JP3427195B2 - Composite mica powder with ultraviolet blocking action - Google Patents
Composite mica powder with ultraviolet blocking actionInfo
- Publication number
- JP3427195B2 JP3427195B2 JP07020594A JP7020594A JP3427195B2 JP 3427195 B2 JP3427195 B2 JP 3427195B2 JP 07020594 A JP07020594 A JP 07020594A JP 7020594 A JP7020594 A JP 7020594A JP 3427195 B2 JP3427195 B2 JP 3427195B2
- Authority
- JP
- Japan
- Prior art keywords
- mica powder
- oxide
- present
- composite
- ultraviolet blocking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- Cosmetics (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
【０００１】[0001]
【産業上の利用分野】この発明は、化粧料、塗料、イン
キ、コーテイング剤、プラスチック、フイルム、繊維、ガラス
及び釉薬等の基剤として使用される新規複合マイカ粉体
及び該複合マイカ粉体を含有するパ−ル顔料に関するも
のである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel composite mica powder used as a base for cosmetics, paints, inks, coating agents, plastics, films, fibers, glass and glazes, and the composite mica powder. containing to Rupa - relates le pigments.
【０００２】[0002]
【従来の技術】マイカ粉体は、その優れた絶縁性、リー
フイング性及び潤滑性等の性質を利用して、塗料添加
材、プラスチック添加材及び化粧料等の多くの用途に使
用されている。マイカ等に酸化鉄、酸化チタン等を被覆
し、パ−ル感を出したり、着色したり、紫外線散乱効果
を出すことは従来から公知である。この従来の複合マイ
カ粉体は、母材のマイカとして、天然の白雲母、金雲
母、セリサイト若しくは合成マイカ等が使用されてい
る。2. Description of the Related Art Mica powder is used in many applications such as paint additives, plastic additives and cosmetics, due to its excellent insulating properties, leafing properties and lubricity. . It is conventionally known that mica or the like is coated with iron oxide, titanium oxide or the like to give a pearly feeling, coloring, or an ultraviolet scattering effect. In this conventional composite mica powder, natural muscovite, phlogopite, sericite, synthetic mica or the like is used as the mica of the base material.
【０００３】しかして、上記用途に使用される場合、十
分な紫外線遮断効果があることが強く求められている
が、上記従来品は、マイカの鱗片形状を利用することに
主眼をおいていたものであり、これらは全て紫外線遮断
効果の点では十分満足すべきものではない。また、特に
化粧品用として使用される場合は、自然な皮膚の色に近
い色彩を有することが求められているが、従来の複合マ
イカ粉体では、この要求を全く満たしていない。更に、
従来のパ−ル顔料は、銀白色に限られていたが、化粧品
等の用途によっては、真珠用光沢に好ましくは肌色の色
彩を付加したパ−ル顔料が求められている。However, when it is used for the above-mentioned applications, it is strongly demanded that it has a sufficient ultraviolet ray blocking effect, but the above-mentioned conventional products are focused on the use of the mica scale shape. However, these are not all sufficiently satisfactory in terms of the ultraviolet blocking effect. In particular, when it is used for cosmetics, it is required to have a color close to that of natural skin, but the conventional composite mica powder does not satisfy this requirement at all. Furthermore,
Although the conventional pearl pigments are limited to silver white, pearl luster is preferably added to the pearl luster for some applications such as cosmetics.
【０００４】[0004]
【発明が解決しようとする課題】この発明は、このよう
な従来の問題点を一挙に解消しようとするものであり、
十分な紫外線遮断効果があり、自然な皮膚の色に近い色
彩を有し、従来にない色彩を付与したパ−ル感を発現す
る複合マイカ粉体を提供することを目的とする。SUMMARY OF THE INVENTION The present invention is intended to solve all of the above-mentioned problems of the prior art.
It is an object of the present invention to provide a composite mica powder which has a sufficient effect of blocking ultraviolet rays, has a color close to that of natural skin, and exhibits a pearly feeling imparted with an unprecedented color.
