JP3530869B2 - Coating method of inorganic substrate - Google Patents

Coating method of inorganic substrate

Info

Publication number
JP3530869B2
JP3530869B2 JP30229399A JP30229399A JP3530869B2 JP 3530869 B2 JP3530869 B2 JP 3530869B2 JP 30229399 A JP30229399 A JP 30229399A JP 30229399 A JP30229399 A JP 30229399A JP 3530869 B2 JP3530869 B2 JP 3530869B2
Authority
JP
Japan
Prior art keywords
coating
inorganic substrate
drying
coating film
organic water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP30229399A
Other languages
Japanese (ja)
Other versions
JP2001121070A (en
Inventor
誠史 岡山
幸雄 嶋田
正樹 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KMEW Co Ltd
Original Assignee
Kubota Matsushitadenko Exterior Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Matsushitadenko Exterior Works Ltd filed Critical Kubota Matsushitadenko Exterior Works Ltd
Priority to JP30229399A priority Critical patent/JP3530869B2/en
Publication of JP2001121070A publication Critical patent/JP2001121070A/en
Application granted granted Critical
Publication of JP3530869B2 publication Critical patent/JP3530869B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】この出願の発明は、無機質基
板の塗装方法に関するものである。さらに詳しくは、こ
の出願の発明は、塗膜のチェッキング防止を安価に実現
することのできる無機質基板の塗装方法に関するもので
ある。
TECHNICAL FIELD The present invention relates to a method for coating an inorganic substrate. More specifically, the invention of this application relates to a method for coating an inorganic substrate, which can inexpensively prevent a coating film from being checked.

【0002】[0002]

【従来の技術】外壁材、瓦等の建築用外装材には、セメ
ント及び繊維成分を主原料とし、フィラー等が適宜添加
配合された無機質板が広く用いられている。その製造に
当たっては、セメントスラリーから成形され、養生硬化
した無機質基板の表面に、化粧及び耐水性、耐候性等を
付与するために塗装が施される。塗料には、主に有機水
系塗料が用いられ、スプレー塗装、フローコーター塗装
等の各種方式により30μm以上の厚膜状の塗膜が無機質
基板表面に形成されるように塗装される。
2. Description of the Related Art Inorganic boards, mainly composed of cement and fiber components, to which fillers and the like are appropriately added and blended, are widely used for exterior wall materials, building exterior materials such as roof tiles. In the production thereof, a surface of an inorganic substrate which is molded from cement slurry and cured by curing is coated to impart makeup, water resistance, weather resistance and the like. As the paint, an organic water-based paint is mainly used, and it is applied by various methods such as spray coating and flow coater coating so that a thick film-like coating film of 30 μm or more is formed on the surface of the inorganic substrate.

【0003】上記無機質基板の塗装については、塗装後
の乾燥により塗膜に割れ等のいわゆるチェッキングがし
ばしば発生するという問題が指摘されている。チェッキ
ングの発生は製品の外観を損ねるばかりでなく、耐水
性、耐候性等の各種性能を低下させる一因ともなる。そ
こで、従来よりチェッキング防止のため方策が検討され
ている。
Regarding the coating of the above-mentioned inorganic substrate, it has been pointed out that so-called checking such as cracking often occurs in the coating film due to drying after coating. The occurrence of checking not only impairs the appearance of the product, but also contributes to deterioration of various performances such as water resistance and weather resistance. Therefore, measures have been conventionally considered to prevent checking.

【0004】[0004]

【発明が解決しようとする課題】例えばその一つに、塗
装前に無機質基板を加温するという案がある。チェッキ
ングは、無機質基板の温度が30℃以下となる冬場に多く
発生している。従って、塗装前に無機質基板を加温して
温度を上げておき、塗膜をその下層側、すなわち無機質
基板側から乾燥させることにより、表面からの乾燥が抑
えられ、チェッキングを防止することができると考えら
れる。
For example, one of the proposals is to heat the inorganic substrate before coating. Checking often occurs in winter when the temperature of the inorganic substrate is 30 ° C or lower. Therefore, by heating the inorganic substrate to raise the temperature before coating and drying the coating film from the lower layer side thereof, that is, the inorganic substrate side, the drying from the surface can be suppressed and the checking can be prevented. It is thought to be possible.

