JP3726330B2 - Washing machine - Google Patents

Washing machine Download PDF

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Publication number
JP3726330B2
JP3726330B2 JP03942696A JP3942696A JP3726330B2 JP 3726330 B2 JP3726330 B2 JP 3726330B2 JP 03942696 A JP03942696 A JP 03942696A JP 3942696 A JP3942696 A JP 3942696A JP 3726330 B2 JP3726330 B2 JP 3726330B2
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JP
Japan
Prior art keywords
water
tap water
water supply
free chlorine
molded body
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JP03942696A
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Japanese (ja)
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JPH09225181A (en
Inventor
守記 福田
俊次 今井
眞一 熊谷
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Panasonic Corp
Panasonic Holdings Corp
Original Assignee
Panasonic Corp
Matsushita Electric Industrial Co Ltd
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Priority to JP03942696A priority Critical patent/JP3726330B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は、洗濯槽に給水する水または洗濯液中に含まれる遊離塩素を除去できるようにした洗濯機に関するものである。
【0002】
【従来の技術】
従来、洗濯機に給水する水道水中の残留遊離塩素を除去する技術は、特開平02−136170号公報、特開平06−154474号公報、特開平06−238092号公報などに記載されたものが知られている。
【0003】
図5は特開平02−136170号公報に記載されているもので、給水ホース1を接続した給水弁2に内部ホース3を接続し、この内部ホース3に給水経路切換部4を接続し、この給水経路切換部4により遊離塩素除去材を充填したカートリッジ(図示せず)を内蔵した残留遊離塩素除去装置5を通して、残留遊離塩素を除去した水道水を給水口6から水槽内に給水できるように構成している。
【0004】
図6は特開平06−154474号公報に記載されているもので、給水ホース1を2連給水弁7に接続し、この2連給水弁7の一方に遊離塩素除去材8を充填したカートリッジ9を内蔵した残留遊離塩素除去装置10を接続し、残留遊離塩素除去装置10の流入口11より入った水道水を遊離塩素除去材8を通して流出口12より出し、残留遊離塩素を除去した水道水を給水口6から水槽内に給水できるように構成している。
【0005】
また、図7は特開平06−238092号公報に記載されているもので、給水弁2に接続した内部ホース3を通して給水する給水経路に、遊離塩素除去剤8を充填したカートリッジ13を収納するフィルターケース14を引き出し状に着脱自在に取り付け、フィルターケース14を装着時には水槽内へ残留遊離塩素を除去した水道水を給水する構成としている。
【0006】
【発明が解決しようとする課題】
特開平02−136170号公報、特開平06−154474号公報に記載された構成では、残留遊離塩素を除去した水道水を水槽内に給水するために、給水経路を完全に切り換えることにより、すべての給水が充填されている遊離塩素除去材中を通過させることと、緻密に充填した遊離塩素除去材中を通過させるために水圧を付加することが必要である。
【0007】
さらに、還元剤を使用したカートリッジ方式では、還元剤としては還元作用を有する粉末の亜硫酸カルシウムを主成分とし、水に難溶性のエチルセルロース等をバインダー(結合剤)として粒状化したものが使用されていた。この結果、反応機構の原理は、残留遊離塩素が亜硫酸カルシウムの粒状体表面に接触して反応するものであった。
【0008】
また、粒状体を充填した構成では、水の通りやすい部分と通りにくい部分を生じ易く、水圧を付加した状態で使用していると、水の通りやすい部分が他の部分よりも多くの残留遊離塩素と反応するために消費して、有効成分を多く残したままショートパスを生じて残留遊離塩素が漏れだして寿命となっていた。
【0009】
