JP3474108B2 - Poorly soluble mineral composition with excellent dispersion stability - Google Patents
Poorly soluble mineral composition with excellent dispersion stabilityInfo
- Publication number
- JP3474108B2 JP3474108B2 JP19691598A JP19691598A JP3474108B2 JP 3474108 B2 JP3474108 B2 JP 3474108B2 JP 19691598 A JP19691598 A JP 19691598A JP 19691598 A JP19691598 A JP 19691598A JP 3474108 B2 JP3474108 B2 JP 3474108B2
- Authority
- JP
- Japan
- Prior art keywords
- sparingly soluble
- composition
- emulsifier
- soluble mineral
- hlb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- General Preparation And Processing Of Foods (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、水に難溶性のミネ
ラルの液状物中での分散性を安定に保つ組成物に関する
ものである。詳しくは、液状食品または食品加工中での
難溶性ミネラルの沈降分離を抑制し、ミネラルの分散性
が均質な食品を製造するために、液状物中で安定な分散
性の得られる難溶性ミネラル組成物の調製に関するもの
である。TECHNICAL FIELD The present invention relates to a composition which maintains stable dispersibility of a water-insoluble mineral in a liquid material. Specifically, in order to suppress the sedimentation and separation of sparingly soluble minerals in liquid foods or food processing and to manufacture foods with a uniform dispersibility of minerals, a sparingly soluble mineral composition that provides stable dispersibility in liquids It relates to the preparation of products.
【０００２】[0002]
【従来の技術】近年、ミネラル摂取量の不足が指摘さ
れ、いろいろな種類のミネラル強化食品が市場に見られ
るようになってきた。これら食品へのミネラルの強化方
法としては、例えばカルシウム強化の場合においては、
塩化カルシウム、乳酸カルシウム等の可溶性カルシウム
を添加する方法と炭酸カルシウム、リン酸カルシウム等
の難溶性カルシウムを添加する方法とが考えられる。2. Description of the Related Art In recent years, it has been pointed out that the intake of minerals is insufficient, and various kinds of mineral-fortified foods have been found on the market. As a method of fortifying minerals in these foods, for example, in the case of calcium fortification,
A method of adding soluble calcium such as calcium chloride and calcium lactate and a method of adding sparingly soluble calcium such as calcium carbonate and calcium phosphate can be considered.
【０００３】しかしながら、可溶性ミネラルを添加する
場合、溶液中で生成したミネラルイオン、もしくは陰イ
オンに起因する塩味、苦味、収斂味等により添加された
食品の風味を著しく損なったり、また、蛋白質と反応し
て凝固物を生成する等、食品中の成分と反応して食品の
組織・物性に悪影響をもたらす等の問題があった。ま
た、難溶性ミネラルを添加する場合、それらの比重が重
く短時間の間に沈降分離したり、粉末の二次凝固の発生
等で食品中での均質化をはかることが難しい等の問題が
あった。However, when soluble minerals are added, the flavor of the added foods is significantly impaired due to salty, bitter, astringent tastes, etc. due to the mineral ions produced in the solution or anions, and the reaction with proteins Then, there is a problem that it reacts with the components in the food, such as producing a coagulated product, which adversely affects the texture and physical properties of the food. In addition, when adding sparingly soluble minerals, there are problems that their specific gravity is heavy and they settle and separate in a short time, and it is difficult to achieve homogenization in foods due to the occurrence of secondary solidification of powder. It was
【０００４】これらの問題の解決策としては、例えば、
炭酸カルシウムの水懸濁液にＨＬＢ１０以上の親水性乳
化剤を配合し、湿式粉砕機を用いて粉砕し炭酸カルシウ
ム分散体を調製する方法（特開平０６−１２７９３９号
公報）、あるいは、リン酸カルシウムの水懸濁液にＨＬ
Ｂ１０以上の親水性乳化剤を配合し、湿式粉砕機を用い
て粉砕し炭酸カルシウム分散体を調製する方法（特開平
０６−１２７９０９号公報）等が提案されているが、こ
れらは、粉末における二次凝集を防止することが主目的
で、添加時の分散性は改善されるものの、添加された液
状食品中での長時間の分散性を保持するには効果が不十
分である。As a solution to these problems, for example,
A method of preparing a calcium carbonate dispersion by blending an aqueous suspension of calcium carbonate with a hydrophilic emulsifier having an HLB of 10 or more and pulverizing it using a wet pulverizer (JP-A 06-127939), or a suspension of calcium phosphate in water. HL for suspension
A method of preparing a calcium carbonate dispersion by blending a hydrophilic emulsifier of B10 or more and pulverizing with a wet pulverizer (Japanese Patent Laid-Open No. 06-127909) and the like have been proposed. The main purpose is to prevent aggregation, but the dispersibility at the time of addition is improved, but the effect is insufficient to maintain long-term dispersibility in the added liquid food.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、食品へのミ
