JP3415191B2 - Manufacturing method of high-strength hot-dip galvanized steel sheet - Google Patents
Manufacturing method of high-strength hot-dip galvanized steel sheetInfo
- Publication number
- JP3415191B2 JP3415191B2 JP09915193A JP9915193A JP3415191B2 JP 3415191 B2 JP3415191 B2 JP 3415191B2 JP 09915193 A JP09915193 A JP 09915193A JP 9915193 A JP9915193 A JP 9915193A JP 3415191 B2 JP3415191 B2 JP 3415191B2
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- steel sheet
- vol
- hot
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- Heat Treatment Of Sheet Steel (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、高張力溶融亜鉛めっき
鋼板の製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a high-strength hot-dip galvanized steel sheet.
【０００２】[0002]
【従来の技術】従来、溶融亜鉛めっき鋼板は、車体防錆
性能の向上を目的として広く自動車車体材料として用い
られてきた。一方、自動車の車体軽量化を目的として、
車体材料にプレス加工性の優れた高張力鋼板を使用する
傾向が高まっている。2. Description of the Related Art Heretofore, hot-dip galvanized steel sheets have been widely used as materials for automobile bodies for the purpose of improving rust-preventive performance of vehicle bodies. On the other hand, in order to reduce the weight of the car body,
There is an increasing tendency to use high-tensile steel plates with excellent press workability as body materials.
【０００３】一般に、高張力鋼板には、Ｓｉ，Ｍｎ，
Ｐ，Ｃｒなどの合金元素が添加されている。これらの元
素を多量に含有する鋼板を、溶融亜鉛めっき設備で焼鈍
・めっきしようとすると、鋼板表面の加熱によってこれ
らの元素、特にＳｉが選択的に酸化され、鋼板表層に拡
散されるため、これらの酸化物が濃化し、鋼板表面で皮
膜を形成する。これらの酸化物は還元焼鈍でも還元され
ず、溶融亜鉛との濡れ性を著しく阻害し、めっき密着性
を悪くする。それにより、鋼板に溶融亜鉛が付着しな
い、いわゆる不めっきがしばしば起こる。In general, high-strength steel sheets include Si, Mn,
Alloying elements such as P and Cr are added. When a steel sheet containing a large amount of these elements is to be annealed / plated in a hot dip galvanizing facility, these elements, particularly Si, are selectively oxidized by the heating of the steel sheet surface and diffused to the surface layer of the steel sheet. The oxide of is thickened and forms a film on the surface of the steel sheet. These oxides are not reduced even by reduction annealing, significantly impair the wettability with molten zinc, and deteriorate the plating adhesion. As a result, so-called non-plating, in which molten zinc does not adhere to the steel sheet, often occurs.
【０００４】優れたプレス加工性を得るためには、Ｓ
ｉ，Ｍｎ，Ｐ，Ｃｒなどの合金元素が添加されている高
張力鋼板を、８００℃以上の高温で焼鈍する必要がある
が、焼鈍温度を高くすると、これらの元素、特にＳｉの
表面濃化が顕著になり、めっき濡れ性を悪くし、著しい
不めっきを生じる。このため、プレス加工性の優れた高
張力鋼板を溶融亜鉛めっきすることはできなかった。In order to obtain excellent press workability, S
It is necessary to anneal a high-tensile steel plate to which alloy elements such as i, Mn, P, and Cr are added at a high temperature of 800 ° C. or higher. However, if the annealing temperature is increased, the surface concentration of these elements, particularly Si, is increased. Markedly deteriorates the wettability of the plating, resulting in significant non-plating. For this reason, hot-dip galvanizing of high-tensile steel sheets with excellent press workability has not been possible.
【０００５】これらを改善する従来の方法としては、特
開昭５５−１２２８６５号公報のようにあらかじめ鋼板
を酸化し、その後還元することにより合金元素の酸化物
皮膜の形成を抑制する方法がある。しかしながら、この
方法は、ＮＯＦ（無酸化炉）の空気比を制御するもので
あり、鋼板表面はバーナーの炎または排ガスにより加熱
され、その雰囲気で酸化または還元されるものである。
従って、微妙な空気比の変化により鋼板表面のＦｅ酸化
物量が変化し安定性を欠く。As a conventional method of improving these, there is a method of suppressing the formation of an oxide film of an alloy element by oxidizing a steel sheet in advance and then reducing it, as in JP-A-55-122865. However, this method controls the air ratio of a NOF (non-oxidizing furnace), and the steel sheet surface is heated by the flame of a burner or exhaust gas, and is oxidized or reduced in the atmosphere.