【０００５】[0005]
【課題を解決するための手段】本発明者等は、この点に
着目し、一連の基礎的研究の結果、従来複合マイカ粉体
の母材として使用されたことのなかった鉄元素を含有す
る合成マイカ粉体を母材として使用した複合マイカ粉体
は、上記要求特性を全て満たす複合機能を有することを
見いだし、本発明に到達した。即ち本発明は、鉄元素を
含有する合成マイカ粉体に、酸化チタン、酸化セリウ
ム、酸化亜鉛、二酸化珪素、酸化アルミニウム及び酸化
ジルコニウムからなる群から選ばれた１種以上の酸化物
で被覆した複合マイカ粉体であって、乾燥時は略白色で
あるが、液体に濡れると肌色に変色することを特徴とす
る。The present inventors have paid attention to this point, and as a result of a series of basic studies, the present inventors have contained an iron element which has never been used as a base material for composite mica powder. The present inventors have found that a composite mica powder that uses a synthetic mica powder as a base material has a composite function that satisfies all the above-mentioned required properties, and has reached the present invention. The present invention provides the synthetic mica powder containing iron elements, titanium oxide, cerium oxide, zinc oxide, silicon dioxide, one or more selected from aluminum oxide and <br/> zirconium arm or Ranaru group It is a composite mica powder coated with the oxide of
However, it is characterized by changing its color to flesh color when wet with liquid .
【０００６】本発明の複合マイカ粉体は、乾燥時は略白
色であるが、液体に濡れると皮膚の色に近い肌色に変色
する性質を有する。人間の皮膚は、水気があるので、こ
の複合粉体を皮膚に塗布すると、肌の色と略同じ色に発
色するので、この複合粉体は、特に化粧品用として好適
である。尚、乾燥時略白色というのは、乾燥時は白色若
しくは若干の赤み等の色彩を帯びている意味である。酸
化チタン、酸化セリウム及び酸化亜鉛の１種以上で被覆
した複合マイカ粉体、特に酸化チタンで被覆した複合マ
イカ粉体は、従来のマイカ粉体及び複合マイカ粉体には
全く見られない卓越した紫外線遮断作用を有する。即
ち、鉄元素を含有しない合成マイカを母材とした従来の
複合マイカ粉体は、後記比較例に記載のように６０％程
度の紫外線遮断率しか示さなかったが、本発明の複合マ
イカ粉体は後記実施例に記載のように９３％以上の紫外
線遮断率を示す。 The composite mica powder of the present invention is substantially white when dried, but has the property of changing to a skin color close to the skin color when wet with a liquid. Since human skin has moisture, when this composite powder is applied to the skin, it develops a color approximately the same as the color of the skin. Therefore, this composite powder is particularly suitable for cosmetics. It should be noted that the term “approximately white when dried” means that the color is white or slightly reddish when dried. Titanium oxide, cerium oxide and the composite mica powder coated with one or more zinc oxide, especially composite mica powder coated with titanium oxide is not seen at all in the conventional mica powder and composite mica powder excellent Has a UV blocking effect. That is, the conventional composite mica powder having the synthetic mica containing no iron element as the base material showed only about 60% of the ultraviolet ray blocking rate as described in the comparative example below, but the composite mica powder of the present invention Indicates an ultraviolet ray blocking ratio of 93 % or more as described in Examples below.
