JP3859412B2 - Reverse osmosis apparatus with automatic reverse osmosis membrane cleaning mechanism, and method for producing pure water using the apparatus - Google Patents

Reverse osmosis apparatus with automatic reverse osmosis membrane cleaning mechanism, and method for producing pure water using the apparatus Download PDF

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JP3859412B2
JP3859412B2 JP33032099A JP33032099A JP3859412B2 JP 3859412 B2 JP3859412 B2 JP 3859412B2 JP 33032099 A JP33032099 A JP 33032099A JP 33032099 A JP33032099 A JP 33032099A JP 3859412 B2 JP3859412 B2 JP 3859412B2
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pure water
reverse osmosis
water
raw water
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JP2000262868A (en
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成泰 金
廣美 朝部
邦彦 山中
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JMS Co Ltd
Kitakyushu Foundation for Advancement of Industry Science and Technology
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JMS Co Ltd
Kitakyushu Foundation for Advancement of Industry Science and Technology
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Description

【0001】
【発明が属する技術分野】
本発明は、原水に含有されたコロイド、難溶性塩類やバクテリアなどの不純物が逆浸透膜の表面に濃縮・蓄積されて、製造された純水(逆浸透水)の水質が悪化すること、逆浸透膜面への不純物の付着、沈殿等の結果、逆浸透膜の透水性能が経時的に低下することを防ぐことを自動的に可能とした逆浸透装置および該装置を使用した逆浸透方法による純水の製造法に関するものである。
【0002】
【従来の技術】
従来の逆浸透装置では逆浸透膜にコロイド、難溶性塩類やバクテリアなどの不純物が膜面に濃縮されたり、沈殿することにより、製造される純水(逆浸水)の純度(導電率・微粒子数・エンドキシン濃度など)が悪化したり、透水性能の経時劣化により耐久性に問題があった。
膜の目詰まりにより透水性能が低下した場合、逆浸透膜モジュールを分離し、薬液循環ラインを形成し、アルカリないし酸性洗浄剤を逆浸透膜の原水流入側に流し込むと言う煩雑な操作を必要とした。
また、前記のような薬液洗浄後は逆浸透膜に残留する前記洗浄に使用した薬液を水洗除去するために大量の水を必要とした。
さらに、前記薬液洗浄自体によって逆浸透膜を化学的に劣化させ、逆浸透膜自体の透水性は回復しても水質は回復しないこともある。このような場合には、高価な逆浸透膜の交換が必要で維持管理コストが増大すると言う課題があった。
【0003】
また、従来、逆浸透水(RO水、reverse osmosed water、また、以下、純水とも呼ぶ。)の製造は、図5に示すような間欠運転逆浸透水製造システムが行われていた。このシステムにおいては、逆浸透装置Cから、濃縮水を除去すると共に、製造される純水(以下、逆浸透水とも言う)を純水タンクに貯留し、該純水タンクが純水で一杯になるとレベルスイッチで検知して制御系fにより原水を逆浸透装置に供給するポンプの運転を中止し、逆に純水タンクの貯水量が低下するとレベルスイッチで検知して制御系fにより前記原水供給ポンプの運転を再開し、純水の製造を行うものが提案されていた。
【0004】
【発明が解決しようとする課題】
逆浸透装置による純水造水時、濃縮水循環ラインを取り付ける事で純水の回収率を著しく向上させる事が可能であるが、反面、逆浸透膜に不純物の蓄積が増加する問題が発生する。
本発明の目的は、原水の製造における前記課題を解決した逆浸透膜自動洗浄機構付逆浸透装置(以下、単に逆浸透装置とも言う)および該装置を使用した純水の製造法を提供することにある。
すなわち、本発明の目的は、逆浸透装置の使用中に自動的な純水洗浄工程を組み込むことにより原水中の不純物の逆浸透膜表面の濃縮や沈着殿形成を防止し、(1)導電率、微粒子数、エンドトキシン濃度などでモニターされる水質を向上させる、純水の製造効率を向上させる、(2)逆浸透膜の透水性能を保持し耐用年数を延長させる、(3)煩雑で膜の化学劣化を起こす薬液洗浄を不溶とする、もしくは頻度を減じる、(4)膜面でのバクテリアの繁殖を低減するなどの課題を解決した逆浸透膜自動洗浄機構付逆浸透装置、および純水の製造法を提供することにある。
【0005】
【課題を解決するための手段】
本発明の第1は、逆浸透装置の原水負荷側に、該装置の運転中に逆浸透装置の逆浸透膜を純水により洗浄するための純水再循環機構を設けた逆浸透膜自動洗浄機構付逆浸透装置を提供することにより、前記のような問題あるいは課題を解決したことにある。
すなわち、本発明の逆浸透装置の特徴は、連続運転を行いながら純水の使用量に対して造水量が優位な時間帯、いいかえると純水タンクの貯水量が多くタンク内液面が高位の状態の時間帯に純水タンク中の余剰の純水を逆浸透膜モジュールへ還流し、該モジュールの洗浄を行う構成にある。つまり連続運転中に間欠的に洗浄工程を挿入する構成の装置にある。余剰の純水を洗浄に利用することにより、純水タンクが溢水に至ることも回避している。
前記「純水タンクの貯水量が多くタンク内液面が高位の状態の時間帯」とは、仮に純水の貯留量が低下しても、ユースポイント(使用する箇所)への逆浸透水の供給量が不足するという問題が生じないような貯留量を指す。これは、例えば図1のレベルスイッチαの位置に液面がある状態(この状態をタンク内液面が高位の状態とも言う)である、これに対して、例えば図1のレベルスイッチβの位置に液面がある状態(この状態をタンク内液面が低位の状態とも言う)あるいは前記レベルスイッチβの位置より低い位置に液面がある状態では、ユースポイント(使用する箇所)への逆浸透水の供給量が不足するというような問題が生じ、純水タンク中の純水を使用して前記のような逆浸透膜モジュールの洗浄を行うことはできない。
本発明の第2は、前記の逆浸透膜自動洗浄機構付逆浸透装置を使用して前記のような問題あるいは課題を解決した純水の製造法である。
【0006】
具体的には、本発明の逆浸透装置は、原水を逆浸透装置に供給する開閉弁を有する原水負荷ライン(a)、原水負荷ラインの逆浸透装置の上流側に設けた原水または純水を高圧にするために使用する装置(以下、液体加圧化手段とも言う)(b)、逆浸透膜を通過した純水と逆浸透膜を素通りした濃縮水に原水を分離する逆浸透膜を有する逆浸透装置(c)、一端が逆浸透装置に接続して他端が前記原水負荷ラインの開閉弁の下流側で原水負荷ラインに接続して再循環ループラインを形成する素通りライン(濃縮水ライン)(d)、前記素通りライン(濃縮水ライン)から分岐して形成された開閉弁を有する排水ライン(e)、前記原水負荷ラインと素通りライン(濃縮水ライン)とで形成され、かつ前記排水ラインが分岐した位置より下流側の素通りラインに開閉弁を有する再循環ループライン(f)、逆浸透装置で製造された純水の貯留容器(g)、一端が純水タンクに接続して他端が原水負荷ラインの開閉弁の下流側で原水負荷ラインに接続した開閉弁を有する純水還流ライン(h)および前記純水ラインから分岐する初期抜水ライン(j)を少なくとも有し、かつ前記素通りライン(d)、排水ライン(e)および純水還流ライン(h)に設けた開閉弁が並列に設けた複数個で構成されていることを特徴とする自動洗浄機構付き逆浸透装置に関する。
逆浸透装置の膜機能の低下は、膜自体の強度劣化でなく膜面に異物の沈着による劣化であるが、本発明の逆浸透装置では、単純な機構によって逆浸透膜面への優れた洗浄効果が得ら、その結果、純水の製造効率が格段に向上し、且つ逆浸透膜の性能が長期に維持される。
【0007】
本発明の純水の製造法は、具体的には、前記の逆浸透装置を使用して、最初に原水を逆浸透装置に供給する原水負荷ライン、初期抜水ライン、排水ラインに連結する素通りライン(濃縮水ライン)および排水ラインを開状態、純水ラインを開閉任意選択とし、その他のラインを閉状態で液体加圧化手段を作動させて逆浸透操作を行い、該操作によって製造された純水を初期抜水ラインから抜水し、該抜水された純水の濃度を検査し、その濃度が一定以上に良くなった段階で、下記(1)〜(3)の各工程を連続して少なくとも1回以上行うことを特徴とする純水の製造法。
(1)純水製造工程
原水負荷ライン、排水ラインに連結する素通りライン(濃縮水ライン)ライン、排水ラインおよびを純水ライン開状態、再循環ループラインは開閉任意選択とし、その他のラインを閉状態で原水を供給し、液体加圧化手段を作動させ原水を高圧化し逆浸透装置に送り純水を製造する工程。
(2)純水置換洗浄工程
