JP3854997B2 - Decorative sheet - Google Patents
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- JP3854997B2 JP3854997B2 JP14656898A JP14656898A JP3854997B2 JP 3854997 B2 JP3854997 B2 JP 3854997B2 JP 14656898 A JP14656898 A JP 14656898A JP 14656898 A JP14656898 A JP 14656898A JP 3854997 B2 JP3854997 B2 JP 3854997B2
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- nonwoven fabric
- decorative
- decorative sheet
- fabric
- polyurethane resin
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Description
【０００１】
【発明の属する技術分野】
本発明は、ポリウレタン樹脂からなる不織布を使用した装飾シートに関するものである。
【０００２】
【従来の技術】
従来、ポプリ等の装飾片をカードや包装材等のデザインに使用するために、網目状または全面に孔を開けた熱可塑性ポリウレタン樹脂接着性フィルムと厚紙等のシート基材の間に該装飾片を置き、加熱加圧するという方法が提案されているが（特開平３−２６８９４３号公報）、熱接着性フィルムとしては、ポリエチレン、ポリプロピレン、ポリアマイド、ポリスチレン等のフィルムを一層又は積層して使用するものであり、風合が悪く、カード類には使用できるが、布帛等のデザインに使用できるものではなかった。
【０００３】
他方、ホットメルト不織布として、エチレン−酢酸ビニルコポリマー（ＥＶＡ）、ポリエチレン−アタクチックポリプロピレン（ＡＰＰ）、エチレン−アクリル酸エチルコポリマー（ＥＥＡ）、ポリアミド、ポリエステル等の樹脂からなるものが知られており、これらは、該不織布と被着体を積層し、加熱により不織布を溶融して接着させるのに用いられているが、このような不織布は、耐薬品性、耐クリーニング性、耐熱性に乏しく、また柔軟性に欠けるため、その用途は限られており、装飾用として使用されることはなかった。
【０００４】
【発明が解決しようとする課題】
本発明は、薄手の編織布等の基材にも、該基材の風合を損なうことなく、ポプリ等の装飾片を自由に接着して、風合よく、装飾性及び機能性に優れた装飾物となしうるような装飾シートを提供することを課題とする。
【０００５】
【課題を解決するための手段】
本発明では、ホットメルト接着性を有する熱可塑性ポリウレタン樹脂フィラメントからなる不織布の表面に、ポプリ等の装飾片を、不織布の前記接着性により貼着することにより、上記課題を解決した。
【０００６】
即ち、本発明者等は、熱可塑性ポリウレタン樹脂を使用して不織布を製造することによって、柔軟性、伸縮性及び通気性のいずれにも優れた製品を得ることができ、しかも、この製品は、常温では感触よく、そのまま直接衣料用等として使用できるが、必要に応じて加熱すると、該不織布を構成するフィラメントの溶融により、どのような基材にも、強力な接着を可能とすることを見いだし、本発明を完成したのである。
【０００７】
かかる不織布を構成する熱可塑性ポリウレタン樹脂は、ＪＩＳ Ｋ７３１１で測定した硬さ（ＪＩＳ−Ａ硬さ）が６５〜９８度であり、流動開始温度が８０〜１５０℃であるのが好ましい。
【０００８】
熱可塑性ポリウレタン樹脂の硬さが６５度未満では、熱間成形による不織布製造が困難となり、また、９８度を越えると、不織布の柔軟性が失われ、衣料用等の装飾用に使用し難いものとなる。また、流動開始温度が８０℃未満では、熱間成形による不織布の製造が困難となり、逆に１５０℃を越えた場合には、不織布の柔軟性が失われ、同時に、高温加工時の変色等も発生し、装飾用に使用し難いものとなる。
【０００９】
なお、ここで流動開始温度とは、樹脂を一定の昇温速度で加熱し、樹脂が溶融し流動し始める温度のことを言い、通常、高化式フローテスター等で測定する。流動開始温度は、ホットメルト不織布接着剤の接着条件、特に加熱温度を限定する重要な物性である。
【００１０】
また、不織布の目付けは１０〜７０ｇ／ｍ2 程度であるのが好ましい。不織布が薄過ぎると、扱い難く、逆に厚過ぎると、樹脂フィルム調の風合及び外観となり、通気性も悪くなるなどの問題を生じ易い。更に、不織布は、伸度５０％以上、通気度５cc／cm2 ／秒以上であるのが好ましく、不織布を構成するフィラメントの繊維径は１００μｍ以下、特に５０μｍ以下であるのがよい。