【0005】しかしながら、この場合には、無機質基板
を塗装前に30℃以上に加温しなければならないため、そ
のための設備として乾燥用の乾燥機を利用するにして
も、乾燥機の温度設定を高くしたり、能力を大きくする
必要があり、コストがかかるという問題がある。その他
としては、乾燥時に塗膜表面に吹き付ける熱風の風速及
び温度を下げるという案がある。
However, in this case, since the inorganic substrate has to be heated to 30 ° C. or more before coating, even if a dryer for drying is used as equipment for that purpose, the temperature setting of the dryer is not possible. There is a problem in that it is necessary to raise the cost and increase the ability, which causes cost. Another option is to reduce the wind speed and temperature of the hot air blown onto the coating film surface during drying.

【0006】塗膜の乾燥方式には熱風を塗膜表面に吹き
付ける、一般にジェット乾燥と呼ばれる乾燥方式が知ら
れている。このジェット乾燥において塗膜表面に吹き付
ける熱風の風速及び温度を下げることにより、無機質基
板を塗装前に加温する上記案と同様に、塗膜表面からの
乾燥が抑制され、チェッキングを防止することができる
と考えられる。
As a method for drying a coating film, a drying method generally known as jet drying is known in which hot air is blown onto the surface of the coating film. In this jet drying, by reducing the wind speed and temperature of the hot air blown onto the coating film surface, drying from the coating film surface is suppressed and checking is prevented, as in the case of the above-mentioned plan in which the inorganic substrate is heated before coating. It is thought that it can be done.

【0007】だが、熱風の風速及び温度が低下すること
に起因して塗膜乾燥のための熱エネルギーが減少し、そ
の結果、乾燥工程は長時間を要し、生産速度が落ち、や
はりコストに反映する。この出願の発明は、以上の通り
の事情に鑑みてなされたものであり、塗膜のチェッキン
グ防止を安価に実現することのできる無機質基板の塗装
方法を提供することを目的としている。
However, the heat energy for drying the coating film is reduced due to the decrease in the wind velocity and temperature of the hot air, and as a result, the drying process requires a long time, the production speed is reduced, and the cost is reduced. reflect. The invention of this application has been made in view of the circumstances as described above, and an object thereof is to provide a method for coating an inorganic substrate that can inexpensively prevent the check of a coating film.

【0008】[0008]

【課題を解決するための手段】この出願の発明は、上記
の課題を解決するものとして、無機質基板の表面に有機
水系塗料を塗膜厚30μm以上として塗装した後に乾燥を
行う無機質基板の塗装方法において、降伏値が50〜170
dyn/cm2の範囲にある有機水系塗料を無機質基板の表面
に塗装し、塗装後の塗膜表面に温度100℃以上、風速7m/
minの熱風を時間30sec 以上吹き付けて乾燥を行うこと
を特徴とする無機質基板の塗装方法(請求項1)を提供
する。
Means for Solving the Problems The invention of the present application is, in order to solve the above problems, a method for coating an inorganic substrate in which an organic water-based paint is applied on the surface of the inorganic substrate to a coating film thickness of 30 μm or more and then dried. At a yield value of 50-170
Apply an organic water-based paint in the range of dyn / cm 2 to the surface of the inorganic substrate, and apply a temperature of 100 ° C or more and a wind speed of 7 m /
A method of coating an inorganic substrate (claim 1) is characterized in that hot air of min is blown for 30 seconds or more to perform drying .

【0009】またこの出願の発明は、塗装前の無機質基
板を20℃以上に加温すること(請求項2)を好ましい態
様として提供するものでもある。以下、この出願の発明
の無機質基板の塗装方法について実施例を示しつつさら
に詳しく説明する。
The invention of this application is also directed to an inorganic base before coating.
Also intended to provide warming the plate to 20 ° C. or more (claim 2) as a good preferable manner. Hereinafter, the method for coating an inorganic substrate according to the invention of this application will be described in more detail with reference to examples.

