JP3943994B2 - Microwave cooking materials - Google Patents

Microwave cooking materials Download PDF

Info

Publication number
JP3943994B2
JP3943994B2 JP2002158489A JP2002158489A JP3943994B2 JP 3943994 B2 JP3943994 B2 JP 3943994B2 JP 2002158489 A JP2002158489 A JP 2002158489A JP 2002158489 A JP2002158489 A JP 2002158489A JP 3943994 B2 JP3943994 B2 JP 3943994B2
Authority
JP
Japan
Prior art keywords
starch
microwave oven
weight
cooking
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2002158489A
Other languages
Japanese (ja)
Other versions
JP2003079334A (en
JP2003079334A5 (en
Inventor
隆弘 柳下
博文 本井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nisshin Seifun Group Inc
Original Assignee
Nisshin Seifun Group Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nisshin Seifun Group Inc filed Critical Nisshin Seifun Group Inc
Priority to JP2002158489A priority Critical patent/JP3943994B2/en
Publication of JP2003079334A publication Critical patent/JP2003079334A/en
Publication of JP2003079334A5 publication Critical patent/JP2003079334A5/ja
Application granted granted Critical
Publication of JP3943994B2 publication Critical patent/JP3943994B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【0001】
【発明の属する技術分野】
本発明は、電子レンジ調理用に適した衣材に関する。
【0002】
【従来の技術】
近年、食生活の簡便化に伴い、電子レンジによる加熱調理が普及している。電子レンジ調理は調理済み食品にマイクロ波を数分間照射することにより、簡便かつ迅速に食事に供することができる利点がある。
しかしながら、調理済み食品が天ぷら、とんかつ、コロッケ、唐揚げ等の揚げ物の場合、電子レンジ加熱することで衣のクリスピー感が消失して、べたついた食感となったり、食感が硬くなり、「引き」が強く歯切れが悪くなる欠点があった。この原因は電子レンジで加熱すると食品内部の温度上昇が速いために、水分の蒸発が多くなり、具材から衣への水分移行が生じると共に、衣を構成している澱粉、蛋白質が過度に熱変性されるためと推測される。
【0003】
従来、これらの問題点を解決する方法として例えば麦粉に対して酸処理澱粉、湿熱処理澱粉、架橋処理済みα化澱粉のうち少なくとも1種類が配合されていることを特徴とする揚げ物衣用ミックスが提案されている(特開平7−303457号公報参照)。しかしながら、この揚げ物衣用ミックスを用いても電子レンジ調理後における食感の改良効果は満足し得るものではなかった。
【0004】
【発明が解決しようとする課題】
そこで本発明者等は、電子レンジで揚げ物を解凍したり、加熱しても衣にクリスピー感を有し、また食感が硬くなく、歯切れの良い特性を有する衣材について種々研究を重ねた結果本発明を完成するに至った。
【0005】
【課題を解決するための手段】
すなわち、本発明は、置換度0.001〜0.1のヒドロキシプロピル澱粉、置換度0.001〜0.1のアセチル化澱粉、RVA最高粘度100〜4,000cpの酸化澱粉またはRVA最高粘度50〜4,000cpの架橋澱粉を加熱して加熱処理前の糊化ピーク温度より0.5〜5.0℃高くした加熱処理澱粉の少なくとも1種を2〜100重量%含有する電子レンジ調理用衣材である。
【0006】