【０００７】鉄元素を含有する合成マイカ粉体に、酸化
チタン及び酸化ジルコニウムで被覆した複合粉体は、パ
−ル顔料として、従来にない紫外線遮断作用を有すると
共に従来にない独特のパ−ル感を発現する。このような
パ−ル顔料は、従来全く知られていなかったものであ
る。特に、酸化チタンで被覆したパ−ル顔料は、その色
彩の点で非常に優れている。酸化チタン及び／または酸
化ジルコニウムで被覆したパ−ル顔料は、優れた紫外線
遮断作用を有し、乾燥時は略白色であるが、液体に濡れ
ると肌色に変色するという従来のパ−ル顔料には全く見
られない性質を示す。鉄元素を含有する合成マイカ粉体
の製造方法は、溶融合成、水熱合成、固相反応などいず
れでも良いが、結晶性が良好であるという理由で特に溶
融合成法が好ましい。[0007] synthetic mica powder containing iron, a composite powder coated with titanium oxide and zirconium beam is Pas - as Le pigments, unique path unprecedented and having an ultraviolet blocking action unprecedented - Express a feeling of ru. Such a pearl pigment has never been known. In particular, Pas oxide coated titanium - Le pigments are excellent in terms of its color. Pas coated with titanium oxide and / or zirconium oxide - Le pigments have an excellent UV blocking effect, although when dry is substantially white, conventional path of discolored skin-colored wet with liquid - Le pigment Indicates a property that cannot be seen at all. The synthetic mica powder containing an iron element may be produced by any of melt synthesis, hydrothermal synthesis, solid-state reaction, etc., but the melt synthesis method is particularly preferable because of its good crystallinity.
【０００８】溶融合成法で鉄元素を含有する合成マイカ
を製造するには、シリカ、酸化アルミニウム、酸化マグ
ネシウム、ケイフッ化カリウム及び酸化鉄等の原料を所
定のモル数で混合し、１４００℃〜１６００℃で溶融
後、冷却して結晶化させればよい。得られた結晶塊は、
公知の粉砕方法で微粉化し、本発明の母材の鉄元素を含
有する合成マイカ粉体とする。このようにして得られた
鉄元素を含有する合成マイカ粉体を、酸処理若しくは熱
処理することにより、種々の色の合成マイカが得られ
る。これらの着色マイカも本発明の母材とすることがで
きる。To produce synthetic mica containing elemental iron by the melt synthesis method, raw materials such as silica, aluminum oxide, magnesium oxide, potassium silicofluoride and iron oxide are mixed in a predetermined number of moles and the temperature is from 1400 ° C to 1600 ° C. After melting at ℃, it may be cooled to crystallize. The obtained crystal mass is
It is pulverized by a known pulverizing method to obtain a synthetic mica powder containing the iron element of the base material of the present invention. By subjecting the thus obtained synthetic mica powder containing iron element to acid treatment or heat treatment, synthetic mica of various colors can be obtained. These colored mica can also be used as the base material of the present invention.
【０００９】鉄元素を含有する合成マイカ粉体を、酸化
チタン、酸化セリウム、酸化亜鉛、二酸化珪素、酸化ア
ルミニウム及び酸化ジルコニウムからなる群から選ばれ
た１種以上の酸化物で被覆する方法は、公知の被覆方法
で行えば良い。例えば、酸化チタンを被覆する方法は、
希薄なチタン酸水溶液中に鉄元素を含有する合成マイカ
粉体を懸濁させ、７０〜１００℃に加温し、チタン塩を
加水分解して鉄元素を含有する合成マイカ粉体上に水和
酸化チタン粒子を析出させ、その後７００〜１０００℃
の高温で焼成して製造することができる。[0009] The method for coating with the synthetic mica powder containing iron elements, titanium oxide, cerium oxide, zinc oxide, silicon dioxide, one or more oxides selected from aluminum oxide and zirconium arm or Ranaru group Can be performed by a known coating method. For example, the method of coating titanium oxide is
A synthetic mica powder containing iron element is suspended in a dilute aqueous solution of titanic acid, heated to 70 to 100 ° C., and the titanium salt is hydrolyzed to hydrate on the synthetic mica powder containing iron element. Precipitate titanium oxide particles, then 700-1000 ° C
It can be manufactured by firing at a high temperature.
