JP3929101B2 - Masking method for acidity - Google Patents

Masking method for acidity Download PDF

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Publication number
JP3929101B2
JP3929101B2 JP04792997A JP4792997A JP3929101B2 JP 3929101 B2 JP3929101 B2 JP 3929101B2 JP 04792997 A JP04792997 A JP 04792997A JP 4792997 A JP4792997 A JP 4792997A JP 3929101 B2 JP3929101 B2 JP 3929101B2
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sucralose
acidity
product
parts
taste
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JPH10243776A (en
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良寿 佐川
淳子 吉藤
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San Ei Gen FFI Inc
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San Ei Gen FFI Inc
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Description

【0001】
【発明の属する技術分野】
本発明は酸味のマスキング方法に関し、より詳細には酸味を呈する製品に、スクラロースを添加することからなる酸味のマスキング方法に関する。
【0002】
【従来の技術及び発明が解決しようとする課題】
酸味は、食品、医薬品及び医薬部外品等の経口摂取又は口内利用可能な製品において、塩味、苦味、甘味等とともに総合的な味覚の完成に重要な要素であり、食品等の上述の製品素材が本来備える場合もあるが、通常は酸味剤等を添加することにより付与される。
【0003】
また、これら酸味剤等は、食品等に酸味を付与するだけでなく、防腐、保存、抗菌、凝固、緩衝作用、粘性調整、ゲル化の調整及び膨張剤として、種々の作用を示すため、単に味覚の構成にとどまらず、これらの作用を期待して食品等の製品中に添加する場合がある。
しかし、有用な作用を期待して添加される酸味剤であっても、一方においてはpHを低下させたり、物性や化学的特性を変化させる場合があり、これにより、食品等の本来の味のバランスを損ない、また、不快な酸味を増強したりして、食品等の嗜好性に悪影響を及ぼす問題があった。
【0004】
これに対して、種々の呈味成分が酸味を緩和するものとして知られている。例えば、糖類やアミノ酸等が挙げられるが、これらを食品等に添加することにより十分な酸味緩和作用を発揮させようとすると、甘味がつきすぎたりして製品自体の味のバランスが損なわれるという問題があった。
また、特公平4−60626号において、アスパルテームが、漬物や梅加工食品において酸味をマイルドにすることが記載されている。しかし、アスパルテーム自体、pH、温度等によって分解し易く、対象の食品によっては長期間安定に保存することができない場合がある。
【0005】
よって、酸味のマスキング効果を十分に発揮するとともに、製品本来の味のバランスを保持し、さらに長期安定性及び熱安定性にすぐれた酸味のマスキング方法が求められている。
【0006】
【課題を解決するための手段】
本出願人は、種々の呈味成分を、酸味を呈する製品に添加することにより、酸味自体、他の味成分とのバランス、長期保存又は熱安定性等について鋭意検討を行い本発明を完成するに至った。
つまり、本発明によれば、酸味を呈する製品に、スクラロースを添加する酸味のマスキング方法が提供される。
【0007】
【発明の実施の形態】
本発明における酸味を呈する製品とは、経口摂取又は口内利用時に酸味を呈する製品を意味し、また、本来酸味は必要ではないが、保存等の目的で酸味剤等を添加したために酸味を呈するに至った製品も含まれ、食品、医薬品、医薬部外品等が挙げられる。これら製品は摂取時又は利用時に液体、半固体、固体状のいずれの形態のものであってもよい。これら製品中において酸味を呈する物質としては、例えば、各種の天然素材、クエン酸、酒石酸、リンゴ酸、フマル酸、乳酸、酢酸、グルコノデルタラクトン、アジピン酸、コハク酸及びリン酸等の天然又は合成酸味剤等が挙げられる。よって、酸味を呈する製品の具体例としては、サイダー、レモンスカッシュ等の炭酸飲料;天然果汁飲料;粉末飲料;乳飲料;乳酸菌飲料;スポーツ飲料;栄養飲料;フラワーペースト、ジャム等を含有する菓子パン類;うどん、ラーメン等のめん類;インスタント米飯;キャンデー、ガム、錠菓、グミキャンデー、スナック等の菓子類;ゼリー、みつまめ、杏仁豆腐、ヨーグルト等のデザート食品;シャーベット等の冷菓;梅干し、ピクルス、しそ漬け等の漬物類;豆腐・油揚げ類;酢、ウスターソース、タルタルソース、マヨネーズ、ドレッシング、トマトケチャップ、ハンバーグソース、ステーキソース等の風味調味料;即席麺(スープ)、ポタージュ、スパゲティーソース、デミグラスソース、チリソース、カレー、ハヤシライス、クリームシチュー、ビーフシチュー、グラタン、ドリア、炊き込みご飯の素、マーボー豆腐の素、酢豚の素、ちらし寿司、いなり寿司、いなり揚げ等のレトルト・調理食品;ピラフ、スパゲティー、親子丼、スープ等の電子レンジ食品等の種々食品、ビタミン剤及び口腔錠剤等の医薬品、口内清涼剤及び歯磨粉等の医薬部外品等が挙げられる。なおこれら製品は、酸味を呈する限り、甘味、塩味、渋味、苦味等の他の味を呈するものであってもよく、保存剤、殺菌剤等の種々の添加剤を含有していてもよい。また、本来酸味は必要ないが、保存剤等の目的で酸味剤等を添加したために、酸味を呈するに至ったものも含む。