また、活性炭を使用したカートリッジでは、水道水中に含まれる異物による目詰まりから、流量低下を生じるとともに、活性炭中を通過する流速が増して吸着能力を越えるために残留遊離塩素が徐々に漏れだして寿命となる。
【0010】
いずれの場合においても、使用者が外から寿命を知ることは不可能なために、使用回数などから寿命を予測して報知することも要求される。
【0011】
つぎに、特開平06−238092号公報に記載された構成では、残留遊離塩素を除去した水道水を水槽内に給水するために、カートリッジを収納したフィルターケースを装着したその部分において、水道水中に含まれる残留遊離塩素を除去するには、難溶性の還元剤では水道水との高い接触効率(広い接触面積)が要求されている。このことから、使用中に徐々に接触面積が小さくなり、同様に使用者が外から寿命を知ることは不可能なために、使用回数などから寿命を予測して報知することも要求される。
【0012】
また、昜溶解性の還元剤では洗濯行程からすすぎ行程の各行程にわたって所定量の還元剤を水道水中に供給することは不可能であった、あまり過剰の還元剤が洗濯液中にあると還元作用により色柄物(染料)に変色を生じさせるために、ほぼ所定量の溶出に制御することが要求される。
【0013】
本発明は、予め設定した所定量の還元剤を水道水中にあるいは洗濯液中に分散または溶解し、還元剤と残留遊離塩素を完全にかつ迅速に酸化還元反応させて除去し、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化等を防止することを目的としている。
【0014】
本発明は上記課題を解決するもので、給水液中に予め設定したほぼ一定量の還元剤を溶出させて、還元剤を配設した部位以降の給水経路途中と水槽内で、給水した水道水に含まれる残留遊離塩素と酸化還元反応を生じさせることにより、残留遊離塩素を完全に、かつ迅速に除去するとともに、還元剤の交換または補給時期がわかるようにすることを目的としている。
【0015】
【課題を解決するための手段】
本発明の洗濯機においては、洗濯槽と、給水経路を介して前記洗濯槽内に水道水を供給する給水弁と、水道水に含まれる遊離塩素を還元する微粒子の還元剤を水に徐溶性の結合剤により固結した成形体と、前記成形体を収納し内外を連通する穴を設けた収納ケースとを備え、前記収納ケースは、前記給水経路途中に配設され前記給水弁からの水道水が前記収納ケース内の成形体の表面を経由することで、前記水に徐溶性の結合剤が溶解し、前記還元剤が前記水道水内に分散放出され前記水道水とともに前記洗濯槽内へ供給されるように構成したものである。
【0016】
これにより、従来例のように、完全に給水経路を切り換えたり、カートリッジに水圧を付加する必要もなく、また、フィルターケースを装着した部分で、水道水中に含まれる残留遊離塩素を除去するために、水道水との高い接触効率が要求されることもなく、給水液中に予め設定したほぼ一定量の還元剤を溶出させて、還元剤を配設した部位以降の給水経路途中と水槽内で、給水した水道水に含まれる残留遊離塩素と酸化還元反応を生じさせることにより、残留遊離塩素を完全に、かつ迅速に除去することができるとともに、還元剤の交換または補給時期についても使用者が容易に知ることができる。
【0017】
【発明の実施の形態】
本発明の請求項1に記載の発明は、洗濯槽と、給水経路を介して前記洗濯槽内に水道水を供給する給水弁と、水道水に含まれる遊離塩素を還元する微粒子の還元剤を水に徐溶性の結合剤により固結した成形体と、前記成形体を収納し内外を連通する穴を設けた収納ケースとを備え、前記収納ケースは、前記給水経路途中に配設され前記給水弁からの水道水が前記収納ケース内の成形体の表面を経由することで、前記水に徐溶性の結合剤が溶解し、前記還元剤が前記水道水内に分散放出され前記水道水とともに前記洗濯槽内へ供給されるように構成したものであり、給水液中にほぼ一定量の還元剤を溶出させて、給水した水道水に含まれる残留遊離塩素と酸化還元反応を生じさせることにより、残留遊離塩素を除去することができ、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化等を防止することができる
【0018】
請求項2に記載の発明は、上記請求項1に記載の発明に加えて、給水経路途中に洗剤を入れる洗剤ケースを設け、収納ケースは、前記洗剤ケース内に着脱可能に配設されるように構成したものであり、洗剤ケース内を水道水が通過するときに、一定量の還元剤が溶出して、給水した水道水に含まれる残留遊離塩素と酸化還元反応を生じさせることにより、残留遊離塩素を除去することができ、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化等を防止することができ、また、洗剤ケースへ洗剤を入れるときに、成形体の消耗状態を確認することができ、使用者に交換時期を示すことができる
【0019】
請求項に記載の発明は、上記請求項に記載の発明において、収納ケース内の成形体は、洗剤ケースの穴または透明部を介して外から視覚で認識できるように構成したものであり、給水部材に水道水が通過するごとにより、還元剤の成形体がほぼ一定量溶出することで、徐々に消耗してなくなって行く状態を、洗剤ケースの穴または透明部を通して外から視覚で認識できるので、使用者に成形体の交換時期を示すことができる。
【0020】