ネラル強化を目的として、上記のような従来の技術の問
題点を解決するために、液状食品、あるいは食品加工工
程で液状状態である中間組成物中での沈降分離が抑制さ
れ、分散安定性の優れた難溶性ミネラル組成物を開発す
ること、および、分散安定性に優れた難溶性組成物の流
通中の品質安定性保持方法を開発することを課題とする
ものである。DISCLOSURE OF THE INVENTION The present invention is a liquid food or a liquid state in a food processing step in order to solve the above-mentioned problems of the conventional techniques for the purpose of strengthening minerals in food. To develop a sparingly soluble mineral composition excellent in dispersion stability in which sedimentation separation in an intermediate composition is suppressed, and a method for maintaining quality stability during distribution of a sparingly soluble composition excellent in dispersion stability. The challenge is to develop.
【０００６】[0006]
【課題を解決するための手段】本発明者等は、上記課題
に鑑み、液状食品中での分散安定性、および、液状態の
食品加工中間組成物中での分散安定性の優れた難溶性ミ
ネラル組成物並びにそれに用いる難溶性ミネラル分散剤
および当該組成物の流通中での品質の保持方法について
鋭意研究を重ねた結果、難溶性ミネラル水懸濁液にＨＬ
Ｂ６以下の乳化剤を必須成分とする乳化剤を配合し、こ
れを乳化機を用いてホモジナイズすることにより、難溶
性ミネラルの長期間分散安定性の優れた組成物が得られ
ること、更には、この組成物に糖類または多価アルコー
ル化合物のいずれか１種または２種以上を配合すること
によって流通中の難溶性ミネラル組成物製品の不均質
化、あるいは腐敗等の品質低下が防止されることを見出
し本発明を完成したものである。In view of the above-mentioned problems, the present inventors have found that the dispersion stability in a liquid food product and the dispersion stability in a liquid state food processing intermediate composition are excellent in solubility. As a result of intensive studies on a mineral composition, a sparingly soluble mineral dispersant used therein, and a method of maintaining the quality of the composition during distribution, HL was added to a sparingly soluble mineral water suspension.
By blending an emulsifier having an emulsifier of B6 or less as an essential component and homogenizing the mixture using an emulsifier, a composition having excellent long-term dispersion stability of a sparingly soluble mineral can be obtained, and further, this composition It has been found that by blending one or more kinds of sugars or polyhydric alcohol compounds into the product, it is possible to prevent inhomogeneity of the poorly soluble mineral composition product in circulation or deterioration of quality such as putrefaction. The invention has been completed.
【０００７】[0007]
【発明の実施の形態】本発明において、難溶性ミネラル
とは水に難溶解性のミネラル物質をいい、難溶性カルシ
ウム、難溶性マグネシウムあるいは難溶性鉄等が適用さ
れる。難溶性カルシウムとしては貝殻カルシウム、骨カ
ルシウム、卵殻カルシウム、サンゴ末等の炭酸カルシウ
ムを主成分とする未焼成天然物またはそれらの焼成物、
天然物、合成による重質または軽質の炭酸カルシウム、
骨カルシウム、乳カルシウム等のリン酸カルシウムを主
成分とする天然物、合成によるリン酸カルシウム等があ
り、難溶性マグネシウムとしては炭酸マグネシウム、酸
化マグネシウム、ドロマイト等があり、難溶性鉄として
はクエン酸鉄、ピロリン酸鉄等があり、これらの難溶性
ミネラルの内のいずれか１種または２種以上の混合物が
用いられる。これらの難溶性ミネラルは食品への応用に
おいては舌触り等の食感を考慮すると可及的微粉末であ
ることが望ましく、食品用として応用するのに適当な粒
子の径は３０ミクロン以下、望ましくは１０ミクロン以
下である。粉末状態における２次凝集による粗粒化は本
発明の組成物調製におけるホモジナイズ工程で再粉砕が
可能である。BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, a sparingly soluble mineral means a sparingly soluble mineral substance in water, and sparingly soluble calcium, sparingly soluble magnesium, sparingly soluble iron or the like is applied. As the sparingly soluble calcium, shell calcium, bone calcium, egg shell calcium, unbaked natural products containing calcium carbonate as a main component such as coral powder or their baked products,
Natural products, synthetic heavy or light calcium carbonate,
Bone calcium, natural products mainly containing calcium phosphate such as milk calcium, synthetic calcium phosphate, etc., magnesium carbonate, magnesium oxide, dolomite, etc. as sparingly soluble magnesium, iron citrate, pyrophosphate as sparingly soluble iron There are iron and the like, and any one of these sparingly soluble minerals or a mixture of two or more thereof is used. These sparingly soluble minerals are preferably as fine powders as possible in consideration of texture such as texture when applied to foods, and the particle size suitable for food applications is 30 microns or less, preferably It is 10 microns or less. The coarsening due to the secondary aggregation in the powder state can be re-ground in the homogenizing step in the preparation of the composition of the present invention.