【００１１】
なお、不織布は、４５度カンチレバー法による剛軟度が４０mm以下、特に３５mm以下であるのが、装飾シートとして風合よく、扱い易い。
【００１２】
本発明では、熱可塑性ポリウレタン樹脂の溶融粘度挙動が温度に対して敏感であることを利用したものであり、従来はフィルムにしか出来なかった熱可塑性ポリウレタン樹脂を連続したフィラメントとし、これをシート状に積層し、そのフィラメントの接触点を該フィラメント自体で融着して形成したものであり、伸縮性及び通気性に富んだ接着性ある不織布である。該不織布は、熱可塑性ポリウレタン樹脂をメルトブロー法でフィラメントに形成しながら、該フィラメントを相互に融着させるというような方法で形成されればよい。例えば、樹脂を、押し出し機で加熱溶融後、適当な紡糸温度にて、メルトブローノズルから吐出し、エアースリットから加熱エアーを噴霧して細化された繊維をその下方を走行する金網ベルトコンベア上に捕集し、該ベルトコンベア上で、平面状に捕集された繊維がそれ自体の熱で相互に融着され、不織布となるようにするという方法で製造できる。
【００１３】
該不織布を構成するポリウレタン樹脂は、常法に従って、脂肪族ジイソシアネート、及び／又は芳香族ジイソシアネート、高分子ジオール及び鎖延長剤を用いて製造されればよく、特に、これら構成成分は限定されない。ただし、高分子ジオールとして、メチル基側鎖を１個以上持つものを使用した場合に、低温柔軟性に優れた製品を得ることができることがわかっている。なお、低温柔軟性は、常温における硬さと低温時における硬さの変化で評価でき、低温での硬さが上昇するものは、風合が悪化して好ましくない。
【００１４】
なお、不織布を構成する熱可塑性ポリウレタン樹脂に、無機系ワックス、有機系ワックス、プロティン粉末、その他の加工性助剤や、特性改善のために酸化防止剤、紫外線防止剤、帯電防止剤、有機可塑剤、他の熱可塑性樹脂、着色料、艶消剤等を添加されてもよい。
【００１５】
本発明の装飾シートは、このような不織布に種々の装飾片を、該不織布のホットメルト性により融着させて形成されるものであるが、装飾片は、基材上に載置された不織布上に載置され、その上に離型性あるシートを置き、加熱加圧されることによって、不織布表面に接着される。
【００１６】
装飾片は、ポプリ、花びら、金属箔及び色箔等の細片状のものであっても、また、造花や折り紙等の多少立体的なものであってもよい。いずれにしても、本発明では、装飾片が、不織布上に、不織布を構成するフィラメントのホットメルト接着性で網目状に接着されるため、接着力に優れたものでありながら、非常に風合のよいものとなる。また、不織布自体の伸縮性も保持されるのである。
【００１７】
かかる本発明の装飾シートは、装飾片を表面に有する不織布状でそのまま使用れてもよいが、装飾片を有する面を外側にして不織布を他の布帛に積層一体化したものや、又は装飾片を有する面を内側にして不織布を他の布帛に積層一体化したものとされてもよい。また、不織布すなわち熱可塑性ポリウレタン樹脂からなるホットメルト接着性不織布を２枚積層し、その間に装飾片が位置するようにしてもよい。なお、本発明で使用する不織布は、柔軟にして伸縮性及び通気性を有するため、積層される上記布帛として、トリコットやジョーゼット等を使用しても、その風合を保持した状態で、非常に扱い易い装飾シートに形成できる。
【００１８】
また、本発明の装飾シートは、そのまま、スカーフやカーテン、テーブルクロス等として直接使用されてもよいが、装飾片を接着した不織布は、なおホットメルト接着性を有するので、不織布の面を種々の基材上に置き、加熱加圧することによって、該基材に装飾シートをアップリケ状に貼着して使用することも可能である。例えば、帽子の装飾やウエディングドレス等の装飾に、本発明の装飾シートを使用することもできるのである。
【００１９】
【発明の実施の形態】
次に、本発明を実施例に従って更に詳しく説明するが、実施例で使用した不織布は製造例１及び２で製造されたものである。
なお、製造例及び実施例に示す物性は、下記の方法で測定した。
(1) 硬さ
ペレットを射出成形機にて成形して得た試験片を、２３℃、５０％ＲＨの条件でＪＩＳ Ｋ７３１１に準じて測定した。
(2) 流動開始温度
島津高化式フローテスターＣＦＴ−５００を使用し、一定の割合で昇温した試験片が固体からゴム弾性域を経て流動域に至るまでの過程を連続的に測定して、ノズルより流れ出す温度を求めた（荷重：１０ｋｆｇ、ノズル：１mmφ×１mmＬで実施）。
(3) 剛軟度
試験片２cm×１５cmをＪＩＳ Ｌ１０９６（カンチレバー法）に準じて測定した。
