JP3469106B2 - Oily cosmetics - Google Patents

Oily cosmetics

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Publication number
JP3469106B2
JP3469106B2 JP31444398A JP31444398A JP3469106B2 JP 3469106 B2 JP3469106 B2 JP 3469106B2 JP 31444398 A JP31444398 A JP 31444398A JP 31444398 A JP31444398 A JP 31444398A JP 3469106 B2 JP3469106 B2 JP 3469106B2
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Japan
Prior art keywords
present
oil
weight
oily
skin
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JP31444398A
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Japanese (ja)
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JP2000143481A (en
Inventor
裕一郎 江川
昇正 佐藤
清美 石井
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カネボウ株式会社
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Description

【発明の詳細な説明】 【0001】 【発明の属する技術分野】本発明は、水溶性多価アルコ
ールと、油溶性一価アルコールと、特定のグルコピラノ
シド誘導体とを含有する油性化粧料に関し、更に詳細に
はべたつきや肌への違和感が少なく、肌の乾燥を防ぐ湿
潤効果及びその持続性、さらに荒れ肌改善効果に優れた
油性化粧料に関する。 【0002】 【従来の技術】一般に油性化粧料は肌への付着性及びそ
の持続性に優れているが、使用時の油性感が強く、べた
つきや違和感を覚えやすいという欠点がある。その欠点
を解消するために、従来はシリコーン油や低分子量の流
動パラフィン等油性感の少ない液状油性原料を多量に配
合したり、水や水溶性多価アルコールを乳化技術をもっ
て配合する試みがなされている。しかしながら、油性感
の少ない油性原料を多量に配合する方法では、べたつき
や、肌への違和感は若干軽減される程度で欠点の解消に
は至らず、到底品質上満足できるものではない。また、
乳化技術により水や水溶性多価アルコールを配合するこ
とによって、べたつきや肌への違和感はかなり軽減され
るが、その乳化に際し、製品の安定性を高めるために界
面活性剤の配合が事実上不可欠となり、その界面活性剤
が時として肌への刺激となり、肌荒れを誘発してしまう
という別の問題点を有している。さらに、界面活性剤を
配合した場合でも光や熱に対する安定性は十分でなく、
長期保存に対しては相応の配慮が必要であり、処方開発
上の制約が発生してしまうという問題がある。 【0003】一方、本発明者らは上記問題点が、特定の
水溶性多価アルコール及び油溶性一価アルコールとを配
合することにより解決されるという提案を行った(特開
平6−239731号公報)。これにより、従来油性化
粧料が有していた官能品質上の欠点を軽減し、しかも肌
の乾燥を防ぐ効果、すなわち肌荒れ予防効果を有する油
性化粧料が得られるが、肌荒れを改善するという効果は
有しておらず、油性化粧料として未だ満足できるもので
はなかった。 【0004】 【発明が解決しようとする課題】本発明は、油性化粧料
が従来から持つべたつきや肌への違和感が少なく、肌の
乾燥を防ぐ湿潤効果及びその持続性、さらに荒れ肌改善
効果に優れた油性化粧料を提供することを目的としてい
る。 【0005】 【課題を解決するための手段】本発明者らは、上記の実
情に鑑み、鋭意検討した結果、水溶性多価アルコール
と、油溶性一価アルコールと、特定のグルコピラノシド
誘導体とを含有する油性化粧料が上記の問題点を解決す
ることを見出し、本発明を完成するに至った。 【0006】すなわち、本発明は、次の成分(A)、
(B)及び(C); (A)水溶性多価アルコール 0.1〜50重量%、 (B)油溶性一価アルコール 0.1〜50重量%、 (C)下記一般式 【化学式2】(但し、式中、Rは炭素数2〜8からなるアルキル基で
ある。)で表されるグルコピラノシド誘導体 0.01
〜5重量%を含有することを特徴とする油性化粧料(但
し、水を含有しない)にある。 【0007】 【発明の実施の形態】本発明に使用される成分(A)の
水溶性多価アルコールは通常化粧品に用いられるもので
あればいずれも使用可能であり、例えば1,3−ブチレ
ングリコール、ジプロピレングリコール、ポリエチレン
グリコール、プロピレングリコール、ポリプロピレング
リコール、ヘキシレングリコール、トリエチレングリコ
ール等の、グリコール類等が挙げられる。これら水溶性
多価アルコールは、1種だけを用いても良く、あるいは
2種以上を併せて用いても良い。上記水溶性多価アルコ
ールは本発明の油性化粧料中、0.1〜50重量%配合
される。配合量が0.1重量%未満では本発明の効果が
十分得られない場合があり、一方、50重量%を越えて
配合すると得られる油性化粧料の安定性が悪くなる場合
があり、好ましくない。 【0008】本発明に使用される成分(B)の油溶性一
価アルコールは通常化粧品に用いられるものであればい
ずれも使用可能であり、例えばセタノール、ラウリルア
