JP3904699B2 - Twin hose and manufacturing method thereof - Google Patents

Twin hose and manufacturing method thereof Download PDF

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Publication number
JP3904699B2
JP3904699B2 JP33808297A JP33808297A JP3904699B2 JP 3904699 B2 JP3904699 B2 JP 3904699B2 JP 33808297 A JP33808297 A JP 33808297A JP 33808297 A JP33808297 A JP 33808297A JP 3904699 B2 JP3904699 B2 JP 3904699B2
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Japan
Prior art keywords
layer
rubber
reinforcing
hose
outer peripheral
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JP33808297A
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Japanese (ja)
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JPH11153264A (en
Inventor
秀輔 斎藤
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Bridgestone Corp
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Bridgestone Corp
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Priority to JP33808297A priority Critical patent/JP3904699B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は、追い焚き風呂循環用、床暖房用、インジェクション温調用等の120℃以下の温水輸送に用いるホ−スに関するもので、主としてホ−スを往き用と戻り用の2本をツイン構造にて使用するホ−スに係るものである。
【0002】
【従来の技術】
従来よりこの種のホ−スとしては、EPDMからなる内層ゴム管と、その外周面にビニロンや芳香族ポリアミド繊維からなる複数本の補強糸を巻回してなる補強層と、その外周面にEPDMからなる外層ゴムを形成してなるホ−スが知られている。
【0003】
これらホ−スをツイン構造とするためには、補強層まで形成したホ−スを2本用意し、その外層ゴムを押出す時にメガネ状に押出しツイン化をなし、その後加硫することで商品となす方法や、単体の加硫済みゴムホ−スを紐、結束治具にて2本結束する方法が知られている。
【0004】
前者の外層ゴムを押出す時にツイン化をなす方法では、補強層を形成済みの2本のホ−スの寸法、曲がりくせ、補強糸の編上角度等のバラツキがあると加工速度も上げられず、加工がしにくくコスト高となってしまう。一方、加硫済みの単体ホ−スを2本結束する方法では結束ピッチを小さくしないと、未結束部でホ−スが離れてしまい取扱いに不便であることと、結束ピッチを小さくすると結束の加工費がかかるという問題があった。
【0005】
他方、熱融着によるツイン構造のホ−スとするには、内層及び外層にPVCを用い、補強層には硬鋼線をラセン状に巻回するか、補強糸を巻回したホ−スが知られている。このPVCホ−スは、内層にもPVCが使用されており、温水が内層PVC管を循環すると温水により内層PVCに配合した可塑剤等が抽出され、ホ−スの硬化が生じホ−スの折れやパイプの接合部で漏れが発生しやすい欠点があった。
【0006】
【発明が解決しようとする課題】
本発明は、ホ−スの最外層に熱可塑性樹脂を用いた複合ホ−スとすることで従来の技術の欠点を改良したものである。
【0007】
【課題を解決するための手段】
本発明は以上の課題を解決するためになされたものであって、その発明の第1は耐温水用のツインホースに係るものであって、カーボンブラックの配合量が5部以下であるEPDMから形成された内層ゴム管と、この内層ゴム管の外周面に補強糸を巻回した補強層と、この補強層の外周面に配置した中間ゴム層と、当該中間ゴム層の外周面に熱可塑性樹脂層を備えた2本の複合ホースが、前記熱可塑性樹脂層において連続的に融着されたことを特徴とする。
【0008】
そして、発明の第2は、ツインホースの製造方法に係るもので、カーボンブラックの配合量が5部以下であるEPDMをゴムまたは樹脂マンドル上に押し出して内層ゴム管を構成する第1工程と、前記内層ゴム管の外周面に補強糸を巻回して補強層を構成する第2工程と、前記補強層の外周面にゴムを押し出して中間ゴム層を構成する第3工程と、加熱して上記各層のゴムを加硫し、次いでマンドルを抜き去る第4工程と、中間ゴム層表面に接着剤を塗布する第5工程と、接着剤を塗布した中間ゴム層の表面に熱可塑性樹脂を押し出して熱可塑性樹脂層を形成する第6工程と、前記第6工程によって得られた複合ホースの熱可塑性樹脂層を加熱、軟化させて前記複合ホース同士を連続的に熱融着させる第7工程とを有する方法である。
【0009】
【発明の実施の形態】
本発明の第1の複合ホ−スは、内層ゴム管と、この内層ゴム管の外周面に補強糸を巻回した補強層と、その補強層の外周面に配置した中間ゴム層と、更にこの中間ゴム層の外周面に熱可塑性樹脂をそなえてなる耐温水用の複合ホ−スで、内層ゴム管は温水の循環に耐えられるようEPDMを用い、塩素水や入浴剤に耐え、かつ抽出物が少なく水分透過も少ない配合とするものが好ましい。特にゴム表面にカ−ボンが抽出されるという黒色汚染を防止するため、カ−ボンの配合量を5部以下に押えることが重要であり、ゴムの硬度は60〜80°が望ましい。
【0010】
補強層に用いられる補強糸は、ホ−スの使用温度で100℃未満の温水時はビニロンを、100℃を越えるときは芳香族ポリアミド繊維、軟鋼線を用いることが好ましい。特に、ビニロンは安価で全使用温度に使用したいが高温水では加水分解の恐れがあるため使用温度を100℃未満とするものである。
【0011】
補強層上に形成される中間ゴム層は、主として外層の樹脂層との接着を確保する目的のために用いるもので、中間ゴム層の外表面に直接又はバフ加工後に接着剤を塗布し、その外周面に樹脂層を押し出し被覆するものである。
【0012】
外層の樹脂層は、熱融着加工を容易とするため熱可塑性樹脂とし100℃未満の温水時はオレフィン系TPE、PVC、ポリウレタン樹脂、スチレン系樹脂等が主として使用され、100℃を越えるときはオレフィン系TPE、シリコ−ン樹脂、ポリアミド樹脂等が使用可能である。
【0013】
これら樹脂の硬度は複合ホ−スとしての柔軟性を確保するため50〜70°が望ましい。又、外層を樹脂層とすることでホ−スのカラ−化が容易となり、かつ往きと戻りのホ−スの色分けも容易にできることとなる。
【0014】
本発明の第2のホ−スの製造方法としては、ゴム又は樹脂マンドルの上に内層ゴム管を規定厚さ押し出す。その外周面に補強糸を巻回し補強層となすが、巻回しする構造はスパイラル状でもプレ−ド状でも良い。この補強層の外周面に中間ゴム層を規定厚さ押し出す。その後、規定の温度で一定時間加硫し加硫後マンドルを抜き出してゴムホ−スを形成させる。これらを連続加工とすることで、加工費の低減、品質の安定性がはかれる。次に加硫済みゴムホ−スの中間ゴム層表面をバフ研磨し、規定の接着剤を塗布後、熱可塑性樹脂を規定厚さ押出し複合ホ−スを形成させる。尚、バフ研磨は必須ではないが、接着力を確保するためにはこの工程を行うことが望ましい。この複合ホ−スを規定長さに切断し、ホ−ス単体2本を熱融着させツイン構造に加工するものである。このツイン構造とするための熱融着の方法は、外層に用いた樹脂の融点に合わせて設定した熱風をノズルの先より吐出し、外層樹脂を軟化させホ−ス同士を圧着することでツイン化が可能となる。