【００２０】
不織布の製造例１
アジペート系ポリエステルポリオール、アミドワックス系滑剤、耐候剤、１，４−ブタンジオール、及び１，６−ヘキサメチレンジイソシアネートから得た熱可塑性ポリウレタン樹脂、硬さ（ＪＩＳ−Ａ硬度）８５度及び流動開始温度１０４℃を加熱溶融後、紡糸温度２０５℃にて0.５φのオリフィスが１０００穴１mmピッチで１列に配列されたメルトブローンノズルから吐出し、スリット幅0.５mmのエアースリットから２０５℃の加熱エアーを噴射して細化された繊維をその下方３０cmを走行するテフロンコーティング金網のベルトコンベア上に捕集し、自己の持つ熱で融着させ、目付け３５ｇ／ｍ2 と５０ｇ／ｍ2 の不織布を得た。なお、これらの不織布は、繊維径は２０μｍであり、１００％伸長時の回復率が８０％以上、剛軟度が３５mm以下である柔軟にして伸縮性あるものであった。
【００２１】
不織布の製造例２
ポリブチレンアジペート、ポリ３−メチル−１，５−ペンタンアジペート、アミドワックス系滑剤、耐候剤、触媒ジブチル錫ジラウレート、１，４−ブタンジオール及び１，６−ヘキサメチレンジイソシアネートから得た熱可塑性ポリウレタン樹脂を押出機にて１６０℃で押し出しペレットを得た。このペレットの硬さは８０で、流動開始温度は９７℃であった。これを用いて、実施例１と同様５０ｇ／ｍ2 の接着性不織布を得た。
この不織布は、繊維径が２０μｍで、引っ張り強度は縦３２０ｇｆ／2.５cm、横３００ｇｆ／2.５cm、１００％伸長時回復率が８７％で剛軟度２２mmのソフトで伸縮性ある接着性不織布であった。
【００２２】
実施例１
離型性シート上に、製造例２で製造した不織布を置き、その上から花びらを散布し、これを更に離型性シートを覆い、１３０℃で加熱加圧して、不織布上に花びらが模様状に接着した装飾シートを得た。該装飾シートは、極薄の和紙に花びらが模様状に一体化されたような外観を有する、非常に柔軟で伸縮性あるものであった。
該装飾シートは、適当に裁断して、封筒上に置き、離型性あるシートを介してアイロン掛けすることによって、封筒を直接花びら模様を施した紙で製造したかのような外観に仕上げることができた。
【００２３】
実施例２
離型性シート上に製造例１で製造した不織布を置き、その上に箔片を散布し、ポリエステルジョーゼットで覆い、加熱加圧した。得られた製品は、ポリエステルジョーゼットの風合をそのまま有し、しかも不織布による極薄の和紙様繊維模様と箔片模様が幻想的に透視できる、非常に妙味ある外観の装飾シートとなった。
この装飾シートは、そのままテーブルクロスやカーテン等に使用してもよいが、装飾シートを適当な模様状に裁断して、不織布のホットメルト接着性を利用して、エプロンに貼着したところ、意匠性に優れた、耐洗濯性ある装飾性ある製品を得ることができた。
【００２４】
なお、製造例１で製造した厚さの異なる２枚の不織布で、同様の製品を製造し、これらを、市販のポリエステル製及びナイロン製のホットメルト不織布で製造したものと比較した。その結果を、表１に示す。
【００２５】
【表１】
【発明の効果】
本発明の装飾シートは、非常に風合よく使用できるものであり、しかも、所望に応じて、不織布のホットメルト性を利用して、種々の基材に任意に接着でき、該基材を装飾性及び機能性に優れた装飾物となしうるものである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a decorative sheet using a nonwoven fabric made of polyurethane resin.
[0002]
[Prior art]
Conventionally, in order to use a decorative piece such as potpourri for the design of a card or a packaging material, the decorative piece is provided between a thermoplastic polyurethane resin adhesive film having a mesh or a hole in the entire surface and a sheet base material such as cardboard. Has been proposed (Japanese Unexamined Patent Publication No. Hei 3-268893), but as a heat-adhesive film, a film made of polyethylene, polypropylene, polyamide, polystyrene or the like is used in a single layer or in a layered manner. The texture is poor and can be used for cards, but it cannot be used for designing fabrics and the like.