ルコール、ステアリルアルコール、オレイルアルコー
ル、セトステアリルアルコール、2−ヘキシルデカノー
ル、2−オクチルドデカノール、ベヘニルアルコール、
ホホバアルコール等の高級脂肪族アルコール類が挙げら
れる。これら油溶性一価アルコールは、1種だけを用い
ても良く、あるいは2種以上を併せて用いても良い。上
記油溶性一価アルコールは本発明の油性化粧料中、0.
1〜50重量%配合される。配合量が0.1重量%未満
では本発明の十分な効果が得られない場合があり、一
方、50重量%を越えて配合すると得られる油性化粧料
の化粧持ちが悪くなる場合があり、好ましくない。 【0009】本発明に使用される成分(C)のグルコピ
ラノシド誘導体は、醸造酒中にごく微量存在する公知物
質であり、その合成方法については数多くの報告(例え
ば、Rocznikichemi、第49巻、第12
号、第2113〜2115頁、1975年)があり、こ
の方法に従えば、安価且つ容易に入手可能である。グル
コピラノシド誘導体の具体例としては、エチルグルコシ
ド、プロピルグルコシド、ブチルグルコシド、イソブチ
ルグルコシド、ペンチルグルコシド、3−メチルブチル
グルコシド、ヘキシルグルコシド、メチルペンチルグル
コシド、ヘプチルグルコシド、4−メチルヘキシルグル
コシド、5−メチルヘキシルグルコシド、4−エチルペ
ンチルグルコシド、オクチルグルコシド、6−メチルヘ
プチルグルコシド、5−メチルヘプチルグルコシド、
5,5−ジメチルヘキシルグルコシド等が挙げられる。
そしてこれらグルコピラノシド誘導体はα体、β体のい
ずれも使用可能である。 【0010】これらグルコピラノシド誘導体は、1種だ
けを用いても良く、あるいは2種以上を併せて用いても
良い。グルコピラノシド誘導体は本発明の油性化粧料
中、0.01〜5重量%配合される。配合量が0.01
重量%未満では本発明の効果が十分得られない場合があ
り、一方、5重量%を越えて配合すると得られる油性化
粧料の安定性や感触が悪くなる場合があり好ましくな
い。さらに(B)成分は(A)成分に対して、0.5〜
10倍量(重量)、(C)成分は(A)成分に対して、
0.01〜2倍量(重量)になるように配合すること
が、本発明の効果の発現、及び得られる油性化粧料の安
定性の面から好ましい。 【0011】本発明の油性化粧料には、上記必須成分の
他、本発明の効果を損なわない範囲で、化粧品に一般的
に用いられる粉体、界面活性剤、酸化防止剤、高分子化
合物、香料、防腐剤、紫外線吸収剤、保湿剤等を配合す
ることができる。 【0012】本発明の油性化粧料は、化粧油、ファンデ
ーション、口紅、アイシャドウ、ほお紅等の種々の剤型
とすることができる。 【0013】 【実施例】以下、実施例により本発明を更に詳細に説明
するが、これに先立ち評価項目及び方法について詳述す
る。尚、本発明はこれらにより限定されるものではな
い。配合量はすべて重量%である。 【0014】(官能評価試験)20才〜50才の女性パ
ネラー20名に試料をブラインドにて使用させ、「べた
つき」、「塗布部への違和感」、「塗布時のしっとり
感」、「塗布2時間後のしっとり感の持続」について各
評価の基準に従って評価を行い、20名の平均点を評価
結果とした。 【0015】「べたつき」及び「塗布部への違和感」の
評価基準 5点:ない 4点:あまりない 3点:どちらともいえない 2点:ややある 1点:ある 【0016】「塗布時のしっとり感」及び「塗布2時間
後のしっとり感」の評価基準 5点:ある 4点:ややある 3点:どちらともいえない 2点:あまりない 1点:ない 【0017】(肌荒れ予防及び改善効果試験)冬期乾燥
時期に、肌荒れ症状を認める20才〜50才の女性パネ
ラー10名を対象として1週間連続塗布効果を調べた。
すなわち、1日2回(朝、夕)試料を塗布し、試験開始
前及び終了後の塗布部の状態を観察し、下記に従い点数
化し、10名の平均点を評価結果とした。 5点:明確に荒れの改善がみられる 4点:やや荒れの改善がみられる 3点:変化なし 2点:やや悪化した 1点:悪化した 【0018】実施例1、2及び比較例1、2 <油性ロ
ーション> 表1に示す油性ローションを調製し、得られた試料につ
いて前記評価試験を行った。その結果も併せて表1に示
す。 【0019】 【表1】 【0020】表1から明らかなように、本発明の油性ロ
ーションは、官能特性に優れ、荒れ肌予防及び改善効果
にも優れたものであった。 【0021】実施例3、4及び比較例3、4 <油性フ
ァンデーション> 表2に示す油性ファンデーションを調製し、金皿に流し
込んで冷却固化して得られた試料について評価試験を行
った。その結果も併せて表2に示す。 【0022】 【表2】【0023】表2から明らかなように、本発明の油性フ
ァンデーションは、官能特性に優れ、荒れ肌予防及び改
善効果にも優れたものであった。 【0024】実施例5及び比較例5 <スティック状口
紅> 表3に示すスティック状口紅を調製し、棒状に冷却固化
して得られた試料について評価試験を行った。その結果
も併せて表3に示す。 【0025】 【表3】【0026】表3の結果から明らかなように、本発明の
スティック状口紅は、官能特性に優れ、口唇荒れ予防及
び改善効果に優れたものであった。 【0027】実施例6及び比較例6 <流し込み口紅> 表4に示す流し込み口紅を常法により調製し、樹脂製の
壺に流し込み冷却固化して得られた試料について評価試
験を行った。その結果も併せて表4に示す。 【0028】 【表4】 【0029】表4の結果から明らかなように、本発明の
流し込み口紅は、官能特性に優れ、口唇荒れ予防及び改
善効果に優れたものであった。 【0030】実施例7及び比較例7 <スティック状ア
イシャドウ> 表5に示すスティック状アイシャドウを常法により調製
し、棒状に冷却固化して得られた試料について評価試験