【０００８】これら難溶性ミネラルの組成物中の配合比
率は、最終の水分散組成物調製中の配合物の流動性が得
られればその量は任意であるが、一般的には５０重量％
以下、更には３５重量％以下が好適である。ＨＬＢが６
以下の乳化剤としては、グリセリン脂肪酸エステル、プ
ロピレングリコール脂肪酸エステル、ソルビタン脂肪酸
エステルがあるが、それらに加えてＨＬＢが６以下であ
るポリグリセリン脂肪酸エステルまたはショ糖脂肪酸エ
ステルも適用可能であり、これらの内のいずれか１種ま
たは２種以上の混合物を用いることができる。The blending ratio of these sparingly soluble minerals in the composition is optional as long as the fluidity of the formulation in the final preparation of the aqueous dispersion composition is obtained, but it is generally 50% by weight.
Hereafter, 35% by weight or less is more preferable. HLB is 6
The following emulsifiers include glycerin fatty acid ester, propylene glycol fatty acid ester, and sorbitan fatty acid ester, and in addition to them, polyglycerin fatty acid ester or sucrose fatty acid ester having HLB of 6 or less are also applicable. Any one of them or a mixture of two or more thereof can be used.
【０００９】単独使用の場合においては、これらの内で
はグリセリン脂肪酸モノエステル若しくはグリセリン脂
肪酸モノ・ジエステルから構成されるグリセリン脂肪酸
エステルが最も効果的である。ＨＬＢ６以下という親油
性の乳化剤が有効である理由は不明であるが、親油性で
あることにより難溶性ミネラル粒子表面に吸着した乳化
剤が水側に溶解・脱着することなく粒子への吸着が維持
されること、また、親油性乳化剤の比重が水の比重より
軽いことにより、難溶性ミネラルと乳化剤の吸着した組
成物粒子の比重が適度なものに調製される等の理由が想
定される。グリセリン脂肪酸エステルが最も効果的であ
ることはその水系での相挙動とこのような効果が重なっ
て影響しているものと推察される。かかる理由から、本
発明においてはＨＬＢ６以下の乳化剤は必須成分であ
る。When used alone, glycerin fatty acid monoester or glycerin fatty acid ester composed of glycerin fatty acid mono / diester is most effective among them. The reason why the lipophilic emulsifier of HLB 6 or less is effective is not clear, but the lipophilic property allows the emulsifier adsorbed on the surface of the sparingly soluble mineral particles to be adsorbed on the particles without being dissolved / desorbed on the water side. In addition, since the specific gravity of the lipophilic emulsifier is lighter than that of water, the reason why the specific gravity of the composition particles in which the sparingly soluble mineral and the emulsifier are adsorbed is adjusted to an appropriate level is assumed. It is speculated that the glycerin fatty acid ester is most effective because the phase behavior in the water system and such effects are overlapped. For this reason, an emulsifier having an HLB of 6 or less is an essential component in the present invention.