【0008】
本発明においては、上記の酸味を呈する製品にスクラロースを添加する。スクラロースの添加量は、得られた製品の味の総合的なバランス等を考慮して適宜調整することができる。スクラロースは高甘味度甘味剤と称され、少量で通常の甘味を呈するため、多量に使用すると他の味の成分とのバランスを損なう。また、スクラロースは甘味を呈する最小値以下の量、つまり甘味の閾値以下の量でも酸味のマスキング効果を奏することができる。ここで、甘味の閾値とは、上述のように、甘味剤の甘味を呈する最小値を意味するが、この値は必ずしも絶対値として表されるものではない。つまり、本願発明者らの試験によれば、クエン酸(結晶)0.1%の水溶液に対するスクラロースの甘味の閾値は0.00075%、クエン酸(結晶)0.3%の水溶液に対する閾値は0.003%であることが確認されている。このように、甘味の閾値は、対象製品の形態(液体、流動体、固体等)、製品中の酸味の種類あるいは強弱、製品中の他の味成分(塩味、渋味等)、製品の摂取又は利用時の温度等により変動する値であると考えられるが、一般に甘味剤として使用する場合の量よりも小さい値である。これによって、酸味のマスキング効果を十分に発揮するとともに、製品本来の味のバランスを保持し、さらに長期安定性、熱安定性にすぐれた酸味のマスキングを行うことができる。また、スクラロース自体、甘味剤として良質の甘味を呈する物質であるため、マスキングされた後の酸味自体の風味を良質なものにすることができる。
【0009】
酸味を呈する製品にスクラロースを添加する方法としては、スクラロースの所定量を、酸味を呈する製品に均一に添加できる限り特に限定されるものではない。例えば、酸味を呈する製品の最終形態、つまり摂取又は利用時の形態が固体の場合は、成型されるまでの製造工程における液体、半固体の形態の時に、所定量のスクラロースをそのまま、又は希釈された溶液の状態で均一に添加し、その後に固体形状に形成する方法、成型された固体形状の製品に、希釈された溶液状のスクラロースを塗布又は噴霧等により均一に添加する方法等が挙げられる。また、酸味を呈する製品の摂取又は利用時の形態が液体又は半固体の場合は、その製造工程中又は最終製品にそのまま又は溶液の状態で均一に添加する方法等が挙げられる。
【0010】
【実施例】
試験例1
スクラロースの安定性を、高甘味度甘味剤であるアスパルテームの安定性と比較した。
まず、100gの水に対して5gの砂糖を溶解した水溶液と同等の甘味を有するスクラロース及びアスパルテーム水溶液をそれぞれ調製した。これらの水溶液を、pH4.0に調節し、80℃に加熱して、10〜16日間保持した。その際の各水溶液中のスクラロース又はアスパルテームの量を測定した。その結果を図1に示す。
【0011】
図1によれば、特に熱が加わる条件下では、アスパルテームは経時的に分解し、この分解にともなって、酸味のマスキング効果も消失していくことが認められた。一方、スクラロースでは、経時的な分解はほとんど認められず、酸味のマスキング効果の消失も認められなかった。
【0012】
実施例1
1/5濃縮グレープ果汁4.5重量部(以下「部」と記す)、クエン酸(結晶)0.12部、L−酒石酸0.05部、グレープエッセンスNo. 66815(三栄源エフ・エフ・アイ株式会社製)0.1部、サンレッドYMF(三栄源エフ・エフ・アイ株式会社製)0.03部、スクラロース0.013部を水にて100部とし、93℃まで加熱し、熱時瓶に充填した。このように調製した直後のグレープ果汁飲料は、酸味のさわやかなグレープ果汁飲料であった。
【0013】
また、このグレープ果汁飲料を、180日間、常温(24±1℃)で保存した。この際、スクラロース0.013部の代わりにアスパルテーム0.0365部、酵素処理ステビア0.048部、サッカリンナトリウム0.024部を用いたグレープ果汁飲料(すべての甘味料は、砂糖7.3部使用のグレープ果汁飲料と同等の甘味に調整した)を同様に180日間保存し、評価した。その結果を表1に示す。
【0014】
【表1】

Figure 0003929101
【0015】
表1から、酸味と甘味とを総合すると、スクラロースが最も高い評価であった。
【0016】
実施例2:梅フィズ
炭酸水50部、ホワイトリカー15部、1/5濃縮梅透明果汁1部、クエン酸(結晶)0.35部、ウメフレーバーNo. 58715(三栄源エフ・エフ・アイ株式会社製)0.1部、サンレッドBM(三栄源エフ・エフ・アイ株式会社製)0.02部、スクラロース0.015部を水にて100部とし、瓶に充填する。70℃の湯浴上で30分間殺菌する。
このように調製したアルコール飲料は、不快な酸味がマスキングされ、梅の酸味のさわやかなフィズであった。
【0017】
実施例3:バーベキューソース