[0003]
On the other hand, as a hot melt nonwoven fabric, what consists of resin, such as ethylene-vinyl acetate copolymer (EVA), polyethylene-atactic polypropylene (APP), ethylene-ethyl acrylate copolymer (EEA), polyamide, polyester, is known, These are used for laminating the non-woven fabric and the adherend, and melting and bonding the non-woven fabric by heating. However, such non-woven fabric has poor chemical resistance, cleaning resistance, and heat resistance. Since it lacks flexibility, its use is limited and it has not been used for decoration.
[0004]
[Problems to be solved by the invention]
The present invention can adhere a decorative piece such as potpourri to a base material such as a thin knitted fabric without impairing the texture of the base material. It is an object to provide a decorative sheet that can be used as a decorative object.
[0005]
[Means for Solving the Problems]
In this invention, the said subject was solved by sticking decoration pieces, such as a potpourri, to the surface of the nonwoven fabric which consists of a thermoplastic polyurethane resin filament which has hot-melt-adhesive property with the said adhesiveness of a nonwoven fabric.
[0006]
That is, the present inventors can obtain a product excellent in flexibility, stretchability and breathability by producing a nonwoven fabric using a thermoplastic polyurethane resin. It is pleasant at normal temperature and can be used directly for clothing, etc., but when heated as necessary, it has been found that the filaments constituting the nonwoven fabric can be strongly bonded to any substrate. The present invention has been completed.
[0007]
The thermoplastic polyurethane resin constituting the nonwoven fabric preferably has a hardness (JIS-A hardness) measured according to JIS K7311 of 65 to 98 degrees and a flow start temperature of 80 to 150 ° C.