【００１０】一方、これらＨＬＢ６以下の乳化剤は親油
性が大きいことによりそれらを単独あるいはＨＬＢ６以
下の乳化剤のみからなる混合物を使用した場合、乳化剤
自体の水系組成物中への十分な溶解性あるいは分散性が
得られない場合がある。このような場合においてはＨＬ
Ｂ６以下の乳化剤に、それらより高いＨＬＢを有する親
水性の乳化剤を併用することによりＨＬＢ６以下の乳化
剤の分散性を改善することができる。On the other hand, since these emulsifiers having an HLB of 6 or less have a large lipophilicity, when they are used alone or a mixture consisting of only an emulsifier having an HLB of 6 or less is used, the emulsifier itself has sufficient solubility or dispersibility in an aqueous composition. May not be obtained. In such a case HL
The dispersibility of the emulsifier having an HLB of 6 or less can be improved by using the emulsifier having a B6 or less and a hydrophilic emulsifier having a higher HLB than those.
【００１１】ＨＬＢ６以下の乳化剤の水分散性を改善す
る目的で使用される高ＨＬＢの乳化剤の種類およびそれ
らのＨＬＢの範囲は特には限定しない。ＨＬＢ６以下の
乳化剤と高ＨＬＢの乳化剤の混合比率は乳化剤混合物中
のＨＬＢ６以下の乳化剤の比率が５重量％以上であれば
任意である。５重量％を下回る混合率の場合は親水性乳
化剤の効果が強く難溶性ミネラルの分散安定性が低下す
る。これら乳化剤の配合量は難溶性ミネラル組成物中
０．１重量％以上５．０重量％以下、好ましくは、０．
５重量％以上２．５重量％以下が適当である。The type of the high HLB emulsifier used for the purpose of improving the water dispersibility of the HLB of 6 or less and the range of those HLBs are not particularly limited. The mixing ratio of the emulsifier having an HLB of 6 or less and the emulsifier having a high HLB is arbitrary as long as the ratio of the emulsifier having an HLB of 6 or less in the emulsifier mixture is 5% by weight or more. When the mixing ratio is less than 5% by weight, the effect of the hydrophilic emulsifier is strong and the dispersion stability of the poorly soluble mineral decreases. The blending amount of these emulsifiers is 0.1% by weight or more and 5.0% by weight or less, preferably 0.
A suitable amount is 5% by weight or more and 2.5% by weight or less.
【００１２】多価アルコールとしては、プロピレングリ
コール、グリセロール、ソルビートルあるいはマルチト
ール等の糖アルコール類が適用でき、糖類としては、グ
ルコース、フラクトース、ショ糖、マルトース、乳糖、
デンプン加水分解物等の単糖類、ニ糖類あるいはオリゴ
糖類あるいは転化糖等が適用できる。これらの多価アル
コールあるいは糖類は組成物の流通中の主として腐敗防
止を目的とする品質安定性を維持するために、いずれか
１種または２種以上の混合物で用いられ、全体の組成あ
るいは対象とする食品あるいは組成物の流通条件等によ
って選択されるが、通常は水系成分中の７０重量％以下
で使用される。As the polyhydric alcohol, sugar alcohols such as propylene glycol, glycerol, sorbitol or maltitol can be applied, and as the saccharides, glucose, fructose, sucrose, maltose, lactose,
Monosaccharides such as starch hydrolysates, disaccharides, oligosaccharides and invert sugars can be applied. These polyhydric alcohols or sugars are used in any one kind or in a mixture of two or more kinds in order to maintain quality stability mainly for the purpose of preventing spoilage during the distribution of the composition, and the composition of the whole or the target is used. Although it is selected depending on the distribution conditions of the food or composition to be used, it is usually used in an amount of 70% by weight or less in the water-based component.
【００１３】本発明がいう難溶性ミネラル組成物には、
難溶性ミネラルにＨＬＢが６以下の乳化剤を必須成分と
する乳化剤を配合してなる組成物、この組成物に多価ア
ルコール及び／または糖類を配合してなる組成物、更に
これらの組成物に水分散組成物を与えるための水の一部
または全部を配合してなる水分散（懸濁）組成物も包含
される。The sparingly soluble mineral composition according to the present invention includes
A composition obtained by mixing a sparingly soluble mineral with an emulsifier having an HLB of 6 or less as an essential component, a composition obtained by mixing a polyhydric alcohol and / or a saccharide with this composition, and further water to these compositions. A water dispersion (suspension) composition prepared by mixing a part or all of water to give a dispersion composition is also included.