を行った。その結果も併せて表5に示す。 【0031】 【表5】 【0032】表5の結果から明らかなように、本発明の
スティック状アイシャドウは、官能特性に優れ、肌荒れ
予防及び改善効果に優れたものであった。 【0033】 【発明の効果】以上記載のごとく、本発明が、油性化粧
料が従来から持つべたつきや肌への違和感が少なく、肌
の乾燥を防ぐ湿潤効果及びその持続性、さらに荒れ肌改
善効果に優れた油性化粧料を提供することは明らかであ
る。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oily cosmetic containing a water-soluble polyhydric alcohol, an oil-soluble monohydric alcohol, and a specific glucopyranoside derivative. The present invention relates to an oil-based cosmetic which is less sticky and uncomfortable to the skin, has a moisturizing effect for preventing dryness of the skin, its durability, and an excellent effect for improving rough skin. [0002] Oily cosmetics generally have excellent adhesion to the skin and long-lasting properties, but have the drawback that they have a strong oily feeling when used and tend to give a sticky feeling and an uncomfortable feeling. In order to solve the drawback, attempts have conventionally been made to mix a large amount of a liquid oily material having a low oiliness such as silicone oil or low molecular weight liquid paraffin, or to mix water or a water-soluble polyhydric alcohol by an emulsification technique. I have. However, in the method of blending a large amount of oily raw materials having a low oily feeling, stickiness and discomfort to the skin are only slightly reduced, and the defects are not eliminated, and the quality is not satisfactory at all. Also,
By mixing water and water-soluble polyhydric alcohol by emulsification technology, stickiness and uncomfortable feeling to the skin are considerably reduced, but in the case of emulsification, it is practically essential to add a surfactant to increase the stability of the product This has another problem that the surfactant sometimes irritates the skin and induces rough skin. Furthermore, even when a surfactant is blended, the stability to light and heat is not sufficient,
Considerable consideration is required for long-term storage, and there is a problem that restrictions on formulation development arise. On the other hand, the present inventors have proposed that the above problems can be solved by blending a specific water-soluble polyhydric alcohol and an oil-soluble monohydric alcohol (Japanese Patent Laid-Open No. 6-239731). ). Thereby, the effect of reducing the sensory qualities of the conventional oil-based cosmetics and preventing the skin from drying can be obtained, that is, an oil-based cosmetic having an effect of preventing skin roughness can be obtained. It did not have it and was still unsatisfactory as