【0015】
尚、本発明の複合ホ−スの大きさは特に限定はされないが、例えば、内層ゴム管1の直径は5〜50mm、厚さ1〜4mm、中間ゴム層3は主としてNBRが採用され、その厚さは0.5〜2mm、外面樹脂層の厚さは0.5〜2mm程度が採用される。
【0016】
【実施例】
以下、実施例をもって本発明を更に詳細に説明する。
図1は本発明の第1における複合ホ−スの側面図であり、図2はこれをツインホ−スとした際の断面図である。図中、1はEPDM製の内層ゴム管、2は芳香族ポリアミド繊維よりなる補強層であり、巻回角度は好ましくは54度44分(静止角度)としたものである。3はNBRを主成分とする中間ゴム層であり、4はPVC製の外層である。この複合ホ−スは当然ホ−ス単体での使用も可能である。この例における各層は、内層ゴム管1の直径は14mm、厚さ1.5mm、中間ゴム層3の厚さは1mm、外面樹脂層の厚さは0.9mmであった。
【0017】
次に、得られた上記複合ホ−スを用い、第2発明の第7工程において熱風ノズル(熱風温度200〜500℃)をもって加熱し、第4層のPVC層を軟化させ、これを押えロ−ラ−等にて加圧接触させることによって図2に示すツインホ−スとしたものである。熱風温度は外面樹脂層の種類及びホ−スの加工速度によって適宜選択されるものである。尚、加工速度は通常は2〜15m/分の範囲にて行われる。
【0018】
【発明の効果】
本発明の第2発明について言えば、複合ホ−スの外層を加熱して接合するだけで簡単にツインホ−スを得ることができ、連続加工とすることで、加工費の低減・品質の安定性がはかれる。
【図面の簡単な説明】
【図1】図1は第1発明における複合ホ−スの側面図である。
【図2】図2は第2発明におけるツインホ−スの断面図である。
【符号の説明】
1‥‥内層ゴム管、
2‥‥補強層、
3‥‥中間ゴム層、
4‥‥樹脂外層。
[0001]
BACKGROUND OF THE INVENTION
TECHNICAL FIELD The present invention relates to a hose used for transporting hot water at 120 ° C. or less for recirculation bath circulation, floor heating, injection temperature control, etc., and mainly has two twins for forward and return use. This relates to the hose used in the above.
[0002]
[Prior art]
Conventionally, as this type of hose, an inner layer rubber tube made of EPDM, a reinforcing layer formed by winding a plurality of reinforcing yarns made of vinylon or aromatic polyamide fiber around its outer peripheral surface, and EPDM on its outer peripheral surface A hose formed by forming an outer-layer rubber made of is known.
[0003]
In order to make these hoses into a twin structure, two hose formed up to the reinforcing layer are prepared, and when the outer layer rubber is extruded, it is extruded into glasses to form a twin and then vulcanized. And a method of binding a single vulcanized rubber hose with a string and a binding jig.
[0004]
In the former method in which the outer layer rubber is twinned when the outer layer rubber is extruded, the processing speed can be increased if there are variations in the dimensions of the two hoses on which the reinforcing layer has been formed, bending, and the knitting angle of the reinforcing yarn. Therefore, processing is difficult and the cost is high. On the other hand, in the method of bundling two vulcanized single hoses, if the bundling pitch is not reduced, the hose is separated at the unbundled portion, which is inconvenient to handle. There was a problem that processing costs were required.
[0005]
On the other hand, in order to make a hose having a twin structure by heat fusion, PVC is used for the inner layer and the outer layer, and a hose in which a hard steel wire is wound in a spiral shape or a reinforcing yarn is wound around the reinforcing layer. It has been known. In this PVC hose, PVC is also used for the inner layer. When warm water circulates in the inner layer PVC pipe, the plasticizer blended in the inner layer PVC is extracted by the hot water, and the hose is hardened and the hose is hardened. There was a drawback that leakage was likely to occur at the folds and pipe joints.
[0006]
[Problems to be solved by the invention]
The present invention improves the drawbacks of the prior art by making a composite hose using a thermoplastic resin as the outermost layer of the hose.
[0007]
[Means for Solving the Problems]
The present invention has been made to solve the above problems, and the first of the invention relates to a twin hose for hot water resistance , and from EPDM in which the blending amount of carbon black is 5 parts or less. The formed inner rubber tube, the reinforcing layer in which the reinforcing thread is wound around the outer peripheral surface of the inner rubber tube, the intermediate rubber layer disposed on the outer peripheral surface of the reinforcing layer, and the outer peripheral surface of the intermediate rubber layer are thermoplastic. Two composite hoses provided with a resin layer are continuously fused in the thermoplastic resin layer .