【００１４】本発明組成物の調製は、使用する乳化剤の
融点以上もしくは水分散温度に調整された水系組成物の
中に乳化剤を添加し、必要に応じてホモジナイズし乳化
剤均質液を調製する。これに難溶性ミネラル粉末を添加
混合することによって得られるが、必ずしもこの方法に
固定されたものではなく、配合順位、混合機械等は適当
に選択可能である。In the preparation of the composition of the present invention, an emulsifier is added to an aqueous composition whose melting point is higher than that of the emulsifier to be used or which is adjusted to a water dispersion temperature, and if necessary, homogenized to prepare a homogeneous emulsifier liquid. It is obtained by adding and mixing a sparingly soluble mineral powder to this, but it is not necessarily fixed to this method, and the compounding order, mixing machine, etc. can be appropriately selected.
【００１５】また、組成物成分としては、分散性を阻害
しない範囲において、その他の油脂、有機酸、アミノ
酸、香料、調味料、色素、その他の添加物を添加するこ
とを否定するものではない。本発明の難溶性ミネラル組
成物は、牛乳、加工乳、乳飲料、乳酸飲料、果汁、茶、
ココア、豆乳、清涼飲料等の液体食品のみならず、プリ
ン、ゼリー、キャンディー等の菓子類、製菓・製パン
類、麺類、水産練り製品、炊飯等広い範囲への食品への
応用が可能である。[0015] As composition components, addition of other fats and oils, organic acids, amino acids, flavors, seasonings, pigments and other additives is not excluded as long as the dispersibility is not impaired. The sparingly soluble mineral composition of the present invention is milk, processed milk, milk drink, lactic acid drink, fruit juice, tea,
Not only liquid foods such as cocoa, soy milk and soft drinks, but also wide range of foods such as confectionery such as pudding, jelly and candy, confectionery / baking products, noodles, seafood paste products, cooked rice and the like.
【００１６】[0016]
【実施例】以下、本発明を実施例をもって説明するが、
本発明は本実施例に限定されるものではない。EXAMPLES The present invention will be described below with reference to examples.
The present invention is not limited to this embodiment.
【００１７】（実施例１）高純度炭酸カルシウム［宇部
マテリアルズ（株）：ＣＳ−３ＮＡ］３０重量％、水道
水６９重量％、グリセリンステアリン酸モノエステル
［理研ビタミン（株）：エマルジーＭＳ：ＨＬＢ＝４．
３］１重量％より組成物を調製した。(Example 1) High-purity calcium carbonate [Ube Materials Co., Ltd .: CS-3NA] 30% by weight, tap water 69% by weight, glycerin stearic acid monoester [RIKEN VITAMIN Co., Ltd .: Emergy MS: HLB] = 4.
3] A composition was prepared from 1% by weight.
【００１８】（比較例１）実施例１のグリセリンステア
リン酸モノエステル部分を水道水に置き換えて組成物を
調製した。Comparative Example 1 A composition was prepared by replacing the glycerin stearic acid monoester portion of Example 1 with tap water.
【００１９】（評価１）実施例１および比較例１の組成
物を生米当りそれぞれ０．６、１．２、及び１．８重量
％添加して炊飯し、炊飯後分散状態を目視にて観察し
た。結果を表−１に示した。実施例１製品は比較例１製
品に比較して分散性が良好であることが認められる。
(Evaluation 1) The compositions of Example 1 and Comparative Example 1 were added to 0.6, 1.2, and 1.8% by weight of raw rice, respectively, to cook rice, and the dispersed state was visually observed after the rice was cooked. I observed. The results are shown in Table-1. It can be seen that the product of Example 1 has better dispersibility than the product of Comparative Example 1.
【００２０】（実施例２）リン酸三カルシウム［太平化
学産業（株）］３０重量％、グリセリン４５重量％、グ
リセリンステアリン酸モノ・ジエステル［理研ビタミン
（株）：ポエムＳ−２００：ＨＬＢ＝３．２］０．５重
量％および水道水２４．５重量％の組成物を調製した。Example 2 Tricalcium phosphate [Taihei Chemical Industry Co., Ltd.] 30% by weight, glycerin 45% by weight, glycerin stearic acid mono-diester [RIKEN VITAMIN CO., LTD .: Poem S-200: HLB = 3] .2] A composition of 0.5 wt% and tap water 24.5 wt% was prepared.