an oily cosmetic. DISCLOSURE OF THE INVENTION [0004] The present invention has less oily cosmetics conventionally having stickiness and discomfort to the skin, and has excellent moisturizing effect for preventing dryness of the skin, its persistence, and improvement effect for rough skin. The purpose is to provide oily cosmetics. Means for Solving the Problems The inventors of the present invention have conducted intensive studies in view of the above circumstances, and as a result, have found that they contain a water-soluble polyhydric alcohol, an oil-soluble monohydric alcohol, and a specific glucopyranoside derivative. The present inventors have found that an oil-based cosmetic that solves the above-mentioned problems has led to the completion of the present invention. That is, the present invention provides the following component (A):
(B) and (C); (A) 0.1 to 50% by weight of a water-soluble polyhydric alcohol, (B) 0.1 to 50% by weight of an oil-soluble monohydric alcohol, (C) the following general formula [Chemical formula 2] (Wherein, R is an alkyl group having 2 to 8 carbon atoms).
Oil-based cosmetics containing up to 5% by weight (however,
And does not contain water) . DETAILED DESCRIPTION OF THE INVENTION The component (A) used in the present invention may be any water-soluble polyhydric alcohol as long as it is commonly used in cosmetics. For example, 1,3-butylene glycol And glycols such as dipropylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, hexylene glycol, and triethylene glycol. These water-soluble polyhydric alcohols may be used alone or in combination of two or more. The water-soluble polyhydric alcohol is incorporated in the oily cosmetic of the present invention in an amount of 0.1 to 50% by weight. If the amount is less than 0.1% by weight, the effect of the present invention may not be sufficiently obtained. On the other hand, if the amount exceeds 50% by weight, the stability of the obtained oily cosmetic may deteriorate, which is not preferable. . [0008] The oil-soluble monohydric alcohol of component (B) used in the present invention can be any of those commonly used in cosmetics, such as cetanol, lauryl alcohol, stearyl alcohol, oleyl alcohol, and cetostearyl. Alcohol, 2-hexyldecanol, 2-octyldodecanol, behenyl alcohol,
Higher aliphatic alcohols such as jojoba alcohol are exemplified. These oil-soluble monohydric alcohols may be used alone or in combination of two or more. The oil-soluble monohydric alcohol is used in the oil-based cosmetic of the present invention in an amount of 0.1.