[0008]
The second aspect of the invention relates to a method for manufacturing a twin hose, and is a first step in which an EPDM having a carbon black content of 5 parts or less is extruded onto a rubber or resin mandle to constitute an inner rubber tube , A second step of forming a reinforcing layer by winding a reinforcing thread around the outer peripheral surface of the inner layer rubber tube, a third step of forming an intermediate rubber layer by extruding rubber on the outer peripheral surface of the reinforcing layer, and heating the above the layers of rubber vulcanized, then extruded and fourth step overtake the mandrel, and a fifth step of applying an adhesive to the surface of the intermediate rubber layer, the surface of the intermediate rubber layer coated with adhesive thermoplastic resin A sixth step of forming a thermoplastic resin layer, and a seventh step of heating and softening the thermoplastic resin layer of the composite hose obtained in the sixth step to continuously heat-bond the composite hoses together. It is the method which has.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
The first composite hose of the present invention includes an inner layer rubber tube, a reinforcing layer in which a reinforcing thread is wound around the outer peripheral surface of the inner layer rubber tube, an intermediate rubber layer disposed on the outer peripheral surface of the reinforcing layer, and A composite hose for hot water resistance that has a thermoplastic resin on the outer peripheral surface of this intermediate rubber layer. The inner rubber tube uses EPDM to withstand the circulation of hot water, withstands chlorine water and bathing agents, and is extracted. It is preferable to use a compound with a small amount of water and low moisture permeation. In particular, in order to prevent black contamination that carbon is extracted on the rubber surface, it is important to keep the amount of carbon blended to 5 parts or less, and the hardness of the rubber is preferably 60 to 80 °.
[0010]
As the reinforcing yarn used for the reinforcing layer, it is preferable to use vinylon when hot water is less than 100 ° C. at the use temperature of the hose, and when it exceeds 100 ° C., aromatic polyamide fiber or mild steel wire is used. In particular, vinylon is inexpensive and is desired to be used at all operating temperatures. However, since hot water may cause hydrolysis, the operating temperature is less than 100 ° C.
[0011]
The intermediate rubber layer formed on the reinforcing layer is mainly used for the purpose of ensuring adhesion with the outer resin layer, and an adhesive is applied directly or after buffing to the outer surface of the intermediate rubber layer. A resin layer is extruded and coated on the outer peripheral surface.
[0012]
The outer resin layer is made of a thermoplastic resin to facilitate heat-sealing, and olefinic TPE, PVC, polyurethane resin, styrenic resin, etc. are mainly used when hot water is less than 100 ° C. Olefin-based TPE, silicone resin, polyamide resin and the like can be used.
[0013]
The hardness of these resins is preferably 50 to 70 ° in order to ensure flexibility as a composite hose. Further, by making the outer layer a resin layer, the hose can be easily colored, and the forward and return hose can be easily color-coded.