Therefore, the amount of Fe oxide on the surface of the steel sheet changes due to a slight change in the air ratio, resulting in lack of stability.
【０００６】その対策として、特開平４−２０２６３０
号公報のように鋼板をある空気比で、酸化速度が一定値
以上すなわち酸化膜の厚みがある範囲になるように酸化
し、その後還元・めっきする方法がある。しかし、この
方法でもってしても、空気比で鋼板表面のＦｅ酸化物量
を制御する以上、微妙な空気比の変化により鋼板表面の
Ｆｅ酸化物量が変化し安定性を欠くことは避けられな
い。これは従来の雰囲気が図１のＯ2 が０．２％以下の
領域であるため、空気比の変化によりＯ2 量が大きく変
化すると、鋼板のＦｅ酸化物量が変化してしまうからで
ある。[0006] As a countermeasure, Japanese Patent Laid-Open No. 4-202630
There is a method of oxidizing a steel sheet with a certain air ratio so that the oxidation rate is a certain value or more, that is, the thickness of the oxide film is within a certain range, and then performing reduction / plating, as in Japanese Patent Laid-Open Publication No. 2003-242242. However, even with this method, as long as the Fe oxide amount on the steel sheet surface is controlled by the air ratio, it is inevitable that the Fe oxide amount on the steel sheet surface changes due to a subtle change in the air ratio, resulting in lack of stability. This is because the conventional atmosphere is a region in which O 2 in FIG. 1 is 0.2% or less, and therefore, when the O 2 amount greatly changes due to the change of the air ratio, the Fe oxide amount of the steel sheet changes.
【０００７】[0007]
【発明が解決しようとする課題】鋼中にＳｉ，Ｍｎ，
Ｐ，Ｃｒなどの合金元素を多量に含有する鋼板に溶融亜
鉛めっきをするためには、これらの元素の表面濃化を抑
制する必要がある。この表面濃化を抑制する方法として
は、上記のようにあらかじめ酸化し、その後還元するこ
とによって酸化物皮膜の形成を抑制する方法があるが、
これは空気比によって酸化皮膜の厚みを調製するという
ことのみであって、安定性に欠ける。本発明は実際の酸
化処理時の雰囲気を直接抑制することによって、鋼中に
Ｓｉ，Ｍｎ，Ｐ，Ｃｒなどの合金元素を多量に含有する
鋼板に不めっきを生ずることなく溶融亜鉛めっきを施す
方法を提供することを目的とするものである。Problems to be Solved by the Invention Si, Mn,
In order to hot-dip galvanize a steel sheet containing a large amount of alloying elements such as P and Cr, it is necessary to suppress surface enrichment of these elements. As a method of suppressing this surface thickening, there is a method of suppressing the formation of an oxide film by previously oxidizing and then reducing as described above,
This is only to adjust the thickness of the oxide film by the air ratio, and lacks stability. The present invention is a method for directly hot-dip galvanizing a steel sheet containing a large amount of alloying elements such as Si, Mn, P and Cr in a steel sheet without causing non-plating by directly controlling the atmosphere during the actual oxidation treatment. It is intended to provide.
【０００８】[0008]
【課題を解決するための手段】本発明は、高張力鋼板の
溶融亜鉛めっき方法において、Ｓｉ０．１ｗｔ％以上
で、Ｓｉ，Ｍｎ，およびＣｒを合計で１．０ｗｔ％以上
含有する高張力鋼板をＯ 2 を０．０１〜５ｖｏｌ％，Ｈ
2 Ｏを２ｖｏｌ％以上含む雰囲気中で酸化処理後、Ｈ2
を３ｖｏｌ％以上含む雰囲気中で還元焼鈍し、溶融めっ
きすることを特徴とする高張力溶融亜鉛めっき鋼板の製
造方法を提供するものである。ここで、酸化処理の雰囲
気は、ＣＯ2 またはＣＯ2 とＣＯを含み、このときＣＯ
／ＣＯ2 の比が０〜０．９、（ＣＯ＋ＣＯ2 ）／全ガス
の比が４〜１５であるのが好ましい。酸化処理時の鋼板
温度は４００〜８００℃がよく、このとき形成される鋼
板表面のＦｅ酸化物は６００〜１８００ｍｇ／ｍ2 が好
ましい。また、本発明は、上記のようにして得た溶融亜
鉛めっき鋼板を加熱合金化する高張力合金化溶融亜鉛め
っき鋼板の製造方法を提供する。SUMMARY OF THE INVENTION The present invention is directed to high strength steel sheets.
