JP3549903B2 - Sugar-containing tablets - Google Patents

Sugar-containing tablets Download PDF

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Publication number
JP3549903B2
JP3549903B2 JP22898992A JP22898992A JP3549903B2 JP 3549903 B2 JP3549903 B2 JP 3549903B2 JP 22898992 A JP22898992 A JP 22898992A JP 22898992 A JP22898992 A JP 22898992A JP 3549903 B2 JP3549903 B2 JP 3549903B2
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Prior art keywords
sugar
binder
erythritol
elevated temperature
maltitol
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JPH07196476A (en
Inventor
アンリ・ミシエル・アンドレ・ゴンズ
モーリツ・フレディ・ルク・ヴアン・デル・シユーレン
レオン・アンドレ・イヴアン・ラペイユ
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Cerestar Holding BV
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/44Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing peptides or proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/02Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
    • A23G3/0205Manufacture or treatment of liquids, pastes, creams, granules, shred or powder
    • A23G3/0226Apparatus for conditioning, e.g. tempering, cooking, heating, cooling, boiling down, evaporating, degassing, liquefying mass before shaping
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/38Sucrose-free products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/42Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Seasonings (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Medicinal Preparation (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Bipolar Transistors (AREA)
  • Confectionery (AREA)
  • Measuring Pulse, Heart Rate, Blood Pressure Or Blood Flow (AREA)
  • Saccharide Compounds (AREA)
  • Pens And Brushes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Conductive Materials (AREA)

Abstract

A lozenge contains a binder such as gelatine and a sweetener which is partly or totally erythritol or maltitol. A process for making the lozenge comprises kneading the erythritol or maltitol at an elevated temperature, e.g. 35 to 60 DEG C, while slowly adding an aqueous solution of the binder, kneading the erythritol or maltitol and binder into a smooth paste, forming the paste into suitable shapes and heating the shapes at an elevated temperature, e.g. 40 to 45 DEG C, to harden them.

