JP3802130B2 - Manufacturing method of rubber crawler - Google Patents

Manufacturing method of rubber crawler Download PDF

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Publication number
JP3802130B2
JP3802130B2 JP11581196A JP11581196A JP3802130B2 JP 3802130 B2 JP3802130 B2 JP 3802130B2 JP 11581196 A JP11581196 A JP 11581196A JP 11581196 A JP11581196 A JP 11581196A JP 3802130 B2 JP3802130 B2 JP 3802130B2
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Japan
Prior art keywords
rubber
rubber crawler
vulcanized
crawler
bonded
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Expired - Lifetime
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JP11581196A
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Japanese (ja)
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JPH09277967A (en
Inventor
靖章 藤田
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Bridgestone Corp
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Bridgestone Corp
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Priority to JP11581196A priority Critical patent/JP3802130B2/en
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Description

【0001】
【発明の属する技術分野】
本発明はゴムクロ−ラのエンドレス成型作業が容易となると共に、有端状加硫時に従来必要としていたエンドレス部の冷却装置が不要となるゴムクロ−ラの製造方法にかかるものである。
【0002】
【従来の技術】
従来のゴムクロ−ラは、芯金、スチ−ルコ−ド等が埋設されたゴムクロ−ラ基体を平板状にて加硫しその後ゴムクロ−ラ基体の両端を接着して無端状ゴムクロ−ラとしていた。円環状の加硫装置によって最初から無端状に加硫することも考えられるが、周長の大きなゴムクロ−ラにあっては加硫装置が大型化するため、ほとんど使用されていないのが実情である。
【0003】
従来のゴムクロ−ラを無端状のものとする接着方法としては、接着する部分を加硫時に冷却して未加硫の状態で残し、最後にこの未加硫ゴム部分を張り合せて再度エンドレス部成形用モ−ルドにセットしなおして加硫接着する方法があり、又、接着する部分を未加硫の状態で残さず加硫してしまいその加硫表面をバフ加工した後、該当表面にゴムのりを塗布し、その上に未加硫ゴムを重ね合わせて加硫接着する方法等がある。
【0004】
【発明が解決しようとする課題】
しかるに、前者の接着部分を未加硫で残す方法では、両端接着部分を未加硫で残した板状のゴムクロ−ラ基体を成形モ−ルド内から取り外し、再度エンドレス加硫機のモ−ルド内にセットする作業が必要となる。従って、モ−ルド内からの脱型が難しく、又、未加硫ゴム部のベタつきにより未加硫部分の取扱いが難しかった。
【0005】
特に未加硫で残された両端接着部分にスチ−ルコ−ドや芯金が埋設されているので、エンドレス加工機のモ−ルドに再セットする時には、ゴム中でそれらのスチ−ルコ−ドや芯金がみだれないように取扱いには十分な注意が必要である。そして接着部分を冷却するための冷却装置が必要となることにより設備が複雑になっていた。
【0006】
又、後者の接着部分を加硫後バフがけする方法では、バフ加工した際に発生するバフ粉末を完全に除去することが困難であり、これにより完全な接着を得ることが難しい問題がある。又、ゴムのりを塗布する場合は有機溶剤による作業環境の悪化という問題も生ずる。
【0007】
【課題を解決するための手段】
本発明は上記の課題を解決するために次の構成を採用したものである。即ち、請求項1記載の発明は、ゴムクロ−ラ基体を有端状にて加硫しその後両端を接着して無端状にするゴムクロ−ラの製造方法であって、前記有端状ゴムクロ−ラ基体の両端の接着に供される面に、該接着面側に凹凸を有しかつ加硫後に前記接着面からの剥離が容易なシ−ト材料を重ね合わせ、その状態にてゴムクロ−ラ基体を加硫し、次いでゴムクロ−ラ基体の両端を接着する直前に前記シ−ト材料を剥して接着面を露出させ、当該接着面間にゴムクロ−ラ基体の接着面における硫黄量よりも硫黄量の多い未加硫ゴムを介在させ、この未加硫ゴムを加硫し無端状にすることを特徴とするゴムクロ−ラの製造方法である。