前記(1)の純水製造工程により製造された純水の貯留量が貯留容器のあらかじめ定められた液面位置に達した状態になった場合(A)、あるいは純水の液面が貯留容器の一定レベル以上にある純水の貯留量で、製造された純水の純度を検知し、その純度が一定以下に悪化した状態になった場合(B)、前記(A)あるいは(B)の状態を検知して原水の供給を停止し、かつ純水ラインを開閉任意選択とし、排水ラインに連結する素通りライン(濃縮水ライン)および排水ラインを開状態で逆浸透装置に純水還流ラインから純水を供給して素通り(濃縮水)ライン中および逆浸透装置中の濃縮水を排出しつつ純水に置換する工程。
(3)高速洗浄工程
前記(2)の工程による純水の置換状態で、原水負荷ラインからの原水の供給を停止状態、再循環ループラインを開状態、および排水ラインを閉状態として液体加圧化手段の作動下で純水を高流量で再循環ループライン中を再循環させて逆浸透装置の逆浸透膜を高速洗浄した後、この不純物を洗い流した洗浄水を排水ラインに連結する素通りライン(濃縮水ライン)、排水ラインおよび純水還流ラインのみを開状態、純水ラインを開閉任意選択とし、その他のラインを閉状態として液体加圧化手段の作動下に新たな純水を注入して排水ラインから排出する工程。
本発明で言う原水としては、例えば水道水、井戸水等を使用できる。
【0008】
以下、本発明の逆浸透装置および該逆浸透装置を使用した純水の製造法を図面に基づいて詳細に説明する。ただし、本発明は、これら実施態様のものに限定されるものではない。
図1は、本発明の自動洗浄機構付逆浸透装置の構成部材および該装置内の配管フローを示した図である。
図1の逆浸透装置Cに原水負荷ライン6を通して原水を供給する。
原水は高圧で逆浸透することにより、逆浸透膜を通過した純水と逆浸透膜を素通りした濃縮水に分離される。逆浸透膜に反撥され膜を透過せずに素通りした濃縮水は、素通りライン(濃縮水ライン)7により逆浸透装置Cから取り出される。
原水負荷ライン6には、その入口側には原水の供給量を調節するための弁1、好ましくは電磁弁を設け、また、該弁1と逆浸透装置Cの間に原水または純水などを加圧するため液体加圧手段(本図のものは高圧ポンプA)を設ける。
原水は前記原水負荷ライン6より導入され、前記ポンプAで加圧され高圧(以下、通水圧力とも言う)下で逆浸透装置C内に導入される。
前記純水の作成量は、膜の透水性、膜間圧力差(通水圧力)、原水の浸透圧、および原水の素通りラインの通過量と純水取り出し量の割合(すなわち回収率)に依存する。
【0009】
一般に、逆浸透装置Cから得られる純水の純度は原水の通水圧力(透過水量)や純水の回収率で変化する。また、純水の純度は通水圧力(膜間圧力差)に応じて動的に変動すること、また、圧変化による揺さぶりが逆浸透内のシール部の閉鎖不全を起こして原水中の成分がリークすることにより純水の水質が劣化しうることから通水圧力は高圧かつ一定圧に保ち変動を避けるのが好ましい。
通水圧力としては、通常5kg/cm2〜20kg/cm2程度の圧力が採用されるが、逆浸透装置Cに負荷する圧力は高圧かつ一定圧であることが好ましい。
【0010】
逆浸透膜に掛かる圧力を一定にするため排水・濃縮循環・純水還流ライン電磁弁と注入ホ゜ンフ゜は重要な役割を果たす。
すなわち、図において、排水用と濃縮水循環ラインの電磁弁並列に2個取り付けたのは、逆浸透膜に流入する流量を一定もしくは、変動を最小にし、高圧ホ゜ンフ゜にはいる圧力をより一定にする目的からである。さらに吐出流量を一定にする事で逆浸透膜にかかる圧力をより一定にする。
【0011】
前記素通りライン(濃縮水ライン)7は高圧ポンプAの上流側(図1のF地点)で原水負荷ライン6に接続し、再循環ループライン8を形成する。再循環ループライン8を構成する素通りライン(濃縮水ライン)7の途中に排液ライン9を設ける。排液ライン9上に排水用の電磁弁4と4aを並列に設けた。該電磁弁4と4aは1個でも良いが、下記実施例に記載する複数の洗浄操作を可能にしたり、また流量調節を容易にし、逆浸透膜に流入する流量を一定にするため複数個が好ましい。
排水ライン9上には前記排水弁に加えて、万が一の閉鎖回路の過負荷対策として該排水弁に並列に圧抜き安全弁Dを設けることが好ましい。
前記再循環ループライン8を形成する際には、素通りライン(濃縮水ライン)7には、該ラインが原水負荷ライン6に接続する地点より手前側に電磁弁3aと3bを設けるのが好ましい。また、これらの電磁弁は、1個であっても良いが、前記排水用の弁4aと4と同様に下記実施例に記載する複数の洗浄操作を可能にしたり、また流量調節を容易にし、逆浸透膜に流入する流量を一定にするため複数個が好ましい。
【0012】
逆浸透装置Cから純水が取り出され、逆浸透装置Cからの純水の取り出し制御する電磁弁2を有する純水ライン10を通って純水タンクに貯留される。該純水ライン10には、逆浸透装置Cから純水が取り出された純水が一定の純度を有するかどうか監視する部材を設けても良い。また、純水ライン10の電磁弁の上流部に分岐を設け始動時に停滞水を排出する初期抜水ラインとし(図示せず)、初期抜水ラインの開閉を調節する電磁弁を設ける。
原水タンクから取り出された純水を原水負荷ライン6に還流させる純水還流ライン11が原水負荷ライン6の高圧ポンプAの上流側に結合される(図1のF地点)。素通り(濃縮)ライン7が原水負荷ライン6に結合するF点と純水還流ライン11が原水負荷ライン6に結合するF点とは同一地点であることが配管を単純化する観点から好ましい、前者と後者のF点の位置は異なっていても良い。この場合、清浄な純水が流れる後者を前者よりも上流に配する方が原水ラインの6の洗浄性にやや優れる。
【0013】
前記純水還流ライン11には、逆流を防止し原水負荷ラインへの還流を容易とし、純水還流ラインの停滞部分の距離を短縮するため、さらに原水ラインの圧力と同等の圧力を供給するために注入ポンプBを設けるのが好ましい。また、注入ポンプBの上流側には、電磁弁5および5aが閉鎖している間の流出路を確保するために、ポンプBを通過した純水の一部を純水タンクに還流するラインを設ける。
前記純水還流ライン11には前記注入ポンプBと前記F点の間に電磁弁である5aと5が設けられており、該5aと5も1個であっても良いが、上述の電磁弁と同様に下記実施例に記載する複数の洗浄操作が可能としたり、流量調節を容易にするため複数個が好ましい(この製造法を第1の製造法と言う)。
【0014】
前記図面に基づく本発明の説明では弁として、並列に配した電磁弁を使用しているが、本発明の装置で使用する弁は電磁弁に限定されるものではないし、また並列に配した電磁弁の代わりに流量調節バルブを使用しても良いし、また、上述のように、複数個でなく1個であっても良い。
【0015】
本発明の純水の製造法の別の実施態様としては、前記第1の製造法において、純水製造工程、純水置換洗浄工程あるいは高速洗浄工程によりタンクの純水液面が中位の状態になった場合、原水負荷ライン、純水還流ライン、排水ラインおよび再循環ループラインを開状態、また、純水ラインは開状態で逆浸透を連続して行うことを特徴とする請求項5〜7のいずれかに記載の純水の製造法が挙げられる(この製造法は請求項に対応し、以下、製造法2とも言う)。この場合、純水タンクの水位が上がるか下がるかは排水ラインから排出される排水量と原水の供給量の大小関係、および純水のユースポイント(使用する箇所)での使用量によって決まる。
【0016】
本発明の純水の製造法のさらに別の実施態様としては、高速洗浄後、排水ライン、再循環ループライン、純水ラインおよび純水還流ラインを開状態として、純水による膜洗浄は、一部は排水しながら、一部は再循環しながら行うことを特徴とする請求項5〜6に記載の純水製造法が挙げられる(この製造法は請求項に対応し、以下、製造法3とも言う)。前記製造法2と3においては、逆浸透膜モジュールの純水側を停滞させると、汚染が発生する可能性があるという理由から、電磁弁2を開状態で実施することが望ましい。
【0017】
以下、本発明の実施例を示す。
【実施例】
実施例1
図に基づいて説明する。
(1)初期抜水工程
図1において、最初に原水を逆浸透装置に供給する原水負荷ライン6、初期抜水ライン(図示せず)、および排水ライン9を開状態、その他のラインを閉状態で液体加圧化手段を作動させて逆浸透操作を行い、該操作によって製造された純水の初期抜水を行う(ただし、本発明において、この初期抜水工程は、絶対に必要な要件ではない)。この初期抜水によって得られた純水の濃度が一定濃度以上、例えば導電率が原水の5%以下の純度になった後、純水製造工程に移行する。(2)純水製造工程および純水置換洗浄工程
初期抜水を行った後、純水の製造を行う。
純水の製造は、まず、高圧ポンプAの作動下で、電磁弁1・2・4と4aの一方が開状態、他の弁が閉状態で最大となるので、この状態で純水の製造が行われ、製造された純水は貯留タンクに貯留される。貯留タンクが満水状態となると、レベルスイッチが作動し、図2に示すように電磁弁4・4a・5・5aを開状態とし、その他の電磁弁を開状態とし、逆浸透装置の逆浸透膜モジュール中および素通りライン(濃縮水)ライン7中の濃縮水が純水で置換・洗浄される。この置換・洗浄操作によって、逆浸透膜表面に沈着沈殿したコロイド、難溶性塩類、バクテリア等を取り除き、膜の濾過効率を改善する。
【0018】
また、前記純水置換操作の開始は、逆浸透装置から取り出される純水の純度が一定純度以下になると行われるようにしても良い。ただし、この純水の純度を検知して行う前記純水置換操作の開始は、純水タンク液面の位置の検知と併用しながら行うのが好ましい。すなわち、純水タンク液面の位置があるレベル以下になっている場合に、純水の純度の検知結果のみに基づいて前記純水置換操作の開始行った場合、純水の使用量が供給量を上回り、さらに純水タンクの液面が低下し、渇水警報が作動する可能性がある。
この段階において、ライン中の流量は、
p=u=v=q+r=x+yの関係を満足する。
【0019】
図2の工程で、電磁弁2を開状態とし純水を製造しながら逆浸透膜モジュール中および素通りライン(濃縮水)ライン7中の濃縮水を純水で置換することもできる。純水の使用量が多く、純水製造の中止時間に余裕がない場合には好都合である(請求項12に対応)。この場合、ライン中の流量は
p=q+r=u=v+z、およびv=x+yの関係を満足する。
【0020】