【００１０】本発明の複合マイカ粉体は、従来の複合マ
イカ粉体と同様にして、紫外線遮断剤及びパ−ル顔料と
して使用することができる。即ち、紫外線遮断剤として
は、本発明の複合粉体を、単独若しくは体質顔料、着色顔
料、紫外線散乱剤及び紫外線吸収剤等に配合し、混合して
使用すれば良い。また、パ−ル顔料としては、各種塗料
に混合して使用したり、各種プラスチックに練り込んで
独特のパ−ル感を発現したり、化粧品等の着色剤とする
ことができる。The composite mica powder of the present invention can be used as an ultraviolet blocking agent and a pearl pigment in the same manner as the conventional composite mica powder. That is, as the ultraviolet blocking agent, the composite powder of the present invention may be used alone or in combination with an extender pigment, a coloring pigment, an ultraviolet scattering agent, an ultraviolet absorbing agent and the like, and mixed and used. Further, the pearl pigment can be used by mixing it with various paints, kneading into various plastics to develop a unique pearly feeling, or as a colorant for cosmetics and the like.
【００１１】[0011]
【作用】本発明の複合マイカ粉体は、母材として鉄元素
を含有する合成マイカ粉体を使用し、これを酸化物で被
覆することによって、母材の紫外線遮断作用と被覆物の
紫外線遮断作用との相乗作用によって、従来の複合マイ
カ粉体には見られない卓越した紫外線遮断作用を有す
る。また、鉄元素を含有する合成マイカ粉体を母材と
し、白色の酸化物で被覆することによって、乾燥時は略
白色であるが、液体に濡れると皮膚の色のような肌色に
変色する性質を示す。これも従来の複合マイカ粉体には
見られない性質である。更に、従来のこの種パ−ル顔料
は、母材が白色であったが、本発明の複合マイカ粉体の
母材は赤色等の色に着色しているので、本発明のパ−ル
顔料は、従来にない独特のパ−ル感を発現する。The composite mica powder of the present invention uses a synthetic mica powder containing an iron element as a base material, and coats this with an oxide to prevent the base material from blocking the ultraviolet rays and the coating from blocking the ultraviolet rays. Due to the synergistic action with the action, it has an excellent ultraviolet ray blocking action which is not found in the conventional composite mica powder. In addition, by using synthetic mica powder containing iron as a base material and coating with a white oxide, it is almost white when dried, but when it gets wet with liquid, it changes to a skin color like skin color Indicates. This is also a property not found in conventional composite mica powder. Further, the conventional base pigment of this kind has a white base material, but the base material of the composite mica powder of the present invention is colored in a color such as red. Expresses a unique and unprecedented pearly feeling.
【００１２】[0012]
【実施例】次に、実施例、比較例を挙げて本発明を更に
説明するが、本発明はこれら実施例に限定されない。
尚、実施例、比較例中の紫外線遮断率の測定は、次の方
法により行った。試験粉体１ｇとひまし油４ｇを３本ロ
−ルで混練し、石英ガラス板上にアプリケ−タ−で１０
ミクロン厚に塗布し、自記分光光度計で３００ｎｍの透
過率から紫外線遮断率を算定した。
実施例１
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均径１０ミクロン、ＢＥＴ比表面積６ｍ
２／ｇ ）を水１リットルに分散させ、これに硫酸チタ
ニルの１モル溶液（ＴｉＯ２８０ｇ／リットル）１００
ミリリットルを加えた。この懸濁液を撹拌しながら急速
に１００℃に加温し、この温度で３時間反応させた。反
応終了後、脱水洗浄し、約１００℃の温度で乾燥した。
乾燥物を８００℃で１時間焼成して本発明品を得た。本
発明品の紫外線遮断率は、９８％であった。EXAMPLES Next, the present invention will be further described with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples.
The UV blocking rate in the examples and comparative examples was measured by the following method. 1 g of the test powder and 4 g of castor oil were kneaded with 3 rolls, and the mixture was placed on a quartz glass plate with an applicator for 10
It was applied to a thickness of micron, and the UV blocking rate was calculated from the transmittance of 300 nm with a self-recording spectrophotometer. Example 1 100 g of synthetic fluorophlogopite containing 9% of iron element (ray
The-type 50% average diameter 10 microns, BET specific surface area 6 m
2 / g) was dispersed in 1 liter of water, and a 1 molar solution of titanyl sulfate (TiO 2 80 g / liter) 100 was added to the dispersion.
