JP3583539B2 - Method for manufacturing porous hose - Google Patents

Method for manufacturing porous hose Download PDF

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Publication number
JP3583539B2
JP3583539B2 JP01947396A JP1947396A JP3583539B2 JP 3583539 B2 JP3583539 B2 JP 3583539B2 JP 01947396 A JP01947396 A JP 01947396A JP 1947396 A JP1947396 A JP 1947396A JP 3583539 B2 JP3583539 B2 JP 3583539B2
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JP
Japan
Prior art keywords
thermoplastic elastomer
hose
water
porous hose
extruded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP01947396A
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Japanese (ja)
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JPH09187854A (en
Inventor
寿之 吉村
誠治 岡谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nishikawa Rubber Co Ltd
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Nishikawa Rubber Co Ltd
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Publication date
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Priority to JP01947396A priority Critical patent/JP3583539B2/en
Publication of JPH09187854A publication Critical patent/JPH09187854A/en
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Publication of JP3583539B2 publication Critical patent/JP3583539B2/en
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  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、多孔性ホースの製造方法に関する。詳細には、農業,園芸,緑化施設の地中埋設型灌水,散水,施肥,施薬,送気,排水用に使用される、周壁に多数の小孔が空けられた多孔性ホースを製造する方法に関する。
【0002】
【従来の技術】
地中埋設型灌水や散水などに使用される小孔が空けられた多孔性ホースには材質により軟質ホースと硬質ホースとがある。軟質ホースの場合には、形状保持性が弱く、ねじれやよじれが生じ易く、これにともないホース内部に残液が接着作用によって貼り付き目詰まりの原因になるなどの欠点がある。一方、硬質ホースの場合には、形状保持性が強いため軟質ホースの場合と同様な欠点はないが収納性,運搬性及び施工性に悪いという欠点がある。
【0003】
これらの欠点を改良するために、機械的処理により細分化したゴムパウダー,オレフィン系樹脂パウダー及び発泡剤パウダーを混合した粉末剤を押出成形法により発泡成形して、ゴムパウダー間の気泡を連通させて、その連通部から水を滲み出させる方法が知られている(例えば、特公平7−53406号公報など)。
【0004】
【発明が解決しようとする課題】
しかしながら、特公平7−53406号公報に記載の方法では、ゴムや樹脂を20〜80メッシュに粉砕し、しかも均一に混合する必要があるので非常に手間がかかるという問題がある。
また、予め発泡剤を混合した粉末剤を使用するため成形途中の段階で連通度合い(発泡度合い)の調節には引き取り速度を変化させるしかないのでその調節幅は小さく、更に発泡剤は化学系のものであるため取り扱いに注意を必要とし、それに加えて高価であるといった製造上の問題がある。
【0005】
そこで本発明の目的は、特に煩雑な作業を行う必要がなく、発泡度合いの調節も容易に行え、しかも取り扱い上の安全性にも優れた多孔性ホースの製造方法を提供することにある。
【0006】
【課題を解決するための手段】
上記の目的を達成するために、本発明の多孔性ホースの製造方法は、熱可塑性エラストマーを発泡押出成形することによって多孔性ホースを製造する方法であって、熱可塑性エラストマーが充填された押出機のシリンダーに所定の圧力下で発泡剤として使用される水を注入しながら熱可塑性エラストマーを押し出して、液体及び/又は気体が透過可能な連続気泡構造を周壁に形成するものである(請求項1)。
【0007】
また、熱可塑性エラストマーの温度を150℃以上として発泡押出成形することが好ましい(請求項2)。
【0008】
更に、水の注入量は、熱可塑性エラストマー100重量部に対して0.05〜5重量部であることが好ましい(請求項3)。
【0009】
熱可塑性エラストマーのショア硬度は、50A〜80Dであることが好ましい(請求項4)。
【0010】
本発明によれば、原材料のパウダー化や混合を行う必要がないので作業が簡単で、しかも化学発泡剤を使用するのではなく水を発泡剤として使用するので安全性にも優れる。また、その水を押出機のシリンダーに注入しながら水発泡押出成形するので、注水量を変更することにより発泡度合いの調節を容易に行える。
【0011】
【発明の実施の形態】
本実施形態の多孔性ホースの製造方法について説明する。
(1)まず、熱可塑性エラストマーを押出機のシリンダーに充填する。押出機はスクリュー付きの押出機であり、高圧液体注入装置が接続されている。高圧液体注入装置は、一般に市販されているポンプ、開閉弁、圧力計などで構成されている。
