JPH09299041A - Processed food - Google Patents

Processed food

Info

Publication number
JPH09299041A
JPH09299041A JP8142324A JP14232496A JPH09299041A JP H09299041 A JPH09299041 A JP H09299041A JP 8142324 A JP8142324 A JP 8142324A JP 14232496 A JP14232496 A JP 14232496A JP H09299041 A JPH09299041 A JP H09299041A
Authority
JP
Japan
Prior art keywords
water content
weight
processed food
water
moisture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8142324A
Other languages
Japanese (ja)
Inventor
Shiyouta Mansei
昌太 満生
Yoko Yamamoto
葉子 山本
Akinori Mizuno
晶徳 水野
Masao Motoki
正雄 本木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Priority to JP8142324A priority Critical patent/JPH09299041A/en
Publication of JPH09299041A publication Critical patent/JPH09299041A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain a processed food capable of suppressing the deterioration in eat feeling thereof accompanying with the transfer of water without affecting an original taste, flavor, etc., by containing a specific component in part thereof deteriorating in the eat feeling by the absorption of a humidity accompanying to the transfer of water and also adjusting a water content in the above part. SOLUTION: This processed food contains >=3wt.% component having >=5wt.% water content (B) (a glass transition water content at 25 deg.C) based on dry weight thereof compared with a characteristic water content (A) (an equilibrium water content in an atmosphere of a super saturated steam) at a part deteriorating in eat feeling thereof by the absorption of a humidity accompanying the transfer of water, of the processed food of which distribution of water changes during preserving and/or cooking thereof, and further contains <=50wt.% water content based on wet weight thereof in the eat feeling deteriorating part. As a material having >=5wt.% water content (B) than that of the water content (A), an agar, a carrageenan, etc., are preferable. For example, in the case where the above processed foods are already fried fries or Japanese fried foods, it is preferable to contain the agar, etc., into bread crumbs or a wheat flour constituting the coating which is the eat feeling deteriorating part.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、製品中に水分に差
のある複数の部分や水分勾配が存在するために、保管中
及び/または調理中に、水が水分含量の高い部分から低
い部分へ移動し、それにより物性が劣化する性質を改善
した食品に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a portion where water has a high water content and a portion having a low water content during storage and / or cooking due to the presence of a plurality of portions having different water contents and a water gradient in a product. The present invention relates to a food product having improved properties in which the physical properties are deteriorated by moving to.

【0002】[0002]

【従来の技術】食品、特に加工食品においては食品の成
分間、素材間、領域間において含水率に差がある場合が
多いことが知られている。こうした食品として、各種油
ちょう済みフライ、てんぷら、ピザ、コーン付きアイス
クリーム、あんかけ堅焼そば等があるが、こうした食品
は保管或いは調理により、より水分の高い部分から低い
部分に蒸気或いは液体にて水分が移動が起こり、食品中
の水分分布が平衡化し、本来好ましいサクサクした食感
が失われる。この食感の劣化は商品価値を大幅に低下せ
しめるため、食品開発上の大きな問題となっていた。
2. Description of the Related Art It is known that in foods, particularly processed foods, there are many cases where there is a difference in the water content among the components of the food, the materials, and the regions. As such foods, there are various types of fried foods, tempura, pizza, ice cream with cones, ankake kenyaki soba, etc., but these foods are stored or cooked in a vapor or liquid form from a higher water content to a lower water content. The movement of water occurs, the water distribution in the food is balanced, and the originally desired crispy texture is lost. This deterioration of texture significantly reduces the commercial value, which has been a major problem in food development.

【0003】また、この様な食品は凍結、解凍行程を経
ることによっても、また電子レンジによる再加熱を行っ
ても、同様の食感劣化を起こすことが知られており、こ
うした品質劣化を防止することは重要な課題と考えられ
てきた。
It is known that such foods also suffer from the same texture deterioration even after undergoing a freezing and thawing process and reheating with a microwave oven, and such quality deterioration is prevented. It has been considered an important task to do.

【0004】この様な問題を克服するために含水率に差
のある部分間の境界となる領域に、可食性のタンパク
質、多糖類を主成分とする保水性被膜(例えば、特開平
4−8255号公報)、油脂性の撥水性被膜(例えば、
特開平5−103581号公報)、多層被膜(例えば、
特開平2−16937号公報)、さらには保水物質、起
泡剤及び乳化等を組み合わせた被膜(例えば、特開平7
−255402号公報)等を形成せしめることにより水
分の移動を抑える試みが多くなされてきた。しかしなが
らこれらの方法によっては、水の移動速度を若干抑制す
ることが出来るものの、水分の移動自体を抑えることは
出来ず、被膜形成を行うために行程が煩雑になる割に充
分な効果は得られていなかった。
In order to overcome such a problem, a water-retaining film containing edible proteins and polysaccharides as a main component is formed in a region serving as a boundary between parts having different water contents (for example, JP-A-4-8255). Gazette), an oily and water repellent coating (for example,
JP-A-5-103581), a multilayer coating (for example,
Japanese Unexamined Patent Publication (Kokai) No. Hei 2-16937), and further a coating film in which a water retention substance, a foaming agent, an emulsifying agent and the like are combined (for example, Japanese Unexamined Patent Publication No. Hei 7 (1994) 7)
-255402) has been made many attempts to suppress the movement of water. However, by these methods, although the moving speed of water can be slightly suppressed, the movement of water itself cannot be suppressed, and a sufficient effect can be obtained despite the complicated process for forming a film. Didn't.

【0005】また、含水率の低い部分(例えば、油ちょ
う済みフライにおけるパン粉)に、コンニャク粉(特開
昭62−74255号公報)、熱凝固性タンパク質(特
開平2−2313号公報)等の物質を加え吸湿軟化を抑
える試みもなされている。しかしながら、このうち前者
によっては充分な効果は得られず、後者によっては比較
的高い効果が期待されるものの、充分な効果を得るため
には50重量%を超える非常に高い比率でタンパク質を
含有せしめねばならず、本来の味、風味、食感に著しい
変化をきたし、実用化にはまだ問題があり、十分な解決
策となっていない。
In addition, konjak flour (Japanese Unexamined Patent Publication (Kokai) No. 62-74255), heat-coagulable protein (Japanese Unexamined Patent Publication (Kokai) No. 2-2313) and the like are added to a portion having a low water content (for example, bread crumbs in a deep-fried frying). Attempts have also been made to suppress moisture absorption and softening by adding substances. However, among these, the former cannot obtain a sufficient effect and the latter is expected to have a relatively high effect, but in order to obtain a sufficient effect, the protein should be contained in a very high ratio exceeding 50% by weight. It is necessary to make a significant change in the original taste, flavor, and texture, and there is still a problem in practical use, which is not a sufficient solution.

【0006】この様な状況の中、合成高分子の分野で長
年研究されてきた非晶性アモルファス物質のガラス転移
の理論を、食品、生体高分子に応用した研究が進み、例
えば澱粉、デキストリン等の非晶性の粉末の吸湿に伴う
軟化は、それら高分子に対する水の可塑剤としての効果
により、弾性的粘弾性体であるガラス状態から粘性的粘
弾性体であるラバー状態への状態変化であり、この変化
により様々な劣化反応が始まること等が明かとなってき
た(例えば、Slade,L.らの報文:CRC Crit.Rev.Food Sc
i.Nutr.,Vol.30,p.115、Karmas,R. らの報文:J.Agric.
Food Chem.,Vol.40,p.873 )。
Under such circumstances, research on applying the theory of glass transition of an amorphous amorphous substance, which has been researched for many years in the field of synthetic polymers, to foods and biopolymers has progressed. For example, starch, dextrin, etc. Due to the effect of water as a plasticizer on these polymers, the softening of amorphous powder of Amorphous due to moisture absorption changes from the elastic viscoelastic body in the glass state to the viscous viscoelastic body in the rubber state. Therefore, it has become clear that various deterioration reactions start due to this change (for example, a report by Slade, L. et al .: CRC Crit. Rev. Food Sc
Report by i.Nutr., Vol.30, p.115, Karmas, R. et al .: J. Agric.
Food Chem., Vol.40, p.873).