Added milliliters. The suspension was rapidly heated to 100 ° C. with stirring and reacted at this temperature for 3 hours. After the completion of the reaction, it was dehydrated and washed and dried at a temperature of about 100 ° C.
The dried product was baked at 800 ° C. for 1 hour to obtain the product of the present invention. The ultraviolet blocking rate of the product of the present invention was 98%.
【００１３】実施例２
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均径１０ミクロン、ＢＥＴ比表面積６ｍ
２／ｇ ）を水１リットルに分散させ、これに塩化セリ
ウムの２５％水溶液１００ミリリットルを加えた。この
懸濁液を撹拌しながら水酸化ナトリウム水溶液でＰＨを
８まで上昇させ、８０℃で２時間反応させた。反応終了
後、脱水洗浄し、約１２０℃の温度で乾燥して本発明品
を得た。本発明品の紫外線遮断率は、９３％であった。Example 2 100 g of synthetic fluorophlogopite containing 9% of iron element (ray
The-type 50% average diameter 10 microns, BET specific surface area 6 m
2 / g) was dispersed in 1 liter of water, and 100 ml of a 25% aqueous solution of cerium chloride was added thereto. While stirring this suspension, the pH was raised to 8 with an aqueous sodium hydroxide solution and reacted at 80 ° C. for 2 hours. After completion of the reaction, the product was dehydrated and washed, and dried at a temperature of about 120 ° C to obtain the product of the present invention. The ultraviolet blocking rate of the product of the present invention was 93%.
【００１４】実施例３
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均径１０ミクロン、ＢＥＴ比表面積６ｍ
２／ｇ ）を水１リットルに分散させ、これに塩化亜鉛
の１モル溶液（ＺｎＯ８１ｇ／リットル）１００ミリリ
ットルを加えた。この懸濁液を撹拌しながらアンモニア
水でＰＨを９まで上昇させ、８０℃で２時間反応させ
た。反応終了後、脱水洗浄し、約２００℃の温度で乾燥
して本発明品を得た。紫外線遮断率は、９３％であっ
た。 Example 3 100 g of synthetic fluorophlogopite containing 9% of iron element (ray
The-type 50% average diameter 10 microns, BET specific surface area 6 m
2 / g) was dispersed in 1 liter of water, and 100 ml of a 1 molar solution of zinc chloride (81 g / l of ZnO) was added thereto. The pH of this suspension was raised to 9 with aqueous ammonia while stirring, and the mixture was reacted at 80 ° C. for 2 hours. After completion of the reaction, the product was dehydrated and washed, and dried at a temperature of about 200 ° C. to obtain the product of the present invention. UV-blocking rate was 93%
It was
【００１５】実施例４
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均径２０ミクロン、ＢＥＴ比表面積３ｍ
２／ｇ ）を水１リットルに分散させ、これに硫酸チタ
ニルの１モル溶液（ＴｉＯ２８０ｇ／リットル）４００
ミリリットルを加えた。この懸濁液を撹拌しながら急速
に１００℃まで加温し、この温度で３時間反応させた。
反応終了後、脱水洗浄し、約１００℃の温度で乾燥し
た。乾燥物を８００℃で１時間焼成して本発明品を得
た。本発明品は、若干赤みを帯びた銀白色のパ−ル光沢
を有する粉体であった。この粉体は、流動パラフインに
濡らすと鮮やかな肌色に発色した。本発明品の紫外線遮
断率は、９８％であった。 [0015]Example 4
100 g of synthetic fluorophlogopite containing 9% of iron element
The-type 50% average diameter 20 microns, BET specific surface area 3 m
2 / g) in 1 liter of water and add
Nyl 1 molar solution (TiO280 g / l) 400
Added milliliters. Rapidly stir this suspension
The mixture was heated to 100 ° C. and reacted at this temperature for 3 hours.
