JP3417740B2 - Method and apparatus for reducing organic sludge - Google Patents

Method and apparatus for reducing organic sludge

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Publication number
JP3417740B2
JP3417740B2 JP24614595A JP24614595A JP3417740B2 JP 3417740 B2 JP3417740 B2 JP 3417740B2 JP 24614595 A JP24614595 A JP 24614595A JP 24614595 A JP24614595 A JP 24614595A JP 3417740 B2 JP3417740 B2 JP 3417740B2
Authority
JP
Japan
Prior art keywords
sludge
anaerobic digestion
membrane
membrane separation
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP24614595A
Other languages
Japanese (ja)
Other versions
JPH0985298A (en
Inventor
克之 片岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Original Assignee
Ebara Corp
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Filing date
Publication date
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Priority to JP24614595A priority Critical patent/JP3417740B2/en
Publication of JPH0985298A publication Critical patent/JPH0985298A/en
Application granted granted Critical
Publication of JP3417740B2 publication Critical patent/JP3417740B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、下水生汚泥、余剰
活性汚泥、混合生汚泥などの有機性汚泥を大幅に減量化
する方法及び装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for significantly reducing the amount of organic sludge such as sewage raw sludge, surplus activated sludge and mixed raw sludge.

【0002】[0002]

【従来の技術】下水の活性汚泥処理施設などからは下水
汚泥、余剰活性汚泥や生汚泥などの有機性汚泥(以下、
「原汚泥」ということもある)が大量に発生しており、
それらの発生量は下水道の施設の拡充に伴って増大しつ
つあり、現在その増大する有機性汚泥の処理処分が最大
の問題となっている。従来、有機性汚泥は脱水助剤(有
機高分子ポリマーなど)を添加し、脱水機で脱水された
後、焼却処分されているが、汚泥が大量の場合には、脱
水機及び焼却炉が大規模なものになり、設備費、維持管
理費などが多大の額となり、焼却処分は経済的にも困難
のものとなっている。
2. Description of the Related Art Organic sludge such as sewage sludge, excess activated sludge and raw sludge (hereinafter,
A lot of "raw sludge" is generated,
The amount of those generated is increasing with the expansion of sewerage facilities, and the treatment and disposal of the increasing organic sludge is now the biggest problem. Conventionally, organic sludge has been dehydrated with a dehydration aid (organic polymer, etc.) and then incinerated after being dehydrated. However, if a large amount of sludge is used, the dehydrator and incinerator are large. It becomes a large scale, the equipment cost, the maintenance cost, etc. are large, and the incineration becomes economically difficult.

【0003】この問題を解決する手段の1つとして、有
機性汚泥の減量化があり、それには種々の手段が提案さ
れている。汚泥の減量化の手段の1つとして従来より生
物学的な汚泥減量化方法があり、それには嫌気性消化法
や好気性消化法が知られている。しかし、それら生物学
的な汚泥減量化方法は、長時間の滞留時間を必要とする
割りには減量化率が劣り、また難脱水性汚泥を生ずる等
の問題があり、最近はほとんど採用されていないのが実
情である。また、有機性汚泥の全量に対しアルカリ処
理、加熱処理を行ってから嫌気性消化をする方法も知ら
れているが、薬品費、加熱費が高額であり、経済的な面
などから実用性が乏しいなどの欠点がある。また、活性
汚泥を直接オゾン処理して、可溶化した後、曝気槽に返
送する方法(特開平7−116685号公報)も提案さ
れているが、オゾン製造のコストが高額であり、経済的
な面などから実用性が乏しいなどの欠点がある。
One of the means for solving this problem is to reduce the amount of organic sludge, and various means have been proposed for that purpose. As one of means for reducing sludge, there has been a biological biological method for reducing sludge, and an anaerobic digestion method and an aerobic digestion method are known. However, these biological sludge reduction methods have problems that the reduction rate is inferior for a long residence time and that hardly-dewatering sludge is produced. The reality is that there is none. In addition, a method is also known in which all of the organic sludge is subjected to alkali treatment and heat treatment and then subjected to anaerobic digestion, but the chemical cost and heating cost are high, and it is not practical from the economical aspect. There are drawbacks such as scarcity. Further, a method has also been proposed in which activated sludge is directly subjected to ozone treatment, solubilized, and then returned to an aeration tank (JP-A-7-116685), but the cost of ozone production is high and economical. There are drawbacks such as poor practicality in terms of aspects.