請求項に記載の発明は、上記請求項1〜3のいずれか1項に記載の発明において、成形体の色と収納ケースの色は、異なる色になるように成したものであり、洗濯機を暗い所に設置している場合でも、成形体が徐々に消耗して交換時期となると、使用者へ成形体が消耗してなくなったことを見やすく示すことができる。
【0021】
【実施例】
以下、本発明の実施例について、図面を参照しながら説明する。なお、従来例と同じ構成のものは同一符号を付して説明を省略する。
【0022】
(実施例1)
図1に示すように、給水ホース1は、一端を水道蛇口(図示せず)に接続し、他端は給水弁2に螺合している。給水弁2の出口側は内部ホース3を介して給水ノズル15と連通している。給水ノズル15の下方には、引き出し状の洗剤ケース16を配設している。成形体17は、還元剤の亜硫酸カルシウムを主成分とし、水に徐溶性の結合剤により固結し、給水口18に配設している。洗剤ケース16と給水口18とを連通して給水部材19を構成し、成形体17の表面を経由して洗濯槽20内へ給水するように構成している。
【0023】
上記構成において、給水弁2が開くと、水道水は内部ホース3、給水ノズル15、洗剤ケース16および還元剤の成形体17の表面を通って給水口18から洗濯槽20へ供給される。このとき、成形体17の結合剤が徐々に溶解して水道水中へ亜硫酸カルシウムの微粒子が分散放出され、水道水とともに給水口18を通って洗濯槽20へ給水される。
【0024】
水道水中に分散放出された亜硫酸カルシウム微粒子は、成形体17の表面から給水口18および洗濯槽20において、水道水中の酸化作用のある残留遊離塩素と酸化還元反応して遊離塩素を除去することができる。したがって、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化などを防止することができる。なお、還元剤の交換時期は、成形体17が残っているかを確認することで容易に判別することができる。
【0025】
(実施例2)
図2に示すように、洗剤ケース16の内部の前面側へ還元剤の亜硫酸カルシウムが主成分で水に徐溶性の結合剤により固結した成形体17を装着し、成形体17の表面を経由して洗濯槽20内へ給水するように構成している。他の構成は上記実施例1と同じである。
【0026】
上記構成において、給水弁2が開くと、水道水は内部ホース3を介して、給水ノズル15から洗剤ケース16内に装着された還元剤の成形体17にシャワー状に供給される。このとき、成形体17の結合剤が徐々に溶解して水道水中へ亜硫酸カルシウムの微粒子が分散放出され、水道水とともに給水口18を通って洗濯槽20へ給水される。
【0027】
水道水中に分散放出された亜硫酸カルシウム微粒子は、洗剤ケース16内と給水口18および洗濯槽20において、水道水中の酸化作用のある残留遊離塩素と酸化還元反応して遊離塩素を除去することができる。したがって、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化などを防止することができる。また、還元剤の交換時期は、洗剤ケース16内へ洗剤を入れるときに、成形体17の消耗状態を確認することで容易に判別することができる。
【0028】
(実施例3)
図3に示すように、還元剤の成形体17は、収納ケース21内に収納し、この収納ケース21を洗剤ケース22内に配設している。収納ケース21には、図4に示すように、内外を連通する穴23を設けている。また、洗剤ケース22に透明窓24を設け、収納ケース21内の成形体17が洗剤ケース22の透明窓24を介して外から臨める構成としている。さらに、成形体17の色は本来の白色で、収納ケース21の色は青色としている他の構成は上記実施例2と同じである。
【0029】
上記構成において、内部ホース3を介して給水ノズル15から給水された水道水が、収納ケース21の連通した穴23を通して成形体17の表面を経由すると、成形体17の表面から結合剤が徐々に溶解して水道水中へ亜硫酸カルシウムの微粒子が分散放出される。この結果、水道水中の酸化作用のある残留遊離塩素と酸化還元反応して遊離塩素を除去することができる。
【0030】
成形体17の表面から結合剤が徐々に溶解して、水道水中へ亜硫酸カルシウムの微粒子が分散放出されると、成形体17は徐々に消耗していく。この消耗状態を洗剤ケース22に設けた透明窓24と収納ケース21に設けた穴23を通して見ることができ、容易に交換時期を確認することができる。
【0031】
このとき、洗剤ケース22内の成形体17の消耗状態は、透明窓24を通して入射した室内の光が収納ケース21表面と成形体17の表面で反射したものを視覚で受けて認識できるものであるが、収納ケース21と成形体17を異なる色としていることにより、さらに容易に認識することができる。そして、交換するときは、成形体17に直接触れることなく、収納ケース21と一体で交換することができる。
【0032】
【発明の効果】