【0007】また、固体全体のガラス転移温度の上昇に
伴い上昇する同じ温度におけるガラス転移水分の上昇に
着目することにより、クッキーのサクサク感を一定の吸
湿処理後も維持できること等も報告されてきた(例え
ば、Slade,L.らの報文:J.Sci.Food Agric.,Vol.63,p.1
33)。これは、Couchman-Karasz 式(例えば、Kalichev
sky,M.T.らの報文:Carbohydr.Polym.,Vol.19,p.271 に
記載)にあるように多成分混合物のガラス転移点は、各
成分のガラス転移温度に構成比をかけたものの総和で決
まるとされており、ガラス転移点のより高い成分を、よ
り多く含有せしめることが固体全体のガラス転移点を上
げることになることに基づいたものである。しかしなが
ら、これは主成分である小麦粉よりガラス転移の高い物
質を添加するのではなく、副成分で小麦粉よりガラス転
移温度の低いシュークロス等を減らす方法であり、大き
な効果が期待できない上、応用できる製品範囲もせまい
ものであった。現在まで、小麦粉の最大構成成分である
澱粉関連物質より、ガラス転移温度が大幅に高い可食性
成分の報告は無いことから、ガラス転移温度の高い成分
のみの添加による問題の解決はむづかしい。
It has also been reported that the crispy sensation of cookies can be maintained even after a certain amount of moisture absorption treatment by paying attention to the increase in the glass transition water content at the same temperature as the glass transition temperature of the whole solid increases. (For example, Slade, L. et al .: J. Sci. Food Agric., Vol. 63, p. 1
33). This is the Couchman-Karasz formula (eg Kalichev
sky, MT et al .: Carbohydr.Polym., Vol.19, p.271)), the glass transition temperature of a multi-component mixture is the sum of the glass transition temperature of each component multiplied by the composition ratio. It is said that the inclusion of a larger amount of a component having a higher glass transition point raises the glass transition point of the solid as a whole. However, this is not a method of adding a substance having a higher glass transition than wheat flour which is the main component, but a method of reducing shoe cloth having a glass transition temperature lower than that of wheat flour by a sub ingredient, and a large effect cannot be expected, and it can be applied. The product range was also narrow. To date, there is no report of an edible component having a glass transition temperature significantly higher than that of the starch-related substance, which is the largest constituent of wheat flour, so it is difficult to solve the problem by adding only the component having a high glass transition temperature.

【0008】[0008]

【発明が解決しようとする課題】本発明は、保管中及び
/または調理中に、水が水分含量の高い部分から低い部
分へ移動することによって起こる加工食品の食感の劣化
抑制を目的とするものであり、本来の味、風味、食感等
に影響がなく、水分移動に伴う食感劣化が抑制された加
工食品を提供することを目的とするものである。
The object of the present invention is to suppress the deterioration of the texture of processed foods caused by the movement of water from a high water content portion to a low water content portion during storage and / or cooking. It is an object of the present invention to provide a processed food that does not affect the original taste, flavor, texture, and the like, and that suppresses the texture deterioration due to water movement.

【0009】[0009]

【課題を解決するための手段】本発明者らは、上記課題
を解決すべく鋭意検討を重ねた結果、たとえガラス転移
温度が高い成分であって、ある一定水蒸気圧条件での平
衡水分が低い成分でなければ、加工食品中の水分移動に
伴い食感が劣化する部分に含有せしめた場合に、吸湿に
起因する悪影響を防止する充分な効果が得られないこと
を見いだし、さらに室温(25℃)における固有の水分
値A(過飽和水蒸気雰囲気における平衡水分)より水分
値B(ガラス転移水分)が高い成分ほど水分移動に伴う
食感劣化を防止したい部分に含有せしめた場合に吸湿に
よる軟化等の劣化を防ぐ効果が高いことを見いだした。
As a result of intensive studies to solve the above problems, the present inventors have found that even a component having a high glass transition temperature has a low equilibrium water content under a certain constant steam pressure condition. It was found that if it is not a component, when it is contained in a portion of the processed food where the texture deteriorates due to the movement of water, a sufficient effect of preventing the adverse effect caused by moisture absorption cannot be obtained, and further, at room temperature (25 ° C). )) Having a higher water content value B (glass transition water content) than the specific water content value A (equilibrium water content in a supersaturated steam atmosphere), the softening due to moisture absorption, etc. We found that the effect of preventing deterioration is high.

【0010】そこで、水分値B−水分値Aが高い成分を
数百種類の多糖類、タンパク質類の中からスクリーニン
グした結果、各種寒天、数種のカラギーナン、筋肉タン
パク質、血液アルブミン、血液グロブリン、数種の架橋
澱粉、ジアルデヒドスターチ、ツェイン、エラスチン、
カードラン、数種のトランスグルタミナーゼ処理タンパ
ク質等が高い値を示すことを見いだした。さらに、実際
に水分移動に伴う食感劣化を防止したい部分に乾重量当
たり3重量%以上これらの成分を含有せしめたところ、
その水分が50重量%より少ない場合には上記課題が解
決できることを確認し、本発明を完成させるに至った。
Then, as a result of screening the components having high water content B-water content A from hundreds of kinds of polysaccharides and proteins, various agars, several kinds of carrageenan, muscle protein, blood albumin, blood globulin, number Seed cross-linked starch, dialdehyde starch, zein, elastin,
It was found that curdlan, several kinds of transglutaminase-treated proteins, etc. showed high values. Furthermore, when 3% by weight or more of these components are contained in the portion where it is desired to prevent the deterioration of the texture due to the movement of water, based on the dry weight,
It was confirmed that the above problem can be solved when the water content is less than 50% by weight, and the present invention has been completed.

【0011】本発明の第一は、保管中及び/または調理
中に水分分布が変化する加工食品において、水分移動に
伴う吸湿により食感劣化する部分に、固有の水分値A
(25℃、過飽和水蒸気雰囲気における平衡水分)より
水分値B(25℃におけるガラス転移水分)が5重量%
以上高い成分を乾重量当たり3重量%以上含み、さらに
その部分に湿重量当たり50重量%より少ない水分量を
含むことを特徴とする加工食品に存する。
The first aspect of the present invention is that, in a processed food whose moisture distribution changes during storage and / or cooking, the moisture value A peculiar to the portion where the texture is deteriorated by moisture absorption due to moisture movement.
Moisture value B (glass transition moisture at 25 ° C) is 5% by weight from (equilibrium moisture in supersaturated steam atmosphere at 25 ° C)
The processed food is characterized in that it contains 3% by weight or more of the above high component per dry weight and further contains less than 50% by weight of wet weight in the portion.

【0012】本発明の第二は、吸湿により食感劣化する
部分が通常小麦粉及び/又は澱粉を主成分としてなる本
発明の第一に記載の加工食品に存する。本発明の第三
は、加工食品が各種油ちょう済みフライ類、てんぷら、
ピザ、コーン付きアイスクリーム、あんかけ堅焼そばの
うちから選ばれる1種である前記本発明の第一又は第二
に記載の加工食品に存する。本発明の第四は、加工食品
が冷凍食品である本発明の第一〜第二又は第三に記載の
加工食品に存する。
The second aspect of the present invention resides in the processed food according to the first aspect of the present invention, in which the portion of which texture is deteriorated by moisture absorption is usually wheat flour and / or starch. The third aspect of the present invention is that processed foods include various types of fried frying, tempura,
The processed food according to the first or second aspect of the present invention is one selected from pizza, ice cream with corn, and ankake kakiyaki soba. A fourth aspect of the present invention resides in the processed food according to the first to second or third aspects of the present invention, in which the processed food is a frozen food.