【0004】[0004]

【解決しようとする課題】有機性廃水の活性汚泥処理法
などが効率的に実施できるようにするためには、そこか
ら生ずる有機性汚泥の減量化が長時間の処理を要せず、
また多くの熱エネルギーを要することなく行えるように
する技術の開発が必要である。本発明は、嫌気性消化法
を見直し、他の減量化と組合せ有機性汚泥を効果的に減
量化する新技術を提供することを課題とするものであ
る。また、本発明は、有機性汚泥を効果的に減量化する
ことによって、汚泥脱水機、焼却炉に持ち込まれる汚泥
量を大きく減少させ、汚泥処理工程を全体としてより合
理化することを課題とするものである。
[Problems to be solved] In order to efficiently carry out the activated sludge treatment method of organic wastewater, reduction of the amount of organic sludge generated therefrom does not require long-term treatment,
In addition, it is necessary to develop technology that can be performed without requiring much heat energy. An object of the present invention is to review the anaerobic digestion method and provide a new technique for effectively reducing the amount of organic sludge in combination with other reductions. Further, the present invention aims to significantly reduce the amount of sludge brought into the sludge dehydrator and incinerator by effectively reducing the amount of organic sludge, and to further rationalize the sludge treatment process as a whole. Is.

【0005】[0005]

【課題を解決するための手段】本発明は、生物学的な嫌
気性消化、アルカリ加熱処理、生物学的な好気的消化に
よる可溶化処理を新規な態様で結合させ、有機性汚泥の
効果的な減量化を実現したものである。すなわち、本発
明は、以下に示す手段により前記の課題を解決すること
ができた。 (1)有機性汚泥を膜分離型嫌気性消化工程で嫌気性消
化と膜分離を行い、膜分離液は系外に排水し、膜分離さ
れた固形消化汚泥の大部分は前記嫌気性消化工程に還流
し、残部は可溶化槽に移送しアルカリ加熱処理して可溶
化した後、好気性消化工程に移送してさらに好気性消化
することを特徴とする有機性汚泥の減量化方法である。(2)有機性汚泥を導入し嫌気性消化と膜分離を行い、
膜分離液を系外に排水する膜分離型嫌気性消化装置、膜
分離された固形消化汚泥の大部分を前記嫌気性消化装置
に還流する手段、残部をアルカリ加熱処理する可溶化装
置、及び該可溶化装置からの可溶化汚泥を好気性消化を
行う消化装置を有することを特徴とする汚泥の減量化装
置。 ここで、好気性消化のための手段として、廃水の生
物処理の曝気槽を使用することができる。なお、嫌気性
消化工程に膜分離手段を組み込み、嫌気性消化工程内で
膜分離して固液分離する処理法を膜分離型嫌気性消化と
いう。
The present invention combines the effects of organic sludge in a novel manner by combining biological anaerobic digestion, alkaline heat treatment and solubilization treatment by biological aerobic digestion. This is a real reduction. That is, the present invention was able to solve the above problems by the means shown below. (1) The organic sludge is subjected to anaerobic digestion and membrane separation in a membrane separation type anaerobic digestion step, the membrane separation liquid is drained to the outside of the system, and most of the solid digested sludge membrane separated is subjected to the anaerobic digestion step. The method is a method for reducing the amount of organic sludge, which comprises the steps of: refluxing to, and transferring the rest to a solubilization tank, subjecting to alkali heat treatment for solubilization, and then transferring to an aerobic digestion step for further aerobic digestion. (2) Introduce organic sludge, perform anaerobic digestion and membrane separation,
Membrane separation type anaerobic digester, membrane that drains the membrane separation liquid to the outside of the system
Most of the separated solid digested sludge is anaerobic digester.
Means for refluxing into the tank
And aerobically digest the solubilized sludge from the solubilizer.
Sludge reduction equipment characterized by having a digester for performing
Place Here, an aeration tank for biological treatment of wastewater can be used as a means for aerobic digestion. A treatment method of incorporating a membrane separation means in the anaerobic digestion step and performing membrane separation and solid-liquid separation in the anaerobic digestion step is called membrane separation type anaerobic digestion.