以上のように本発明の請求項1に記載の発明によれば、洗濯槽と、給水経路を介して前記洗濯槽内に水道水を供給する給水弁と、水道水に含まれる遊離塩素を還元する微粒子の還元剤を水に徐溶性の結合剤により固結した成形体と、前記成形体を収納し内外を連通する穴を設けた収納ケースとを備え、前記収納ケースは、前記給水経路途中に配設され前記給水弁からの水道水が前記収納ケース内の成形体の表面を経由することで、前記水に徐溶性の結合剤が溶解し、前記還元剤が前記水道水内に分散放出され前記水道水とともに前記洗濯槽内へ供給されるように構成しから、給水液中にほぼ一定量の還元剤を溶出させて、給水した水道水に含まれる残留遊離塩素と酸化還元反応を生じさせることにより、残留遊離塩素を除去することができ、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化等を防止することができる。また、従来例と異なり、水との大きな接触面積を必要としないことから、コンパクト化できるとともに、還元剤をほぼ100%有効に使用でき、さらに、還元剤の交換時期についても使用者が外から成形体の消耗状態を確認することでわかるだけでなく、簡単に交換することができる。また、成形体は収納ケースに収納されているので、成形体を着脱するときに、表面が軟化している成形体を直接手で触れないようにすることができる。
【0033】
また、請求項2に記載の発明によれば、給水経路途中に洗剤を入れる洗剤ケースを設け、収納ケースは、前記洗剤ケース内に着脱可能に配設されるように構成したから、洗剤ケース内を水道水が通過するときに、一定量の還元剤が溶出して、給水した水道水に含まれる残留遊離塩素と酸化還元反応を生じさせることにより、残留遊離塩素を除去することができ、水道水に含まれる残留遊離塩素の酸化作用による色柄物(染料)の変退色やシルクの黄変や各種有機系の繊維表面加工材の酸化等を防止することができ、また、洗剤ケースへ洗剤を入れるときに、成形体の消耗状態を確認することができ、使用者に交換時期を示すことができる
【0034】
また、請求項に記載の発明によれば、収納ケース内の成形体は、洗剤ケースの穴または透明部を介して外から視覚で認識できるように構成したから、給水部材に水道水が通過するごとにより、還元剤の成形体がほぼ一定量溶出することで、徐々に消耗してなくなって行く状態を、洗剤ケースの穴または透明部を通して外から視覚で認識できるので、使用者に成形体の交換時期を示すことができる。
【0035】
また、請求項に記載の発明によれば、成形体の色と収納ケースの色は、異なる色になるように成したから、洗濯機を暗い所に設置している場合でも、成形体が徐々に消耗して交換時期となると、使用者へ成形体が消耗してなくなったことを見やすく示すことができる。
【図面の簡単な説明】
【図1】 本発明の第1の実施例の洗濯機の要部断面図
【図2】 本発明の第2の実施例の洗濯機の要部断面図
【図3】 本発明の第3の実施例の洗濯機の要部断面図
【図4】 同洗濯機の収納ケースに収納した成形体の斜視図
【図5】 従来の洗濯機の一例の要部分解斜視図
【図6】 (a)従来の洗濯機の他の例の要部分解斜視図
(b)同洗濯機の残留遊離塩素除去装置の断面図
【図7】 (a)従来の洗濯機の他の例の要部分解斜視図
(b)同洗濯機のカートリッジの一部切欠した斜視図
【符号の説明】
17 成形体(還元剤)
19 給水部材
20 洗濯槽
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a washing machine capable of removing free chlorine contained in water or washing liquid supplied to a washing tub.
[0002]
[Prior art]
Conventionally, techniques for removing residual free chlorine in tap water supplied to a washing machine are described in Japanese Patent Laid-Open Nos. 02-136170, 06-154474, 06-238092, and the like. It has been.
[0003]
FIG. 5 is described in Japanese Patent Application Laid-Open No. 02-136170. An internal hose 3 is connected to a water supply valve 2 to which a water supply hose 1 is connected, and a water supply path switching unit 4 is connected to the internal hose 3. The tap water from which the residual free chlorine has been removed can be supplied into the water tank from the water supply port 6 through the residual free chlorine removing device 5 containing the cartridge (not shown) filled with the free chlorine removing material by the water supply path switching unit 4. It is composed.