[0014]
In the second hose manufacturing method of the present invention, an inner layer rubber tube is extruded on a rubber or resin mandle to a specified thickness. A reinforcing thread is wound around the outer peripheral surface to form a reinforcing layer, and the wound structure may be spiral or preed. An intermediate rubber layer is extruded to a predetermined thickness on the outer peripheral surface of the reinforcing layer. Thereafter, vulcanization is carried out at a specified temperature for a certain time, and after vulcanization, the mandle is extracted to form a rubber hose. By making these continuous processing, processing costs can be reduced and quality can be stabilized. Next, the surface of the intermediate rubber layer of the vulcanized rubber hose is buffed, a prescribed adhesive is applied, a thermoplastic resin is extruded to a prescribed thickness, and a composite hose is formed. Buffing is not essential, but it is desirable to perform this step in order to ensure adhesion. This composite hose is cut to a specified length, and two hose units are heat-sealed to form a twin structure. The method of heat fusion for making this twin structure is as follows. The hot air set according to the melting point of the resin used for the outer layer is discharged from the tip of the nozzle, the outer layer resin is softened and the hoses are pressure-bonded. Can be realized.
[0015]
The size of the composite hose of the present invention is not particularly limited. For example, the inner rubber tube 1 has a diameter of 5 to 50 mm, a thickness of 1 to 4 mm, and the intermediate rubber layer 3 is mainly made of NBR. The thickness is 0.5-2 mm, and the thickness of the outer resin layer is about 0.5-2 mm.
[0016]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples.
FIG. 1 is a side view of a composite hose according to the first aspect of the present invention, and FIG. 2 is a cross-sectional view of this composite hose. In the figure, 1 is an inner rubber tube made of EPDM, 2 is a reinforcing layer made of an aromatic polyamide fiber, and the winding angle is preferably 54 degrees 44 minutes (static angle). 3 is an intermediate rubber layer mainly composed of NBR, and 4 is an outer layer made of PVC. Of course, this composite hose can be used as a single hose. In each layer in this example, the diameter of the inner rubber tube 1 was 14 mm, the thickness was 1.5 mm, the thickness of the intermediate rubber layer 3 was 1 mm, and the thickness of the outer resin layer was 0.9 mm.
[0017]
Next, using the obtained composite hose, in the seventh step of the second invention, it is heated with a hot air nozzle (hot air temperature 200 to 500 ° C.) to soften the fourth PVC layer. -The twin hose shown in Fig. 2 is formed by pressure contact with a roller or the like. The hot air temperature is appropriately selected depending on the type of the outer surface resin layer and the processing speed of the hose. The processing speed is usually in the range of 2 to 15 m / min.
[0018]
【The invention's effect】
Speaking of the second invention of the present invention, a twin hose can be obtained simply by heating and joining the outer layers of the composite hose. By continuous processing, the processing cost is reduced and the quality is stabilized. Sex is measured.
[Brief description of the drawings]
FIG. 1 is a side view of a composite hose according to a first invention.
FIG. 2 is a sectional view of a twin hose in the second invention.
[Explanation of symbols]
1 ... Inner rubber tube,
2 ... Reinforcing layer,
3. Intermediate rubber layer,
4 ... The resin outer layer.