【0008】
そして、好ましくは、硫黄量の差が1〜10PHRの範囲であるゴムクロ−ラの製造方法にかかるものである。
【0009】
【発明の実施の形態】
本発明にあっては、無端状ゴムクロ−ラを製造するに際して、有端のゴムクロ−ラ基体の接着する部分に、予め加硫する前にその接着部分の面に少なくとも片面に凹凸を持ち加硫ゴムとの剥離が容易なシ−ト材料を重ね合わせた状態にした上で加硫を行い、その後にその部分の両者を接着する直前に該シ−ト材料を剥してブリ−ドのない新鮮な面を露出し、両接着面間に接着用ゴムとして互いに接着するゴムの硫黄量よりも硫黄量の多い未加硫ゴムを挟み込んだ状態で加硫接着させるものである。
【0010】
本発明は、従来の技術にて行われているバフ加工という作業を接着する直前にシ−ト材料を剥し、接着技術上新鮮な面を露出させるという作業によって省略され、バフ粉末を除去するという作業もなくなり、完全な接着を得ることが容易となる。又、バフ加工をしないことからゴムのりを塗布する必要もなくなり作業環境の改善ともなる。又、接着部分を冷却せずに加硫してしまうことにより、モ−ルドからの脱型や接着部分の取扱が容易になり、更に接着部分を冷却するための冷却装置が不要となるという特徴もある。
【0011】
シ−ト材料は例えばPET製の帆布であり、Rmax が1〜5000μm、好ましくは20〜200μmのものを使用することにより、シ−ト材料が剥されたゴムの表面は丁度バフ加工した時のような適度の凹凸が容易に得られ、バフ加工等によるバフ粉末等の汚れも無くきれいな状態のものが得られる。この凹凸は加硫時にいわゆるアンカ−効果がもたらされるものであって、その分接着力が高められることになる。尚、シ−ト材料、例えばPET製の帆布が伸縮性のある帆布であってもよい。
【0012】
通常のモ−ルド成形による加硫ゴム表面には時間と共にオイル、ワックス、老化防止剤等のゴム配合物がブリ−ドし接着を阻害する要因となるが、本発明にあっては、接着の直前にシ−ト材料を剥すことにより、該接着される面が清浄な面即ちブリ−ドレスの状態として容易に得られ、接着力を十分保証することができることになる。
【0013】
更に、接着用ゴムとして、ゴムクロ−ラ本体の加硫ゴムと比較して硫黄量の多いゴム、特に硫黄量の差が1〜10PHRのゴムを使用することによって、より接着力の強いものが得られる。硫黄量が同等或いはそれより少なければ接着ゴム側から加硫ゴム側への硫黄の移行により弾性率の低下を引き起こして接着力の低下を招くことになり、一方、硫黄量の差が10PHRを越えた場合は接着ゴムの物性低下を招き、これ又接着力の低下につながることになる。
特にゴムクロ−ラの場合、接着面の部位によって硫黄量の差を変えた未加硫ゴムを用いることによりより接着力の強いものが得られる。例えば、接着ゴムの厚みが厚い場合には上記範囲の硫黄量の中で少なめの硫黄量の差とし、接着ゴムの厚みが薄い場合には硫黄量の差を多めとすることが好ましい。
【0014】
【実施例】
以下、本発明について実施例により更に説明する。
[実施例1]
ゴムクロ−ラを構成する未加硫ゴムを加硫する際、無端状とするために後で接着する部分、即ち接着予定部分にPET製帆布[オックス帆布](250D/1(203本/5cm)x250D/2(122本/5cm))を貼り付け、この状態で加硫する。加硫後、接着直前に上記帆布を引き剥し、更に接着ゴムとして硫黄量6PHR配合したものを加硫ゴム/加硫ゴム間に挿入して接着した。
【0015】
[実施例2]
接着ゴムとして硫黄量2PHRのものを用いたこと以外は実施例1と同様にしてゴムクロ−ラを得た。
【0016】
[比較例1]
上記実施例1において、帆布を用いず接着面をバフ加工及びゴムセメントを塗布した以外は実施例1と同様にしてゴムクロ−ラを得た。
【0017】
[比較例2]
上記実施例1において、帆布を適用せず、接着面をモ−ルド面としたこと以外は実施例1と同様にしてゴムクロ−ラを得た。
【0018】
[比較例3]
接着ゴムとして、硫黄量13PHRのものを用いた以外は実施例1と同様にしてゴムクロ−ラを得た。
【0019】
上記、実施例及び各比較例により得たゴムクロ−ラについて、その接着面の強度及び疲労強度試験を行った。この結果を表1に示す。
【0020】
【表1】

Figure 0003802130
【0021】
接着試験としては、加硫ゴム間に0.5mmtの厚さの接着ゴムを挟み、加硫する。得られたゴムクロ−ラをスライサ−により2mmtの厚さのサンプルとした。このサンプルからJIS−K6301規格により引張強度(接着強度)、及び疲労
強度(0〜100%伸張繰り返し回数)を測定した。尚、本実施例、比較例におい
て使用したゴムクロ−ラの加硫ゴム組成及び接着ゴム組成の処方は表2に示す。
【0022】
【表2】
Figure 0003802130
【0023】
【発明の効果】
本発明は以上の構成を採用したことによりゴムクロ−ラのエンドレス成型作業が容易となり、更にエンドレス部の冷却装置が不要となるため設備が簡便安価となった。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method of manufacturing a rubber crawler that facilitates endless molding of a rubber crawler and eliminates the need for a cooling device for an endless portion that was conventionally required during end-capped vulcanization.