【0006】[0006]

【発明の実施の形態】本発明の有機性汚泥の減量化方法
及び装置を図1により説明する。図1において、有機性
汚泥1をまず嫌気性消化工程2において嫌気性消化し、
生物学的に分解され易い部分を減量化する。嫌気性消化
の処理は、従来知られている嫌気性消化の方法により行
うものであって、消化されるのは原汚泥中のSS重量の
60%程度である。この嫌気性消化工程2によって有機
性汚泥は低分子の可溶性の有機化合物となる結果、有機
性汚泥はその分減量化される。
BEST MODE FOR CARRYING OUT THE INVENTION Organic sludge weight reduction method of the present invention
The apparatus will be described with reference to FIG. In FIG. 1, organic sludge 1 is first anaerobically digested in anaerobic digestion step 2,
Reduce the amount of biodegradable parts. The anaerobic digestion process is performed by a conventionally known anaerobic digestion method, and about 60% of the SS weight in the raw sludge is digested. By this anaerobic digestion step 2, the organic sludge becomes a low molecular weight soluble organic compound, and as a result, the amount of the organic sludge is reduced accordingly.

【0007】嫌気性消化工程2中には膜分離手段3(U
F膜ユニットなど)が組み込まれており、消化汚泥を固
液分離し、SSがほとんどゼロの分離液4を得る。また
分離された固形の膜分離汚泥の大部分5は嫌気性消化工
程2の汚泥濃度を所定の濃度に維持するために還流す
る。嫌気性消化工程2内の汚泥濃度は汚泥の攪拌が充分
に行える6%程度以下にとどめるのが良い。汚泥濃度が
高すぎると粘度が大きくなりすぎ充分汚泥を攪拌できな
くなる。膜分離汚泥の残部6は系外の可溶化槽7に抜き
出し加熱およびアルカリ処理して汚泥を可溶化する。そ
の後可溶化汚泥9を好気性消化工程8に供給し、好気性
微生物によって可溶化汚泥を炭酸ガスと水に分解する。
可溶化汚泥9を好気性消化工程8に供給する代わりに汚
水の活性化汚泥処理工程の曝気槽に送って好気性微生物
によって生物学処理をしても良い。可溶化汚泥9を好気
性消化工程8で生物学処理をすると原汚泥の90重量%
が減量される。
During the anaerobic digestion step 2, the membrane separation means 3 (U
(F membrane unit etc.) is incorporated, solid-liquid separation of digested sludge is carried out, and separation liquid 4 having almost zero SS is obtained. Further, most of the separated solid membrane separation sludge 5 is refluxed to maintain the sludge concentration in the anaerobic digestion step 2 at a predetermined concentration. The sludge concentration in the anaerobic digestion step 2 should be kept to about 6% or less at which sludge can be sufficiently stirred. If the sludge concentration is too high, the viscosity becomes too large and the sludge cannot be sufficiently stirred. The remaining portion 6 of the membrane separation sludge is taken out to a solubilization tank 7 outside the system and heated and treated with an alkali to solubilize the sludge. After that, the solubilized sludge 9 is supplied to the aerobic digestion step 8, and the solubilized sludge is decomposed into carbon dioxide gas and water by aerobic microorganisms.
Instead of supplying the solubilized sludge 9 to the aerobic digestion step 8, the solubilized sludge may be sent to the aeration tank of the activated sludge treatment step for biological treatment with aerobic microorganisms. When solubilized sludge 9 is biologically treated in aerobic digestion step 8, 90% by weight of the original sludge
Is reduced.