【0010】[0010]

【発明の実施の形態】この出願の発明の無機質基板の塗
装方法においても、これまでと同様に、無機質基板の表
面に有機水系塗料を塗膜厚30μm以上として塗装した後
に乾燥を行うが、この出願の発明の無機質基板の塗装方
法では、降伏値が50〜170 dyn/cm2 の範囲にある有機水
系塗料を無機質基板の表面に塗装する。
BEST MODE FOR CARRYING OUT THE INVENTION In the method for coating an inorganic substrate according to the invention of this application, the organic water-based coating material is applied to the surface of the inorganic substrate to a coating film thickness of 30 μm or more and then dried, as in the past. In the method for coating an inorganic substrate according to the invention of the application, an organic water-based coating material having a yield value in the range of 50 to 170 dyn / cm 2 is coated on the surface of the inorganic substrate.

【0011】この出願の発明者等は、これまで塗装に使
用されていた有機水系塗料の降伏値が10〜40 dyn/cm2
範囲にあることに着目し、この値が低いために、30μm
以上の厚膜状の塗膜では、乾燥時に表面乾燥が起きた後
に未乾燥の内部塗料が容易に流動を起こし、チェッキン
グするのではないかと考えた。そして、チェッキングの
発生が効果的に抑制される有機水系塗料の降伏値の範囲
を見出し、降伏値が50〜170 dyn/cm2 の範囲にある有機
水系塗料を無機質基板の表面に塗装する場合には、前記
二案に指摘されるコスト高の問題が解消されるとの知見
を得、この出願の発明を完成したのである。
The inventors of the present application have noticed that the yield value of the organic water-based paint used for coating is in the range of 10 to 40 dyn / cm 2 , and the low value of 30 μm
In the above thick coating film, it was thought that the undried internal coating material could easily flow and check after surface drying occurred during drying. Then, when the yield value range of the organic water-based paint in which the occurrence of checking is effectively suppressed is found, and the organic water-based paint having a yield value in the range of 50 to 170 dyn / cm 2 is applied to the surface of the inorganic substrate. Obtained the knowledge that the high cost problem pointed out in the above two alternatives could be solved, and completed the invention of this application.

【0012】ここで降伏値とは、一般に、物体(固体及
び液体)に十分大きい力(応力)を加えた時に、生じた
変形が元に戻らなくなる時の力を言い、塗料に関して言
えば、降伏値は流動の限界を意味する。従って、降伏値
が大きい塗料程、垂れや収縮等の動きが起こりにくくな
る。有機水系塗料の降伏値が50dyn/cm2 以上の場合に
は、無機質基板を塗装前に特に加温しなくても、また、
ジェット乾燥する際の熱風の風速及び温度を下げなくと
も、30μm以上の厚膜状に塗装される塗膜には乾燥によ
りチェッキングは発生しない。だが、有機水系塗料の降
伏値が170 dyn/cm2 を超えると、チェッキング防止は実
現されるものの、塗膜表面がゆず肌状となり、新たな外
観不良の発生や、スプレー塗装には不向きとなり、この
ため、生産速度が低下し、コスト高になる等の問題が指
摘される。このことから、この出願の発明の無機質基板
の塗装方法では、無機質基板表面を塗装する有機水系塗
料の降伏値を50〜170 dyn/cm2 の範囲としている。有機
水系塗料の降伏値は、例えば、増粘剤の添加量、種類等
を変更することにより調整可能であり、上記範囲への調
整は容易である。
Here, the yield value generally refers to the force at which the generated deformation cannot be restored when a sufficiently large force (stress) is applied to an object (solid and liquid). The value means the limit of flow. Therefore, the greater the yield value of the paint, the less likely it is that movement such as sagging or shrinkage will occur. When the yield value of the organic water-based paint is 50 dyn / cm 2 or more, the inorganic substrate is not particularly heated before coating,
Even if the velocity and temperature of the hot air during jet drying are not reduced, the coating applied in the form of a thick film having a thickness of 30 μm or more does not cause the check due to the drying. However, when the yield value of the organic water-based paint exceeds 170 dyn / cm 2 , although the checking can be prevented, the surface of the paint film will become discolored, causing a new appearance defect and making it unsuitable for spray painting. Therefore, it is pointed out that the production speed is lowered and the cost is increased. Therefore, in the method for coating an inorganic substrate according to the invention of this application, the yield value of the organic water-based coating material for coating the surface of the inorganic substrate is set in the range of 50 to 170 dyn / cm 2 . The yield value of the organic water-based paint can be adjusted, for example, by changing the addition amount and type of the thickener, and the adjustment to the above range is easy.