【0013】本発明の第五は、前記水分値Aより前記水
分値Bが5重量%以上高い成分が寒天、カラギーナン、
動物性筋肉タンパク質、血液アルブミン、血液グロブリ
ン、架橋澱粉、ツェイン、トランスグルタミナーゼ処理
タンパク質のうちから選ばれる1種類以上である前記本
発明の第一、第二、第三又は第四に記載の加工食品に存
する。
In a fifth aspect of the present invention, the component having a water content B higher than the water content A by 5% by weight or more is agar, carrageenan,
The processed food according to the first, second, third or fourth of the present invention, which is one or more kinds selected from animal muscle protein, blood albumin, blood globulin, cross-linked starch, zein, and transglutaminase-treated protein. Exist in.

【0014】[0014]

【発明の実施の形態】本発明において、水分移動に伴う
食感劣化を防止したい部分に添加する成分の固有の水分
値Aとは、25℃、過飽和水蒸気雰囲気における平衡水
分のことであり、25℃で過飽和水蒸気を1.6リット
ル/分で送り込んでいるデシケーター中に各成分の約1
0重量%溶液あるいは懸濁液の凍結乾燥後の粗粉砕物を
置き、20時間を超えた程度で重量が平衡に達したとこ
ろで取り出し、その重量における105℃、20時間乾
燥した前後の重量変化から求められる水分の組成比(重
量%)を求めたものである。
BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, the inherent water content value A of a component added to a portion where it is desired to prevent the texture deterioration due to water movement is the equilibrium water content in a supersaturated steam atmosphere at 25 ° C. Approximately 1 of each component was placed in a desiccator that was sending supersaturated steam at 1.6 liters / min.
Place the coarsely pulverized product of the 0 wt% solution or suspension after freeze-drying, take out when the weight reaches equilibrium for more than 20 hours, and take out the weight change before and after drying at 105 ° C for 20 hours. The required composition ratio (% by weight) of water is obtained.

【0015】また本発明において、水分移動に伴う食感
劣化を防止したい部分に添加する成分の固有の水分値B
とは、25℃におけるガラス転移水分のことであり、各
成分の前記凍結乾燥粗粉砕物を水蒸気を用いて種々の水
分値に吸湿、調製した後、各々のガラス転移温度を示差
走査熱量計(以下、DSC)にて測定した結果から、ガ
ラス転移温度の水分依存のグラフを作成し、その曲線か
ら求められる25℃における各成分のガラス状態からラ
バー状態に変わる水分値(重量%)である。尚、水分値
A、水分値Bを25℃の値に設定したのは、加工食品は
通常の料理と異なり、弁当等のように室温に近い品温で
の喫食が多いからであり、この状態で食感が軟化等の劣
化を起こしているかどうかの指標とするためである。
Further, in the present invention, the water content B peculiar to the component to be added to the portion where it is desired to prevent the texture deterioration due to water movement.
Is the glass transition water content at 25 ° C., and the freeze-dried coarsely pulverized product of each component was absorbed and adjusted to various water values using water vapor, and then each glass transition temperature was measured by a differential scanning calorimeter ( Hereinafter, a graph showing the dependence of the glass transition temperature on the water content is prepared from the results measured by DSC, and the water content (% by weight) at 25 ° C at which the glass state of each component changes from the rubber state to the rubber state is obtained. The reason why the moisture value A and the moisture value B are set to 25 ° C. is that processed foods are different from ordinary foods because they often eat at product temperatures close to room temperature such as lunch boxes. This is because it is used as an index of whether or not the texture has deteriorated such as softening.

【0016】本発明において好ましい成分は、その成分
固有の水分値Aより水分値Bが大きいものである。前記
加工食品中の水分移動に伴う食感劣化を防止したい部分
は、通常そのほとんどが小麦粉であるが、その主要構成
成分である小麦澱粉やその分解物であるデキストリン及
びグルテンは、その固有の水分値Bから水分値Aを引い
た値が−15重量%以上、1重量%以下の間にあって、
水分値差が小さいことから、添加成分の水分値差がこの
範囲に近ければ食感劣化防止効果は低い。それ故、水分
値差が水分重量%として5重量%以上の差がある成分が
好ましく、この差が大きいものであれば大きいものであ
るほどさらに好ましい。
In the present invention, the preferred component has a water content value B larger than the water content value A inherent to the component. The part of the processed food which is desired to prevent texture deterioration due to water movement is usually wheat flour, but the main constituents thereof are wheat starch and its decomposition products, dextrin and gluten, have a specific moisture content. If the value obtained by subtracting the water content A from the value B is between -15% by weight and 1% by weight,
Since the difference in water content is small, if the difference in water content between the added components is close to this range, the effect of preventing texture deterioration is low. Therefore, a component having a difference in water content of 5% by weight or more in terms of water content by weight is preferable, and the larger the difference, the more preferable.

【0017】具体的物質としては、水分値Bが水分値A
より5重量%以上高いものであれば特に限定されない
が、可食性成分であることが好ましく、各種寒天、数種
のカラギーナン、筋肉タンパク質、血液アルブミン、血
液グロブリン、数種の架橋澱粉、ジアルデヒドスター
チ、ツェイン、エラスチン、カードラン、数種のトラン
スグルタミナーゼ処理タンパク質等が好ましい。但し、
水溶性の低い成分では、他のアモルファス共存成分と混
練した場合、均一なマトリックス構造が作りにくい場合
も多く、他の成分のガラス転移点を引き上げる効果に欠
けるため、これらのうち水溶性である各種寒天、数種の
カラギーナン、筋肉タンパク質、血液アルブミン、血液
グロブリン、数種の架橋澱粉、数種のトランスグルタミ
ナーゼ処理タンパク質等が特に好ましい。また、これら
は各々単独で含有せしめても、他の成分と併せて含有せ
しめても良く、組み合わせも特に限定されるものではな
い。
As a concrete substance, the water content B is the water content A.
It is not particularly limited as long as it is 5% by weight or more, but is preferably an edible component, such as various types of agar, several kinds of carrageenan, muscle protein, blood albumin, blood globulin, several kinds of crosslinked starch, and dialdehyde starch. , Zein, elastin, curdlan, several transglutaminase-treated proteins and the like are preferable. However,
When a low water-soluble component is kneaded with other amorphous coexisting components, it is often difficult to form a uniform matrix structure, and the effect of raising the glass transition point of the other components is lacking. Agar, several kinds of carrageenan, muscle protein, blood albumin, blood globulin, several kinds of crosslinked starch, several kinds of transglutaminase-treated protein and the like are particularly preferable. Further, each of these may be contained alone or in combination with other components, and the combination is not particularly limited.

【0018】本発明において、水分移動に伴う食感劣化
を防止したい部分に添加する固有の水分値Aより水分値
Bが5重量%以上高い成分の含有比率は、少なすぎれば
効果が低いため、乾重量当たり3重量%以上含有せしめ
ることが好ましい。一方、含有比率が高すぎると、含有
せしめる成分によって加工食品本来の食感、風味、物性
に変化を起こす場合もあり、必要以上に含有させない方
が好ましい。従って最も好ましい含有比率は、含有せし
める成分の効果の他、食感劣化を防止しようとする加工
食品の部位の特性等により異なってくるが、当業者であ
れば容易に設定できる。
In the present invention, if the content ratio of the component having a water content value B which is 5% by weight or more higher than the specific water content value A added to the portion where the texture deterioration due to water movement is to be prevented, the effect is low. It is preferable to contain 3% by weight or more based on the dry weight. On the other hand, if the content ratio is too high, the original texture, flavor, and physical properties of the processed food may change depending on the components to be contained, so it is preferable that the content is not unnecessarily large. Therefore, the most preferable content ratio differs depending on the effect of the component to be contained and the characteristics of the portion of the processed food for which texture deterioration is to be prevented, but can be easily set by those skilled in the art.