【0008】消化汚泥の可溶化のための加熱温度は50
〜100℃、加熱時間は1〜6時間、アルカリ処理のp
Hは10〜13程度が好適である。アルカリ剤は苛性ソ
ーダが好ましい。嫌気性消化の結果、汚泥量が減少し、
かつアルカリ加熱処理するのは原汚泥の一部で済むの
で、原汚泥に対してアルカリ加熱処理する方法に比較し
て、加熱費、アルカリ剤費が大きく減少する。嫌気性消
化時間は、15〜30日間程度で充分である。従来のよ
うに原汚泥に対してアルカリ加熱処理すると、汚泥から
膜の閉鎖を促進するなんらかの有機物が溶出するので、
この後で膜分離すると膜閉鎖が起こる。本発明では原汚
泥を嫌気性消化した後膜分離するので膜閉鎖の原因とな
る物質が少なく、本発明は有利である。嫌気性消化工程
に膜分離を組み込み分離液側への汚泥の流出を完全に阻
止することは本発明において必須の因子である。なぜな
ら、膜分離でなく、沈殿分離や遠心分離などの固液分離
手段を採用すると、分離液側に多量の汚泥がリークして
しまい、可溶化処理されないで汚泥が系外に流出してし
まうからである。図1に本発明の工程フローの1実施例
を示した。
The heating temperature for solubilizing digested sludge is 50.
~ 100 ° C, heating time 1 ~ 6 hours, alkali treatment p
H is preferably about 10 to 13. The alkaline agent is preferably caustic soda. As a result of anaerobic digestion, the amount of sludge decreases,
In addition, since only a part of the raw sludge needs to be subjected to the alkali heat treatment, the heating cost and the alkali agent cost are greatly reduced as compared with the method of subjecting the raw sludge to the alkali heat treatment. An anaerobic digestion time of about 15 to 30 days is sufficient. Alkali heat treatment of raw sludge as in the past causes some organic matter that promotes membrane closure to elute from the sludge.
Subsequent membrane separation results in membrane closure. In the present invention, since the raw sludge is anaerobically digested and then the membrane is separated, there are few substances causing the membrane closure, and the present invention is advantageous. It is an essential factor in the present invention to incorporate membrane separation in the anaerobic digestion process and completely prevent the sludge from flowing out to the separation liquid side. This is because if solid-liquid separation means such as precipitation separation or centrifugation is adopted instead of membrane separation, a large amount of sludge will leak to the separation liquid side, and the sludge will flow out of the system without being solubilized. Is. FIG. 1 shows one embodiment of the process flow of the present invention.

【0009】[0009]

【実施例】以下に、本発明の有機性汚泥の減量化方法の
実施例を示す。しかし、本発明は以下の実施例によって
制限されるものではない。 図1に基づく実施例:下水の混合生汚泥(固形物濃度2
4.0g/リットル)を前記図1に示した処理フローに
従って処理した。嫌気性消化工程で使用する消化槽の容
積は150リットル、嫌気性消化の温度は35℃で、原
汚泥の供給量は10リットル/日(240g/日)であ
る。固液分離には膜分離法を適用し、膜は分画分子量1
5万のUF膜を用いた。
EXAMPLES Examples of the method for reducing the amount of organic sludge of the present invention will be shown below. However, the present invention is not limited to the examples below. Example based on FIG. 1: Sewage mixed raw sludge (solids concentration 2
4.0 g / liter) was treated according to the treatment flow shown in FIG. The volume of the digestion tank used in the anaerobic digestion step is 150 liters, the anaerobic digestion temperature is 35 ° C., and the amount of raw sludge supplied is 10 liters / day (240 g / day). Membrane separation method is applied for solid-liquid separation, and the molecular weight of the membrane is 1
50,000 UF membranes were used.

【0010】10リットル容積の可溶化槽に固液分離さ
れた消化汚泥の固形物を供給し、アルカリ加熱処理を行
った。加熱温度は80℃、pHは12である。その後、
可溶化汚泥を好気性消化工程に供給し、好気性微生物に
よって可溶化汚泥を生物学的に処理する。滞留時間は7
日間で特に加熱は行わない。この条件で下水処理工程か
ら発生する混合生汚泥の減量処理を行ったところ、残渣
汚泥の発生量は18〜20g/日であり、原汚泥の90
%以上が分解消滅した。比較のため、アルカリ加熱処理
と後続の好気性消化を削除して、前記実施例と同様の処
理を行ったところ残渣汚泥の発生量は86〜90g/日
であり、本発明に比較し、汚泥の減量の効率は大きく劣
っていた。
The solid matter of the digested sludge, which had been solid-liquid separated, was supplied to a solubilization tank having a volume of 10 liters and subjected to an alkali heat treatment. The heating temperature is 80 ° C. and the pH is 12. afterwards,
The solubilized sludge is supplied to the aerobic digestion process, and the solubilized sludge is biologically treated by aerobic microorganisms. Residence time is 7
No particular heating is performed during the day. When the reduction treatment of the mixed raw sludge generated from the sewage treatment process was performed under these conditions, the amount of residual sludge generated was 18 to 20 g / day, which was 90% of that of the original sludge.
% Or more decomposed and disappeared. For comparison, when the alkali heat treatment and the subsequent aerobic digestion were deleted and the same treatment as in the above example was performed, the amount of residual sludge generated was 86 to 90 g / day, which was compared to the present invention. The efficiency of weight loss was significantly inferior.