[0004]
FIG. 6 is described in Japanese Patent Application Laid-Open No. 06-154474. A cartridge 9 in which a water supply hose 1 is connected to a double water supply valve 7 and one of the two water supply valves 7 is filled with a free chlorine removing material 8. Is connected to a residual free chlorine removing device 10, and tap water entered from the inlet 11 of the residual free chlorine removing device 10 is discharged from the outlet 12 through the free chlorine removing material 8, and the tap water from which residual free chlorine has been removed It is comprised so that water can be supplied into the water tank from the water supply port 6.
[0005]
Further, FIG. 7 is described in Japanese Patent Application Laid-Open No. 06-238092, and is a filter that houses a cartridge 13 filled with a free chlorine removing agent 8 in a water supply path for supplying water through an internal hose 3 connected to a water supply valve 2. The case 14 is detachably attached in a drawer shape, and tap water from which residual free chlorine has been removed is supplied to the water tank when the filter case 14 is mounted.
[0006]
[Problems to be solved by the invention]
In the configuration described in Japanese Patent Laid-Open Nos. 02-136170 and 06-154474, all the water supply paths are completely switched to supply tap water from which residual free chlorine has been removed to the water tank. It is necessary to pass through the free chlorine removing material filled with the feed water and to apply water pressure to pass through the densely packed free chlorine removing material.
[0007]
Furthermore, in the cartridge system using a reducing agent, the reducing agent is mainly made of powdered calcium sulfite having a reducing action and granulated with water-soluble ethylcellulose or the like as a binder (binder). It was. As a result, the principle of the reaction mechanism is that the residual free chlorine comes into contact with the surface of the calcium sulfite granules and reacts.
[0008]
In addition, in the structure filled with granular material, it is easy to generate parts that are easy to pass water and parts that are difficult to pass, and when used with water pressure applied, the part that is easy to pass water has more residual release than other parts. Consumed to react with chlorine, a short pass was generated while leaving many active ingredients, and the residual free chlorine leaked out, resulting in a lifetime.
[0009]
In addition, in the cartridge using activated carbon, the flow rate decreases due to clogging by foreign substances contained in tap water, and the residual free chlorine gradually leaks because the flow velocity passing through the activated carbon increases and exceeds the adsorption capacity. Life is reached.
[0010]
In any case, since it is impossible for the user to know the lifetime from the outside, it is also required to predict and notify the lifetime based on the number of uses.
[0011]
Next, in the configuration described in Japanese Patent Application Laid-Open No. 06-238092, in order to supply tap water from which residual free chlorine has been removed into the aquarium, in the portion where the filter case containing the cartridge is mounted, In order to remove the residual free chlorine contained, a poorly soluble reducing agent is required to have high contact efficiency (wide contact area) with tap water. For this reason, the contact area gradually decreases during use, and similarly, it is impossible for the user to know the life from the outside. Therefore, it is also required to predict and notify the life from the number of times of use.
[0012]
In addition, it was impossible to supply a predetermined amount of reducing agent into the tap water from the washing process to the rinsing process with the solubilizing reducing agent. In order to cause discoloration of the colored pattern (dye) by the action, it is required to control the elution to a predetermined amount.
[0013]
The present invention disperses or dissolves a predetermined amount of a predetermined reducing agent in tap water or in a washing liquid, and removes the reducing agent and residual free chlorine by a complete and rapid oxidation-reduction reaction and is contained in tap water. The purpose is to prevent discoloration of colored patterns (dyes) due to the oxidation action of residual free chlorine, yellowing of silk, oxidation of various organic fiber surface treatment materials, and the like.
[0014]
The present invention solves the above-described problem, and elutes a substantially constant amount of reducing agent set in advance in the feed water, and tap water supplied in the water tank and in the water tank after the site where the reducing agent is disposed. The purpose is to remove the residual free chlorine completely and quickly and to make it possible to know the replacement or replenishment timing of the reducing agent.
[0015]
[Means for Solving the Problems]
In the washing machine of the present invention, a washing tub, a water supply valve for supplying tap water into the washing tub through a water supply path, and a particulate reducing agent for reducing free chlorine contained in tap water are gradually dissolved in water. And a storage case provided with a hole for storing the molded body and communicating inside and outside, the storage case being disposed in the middle of the water supply path , from the water supply valve By passing the tap water through the surface of the molded body in the storage case, the gradually soluble binder is dissolved in the water, and the reducing agent is dispersed and released in the tap water, together with the tap water in the washing tub. in which you configured so that is supplied to the.