トマトベースト35部、ワインビネガー30部、食塩3部、サラダ油3部、スパイス0.2部、ガーリックパウダー0.05部、スクラロース0.012部を水にて100部とし、容器に充填する。80℃の湯浴上で30分間殺菌する。
【0018】
このように調製したバーベキューソースは、ワインビネガー由来の酢酸臭が、スクラロースによってマスキングされ、酸味の不快味がマスキングされたバーベキューソースであった。
【0019】
【発明の効果】
本発明によれば、酸味を呈する製品に、スクラロースを添加することにより、製品本来の味のバランスを保持し、さらに長期安定性、熱安定性にすぐれた酸味のマスキング効果を十分に発揮することができる。また、スクラロース自体、甘味剤として良質の甘味を呈する物質であるため、マスクングされた後の酸味自体の風味を良質なものにすることができる。
【図面の簡単な説明】
【図1】スクラロースとアスパルテームの経時的な安定性を示すグラフである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a sour masking method, and more particularly to a sour masking method comprising adding sucralose to a sour product.
[0002]
[Prior art and problems to be solved by the invention]
Acidity is an important factor for the completion of a comprehensive taste as well as salty taste, bitterness, sweetness, etc. in products that can be taken orally or taken orally, such as foods, pharmaceuticals and quasi drugs. May be originally provided, but is usually provided by adding a sour agent or the like.
[0003]
In addition, these sour agents not only give sourness to foods, but also exhibit various effects as antiseptic, storage, antibacterial, coagulation, buffering, viscosity adjustment, gelation adjustment and swelling agents, so In addition to the structure of the taste, it may be added to products such as food in anticipation of these effects.
However, even a sour agent added with the expectation of a useful action may lower the pH or change the physical properties or chemical properties on the one hand, There is a problem of adversely affecting the palatability of food and the like by impairing the balance and enhancing unpleasant sourness.
[0004]
On the other hand, various taste components are known to relieve acidity. For example, saccharides and amino acids may be mentioned, but if they are added to foods, etc., to try to exert sufficient acidity mitigating action, the problem is that the taste balance of the product itself is impaired due to excessive sweetness. was there.
Japanese Patent Publication No. 4-60626 describes that aspartame makes the acidity mild in pickles and processed ume foods. However, aspartame itself is easily decomposed by pH, temperature, etc., and depending on the target food, it may not be stably stored for a long time.
[0005]
Accordingly, there is a need for a sour masking method that fully exhibits the sour masking effect, maintains the original taste balance of the product, and is excellent in long-term stability and thermal stability.