Claims (6)

カーボンブラックの配合量が5部以下であるEPDMから形成された内層ゴム管と、この内層ゴム管の外周面に補強糸を巻回した補強層と、この補強層の外周面に配置した中間ゴム層と、当該中間ゴム層の外周面に熱可塑性樹脂層を備えた2本の複合ホースが、前記熱可塑性樹脂層において連続的に融着されてなることを特徴とする耐温水用のツインホース。 Inner layer rubber tube formed of EPDM having a carbon black content of 5 parts or less, a reinforcing layer in which a reinforcing thread is wound around the outer peripheral surface of the inner layer rubber tube, and an intermediate rubber disposed on the outer peripheral surface of the reinforcing layer A twin hose for hot water resistance, characterized in that two composite hoses having a thermoplastic resin layer on the outer peripheral surface of the intermediate rubber layer and the intermediate rubber layer are fused continuously in the thermoplastic resin layer . 補強糸がビニロンである請求項1に記載の耐温水用のツインホース。The twin hose for hot water resistance according to claim 1, wherein the reinforcing yarn is vinylon. 補強糸が芳香族ポリアミド繊維である請求項1に記載の耐温水用のツインホース。The twin hose for hot water resistance according to claim 1, wherein the reinforcing yarn is an aromatic polyamide fiber. カーボンブラックの配合量が5部以下であるEPDMをゴムまたは樹脂マンドル上に押し出して内層ゴム管を構成する第1工程と、A first step of forming an inner rubber tube by extruding EPDM having a carbon black content of 5 parts or less onto a rubber or resin mandle;
前記内層ゴム管の外周面に補強糸を巻回して補強層を構成する第2工程と、A second step of forming a reinforcing layer by winding a reinforcing thread around the outer peripheral surface of the inner layer rubber tube;
前記補強層の外周面にゴムを押し出して中間ゴム層を構成する第3工程と、A third step of forming an intermediate rubber layer by extruding rubber to the outer peripheral surface of the reinforcing layer;
加熱して上記各層のゴムを加硫し、次いでマンドルを抜き去る第4工程と、A fourth step of heating to vulcanize the rubber of each layer and then pulling out the mandle;
中間ゴム層の表面に接着剤を塗布する第5工程と、A fifth step of applying an adhesive to the surface of the intermediate rubber layer;
接着剤を塗布した中間ゴム層の表面に熱可塑性樹脂を押し出して熱可塑性樹脂層を形成する第6工程と、A sixth step of forming a thermoplastic resin layer by extruding a thermoplastic resin on the surface of the intermediate rubber layer coated with the adhesive;
前記第6工程によって得られた複合ホースの熱可塑性樹脂層を加熱、軟化させて前記複合ホース同士を連続的に熱融着させる第7工程とA seventh step of heating and softening the thermoplastic resin layer of the composite hose obtained in the sixth step to continuously heat-bond the composite hoses together;
を有してなることを特徴とするツインホースの製造方法。A method for producing a twin hose, comprising:
補強糸がビニロンである請求項4に記載のツインホースの製造方法。The method for producing a twin hose according to claim 4, wherein the reinforcing yarn is vinylon. 補強糸が芳香族ポリアミド繊維である請求項4に記載のツインホースの製造方法。The method for producing a twin hose according to claim 4, wherein the reinforcing yarn is an aromatic polyamide fiber.
JP33808297A 1997-11-22 1997-11-22 Twin hose and manufacturing method thereof Expired - Lifetime JP3904699B2 (en)

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JP33808297A JP3904699B2 (en) 1997-11-22 1997-11-22 Twin hose and manufacturing method thereof

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JP2006156627A Division JP2006308104A (en) 2006-06-05 2006-06-05 Composite hose

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JPH11153264A JPH11153264A (en) 1999-06-08
JP3904699B2 true JP3904699B2 (en) 2007-04-11

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JP4618584B2 (en) * 2006-01-30 2011-01-26 株式会社 メイジフローシステム Fluid hose
JP2009228753A (en) * 2008-03-21 2009-10-08 Bridgestone Corp Flexible hose
JP5542424B2 (en) * 2009-12-22 2014-07-09 株式会社ブリヂストン Composite hose

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