[0002]
[Prior art]
In the conventional rubber crawler, an endless rubber crawler was formed by vulcanizing a rubber crawler base in which a core metal, steel cord, etc. were embedded in a flat plate shape, and then bonding both ends of the rubber crawler base. . Although it is conceivable to vulcanize endlessly from the beginning with an annular vulcanizer, in the case of a rubber crawler with a large circumference, the vulcanizer becomes larger, so it is rarely used. is there.
[0003]
The conventional rubber crawler has an endless structure. The part to be bonded is cooled at the time of vulcanization and left unvulcanized, and finally the unvulcanized rubber part is pasted together to endless part again. There is a method of re-setting to the molding mold and vulcanizing and bonding, and after vulcanizing all the parts to be bonded in an unvulcanized state and buffing the vulcanized surface, There is a method in which a rubber paste is applied, and an unvulcanized rubber is overlaid thereon and vulcanized and bonded.
[0004]
[Problems to be solved by the invention]
However, in the former method in which the bonded portion is left uncured, the plate-shaped rubber crawler base with the two-sided bonded portions left uncured is removed from the molding mold, and again the endless vulcanizer mold. Work to set in is required. Therefore, it is difficult to remove the mold from the mold, and it is difficult to handle the unvulcanized part due to the stickiness of the unvulcanized rubber part.
[0005]
In particular, steel cords and metal cores are embedded in the uncured left-end bonded parts, so when re-setting them to the endless processing machine mold, these steel cords are in rubber. Care must be taken in handling so that no metal cores can be seen. And the installation became complicated by the need of a cooling device for cooling the bonded portion.
[0006]
Further, in the latter method of buffing the bonded portion after vulcanization, it is difficult to completely remove the buff powder generated during the buffing process, and thus there is a problem that it is difficult to obtain complete bonding. In addition, when a rubber paste is applied, there is a problem that the working environment is deteriorated by an organic solvent.