【0012】
ここでいう熱可塑性エラストマーとしては、スチレン系、ポリオレフィン系、ポリ塩化ビニル系、ポリウレタン系、ポリエステル系、ポリアミド系、1,2ボリブタジエン系、トランスポリイソプレン系、フッ素ゴム系、塩素化ポリエチレン系、動的架橋系などの熱可塑性エラストマー全般が含まれる。
なお、熱可塑性エラストマーのショア硬度は50A〜80D(ASTM D 2240)であることが好ましい。ショア硬度が50Aより小さいと押し出された成型品である多孔性ホースの自己形状保持力が弱くなり、逆に80Dより大きいとホースが硬くなり過ぎて収納性,運搬性及び施工性が悪くなるからである。
【0013】
(2)そして、高圧液体注入装置を介して押出機のシリンダーに所定の圧力下で発泡剤として使用される水を注入して押出機内でスクリューの回転によって熱可塑性エラストマーと水とを混合しながら、熱可塑性エラストマーを発泡押出成形する。
このとき、熱可塑性エラストマーの温度を150℃〜220℃として発泡押出成形することが好ましい。温度が150℃より低いと熱可塑性エラストマーの粘度が高くなり、発泡剤(水)の膨張度合いが小さくなる。このため、発泡度が低くなりホースの周壁に十分な連続気泡構造が得られず、液体及び/又は気体が透過し難くなるからである。また、温度が220℃より高いと押出された熱可塑性エラストマーが引きのばされやすくなり、その結果、気泡がつぶれやすくなり液体及び/又は気体が透過し難くなるからである。
【0014】
また、水の注入量は、熱可塑性エラストマー100重量部に対して0.05〜5重量部であることが好ましい。水の注入量が0.05重量部より少ないと気泡が十分でなく、ホースの内側から外側に対して液体及び/又は気体は透過しにくく、逆に5重量部より多いと水発泡し過ぎて成形が困難になるからである。なお、水の注入量を熱可塑性エラストマー100重量部に対して0.1〜2重量部にすることが最も好ましい。また注水する液体は水以外、例えば尿素水などを使用してもよい。
【0015】
以上のようにして水発泡押出成形したホースの部分断面は、図1に示すように、液体及び/又は気体が透過可能な連続気泡構造、すなわち気泡部3が連なった連通部4が、熱可塑性エラストマー5で成型されたホースの周壁に形成されたものとなる。これを、従来例で示した混合粉末剤を押出成形したホースの部分断面を示す図2と比較すると本実施形態に係る水発泡押出成形したホースの方が連通部4、すなわち周壁内に占める連続気泡度合いが多く、水の滲み出し量が大きいことが分かる。なお図2において、符号1はゴムパウダー,2はオレフィン系樹脂パウダー,3は気泡部,4は連通部を示す。
【0016】
また本実施形態に係る水発泡押出成形したホース(注水量0.5重量%の場合と注水量1.0重量%の場合)と従来例で示した混合粉末剤を押出成形したホースからなる試験体8を各50m地上に水平に施設して、図3に示すような、滲み出し量の測定装置に接続して、入口側圧力計7が1.0kgf/cmになるように水道の蛇口6から水を流したところ、測定距離(m)と滲み出し量(ml/分/m)との関係は図4に示すようになった。なお、符号9は末端圧力計を示す。これからも、本実施形態に係る水発泡押出成形したホースの方が水の滲み出し量が大きいことが分かる。
【0017】
【発明の効果】
以上のとおり、本発明によれば、原材料のパウダー化や混合を行う必要がないので作業が簡単で、しかも化学発泡剤を使用するのではなく水を発泡剤として使用するので安全性にも優れ、その上安価である。また、その水を押出機のシリンダーに注入しながら水発泡押出成形するので、注水量を変更することにより発泡度合いの調節を容易に行え、調節幅が大きい。これにより成型されたホースは熱可塑性エラストマーの単体であるので、リサイクルが容易であり、また工程が短くなることから安価に製造することができる。
【図面の簡単な説明】
【図1】本発明の実施の形態に係る、熱可塑性エラストマー5を水発泡押出成形したホースの部分断面図である。
【図2】従来例に係る、混合粉末剤を押出成形したホースの部分断面図である。
【図3】滲み出し量の測定装置を示す外観図である。
【図4】本発明の実施の形態に係る、熱可塑性エラストマー5を水発泡押出成形したホース(注水量0.5重量%の場合と注水量1.0重量%の場合)と従来例に係る、混合粉末剤を押出成形したホースについての、測定距離(m)と滲み出し量(ml/分/m)との関係を示すグラフである。
【符号の説明】
1 ゴムパウダー
2 オレフィン系樹脂パウダー
3 気泡部
4 連通部
5 熱可塑性エラストマー
6 水道の蛇口
7 入口側圧力計
8 試験体
9 末端圧力計
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a method for manufacturing a porous hose. Specifically, a method of manufacturing a porous hose having a number of small holes in a peripheral wall, which is used for underground irrigation, watering, fertilization, chemical application, air supply, and drainage of agriculture, horticulture, and greening facilities. About.
[0002]
[Prior art]
There are a soft hose and a hard hose depending on the material of the porous hose having a small hole used for underground type irrigation or watering. In the case of a soft hose, there are drawbacks such as poor shape retention, easy torsion and kinking, and consequently, residual liquid adheres to the inside of the hose due to an adhesive action and causes clogging. On the other hand, a hard hose does not have the same drawbacks as a soft hose because of its strong shape retention, but has a drawback of poor storage, transportability and workability.