【0013】なお、有機水系塗料については、耐候性を
考慮した場合、固形分濃度が45% 以上であることが好ま
しい。固形分濃度が45% 未満となると塗膜の耐候性が低
下する。このように、この出願の発明の無機質基板の塗
装方法は、降伏値が50〜170 dyn/cm2 の範囲にある有機
水系塗料を無機質基板の表面に塗装することにより、乾
燥により発生しやすかった塗膜のチェッキングが防止さ
れ、しかもこれを安価に実現することができる。このた
め、塗装後にいわゆるジェット乾燥を行う場合には、塗
装後の塗膜表面に温度100 ℃以上、風速7m/minの熱風を
時間30sec以上吹き付けて乾燥させることができ、生産
速度を高く維持することも可能となる。
In consideration of weather resistance, the organic water-based paint preferably has a solid content concentration of 45% or more. If the solid content concentration is less than 45%, the weather resistance of the coating film will deteriorate. Thus, the coating method of the inorganic substrate of the invention of this application, the yield value was 50-170 dyn / cm 2 by coating the surface of the inorganic substrate with an organic water-based coating, it was likely to occur by drying. Checking of the coating film is prevented, and this can be realized at low cost. For this reason, when so-called jet drying is performed after painting , hot air with a temperature of 100 ° C or more and a wind speed of 7 m / min can be blown on the surface of the coated film for 30 seconds or more to dry it, maintaining a high production rate. It is also possible to do.

【0014】また、この出願の発明の無機質基板の塗装
方法では、塗装前の無機質基板を20℃以上に加温とする
こともできる。前述の通りに、冬場等で無機質基板の温
度が30℃以下となると、乾燥により塗膜にチェッキング
が発生しやすかったが、この出願の発明の無機質基板の
塗装方法では、有機水系塗料の降伏値が50〜170 dyn/cm
2 の範囲にあるため、たとえ塗装前の無機質基板の温度
が30℃以下であっても、塗膜にチェッキングは発生しな
い。だが、塗装前の無機質基板の温度が20℃を下回る
と、乾燥に長時間を要し、生産速度に少なからず影響を
及ぼす。そこで、この出願の発明の無機質基板の塗装方
法では、塗装前に無機質基板を20℃以上に加温し、乾燥
時間の短縮化を図ることができる。加温する温度は20℃
以上に軽減されるため、例えば乾燥機への負担は小さく
済み、上記したジェット乾燥の場合には容易に実現さ
れ、コストへの影響もほとんどない。
In the method for coating an inorganic substrate according to the invention of this application, the inorganic substrate before coating can be heated to 20 ° C. or higher. As described above, when the temperature of the inorganic substrate becomes 30 ° C. or lower in the winter, etc., the coating film was likely to be checked due to drying.However, in the coating method for the inorganic substrate of the invention of this application, the yield of the organic water-based paint was Values 50-170 dyn / cm
Since it is in the range of 2 , even if the temperature of the inorganic substrate before coating is 30 ° C. or less, the check does not occur in the coating film. However, if the temperature of the inorganic substrate before coating falls below 20 ° C, it will take a long time to dry, and the production rate will be affected to a considerable extent. Therefore, in the method for coating an inorganic substrate of the invention of this application, the inorganic substrate can be heated to 20 ° C. or higher before coating to shorten the drying time. The heating temperature is 20 ℃
Since it is reduced as described above, for example, the load on the dryer is small, the jet drying described above is easily realized, and the cost is hardly affected.

【0015】[0015]

【実施例】瓦用の無機質基板の表面に、表1に示した降
伏値に調整した固形分濃度45% の有機水系塗料をスプレ
ー塗装し、その後塗膜を温度100 ℃、風速7m/minの熱風
を時間30sec 吹き付けて乾燥させた(ジェット乾燥)。
乾燥によるチェッキングの有無並びに塗膜の外観、そし
て、スプレー塗装性について評価した。その結果は、表
1に示した通りである。
[Example] On the surface of an inorganic substrate for roof tiles, an organic water-based paint having a solid content concentration of 45% adjusted to the yield value shown in Table 1 was spray-coated, and then the coating film was heated at a temperature of 100 ° C and a wind speed of 7 m / min. It was dried by blowing hot air for 30 seconds (jet drying).
The presence or absence of checking due to drying, the appearance of the coating film, and the spray coatability were evaluated. The results are as shown in Table 1.