【0019】本発明において水分移動に伴う食感劣化を
防止したい部分に含まれる水分は、湿重量として50重
量%以下である。50重量%を超えた場合、固有の水分
値Aより水分値Bが5重量%以上高い成分の添加効果は
はっきりしなくなるため、これ以下の水分であることが
好ましい。
In the present invention, the water content contained in the portion where it is desired to prevent the texture deterioration due to the water movement is 50% by weight or less as the wet weight. When it exceeds 50% by weight, the effect of adding a component having a moisture value B of 5% by weight or more higher than the inherent moisture value A becomes unclear, so that the moisture content is preferably less than this.

【0020】本発明における加工食品とは特に限定され
るものでなく、保管中及び/または調理中の水分分布変
化により、好ましいサクサク或いはパリパリとした食感
を失うことで品質がかわる加工食品に広く適用可能であ
り、各種油ちょう済みフライ類、てんぷら、ピザ、コー
ン付きアイスクリーム、あんかけ堅焼そばの何れにも利
用可能である。本発明における油ちょう済みフライ類も
特に限定されるものではなく、コロッケ、カツ等のパン
粉付きフライの他、鶏肉、豚肉及び牛肉等各種肉の唐揚
げ、磯部揚げ及び竜田揚げ、フライドポテト、フレンチ
フライ、揚げ餃子、揚げ焼売、揚げ春巻等の何れにも利
用可能である。本発明におけるてんぷらも特に限定され
るものではなく、野菜類、魚介類或いはそれらを2種類
以上混ぜ合わせたかき揚げ等何れにも利用可能である。
The processed food in the present invention is not particularly limited, and it is widely applied to processed foods of which quality is changed by losing a preferable crispy or crispy texture due to a change in water distribution during storage and / or cooking. It is applicable, and can be used for all kinds of deep-fried frying, tempura, pizza, ice cream with cone, and ankake kakiyaki soba. The fried foods according to the present invention are not particularly limited, and croquettes, fried bread crumbs such as cutlet, fried chicken, pork, beef, and other various meats, fried Isobe and fried Tatsuda, fried potatoes, French It can be used for fried foods, fried dumplings, fried fried rice, fried spring rolls, etc. The tempura used in the present invention is not particularly limited, and it can be used for vegetables, seafood, or fried kakiage prepared by mixing two or more of them.

【0021】本発明において、固有の水分値Aより水分
値Bが5重量%以上高い成分を添加し、水分移動に伴う
食感劣化を防止したい部分とは、前記加工食品の種類に
より異なるものであり、例えば各種油ちょう済みフライ
類、てんぷらであれば衣の部分であり、ピザであればク
ラストの部分であり、コーン付きアイスクリームであれ
ばコーンでありさらにあんかけ堅焼そばでは麺の部分で
ある。通常これらの部分は小麦粉を主成分としてなるた
め、小麦粉成分を固有の水分値Aより水分値Bが5重量
%以上高い成分に置き換える利用法が一般的であり好ま
しいが、本発明は小麦粉を置き換える利用法に限定した
ものではない。また、本発明における加工食品は前記水
分値差が大きい成分により水分移動に伴う食感劣化を防
止したい部分が被覆されたものも含む。
In the present invention, a portion where a component having a moisture content B higher than the specific moisture content A by 5% by weight or more is added to prevent texture deterioration due to moisture migration is different depending on the type of the processed food. Yes, for example, various fried frying, tempura is the batter part, pizza is the crust part, ice cream with corn is the corn, and Ankake Ken Yakisoba is the noodle part. is there. Usually, since these parts are mainly composed of wheat flour, it is common and preferable to replace the wheat flour component with a component having a moisture content B higher than the inherent moisture content A by 5% by weight or more, but the present invention replaces the flour. It is not limited to usage. In addition, the processed food in the present invention also includes a product in which a portion whose texture value is desired to be prevented from being deteriorated due to the movement of water is coated with the component having a large water content difference.

【0022】本発明において用いることのできる好まし
い成分である寒天は、固有の水分値Bが水分値Aより5
重量%以上であれば特に限定されるものではなく、主原
料の藻類の種類、抽出法、精製法、処理法の種類にかか
わらず、何れも利用可能である。寒天にはその原料、製
法により種々の特性を有するものが知られているが、本
発明における水分移動に伴う食感劣化を防止したい部分
への添加成分としての寒天は、一般に寒天のゼリー強度
が高い程、固有の水分値AとBの差が大きく、含有せし
めた場合の単位重量当たりの効果は高い傾向にある。ゼ
リー強度が高い寒天は一方で溶け難い、粘度が高い、ゲ
ル化する等、加工特性、ハンドリング性が悪い難点があ
る。そのため、加工特性、ハンドリング性を重視する場
合には、酸あるいは酵素により低分子に分解されたも
の、あるいは硫酸化等の化学修飾が施されたもの等、低
ゼリー強度の寒天が好ましい場合もある。
Agar, which is a preferred component that can be used in the present invention, has an inherent water value B of 5 or more than that of the water value A.
There is no particular limitation as long as it is at least wt%, and any of them can be used regardless of the type of algae as the main raw material, the extraction method, the purification method, and the treatment method. Agar is known to have various properties depending on its raw material and manufacturing method, but agar as an additive component to the part to prevent texture deterioration due to moisture movement in the present invention generally has a jelly strength of agar. The higher the difference, the larger the difference between the intrinsic moisture values A and B, and the higher the effect per unit weight when incorporated, the higher the tendency. On the other hand, agar, which has a high jelly strength, has problems that it is difficult to melt, has high viscosity, gels, and has poor processing characteristics and handleability. Therefore, when processing characteristics and handleability are important, agar having a low jelly strength may be preferable, such as one decomposed into a low molecule by an acid or an enzyme, or one chemically modified such as sulfation. .

【0023】例えば、寒天を含有せしめたフライ用のパ
ン粉を製造するためのドウを調製する場合、高ゼリー強
度の寒天では粘性が高く、すぐにゲル化が起こるため小
麦粉との混合が容易でない上、調製したドウが発酵によ
って十分に膨らまない場合がある。しかし低ゼリー強度
の寒天を用いれば、単位添加量当たりの効果は低くなる
ものの、良好な特性を備えたドウの調製が容易になる。
さらに寒天を含有せしめた衣を有するてんぷら、唐揚げ
等を調製する場合にも、高ゼリー強度の寒天では粘性が
高く、すぐにゲル化が起こるため小麦粉等他の成分との
混合が容易でないが、低ゼリー強度の寒天を用いれば、
単位添加量当たりの効果はやはり低くなるものの、良好
な特性を備えた衣の調製が容易になる。このように、寒
天の場合、含有せしめる加工食品の部分毎に好ましい寒
天の種類があると考えられるが、当業者であれば、それ
ぞれの対象食品に適する性質を有する寒天の種類を選定
することは容易である。
For example, when a dough for producing bread crumbs containing agar is prepared, agar with high jelly strength has a high viscosity and gelation occurs immediately, so that mixing with wheat flour is not easy. , The prepared dough may not swell due to fermentation. However, when agar having a low jelly strength is used, the effect per unit addition amount becomes low, but the dough having good characteristics can be easily prepared.
Furthermore, even when preparing tempura with agar-containing batter, fried chicken, etc., agar with high jelly strength has a high viscosity and gelation occurs quickly, so mixing with other ingredients such as flour is not easy. , If you use low jelly strength agar,
Although the effect per unit amount of addition is still low, it is easy to prepare clothes with good properties. As described above, in the case of agar, it is considered that there is a preferable type of agar for each part of the processed food to be contained, but those skilled in the art can select the type of agar having the property suitable for each target food. It's easy.