[0016]
This eliminates the need to completely switch the water supply path or add water pressure to the cartridge as in the conventional example, and to remove residual free chlorine contained in tap water at the part where the filter case is attached. Without requiring high contact efficiency with tap water, a substantially constant amount of reducing agent set in advance is eluted in the feed water, and in the water tank in the middle of the water supply path after the site where the reducing agent is disposed. In addition, by generating a redox reaction with residual free chlorine contained in the supplied tap water, the residual free chlorine can be removed completely and quickly, and the user can also replace or replenish the reducing agent. It is easy to know.
[0017]
DETAILED DESCRIPTION OF THE INVENTION
The invention according to claim 1 of the present invention includes a washing tub, a water supply valve that supplies tap water into the washing tub through a water supply path, and a particulate reducing agent that reduces free chlorine contained in the tap water. comprising a molded body consolidated with a binder Xu soluble in water, and a storage case provided with a hole which communicates the inside and outside by accommodating the molded body, wherein the storage case is disposed midway the water supply path, wherein The tap water from the water supply valve passes through the surface of the molded body in the storage case, so that the gradually soluble binder is dissolved in the water, and the reducing agent is dispersed and released into the tap water together with the tap water. are those constructed to so that is supplied to the washing tub, eluting a substantially constant amount of the reducing agent in a water solution, by causing a redox reaction with the residual free chlorine contained in the water supply tap water Residual free chlorine can be removed and tap water It is possible to prevent oxidation of discoloration and silk yellowing and various organic fibers surface treatment material of the color due to oxidation of Murrell residual free chlorine patterned (dye).
[0018]
Invention according to claim 2, in addition to the invention described in claim 1, provided with a detergent case to put the detergent in the middle water supply channel, the housing case is detachably attached in the detergent case so that When tap water passes through the detergent case, a certain amount of reducing agent elutes, causing residual free chlorine contained in the supplied tap water to cause an oxidation-reduction reaction. It can remove free chlorine and prevent discoloration of colored products (dyes), yellowing of silk and oxidation of various organic fiber surface treatment materials due to oxidation of residual free chlorine contained in tap water In addition, when the detergent is put into the detergent case, the state of wear of the molded body can be confirmed, and the time for replacement can be indicated to the user .
[0019]
Those invention according to claim 3, in the invention described in the claim 2, the molded body in the storage case, which have configured to recognize visually from the outside through a hole or a transparent portion of the detergent case , and the visual by every tap water to the water supply member is passed, that the molded article of the reducing agent is substantially constant elution amount, the state goes missing gradually depleted, from the outside through a hole or a transparent portion of the detergent case in can recognize, it is possible to indicate the time to replace the shaped body to a user.
[0020]
The invention of claim 4 is the invention according to any one of the above claims 1-3, color of the housing case of the molded article, which have configured such that different colors Even when the washing machine is installed in a dark place, when the molded body is gradually consumed and it is time to replace it, it can be easily shown to the user that the molded body has been consumed.
[0021]
【Example】
Embodiments of the present invention will be described below with reference to the drawings. In addition, the thing of the same structure as a prior art example attaches | subjects the same code | symbol, and abbreviate | omits description.
[0022]
(Example 1)
As shown in FIG. 1, the water supply hose 1 has one end connected to a water tap (not shown) and the other end screwed to the water supply valve 2. The outlet side of the water supply valve 2 communicates with the water supply nozzle 15 via the internal hose 3. A drawer-like detergent case 16 is disposed below the water supply nozzle 15. The molded body 17 is mainly composed of a reducing agent, calcium sulfite, and is solidified by a binder that is gradually soluble in water and disposed in the water supply port 18. The detergent case 16 and the water supply port 18 are communicated to form a water supply member 19, and water is supplied into the washing tub 20 through the surface of the molded body 17.
[0023]
In the above configuration, when the water supply valve 2 is opened, tap water is supplied from the water supply port 18 to the washing tub 20 through the surfaces of the internal hose 3, the water supply nozzle 15, the detergent case 16, and the reducing agent molding 17. At this time, the binder of the molded body 17 is gradually dissolved, and the calcium sulfite fine particles are dispersed and released into the tap water, and supplied to the washing tub 20 through the water supply port 18 together with the tap water.
[0024]
The calcium sulfite fine particles dispersed and released in the tap water can be removed from the surface of the molded body 17 through an oxidation-reduction reaction with residual free chlorine having an oxidizing action in the water supply port 18 and the washing tub 20 in the tap water. it can. Therefore, it is possible to prevent discoloration of colored objects (dyes), yellowing of silk, oxidation of various organic fiber surface treatment materials, and the like due to the oxidation of residual free chlorine contained in tap water. Note that the replacement time of the reducing agent can be easily determined by checking whether the molded body 17 remains.