1 to 50% by weight is blended. If the amount is less than 0.1% by weight, the sufficient effect of the present invention may not be obtained. On the other hand, if the amount is more than 50% by weight, the cosmetic durability of the obtained oily cosmetic may deteriorate, which is preferable. Absent. The glucopyranoside derivative of the component (C) used in the present invention is a known substance which is present in a very small amount in brewed sake, and its synthesis method has been reported in many reports (for example, Rocznikikim, Vol. 49, No. 12).
No. 2113-2115, 1975), and according to this method, it is inexpensive and easily available. Specific examples of the glucopyranoside derivatives include ethyl glucoside, propyl glucoside, butyl glucoside, isobutyl glucoside, pentyl glucoside, 3-methylbutyl glucoside, hexyl glucoside, methyl pentyl glucoside, heptyl glucoside, 4-methylhexyl glucoside, and 5-methylhexyl glucoside. , 4-ethylpentyl glucoside, octyl glucoside, 6-methylheptyl glucoside, 5-methylheptyl glucoside,
5,5-dimethylhexylglucoside and the like.
These glucopyranosides can be used in both α-form and β-form. [0010] One of these glucopyranosides may be used alone, or two or more thereof may be used in combination. The glucopyranoside derivative is incorporated in the oily cosmetic of the present invention in an amount of 0.01 to 5% by weight. The amount is 0.01
If the amount is less than 5% by weight, the effect of the present invention may not be sufficiently obtained. On the other hand, if the amount exceeds 5% by weight, the stability and feel of the resulting oily cosmetic may be unfavorably deteriorated. Further, the component (B) is 0.5 to 0.5% of the component (A).
10 times the amount (weight), component (C) is relative to component (A)
It is preferable to mix it in an amount of 0.01 to 2 times (weight) from the viewpoint of the effect of the present invention and the stability of the obtained oily cosmetic. The oily cosmetic of the present invention contains, in addition to the above essential components, powders, surfactants, antioxidants, polymer compounds, and the like generally used in cosmetics as long as the effects of the present invention are not impaired. Perfumes, preservatives, ultraviolet absorbers, humectants and the like can be added. The oily cosmetic of the present invention can be in various forms such as cosmetic oil, foundation, lipstick, eyeshadow, blusher and the like. EXAMPLES The present invention will be described in more detail with reference to the following examples. Prior to this, evaluation items and methods will be described in detail. The present invention is not limited by these. All amounts are by weight. (Sensory Evaluation Test) Twenty female panelists aged 20 to 50 years old were allowed to use the sample in a blind, and they were "sticky", "uncomfortable to the coated part", "moist feeling at the time of coating", and "coated 2". The "permanence of moist feeling after time" was evaluated according to the criteria of each evaluation, and the average score of 20 persons was used as the evaluation result. Evaluation criteria for "stickiness" and "uncomfortable feeling to coating part" 5 points: not 4 points: not so much 3 points: neither of them 2 points: a little 1 point: a certain "moist at the time of coating" Evaluation criteria of "feel" and "moist feeling 2 hours after application" 5 points: 4 points: Somewhat 3 points: Neither can be 2 points: Not so much 1 point: No (Test for effect of prevention and improvement of rough skin) 1) The effect of continuous application for one week was examined on 10 female panelists aged 20 to 50 years old who showed rough skin symptoms during the dry season in winter.