[0003]
In order to improve these drawbacks, a powder mixture obtained by mixing rubber powder, olefin-based resin powder and foaming agent powder, which has been finely divided by mechanical treatment, is foam-formed by an extrusion molding method so that air bubbles between the rubber powders are communicated. Thus, a method of exuding water from the communication portion is known (for example, Japanese Patent Publication No. 7-53406).
[0004]
[Problems to be solved by the invention]
However, the method disclosed in Japanese Patent Publication No. 7-53406 has a problem that it is extremely troublesome because it is necessary to pulverize rubber or resin into 20 to 80 meshes and mix them evenly.
In addition, since a powder agent mixed with a foaming agent in advance is used, the degree of communication (foaming degree) can only be adjusted in the middle of molding by changing the take-up speed. Since it is a product, care must be taken in handling, and in addition, there is a manufacturing problem that it is expensive.
[0005]
Therefore, an object of the present invention is to provide a method of manufacturing a porous hose which does not require particularly complicated operations, can easily adjust the degree of foaming, and is excellent in handling safety.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, a method for producing a porous hose of the present invention is a method for producing a porous hose by foaming and extruding a thermoplastic elastomer, and an extruder filled with a thermoplastic elastomer. The thermoplastic elastomer is extruded while pouring water used as a foaming agent under a predetermined pressure into a cylinder of the cylinder to form an open cell structure through which a liquid and / or a gas can permeate on the peripheral wall. ).
[0007]
In addition, it is preferable that the temperature of the thermoplastic elastomer is set to 150 ° C. or more and foam extrusion is performed (claim 2).
[0008]
Further, the amount of water to be injected is preferably 0.05 to 5 parts by weight based on 100 parts by weight of the thermoplastic elastomer.
[0009]
The Shore hardness of the thermoplastic elastomer is preferably 50A to 80D (Claim 4).
[0010]
According to the present invention, since there is no need to powder or mix the raw materials, the operation is simple, and since water is used as a blowing agent instead of using a chemical blowing agent, safety is also excellent. Also, since the water is foamed and extruded while pouring the water into the cylinder of the extruder, the degree of foaming can be easily adjusted by changing the amount of water injected.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
A method for manufacturing the porous hose of the present embodiment will be described.