[0008]
If the hardness of the thermoplastic polyurethane resin is less than 65 degrees, it becomes difficult to produce a nonwoven fabric by hot forming. If it exceeds 98 degrees, the flexibility of the nonwoven fabric is lost and it is difficult to use for decoration such as clothing. It becomes. In addition, when the flow start temperature is less than 80 ° C, it becomes difficult to produce a nonwoven fabric by hot forming. Conversely, when the temperature exceeds 150 ° C, the flexibility of the nonwoven fabric is lost, and at the same time, discoloration during high temperature processing, etc. Occurs and becomes difficult to use for decoration.
[0009]
Here, the flow start temperature refers to a temperature at which the resin is heated at a constant heating rate, and the resin starts to melt and flow, and is usually measured with a Koka flow tester or the like. The flow initiation temperature is an important physical property that limits the bonding conditions, particularly the heating temperature, of the hot melt nonwoven fabric adhesive.
[0010]
Moreover, it is preferable that the fabric weight of a nonwoven fabric is about 10-70 g / m < 2 >. If the nonwoven fabric is too thin, it is difficult to handle, and if it is too thick, problems such as a resin film-like texture and appearance and poor air permeability are likely to occur. Further, the nonwoven fabric preferably has an elongation of 50% or more and an air permeability of 5 cc / cm 2 / second or more, and the fiber diameter of the filament constituting the nonwoven fabric is preferably 100 μm or less, particularly 50 μm or less.
[0011]
The nonwoven fabric has a bending resistance of 40 mm or less, particularly 35 mm or less as measured by a 45 degree cantilever method, as a decorative sheet, and feels good and easy to handle.
[0012]
The present invention utilizes the fact that the melt viscosity behavior of a thermoplastic polyurethane resin is sensitive to temperature. Conventionally, a thermoplastic polyurethane resin, which could only be made into a film, is made into a continuous filament, which is formed into a sheet-like shape. It is a non-woven fabric that is adhesive and rich in stretchability and breathability. The nonwoven fabric may be formed by a method in which a thermoplastic polyurethane resin is formed into a filament by a melt blow method and the filaments are fused to each other. For example, the resin is melted by heating with an extruder, then discharged from a melt blow nozzle at an appropriate spinning temperature, and sprayed with heated air from an air slit on a wire mesh belt conveyor that travels underneath. The fibers collected and collected on the belt conveyor in a planar shape can be manufactured by a method in which the fibers are fused to each other by their own heat to form a nonwoven fabric.
[0013]
The polyurethane resin constituting the nonwoven fabric may be produced by using an aliphatic diisocyanate and / or an aromatic diisocyanate, a polymer diol and a chain extender according to a conventional method, and these components are not particularly limited. However, it has been found that when a polymer diol having one or more methyl group side chains is used, a product excellent in low-temperature flexibility can be obtained. The low-temperature flexibility can be evaluated by a change in hardness at normal temperature and hardness at low temperature, and a material whose hardness at low temperature increases is not preferable because the texture deteriorates.
[0014]
It should be noted that the thermoplastic polyurethane resin constituting the nonwoven fabric is added to inorganic wax, organic wax, protein powder, other processability aids, antioxidants, UV inhibitors, antistatic agents, organic plastics to improve properties. Agents, other thermoplastic resins, colorants, matting agents and the like may be added.
[0015]
The decorative sheet of the present invention is formed by fusing various decorative pieces to such a nonwoven fabric by the hot melt property of the nonwoven fabric. The decorative piece is a nonwoven fabric placed on a substrate. The sheet is placed on the sheet, and a sheet having a releasability is placed on the sheet and heated and pressed to adhere to the surface of the nonwoven fabric.
[0016]
The decorative piece may be in the form of strips such as potpourri, petals, metal foil, and colored foil, or may be somewhat three-dimensional such as artificial flowers or origami. In any case, in the present invention, the decorative piece is bonded on the nonwoven fabric in a mesh shape with the hot-melt adhesiveness of the filaments constituting the nonwoven fabric. It will be good. Further, the stretchability of the nonwoven fabric itself is also maintained.