【００２１】（比較例２）リン酸三カルシウム［太平化
学産業（株）］３０重量％、ショ糖ステアリン酸モノエ
ステル［三菱化学フーズ（株）：リョートーエステルＳ
−１６７０：ＨＬＢ＝１６］０．６重量％および水道水
６９．４重量％の組成物を調製した。(Comparative Example 2) Tricalcium phosphate [Taihei Chemical Industry Co., Ltd.] 30% by weight, sucrose stearate monoester [Mitsubishi Chemical Foods Corporation: Ryoto-ester S
-1670: HLB = 16] A composition of 0.6% by weight and 69.4% by weight tap water was prepared.
【００２２】（評価２）実施例２および比較例２の組成
物を市販の牛乳に０．５重量％添加しピストンホモゲナ
イザーにて１５０kg/cm２の圧力で均質化した後、１３
０℃、２秒間のＵＨＴ殺菌処理を施した。冷却後冷蔵庫
中に保存し、経時的に分散状態を観察した。また、実施
例２および比較例２の組成物をガラス瓶に密封し、室温
に放置して組成物の安定性を観察した。評価結果を表−
２に示した。
組成物の保存安定性および牛乳中での分散安定性ともに
実施例が優れていることが認められる。(Evaluation 2) 0.5% by weight of the composition of Example 2 and Comparative Example 2 was added to commercially available milk and homogenized with a piston homogenizer at a pressure of 150 kg / cm 2 , and then 13
UHT sterilization treatment was performed at 0 ° C. for 2 seconds. After cooling, it was stored in a refrigerator and the dispersed state was observed with time. Further, the compositions of Example 2 and Comparative Example 2 were sealed in glass bottles and left at room temperature to observe the stability of the compositions. Table of evaluation results
Shown in 2. It is recognized that the examples are excellent in both storage stability of the composition and dispersion stability in milk.
【００２３】（実施例３〜８；比較例３〜４）果糖ぶど
う糖液２０．０重量％、ペクチン０．５重量％および水
道水７８．５重量％から構成される糖液に、別途調製さ
れた表−３に示す実施例３〜８および比較例３〜４の組
成物それぞれを糖液に対して１．０重量％添加し、攪拌
した後殺菌し、ガラス容器に密封し難溶性ミネラル添加
糖液を得た。これを冷蔵庫中に静置し経時的なミネラル
の沈降状態を観察した。(Examples 3 to 8; Comparative Examples 3 to 4) Fructose-glucose solution 20.0% by weight, pectin 0.5% by weight and tap water 78.5% by weight were separately prepared as sugar solutions. Each of the compositions of Examples 3 to 8 and Comparative Examples 3 to 4 shown in Table 3 was added to the sugar solution in an amount of 1.0% by weight, stirred, sterilized, sealed in a glass container, and added with a sparingly soluble mineral. A sugar solution was obtained. This was left to stand in a refrigerator and the sedimentation state of minerals with time was observed.
【００２４】また、実施例３〜８および比較例３〜４の
組成物をガラス容器に密封し、室温に静置し組成物の分
離安定性を観察した。結果を表−４に示した。
グリセリンステアリン酸モノエステル：理研ビタミン
（株）：エマルジーＭＳ（HLB=4.3）
グリセリンステアリン酸モノ・ジエステル：理研ビタミ
ン（株）：ポエムＳ−２００（HLB=3.2）
ジグリセリンステアリン酸モノエステル：理研ビタミン
（株）：ポエムＤＳ−１００（HLB=5.5）
プロピレングリコールステアリン酸モノエステル：理研
ビタミン（株）：リケマールＰＳ−１００（HLB=3.9）
デカグリセリンステアリン酸モノエステル：理研ビタミ
ン（株）：ポエムＪ−００８１（HLB=12）
ショ糖パルミチン酸モノエステル：三菱化学フーズ
（株）：リョートーエステルＰ−１６７０（HLB=16）
［組成物の分離安定性］ ［糖液中での沈降状態］
Ａ：ほとんど沈降せず安定である ａ：沈降はほとんど確認できない
Ｂ：わずかに沈降分離している ｂ：わずかに沈降が認められる
Ｃ：多量の沈降が認められる ｃ：ほとんど沈降分離している
実施例の組成物の安定性がいずれの場合においても良好
であることが認められる。The compositions of Examples 3 to 8 and Comparative Examples 3 to 4 were sealed in glass containers and allowed to stand at room temperature to observe the separation stability of the compositions. The results are shown in Table-4. Glycerin stearic acid monoester: Riken Vitamin Co., Ltd .: Emergy MS (HLB = 4.3) Glycerin stearic acid mono / diester: Riken Vitamin Co., Ltd .: Poem S-200 (HLB = 3.2) Diglycerin stearic acid monoester: Riken Vitamin Co., Ltd .: Poem DS-100 (HLB = 5.5) Propylene glycol stearic acid monoester: Riken Vitamin Co., Ltd .: Riquemal PS-100 (HLB = 3.9) Decaglycerin stearic acid monoester: Riken Vitamin Co., Ltd .: Poem J -0081 (HLB = 12) Sucrose palmitic acid monoester: Mitsubishi Chemical Foods Corporation: Ryoto-ester P-1670 (HLB = 16) [Separation stability of composition] [Sedimentation state in sugar solution] A: Almost no sedimentation and stable a: Almost no sedimentation can be confirmed B: Slight sedimentation and separation b: Slight sedimentation is observed C: A large amount of sedimentation is observed. C: Almost sedimentation separation is observed, and the stability of the compositions of Examples is good in any case.