Description

【0001】
【産業上の利用分野】
本発明は、含糖錠剤、特に減少されたカロリー含有量を有しかつ実質上ノンカロリーである含糖錠剤に関する。
【0002】
【従来の技術】
含糖錠剤は、通常砂糖から作られた菓子の形態であり、砂糖は形状の美しい状態を低減させ、水及び結合剤、常にゴム、たとえばアラビアゴムと捏和してこの粉粘稠度に影響を与える。まだこねて形作れる間、こね粉を切断して、乾燥し、硬化させる適する形態となす。適する風味剤、着色料及び(又は)酸をも含有する含糖錠剤は、硬いかつ砕けやすい粘稠度を有しなければならない。
【0003】
健康的な生活を助けるものとして低カロリー生成物に関して増加する興味は、減少されたカロリー菓子類のマーケットを作ることであり、この菓子類とは実際上糖を同一又は類似の程度の甘味度の低カロリー甘味料に代えることを意味する。この目的に対して提案された生成物の1つのグループは、糖アルコール、特にエリスリトール、キシリトール、ソルビトール、マンニトール、マルチトール及び市場で入手できる糖アルコール混合物、たとえばいわゆる水素添加でんぷん水解物であり、この水解物はソルビトール、マルチトール及び3又はそれ以上のくり返し単位(DP>3)を有する高級オリゴマーを含有する。
【0004】
多かれ少なかれこれらの生成物は通常使用される砂糖、グルコース及びシヨ糖よりも低いカロリーであるという追加的な利点を有する。
上記糖アルコールのすべては、甘味料として市場で適用されるが、これらはすべての適用で及び特に菓子類分野で必ずしも同等ではない。というのは種々のタイプの製品の異なる要求は、砂糖の一部又はすべてを置き代えることを意図する甘味料中で性質の正しい組合せを見い出すのに注意深い選択を要する。
【0005】
【発明が解決しようとする課題】
本発明者は、通常の砂糖を基体とする含糖錠剤、しかしそうでなければこれと区別できないものよりも低いカロリー含有量を有する含糖錠剤を製造する目的をもって研究を行い、そしてこの目的が砂糖の一部又は全部をエリスリトール又はマルチトールで置き代えることによって関連する処理の利点と共に達成されることを見い出した。これらの2つのポリオールは、含糖錠剤形で独特の性質を有することが分った。このポリオールはこの形を別の甘味料よりも著しく良好にし、主要成分としてマルチトールを有する糖アルコールの入手可能な混合物よりも良くする。
【0006】
【課題を解決するための手段】
したがって、本発明は、甘味料及び結合剤を含有し、甘味料の一部又は全部がエリスリトール又はマルチトールであること特徴とする含糖錠剤から成る。
【0007】
マルチトールは少なくとも95%純粋、好ましくは少なくとも98%純粋、及び特に少なくとも99%純粋でなければならない。市場で入手できるマルチトール含有− 生成物──これ中でマルチトール濃度は乾燥物質に対して90重量%までである──は、本発明に従って含糖錠剤を製造するのに不適当である。
【0008】
発酵処理の生成物として市場で入手できるエリスリトールは、極めて結晶性であり、実質上シヨ糖のほぼ70%にあたる甘味を有しかつノンカロリー及び非虫歯誘発である純粋な生成物である。
【0009】
本発明による含糖錠剤を製造するのに使用される結合剤を、砂糖含糖錠剤の製造に通常使用されるこれらの結合剤から選択することができる。たとえば結合剤は天然ゴム、たとえばアラビアゴム又は生成物、たとえばゼラチンである。
【0010】
含糖錠剤を製造するのに使用される組成物中の結合剤及び甘味料の量は、水18〜26.0重量%共に結合剤0.2〜3.0重量%及びエリスリトール又はマルチトール98.0〜71.0重量%である。
【0011】
製造方法は、高められた温度、たとえば35〜60℃、好ましくは40〜50℃を保ちながら、適する捏和機/ミキサー中で結合剤及び水を甘味料に徐々に加えることを含む。添加の終了後、混合物が柔かな均一ペーストになるまで混合を続ける。次いでペーストを捏和機/ミキサーから除き、ロールで伸ばし、適する形にこれを最後に、たとえば40〜50℃の高められた温度で熱処理し、包装する前に含糖錠剤を硬化する。本発明の1つの利点は、熱処理時間が砂糖を基体とする含糖錠剤に要求される時間に比してかなり減少し、8〜24時間の範囲であることにある。
【0012】
砂糖を基体とする含糖錠剤のように、本発明による含糖錠剤は、適する風味剤、着色料及び(又は)酸を含有することができる。
【0013】
【実施例】
本発明を、次の例によって詳述する。含糖錠剤の製造方法は、次の通りである。
【0014】
〔例〕
Z- ブレート(blade) ミキサーを、40〜45℃に予備加熱し、テスト甘味料1500gを入れる。50℃に加熱されたゼラチン溶液10重量%を、甘味料を捏和しながら甘味料に徐々に加える。水性ゼラチン溶液の変化する量を、本発明による甘味料に従ってこの方法で加え、捏和/混合をなめらかな均一ペーストを得るために添加後に10分間続ける。次いでペーストをミキサーから除き、ロールで伸ばし、45℃に熱処理する前に切断して形づけ、含糖錠剤を硬化する。含糖錠剤の品質を、その硬度をインストロン硬度計で及びその吸湿度を65%相対湿度下で下記の時間後のその水分吸収によって測定することによって評価する。種々の甘味料に関して得られる結果は、次の通りである:
【0015】
【表1】