次に図3に示すように、高圧ポンプAおよび供給ポンプBの作動下で(ただし、この供給ポンプBを設置するか設置しないか、あるいはどのような作動させるか任意)、電磁弁3・3aを開状態にし、他の電磁弁を閉状態にすることで純水は逆浸透装置の再循環ループライン8内で高流量に循環し膜を高速洗浄する。電磁弁2を開状態で洗浄と同時に純水製造を平行して行ってもよい。この場合電磁弁5aないし5は開状態としなければならない。還流する純水量は電磁弁5aおよび5の開閉状態により規定され、還流量が純水製造量と等しい。
この段階において、ライン中の流量は、
u=q+r+s+t=v+z、v=s+t、およびz=p=q+rの関係を満足する。
次に、一定時間経過し十分な洗浄が達成された後かもしくは純水タンクレベルが低下した時点で、図2に示すように、電磁弁4・4a・5・5aを開状態とし、その他の電磁弁は閉状態として、新たな純水を注入して、素通り(濃縮水)ライン7および再循環ループライン8内を再循環して不純物を洗い流した水をシングルバスにて洗浄、排水する。電磁弁2は開状態でもよい。この工程で純水タンクレベルが低下しレベルスイッチが作動した時点、もしくは、不純物を洗い流した水を新たな純水で排水した時点で最初の純水製造状態に戻る。
以上のような工程を繰り重しながら逆浸透膜に不純物が蓄積する前に洗浄除去を効率的に行うことで水質と膜の性能を維持し、併せて配管、逆浸透膜および純水タンク中のバクテリア等の繁殖を防ぐ。
【0021】
実施例2
前記図3の工程の後で、純水タンク液面が中間位にある時は、図4の工程で高圧ポンプAおよび供給ポンプBの作動下に電磁弁3a、4a、5aを開状態とし、その他の電磁弁を閉状態にする制御で純水による膜洗浄は、一部は排水しながら、また、一部は再循環することで膜の不純物を洗浄除去することができる。
さらに、電磁弁2を開状態でさらに一部は純水を製造しながら行うことができる(請求項11に対応)。この制御において、ライン中の流量は、
u=v+z、p=q、u=q+sおよびv=s+xの関係を満足する。
【0022】
実施例3
前記実施の電磁弁1を開とした純水製造工程下のバリエーションとして、例えば電磁弁4aおよび4を開、3aを開、3を閉とすると濃縮水の流れは排水が相対的に増加し、回収率が低下する(図6)。逆に3aおよび3を開、4aを開、4を閉とすると回収率は向上し純水製造に有利となる(図7)。3aおよび3を開、4aおよび4を閉とするとさらに回収率は向上する(図8)。また、電磁弁1を開の状態で、電磁弁5aおよび5、電磁弁5aおよび5の一方を開で一方を閉あるいは両方を閉にするとそれぞれ純水の還流割合が低下していく(例えば図9)。純水の還流量を増やしタンク内の逆浸透水を再度逆浸透することにより純水タンクの清浄化が達成される。
【0023】
本発明においては、前記のように並列に設けた複数個の弁の開閉状態を組み合わせることにより、純水の製造と膜洗浄を同時に行うことができる。ただし、電磁弁の開閉状態の組み合わせは前記のようなものに限定されるものではなく、純水の製造と純水による膜洗浄を同時に行うことができるものであれば良い。なお、図1〜8において、塗り潰し状態の弁は閉状態、塗り潰されていない状態の弁は開状態をそれぞれ示す
【0024】
【効果】
発明に係る逆浸透装置および該装置を使用した純水の製造法によると、純水による逆浸透膜への優れたた洗浄効果により逆浸透膜のの性能が長期に維持され、さらに鈍水の水質も従来の装置に比べ優れている。また、純水の製造効率も格段に改善される。逆浸透膜の交換頻度や薬液洗浄の頻度が減少することにより、保守にかかる費用も格段に少ない。大量の純水の安定供給を必要とする血液透析治療のための透析用水の供給手段として応用できる。
【図面の簡単な説明】
【図1】逆浸透膜自動製造機構付逆浸透装置の各部品取り付け配置および配管フローを説明した図である。
【図2】逆浸透膜をシングルバス洗浄するフロー図である。
【図3】逆浸透膜を純水で再循環洗浄するフロー図である。
【図4】逆浸透膜を純水で再循環洗浄し、一部を排水するとともに純水製造も平行して実施できるフロー図である。
【図5】従来例の間欠運転型ROシステムフロー図である。
【符号の説明】
A 高圧ポンプ
B 供給ポンプ
C 逆浸透装置
α レベルスイッチ
β レベルスイッチ
p 純水タンクからの再循環量
q 弁を通過する流量
q 弁を通過する流量
r 弁を通過する流量
s 弁を通過する流量
t 弁を通過する流量
u ポンプを通過する流量
v 流量
w ポンプを通過する流量
x 弁を通過する流量
y 弁を通過する流量
z 弁を通過する流量
1 電磁弁
2 電磁弁
3 電磁弁
3a 電磁弁
4 電磁弁
4a 電磁弁
5 電磁弁
5a 電磁弁
6 原水負荷ライン
7 素通り(濃縮水)ライン
8 再循環ループライン
9 排水ライン
10 純水(逆浸透水)ライン
11 純水還流ライン
12 三方電磁弁
13 初期抜水ライン
[0001]
[Technical field to which the invention belongs]
In the present invention, impurities such as colloids, sparingly soluble salts and bacteria contained in raw water are concentrated and accumulated on the surface of the reverse osmosis membrane, and the quality of the produced pure water (reverse osmosis water) deteriorates. According to a reverse osmosis device that automatically prevents the water permeation performance of a reverse osmosis membrane from being deteriorated over time as a result of adhesion of impurities to the surface of the osmosis membrane, precipitation, etc., and a reverse osmosis method using the device The present invention relates to a method for producing pure water.
[0002]
[Prior art]
In conventional reverse osmosis equipment, the purity (conductivity and number of fine particles) of pure water (reverse immersion water) produced by condensing or precipitating impurities such as colloids, sparingly soluble salts and bacteria on the reverse osmosis membrane・ Endotoxin concentration etc.) deteriorated and water permeability performance deteriorated over time.
When the water permeability is reduced due to clogging of the membrane, the reverse osmosis membrane module is separated, a chemical circulation line is formed, and the complicated operation of pouring an alkali or acidic detergent into the raw water inflow side of the reverse osmosis membrane is required. did.
In addition, a large amount of water was required after washing with the chemical solution as described above in order to wash away the chemical solution used in the washing remaining on the reverse osmosis membrane.
Furthermore, even if the reverse osmosis membrane is chemically deteriorated by the chemical cleaning itself and the water permeability of the reverse osmosis membrane itself is recovered, the water quality may not be recovered. In such a case, there has been a problem that an expensive reverse osmosis membrane needs to be replaced and maintenance costs increase.
[0003]
