JP3400253B2 - Algae controlling agent and algae controlling method - Google Patents
Algae controlling agent and algae controlling methodInfo
- Publication number
- JP3400253B2 JP3400253B2 JP20997896A JP20997896A JP3400253B2 JP 3400253 B2 JP3400253 B2 JP 3400253B2 JP 20997896 A JP20997896 A JP 20997896A JP 20997896 A JP20997896 A JP 20997896A JP 3400253 B2 JP3400253 B2 JP 3400253B2
- Authority
- JP
- Japan
- Prior art keywords
- algae
- dimethyliminio
- poly
- ethylene
- algae controlling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、各種工場やビル等
の温度調節設備における熱交換用循環水系内などに藻類
が発生することを防止し、スライムなどの形成を抑制す
るための藻類防除剤及び藻類防除方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an algae control agent for preventing the formation of algae in a circulating water system for heat exchange in temperature control equipment such as various factories and buildings and for suppressing the formation of slime. And a method for controlling algae.
【０００２】[0002]
【従来の技術】従来、製紙パルプ工場の抄紙工程、金属
加工油循環工程、工業用冷却水循環工程などの循環水系
内には、藻類、細菌類その他の微生物が繁殖しやすく、
種々の障害を引き起こすことが知られている。特に循環
使用されている用水系でスライムが発生すると配管内の
流れを阻害し、冷却効率を低下させるなどの経済的な損
失につながることが知られている。2. Description of the Related Art Conventionally, algae, bacteria and other microorganisms are easily proliferated in a circulating water system such as a papermaking process at a paper pulp mill, a metal working oil circulation process, and an industrial cooling water circulation process.
It is known to cause various disorders. In particular, it is known that when slime is generated in a water system that is circulated and used, it impedes the flow in the pipe and leads to economical loss such as cooling efficiency reduction.
【０００３】そのために用水系におけるスライムなどの
原因となる藻類の防除剤として、従来から種々の化合物
が提案され使用されてきている。こうした藻類防除剤の
中で、塩素などは効果的ではあるが金属に対して腐食性
を有し、また継続して添加することが必要であって煩わ
しい欠点があり、またイソチアゾロン類の化合物は有効
ではあるが毒性、皮膚刺激性、粘膜刺激性が強く、取扱
いにくいという欠点がある。For this reason, various compounds have been proposed and used as control agents for algae that cause slime and the like in water systems. Among such algae control agents, chlorine and the like are effective, but have corrosiveness to metals, and have the troublesome drawback of requiring continuous addition, and isothiazolone compounds are effective. However, it has a drawback that it is difficult to handle because it has strong toxicity, skin irritation and mucous membrane irritation.
【０００４】また４級アンモニウム化合物は一般に泡立
ちが激しいという欠点があるが、ポリ〔オキシエチレン
（ジメチルイミニオ）エチレン（ジメチルイミニオ）エ
チレンジクロリド〕は実質的に非発泡性であり、しかも
低刺激性であることが知られている（特公昭５３−２３
３７７号）。また、ポリ（ヘキサメチレンビグアニド）
又はその塩も、強力な抗菌性を有することが知られてお
り、藻類の成長抑制にも有効であることが知られている
（特公昭５７−６１００６）。しかし、これらは何れも
用水系に対して単独で使用しても、高濃度にしないと充
分な藻類防除効果を得ることができないという問題があ
った。Further, although quaternary ammonium compounds generally have the drawback of causing a lot of foaming, poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylenedichloride] is substantially non-foaming and has low irritation. It is known to be sexual (Japanese Patent Publication No. 53-23)
377). In addition, poly (hexamethylene biguanide)
Alternatively, its salt is also known to have a strong antibacterial property, and is also known to be effective in suppressing the growth of algae (Japanese Patent Publication No. 57-61006). However, there is a problem that even if any of these is used alone in the water system, a sufficient algae control effect cannot be obtained unless the concentration is made high.
【０００５】[0005]
【発明が解決しようとする課題】本発明者らは、特に循
環水系などに発生する藻類を防除するに適した薬剤につ
いて研究を進めていたところ、上記の公知の化合物のう
ち特定の化合物を組み合わせて使用すると際立った相乗
作用がみられ、低使用量でも効果的な藻類防除効果を得
ることができることを見出した。本発明はかかる新しい
事実に基づいてなされたもので、低毒性で取扱いが容易
であり、低濃度で高い殺藻効果を発揮する、経済的な藻
類防除剤及び藻類防除方法を提供することを目的とした
ものである。The present inventors have been conducting research on a drug suitable for controlling algae particularly in circulating water systems, and found that a specific compound among the above-mentioned known compounds was combined. It was found that the synergistic effect was remarkable when used as a product, and an effective algae control effect could be obtained even in a small amount. The present invention has been made on the basis of such new facts, and an object thereof is to provide an economical algae control agent and an algae control method, which are low in toxicity, easy to handle, and exhibit a high algicidal effect at a low concentration. It is what
【０００６】[0006]
【課題を解決するための手段】上記の目的を達成するこ
とができる本発明の藻類防除剤は、ポリ〔オキシエチレ
ン（ジメチルイミニオ）エチレン（ジメチルイミニオ）
エチレンジクロリド〕（Ａ）と、ポリ（ヘキサメチレン
ビグアニド）又はその塩（Ｂ）とを、有効成分として含
有するものである。The algae control agent of the present invention which can achieve the above object is poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio)].