[0017]
Such a decorative sheet of the present invention may be used as it is in the form of a non-woven fabric having decorative pieces on its surface, but the non-woven fabric is laminated and integrated with another fabric with the surface having the decorative pieces on the outside, or the decorative pieces The non-woven fabric may be laminated and integrated with another fabric with the surface having the inner side facing inward. Further, two non-woven fabrics, that is, two hot-melt adhesive nonwoven fabrics made of thermoplastic polyurethane resin may be laminated, and the decorative piece may be positioned between them. In addition, since the nonwoven fabric used in the present invention is flexible and has stretchability and air permeability, even if tricot or georgette is used as the above-mentioned fabric to be laminated, It can be formed into a decorative sheet that is easy to handle.
[0018]
In addition, the decorative sheet of the present invention may be used directly as a scarf, curtain, table cloth or the like, but the nonwoven fabric to which the decorative piece is bonded still has hot-melt adhesiveness, so the surface of the nonwoven fabric can be used in various ways. By placing on a base material and heating and pressurizing, the decorative sheet can be attached to the base material in the form of an applique and used. For example, the decorative sheet of the present invention can be used for decorations such as hat decorations and wedding dresses.
[0019]
DETAILED DESCRIPTION OF THE INVENTION
Next, although this invention is demonstrated in more detail according to an Example, the nonwoven fabric used in the Example is manufactured by the manufacture examples 1 and 2. FIG.
In addition, the physical property shown to a manufacture example and an Example was measured with the following method.
(1) A test piece obtained by molding a hardness pellet with an injection molding machine was measured according to JIS K7311 under the conditions of 23 ° C. and 50% RH.
(2) Flow start temperature Using a Shimadzu Koka-type flow tester CFT-500, continuously measure the process from when the test piece heated at a certain rate passes from the solid to the flow region through the rubber elastic region. The temperature flowing out from the nozzle was determined (load: 10 kfg, nozzle: 1 mmφ × 1 mmL).
(3) A 2 cm × 15 cm bending resistance test piece was measured according to JIS L1096 (cantilever method).
[0020]
Nonwoven Fabric Production Example 1
Thermoplastic polyurethane resin obtained from adipate polyester polyol, amide wax lubricant, weathering agent, 1,4-butanediol, and 1,6-hexamethylene diisocyanate, hardness (JIS-A hardness) 85 degrees and flow initiation temperature After heating and melting at 104 ° C, a 0.5φ orifice was discharged from a melt blown nozzle arranged in a row with a pitch of 1000mm at 1mm pitch at a spinning temperature of 205 ° C, and heated air at 205 ° C from an air slit with a slit width of 0.5mm. The thinned fiber is collected on a Teflon-coated wire mesh belt conveyor that runs 30 cm below it, and is fused with its own heat to form a nonwoven fabric with a basis weight of 35 g / m 2 and 50 g / m 2 . Obtained. These nonwoven fabrics were flexible and stretchable with a fiber diameter of 20 μm, a recovery rate at 100% elongation of 80% or more, and a bending resistance of 35 mm or less.
[0021]
Non-woven fabric production example 2
Thermoplastic polyurethane resin obtained from polybutylene adipate, poly-3-methyl-1,5-pentane adipate, amide wax lubricant, weathering agent, catalyst dibutyltin dilaurate, 1,4-butanediol and 1,6-hexamethylene diisocyanate Was extruded at 160 ° C. with an extruder to obtain pellets. The pellets had a hardness of 80 and a flow start temperature of 97 ° C. Using this, an adhesive nonwoven fabric of 50 g / m 2 was obtained in the same manner as in Example 1.
This non-woven fabric has a fiber diameter of 20 μm, a tensile strength of 320 gf / 2.5 cm in length, 300 gf / 2.5 cm in width, a recovery rate at 100% elongation of 87%, and a soft and stretchable adhesive non-woven fabric with a stiffness of 22 mm. Met.