【００２５】[0025]
【発明の効果】本発明により、保存性に優れ、且つ、液
状食品へ添加した場合の分散安定性の良好な難溶性ミネ
ラル組成物が得られる。この組成物を添加することによ
り、難溶性ミネラルが均質に分散された風味の良好な各
種の食品が可能となり、食品に対するミネラル成分の強
化に有用である。Industrial Applicability According to the present invention, a sparingly soluble mineral composition having excellent preservability and good dispersion stability when added to liquid foods can be obtained. Addition of this composition enables various foods having a good flavor in which sparingly soluble minerals are uniformly dispersed, and is useful for strengthening mineral components in foods.
Claims (5)
化剤を難溶性ミネラルに配合してなる液状物中で分散安
定性の優れた難溶性ミネラル組成物。[Claim 1] A sparingly soluble mineral composition having excellent dispersion stability in a liquid material, which is obtained by mixing a sparingly soluble mineral with an emulsifier having an HLB of 6 or less as an essential component.
び／または糖類のいずれか１種または２種以上とを難溶
性ミネラルに配合してなる分散安定性の優れた難溶性ミ
ネラル組成物。2. A sparingly soluble mineral composition having excellent dispersion stability, which is obtained by mixing the emulsifier according to claim 1 and one or more kinds of polyhydric alcohol and / or saccharide into a sparingly soluble mineral.
性マグネシウムまたは難溶性鉄のいずれか１種または２
種以上の混合物である請求項１または２記載の分散安定
性の優れた難溶性ミネラル組成物。3. The sparingly soluble mineral is one or two of sparingly soluble calcium, sparingly soluble magnesium or sparingly soluble iron.
The sparingly soluble mineral composition having excellent dispersion stability according to claim 1 or 2, which is a mixture of one or more kinds.
脂肪酸エステルである請求項１から３までのいずれか１
項記載の分散安定性の優れた難溶性ミネラル組成物。4. The emulsifier having an HLB of 6 or less is a glycerin fatty acid ester, and any one of claims 1 to 3.
A sparingly soluble mineral composition having excellent dispersion stability as described in the item.
乳化剤を有効成分とする分散安定性に優れた液状物を与
えるための難溶性ミネラル分散剤。5. A sparingly soluble mineral dispersant for providing a liquid substance having an emulsifier having an HLB of 6 or less as an essential ingredient and having an emulsifier as an active ingredient and excellent in dispersion stability.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19691598A JP3474108B2 (en) | 1998-07-13 | 1998-07-13 | Poorly soluble mineral composition with excellent dispersion stability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19691598A JP3474108B2 (en) | 1998-07-13 | 1998-07-13 | Poorly soluble mineral composition with excellent dispersion stability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000023626A JP2000023626A (en) | 2000-01-25 |
| JP3474108B2 true JP3474108B2 (en) | 2003-12-08 |
Family
ID=16365788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19691598A Expired - Fee Related JP3474108B2 (en) | 1998-07-13 | 1998-07-13 | Poorly soluble mineral composition with excellent dispersion stability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3474108B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4211217B2 (en) | 1999-12-01 | 2009-01-21 | 味の素株式会社 | Edible oil and fat substitute |
| CN115251397A (en) * | 2021-05-13 | 2022-11-01 | 南京北极光生物科技有限公司 | Stable milky mineral supplement |
-
1998
- 1998-07-13 JP JP19691598A patent/JP3474108B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000023626A (en) | 2000-01-25 |
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