[0006]
[Means for Solving the Problems]
The present applicant has completed the present invention by adding various taste ingredients to a product exhibiting sourness, and intensively examining the sourness itself, balance with other taste ingredients, long-term storage or thermal stability, etc. It came to.
That is, according to the present invention, there is provided a sour masking method of adding sucralose to a sour product.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
The product exhibiting acidity in the present invention means a product that exhibits acidity when ingested or used in the mouth, and although acidity is not necessary originally, but because of the addition of an acidulant or the like for the purpose of storage, the acidity is exhibited. Products are also included, including foods, pharmaceuticals, and quasi drugs. These products may be in liquid, semi-solid or solid form when ingested or used. Examples of substances that exhibit acidity in these products include various natural materials such as citric acid, tartaric acid, malic acid, fumaric acid, lactic acid, acetic acid, glucono delta lactone, adipic acid, succinic acid, and phosphoric acid. Examples include synthetic acidulants. Therefore, specific examples of products exhibiting sourness include carbonated drinks such as cider and lemon squash; natural fruit juice drinks; powder drinks; milk drinks; lactic acid bacteria drinks; sports drinks; nutritional drinks; Noodles such as udon and ramen; instant cooked rice; confectionery such as candy, gum, tablet confectionery, gummy candy and snacks; dessert foods such as jelly, mitsumeme, apricot tofu and yogurt; frozen desserts such as sorbet; plum dried, pickles, Pickles such as shiso pickles; tofu and fried foods; flavoring seasonings such as vinegar, Worcester sauce, tartar sauce, mayonnaise, dressing, tomato ketchup, hamburg sauce, steak sauce; instant noodles (soup), potage, spaghetti sauce, demiglace sauce, Chili sauce, curry, hayashi rice, Ream stew, beef stew, gratin, doria, cooked rice, marvo tofu, sour pork, chirashi sushi, inari sushi, inari fried foods such as pilaf, spaghetti, oyakodon, soup Examples include various foods such as range foods, pharmaceuticals such as vitamins and oral tablets, and quasi-drugs such as mouth fresheners and toothpastes. In addition, these products may exhibit other tastes such as sweetness, salty taste, astringency, and bitterness as long as they exhibit acidity, and may contain various additives such as preservatives and bactericides. . Moreover, although the acidity is not originally required, the acidity is added for the purpose of a preservative and the like, so that the acidity is exhibited.
[0008]
In the present invention, sucralose is added to the product exhibiting the acidity. Amount of sucralose, Ru can be appropriately adjusted in consideration of the overall balance and the like taste of the resulting product. Scan Kurarosu is referred to as the high sweetness sweetener, for exhibiting normal sweetness in small amounts, if a loss of the balance between a large amount use of other flavor ingredients. Further, sucralose can exert a sour masking effect even in an amount below the minimum value that exhibits sweetness, that is, an amount below the sweet taste threshold . Here, as described above, the sweetness threshold means the minimum value that exhibits the sweetness of the sweetener, but this value is not necessarily expressed as an absolute value. That is, according to the present inventors' test, it was confirmed that the threshold for sweetness of sucralose for an aqueous solution of 0.1% citric acid (crystal) was 0.00075% and the threshold for an aqueous solution of 0.3% citric acid (crystal) was 0.003%. Has been. As described above, the sweetness threshold is determined based on the form of the target product (liquid, fluid, solid, etc.), the type or strength of sourness in the product, other taste components in the product (salt taste, astringency, etc.), and product intake. Alternatively, it is considered that the value varies depending on the temperature at the time of use, but is generally smaller than the amount used when used as a sweetener. As a result, the sour masking effect is sufficiently exhibited, the original taste balance of the product is maintained, and sour masking with excellent long-term stability and thermal stability can be performed. Moreover, since sucralose itself is a substance exhibiting good quality sweetness as a sweetener, the taste of the acidity itself after masking can be made high quality.