【0024】本発明に用いることのできるカラギーナン
は、固有の水分値Bが水分値Aより5重量%以上であれ
ば特に限定されるものではなく、主原料の藻類の種類、
抽出法、精製法、処理法の種類、塩の種類にかかわら
ず、何れも利用可能である。
The carrageenan which can be used in the present invention is not particularly limited as long as the inherent water content B is 5% by weight or more than the water content A, the kind of the main raw material algae,
Any of these can be used regardless of the type of extraction method, purification method, treatment method, or salt.

【0025】本発明に用いることのできる動物性筋肉タ
ンパク質は、固有の水分値Bが水分値Aより5重量%以
上であれば特に限定されるものではなく、甲殻類等の無
脊椎動物から、魚類、ほ乳類等の脊椎動物まで何れの動
物の筋肉タンパク質も含まれる。また、この範囲内にあ
れば、使用に際しての筋肉タンパク質の調製方法、精製
度合いは水分移動に伴う食感劣化を防止する対象となる
部分への添加効果の有無に影響しない。
The animal muscle protein that can be used in the present invention is not particularly limited as long as the inherent water content B is 5% by weight or more than the water content A. From invertebrates such as crustaceans, Muscle proteins of any animal up to vertebrates such as fish and mammals are included. Within this range, the muscle protein preparation method at the time of use and the degree of purification do not affect whether or not the effect is added to the target portion for preventing the texture deterioration due to water movement.

【0026】本発明に用いることのできる血液グロブリ
ン、アルブミンは、固有の水分値Bが水分値Aより5重
量%以上であれば特に限定されるものではなく、甲殻類
等の無脊椎動物から、魚類、ほ乳類等の脊椎動物まで何
れの動物のものも含まれる。また、この範囲内にあれ
ば、使用に際しての血液グロブリン、アルブミン各々の
調製方法、精製度合いは水分移動に伴う食感劣化を防止
する対象となる部分への添加効果の有無に影響しない。
The blood globulin and albumin which can be used in the present invention are not particularly limited as long as the intrinsic water content B is 5% by weight or more than the water content A, and from invertebrates such as crustaceans, Any animal including vertebrates such as fish and mammals is also included. Within this range, the method of preparing each of blood globulin and albumin at the time of use and the degree of purification do not affect the effect of addition to the target portion for preventing texture deterioration due to water movement.

【0027】本発明に用いることのできる架橋澱粉は、
固有の水分値Bが水分値Aより5重量%以上であれば特
に限定されるものではなく、何れの澱粉原料のものも含
まれ、またこの水分値差の向上のための架橋処理方法も
限定されない。
The crosslinked starch that can be used in the present invention is
The specific moisture value B is not particularly limited as long as it is 5% by weight or more than the moisture value A, any starch raw material is included, and the crosslinking treatment method for improving this moisture value difference is also limited. Not done.

【0028】本発明に用いることのできるツェインは、
固有の水分値Bが水分値Aより5重量%以上であれば特
に限定されるものではなく、主原料のとうもろこしの種
類、抽出法、精製法、処理法の種類にかかわらず、何れ
も利用可能である。
Zein that can be used in the present invention is
The specific moisture value B is not particularly limited as long as it is 5% by weight or more than the moisture value A, and any one can be used regardless of the type of corn as the main raw material, the extraction method, the purification method, and the treatment method. Is.

【0029】本発明に用いることのできるトランスグル
タミナーゼ処理タンパク質は、固有の水分値Bが水分値
Aより5重量%以上であれば特に限定されるものではな
い。トランスグルタミナーゼの起源、調製方法及び精製
度、トランスグルタミナーゼ処理するタンパク質の種
類、タンパク質をトランスグルタミナーゼ処理する場合
の酵素濃度、タンパク質の状態、反応時間、共存物の種
類等の処理条件も特に限定されるものではない。しかし
ながらトランスグルタミナーゼによるタンパク質の架橋
反応が進行し過ぎると、タンパク質は不溶化し、小麦粉
等他の成分との混合が容易でなくなる場合もある。この
ように、本発明における水分移動に伴い食感劣化する部
分に含有せしめるトランスグルタミナーゼ処理タンパク
質において、加工特性、ハンドリング性を重視する場合
には、トランスグルタミナーゼの種類、被処理タンパク
質の種類に毎に好ましい処理条件があると考えられる
が、当業者であれば、それぞれの対象食品に適する処理
条件を選定することは容易である。
The transglutaminase-treated protein that can be used in the present invention is not particularly limited as long as the intrinsic water content B is 5% by weight or more than the water content A. The processing conditions such as the origin of transglutaminase, the preparation method and the degree of purification, the type of protein to be treated with transglutaminase, the enzyme concentration when the protein is treated with transglutaminase, the state of the protein, the reaction time, the type of coexisting substances, etc. are also particularly limited. Not a thing. However, if the protein cross-linking reaction by transglutaminase progresses too much, the protein becomes insoluble and mixing with other components such as wheat flour may not be easy. As described above, in the transglutaminase-treated protein to be contained in the portion where the texture is deteriorated with the movement of water in the present invention, when the processing characteristics and the handling property are emphasized, the type of transglutaminase and the type of the treated protein are different. Although it is considered that there are preferable processing conditions, those skilled in the art can easily select the processing conditions suitable for each target food.

【0030】さらに、トランスグルタミナーゼ未処理で
前記水分値差が5重量%未満のタンパク質でもトランス
グルタミナーゼ処理後に前記水分値差が5重量%を超え
るものであれば利用できる。また、加工特性、ハンドリ
ング性を重視する場合には、小麦粉等他の成分と混合
中、混合後或いは対象食品の調製後にトランスグルタミ
ナーゼが作用するようにせしめる方法も利用可能であ
る。尚、トランスグルタミナーゼについては特公平1−
50382号、特開昭64−27471号参照のこと。
Furthermore, even proteins that have not been treated with transglutaminase and have a water content difference of less than 5% by weight can be used if the water content difference after transglutaminase treatment is more than 5% by weight. In addition, when importance is attached to processing characteristics and handleability, a method in which transglutaminase is allowed to act during or after mixing with other components such as wheat flour or after preparation of the target food can also be used. Regarding transglutaminase, Japanese Patent Publication 1-
See 50382 and JP-A No. 64-27471.

【0031】[0031]

【実施例】以下に、本発明を実施例に基づいて説明する
が、本発明はこれらにより限定されるものではない。
EXAMPLES The present invention will be described below based on examples, but the present invention is not limited thereto.

【0032】実施例1 小麦澱粉の平衡水分(水分値A)の測定:前記水分値A
の測定方法に従い、25℃で過飽和水蒸気を1.6リッ
トル/分で送り込んでいるデシケーター中に、予め糊化
した後、凍結乾燥した小麦澱粉の粗粉砕物を置いた場合
の、澱粉の水分含量増加の経時変化を測定した。尚、小
麦澱粉は、その結果を図1に示したが、約20時間で小
麦澱粉は平衡水分、すなわち19.8重量%に達してい
ることがわかる。小麦澱粉固有の水分値Aは19.8重
量%であった。
Example 1 Measurement of equilibrium water content (water content A) of wheat starch: Water content A described above
According to the measuring method of 1., the moisture content of the starch in the case where the coarsely ground wheat starch that has been gelatinized in advance and then freeze-dried is placed in a desiccator in which supersaturated steam is fed at 1.6 liter / min at 25 ° C. The time course of the increase was measured. The results of wheat starch are shown in FIG. 1, and it can be seen that the equilibrium water content of wheat starch, that is, 19.8 wt% was reached in about 20 hours. The moisture value A peculiar to wheat starch was 19.8% by weight.