In the hot dip galvanizing method, Si 0.1 wt% or more
And the total amount of Si, Mn, and Cr is 1.0 wt% or more.
O containing high strength steel sheet 20.01 to 5 vol%, H
2After oxidation treatment in an atmosphere containing 2 vol% or more of O, H2
Is annealed in an atmosphere containing 3 vol% or more of
Of high-strength hot-dip galvanized steel sheet characterized by
It provides a manufacturing method. Where the atmosphere of the oxidation treatment
Qi, CO2Or CO2And CO, including CO
/ CO2Ratio of 0 to 0.9, (CO + CO2) / All gases
It is preferable that the ratio is 4 to 15. Steel sheet during oxidation treatment
The temperature is preferably 400-800 ° C, and the steel formed at this time
Fe oxide on the plate surface is 600-1800 mg / m2Is good
Good The present invention also relates to the molten alloy obtained as described above.
High-strength alloyed hot-dip zinc alloy for heat-alloying lead-plated steel sheet
A method for manufacturing a hardened steel sheet is provided.
【０００９】[0009]
【作用】本発明は、高張力鋼板の溶融亜鉛めっきあるい
は合金化溶融亜鉛めっきに際し、焼鈍雰囲気を調整する
ことにより、Ｓｉ，Ｍｎ，Ｐ，Ｃｒなどの合金元素の選
択酸化を抑制し、めっき性を阻害する酸化物皮膜の形成
を防いで溶融亜鉛めっき濡れ性を確保することにより、
不めっきを生じないようにする方法に関する。The present invention suppresses the selective oxidation of alloying elements such as Si, Mn, P, and Cr by adjusting the annealing atmosphere during hot dip galvanizing or alloying hot dip galvanizing of high-strength steel sheets, thereby improving the plating property. By preventing the formation of an oxide film that inhibits
The present invention relates to a method for preventing non-plating.
【００１０】高張力鋼板には高張力を得るため、鋼中に
Ｓｉ，Ｍｎ，Ｐ，Ｃｒなどの合金元素が添加されてい
る。そのうちＳｉは０．１ｗｔ％以上添加することによ
り鋼板の高張力化に効果がある。さらに、Ｓｉ，Ｍｎ，
およびＣｒの添加量の合計が１．０ｗｔ％以上のときに
本発明の効果が顕現する。In order to obtain high tensile strength, high tensile strength steel sheets are added with alloying elements such as Si, Mn, P and Cr. Of these, Si is effective in increasing the tensile strength of the steel sheet by adding 0.1 wt% or more. Furthermore, Si, Mn,
The effect of the present invention becomes apparent when the total amount of Cr and Cr added is 1.0 wt% or more.
【００１１】この高張力鋼板を焼鈍するのであるが、溶
融亜鉛めっき設備で鋼板を焼鈍するに際して、炉内の雰
囲気を制御することは本発明の重要な構成要件で、それ
によって添加元素の選択酸化を防ぎ良好なめっき性が確
保される。すなわち、酸化処理時に、バーナーを鋼板よ
り遠ざけるなどしてその炎などで直接酸化されないよう
にしたうえ、排気されるガスの測定値に基づいて、燃焼
ガスの送入口と異なる部分から雰囲気ガスを送入して、
炉内の雰囲気を極めて限られた範囲に直接制御すること
によって酸化させることが肝要である。This high-strength steel sheet is annealed. When the steel sheet is annealed by the hot dip galvanizing equipment, controlling the atmosphere in the furnace is an important constituent of the present invention. And good plating property is secured. That is, during the oxidation treatment, the burner is kept away from the steel plate so that it is not directly oxidized by the flame, and based on the measured value of the exhaust gas, the atmosphere gas is sent from a part different from the combustion gas inlet. Enter,
It is essential to oxidize by directly controlling the atmosphere in the furnace within a very limited range.