Figure 0003549903
【0016】
【発明の効果】
類似の甘味料も、含糖錠剤を製造する場合上記形態で使用される。パラチニト及び水素添加されたでんぷん水解物(これは乾燥物質に対して85重量%マルチトールを含有する)の両方は、Zブレードミキサー中で捏和することができないと証明されている混合物を生じる。一方ラクチトールから作られる含糖錠剤は40時間の熱処理時間を要求し、これは明きらかに処理工程にとって不利である。上記結果から明らかな様に、エリスリトールから作られた含糖錠剤は、最も短い熱処理時間を要求し、極めて硬い仕上げを有する生成物を製造する。エリスリトールをベースとする生成物よりも長い熱処理時間を要求するマルチトールをベースとする含糖錠剤は、同等の砂糖生成物よりも硬い含糖錠剤を製造する。[0001]
[Industrial applications]
The present invention relates to sugar-containing tablets, in particular sugar-containing tablets having a reduced caloric content and being substantially non-caloric.
[0002]
[Prior art]
Sugar-containing tablets are usually in the form of confections made from sugar, which reduces the beautiful shape of the sugar and kneads it with water and a binder, always gum, for example gum arabic, to affect this powder consistency give. While still kneading and forming, the dough is cut, dried and cured into a suitable form. Sugar-containing tablets, which also contain suitable flavoring agents, coloring agents and / or acids, must have a firm and brittle consistency.
[0003]
An increasing interest in low-calorie products as aiding in a healthy life is to create a market for reduced-calorie confectionery, which effectively replaces sugar with the same or similar degree of sweetness. This means replacing low calorie sweeteners. One group of products proposed for this purpose is sugar alcohols, especially erythritol, xylitol, sorbitol, mannitol, maltitol and commercially available sugar alcohol mixtures, such as the so-called hydrogenated starch hydrolysates. The hydrolyzate contains sorbitol, maltitol and higher oligomers having three or more repeating units (DP> 3).
[0004]
More or less these products have the additional advantage of being lower calories than the commonly used sugars, glucose and sucrose.
All of the above sugar alcohols are marketed as sweeteners, but they are not necessarily equivalent in all applications and especially in the confectionery sector. Because the different requirements of different types of products require careful selection to find the right combination of properties in sweeteners intended to replace some or all of the sugar.
[0005]
[Problems to be solved by the invention]
The inventor has studied with the aim of producing sugar-containing tablets based on normal sugar, but having a lower caloric content than otherwise otherwise indistinguishable, and this objective was It has been found that replacing some or all of the sugar with erythritol or maltitol is achieved with the associated processing benefits. These two polyols have been found to have unique properties in sugar-containing tablet form. This polyol makes this form significantly better than another sweetener and better than the available mixtures of sugar alcohols with maltitol as a major component.
[0006]
[Means for Solving the Problems]
Accordingly, the present invention comprises a sugar-containing tablet containing a sweetener and a binder, wherein part or all of the sweetener is erythritol or maltitol.
[0007]
Maltitol must be at least 95% pure, preferably at least 98% pure, and especially at least 99% pure. The commercially available maltitol-containing product, in which the maltitol concentration is up to 90% by weight, based on dry matter, is unsuitable for producing sugar-containing tablets according to the invention.
[0008]
Erythritol, which is commercially available as the product of the fermentation process, is a pure product that is extremely crystalline, has a sweetness substantially equal to approximately 70% of sucrose, and is non-caloric and non-cariogenic.
[0009]
The binders used to make the sugar-containing tablets according to the invention can be selected from those binders usually used for making sugar-containing tablets. For example, the binder is a natural gum, for example gum arabic, or a product, for example gelatin.
[0010]
The amount of binder and sweetener in the composition used to make the sugar-containing tablet is 0.2-3.0% by weight of binder together with 18-26.0% by weight of water and erythritol or maltitol 98 0.0 to 71.0% by weight.
[0011]
The method of manufacture involves the gradual addition of the binder and water to the sweetener in a suitable kneader / mixer while maintaining the elevated temperature, e.g., 35-60C, preferably 40-50C. After the end of the addition, continue mixing until the mixture becomes a soft homogeneous paste. The paste is then removed from the kneader / mixer, rolled and finally heat-treated in a suitable form at an elevated temperature, for example at 40-50 ° C, to cure the sugar-containing tablet before packaging. One advantage of the present invention is that the heat treatment time is significantly reduced compared to the time required for sugar-based sugar-containing tablets, ranging from 8 to 24 hours.
[0012]
Like sugar-based sugar-containing tablets, sugar-containing tablets according to the invention can contain suitable flavoring agents, coloring agents and / or acids.
[0013]
【Example】
The present invention will be described in detail by the following examples. The method for producing the sugar-containing tablet is as follows.
[0014]
[Example]
Z- Bureto a (blade) mixer, preheated to 40~45 ℃, put the test sweetener 1500g. 10% by weight of the gelatin solution heated to 50 ° C. is gradually added to the sweetener while kneading the sweetener. Varying amounts of the aqueous gelatin solution are added in this way according to the sweetener according to the invention, and kneading / mixing is continued for 10 minutes after the addition in order to obtain a smooth homogeneous paste. The paste is then removed from the mixer, rolled, cut and shaped before heat treatment to 45 ° C, and the sugar-containing tablet is cured. The quality of the sugar-containing tablet is assessed by measuring its hardness with an Instron hardness tester and its moisture absorption by its water absorption after the following times at 65% relative humidity. The results obtained for the various sweeteners are as follows:
[0015]
[Table 1]
Figure 0003549903
[0016]
【The invention's effect】
Similar sweeteners are also used in the above form when making sugar-containing tablets. Both palatinit and hydrogenated starch hydrolyzate, which contains 85% maltitol by weight on dry matter, give a mixture which has proven to be incapable of kneading in a Z- blade mixer. Sugar-containing tablets made from lactitol, on the other hand, require a heat treatment time of 40 hours, which is clearly disadvantageous for the processing step . As can be seen from the above results, sugar-containing tablets made from erythritol require the shortest heat treatment time and produce a product with an extremely hard finish. Maltitol- based sugar-containing tablets, which require a longer heat treatment time than erythritol- based products, produce harder sugar-containing tablets than the equivalent sugar product.