[0022]
Example 1
Place the non-woven fabric produced in Production Example 2 on the releasable sheet, spray the petals on it, cover the releasable sheet further, heat and press at 130 ° C, and the petals are patterned on the non-woven fabric. A decorative sheet adhered to was obtained. The decorative sheet was very flexible and stretchable with an appearance that petals were integrated in a pattern on ultrathin Japanese paper.
The decorative sheet is appropriately cut, placed on the envelope, and ironed through a releasable sheet to finish the envelope as if it were made of paper with petal pattern directly. I was able to.
[0023]
Example 2
The non-woven fabric produced in Production Example 1 was placed on the releasable sheet, and foil pieces were sprayed thereon, covered with a polyester georgette, and heated and pressurized. The obtained product had a texture of polyester georgette as it was, and it became a decorative sheet with a very delicious appearance in which an ultrathin Japanese paper-like fiber pattern and a foil piece pattern made of non-woven fabric could be fantastically seen through.
This decorative sheet may be used as it is for a table cloth, a curtain, etc., but when the decorative sheet is cut into an appropriate pattern and applied to the apron using the hot melt adhesive property of the nonwoven fabric, A decorative product with excellent washability and washing resistance could be obtained.
[0024]
In addition, the same product was manufactured with two nonwoven fabrics with different thicknesses manufactured in Production Example 1, and these were compared with those manufactured with commercially available polyester and nylon hot melt nonwoven fabrics. The results are shown in Table 1.
[0025]
[Table 1]
【The invention's effect】
The decorative sheet of the present invention can be used very well, and can be arbitrarily bonded to various substrates by utilizing the hot melt property of the nonwoven fabric as desired. It can be used as a decorative product having excellent properties and functionality.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14656898A JP3854997B2 (en) | 1998-05-11 | 1998-05-11 | Decorative sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14656898A JP3854997B2 (en) | 1998-05-11 | 1998-05-11 | Decorative sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11320800A JPH11320800A (en) | 1999-11-24 |
| JP3854997B2 true JP3854997B2 (en) | 2006-12-06 |
Family
ID=15410632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14656898A Expired - Lifetime JP3854997B2 (en) | 1998-05-11 | 1998-05-11 | Decorative sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3854997B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161309A (en) * | 2010-02-24 | 2011-08-24 | 丰田合成株式会社 | Sealing strip and manufacture method thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4828110B2 (en) * | 2004-10-18 | 2011-11-30 | ブリヂストン化成品株式会社 | Manufacturing method of laminated body of leather and urethane foam |
| US8850719B2 (en) | 2009-02-06 | 2014-10-07 | Nike, Inc. | Layered thermoplastic non-woven textile elements |
| US8906275B2 (en) | 2012-05-29 | 2014-12-09 | Nike, Inc. | Textured elements incorporating non-woven textile materials and methods for manufacturing the textured elements |
| US20100199406A1 (en) | 2009-02-06 | 2010-08-12 | Nike, Inc. | Thermoplastic Non-Woven Textile Elements |
| US9682512B2 (en) | 2009-02-06 | 2017-06-20 | Nike, Inc. | Methods of joining textiles and other elements incorporating a thermoplastic polymer material |
| JP5129178B2 (en) * | 2009-02-23 | 2013-01-23 | 株式会社アデランス | wig |
| US20130255103A1 (en) | 2012-04-03 | 2013-10-03 | Nike, Inc. | Apparel And Other Products Incorporating A Thermoplastic Polymer Material |
-
1998
- 1998-05-11 JP JP14656898A patent/JP3854997B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161309A (en) * | 2010-02-24 | 2011-08-24 | 丰田合成株式会社 | Sealing strip and manufacture method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11320800A (en) | 1999-11-24 |
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