(1) First, a thermoplastic elastomer is charged into a cylinder of an extruder. The extruder is an extruder with a screw, and is connected to a high-pressure liquid injection device. The high-pressure liquid injection device includes a commercially available pump, an on-off valve, a pressure gauge, and the like.
[0012]
Examples of the thermoplastic elastomer used herein include styrene-based, polyolefin-based, polyvinyl chloride-based, polyurethane-based, polyester-based, polyamide-based, 1,2-polybutadiene-based, trans polyisoprene-based, fluororubber-based, chlorinated polyethylene-based, It includes all thermoplastic elastomers such as dynamically crosslinked systems.
The thermoplastic elastomer preferably has a Shore hardness of 50A to 80D (ASTM D2240). If the Shore hardness is less than 50A, the extruded molded porous hose has a weak self-shape retention force, whereas if it is larger than 80D, the hose becomes too hard, resulting in poor storage, transportability and workability. It is.
[0013]
(2) Then, water used as a foaming agent is injected under predetermined pressure into a cylinder of the extruder through a high-pressure liquid injection device, and the thermoplastic elastomer and water are mixed by rotating a screw in the extruder. And foam extrusion of a thermoplastic elastomer.
At this time, it is preferable that the temperature of the thermoplastic elastomer is set to 150 ° C. to 220 ° C. to perform foam extrusion molding. When the temperature is lower than 150 ° C., the viscosity of the thermoplastic elastomer increases, and the degree of expansion of the foaming agent (water) decreases. For this reason, the degree of foaming becomes low, and a sufficient open cell structure cannot be obtained on the peripheral wall of the hose, and liquid and / or gas hardly permeate. On the other hand, if the temperature is higher than 220 ° C., the extruded thermoplastic elastomer is easily stretched, and as a result, bubbles are easily crushed and liquid and / or gas are hardly permeated.
[0014]
Further, the injection amount of water is preferably 0.05 to 5 parts by weight based on 100 parts by weight of the thermoplastic elastomer. If the injection amount of water is less than 0.05 parts by weight, the bubbles are not sufficient, and the liquid and / or gas is difficult to permeate from the inside to the outside of the hose. This is because molding becomes difficult. It is most preferable that the amount of water injected be 0.1 to 2 parts by weight based on 100 parts by weight of the thermoplastic elastomer. The liquid to be injected may be other than water, such as urea water.
[0015]
As shown in FIG. 1, the partial cross section of the water foamed and extruded hose has a continuous cell structure through which a liquid and / or a gas can pass, that is, a communication part 4 in which the cell parts 3 are connected to each other. It is formed on the peripheral wall of the hose molded with the elastomer 5. This is compared with FIG. 2 showing a partial cross section of a hose extruded from the mixed powder agent shown in the conventional example, and the water foamed extruded hose according to the present embodiment has a continuous portion occupying the communicating portion 4, that is, the continuous wall occupying the peripheral wall. It can be seen that the degree of bubbles is large and the amount of seeping water is large. In FIG. 2, reference numeral 1 denotes a rubber powder, 2 denotes an olefin resin powder, 3 denotes a bubble portion, and 4 denotes a communication portion.
[0016]
In addition, a test comprising the hose foamed and extruded according to the present embodiment (in the case of a water injection amount of 0.5% by weight and in the case of a water injection amount of 1.0% by weight) and the hose formed by extrusion molding of the mixed powder shown in the conventional example. the body 8 and facilities horizontally to each 50m ground, as shown in FIG. 3, connected to the bleeding amount of the measuring device, inlet pressure gauge 7 is water so that 1.0 kgf / cm 2 faucet When water was flowed from No. 6, the relationship between the measured distance (m) and the amount of oozing (ml / min / m) was as shown in FIG. Reference numeral 9 denotes a terminal pressure gauge. From this, it can be seen that the water-blowing extruded hose according to the present embodiment has a larger water seeping amount.