【００１２】鋼中にＳｉ，Ｍｎ，Ｐ，Ｃｒなどの合金元
素が含有された高張力鋼板を、Ｏ2が０．０１〜５ｖｏ
ｌ％，Ｈ2 Ｏが２ｖｏｌ％以上という極めて限られた範
囲に制御し残部をＮ2 とした雰囲気中で酸化処理後、Ｈ
2 ３ｖｏｌ％以上で残部をＮ 2 とした雰囲気で還元焼鈍
すると、高張力溶融亜鉛めっき鋼板の製造に十分な溶融
亜鉛めっき濡れ性を保持するようになる。Alloying elements such as Si, Mn, P, and Cr in steel
The high-tensile steel sheet containing the element2Is 0.01-5vo
1%, H2Very limited range of O of 2 vol% or more
To control the balance and N2After the oxidation treatment in the atmosphere
2The balance is N at 3 vol% or more 2Reduction annealing in an atmosphere
Then, sufficient melting for the production of high-strength hot-dip galvanized steel sheet
It keeps the zinc plating wettability.
【００１３】酸化処理において、Ｏ2 量を０．０１〜５
ｖｏｌ％の範囲としたのは、Ｏ2 が０．０１ｖｏｌ％未
満では、鋼板のＦｅ酸化物量が少なく合金元素の表面濃
化を防止することができずに、めっき性を劣化させ、Ｏ
2 が５ｖｏｌ％を超えると、鋼板のＦｅ酸化物量が多く
なり後の焼鈍で十分に還元されず、めっき性を劣化させ
るからである。In the oxidation treatment, the amount of O 2 is 0.01-5.
The range of vol% is set so that when O 2 is less than 0.01 vol%, the amount of Fe oxide in the steel sheet is small and the surface concentration of alloying elements cannot be prevented, and the plating property is deteriorated.
This is because if 2 exceeds 5 vol%, the amount of Fe oxide in the steel sheet increases and the steel sheet is not sufficiently reduced in the subsequent annealing, which deteriorates the plating property.
【００１４】しかし、従来は、空気比により鋼板のＦｅ
酸化物量を制御していたし、雰囲気が、図１のＯ2 が
０．２ｖｏｌ％以下の領域であるため、空気比の変化で
Ｏ2 量が大きく変化すると、鋼板のＦｅ酸化物量が変化
して、その制御に安定性を欠いていた。そのため、本発
明ではＯ2 量が少々変化しても鋼板のＦｅ酸化物量が一
定になる範囲、すなわち目標Ｆｅ酸化物量が容易に得ら
れ、効果が発揮されやすくなる０．３〜２ｖｏｌ％の範
囲がより好ましい。However, conventionally, the Fe ratio of the steel sheet is changed by the air ratio.
Since the amount of oxides was controlled and the atmosphere was in the region where O 2 in FIG. 1 was 0.2 vol% or less, when the amount of O 2 changed significantly due to the change of the air ratio, the amount of Fe oxides in the steel sheet changed. , Lacked stability in its control. Therefore, in the present invention, the range in which the Fe oxide amount of the steel sheet is constant even if the O 2 amount changes slightly, that is, the target Fe oxide amount is easily obtained, and the effect is easily exhibited, in the range of 0.3 to 2 vol% Is more preferable.
【００１５】また、Ｏ2 だけ含まれた雰囲気中では、合
金元素の表面濃化を抑制するのに十分なＦｅ酸化物量は
得られず、Ｈ2 Ｏも同時に一定量以上含む必要があるこ
とを我々は見いだした。図１に雰囲気中の酸素量とＦｅ
酸化物量の関係を示すが、Ｈ 2 Ｏが１ｖｏｌ％ではほと
んど酸化されず、２ｖｏｌ％では著しく酸化されてい
る。Also, O2In the atmosphere included only,
The amount of Fe oxide sufficient to suppress the surface enrichment of the gold element is
Not obtained, H2O must also be included in a certain amount or more at the same time.
We found. Figure 1 shows the oxygen content and Fe in the atmosphere.
The relation of the amount of oxide is shown, but H 2When O is 1 vol%
It is not oxidized at all and is significantly oxidized at 2 vol%
It
【００１６】Ｈ2 Ｏ ２ｖｏｌ％以上としたのは、露点
＋２０℃以上すなわち図２よりＨ2Ｏが２ｖｏｌ％以上
でないと合金元素の表面濃化を抑制するのに十分なＦｅ
酸化物量が得られず、めっき性が劣化するためである。H 2 O 2 vol% or more means that the dew point is not less than + 20 ° C., that is, if H 2 O is not more than 2 vol% as shown in FIG.