【発明の実施の形態】
本発明の加熱処理澱粉に用いられるヒドロキシプロピル澱粉は、置換度0.001〜0.1、特に0.01〜0.08の範囲のものが好ましい。この置換度が0.001未満では改質の効果がなく、また0.1を超えると改質効果が低下する。
【0007】
アセチル化澱粉は、置換度0.001〜0.1、特に0.01〜0.08の範囲のものが好ましい。この置換度が0.001未満の場合には改質の効果がなく、また0.1を超えると改質効果が低下する。
なお前記置換度(DS)はグルコース残基1個当りの置換水酸基の平均値である。
【0008】
酸化澱粉は、RVA最高粘度100〜4,000cp、特に500〜2,500cpの範囲のものが好ましい。このRVA最高粘度が100cp未満であると改質効果がなく、一方4,000cpを超えると改質効果が低下する。
【0009】
架橋澱粉は、RVA最高粘度50〜4,000cp、特に100〜2,500cpの範囲のものが好ましい。このRVA最高粘度が50cp未満であると改質効果がなく、一方4,000cpを超えると改質効果が低下する。
【0010】
本発明において用いられる加熱処理澱粉の澱粉類としてはタピオカ澱粉、コーンスターチ、馬鈴薯澱粉、甘藷澱粉、小麦澱粉、米澱粉、サゴ澱粉、ソルガム澱粉等が挙げられるが、特にタピオカ澱粉が好ましい。
【0011】
本発明の加熱処理後における糊化ピーク温度を0.5〜5.0℃上昇させた加熱処理澱粉を調製する方法としては種々の加熱処理方法が採用できるが、例えば水分調整した澱粉をレトルト袋に入れ、オートクレーブにより120℃で60分間加熱処理することにより得ることができる。
この際澱粉は水分含量を8〜25重量%、特に15〜19%の範囲とすることが好ましい。この水分含量が8重量%未満であると処理による改質効果が少なく、一方25重量%を超えると澱粉の崩壊がはじまりべとつきを生じるようになる。
【0012】
前記加熱処理による糊化ピーク温度の上昇が0.5℃未満であると電子レンジ調理用衣材の食感にひきがでるようになり、一方5.0℃を超えると食感が重たく口溶けが悪くなる。
【0013】
本発明の加熱処理澱粉は1種または2種以上を適宜混合して使用することができる。
【0014】
電子レンジ調理用衣材に添加される加熱処理澱粉の添加量は、電子レンジ調理用衣材中に2〜100重量%、特に5〜75重量%(乾物換算)含有させることが好ましい。
【0015】
本発明の電子レンジ調理用衣材に用いられる素材としては前記加熱処理澱粉の外、小麦粉、大豆タンパク粉、デキストリン、卵白粉、脱脂粉乳、粉末油脂、ベーキングパウダー、重曹、食塩、グルタミン酸ソーダ等の衣材として用いられるものであればいずれも好適に用いることができる。
【0016】
本発明における糊化エネルギーは下記のようにして測定する。
RVA最高粘度の測定
迅速粘度測定装置(ニューポート サンエンティフィク社製)を用い、アルミ缶に供試澱粉(水分14%換算)2gおよび蒸留水25mLを加えた後パドル(撹拌子)を入れタワーにセットしパドルを回転(160 r/min)させながら加熱上昇させて粘度を測定する。この時の加熱上昇条件は、はじめに供試澱粉懸濁液を50℃で1分間保持した後7分30秒をかけて95℃まで上昇させ、同温度で5分間保持する。次いで7分30秒を要して50℃まで冷却した後同温度で2分間保持し粘度の測定を終了する。そしてこの測定結果で最も粘度の高い値をRVA最高粘度(cp)とする。
糊化ピーク温度の測定
示差走査型熱量計(セイコー社製)を用い、供試澱粉の乾物重量10mgに対し40mgの蒸留水を加えたアルミカプセルと、同量の蒸留水のみを加えたアルミカプセルを比較対照して、25℃から140℃まで毎分5℃ずつ昇温させて、対照との吸熱エネルギーの差異を測定する。そして糊化される時に生じる吸熱エネルギー(30℃から100℃の間に形成されるピーク)の頂点を糊化ピーク温度(℃)として表わす。
【0017】
本発明の電子レンジ調理用衣材は具体的にはコロッケ、天ぷら、唐揚げ、とんかつ、アメリカンドック、フリッター、フィッシュポーション、春巻等の揚げ物の衣材として用いることができる。
【0018】
【実施例】
本発明をさらに具体的に説明するために実施例を掲げるが、本発明は以下の実施例に限定されるものではない。
【0019】
実施例1〜2、比較例1〜3
小麦粉60重量部、供試澱粉25重量部、大豆蛋白15重量部および水300重量部からなるバッター液を調製した。コロッケの具に前記バッター液をつけた後パン粉をまぶし、175℃で3分30秒間油ちょうした。これを急速冷凍し、−20℃で20日間保存した。次に冷凍コロッケを電子レンジ(500W)で調理し、表1に示す評価基準に従って評価した。その評価結果を示せば表2のとおりである。
【0020】
【表1】