[0025]
(Example 2)
As shown in FIG. 2, a molded body 17 in which the reducing agent calcium sulfite is a main component and solidified with a binder that is gradually soluble in water is attached to the front side of the interior of the detergent case 16. Thus, water is supplied into the washing tub 20. Other configurations are the same as those of the first embodiment.
[0026]
In the above configuration, when the water supply valve 2 is opened, tap water is supplied from the water supply nozzle 15 via the internal hose 3 to the reducing agent molded body 17 mounted in the detergent case 16 in the form of a shower. At this time, the binder of the molded body 17 is gradually dissolved, and the calcium sulfite fine particles are dispersed and released into the tap water, and supplied to the washing tub 20 through the water supply port 18 together with the tap water.
[0027]
The calcium sulfite fine particles dispersed and released in the tap water can be removed in the detergent case 16, the water supply port 18 and the washing tub 20 by an oxidation-reduction reaction with residual free chlorine having an oxidizing action in the tap water. . Therefore, it is possible to prevent discoloration of colored objects (dyes), yellowing of silk, oxidation of various organic fiber surface treatment materials, and the like due to the oxidation of residual free chlorine contained in tap water. Further, the replacement time of the reducing agent can be easily determined by checking the consumption state of the molded body 17 when the detergent is put into the detergent case 16.
[0028]
(Example 3)
As shown in FIG. 3, the reducing agent molded body 17 is stored in a storage case 21, and the storage case 21 is disposed in a detergent case 22. As shown in FIG. 4, the storage case 21 is provided with a hole 23 that communicates inside and outside. Further, a transparent window 24 is provided in the detergent case 22 so that the molded body 17 in the storage case 21 can be exposed from the outside through the transparent window 24 of the detergent case 22. Further, the other configuration in which the color of the molded body 17 is originally white and the color of the storage case 21 is blue is the same as that of the second embodiment.
[0029]
In the above configuration, when the tap water supplied from the water supply nozzle 15 via the internal hose 3 passes through the surface of the molded body 17 through the hole 23 communicated with the storage case 21, the binder is gradually released from the surface of the molded body 17. Dissolves and releases calcium sulfite particles in tap water. As a result, free chlorine can be removed by oxidation-reduction reaction with residual free chlorine having an oxidizing action in tap water.
[0030]
When the binder is gradually dissolved from the surface of the molded body 17 and the calcium sulfite fine particles are dispersed and released into the tap water, the molded body 17 is gradually consumed. This exhausted state can be seen through the transparent window 24 provided in the detergent case 22 and the hole 23 provided in the storage case 21, and the replacement time can be easily confirmed.
[0031]
At this time, the consumption state of the molded body 17 in the detergent case 22 is such that the indoor light incident through the transparent window 24 can be visually recognized and reflected by the surface of the storage case 21 and the surface of the molded body 17. However, since the storage case 21 and the molded body 17 have different colors, it can be recognized more easily. And when replacing | exchanging, it can replace | exchange with the storage case 21 integrally, without touching the molded object 17 directly.
[0032]
【The invention's effect】
As described above, according to the first aspect of the present invention, a washing tub, a water supply valve for supplying tap water into the washing tub through a water supply path, and free chlorine contained in the tap water are reduced. A molded body obtained by solidifying a reducing agent of fine particles to be solidified with a binder that is gradually soluble in water, and a storage case that stores the molded body and has a hole that communicates the inside and the outside, the storage case being provided in the middle of the water supply path disposed, said that tap water from the water supply valve via the surface of the molded body in the housing case, the binder gradually soluble is dissolved in water, dispersing the reducing agent in said tap water because it configured so that is supplied to the released the washing tub together with the tap water, eluting a substantially constant amount of the reducing agent in a water solution, a redox reaction with the residual free chlorine contained in the water supply tap water This can remove residual free chlorine. It is possible to prevent oxidation of the fiber surface processed material discoloration or yellowing and various organic silk color by oxidation of residual free chlorine contained in tap water patterned (dye). In addition, unlike a conventional example, since a large contact area with water is not required, it can be made compact, and the reducing agent can be used almost 100% effectively. Not only can it be confirmed by checking the state of wear of the compact, but it can also be easily replaced. Further, since the molded body is stored in the storage case, it is possible to prevent the molded body whose surface is softened from being touched directly by hand when the molded body is attached or detached.