This is because the amount of oxide cannot be obtained and the plating property is deteriorated.
【００１７】この酸化処理雰囲気は、Ｃ化合物を含有す
る燃料の燃焼ガスを熱源として使用する場合にはＣＯ2
またはＣＯ2 とＣＯを含有することとなり、その場合Ｃ
Ｏ／ＣＯ2 比が０〜０．９で、全ガスに占めるＣＯ＋Ｃ
Ｏ2 の割合が４〜１５ｖｏｌ％の範囲となり、本発明は
このような雰囲気において効果を発揮する。特にＣＯ／
ＣＯ2 比が０．１〜０．８の時に、よりいっそうの効果
が発揮される。ＣＯ／ＣＯ2 比とＯ2 の適正範囲を図３
に示すが、ＣＯ／ＣＯ2 比が高いすなわちＣＯが多いと
き、Ｏ2 は、２ＣＯ＋Ｏ2 →２ＣＯ2 の反応に使用され
る量が多くなり、鋼板の酸化に使用される量が減ってく
る。そのため、規定量に加えて余分のＯ2 が必要にな
る。しかし、その逆のＣＯ／ＣＯ2 比が小さいときは、
ＣＯ2 生成用のＯ2 が少なくてよくなるので、規定量の
Ｏ2 で十分になる。This oxidizing treatment atmosphere is CO 2 when the combustion gas of the fuel containing the C compound is used as a heat source.
Or it contains CO 2 and CO, in which case C
O / CO 2 ratio of 0 to 0.9, CO + C in all gases
The proportion of O 2 is in the range of 4 to 15 vol%, and the present invention is effective in such an atmosphere. Especially CO /
Further effects are exhibited when the CO 2 ratio is 0.1 to 0.8. Fig. 3 shows the appropriate range of CO / CO 2 ratio and O 2 .
As shown in Table 1, when the CO / CO 2 ratio is high, that is, the amount of CO is large, the amount of O 2 used in the reaction of 2CO + O 2 → 2CO 2 increases, and the amount used for the oxidation of the steel sheet decreases. Therefore, extra O 2 is required in addition to the specified amount. However, when the opposite CO / CO 2 ratio is small,
Because O 2 in CO 2 for generating is well less will suffice defined amount of O 2.
【００１８】酸化温度４００〜８００℃の範囲としたの
は、本発明で用いる雰囲気で酸化した場合、Ｆｅ酸化物
量が６００〜１８００ｍｇ／ｍ2 となるのはこの範囲だ
からである。Ｆｅ酸化物量を６００〜１８００ｍｇ／ｍ
2 の範囲としたのは、Ｆｅ酸化物量が６００ｍｇ／ｍ2
未満では、鋼板のＦｅ酸化物量が少なく合金元素の表面
濃化を防止することができず、めっき性を劣化させるか
らであり、Ｆｅ酸化物量が１８００ｍｇ／ｍ2 を越える
と、鋼板のＦｅ酸化物量が多すぎ、後の還元焼鈍で十分
還元されなかった未還元物が残り、めっき性を劣化させ
るからである。The reason why the oxidation temperature is in the range of 400 to 800 ° C. is that the amount of Fe oxide is 600 to 1800 mg / m 2 when oxidized in the atmosphere used in the present invention. Fe oxide amount of 600 to 1800 mg / m
The range of 2 is that the amount of Fe oxide is 600 mg / m 2
When the Fe oxide content is less than 1800 mg / m 2 , the Fe oxide content of the steel sheet is too small to prevent the surface concentration of the alloy element from being prevented and the plating property is deteriorated. Is too much, and unreduced substances that have not been sufficiently reduced in the subsequent reduction annealing remain and deteriorate the plating property.