【0011】[0011]

【発明の効果】本発明によれば、生物学的な汚泥減量化
のみによって汚泥減量化をするのではないので、生物学
的な汚泥減量化の時間が短縮でき、また先に生物学的な
汚泥減量化を行い、かつ分離水は除去し、固形消化汚泥
の一部を可溶化するので加熱費およびアルカリ消費量を
大幅に削減することができ、かつ有機性汚泥の減量効果
が大きい。さらに、生物学的な汚泥減量化方法を併用せ
ず、原汚泥全体をアルカリ加熱処理する場合より汚泥脱
水機の規模が大幅に縮小できた。
According to the present invention, since the sludge reduction is not performed only by the biological sludge reduction, the biological sludge reduction time can be shortened and the biological sludge reduction can be performed first. Since the sludge volume is reduced, the separated water is removed, and a part of the solid digested sludge is solubilized, the heating cost and alkali consumption can be significantly reduced, and the organic sludge volume reduction effect is great. Furthermore, the scale of the sludge dewatering machine could be greatly reduced compared to the case where the entire raw sludge was heat-treated with alkali without using the biological sludge reduction method.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1は、本発明において、嫌気性消化工程、膜
分離工程、アルカリ加熱処理工程及び好気性消化工程を
行う方法の場合を示す。
FIG. 1 shows a case of a method of performing an anaerobic digestion step, a membrane separation step, an alkali heat treatment step and an aerobic digestion step in the present invention.

【符号の説明】[Explanation of symbols]

1 有機性汚泥 2 嫌気性消化工程 3 膜分離手段 4 分離液 5 固形分離汚泥 6 固形分離汚泥 7 可溶化槽 8 好気性消化工程 9 可溶化汚泥 1 organic sludge 2 Anaerobic digestion process 3 Membrane separation means 4 Separation liquid 5 Solid separation sludge 6 Solid separation sludge 7 Solubilization tank 8 Aerobic digestion process 9 Solubilized sludge

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) C02F 11/00 - 11/20 C02F 3/12 ─────────────────────────────────────────────────── ─── Continuation of front page (58) Fields surveyed (Int.Cl. 7 , DB name) C02F 11/00-11/20 C02F 3/12

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 有機性汚泥を膜分離型嫌気性消化工程で
嫌気性消化と膜分離を行い、膜分離液は系外に排水し、
膜分離された固形消化汚泥の大部分は前記嫌気性消化工
程に還流し、残部は可溶化槽に移送しアルカリ加熱処理
して可溶化した後、好気性消化工程に移送してさらに好
気性消化することを特徴とする有機性汚泥の減量化方
法。
1. An organic sludge is subjected to anaerobic digestion and membrane separation in a membrane separation type anaerobic digestion step, and the membrane separation liquid is discharged to the outside of the system,
Most of the membrane-separated solid digested sludge is refluxed to the anaerobic digestion step, the rest is transferred to a solubilization tank and alkali-heated for solubilization, and then transferred to the aerobic digestion step for further aerobic digestion. A method for reducing the amount of organic sludge, which comprises:
【請求項2】 有機性汚泥を導入し嫌気性消化と膜分離2. Anaerobic digestion and membrane separation by introducing organic sludge
を行い、膜分離液を系外に排水する膜分離型嫌気性消化Membrane-separated anaerobic digestion that drains the membrane separation liquid to the outside of the system
装置、膜分離された固形消化汚泥の大部分を前記嫌気性Most of the equipment and membrane-digested solid digested sludge are anaerobic
消化装置に還流する手段、残部をアルカリ加熱処理するMeans for refluxing to digester, heat treatment with alkali
可溶化装置、及び該可溶化装置からの可溶化汚泥を好気Aerobic solubilizer and solubilized sludge from the solubilizer
性消化を行う消化装置を有することを特徴とする汚泥のSludge characterized by having a digester for sexual digestion
減量化装置。Weight reduction device.
JP24614595A 1995-09-25 1995-09-25 Method and apparatus for reducing organic sludge Expired - Fee Related JP3417740B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24614595A JP3417740B2 (en) 1995-09-25 1995-09-25 Method and apparatus for reducing organic sludge

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CA3207201A1 (en) 2014-03-20 2015-09-24 Bl Technologies, Inc. Wastewater treatment with primary treatment and mbr or mabr-ifas reactor
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