obtained by dividing the depth of the entire pore by the depth of the pore enlargement opening and is 1.25 or more and 5 or less. 前記ポアの拡大した径は、同ポアの拡大してない部分の径よりも大きく、最大2倍であって2倍以下の範囲であり、拡大部の形状は底部に向って除々に減少する漏斗状であって、その深さは、ポア全体の深さをポア拡大開口部の深さで除算した値が1.25以上5以下であることを特徴とする請求項3から5のいずれかに記載のスクロール部材の製造方法。  The enlarged diameter of the pore is larger than the diameter of the non-expanded portion of the pore and is in the range of up to 2 times and less than 2 times, and the shape of the enlarged portion gradually decreases toward the bottom. 6. The depth according to claim 3, wherein a value obtained by dividing the depth of the entire pore by the depth of the pore enlargement opening is 1.25 or more and 5 or less. The manufacturing method of the scroll member of description.
JP2002160882A 2002-06-03 2002-06-03 Scroll type fluid machine, scroll member and method of manufacturing the member Expired - Fee Related JP3958118B2 (en)

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