【００１９】この酸化処理後、Ｈ2 が３ｖｏｌ％以上で
残部がＮ2 の雰囲気中、８００〜８８０℃で還元焼鈍す
るが、Ｈ2 が３ｖｏｌ％未満では還元量が少なく未還元
物が残り、不めっきが発生する。その後、溶融めっきあ
るいはさらに合金化処理することによって高張力溶融亜
鉛めっき鋼板あるいは合金化溶融亜鉛めっき鋼板を製造
することができる。After this oxidation treatment, reduction annealing is carried out at 800 to 880 ° C. in an atmosphere of H 2 of 3 vol% or more and the balance of N 2 , but when H 2 is less than 3 vol%, the amount of reduction is small and unreduced products remain. Non-plating occurs. Then, hot-dip galvanized steel sheet or alloyed hot-dip galvanized steel sheet can be manufactured by hot-dip galvanizing or further alloying treatment.
【００２０】[0020]
【実施例】以下に実施例に基づき本発明を具体的に説明
する。
（実施例）表１に示す組成の冷延鋼板を溶融亜鉛めっき
設備で酸化・還元・めっきして、溶融亜鉛めっき鋼板を
製造した。ＣＯ／ＣＯ2 は０〜１．０，Ｏ2 は０．００
１〜８ｖｏｌ％，Ｈ2 Ｏは１〜２０ｖｏｌ％、残部はＮ
2 の雰囲気で酸化処理した後、Ｈ2 ２〜２０ｖｏｌ％、
残部はＮ2 の雰囲気中で還元焼鈍し、溶融めっきした。
還元焼鈍は、鋼Ｎｏ．１が８１０℃、鋼Ｎｏ．２が８７
０℃、鋼Ｎｏ．３が８４０℃で行った。また、めっき浴
は、Ａｌを０．１４％添加した浴で、めっき浴温度は、
４８０℃とした。そのめっき外観の判定を表２に示す
が、本発明範囲外で酸化処理および還元焼鈍した場合、
点状の不めっきが発生した。しかし、本発明範囲内で酸
化処理および還元焼鈍した場合、表面外観は良好で、不
めっきは発生しなかった。また、同様にして製造した溶
融亜鉛めっき鋼板を、加熱合金化処理して合金化溶融亜
鉛めっき鋼板を製造した。そのめっき外観の判定も表３
に示すが、本発明範囲外で酸化処理および還元焼鈍した
場合、合金化むらが発生した。しかし、本発明範囲内で
酸化処理および還元焼鈍した場合、表面外観は良好だっ
た。EXAMPLES The present invention will be specifically described below based on examples. (Example) A cold-rolled steel sheet having the composition shown in Table 1 was oxidized, reduced and plated in a hot-dip galvanizing facility to produce a hot-dip galvanized steel sheet. CO / CO 2 is 0 to 1.0, O 2 is 0.00
1 to 8 vol%, H 2 O is 1 to 20 vol%, and the balance is N
2 to 20% by volume of H 2 after oxidation treatment in the atmosphere of 2 ,
The rest was reduction-annealed in N 2 atmosphere and hot-dipped.
Reduction annealing is performed for steel No. No. 1 is 810 ° C., steel No. 2 is 87
0 ° C, steel No. 3 was performed at 840 ° C. The plating bath was a bath containing 0.14% Al added, and the plating bath temperature was
The temperature was 480 ° C. The judgment of the plating appearance is shown in Table 2. When the oxidation treatment and the reduction annealing are performed outside the scope of the present invention,
Spot-like non-plating occurred. However, when the oxidation treatment and the reduction annealing were carried out within the scope of the present invention, the surface appearance was good and no plating occurred. Further, the hot-dip galvanized steel sheet produced in the same manner was heat-alloyed to produce an alloyed hot-dip galvanized steel sheet. The judgment of the plating appearance is also shown in Table 3.
However, when the oxidation treatment and the reduction annealing were performed outside the scope of the present invention, uneven alloying occurred. However, when the oxidation treatment and the reduction annealing were performed within the scope of the present invention, the surface appearance was good.
【００２１】 [0021]
【００２２】[0022]
【表１】 [Table 1]
【表２】 [Table 2]
【００２３】[0023]
【表３】 [Table 3]
【表４】 [Table 4]
【００２４】[0024]
【発明の効果】以上述べたように、本発明による雰囲気
で酸化・還元処理を行うことによって、Ｓｉ，Ｍｎ含有
高張力鋼板であっても、普通鋼と同様な不めっきのない
溶融亜鉛めっき鋼板あるいは合金化溶融亜鉛めっき鋼板
が製造できる。As described above, by performing the oxidation / reduction treatment in the atmosphere according to the present invention, the hot-dip galvanized steel sheet having no unplating, which is the same as the ordinary steel, can be used even for the high-strength steel sheets containing Si and Mn. Alternatively, a galvannealed steel sheet can be manufactured.