Figure 0003943994
【0021】
【表2】
Figure 0003943994
【0022】
実施例3〜13、比較例4〜10
イモに小麦粉の打ち粉をふり、これを小麦粉90重量部、供試澱粉10重量部、ベーキングパウダー1.5重量部および水150重量部からなるバッター液につけ、170℃で3分間油ちょうしてイモ天ぷらを得た。得られたイモ天ぷらを30分間冷却した後、冷蔵庫(4℃)で24時間保存した。これを電子レンジ(500W)で1分間加熱調理し、表3に示す評価基準に従い評価した。その評価結果を示せば表4〜表6のとおりである。
【0023】
【表3】
Figure 0003943994
【0024】
【表4】
Figure 0003943994
【0025】
【表5】
Figure 0003943994
【0026】
【表6】
Figure 0003943994
【0027】
【発明の効果】
本発明の電子レンジ調理用衣材を用いて揚げ物を調製すると冷蔵あるいは冷凍保存時の劣化を防ぎ、また電子レンジで解凍・加熱しても食感の硬化や「引き」が生ぜず、揚げたてのクリスピー感のあるサクサクした食感を有し、さらに電子レンジ調理後の老化をも抑制することができる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a clothing material suitable for cooking in a microwave oven.
[0002]
[Prior art]
In recent years, with the simplification of eating habits, cooking with a microwave oven has become widespread. Microwave cooking has the advantage that it can be easily and quickly served by irradiating cooked food with microwaves for several minutes.
However, when the prepared food is deep-fried food such as tempura, tonkatsu, croquette, fried chicken, etc., the crispy feeling of the clothes disappears by heating in the microwave, resulting in a sticky texture or a hard texture. There was a drawback that the “pull” was strong and the crispness was poor. The reason for this is that heating in a microwave oven causes the temperature inside the food to rise quickly, resulting in increased evaporation of moisture, resulting in moisture transfer from the ingredients to the clothing, and the starch and proteins that make up the clothing are overheated. This is presumed to be denatured.
[0003]
Conventionally, as a method for solving these problems, for example, there is a mix for fried foods characterized in that at least one of acid-treated starch, wet heat-treated starch and cross-linked pre-gelatinized starch is blended with wheat flour. It has been proposed (see JP-A-7-303457). However, even when this fried food mix was used, the effect of improving the texture after cooking in a microwave oven was not satisfactory.
[0004]
[Problems to be solved by the invention]
Therefore, the present inventors have conducted various researches on clothing materials that have a crispy feeling even if they are thawed or heated in a microwave oven, and have a crispy texture even when heated, and have a crisp character. The present invention has been completed.
[0005]
[Means for Solving the Problems]
That is, the present invention relates to hydroxypropyl starch having a substitution degree of 0.001 to 0.1, acetylated starch having a substitution degree of 0.001 to 0.1, oxidized starch having an RVA maximum viscosity of 100 to 4,000 cp, or an RVA maximum viscosity of 50. Microwave cooking clothing containing 2 to 100% by weight of at least one kind of heat-treated starch heated to 0.5 to 5.0 ° C. higher than the gelatinization peak temperature before heat treatment by heating ˜4,000 cp cross-linked starch It is a material.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
The hydroxypropyl starch used in the heat-treated starch of the present invention preferably has a substitution degree of 0.001 to 0.1, particularly 0.01 to 0.08. If the degree of substitution is less than 0.001, there is no effect of reforming, and if it exceeds 0.1, the reforming effect decreases.
[0007]
The acetylated starch preferably has a substitution degree of 0.001 to 0.1, particularly 0.01 to 0.08. When the degree of substitution is less than 0.001, there is no effect of modification, and when it exceeds 0.1, the modification effect decreases.
The degree of substitution (DS) is an average value of substituted hydroxyl groups per glucose residue.
[0008]
The oxidized starch preferably has a RVA maximum viscosity of 100 to 4,000 cp, particularly 500 to 2,500 cp. If the RVA maximum viscosity is less than 100 cp, there is no modification effect, while if it exceeds 4,000 cp, the modification effect is lowered.
[0009]
The cross-linked starch preferably has a RVA maximum viscosity of 50 to 4,000 cp, particularly 100 to 2,500 cp. If the RVA maximum viscosity is less than 50 cp, there is no modification effect, while if it exceeds 4,000 cp, the modification effect is lowered.
[0010]
The starches of the heat-treated starch used in the present invention include tapioca starch, corn starch, potato starch, sweet potato starch, wheat starch, rice starch, sago starch, sorghum starch and the like, with tapioca starch being particularly preferred.
[0011]
Various heat treatment methods can be adopted as a method for preparing the heat-treated starch having the gelatinization peak temperature increased by 0.5 to 5.0 ° C. after the heat treatment of the present invention. And heat-treated at 120 ° C. for 60 minutes by an autoclave.