【0016】[0016]

【表1】 [Table 1]

【0017】この表1に示した通り、無機質基板表面を
塗装する有機水系塗料の降伏値が50〜170 dyn/cm2 の範
囲にある場合には、十分高温で、高速の熱風によりジェ
ット乾燥を行っても、塗膜にチェッキングは発生せず、
良好な外観が得られる。また、スプレー塗装も可能であ
り、生産速度が高く維持される。有機水系塗料の降伏値
が50dyn/cm2 未満では乾燥により塗膜にチェッキングが
発生し、降伏値が170dyn/cm2 を超えると、新たな外観
不良が発生し、しかもスプレー塗装性が阻害される。
As shown in Table 1, when the yield value of the organic water-based paint for coating the surface of the inorganic substrate is in the range of 50 to 170 dyn / cm 2 , jet drying is performed at a sufficiently high temperature with high speed hot air. Even if you go, the coating will not be checked,
A good appearance is obtained. Also, spray painting is possible, and the production rate is kept high. If the yield value of the organic water-based paint is less than 50 dyn / cm 2 , the coating will be checked due to drying, and if the yield value exceeds 170 dyn / cm 2 , a new appearance defect will occur and the spray coatability will be impaired. It

【0018】勿論、この出願の発明は、以上の実施形態
並びに実施例によって限定されるものではない。有機水
系塗料の種類並びに固形分濃度、乾燥条件等の細部につ
いては様々な態様が可能であることは言うまでもない。
Of course, the invention of this application is not limited to the above-described embodiments and examples. It goes without saying that various aspects are possible in terms of details such as the type of organic water-based paint, solid content concentration, and drying conditions.

【0019】[0019]

【発明の効果】以上詳しく説明した通り、この出願の発
明によって、外壁材、瓦等の建築用外装材の製造におい
て無機質基板の表面を塗装する際の塗膜のチェッキング
防止が安価に実現される。
As described above in detail, according to the invention of the present application, it is possible to inexpensively prevent the check of the coating film when coating the surface of the inorganic substrate in the production of the exterior wall material, the roof tile and other building exterior materials. It

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平5−96233(JP,A) 特開 昭49−99530(JP,A) 特開 平9−188578(JP,A) (58)調査した分野(Int.Cl.7,DB名) B05D 7/00 B05D 3/02 B05D 7/24 301 ─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-5-96233 (JP, A) JP-A-49-99530 (JP, A) JP-A-9-188578 (JP, A) (58) Field (Int.Cl. 7 , DB name) B05D 7/00 B05D 3/02 B05D 7/24 301

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 無機質基板の表面に有機水系塗料を塗膜
厚30μm以上として塗装した後に乾燥を行う無機質基板
の塗装方法において、降伏値が50〜170 dyn/cm2の範囲
にある有機水系塗料を無機質基板の表面に塗装し、塗装
後の塗膜表面に温度100℃以上、風速7m/minの熱風を時
間30sec 以上吹き付けて乾燥を行うことを特徴とする無
機質基板の塗装方法。
1. A method for coating an inorganic substrate, which comprises applying an organic water-based coating on the surface of an inorganic substrate so as to have a coating film thickness of 30 μm or more, and then drying the coating, wherein the yield value is in the range of 50 to 170 dyn / cm 2. It was coated on the surface of the inorganic substrate, coating
When hot air with a temperature of 100 ° C or more and a wind speed of 7 m / min is applied to the surface of the subsequent coating film.
A method for coating an inorganic substrate, characterized by spraying and drying for at least 30 seconds .
【請求項2】 塗装前の無機質基板を20℃以上に加温す
請求項1記載の無機質基板の塗装方法。
2. The inorganic substrate before coating is heated to 20 ° C. or higher.
The method for coating an inorganic substrate according to claim 1, wherein
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