[0017]
【The invention's effect】
As described above, according to the present invention, there is no need to powder or mix the raw materials, so that the operation is simple, and since water is used as a blowing agent instead of using a chemical blowing agent, safety is also excellent. , And it is cheap. In addition, since the water is foamed and extruded while pouring the water into the cylinder of the extruder, the degree of foaming can be easily adjusted by changing the amount of injected water, and the adjustment range is large. Since the molded hose is a single thermoplastic elastomer, it can be easily recycled, and can be manufactured at low cost because the process is shortened.
[Brief description of the drawings]
FIG. 1 is a partial cross-sectional view of a hose obtained by water-blowing extrusion molding of a thermoplastic elastomer 5 according to an embodiment of the present invention.
FIG. 2 is a partial cross-sectional view of a hose in which a mixed powder is extruded according to a conventional example.
FIG. 3 is an external view showing an apparatus for measuring a seepage amount.
FIG. 4 shows a hose (water injection amount of 0.5% by weight and water injection amount of 1.0% by weight) of a thermoplastic elastomer 5 according to an embodiment of the present invention, and a conventional example. 7 is a graph showing the relationship between the measurement distance (m) and the amount of oozing (ml / min / m) for a hose extruded from a mixed powder agent.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Rubber powder 2 Olefin resin powder 3 Bubble part 4 Communication part 5 Thermoplastic elastomer 6 Water tap 7 Inlet pressure gauge 8 Specimen 9 Terminal pressure gauge

Claims (4)

熱可塑性エラストマーを発泡押出成形することによって多孔性ホースを製造する方法であって、熱可塑性エラストマーが充填された押出機のシリンダーに所定の圧力下で発泡剤として使用される水を注入しながら熱可塑性エラストマーを押し出して、液体及び/又は気体が透過可能な連続気泡構造を周壁に形成することを特徴とする多孔性ホースの製造方法。A method for producing a porous hose by foaming and extruding a thermoplastic elastomer, wherein a water used as a foaming agent is injected under a predetermined pressure into a cylinder of an extruder filled with the thermoplastic elastomer while heating. A method for producing a porous hose, comprising extruding a plastic elastomer to form an open-cell structure on a peripheral wall through which a liquid and / or a gas can pass. 前記熱可塑性エラストマーの温度を150℃以上として発泡押出成形することを特徴とする請求項1に記載の多孔性ホースの製造方法。The method for producing a porous hose according to claim 1, wherein the thermoplastic elastomer is foamed and extruded at a temperature of 150 ° C or higher. 前記水の注入量は、熱可塑性エラストマー100重量部に対して0.05〜5重量部であることを特徴とする請求項1又は請求項2に記載の多孔性ホースの製造方法。The method for producing a porous hose according to claim 1 or 2, wherein the amount of the water injected is 0.05 to 5 parts by weight based on 100 parts by weight of the thermoplastic elastomer. 前記熱可塑性エラストマーのショア硬度は、50A〜80Dであることを特徴とする請求項1乃至請求項3のうちいずれか一つに記載の多孔性ホースの製造方法。The method according to any one of claims 1 to 3, wherein the thermoplastic elastomer has a Shore hardness of 50A to 80D.
JP01947396A 1996-01-09 1996-01-09 Method for manufacturing porous hose Expired - Fee Related JP3583539B2 (en)

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Application Number Priority Date Filing Date Title
JP01947396A JP3583539B2 (en) 1996-01-09 1996-01-09 Method for manufacturing porous hose

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JP3583539B2 true JP3583539B2 (en) 2004-11-04

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JP4597288B2 (en) * 1999-09-07 2010-12-15 ダイセルノバフォーム株式会社 Foam molded body and method for producing the same
JP3902927B2 (en) * 2001-08-10 2007-04-11 日本化学販売株式会社 Drain pipe
KR101228724B1 (en) * 2010-11-30 2013-02-01 경상대학교산학협력단 Hose for preventing water waste, and preparation method thereof
FR2969528B1 (en) * 2010-12-27 2016-12-30 Arkema France PROCESS FOR EXTRUSION OF A POLYMER IN THE PRESENCE OF WATER

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