[0033]
Further, according to the invention described in claim 2, the detergent case to put the detergent in the middle water supply path is provided, the storage case, since you configured so that is arranged detachably on the said detergent case, detergent Case When tap water passes through, a certain amount of reducing agent elutes, and residual free chlorine contained in the supplied tap water can cause an oxidation-reduction reaction, thereby removing residual free chlorine. It can prevent discoloration of colored products (dyes) due to oxidation of residual free chlorine contained in tap water, yellowing of silk, oxidation of various organic fiber surface treatment materials, etc. When inserting, the consumption state of the molded body can be confirmed, and the replacement time can be shown to the user .
[0034]
Further, according to the invention described in claim 3, the molded body in the storage case, Takara form configured so as to be recognized visually from the outside through a hole or a transparent portion of the detergent case, tap water to the water supply member Each time it passes, the molded product of the reducing agent elutes almost constant amount, so that it can be visually recognized from the outside through the hole or transparent part of the detergent case so that it can be gradually consumed. Can indicate body replacement time.
[0035]
Further, according to the invention described in claim 4, color of the housing case of the molded article, Takara form configured to be different colors, even if installed at a dark washing machine, moldings When the battery is gradually consumed and the replacement time is reached, it can be easily shown to the user that the molded body has been consumed.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of main parts of a washing machine according to a first embodiment of the present invention. FIG. 2 is a cross-sectional view of main parts of a washing machine according to a second embodiment of the present invention. Sectional drawing of the principal part of the washing machine of an Example [FIG. 4] The perspective view of the molded object accommodated in the storage case of the washing machine [FIG. 5] The principal part disassembled perspective view of an example of the conventional washing machine [FIG. ) An exploded perspective view of main parts of another example of a conventional washing machine (b) A cross-sectional view of a residual free chlorine removing device of the washing machine [FIG. 7] (a) An exploded perspective view of main parts of another example of a conventional washing machine. Fig. (B) Perspective view of the washing machine cartridge with a part cut away.
17 Molded body (reducing agent)
19 Water supply member 20 Washing tub

Claims (4)

洗濯槽と、給水経路を介して前記洗濯槽内に水道水を供給する給水弁と、水道水に含まれる遊離塩素を還元する微粒子の還元剤を水に徐溶性の結合剤により固結した成形体と、前記成形体を収納し内外を連通する穴を設けた収納ケースとを備え、前記収納ケースは、前記給水経路途中に配設され前記給水弁からの水道水が前記収納ケース内の成形体の表面を経由することで、前記水に徐溶性の結合剤が溶解し、前記還元剤が前記水道水内に分散放出され前記水道水とともに前記洗濯槽内へ供給されるように構成した洗濯機。Molding in which a washing tank, a water supply valve for supplying tap water into the washing tub through a water supply path, and a fine particle reducing agent for reducing free chlorine contained in tap water are solidified with a binder that is gradually soluble in water A storage case having a hole for storing the molded body and communicating the inside and the outside, wherein the storage case is disposed in the water supply path , and tap water from the water supply valve is disposed in the storage case. by way of the surface of the molded body, the dissolved binder Xu soluble in water, the reducing agent is configured to so that is supplied to the washing tub together with dispersed released the tap water in said tap water Washing machine. 水経路途中に洗剤を入れる洗剤ケースを設け、収納ケースは、前記洗剤ケース内に着脱可能に配設されるように構成した請求項1記載の洗濯機。Detergent case to put the detergent in the middle water supply path is provided, the storage case is a washing machine according to claim 1, wherein configured to so that is detachably attached into the detergent case. 収納ケース内の成形体は、洗剤ケースの穴または透明部を介して外から視覚で認識できるように構成した請求項記載の洗濯機。Molding of the storage case, the washing machine according to claim 2 have configured to recognize visually from the outside through a hole or a transparent portion of the detergent case. 成形体の色と収納ケースの色は、異なる色になるように成した請求項1〜3のいずれか1項に記載の洗濯機。Color of the housing case of the molded article, washing machine as claimed in any one of claims 1 to 3 have configured to be different colors.
JP03942696A 1996-02-27 1996-02-27 Washing machine Expired - Fee Related JP3726330B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03942696A JP3726330B2 (en) 1996-02-27 1996-02-27 Washing machine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03942696A JP3726330B2 (en) 1996-02-27 1996-02-27 Washing machine

Publications (2)

Publication Number Publication Date
JPH09225181A JPH09225181A (en) 1997-09-02
JP3726330B2 true JP3726330B2 (en) 2005-12-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP03942696A Expired - Fee Related JP3726330B2 (en) 1996-02-27 1996-02-27 Washing machine

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