At this time, the starch preferably has a moisture content of 8 to 25% by weight, particularly 15 to 19%. If the water content is less than 8% by weight, the effect of modification by the treatment is small.
[0012]
When the increase in the gelatinization peak temperature due to the heat treatment is less than 0.5 ° C., the texture of the microwave cooking apparel is drawn. On the other hand, when it exceeds 5.0 ° C., the texture is heavy and the mouth melts. Deteriorate.
[0013]
The heat-treated starch of the present invention can be used alone or in combination of two or more.
[0014]
The amount of the heat-treated starch added to the microwave oven cooking material is preferably 2 to 100% by weight, particularly 5 to 75% by weight (in terms of dry matter), in the microwave oven cooking material.
[0015]
In addition to the heat-treated starch, the ingredients used in the microwave cooking apparel of the present invention include wheat flour, soy protein powder, dextrin, egg white powder, skim milk powder, powdered fats and oils, baking powder, baking soda, sodium chloride, sodium glutamate, etc. Any material can be suitably used as long as it is used as a clothing material.
[0016]
The gelatinization energy in the present invention is measured as follows.
RVA maximum viscosity measurement Using a rapid viscosity measuring device (Newport Sanentific), add 2 g of test starch (converted to 14% water) and 25 mL of distilled water to an aluminum can, and then put a paddle (stir bar) into the tower. The viscosity is measured by heating and raising the paddle while rotating the paddle ( 160 r / min). The heating increase condition at this time is as follows. First, the test starch suspension is held at 50 ° C. for 1 minute, then raised to 95 ° C. over 7 minutes and 30 seconds, and held at that temperature for 5 minutes. Next, after cooling for 7 minutes 30 seconds to 50 ° C., the temperature is kept at the same temperature for 2 minutes to complete the measurement of the viscosity. The highest viscosity value in this measurement result is defined as the RVA maximum viscosity (cp).
Measurement of gelatinization peak temperature Using a differential scanning calorimeter (Seiko Co., Ltd.), aluminum capsules with 40 mg of distilled water added to 10 mg dry matter weight of the test starch, and aluminum capsules with only the same amount of distilled water added In comparison, the temperature is raised from 25 ° C. to 140 ° C. by 5 ° C. per minute, and the difference in endothermic energy from the control is measured. And the vertex of the endothermic energy (peak formed between 30 degreeC and 100 degreeC) produced when gelatinizing is represented as gelatinization peak temperature (degreeC).
[0017]
Specifically, the microwave oven cooking material of the present invention can be used as a material for fried foods such as croquettes, tempura, fried chicken, tonkatsu, American docks, fritters, fish potions, spring rolls and the like.
[0018]
【Example】
Examples are provided to further illustrate the present invention, but the present invention is not limited to the following examples.
[0019]
Examples 1-2 and Comparative Examples 1-3
A batter solution comprising 60 parts by weight of wheat flour, 25 parts by weight of the test starch, 15 parts by weight of soy protein and 300 parts by weight of water was prepared. After the batter liquid was put on the croquette, the bread crumbs were applied and oiled at 175 ° C. for 3 minutes and 30 seconds. This was snap frozen and stored at -20 ° C for 20 days. Next, the frozen croquette was cooked in a microwave oven (500 W) and evaluated according to the evaluation criteria shown in Table 1. The evaluation results are shown in Table 2.
[0020]
[Table 1]
Figure 0003943994
[0021]
[Table 2]
Figure 0003943994
[0022]
Examples 3 to 13 and Comparative Examples 4 to 10
Sprinkle flour with potatoes, put it in a batter consisting of 90 parts by weight of wheat flour, 10 parts by weight of the test starch, 1.5 parts by weight of baking powder and 150 parts by weight of water, and oil at 170 ° C for 3 minutes. I got tempura. The obtained potato tempura was cooled for 30 minutes and then stored in a refrigerator (4 ° C.) for 24 hours. This was cooked for 1 minute in a microwave oven (500 W) and evaluated according to the evaluation criteria shown in Table 3. The evaluation results are shown in Tables 4-6.
[0023]
[Table 3]
Figure 0003943994
[0024]
[Table 4]
Figure 0003943994
[0025]
[Table 5]
Figure 0003943994
[0026]
[Table 6]
Figure 0003943994
[0027]
【The invention's effect】
Preparation of deep-fried food using the microwave cooking material of the present invention prevents deterioration during refrigeration or freezing storage, and does not cause texture hardening or “pull” even when thawed and heated in a microwave oven. It has a crispy and crispy texture and can also suppress aging after cooking in a microwave oven.