Claims (9)

甘味料全体がエリスリトールであることを特徴とする、甘味料及び結合剤を含有する含糖錠剤。A sugar-containing tablet comprising a sweetener and a binder, wherein the whole sweetener is erythritol . 結合剤がゼラチン又は天然に生じるゴムである、請求項1記載の含糖錠剤。The sugar-containing tablet according to claim 1, wherein the binder is gelatin or a naturally occurring rubber. 天然に生じるゴムがアラビアゴムである、請求項2記載の含糖錠剤。The sugar-containing tablet according to claim 2, wherein the naturally occurring gum is gum arabic. 含糖錠剤を製造するのに使用される調合物中の結合剤及び甘味料は、水1.8〜26.0重量%と共に、夫々0.2〜3.0及び98.0〜71.0重量%である、請求項1〜3のいずれかに記載の含糖錠剤。Binders and sweeteners in the formulation used to make the sugar-containing tablets are 0.2-3.0 and 98.0-71.0, respectively, with 1.8-26.0% by weight of water. The sugar-containing tablet according to any one of claims 1 to 3, which is% by weight. a)結合剤の水性溶液をエリスリトールに徐々に加えながら、高められた温度で捏和し、
b)エリスリトール及び結合剤を捏和して、なめらかな均一ペーストとなし、
c)このペーストを適する型に成形し、次いで
d)これを硬化するために、型を高められた温度で加熱(熱処理)すること
を特徴とする、請求項1記載の含糖錠剤の製造方法。
a) kneading at elevated temperature while gradually adding the aqueous solution of the binder to erythritol ,
b) kneading erythritol and a binder into a smooth uniform paste;
2. A process for producing sugar-containing tablets according to claim 1, characterized in that c) the paste is formed into a suitable mold and then d) the mold is heated (heat-treated) at an elevated temperature in order to cure it. .
段階a)の高められた温度が35〜60℃である、請求項5記載の方法。The method of claim 5, wherein the elevated temperature of step a) is 35-60C. 高められた温度が40〜50℃である、請求項5又は6記載の方法。The method of claim 5 or 6, wherein the elevated temperature is between 40 and 50 ° C. 段階d)の高められた温度が40〜50℃である、請求項5〜7のいずれかに記載の方法。The method according to any of claims 5 to 7, wherein the elevated temperature of step d) is between 40 and 50C. 段階d)の加熱時間が8〜24時間の範囲である、請求項5ないし8のいずれかに記載の方法。9. The method according to any of claims 5 to 8, wherein the heating time of step d) ranges from 8 to 24 hours.
JP22898992A 1991-08-29 1992-08-27 Sugar-containing tablets Expired - Lifetime JP3549903B2 (en)

Applications Claiming Priority (2)

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GB919118486A GB9118486D0 (en) 1991-08-29 1991-08-29 Lozenges
GB9118486:1 1991-08-29

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JPH07196476A JPH07196476A (en) 1995-08-01
JP3549903B2 true JP3549903B2 (en) 2004-08-04

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FI923868A (en) 1993-03-01
DE69222387T2 (en) 1998-01-15
NO304092B1 (en) 1998-10-26
EP0530995A1 (en) 1993-03-10
EP0530995B1 (en) 1997-09-24
FI923868A0 (en) 1992-08-28
FI106429B (en) 2001-02-15
NO923387D0 (en) 1992-08-28
US5700514A (en) 1997-12-23
ATE158474T1 (en) 1997-10-15
DK0530995T3 (en) 1997-10-20

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