Conventionally, reverse osmosis water (RO water, reverse osmosed water, hereinafter also referred to as pure water) has been manufactured by an intermittent operation reverse osmosis water production system as shown in FIG. In this system, the concentrated water is removed from the reverse osmosis device C, and the produced pure water (hereinafter also referred to as reverse osmosis water) is stored in a pure water tank, and the pure water tank is filled with pure water. Then, the operation of the pump that supplies the raw water to the reverse osmosis device by the control system f is stopped by the level switch, and conversely, when the amount of water stored in the pure water tank decreases, the control system f detects that the raw water is supplied. The one that resumed the operation of the pump and produced pure water was proposed.
[0004]
[Problems to be solved by the invention]
At the time of pure water preparation by a reverse osmosis device, it is possible to remarkably improve the recovery rate of pure water by attaching a concentrated water circulation line, but on the other hand, there is a problem that the accumulation of impurities increases in the reverse osmosis membrane.
An object of the present invention is to provide a reverse osmosis device with a reverse osmosis membrane automatic cleaning mechanism (hereinafter also simply referred to as a reverse osmosis device) that solves the above-described problems in the production of raw water and a method for producing pure water using the device. It is in.
That is, the object of the present invention is to prevent the concentration of impurities in the reverse osmosis membrane surface and the formation of deposits by incorporating an automatic pure water washing process during use of the reverse osmosis apparatus, and (1) conductivity. Improve the water quality monitored by the number of fine particles, endotoxin concentration, etc., improve the production efficiency of pure water, (2) maintain the water permeability of the reverse osmosis membrane and extend the service life, (3) cumbersome membrane A reverse osmosis device with a reverse osmosis membrane automatic cleaning mechanism that has solved problems such as insoluble or reduced frequency of chemical cleaning that causes chemical degradation and (4) reduced bacterial growth on the membrane surface, and pure water It is to provide a manufacturing method.
[0005]
[Means for Solving the Problems]
The first of the present invention is a reverse osmosis membrane automatic cleaning provided with a pure water recirculation mechanism for cleaning the reverse osmosis membrane of the reverse osmosis device with pure water during the operation of the device on the raw water load side of the reverse osmosis device. By providing a reverse osmosis apparatus with a mechanism, the above problems or problems are solved.
That is, the reverse osmosis device of the present invention is characterized by a time zone in which the amount of water produced is superior to the amount of pure water used during continuous operation, in other words, the amount of water stored in the pure water tank is large and the liquid level in the tank is high. In the state time zone, excess pure water in the pure water tank is returned to the reverse osmosis membrane module, and the module is cleaned. In other words, the apparatus is configured to insert the cleaning process intermittently during continuous operation. By using excess pure water for cleaning, the pure water tank is prevented from overflowing.
The “time zone in which the amount of water stored in the pure water tank is large and the liquid level in the tank is high” means that even if the amount of pure water stored decreases, the reverse osmosis water to the point of use (where it is used) The amount of storage that does not cause the problem of insufficient supply. This is, for example, a state in which the liquid level is at the position of the level switch α in FIG. 1 (this state is also referred to as a state in which the liquid level in the tank is high). In contrast, for example, the position of the level switch β in FIG. When there is a liquid level in the tank (this state is also referred to as a low liquid level in the tank) or in a state where the liquid level is lower than the level switch β, reverse osmosis to the point of use (where to use) There arises a problem that the supply amount of water is insufficient, and the reverse osmosis membrane module cannot be cleaned using pure water in the pure water tank.
A second aspect of the present invention is a method for producing pure water that uses the reverse osmosis device with a reverse osmosis membrane automatic cleaning mechanism to solve the above problems or problems.