Claims (2)

置換度0.001〜0.1のヒドロキシプロピル澱粉、置換度0.001〜0.1のアセチル化澱粉、RVA最高粘度100〜4,000cpの酸化澱粉またはRVA最高粘度50〜4,000cpの架橋澱粉を加熱して加熱処理前の糊化ピーク温度より0.5〜5.0℃高くした加熱処理澱粉の少なくとも1種を2〜100重量%含有することを特徴とする電子レンジ調理用衣材。 Hydroxypropyl starch having a degree of substitution of 0.001 to 0.1, acetylated starch having a degree of substitution of 0.001 to 0.1, oxidized starch having a maximum RVA viscosity of 100 to 4,000 cp, or crosslinking having a maximum RVA viscosity of 50 to 4,000 cp A cooking material for microwave oven cooking comprising 2 to 100% by weight of at least one kind of heat-treated starch heated to 0.5 to 5.0 ° C. higher than the gelatinization peak temperature before heat treatment by heating the starch . 澱粉がタピオカ澱粉である請求項1記載の電子レンジ調理用衣材。  The microwave oven cooking material according to claim 1, wherein the starch is tapioca starch.
JP2002158489A 2001-06-29 2002-05-31 Microwave cooking materials Expired - Lifetime JP3943994B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002158489A JP3943994B2 (en) 2001-06-29 2002-05-31 Microwave cooking materials