After completion of the reaction, dehydration washing and drying at a temperature of about 100 ° C
It was The dried product is baked at 800 ° C. for 1 hour to obtain the product of the present invention.
It was The product of the present invention has a slightly reddish silver-white pearly luster.
It was a powder having This powder becomes a fluid paraffin
When wet, it developed a bright skin color. UV protection of the product of the present invention
The cut rate is 98%there were.
【００１６】実施例５
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均径２０ミクロン、ＢＥＴ比表面積３ｍ
２／ｇ ）を水１リットルに分散させ、これに硫酸ジル
コニウム（Ｚｒ（ＳＯ４）２・４Ｈ２Ｏ）２００ｇを加
えた。更に尿素７０ｇを加え、この懸濁液を撹拌しなが
ら１００℃まで加温し、この温度で３時間反応させた。
反応終了後、脱水洗浄し、約１００℃の温度で乾燥し
た。乾燥物を８００℃で１時間焼成して本発明品を得
た。本発明品は、銀白色のパ−ル光沢を有する粉体であ
った。この粉体は、流動パラフインに濡らすと鮮やかな
肌色に発色した。本発明品の紫外線遮断率は、９５％で
あった。 [0016]Example 5
100 g of synthetic fluorophlogopite containing 9% of iron element
The-type 50% average diameter 20 microns, BET specific surface area 3 m
2 / g) in 1 liter of water and add
Added 200 g of Konium (Zr (SO4) 2.4H2O)
I got it. Add another 70 g of urea and stir this suspension.
The mixture was heated to 100 ° C. and reacted at this temperature for 3 hours.
After completion of the reaction, dehydration washing and drying at a temperature of about 100 ° C
It was The dried product is baked at 800 ° C. for 1 hour to obtain the product of the present invention.
It was The product of the present invention is a powder having a silver-white pearly luster.
It was. This powder becomes vivid when wet with flowing paraffin.
It turned into a complexion. The UV blocking rate of the product of the present invention is 95%.
there were.
【００１７】実施例６
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均粒子径２０ミクロン、ＢＥＴ比表面積
３ｍ２／ｇ ）を水１リットルに分散させ、これに珪酸
ナトリウム溶液（３６％Ｎａ４ＳｉＯ４）１００ｇを蒸
留水で１リットルに希釈し、マイカ懸濁液に加えた。こ
の懸濁液を撹拌しアンモニア水でＰＨを９に調整しなが
ら、７０℃で２時間反応させた。ついで、希塩酸を加
え、ＰＨを３．５に調整後、スラリ−を脱水洗浄し、約
１００℃の温度で乾燥した。乾燥物を８００℃で１時間
焼成して本発明品を得た。本発明品は、白色の粉体であ
るが油等に濡れると肌色に発色し、化粧品の基材として
好適なものであった。[0017]Example 6
100 g of synthetic fluorophlogopite containing 9% of iron element
The-type 50% average particle size 20 microns, BET specific surface area
3 m2 / g) in 1 liter of water and add silicic acid
Steam 100g of sodium solution (36% Na4SiO4)
It was diluted to 1 liter with distilled water and added to the mica suspension. This
Stir the suspension of and adjust the pH to 9 with aqueous ammonia.
And reacted at 70 ° C. for 2 hours. Then add dilute hydrochloric acid.
After adjusting the pH to 3.5, dehydration and washing the slurry,
It was dried at a temperature of 100 ° C. Dried at 800 ° C for 1 hour
The product of the present invention was obtained by firing. The product of the present invention is a white powder.
If it gets wet with oil etc., it will turn into a complexion color and as a base material for cosmetics.
It was suitable.