[0006]
Specifically, the reverse osmosis device of the present invention includes a raw water load line (a) having an on-off valve for supplying raw water to the reverse osmosis device, and raw water or pure water provided upstream of the reverse osmosis device of the raw water load line. An apparatus used for increasing the pressure (hereinafter also referred to as liquid pressurizing means) (b), having a reverse osmosis membrane that separates raw water into pure water that has passed through the reverse osmosis membrane and concentrated water that has passed through the reverse osmosis membrane A reverse osmosis device (c), one end connected to the reverse osmosis device and the other end connected to the raw water load line downstream of the open / close valve of the raw water load line to form a recirculation loop line (concentrated water line) ) (D), a drainage line (e) having an on- off valve formed by branching from the passage line (concentrated water line), the raw water load line and the passage line (concentrated water line), and the drainage Downstream from the position where the line branches Recirculation loop line having an on-off valve in the flow-through line (f), the reservoir of pure water produced by the reverse osmosis unit (g), one end of the other end connected to the pure water tank raw load line of the opening and closing valve At least a pure water recirculation line (h) having an on- off valve connected to the raw water load line on the downstream side, and an initial drain line (j) branched from the pure water line, and the passing line (d), drainage The present invention relates to a reverse osmosis device with an automatic cleaning mechanism, characterized in that a plurality of on-off valves provided in line (e) and a pure water reflux line (h) are provided in parallel .
The decrease in the membrane function of the reverse osmosis device is not due to the strength deterioration of the membrane itself but due to the deposition of foreign matter on the membrane surface. In the reverse osmosis device of the present invention, excellent cleaning of the reverse osmosis membrane surface by a simple mechanism is performed. As a result, the production efficiency of pure water is remarkably improved, and the performance of the reverse osmosis membrane is maintained for a long time.
[0007]
Specifically, the pure water production method of the present invention uses the reverse osmosis device described above, and first connects the raw water load line, the initial drainage line, and the drainage line for supplying raw water to the reverse osmosis device. A line (concentrated water line) and a drainage line are opened, a pure water line is optionally opened and closed, a liquid pressurizing means is operated with the other lines closed and a reverse osmosis operation is performed. The pure water is drained from the initial drain line, the concentration of the drained pure water is inspected, and the steps (1) to (3) below are continuously performed when the concentration has become better than a certain level. And at least once, a method for producing pure water.
(1) Pure water production process Raw water load line, passage line (concentrated water line) line connected to drainage line, drainage line and pure water line open state, recirculation loop line can be opened and closed arbitrarily, and other lines are closed Supplying raw water in a state, operating the liquid pressurizing means to increase the pressure of the raw water and sending it to the reverse osmosis device to produce pure water.
(2) Pure water replacement cleaning process (A) when the amount of pure water produced by the pure water production process of (1) reaches the predetermined liquid level of the storage container (A), or When the purity of the produced pure water is detected by the amount of pure water stored at a certain level or higher in the storage container and the purity of the pure water is deteriorated below a certain level (B), (A) or (B) is detected, the supply of raw water is stopped, the pure water line is optionally opened and closed, and the passage line (concentrated water line) connected to the drainage line and the drainage line are reversed. A step of supplying pure water from the pure water reflux line to the permeation device and replacing it with pure water while discharging the concentrated water in the passage (concentrated water) line and the reverse osmosis device.
(3) High-speed washing process In the pure water replacement state in the step (2), liquid pressurization is performed with the raw water supply from the raw water load line stopped, the recirculation loop line opened, and the drain line closed. Under normal operation, pure water is recirculated through the recirculation loop line at a high flow rate and the reverse osmosis membrane of the reverse osmosis unit is washed at high speed, and then the wash water that has washed away these impurities is connected to the drainage line. (Concentrated water line), drainage line and pure water recirculation line only open, pure water line open / close optional, other lines closed and fresh pure water injected under the operation of the liquid pressurizing means The process of discharging from the drainage line.
As raw water as referred to in the present invention, for example, tap water, well water and the like can be used.
[0008]
Hereinafter, a reverse osmosis device of the present invention and a method for producing pure water using the reverse osmosis device will be described in detail with reference to the drawings. However, the present invention is not limited to these embodiments.
FIG. 1 is a diagram showing constituent members of a reverse osmosis device with an automatic cleaning mechanism of the present invention and piping flow in the device.
Raw water is supplied through the raw water load line 6 to the reverse osmosis device C of FIG.
The raw water is separated into pure water that has passed through the reverse osmosis membrane and concentrated water that has passed through the reverse osmosis membrane by reverse osmosis at high pressure. Concentrated water which is repelled by the reverse osmosis membrane and passes through the membrane without passing through the membrane is taken out from the reverse osmosis device C by a passage line (concentrated water line) 7.
The raw water load line 6 is provided with a valve 1 for adjusting the supply amount of raw water, preferably a solenoid valve, on the inlet side, and raw water or pure water is supplied between the valve 1 and the reverse osmosis device C. In order to pressurize, a liquid pressurizing means (the high-pressure pump A in this figure) is provided.
Raw water is introduced from the raw water load line 6, pressurized by the pump A, and introduced into the reverse osmosis device C under high pressure (hereinafter also referred to as water flow pressure).
The amount of pure water produced depends on the water permeability of the membrane, the pressure difference between the membranes (water flow pressure), the osmotic pressure of the raw water, and the ratio of the raw water passage line and the amount of pure water taken out (that is, the recovery rate). To do.
[0009]
In general, the purity of pure water obtained from the reverse osmosis device C varies depending on the water pressure (permeated water amount) of raw water and the recovery rate of pure water. In addition, the purity of pure water changes dynamically according to the water flow pressure (transmembrane pressure difference), and the shaking caused by the pressure change causes the closure failure of the seal part in reverse osmosis, causing the components in the raw water to Since the quality of pure water can deteriorate due to leakage, it is preferable to keep the water flow pressure at a high and constant pressure to avoid fluctuations.
As the water flow pressure, a pressure of about 5 kg / cm 2 to 20 kg / cm 2 is usually employed, but the pressure applied to the reverse osmosis device C is preferably high and constant.
[0010]
In order to make the pressure applied to the reverse osmosis membrane constant, the drainage / concentration circulation / pure water reflux line solenoid valve and injection pump play an important role.
That is, in the figure, the two attached in parallel with the solenoid valve for the drainage and the concentrated water circulation line make the flow rate flowing into the reverse osmosis membrane constant or minimize the fluctuation, and make the pressure entering the high-pressure phone more constant. From the purpose. Further, by making the discharge flow rate constant, the pressure applied to the reverse osmosis membrane is made more constant.
[0011]
The passing line (concentrated water line) 7 is connected to the raw water load line 6 on the upstream side of the high-pressure pump A (point F in FIG. 1) to form a recirculation loop line 8. A drain line 9 is provided in the middle of a passage line (concentrated water line) 7 constituting the recirculation loop line 8. Solenoid valves 4 and 4a for drainage are provided in parallel on the drainage line 9. The electromagnetic valves 4 and 4a may be one, but a plurality of electromagnetic valves 4 and 4a may be used to enable a plurality of washing operations described in the following examples, to facilitate flow rate adjustment, and to keep the flow rate flowing into the reverse osmosis membrane constant. preferable.
In addition to the drain valve, it is preferable to provide a pressure relief safety valve D on the drain line 9 in parallel with the drain valve as a measure against overload of the closed circuit.
When the recirculation loop line 8 is formed, it is preferable that the passing-through line (concentrated water line) 7 is provided with solenoid valves 3 a and 3 b before the point where the line is connected to the raw water load line 6. In addition, the number of these solenoid valves may be one, but the plurality of washing operations described in the following examples can be performed similarly to the drainage valves 4a and 4, and the flow rate can be easily adjusted. A plurality is preferable in order to make the flow rate flowing into the reverse osmosis membrane constant.