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2001199095 2001-06-29
JP2001-199095 2001-06-29
JP2002158489A JP3943994B2 (en) 2001-06-29 2002-05-31 Microwave cooking materials

Publications (3)

Publication Number Publication Date
JP2003079334A JP2003079334A (en) 2003-03-18
JP2003079334A5 JP2003079334A5 (en) 2005-06-30
JP3943994B2 true JP3943994B2 (en) 2007-07-11

Family

ID=26617890

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002158489A Expired - Lifetime JP3943994B2 (en) 2001-06-29 2002-05-31 Microwave cooking materials

Country Status (1)

Country Link
JP (1) JP3943994B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101527780B1 (en) * 2013-12-24 2015-06-10 대상 주식회사 Premix composition of stuffed pancake for baking in microwave oven and manufacturing method of stuffed pancake

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4563713B2 (en) * 2004-04-07 2010-10-13 理研ビタミン株式会社 Edible cross-linked starch and food using the same
JP4374497B2 (en) * 2004-04-20 2009-12-02 松谷化学工業株式会社 Edible film
JP5107294B2 (en) * 2009-03-31 2012-12-26 日清フーズ株式会社 Heat-treated flour for fried food
JP5843314B2 (en) * 2011-10-19 2016-01-13 日清フーズ株式会社 Takoyaki or okonomiyaki powder mix
JP6506135B2 (en) * 2015-08-14 2019-04-24 日清フーズ株式会社 Method for producing refrigerated fresh pasta
PE20200712A1 (en) * 2017-07-28 2020-06-25 J Oil Mills Inc METHOD OF PRODUCING RUSTED STARCH FOR COATING MATERIAL
US20220015401A1 (en) * 2018-11-30 2022-01-20 Nisshin Foods Inc. Batter for fried food

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101527780B1 (en) * 2013-12-24 2015-06-10 대상 주식회사 Premix composition of stuffed pancake for baking in microwave oven and manufacturing method of stuffed pancake

Also Published As

Publication number Publication date
JP2003079334A (en) 2003-03-18

Similar Documents

Publication Publication Date Title
JP5069885B2 (en) How to use wet heat-treated flour used as flour for breaded fried food
JP6773691B2 (en) Modified wheat flour for fried food batter
JP5069886B2 (en) How to use wet heat-treated flour to be used as fried flour
JP7076381B2 (en) Batter for fried food
WO2012175930A1 (en) Microwaveable batter
JP3943994B2 (en) Microwave cooking materials
JP4249974B2 (en) Manufacturing method of Tatsuta fried
KR101595292B1 (en) A premix composition for fried food maintaining crispness for a long time under storage in heating cabinet, a fried food prepared by using the same and a method for preparing the fried food
JP2001069903A (en) Flour for tako pancake
JP4415408B2 (en) Fried food batter
JPH07303457A (en) Mix for coating of fried food
JP4618952B2 (en) Manufacturing method of fried food
JP7254910B2 (en) dusting composition
JPH0411858A (en) Flour for frying batter
KR20220002283A (en) modified wheat flour
JP2000316509A (en) Coating matter for frozen fried food
JPH10150957A (en) Flour for baked dumpling containing sliced octopus meat
JP7153145B1 (en) Coating material composition for fried food
JP2002142700A (en) Mix for coating of fried food
JP6960563B1 (en) How to make fried food
JP5890701B2 (en) Batter mix for frozen fried food
JPH11169117A (en) Batter for fried food and fried food using the same
JP4077583B2 (en) Fried food and manufacturing method thereof
JPH09299041A (en) Processed food
JPH11332495A (en) Batter for fried food

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20041008

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20041008

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050801

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20060815

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20061016

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20061017

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20070403

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20070406

R150 Certificate of patent or registration of utility model

Ref document number: 3943994

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110413

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110413

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120413

Year of fee payment: 5

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120413

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130413

Year of fee payment: 6

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140413

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term