【図面の簡単な説明】[Brief description of drawings]
【図１】 酸化雰囲気中のＯ2 量とＦｅ酸化物生成量の
関係を示す図である。FIG. 1 is a diagram showing the relationship between the amount of O 2 in an oxidizing atmosphere and the amount of Fe oxide produced.
【図２】 酸化雰囲気の露点とＨ2 Ｏ量との関係を示す
図である。FIG. 2 is a diagram showing the relationship between the dew point of an oxidizing atmosphere and the amount of H 2 O.
【図３】 酸化雰囲気のＣＯ／ＣＯ2 比とＯ2 量との関
係を示す図である。FIG. 3 is a diagram showing a relationship between a CO / CO 2 ratio and an O 2 amount in an oxidizing atmosphere.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｃ２３Ｃ 2/06 Ｃ２３Ｃ 2/06 8/14 8/14 (72)発明者 森 戸 延 行 千葉県千葉市中央区川崎町１番地 川崎 製鉄株式会社技術研究本部内 (56)参考文献 特開 平５−65612（ＪＰ，Ａ) 特開 平５−51714（ＪＰ，Ａ) 特開 平４−202631（ＪＰ，Ａ) 特開 平３−134147（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) C23C 2/00 - 2/40 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 7 Identification code FI C23C 2/06 C23C 2/06 8/14 8/14 (72) Inventor Morito Extension No. 1 Kawasaki-cho, Chuo-ku, Chiba-shi, Chiba Prefecture Address Kawasaki Steel Works, Ltd. Technical Research Division (56) Reference JP-A-5-65612 (JP, A) JP-A-5-51714 (JP, A) JP-A-4-202631 (JP, A) JP-A 3-134147 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) C23C 2/00-2/40
Claims (5)
て、Ｓｉ０．１ｗｔ．％以上で、Ｓｉ，Ｍｎ，およびＣ
ｒを合計で１．０ｗｔ．％以上含有する高張力鋼板をＯ
2 を０．０１〜５ｖｏｌ％，Ｈ2 Ｏを２ｖｏｌ％以上含
み、ＣＯ／ＣＯ 2 比が０〜０．９であり、（ＣＯ＋ＣＯ
2 ）／全ガスの比が４〜１５ｖｏｌ％である雰囲気中で
鋼板温度４００〜８００℃の条件で酸化処理後、Ｈ2 を
３ｖｏｌ％以上含む雰囲気で還元焼鈍し、溶融めっきす
ることを特徴とする高張力溶融亜鉛めっき鋼板の製造方
法。1. A method of hot dip galvanizing a high-strength steel sheet, comprising: Si 0.1 wt. %, Si, Mn, and C
r is 1.0 wt. % High strength steel sheet containing O
2 0.01~5vol%, of H 2 O or more 2 vol% free
The CO / CO 2 ratio is 0 to 0.9, and (CO + CO 2
2 ) in an atmosphere with a total gas ratio of 4-15 vol%
A method for producing a high-strength hot-dip galvanized steel sheet, which comprises subjecting the steel sheet to an oxidation treatment under a condition of a steel sheet temperature of 400 to 800 ° C. , reduction annealing in an atmosphere containing 3 vol% or more of H 2, and hot dip galvanizing.
て、Ｓｉ０．１ｗｔ．％以上で、ＳｉおよびＭｎを合計
で１．０ｗｔ．％以上含有する高張力鋼板をＯ 2 を０．
０１〜５ｖｏｌ％，Ｈ 2 Ｏを２ｖｏｌ％以上含み、ＣＯ
／ＣＯ 2 比が０〜０．９であり、（ＣＯ＋ＣＯ 2 ）／全
ガスの比が４〜１５ｖｏｌ％である雰囲気中で鋼板温度
４００〜８００℃の条件で酸化処理後、Ｈ 2 を３ｖｏｌ
％以上含む雰囲気で還元焼鈍し、溶融めっきすることを
特徴とする高張力溶融亜鉛めっき鋼板の製造方法。 2. A method for hot dip galvanizing a high-strength steel sheet.
Si 0.1 wt. %, Total of Si and Mn
1.0 wt. % High-strength steel sheet containing 0 % or more of O 2 .