[0012]
Pure water is taken out from the reverse osmosis device C and stored in a pure water tank through a pure water line 10 having an electromagnetic valve 2 that controls the removal of pure water from the reverse osmosis device C. The pure water line 10 may be provided with a member for monitoring whether or not the pure water from which the pure water is taken out from the reverse osmosis device C has a certain purity. In addition, a branch is provided upstream of the solenoid valve of the pure water line 10 as an initial drain line for discharging stagnant water at the start (not shown), and an electromagnetic valve for adjusting the opening and closing of the initial drain line is provided.
A pure water recirculation line 11 for recirculating pure water taken out from the raw water tank to the raw water load line 6 is coupled to the upstream side of the high-pressure pump A of the raw water load line 6 (point F in FIG. 1). From the viewpoint of simplifying the piping, it is preferable that the point F where the passage (concentration) line 7 is coupled to the raw water load line 6 and the point F where the pure water reflux line 11 is coupled to the raw water load line 6 are preferable. The position of the latter F point may be different. In this case, it is somewhat superior in the washability of the raw water line 6 that the latter in which clean pure water flows is arranged upstream of the former.
[0013]
The pure water reflux line 11 is supplied with a pressure equal to the pressure of the raw water line in order to prevent back flow and facilitate return to the raw water load line, to shorten the distance of the stagnant portion of the pure water reflux line. It is preferable to provide an infusion pump B. Further, on the upstream side of the injection pump B, a line for returning a part of the pure water that has passed through the pump B to the pure water tank is provided in order to secure an outflow path while the solenoid valves 5 and 5a are closed. Provide.
The pure water reflux line 11 is provided with solenoid valves 5a and 5 between the injection pump B and the point F. The solenoid valve 5a and 5 may be one. Similarly, a plurality of cleaning operations described in the following examples are possible, and a plurality of cleaning operations are preferable in order to easily adjust the flow rate (this manufacturing method is referred to as a first manufacturing method).
[0014]
In the description of the present invention based on the drawings, a solenoid valve arranged in parallel is used as a valve. However, the valve used in the apparatus of the present invention is not limited to the solenoid valve, and the solenoid valve arranged in parallel is used. Instead of the valve, a flow rate adjusting valve may be used, and as described above, one may be used instead of a plurality.
[0015]
In another embodiment of the pure water production method of the present invention, in the first production method, the pure water liquid level of the tank is in a middle state by the pure water production step, the pure water replacement washing step or the high-speed washing step. If it becomes, the raw water load line, pure water reflux line, drain line and a recirculation loop line opened, also claim 5 pure water line, characterized in that the continuously performed reverse osmosis in the open state 7. The method for producing pure water according to any one of 7 is mentioned (this production method corresponds to claim 8 and is hereinafter also referred to as production method 2). In this case, whether the level of the pure water tank rises or falls depends on the magnitude relationship between the amount of drainage discharged from the drainage line and the amount of raw water supplied, and the amount used at the point of use of pure water (where it is used).
[0016]
In another embodiment of the pure water production method of the present invention, after the high-speed cleaning, the draining line, the recirculation loop line, the pure water line and the pure water reflux line are opened, and the membrane cleaning with pure water is performed as follows. The pure water production method according to claim 5 , wherein the part is carried out while draining, and part is recirculated (this production method corresponds to claim 7 , hereinafter the production method). 3). In the manufacturing methods 2 and 3, it is desirable that the solenoid valve 2 is opened in the open state because the contamination may occur if the pure water side of the reverse osmosis membrane module is stagnated.
[0017]
Examples of the present invention will be described below.
【Example】
Example 1
This will be described with reference to the drawings.
(1) Initial drainage process In FIG. 1, the raw water load line 6 for initially supplying raw water to the reverse osmosis device, the initial drainage line (not shown), and the drainage line 9 are opened, and the other lines are closed. The liquid pressurizing means is operated to perform reverse osmosis operation, and initial drainage of pure water produced by the operation is performed (however, in the present invention, this initial drainage step is not absolutely necessary requirement) Absent). After the concentration of pure water obtained by this initial drainage becomes a certain concentration or more, for example, the conductivity is 5% or less of the raw water, the process proceeds to the pure water production process. (2) Pure water production process and pure water replacement washing process After the initial drainage, pure water is produced.
In the production of pure water, first, under the operation of the high pressure pump A, one of the solenoid valves 1, 2, 4 and 4a is opened and the other valve is closed. The produced pure water is stored in a storage tank. When the storage tank is full, the level switch is activated, the electromagnetic valves 4, 4a, 5, 5a are opened as shown in FIG. 2, the other electromagnetic valves are opened, and the reverse osmosis membrane of the reverse osmosis device The concentrated water in the module and in the passage line (concentrated water) line 7 is replaced and washed with pure water. This replacement / washing operation removes colloids, sparingly soluble salts, bacteria, etc. deposited on the surface of the reverse osmosis membrane and improves the filtration efficiency of the membrane.
[0018]
In addition, the pure water replacement operation may be started when the purity of pure water taken out from the reverse osmosis apparatus is equal to or lower than a certain level. However, the start of the pure water replacement operation performed by detecting the purity of the pure water is preferably performed in combination with the detection of the position of the pure water tank liquid level. That is, when the pure water tank liquid level is below a certain level and the pure water replacement operation is started based only on the pure water purity detection result, the amount of pure water used is the supply amount. There is a possibility that the water level of the pure water tank will drop and the drought warning will be activated.
At this stage, the flow rate in the line is
The relationship of p = u = v = q + r = x + y is satisfied.
[0019]
In the step of FIG. 2, the concentrated water in the reverse osmosis membrane module and the passage line (concentrated water) line 7 can be replaced with pure water while the electromagnetic valve 2 is opened and pure water is produced. It is convenient when the amount of pure water used is large and there is no allowance for the stop time of pure water production (corresponding to claim 12). In this case, the flow rate in the line satisfies the relationship of p = q + r = u = v + z and v = x + y.
[0020]
Next, as shown in FIG. 3, under the operation of the high-pressure pump A and the supply pump B (however, whether the supply pump B is installed or not, or how it is operated is optional), the solenoid valves 3 and 3a Is opened and the other solenoid valve is closed, so that pure water circulates at a high flow rate in the recirculation loop line 8 of the reverse osmosis device, and the membrane is washed at high speed. The pure water production may be performed in parallel with the cleaning while the electromagnetic valve 2 is opened. In this case, the solenoid valves 5a to 5 must be opened. The amount of pure water to be refluxed is defined by the open / close state of the solenoid valves 5a and 5, and the amount of reflux is equal to the amount of pure water produced.
At this stage, the flow rate in the line is
The relationships u = q + r + s + t = v + z, v = s + t, and z = p = q + r are satisfied.
Next, after a certain time has passed and sufficient cleaning has been achieved or when the pure water tank level has dropped, as shown in FIG. 2, the solenoid valves 4, 4a, 5, 5a are opened, and the other The solenoid valve is closed, and fresh pure water is injected to recirculate in the flow-through (concentrated water) line 7 and the recirculation loop line 8 to wash and drain the water from which impurities have been washed away in a single bath. The electromagnetic valve 2 may be in an open state. In this step, when the level of the pure water tank is lowered and the level switch is activated, or when the water from which impurities have been washed away is drained with new pure water, the first pure water production state is restored.