[0007]
[Means for Solving the Problems]
The present invention employs the following configuration in order to solve the above problems. That is, the invention according to claim 1 is a method of manufacturing a rubber crawler in which a rubber crawler substrate is vulcanized in an end shape and then bonded at both ends to make it endless. On the surface used for bonding at both ends of the substrate, a sheet material that has unevenness on the bonding surface side and that can be easily peeled off from the bonding surface after vulcanization is overlaid, and in this state, the rubber crawler substrate Then, immediately before bonding the both ends of the rubber crawler substrate, the sheet material is peeled off to expose the bonding surface, and the sulfur content is higher than the sulfur content on the bonding surface of the rubber crawler substrate between the bonding surfaces. This is a method for producing a rubber crawler, characterized in that a large amount of unvulcanized rubber is interposed, and the unvulcanized rubber is vulcanized to be endless.
[0008]
And preferably, it is based on the manufacturing method of the rubber crawler whose difference of sulfur amount is the range of 1-10PHR.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
In the present invention, when producing an endless rubber crawler, the portion to be bonded to the end of the rubber crawler substrate is vulcanized at least on one side of the surface of the bonded portion before vulcanization in advance. A sheet material that can be easily peeled off from rubber is laid on top of each other and then vulcanized, and then the sheet material is peeled off immediately before bonding the two parts together to remove the fresh material without a blade. In this state, the unvulcanized rubber having a sulfur amount larger than the sulfur amount of the rubber bonded to each other as an adhesive rubber is sandwiched between the two adhesive surfaces and vulcanized and bonded.
[0010]
The present invention eliminates the buff powder by removing the sheet material immediately before bonding the work of buffing performed in the prior art and exposing the fresh surface in the bonding technique. There is no work, and it is easy to obtain complete adhesion. In addition, since no buffing is performed, it is not necessary to apply rubber glue, which improves the working environment. In addition, vulcanization without cooling the bonded part makes it easy to remove the mold from the mold and handle the bonded part, and further eliminates the need for a cooling device for cooling the bonded part. There is also.
[0011]
The sheet material is, for example, a canvas made of PET, and when the R max is 1 to 5000 μm, preferably 20 to 200 μm, the surface of the rubber from which the sheet material has been peeled is just buffed. As a result, moderate irregularities such as the above can be easily obtained, and there can be obtained a clean state without contamination such as buffing powder by buffing or the like. This unevenness brings about a so-called anchor effect at the time of vulcanization, and the adhesive force is increased accordingly. Note that a sheet material such as a canvas made of PET may be a stretchable canvas.
[0012]
A rubber compound such as oil, wax, anti-aging agent, etc. will bleed on the surface of the vulcanized rubber by the usual mold molding over time, and it will be a factor that inhibits adhesion. By peeling off the sheet material immediately before, the surface to be bonded can be easily obtained as a clean surface, that is, a state of a bridgeless, and the adhesive force can be sufficiently ensured.
[0013]
Further, as the adhesive rubber, a rubber having a higher adhesive strength can be obtained by using a rubber having a larger amount of sulfur compared to the vulcanized rubber of the rubber track body, particularly a rubber having a difference in sulfur amount of 1 to 10 PHR. It is done. If the amount of sulfur is equal to or less than that, the transfer of sulfur from the adhesive rubber side to the vulcanized rubber side will cause a decrease in elastic modulus, leading to a decrease in adhesive strength, while the difference in sulfur amount exceeds 10 PHR. In this case, the physical properties of the adhesive rubber are reduced, and this also leads to a decrease in the adhesive strength.
In particular, in the case of a rubber crawler, a stronger adhesive strength can be obtained by using an unvulcanized rubber in which the difference in sulfur amount is changed depending on the part of the adhesive surface. For example, when the thickness of the adhesive rubber is large, it is preferable that the difference in sulfur amount is small in the above range, and when the thickness of the adhesive rubber is thin, the difference in sulfur amount is large.
[0014]
【Example】
Hereinafter, the present invention will be further described with reference to examples.