Wherein 01~5vol%, of H 2 O or more 2 vol%, CO
/ CO 2 ratio is 0 to 0.9, (CO + CO 2 ) / total
Steel plate temperature in an atmosphere with a gas ratio of 4 to 15 vol%
After oxidation treatment under conditions of 400 to 800 ° C., 3 vol of H 2
% In an atmosphere containing more than 100%
A method for producing a high-strength hot-dip galvanized steel sheet, which is characterized.
て、Ｓｉを０．１〜０．６ｗｔ．％含有し、Ｍｎを１．
８ｗｔ．％以下含有し、Ｃｒを０．２ｗｔ．％以下含有
し、Ｓｉ，Ｍｎ，およびＣｒを合計で１．０ｗｔ．％以
上含有する高張力鋼板をＯ 2 を０．０１〜５ｖｏｌ％，
Ｈ 2 Ｏを２ｖｏｌ％以上含み、ＣＯ／ＣＯ 2 比が０〜
０．９であり、（ＣＯ＋ＣＯ 2 ）／全ガスの比が４〜１
５ｖｏｌ％である雰囲気中で鋼板温度４００〜８００℃
の条件で酸化処理後、Ｈ 2 を３ｖｏｌ％以上含む雰囲気
で還元焼鈍し、溶融めっきすることを特徴とする高張力
溶融亜鉛めっき鋼板の製造方法。 3. A method for hot dip galvanizing a high-strength steel sheet.
And 0.1 to 0.6 wt. %, And Mn is 1.
8 wt. % Or less, and contains 0.2 wt.% Of Cr. % Or less
And Si, Mn, and Cr in total 1.0 wt. % Or less
The high-strength steel sheet containing above contains 0.01 to 5% by volume of O 2 ,
Contains 2 vol% or more of H 2 O and has a CO / CO 2 ratio of 0
0.9, and the ratio of (CO + CO 2 ) / total gas is 4 to 1
Steel plate temperature 400 to 800 ° C in an atmosphere of 5 vol%
Atmosphere containing 3 vol% or more of H 2 after oxidation treatment under the conditions
High tensile strength characterized by reduction annealing and hot dip coating
Manufacturing method of hot-dip galvanized steel sheet.
８００ｍｇ／ｍ2 のＦｅ酸化物を生成させる請求項１な
いし３のいずれかに記載の高張力溶融亜鉛めっき鋼板の
製造方法。4. The steel sheet surface is 600 to 1 by the oxidation treatment.
The method for producing a high-strength hot-dip galvanized steel sheet according to claim 1, wherein 800 mg / m 2 of Fe oxide is produced.
によって溶融亜鉛めっきした後、さらに加熱合金化処理
を施す高張力合金化溶融亜鉛めっき鋼板の製造方法。 5. A method for producing a high-strength galvannealed steel sheet, which is obtained by hot-dip galvanizing by the method according to any one of claims 1 to 4, and further heat-alloying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09915193A JP3415191B2 (en) | 1993-04-26 | 1993-04-26 | Manufacturing method of high-strength hot-dip galvanized steel sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09915193A JP3415191B2 (en) | 1993-04-26 | 1993-04-26 | Manufacturing method of high-strength hot-dip galvanized steel sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06306561A JPH06306561A (en) | 1994-11-01 |
| JP3415191B2 true JP3415191B2 (en) | 2003-06-09 |
Family
ID=14239696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP09915193A Expired - Fee Related JP3415191B2 (en) | 1993-04-26 | 1993-04-26 | Manufacturing method of high-strength hot-dip galvanized steel sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3415191B2 (en) |
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| EP2933351A4 (en) * | 2012-12-11 | 2016-01-27 | Jfe Steel Corp | Production method for hot-dip galvanized steel sheet |
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| JP4701852B2 (en) * | 2005-06-16 | 2011-06-15 | Ｊｆｅスチール株式会社 | Method for producing hot-dip galvanized steel sheet |
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-
1993
- 1993-04-26 JP JP09915193A patent/JP3415191B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2933351A4 (en) * | 2012-12-11 | 2016-01-27 | Jfe Steel Corp | Production method for hot-dip galvanized steel sheet |
| US9677148B2 (en) | 2012-12-11 | 2017-06-13 | Jfe Steel Corporation | Method for manufacturing galvanized steel sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06306561A (en) | 1994-11-01 |
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