【0033】実施例2 小麦澱粉のガラス転移水分(水分値B)測定:前記水分
値Bの測定方法に従い、予め糊化した後、凍結乾燥した
小麦澱粉を種々の水分値に吸湿せしめた試料を、銀製容
器に密封した後、各々のガラス転移温度をDSC(セイ
コー電子工業(株)製品、以下同様)にて測定した結果
を図2に示す。図から、水分上昇に従い小麦澱粉のガラ
ス転移温度は低下し、水が小麦澱粉の可塑剤として働い
ていることが分かる。また、その各測定点を結ぶ図中の
曲線から、25℃における小麦澱粉のガラス状態からラ
バー状態に変わる水分値は20.1重量%であると推定
される。従って、小麦澱粉固有の水分値Bは20.1重
量%であった。
Example 2 Measurement of glass transition moisture (moisture value B) of wheat starch: According to the measuring method of moisture value B described above, a sample obtained by preliminarily gelatinizing and freeze-drying wheat starch to various moisture values was used. After sealing in a silver container, each glass transition temperature was measured by DSC (manufactured by Seiko Denshi Kogyo KK, the same applies hereinafter). The results are shown in FIG. From the figure, it can be seen that the glass transition temperature of wheat starch decreases as the water content increases, and that water acts as a plasticizer for wheat starch. Further, from the curve in the figure connecting the respective measurement points, it is estimated that the moisture value at 25 ° C at which the glass state of the wheat starch changes to the rubber state is 20.1% by weight. Therefore, the moisture value B peculiar to wheat starch was 20.1% by weight.

【0034】以上、実施例1、2の結果から小麦澱粉の
水分値B−水分値Aは0.3重量%であることがわか
り、本発明にて好ましいと規定している5重量%には満
たない成分であることがわかる。
As described above, the results of Examples 1 and 2 show that the moisture value B-moisture value A of wheat starch is 0.3% by weight. It can be seen that the ingredients do not meet the requirements.

【0035】実施例3 各種多糖類、タンパク質類の固有の水分値A、B測定結
果:実施例1、2と同様の方法にて、数百種類の多糖
類、タンパク質類の固有の水分値A、水分値Bを測定し
た。尚、固有の水分値Aに関しては、測定場所の湿度、
飽和水蒸気の製造機器及びデシケーターの形状により数
重量%程度本発明における測定値と異なる場合が考えら
れるが、その場合には各測定場所において、測定を行う
成分の固有の水分値Aと小麦澱粉の固有の水分値Aとの
差を求め、本発明における小麦澱粉の固有の水分値A測
定結果である19.8重量%にその差を足し引きすれ
ば、本発明でいう各成分固有の水分値Aとはかい離しな
い値が得られる。
Example 3 Specific moisture values A and B of various polysaccharides and proteins Measurement results: In the same manner as in Examples 1 and 2, several hundreds of types of polysaccharides and proteins have specific moisture values A The water content B was measured. Regarding the specific moisture value A, the humidity at the measurement location,
Depending on the shape of the saturated steam producing equipment and the desiccator, it may be different from the measured value in the present invention by about several% by weight. In that case, the water content A of the component to be measured and the wheat starch If the difference from the specific moisture value A is obtained and the difference is added to the 19.8 wt% which is the measurement result of the specific moisture value A of wheat starch in the present invention, the moisture value specific to each component in the present invention is calculated. A value that is not separated from A is obtained.

【0036】測定を行った成分のうち、代表的な物質の
測定結果を表1に示した。表から分かるように、各種寒
天、数種のカラギーナン、筋肉タンパク質、血清アルブ
ミン、血清グロブリン、数種の架橋澱粉、ジアルデヒド
スターチ、ツェイン、エラスチン、カードラン、トラン
スグルタミナーゼ処理カゼイン等が水分値B−水分値A
が高い値を示した。これらに比べ、加工食品において水
分移行に伴う食感劣化が起こる部分の主構成分としてよ
く用いられる実施例1、2にて測定した小麦澱粉及びそ
の分解物であるデキストリンの水分値B−水分値Aは低
い値となっていた。また、架橋澱粉、カラギーナンには
低い値のものもあり、カゼインもトランスグルタミナー
ゼ処理(反応条件:80U/g ・ カゼイン、pH=7.5、40℃)
を施こす前は低値であった。また、大量にパン粉に混ぜ
た場合、吸湿に伴う軟化を抑える効果があるという報告
(特開平2−2313号公報)がある熱凝固性タンパク
質で、中でも最も好ましいとされているグルテンの水分
値B−水分値Aは−2.8重量%と低い値であり、充分
な効果は得られないと考えられる。
Table 1 shows the measurement results of representative substances among the measured components. As can be seen from the table, various agars, several kinds of carrageenan, muscle protein, serum albumin, serum globulin, several kinds of cross-linked starch, dialdehyde starch, zein, elastin, curdlan, transglutaminase-treated casein, etc. Moisture value A
Showed a high value. In comparison with these, the moisture value B-moisture value of wheat starch and dextrin, which is a degradation product thereof, measured in Examples 1 and 2, which is often used as a main constituent of a portion where texture deterioration occurs due to moisture migration in processed foods. A was a low value. In addition, cross-linked starch and carrageenan have low values, and casein is also treated with transglutaminase (reaction conditions: 80U / g casein, pH = 7.5, 40 ° C).
The value was low before the treatment. In addition, there is a report (JP-A-2-2313) that when mixed in a large amount with bread crumbs, the effect of suppressing softening due to moisture absorption is reported, and among them, the water content B of gluten which is considered to be the most preferable is B. -The water content A is a low value of -2.8% by weight, and it is considered that a sufficient effect cannot be obtained.

【0037】[0037]

【表1】 [Table 1]

【0038】実施例4 油ちょう済みパン粉衣フライでの評価:実施例3のなか
で固有の水分値B−水分値Aが高いと認められた物質を
加工食品中の水分移動に伴い食感劣化する部分に含有せ
しめた場合、実際に吸湿に伴う劣化を抑えることができ
るのかを評価するため、固有の水分値B−水分値Aが高
かった寒天を含有せしめたパン粉を調製し、このパン粉
を衣とする油ちょう済みフライの吸湿に伴う食感劣化が
抑制されているかを評価、検討した。
Example 4 Evaluation in a pan-fried breaded fried with oil sauce: A substance which was found to have a high intrinsic moisture content B-moisture content A in Example 3 was deteriorated in texture with the migration of moisture in the processed food. In order to evaluate whether deterioration due to moisture absorption can be suppressed when it is contained in the portion to be prepared, a bread crumb containing impregnated agar with a high specific moisture value B-moisture value A is prepared, and this bread crumb is It was evaluated and examined whether the deterioration of the texture due to moisture absorption of the oil-fried fry used as clothes was suppressed.

【0039】予め加熱溶解せしめた低ゼリー強度の寒天
(伊那食品工業(株)製品、ウルトラ寒天AX−30)
を、ゲル化しない程度に熱い状態のまま乾重量当たり1
0重量%となるよう小麦薄力粉、卵、食塩、砂糖、牛
乳、ベーキングパウダーと共に混練した後、蒸し器中で
膨化させた。これを急速に凍結した後、乾燥、粉砕する
ことにより寒天入りパン粉を調製した。また、寒天を添
加しない対照品も寒天添加重量部を小麦薄力粉に置き換
え、同様に調製した。
Agar of low jelly strength that has been melted in advance by heating (Ina Food Industry Co., Ltd. product, Ultra Agar AX-30)
1 per dry weight while still hot enough not to gel
The mixture was kneaded with wheat flour, egg, salt, sugar, milk, and baking powder so as to be 0% by weight, and then puffed in a steamer. This was rapidly frozen, then dried and pulverized to prepare breadcrumbs containing agar. In addition, a control product to which agar was not added was also prepared in the same manner by replacing the weight part added with agar with wheat flour.