Maintaining water quality and membrane performance by performing washing and removal efficiently before impurities accumulate in the reverse osmosis membrane while repeating the above processes, and also in the piping, reverse osmosis membrane and pure water tank Prevent the growth of bacteria.
[0021]
Example 2
After the step of FIG. 3, when the pure water tank liquid level is in an intermediate position, the solenoid valves 3a, 4a, 5a are opened under the operation of the high pressure pump A and the supply pump B in the step of FIG. By controlling the other solenoid valves to be closed, the membrane cleaning with pure water can remove and remove impurities from the membrane by partially draining and recirculating partially.
Further, it can be performed while the solenoid valve 2 is opened and a part of the pure water is produced (corresponding to claim 11). In this control, the flow rate in the line is
The relationship of u = v + z, p = q, u = q + s and v = s + x is satisfied.
[0022]
Example 3
As a variation of a pure water manufacturing process the electromagnetic valve 1 is opened in the embodiment, for example, an electromagnetic valve 4a and 4 open, 3a open, 3 to the flow of the concentrated water to the closed drainage is relatively increased The recovery rate decreases (FIG. 6). Conversely, when 3a and 3 are opened, 4a is opened, and 4 is closed, the recovery rate is improved, which is advantageous for producing pure water (FIG. 7). When 3a and 3 are opened and 4a and 4 are closed, the recovery rate is further improved (FIG. 8). In addition, when the solenoid valve 1 is open and one of the solenoid valves 5a and 5 and the solenoid valves 5a and 5 is opened and one of them is closed or both are closed, the reflux rate of pure water decreases (for example, FIG. 9). Purification of the pure water tank is achieved by increasing the reflux amount of pure water and reverse osmosis of reverse osmosis water in the tank again.
[0023]
In the present invention , pure water production and membrane cleaning can be performed simultaneously by combining the open / close states of a plurality of valves provided in parallel as described above . However, the combination of the open / close states of the solenoid valves is not limited to the above, and any combination may be used as long as the production of pure water and the membrane cleaning with pure water can be performed simultaneously. 1 to 8, the filled valve indicates a closed state, and the unfilled valve indicates an open state .
[0024]
【effect】
According to the reverse osmosis device according to the invention and the method for producing pure water using the device, the performance of the reverse osmosis membrane is maintained for a long time due to the excellent cleaning effect of the pure water on the reverse osmosis membrane, and further the blunt water Water quality is also superior to conventional equipment. In addition, the production efficiency of pure water is greatly improved. Since the frequency of replacement of the reverse osmosis membrane and the frequency of chemical cleaning are reduced, the maintenance cost is remarkably low. It can be applied as a means for supplying dialysis water for hemodialysis treatment that requires a stable supply of a large amount of pure water.
[Brief description of the drawings]
BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a diagram for explaining each component mounting arrangement and piping flow of a reverse osmosis device with a reverse osmosis membrane automatic manufacturing mechanism.
FIG. 2 is a flowchart for single bath cleaning of a reverse osmosis membrane.
FIG. 3 is a flow chart for recirculating and washing a reverse osmosis membrane with pure water.
FIG. 4 is a flow chart in which a reverse osmosis membrane is recirculated and washed with pure water, a part of the reverse osmosis membrane is drained, and pure water production can be performed in parallel.
FIG. 5 is a flowchart of a conventional intermittent operation type RO system.
[Explanation of symbols]
A High pressure pump B Supply pump C Reverse osmosis device α Level switch β Level switch p Recirculation amount from pure water tank q Flow rate passing through valve q Flow rate passing through valve r Flow rate passing through valve s Flow rate passing through valve t Flow rate through the valve u Flow rate through the pump v Flow rate w Flow rate through the pump x Flow rate through the valve y Flow rate through the valve z Flow rate through the valve 1 Solenoid valve 2 Solenoid valve 3 Solenoid valve 3a Solenoid valve 4 Solenoid valve 4a Solenoid valve 5 Solenoid valve 5a Solenoid valve 6 Raw water load line 7 Through (concentrated water) line 8 Recirculation loop line 9 Drain line 10 Pure water (reverse osmosis water) line 11 Pure water recirculation line 12 Three-way solenoid valve 13 Initial Drainage line

Claims (8)

原水を逆浸透装置に供給する開閉弁を有する原水負荷ライン(a)、原水負荷ラインの逆浸透装置の上流側に設けた原水または純水を高圧にするために使用する装置(以下、液体加圧化手段とも言う)(b)、逆浸透膜を通過した純水と逆浸透膜を素通りした濃縮水に原水を分離する逆浸透膜を有する逆浸透装置(c)、一端が逆浸透装置に接続して他端が前記原水負荷ラインの開閉弁の下流側で原水負荷ラインに接続して再循環ループラインを形成する素通りライン(濃縮水ライン)(d)、前記素通りライン(濃縮水ライン)から分岐して形成された開閉弁を有する排水ライン(e)、前記原水負荷ラインと素通りライン(濃縮水ライン)とで形成され、かつ前記排水ラインが分岐した位置より下流側の素通りラインに開閉弁を有する再循環ループライン(f)、逆浸透装置で製造された純水の貯留容器(g)、一端が純水タンクに接続して他端が原水負荷ラインの開閉弁の下流側で原水負荷ラインに接続した開閉弁を有する純水還流ライン(h)および前記純水ラインから分岐する初期抜水ライン(j)を少なくとも有し、かつ前記素通りライン(d)、排水ライン(e)および純水還流ライン(h)に設けた開閉弁が並列に設けた複数個で構成されていることを特徴とする自動洗浄機構付き逆浸透装置。A raw water load line (a) having an on-off valve for supplying raw water to the reverse osmosis device, and a device (hereinafter referred to as liquid additive) used to increase the pressure of raw water or pure water provided upstream of the reverse osmosis device of the raw water load line. (B), a reverse osmosis device (c) having a reverse osmosis membrane that separates raw water into pure water that has passed through the reverse osmosis membrane and concentrated water that has passed through the reverse osmosis membrane, one end being a reverse osmosis device Connected line (concentrated water line) (d) connecting the other end to the raw water load line on the downstream side of the open / close valve of the raw water load line to form a recirculation loop line (d), the passing line (concentrated water line) A drainage line (e) having an opening / closing valve formed by branching from the drainage line (e), formed by the raw water load line and a passage line (concentrated water line), and opened and closed to a passage line downstream from the position where the drainage line branches. re having a valve Ring loopline (f), connected to the raw water load line downstream of the reverse osmosis reservoir of pure water produced by the apparatus (g), one end of the other end connected to the pure water tank off valve of the raw water load line A pure water return line (h) having an open / close valve and an initial drain line (j) branched from the pure water line, and the passing line (d), the drain line (e), and the pure water return line A reverse osmosis device with an automatic cleaning mechanism, wherein the open / close valve provided in (h) is constituted by a plurality provided in parallel . 素通りライン(d)、排水ライン(e)および純水還流ライン(h)の開閉弁に代えて流量調節バルブを設けたことを特徴とする請求項1に記載の自動洗浄機構付き逆浸透装置 The reverse osmosis device with an automatic cleaning mechanism according to claim 1, wherein a flow rate adjusting valve is provided in place of the on-off valves of the passage line (d), the drainage line (e) and the pure water recirculation line (h) . 素通りライン(濃縮水ライン)と純水還流ラインが高圧ポンプの上流側で前記原水負荷ラインに接続されたことを特徴とする請求項1または2に記載の逆浸透装置。  The reverse osmosis device according to claim 1 or 2, wherein a passage line (concentrated water line) and a pure water reflux line are connected to the raw water load line on the upstream side of the high-pressure pump. 素通りライン(濃縮水ライン)と純水還流ラインが原水負荷ラインの同一地点(該地点をF地点とも言う)に接続されたことを特徴とする請求項1〜3のいずれかに記載の逆浸透装置。  The reverse osmosis according to any one of claims 1 to 3, wherein the passage line (concentrated water line) and the pure water return line are connected to the same point of the raw water load line (this point is also referred to as F point). apparatus. 請求項1、3または4記載の逆浸透装置を使用して、最初に原水を逆浸透装置に供給する原水負荷ライン、初期抜水ラインおよび排水ラインの開閉弁を開状態、再循環ループラインの開閉弁を開閉任意選択とし、その他のラインの開閉弁を閉状態で液体加圧化手段を作動させて逆浸透操作を行い、該操作によって製造された純水を初期抜水ラインから抜水し、該抜水された純水の濃度を検査し、その濃度が一定以上に良くなった段階で、下記(1)〜(3)の各工程を連続して少なくとも1回以上行うことを特徴とする純水の製造法。