[Example 1]
When vulcanizing the unvulcanized rubber constituting the rubber crawler, PET canvas [Ox canvas] (250D / 1 (203 / 5cm) is attached to the part to be bonded later to make it endless, that is, the part to be bonded. x250D / 2 (122 pieces / 5 cm)) is pasted and vulcanized in this state. After vulcanization, the canvas was peeled off immediately before bonding, and an adhesive rubber blended with a sulfur amount of 6PHR was inserted between the vulcanized rubber / vulcanized rubber and bonded.
[0015]
[Example 2]
A rubber crawler was obtained in the same manner as in Example 1 except that an adhesive rubber having a sulfur content of 2 PHR was used.
[0016]
[Comparative Example 1]
In Example 1 above, a rubber crawler was obtained in the same manner as in Example 1 except that the canvas was not used and the adhesive surface was buffed and rubber cement was applied.
[0017]
[Comparative Example 2]
A rubber crawler was obtained in the same manner as in Example 1 except that the canvas was not applied and the adhesive surface was changed to a mold surface.
[0018]
[Comparative Example 3]
A rubber track was obtained in the same manner as in Example 1 except that an adhesive rubber having a sulfur content of 13 PHR was used.
[0019]
The rubber crawlers obtained in the above examples and comparative examples were subjected to strength and fatigue strength tests on the bonded surfaces. The results are shown in Table 1.
[0020]
[Table 1]
Figure 0003802130
[0021]
As an adhesion test, an adhesive rubber having a thickness of 0.5 mmt is sandwiched between vulcanized rubbers and vulcanized. The obtained rubber crawler was used as a sample having a thickness of 2 mm by a slicer. From this sample, tensile strength (adhesive strength) and fatigue strength (0-100% number of repeated stretches) were measured according to JIS-K6301 standards. Table 2 shows the formulations of the vulcanized rubber composition and adhesive rubber composition of the rubber crawler used in this example and comparative example.
[0022]
[Table 2]
Figure 0003802130
[0023]
【The invention's effect】
By adopting the above-described configuration, the present invention facilitates endless molding work of the rubber crawler, and further eliminates the need for a cooling device for the endless part, thus making the equipment simple and inexpensive.

Claims (2)

ゴムクロ−ラ基体を有端状にて加硫しその後両端を接着して無端状にするゴムクロ−ラの製造方法であって、前記有端状ゴムクロ−ラ基体の両端の接着に供される面に、該接着面側に凹凸を有しかつ加硫後に前記接着面からの剥離が容易なシ−ト材料を重ね合わせ、その状態にてゴムクロ−ラ基体を加硫し、次いでゴムクロ−ラ基体の両端を接着する直前に前記シ−ト材料を剥して接着面を露出させ、当該接着面間にゴムクロ−ラ基体の接着面における硫黄量よりも硫黄量の多い未加硫ゴムを介在させ、この未加硫ゴムを加硫し無端状にすることを特徴とするゴムクロ−ラの製造方法。  A method for producing a rubber crawler in which a rubber crawler substrate is vulcanized in an end shape and thereafter bonded at both ends to be endless, and the surface used for adhering both ends of the end rubber rubber substrate In addition, a sheet material that has irregularities on the bonding surface side and is easy to peel off from the bonding surface after vulcanization is overlaid, and in this state, the rubber track substrate is vulcanized, and then the rubber track substrate Immediately before adhering both ends of the sheet, the sheet material is peeled to expose the bonding surface, and an unvulcanized rubber having a sulfur amount higher than the sulfur amount in the bonding surface of the rubber track substrate is interposed between the bonding surfaces. A method for producing a rubber crawler, characterized in that the unvulcanized rubber is vulcanized to be endless. 硫黄量の差が1〜10PHRの範囲である請求項第1項記載のゴムクロ−ラの製造方法。  2. The method for producing a rubber crawler according to claim 1, wherein the difference in the amount of sulfur is in the range of 1 to 10 PHR.
JP11581196A 1996-04-12 1996-04-12 Manufacturing method of rubber crawler Expired - Lifetime JP3802130B2 (en)

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