【0040】ゆでた後に皮をむき、つぶしておいたじゃ
がいも100重量部に豚挽き肉25重量部、たまねぎ2
5重量部を混ぜ、さらに少量の塩、胡椒を添加し、成形
することにより中具を調製した。これに打ち粉(組成:
小麦粉90重量%及び油脂10重量%)を施し、バッタ
ー液(組成:小麦粉50重量%、粉末卵白5重量%、油
脂5重量%及び水40重量%)を付けたものに前記の2
種の調製パン粉を付けた後、170℃で4分程度油ちょ
うすることにより、2種類の油ちょう済みコロッケを得
た。これらを油ちょう後すぐに急速に冷凍した後、−2
0℃で冷凍保管し、冷凍保管に伴う食感劣化の経時変化
を評価、比較した。
100 parts by weight of potatoes that have been peeled and crushed after boiling, 25 parts by weight of ground pork, 2 onions
5 parts by weight were mixed, a small amount of salt and pepper were further added, and the mixture was molded to prepare a filling. Dust powder (composition:
Wheat flour 90% by weight and fats and oils 10% by weight) and batter solution (composition: wheat flour 50% by weight, powdered egg white 5% by weight, fats and oils 5% by weight and water 40% by weight) are added to the above 2
Preparation of seeds After adding bread crumbs, oil-cooking was performed at 170 ° C for about 4 minutes to obtain two kinds of fried croquettes. After freezing them immediately after frying, -2
The sample was frozen and stored at 0 ° C., and changes over time in texture deterioration due to frozen storage were evaluated and compared.

【0041】評価は一定期間冷凍保管した油ちょう済み
コロッケを電子レンジ(家庭用、500W)で2分間程
度解凍・調理し、パン粉部分の食感(クリスピー感)を
評価パネル数20名により5点満点の5段階で官能評価
することにより行った。尚、クリスピー感を感じるギリ
ギリの食感を3点とするよう予めパネルには伝えた。結
果を図3に示す。
Evaluation was performed by thawing and cooking the oiled croquette frozen for a certain period of time in a microwave oven (household, 500W) for about 2 minutes, and the texture of the bread crumbs (crispy) was evaluated by 20 persons on 5 panels. It was performed by sensory evaluation on a scale of 5 points. It should be noted that the panel was informed in advance that the crispy texture should be 3 points. The results are shown in FIG.

【0042】図より、両コロッケともそのパン粉のクリ
スピー感は、保管期間の長さ、即ち水分含量の上昇に伴
い減少しているものの、パン粉に寒天を添加したものの
方が無添加のものより常に高いクリスピー感を示してい
た。また、図よりクリスピー感を感じる限界である3点
を維持する期間、即ち商品価値を有している期間は、無
添加のパン粉を付けたコロッケでは30日程度であるの
に比べ、寒天添加パン粉を付けたコロッケでは75日と
2.5倍に延長されていた。尚、32日保存後のパン粉
の水分含量を測定した所、無添加品は13.5重量%、
寒天添加品は13.8重量%と両者に大差は無かった。
従って、固有の水分値BとAとの差が5重量%を超える
成分を含有せしめることにより、吸湿に伴う劣化が抑制
でき、商品価値を有する期間の延長が図れることを確認
できた。
From the figure, the crispy sensation of the bread crumbs of both croquettes decreased with the length of the storage period, that is, with an increase in the water content. It had a high crispiness. Also, from the figure, the period of maintaining the 3 points, which is the limit to feel crispy, that is, the period of having commercial value, is about 30 days for croquette with non-added breadcrumbs, compared to agar-added breadcrumbs. In the croquette with a mark, it was extended to 2.5 days by 75 days. The moisture content of the bread crumbs after storage for 32 days was measured to find that the additive-free product was 13.5% by weight,
The agar-added product was 13.8% by weight, which was not much different.
Therefore, it was confirmed that by incorporating a component in which the difference between the specific water content values B and A exceeds 5% by weight, deterioration due to moisture absorption can be suppressed and the period of commercial value can be extended.

【0043】実施例5 じゃがいものてんぷらでの評価:実施例4と同様に固有
の水分値B−水分値Aが高かった寒天を含有せしめた衣
を有する油ちょう済みのじゃがいものてんぷらにおい
て、その衣の吸湿に伴う食感劣化が抑制されているかを
評価、検討した。
Example 5 Evaluation with Tempura of Potato: Similar to Example 4, the boiled potato tempura having a garment containing agar having a high inherent water content B-high water content A was used. It was evaluated and examined whether the texture deterioration due to moisture absorption was suppressed.

【0044】予め加熱溶解せしめた20重量部の低ゼリ
ー強度の寒天(伊那食品工業(株)製品、ウルトラ寒天
AX−30)を、ゲル化しない程度に熱い状態に維持し
たまま、80重量部の小麦薄力粉と180重量部の水と
共に混練し、調製した衣液を、予め皮をむき、スライス
後ゆでておいたじゃがいもに付けた。これを170℃の
油で3分程度油ちょうし、寒天添加衣を有するじゃがい
ものてんぷらを得た。また、寒天無添加品は、寒天添加
品の寒天添加重量部を小麦薄力粉に置き換え、水の添加
量を150重量部にした以外は寒天添加品と同様の方法
で調製した。これらを油ちょう後すぐに急速に冷凍した
後、−20℃で冷凍保管し、冷凍保管に伴う食感劣化の
経時変化を評価、比較した。
80 parts by weight of 20 parts by weight of agar having a low jelly strength (Ultra Food Agar AX-30 manufactured by Ina Food Industry Co., Ltd.), which had been heated and dissolved in advance, was maintained in a hot state not to gel. Kneading was performed with wheat flour and 180 parts by weight of water, and the prepared coating liquid was peeled in advance, sliced and then applied to boiled potatoes. This was fried with oil at 170 ° C. for about 3 minutes to obtain a tempura of tempura having an agar-added batter. The agar-free product was prepared in the same manner as the agar-added product, except that the agar-added part by weight of the agar-added product was replaced with wheat flour and the amount of water added was 150 parts by weight. These were rapidly frozen immediately after frying, and then frozen and stored at −20 ° C., and changes with time in texture deterioration due to frozen storage were evaluated and compared.

【0045】評価は一定期間冷凍保管したじゃがいもの
てんぷらを電子レンジ(家庭用、500W)で1分間程
度解凍・調理し、衣の部分の食感(クリスピー感)を評
価パネル数20名により5点満点の5段階で官能評価す
ることにより行った。尚、クリスピー感を感じるギリギ
リの食感を3点とするよう予めパネルには伝えた。結果
を図4に示す。
Evaluation was performed by thawing and cooking potato tempura that had been frozen and stored for a certain period of time in a microwave oven (household, 500 W) for about 1 minute, and the texture of the clothes (crispy feeling) was evaluated by 20 persons on 5 evaluation panels. It was performed by sensory evaluation on a scale of 5 points. It should be noted that the panel was informed in advance that the crispy texture should be 3 points. FIG. 4 shows the results.