[0009]
The method for adding sucralose to a product exhibiting sourness is not particularly limited as long as a predetermined amount of sucralose can be uniformly added to a product exhibiting sourness. For example, if the final form of a product that exhibits sourness, that is, the form when ingested or used, is a solid, a predetermined amount of sucralose is diluted or diluted as it is in a liquid or semi-solid form in the manufacturing process until molding. For example, a method of uniformly adding the solution in the form of a solution and then forming it into a solid form, a method of uniformly adding a diluted solution of sucralose to the molded solid form product by coating or spraying, etc. . Moreover, when the form at the time of ingestion or utilization of the product which exhibits sourness is a liquid or a semi-solid, the method etc. which add uniformly in the state of the manufacturing process or the final product as it is in the state of a solution, etc. are mentioned.
[0010]
【Example】
Test example 1
The stability of sucralose was compared with that of aspartame, a high intensity sweetener.
First, sucralose and an aspartame aqueous solution having sweetness equivalent to an aqueous solution in which 5 g of sugar was dissolved in 100 g of water were prepared. These aqueous solutions were adjusted to pH 4.0, heated to 80 ° C. and held for 10 to 16 days. The amount of sucralose or aspartame in each aqueous solution at that time was measured. The result is shown in FIG.
[0011]
According to FIG. 1, it was recognized that aspartame decomposed with time, particularly under conditions where heat was applied, and the sour masking effect disappeared with this decomposition. On the other hand, sucralose showed almost no degradation over time, and no disappearance of the sour masking effect.
[0012]
Example 1
1/5 concentrated grape juice 4.5 parts by weight (hereinafter referred to as “parts”), citric acid (crystal) 0.12 parts, L-tartaric acid 0.05 parts, grape essence No. 66815 (San-Eigen F.F. 0.1 part from I Co., Ltd., 0.03 part Sun Red YMF (manufactured by Saneigen FFI Co., Ltd.), 0.013 part sucralose to 100 parts with water, heated to 93 ° C., heat When the bottle was filled. The grape juice drink immediately after preparation in this way was a refreshing sour grape juice drink.
[0013]
The grape juice drink was stored at room temperature (24 ± 1 ° C.) for 180 days. At this time, grape juice drink using 0.0365 parts of aspartame, 0.048 parts of enzyme-treated stevia and 0.024 parts of saccharin sodium instead of 0.013 parts of sucralose (all sweeteners are 7.3 parts of sugar used) The sweetness of the grape juice beverage was adjusted to the same sweetness) and stored for 180 days in the same manner. The results are shown in Table 1.
[0014]
[Table 1]
Figure 0003929101
[0015]
From Table 1, when the acidity and sweetness were combined, sucralose had the highest evaluation.
[0016]
Example 2: 50 parts of plum fizz carbonated water, 15 parts of white liquor, 1 part of 1/5 concentrated ume transparent fruit juice, 0.35 part of citric acid (crystal), Ume flavor No. 58715 (San-Eigen FFI Co., Ltd.) 0.1 part), Sun Red BM (manufactured by Saneigen FFI Co., Ltd.) 0.02 part, and 0.015 part of sucralose to 100 parts with water and filled into a bottle. Sterilize on a 70 ° C. water bath for 30 minutes.
The alcoholic beverage prepared in this manner was masked with unpleasant sourness and was a refreshing fizz of sourness of plum.
[0017]
Example 3: Barbecue sauce tomato base 35 parts, wine vinegar 30 parts, salt 3 parts, salad oil 3 parts, spices 0.2 parts, garlic powder 0.05 parts, sucralose 0.012 parts with water 100 parts, Fill container. Sterilize in an 80 ° C. water bath for 30 minutes.
[0018]
The barbecue sauce prepared in this way was a barbecue sauce in which the acetic acid odor derived from wine vinegar was masked by sucralose and the unpleasant taste of sourness was masked.
[0019]
【The invention's effect】
According to the present invention, by adding sucralose to a product exhibiting sourness, the balance of the original taste of the product can be maintained, and a long-term stability and thermal stability can be sufficiently exhibited. Can do. Moreover, since sucralose itself is a substance exhibiting good quality sweetness as a sweetener, the taste of the sourness itself after masking can be improved.
[Brief description of the drawings]
FIG. 1 is a graph showing the stability of sucralose and aspartame over time.

Claims (1)

酸味を呈する製品に、スクラロースを、該製品の重量に対して0.012〜0.015重量%で用いることを特徴とする酸味のマスキング方法。A method for masking sourness, characterized in that sucralose is used in a product exhibiting sourness in an amount of 0.012 to 0.015% by weight based on the weight of the product .
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