(1)純水製造工程
原水負荷ライン、排水ラインおよび純水ラインの開閉弁を開状態、再循環ループラインの開閉弁を開閉任意選択とし、その他のラインの開閉弁を閉状態で原水を供給し、液体加圧化手段を作動させ原水を高圧化し逆浸透装置に送り純水を製造する工程。
(2)純水置換洗浄工程
前記(1)の純水製造工程により製造された純水の貯留量が貯留容器のあらかじめ定められた高位の液面位置に達した状態になった場合(A)、あるいは純水の液面が貯留容器の一定レベル以上にある純水の貯留量で、製造された純水の純度を検知し、その純度が一定以下に悪化した状態になった場合(B)、前記(A)あるいは(B)の状態を検知して原水の供給を停止し、かつ純水ラインの開閉弁を開閉任意選択とし、排水ラインを開状態、再循環ループラインを閉状態で逆浸透装置に純水還流ラインから純水を供給して素通り(濃縮水)ライン中および逆浸透装置中の濃縮水を排出しつつ純水に置換する工程。
(3)高速洗浄工程
前記(2)の工程による純水の置換状態で、原水負荷ラインからの原水の供給を停止状態、再循環ループラインを開状態、および排水ラインを閉状態として液体加圧化手段の作動下で純水を高流量で再循環ループライン中を再循環させて逆浸透装置の逆浸透膜を高速洗浄した後、この不純物を洗い流した洗浄水を排水ラインおよび純水還流ラインのみを開状態、純水ラインは開閉任意選択とし、その他のラインを閉状態として液体加圧化手段の作動下に新たな純水を注入して排水ラインから排出する工程。
Using the reverse osmosis device according to claim 1, 3 or 4, the raw water load line for supplying raw water to the reverse osmosis device, the initial drain line and the drain line open / close valve are opened, and the recirculation loop line The open / close valve is arbitrarily opened and closed, the reverse pressure osmosis operation is performed by operating the liquid pressurizing means with the open / close valves of the other lines closed, and the pure water produced by the operation is drained from the initial drain line. The concentration of the drained pure water is inspected, and the following steps (1) to (3) are continuously performed at least once at a stage when the concentration has become better than a certain level. To produce pure water.
(1) Pure water production process Supply of raw water with the open / close valves of the raw water load line, drainage line and pure water line open, the open / close valve of the recirculation loop line can be arbitrarily opened and closed, and the open / close valves of other lines are closed Then, the liquid pressurizing means is operated to increase the pressure of the raw water and send it to the reverse osmosis device to produce pure water.
(2) Pure water replacement cleaning step When the amount of pure water produced by the pure water production step (1) reaches a predetermined high liquid level in the storage container (A) Or, when the purity of the produced pure water is detected by the amount of pure water stored with a pure water level above a certain level in the storage container, and the purity deteriorates below a certain level (B) Detecting the state of (A) or (B) above, stopping the supply of raw water, making the open / close valve of the pure water line optional, reverse the drainage line open, the recirculation loop line closed A step of supplying pure water from the pure water reflux line to the permeation device and replacing it with pure water while discharging the concentrated water in the passage (concentrated water) line and the reverse osmosis device.
(3) High-speed washing step In the pure water replacement state in the step (2), liquid pressurization is performed with the raw water supply from the raw water load line stopped, the recirculation loop line opened, and the drain line closed. After the pure water is recirculated through the recirculation loop line at a high flow rate under the operation of the purification means, the reverse osmosis membrane of the reverse osmosis unit is washed at high speed, and then the washing water from which the impurities have been washed away is discharged into the drainage line and the pure water reflux line. Only the open state, the pure water line is arbitrarily opened and closed, the other lines are closed, and fresh pure water is injected under the operation of the liquid pressurizing means and discharged from the drain line.
純水置換洗浄および洗浄工程の実行時間をあらかじめ定めた一定時間行うとともに、該時間内であってもタンクの液面があらかじめ定めた低位の液面以下になった場合には直ちに純水製造工程に移行させることを特徴とする請求項5に記載の純水の製造法。  The execution time of the pure water replacement cleaning and the cleaning process is performed for a predetermined time, and if the liquid level in the tank falls below a predetermined lower liquid level even within the predetermined time, the pure water production process is immediately performed. 6. The method for producing pure water according to claim 5, wherein 高速洗浄後、排水ライン、再循環ループライン、純水ラインおよび純水還流ラインの開閉弁を開状態として、純水による膜洗浄は、一部は排水しながら、一部は再循環しながら行うことを特徴とする請求項5または6に記載の純水製造法。  After high-speed cleaning, open / close valves of the drainage line, recirculation loop line, pure water line and pure water reflux line are opened, and membrane cleaning with pure water is performed while partly draining and partly recirculating. The method for producing pure water according to claim 5 or 6, wherein: 純水製造工程、純水置換洗浄工程あるいは高速洗浄工程によりタンクの純水液面があらかじめ定めた低位と高位の液面間にある場合、原水負荷ライン、純水還流ライン、排水ラインおよび再循環ループラインを開状態、また、純水ラインは開状態で逆浸透を連続して行うことを特徴とする請求項5〜7のいずれかに記載の純水の製造法。  When the pure water level of the tank is between the predetermined low and high levels in the pure water production process, pure water replacement cleaning process or high-speed cleaning process, the raw water load line, pure water reflux line, drainage line and recirculation The method for producing pure water according to any one of claims 5 to 7, wherein reverse osmosis is continuously performed with the loop line open and the pure water line open.
JP33032099A 1998-10-19 1999-10-18 Reverse osmosis apparatus with automatic reverse osmosis membrane cleaning mechanism, and method for producing pure water using the apparatus Expired - Fee Related JP3859412B2 (en)

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KR100465769B1 (en) * 2002-04-11 2005-01-13 조희남 subsurface water purify manage equipment
JP2004033947A (en) * 2002-07-04 2004-02-05 Mitsubishi Rayon Eng Co Ltd Apparatus for manufacturing refined water
AU2003901279A0 (en) * 2003-03-19 2003-04-03 Healey, Arthur Stephen Water purification system
JP5811551B2 (en) * 2011-03-08 2015-11-11 株式会社ジェイ・エム・エス Pure water production equipment
CN106830399A (en) * 2017-01-23 2017-06-13 上海六滴环保科技有限公司 A kind of Novel water purifier with pure water vacuolar membrane function when shutting down static
CN106830400A (en) * 2017-01-23 2017-06-13 上海六滴环保科技有限公司 A kind of water purifier with pure water vacuolar membrane function when shutting down static
JP6300988B2 (en) * 2017-05-08 2018-03-28 旭化成株式会社 Method for operating water treatment apparatus and method for producing potable water
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