【００１８】実施例７
鉄元素を９％含有する合成フッ素金雲母１００ｇ（レ−
ザ−式５０％平均径２０ミクロン、ＢＥＴ比表面積３ｍ
２／ｇ ）を水１リットルに分散させ、これに硫酸アル
ミニウム（Ａｌ２（ＳＯ４）３・１８Ｈ２Ｏ）２００ｇ
を蒸留水で１リットルに希釈した液を加えた。この懸濁
液を撹拌しアンモニア水でＰＨを７に調整しながら、７
０℃で２時間反応させた。反応終了後、スラリ−を脱水
洗浄し、約１００℃の温度で乾燥した。乾燥物を８００
℃で１時間焼成して本発明品を得た。本発明品は、白色
粉体であるが油等に濡れると肌色に発色し、化粧品の基
材として好適なものであった。
比較例１
実施例１の鉄元素を含有しない合成フッ素金雲母を使用
し、実施例１と同様な方法で複合マイカ粉体を得た。こ
の本発明品の紫外線遮断率は、６０％であった。Example7
100 g of synthetic fluorophlogopite containing 9% of iron element
The-type 50% average diameter 20 microns, BET specific surface area 3 m
2 / g) in 1 liter of water and add
Minium (Al2 (SO4) 3.18H2O) 200g
Was diluted with distilled water to 1 liter and added. This suspension
While stirring the liquid and adjusting the pH to 7 with aqueous ammonia,
The reaction was carried out at 0 ° C for 2 hours. After the reaction is complete, the slurry is dehydrated
It was washed and dried at a temperature of about 100 ° C. 800 dried products
The product of the present invention was obtained by firing at 1 ° C for 1 hour. The product of the present invention is white
It is a powder, but when it gets wet with oil etc. it develops a complexion color and is the basis of cosmetics.
It was a suitable material.
Comparative Example 1
The synthetic fluorine phlogopite containing no iron element of Example 1 is used.
Then, a composite mica powder was obtained in the same manner as in Example 1. This
The ultraviolet blocking rate of the product of the present invention was 60%.
【００１９】[0019]
【効果】以上述べたごとく、本発明によれば、鉄元素を
含有する合成マイカ粉体を母材とすることによって、紫
外線遮断率が著しく向上するほか、母材が着色している
ので、乾燥時は略白色であるが液体に濡れると肌色に発
現するというこの種従来の複合マイカ粉体には全く見ら
れない性質を示すと共に、パ−ル顔料とした場合は、従
来のパ−ル顔料にない紫外線遮断効果と、独特の色彩を
帯びたパ−ル感を発現する。[Effect] As described above, according to the present invention, by using the synthetic mica powder containing the iron element as the base material, the ultraviolet ray blocking ratio is remarkably improved, and the base material is colored, so that it is dried. When it is a white pigment, it is almost white, but when it gets wet with a liquid, it develops a skin color. It has an unprecedented UV blocking effect and a uniquely colored pearly feeling.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｃ０９Ｋ 3/00 １０４ Ｃ０９Ｋ 3/00 １０４Ｚ // Ａ６１Ｋ 7/42 Ａ６１Ｋ 7/42 (72)発明者 小杉 哲史 愛知県豊橋市明海町１番地 トピー工業 株式会社豊橋製造所内 (56)参考文献 特開 平１−143822（ＪＰ，Ａ) 特開 平５−230394（ＪＰ，Ａ) 特開 昭62−16408（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/02 A61K 7/00 C01B 33/20 C09C 1/42 C09K 3/00 104 A61K 7/42 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI C09K 3/00 104 C09K 3/00 104Z // A61K 7/42 A61K 7/42 (72) Inventor Satoshi Kosugi Akemi, Toyohashi City, Aichi Prefecture Town No. 1 Topy Industries Co., Ltd., Toyohashi Plant (56) Reference JP-A-1-143822 (JP, A) JP-A-5-230394 (JP, A) JP-A-62-16408 (JP, A) (58) ) Fields surveyed (Int.Cl. 7 , DB name) A61K 7/02 A61K 7/00 C01B 33/20 C09C 1/42 C09K 3/00 104 A61K 7/42
Claims (4)
チタン、酸化セリウム、酸化亜鉛、二酸化珪素、酸化ア
ルミニウム及び酸化ジルコニウムからなる群から選ばれ
た１種以上の酸化物で被覆した複合マイカ粉体であっ
て、乾燥時は略白色であるが、液体に濡れると肌色に変
色することを特徴とする紫外線遮断作用を有する複合マ
イカ粉体。To 1. A synthetic mica powder containing iron elements, titanium oxide, cerium oxide, zinc oxide, with silicon dioxide, one or more oxides selected from aluminum oxide and zirconium arm or Ranaru group Coated mica powder
The color is almost white when dry, but it changes to a complexion when wet with liquid.