That is, the sample was applied twice a day (morning and evening), the state of the applied part before and after the start of the test was observed, scored according to the following, and the average score of 10 persons was used as the evaluation result. 5 points: roughness is clearly improved 4 points: slight improvement of roughness 3 points: no change 2 points: slightly deteriorated 1 point: deteriorated Examples 1 and 2 and Comparative Examples 1 and 2 2 <Oil-based lotion> The oil-based lotion shown in Table 1 was prepared, and the evaluation test was performed on the obtained sample. Table 1 also shows the results. [Table 1] As apparent from Table 1, the oily lotion of the present invention was excellent in organoleptic properties, and was also excellent in the effects of preventing and improving rough skin. Examples 3 and 4 and Comparative Examples 3 and 4 <Oil-based foundation> An oil-based foundation shown in Table 2 was prepared, poured into a metal dish, cooled and solidified, and an evaluation test was performed on the obtained sample. Table 2 also shows the results. [Table 2] As is clear from Table 2, the oily foundation of the present invention was excellent in organoleptic properties, and also excellent in preventing and improving rough skin. Example 5 and Comparative Example 5 <Stick Lipstick> An evaluation test was performed on a sample obtained by preparing a stick lipstick shown in Table 3 and cooling and solidifying the stick lipstick. Table 3 also shows the results. [Table 3] As is clear from the results shown in Table 3, the stick-like lipstick of the present invention was excellent in organoleptic properties and excellent in prevention and improvement of lip roughening. Example 6 and Comparative Example 6 <Pour-in lipstick> A lipstick shown in Table 4 was prepared by a conventional method, poured into a resin pot, cooled and solidified, and an evaluation test was performed. Table 4 also shows the results. [Table 4] As is evident from the results in Table 4, the cast lipstick of the present invention was excellent in organoleptic properties and excellent in prevention and improvement of rough lips. Example 7 and Comparative Example 7 Stick Eyeshadow A stick eyeshadow shown in Table 5 was prepared by a conventional method, and an evaluation test was performed on a sample obtained by cooling and solidifying into a rod shape. Table 5 also shows the results. [Table 5] As is clear from the results shown in Table 5, the stick-shaped eyeshadow of the present invention was excellent in sensory characteristics and excellent in the effects of preventing and improving rough skin. [0033] As described above, the present invention provides the oily cosmetics with a less sticky or uncomfortable feeling to the skin, a moisturizing effect for preventing dryness of the skin, a long-lasting effect, and an effect for improving rough skin. It is clear that it provides an excellent oily cosmetic.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) A61K 7/00 - 7/50 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7/ 00-7/50

Claims (1)

(57)【特許請求の範囲】 【請求項1】 次の成分(A)、(B)及び(C); (A)水溶性多価アルコール 0.1〜50重量%、 (B)油溶性一価アルコール 0.1〜50重量%、 (C)下記一般式 【化1】(但し、式中、Rは炭素数2〜8からなるアルキル基で
ある。)で表されるグルコピラノシド誘導体 0.01
〜5重量% を含有することを特徴とする油性化粧料(但し、水を含
有しない)
(57) [Claims] (1) The following components (A), (B) and (C); (A) 0.1 to 50% by weight of a water-soluble polyhydric alcohol, and (B) oil solubility. 0.1 to 50% by weight of a monohydric alcohol, (C) the following general formula: (Wherein, R is an alkyl group having 2 to 8 carbon atoms).
Oil-based cosmetics (but not including water).
No) .
JP31444398A 1998-11-05 1998-11-05 Oily cosmetics Expired - Lifetime JP3469106B2 (en)

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Application Number Priority Date Filing Date Title
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JP3469106B2 true JP3469106B2 (en) 2003-11-25

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Country Link
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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003012493A (en) * 2001-07-04 2003-01-15 Kobayashi Pharmaceut Co Ltd Oil-based semisolid external preparation
FR3104962B1 (en) * 2019-12-20 2021-12-31 Oreal Cosmetic composition comprising at least one polar oil, one aliphatic monoalcohol, a mixture of polyols and at least one hydrophilic active

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