【0046】図より、両てんぷらともその衣のクリスピ
ー感は、保管期間の長さ、即ち水分含量の上昇に伴い減
少しているものの、寒天添加品の方が無添加品より常に
高いクリスピー感を示していた。また、図よりクリスピ
ー感を感じる限界である3点を維持する期間、即ち商品
価値を有している期間は、無添加の衣は1日にも満たな
いのに比べ、寒天添加の衣は90日と大幅に延長されて
いた。尚、16日保存後のてんぷら衣の水分含量を測定
した所、無添加品は21.1重量%、寒天添加品は2
0.7重量%と大差は無かった。従って、パン粉衣から
なる油ちょう済みフライ同様、固有の水分値BとAとの
差が5重量%を超える成分を含有せしめることにより、
吸湿に伴う劣化が抑制でき、商品価値を有する期間の大
幅な延長が図れることを確認できた。
As can be seen from the figure, the crispy sensation of the clothes of both tempuras decreased with the length of the storage period, that is, as the water content increased, but the agar-added product always had a higher crispy sensation than the non-added product. Was showing. Also, from the figure, during the period of maintaining the 3 points, which is the limit of crispy feeling, that is, during the period when the product has a commercial value, the agar-added batter is 90 It was significantly extended from the day. The water content of the tempura batter after storage for 16 days was measured to be 21.1% by weight for the additive-free product and 2 for the agar-added product.
There was no great difference with 0.7% by weight. Therefore, as with the oiled fry made of bread crumbs, by incorporating a component in which the difference between the intrinsic moisture values B and A exceeds 5% by weight,
It was confirmed that deterioration due to moisture absorption can be suppressed, and the period of commercial value can be significantly extended.

【0047】[0047]

【発明の効果】以上、詳述したように、本発明によれ
ば、加工食品において保管中及び/または調理中に、水
が水分含量の高い部分から低い部分へ移動することによ
って食感劣化が起こる部分に対して、前記した固有の水
分値Aより水分値Bが5重量%以上高い成分を添加する
ことにより、本来の味、風味、食感等に影響がなく、水
分移動に伴う食感劣化が抑制された加工食品を提供する
ことを可能としたものである。
As described above in detail, according to the present invention, the deterioration of the texture is caused by the movement of water from a portion having a high water content to a portion having a low water content during storage and / or cooking in a processed food. By adding a component whose water content value B is 5% by weight or more higher than the inherent water content value A to the portion where it occurs, the original taste, flavor, texture, etc. are not affected and the texture associated with the movement of water content is not affected. It is possible to provide a processed food with suppressed deterioration.

【図面の簡単な説明】[Brief description of drawings]

【図1】小麦澱粉の水分値Aの測定結果を示す図。FIG. 1 is a diagram showing the measurement results of moisture value A of wheat starch.

【図2】小麦澱粉の水分値Bの測定結果を示す図。FIG. 2 is a diagram showing the measurement results of moisture value B of wheat starch.

【図3】パン粉組成の異なる各種コロッケの保管期間に
伴う食感変化を示す図。
FIG. 3 is a view showing a change in texture of various croquettes having different bread crumb compositions with storage period.

【図4】衣組成の異なる各種じゃがいもてんぷらの保管
期間に伴う食感変化を示す図。
FIG. 4 is a diagram showing a change in texture with the storage period of various types of potato tempura having different clothing compositions.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 A23L 1/176 A23L 1/176 1/48 1/48 (72)発明者 本木 正雄 神奈川県川崎市川崎区鈴木町1番1号 味 の素株式会社食品総合研究所内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Internal reference number FI Technical display location A23L 1/176 A23L 1/176 1/48 1/48 (72) Inventor Masao Motoki Kawasaki, Kanagawa Prefecture 1-1, Suzuki-cho, Kawasaki-ku, Ichi Ajinomoto Co., Inc. Food Research Institute

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 保管中及び/または調理中に水分分布が
変化する加工食品において、水分移動に伴う吸湿により
食感劣化する部分に、固有の水分値A(25℃、過飽和
水蒸気雰囲気における平衡水分)より水分値B(25℃
におけるガラス転移水分)が5重量%以上高い成分を乾
重量当たり3重量%以上含み、さらに前記吸湿により食
感劣化する部分に湿重量当たり50重量%より少ない水
分量を含むことを特徴とする加工食品。
1. In a processed food having a moisture distribution that changes during storage and / or cooking, a unique moisture value A (25 ° C., equilibrium moisture content in a supersaturated steam atmosphere) is present in a portion where the texture deteriorates due to moisture absorption due to moisture movement. ) From water content B (25 ℃
A glass transition water content of 5% by weight or more is contained in an amount of 3% by weight or more on a dry weight basis, and the amount of water content is less than 50% by weight on a wet weight basis in a portion where the texture is deteriorated by moisture absorption. Food.
【請求項2】 吸湿により食感劣化する部分が通常小麦
粉及び/又は澱粉を主成分としてなる請求項1記載の加
工食品。
2. The processed food according to claim 1, wherein the portion whose texture is deteriorated by moisture absorption usually contains wheat flour and / or starch as a main component.
【請求項3】 加工食品が各種油ちょう済みフライ類、
てんぷら、ピザ、コーン付きアイスクリーム、あんかけ
堅焼そばのうちから選ばれる1種である請求項1又は2
記載の加工食品。
3. The processed food is various types of fried frying,
The one selected from tempura, pizza, ice cream with corn, and ankake ken yakisoba.
Processed food as described.
【請求項4】 加工食品が冷凍食品である請求項1、2
又は3記載の加工食品。
4. The processed food is a frozen food as claimed in claim 1.
Or the processed food according to 3.
【請求項5】 前記水分値Aより前記水分値Bが5重量
%以上高い成分が寒天、カラギーナン、動物性筋肉タン
パク質、血液アルブミン、血液グロブリン、架橋澱粉、
ツェイン、トランスグルタミナーゼ処理タンパク質のう
ちから選ばれる1種類以上である請求項1、2、3又は
4記載の加工食品。
5. A component in which the water content B is 5% by weight or more higher than the water content A is agar, carrageenan, animal muscle protein, blood albumin, blood globulin, cross-linked starch,
The processed food according to claim 1, which is one or more kinds selected from zein and transglutaminase-treated proteins.
JP8142324A 1996-05-14 1996-05-14 Processed food Pending JPH09299041A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8142324A JPH09299041A (en) 1996-05-14 1996-05-14 Processed food

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8142324A JPH09299041A (en) 1996-05-14 1996-05-14 Processed food

Publications (1)

Publication Number Publication Date
JPH09299041A true JPH09299041A (en) 1997-11-25

Family

ID=15312706

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8142324A Pending JPH09299041A (en) 1996-05-14 1996-05-14 Processed food

Country Status (1)

Country Link
JP (1) JPH09299041A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009219489A (en) * 2008-02-29 2009-10-01 Kraft Foods Global Brands Llc Snappy filled and baked confectionery having high water content
JP2011523855A (en) * 2008-06-13 2011-08-25 ネステク ソシエテ アノニム Food
JP2015195758A (en) * 2014-04-01 2015-11-09 日清製粉株式会社 Manufacturing method of spring roll
WO2021132391A1 (en) * 2019-12-25 2021-07-01 日清フーズ株式会社 Mix for deep-fried food products, method for producing deep-fried food product using same, and method for improving texture of deep-fried food product

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009219489A (en) * 2008-02-29 2009-10-01 Kraft Foods Global Brands Llc Snappy filled and baked confectionery having high water content
JP2011523855A (en) * 2008-06-13 2011-08-25 ネステク ソシエテ アノニム Food
JP2015195758A (en) * 2014-04-01 2015-11-09 日清製粉株式会社 Manufacturing method of spring roll
WO2021132391A1 (en) * 2019-12-25 2021-07-01 日清フーズ株式会社 Mix for deep-fried food products, method for producing deep-fried food product using same, and method for improving texture of deep-fried food product

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A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20040105