A composite mica powder having an ultraviolet blocking action characterized by being colored .
及び酸化亜鉛の１種以上である請求項１に記載の複合マ
イカ粉体。2. The oxide is titanium oxide or cerium oxide.
And at least one of zinc oxide .
Squid powder .
に記載の複合マイカ粉体。3. The oxide is titanium oxide.
The composite mica powder described in.
チタン及び／または酸化ジルコニウムで被覆したことを
特徴とする紫外線遮断作用を有し、乾燥時は略白色であ
るが、液体に濡れると肌色に変色するパ−ル顔料。4. A synthetic mica powder containing iron element has an ultraviolet blocking action, characterized in that coated with titanium oxide and / or oxide zirconium arm, when dry substantially white Der
However, it is a pearlescent pigment that turns skin-colored when wet with liquid .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP07020594A JP3427195B2 (en) | 1994-03-16 | 1994-03-16 | Composite mica powder with ultraviolet blocking action |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP07020594A JP3427195B2 (en) | 1994-03-16 | 1994-03-16 | Composite mica powder with ultraviolet blocking action |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07258031A JPH07258031A (en) | 1995-10-09 |
| JP3427195B2 true JP3427195B2 (en) | 2003-07-14 |
Family
ID=13424795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP07020594A Expired - Lifetime JP3427195B2 (en) | 1994-03-16 | 1994-03-16 | Composite mica powder with ultraviolet blocking action |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3427195B2 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5741355A (en) * | 1995-01-27 | 1998-04-21 | Topy Industries, Limited | Pearlescent pigment, and paint composition, cosmetic material, ink and plastics blended with the new pearlescent pigment |
| TW390901B (en) * | 1995-01-27 | 2000-05-21 | Topy Ind | Pearlescent pigment, and paint composition, cosmetic material, ink and plastics blended with the new pearlescent pigment |
| DE59813594D1 (en) * | 1997-08-09 | 2006-07-27 | Merck Patent Gmbh | Sunscreen with ultraspectral protection |
| JP4251685B2 (en) * | 1998-04-22 | 2009-04-08 | メルク株式会社 | UV absorber |
| JP2000179069A (en) * | 1998-12-17 | 2000-06-27 | Inax Corp | Ultraviolet absorbing building material |
| JP2002114964A (en) * | 2000-10-06 | 2002-04-16 | Kunimine Industries Co Ltd | Ultraviolet-protecting agent and its manufacturing method |
| KR100337000B1 (en) * | 2000-10-14 | 2002-05-17 | 장길완 | Method for Preparing Pearlescent Pigments by Coating Metal Oxides on the Synthesized Mica |
| SE524197C2 (en) * | 2002-03-12 | 2004-07-06 | Ove Karlsson Med Ove Karlsson | New composition |
| JP5789800B2 (en) * | 2011-03-31 | 2015-10-07 | 河合石灰工業株式会社 | Boehmite composite particles and method for producing the same |
| CN107236237A (en) * | 2017-06-30 | 2017-10-10 | 常州思宇环保材料科技有限公司 | A kind of preparation method of ultraviolet shielded material |
-
1994
- 1994-03-16 JP JP07020594A patent/JP3427195B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07258031A (en) | 1995-10-09 |
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