Ethylene dichloride] (A) and poly (hexamethylene biguanide) or its salt (B) are contained as active ingredients.
【０００７】また本発明の藻類防除方法は、ポリ〔オキ
シエチレン（ジメチルイミニオ）エチレン（ジメチルイ
ミニオ）エチレンジクロリド〕（Ａ）と、ポリ（ヘキサ
メチレンビグアニド）又はその塩（Ｂ）とを、藻類防除
対象水系に対して添加することを特徴とするものであ
る。The method for controlling algae of the present invention comprises poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylenedichloride] (A) and poly (hexamethylenebiguanide) or a salt thereof (B), It is characterized by being added to an algae control target water system.
【０００８】[0008]
【発明の実施の形態】本発明の藻類防除剤におけるＡ成
分のポリ〔オキシエチレン（ジメチルイミニオ）エチレ
ン（ジメチルイミニオ）エチレンジクロリド〕は、ジク
ロロエチルエーテルとＮ，Ｎ，Ｎ′，Ｎ′−テトラメチ
ルエチレンジアミンとの反応により得られるもので、平
均分子量が１０００〜１００００程度のものを使用する
ことができる。BEST MODE FOR CARRYING OUT THE INVENTION Poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylenedichloride], which is the component A in the algae control agent of the present invention, comprises dichloroethyl ether and N, N, N ', N'. -Those obtained by the reaction with tetramethylethylenediamine and having an average molecular weight of about 1,000 to 10,000 can be used.
【０００９】また、本発明の藻類防除剤におけるＢ成分
のポリ（ヘキサメチレンビグアニド）は、平均分子量が
９００〜１８００程度のものが使用できる。しかしその
水溶性の点から、塩酸塩や炭酸塩等の中性塩として使用
することが好ましく、その効果は実質的に同等である。The poly (hexamethylene biguanide) as the component B in the agent for controlling algae of the present invention may have an average molecular weight of about 900 to 1800. However, from the viewpoint of water solubility, it is preferably used as a neutral salt such as a hydrochloride or a carbonate, and the effect is substantially the same.
【００１０】本発明の藻類防除剤におけるＡ成分とＢ成
分との使用比率は、重量で１：１０〜１０：１の範囲が
良く、特に１：５〜５：１の範囲内で優れた相乗効果を
示す。またかかる藻類防除剤を用いて藻類防除対象水系
中の微生物を防除するに当たっては、対象水系に対する
有効成分添加量が１mg/l〜１０００mg/lの範囲内である
ことが好ましい。The ratio of the component A and the component B used in the algae control agent of the present invention is preferably in the range of 1:10 to 10: 1 by weight, and particularly in the range of 1: 5 to 5: 1, excellent synergism is achieved. Show the effect. In controlling microorganisms in the algae control target water system using such algae control agent, the amount of the active ingredient added to the target water system is preferably in the range of 1 mg / l to 1000 mg / l.
【００１１】本発明の藻類防除剤は、上記のＡ成分とＢ
成分とに加えて、更に通常の水処理剤に配合される腐食
防止剤、スケール防止剤、若しくは分散剤などとして既
知の薬品を含むことができる。かかる薬品の例として
は、１−ヒドロキシエチリデン−１，１−ジホスホン
酸、２−ホスホノブタン−１，２，４−トリカルボン
酸、ポリマレイン酸、ポリアクリル酸、ホスフィン酸、
クロム酸又はその塩、正リン酸塩、重合リン酸塩、モリ
ブデン酸塩、亜硝酸塩、ケイ酸塩、亜鉛塩などを挙げる
ことができる。The algal control agent of the present invention comprises the above-mentioned components A and B.
In addition to the components, chemicals known as a corrosion inhibitor, a scale inhibitor, a dispersant, etc., which are added to ordinary water treatment agents, can be included. Examples of such chemicals include 1-hydroxyethylidene-1,1-diphosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, polymaleic acid, polyacrylic acid, phosphinic acid,
Examples thereof include chromic acid or a salt thereof, orthophosphate, polymerized phosphate, molybdate, nitrite, silicate, zinc salt and the like.
【００１２】また、本発明の藻類防除剤に対しては、更
に別なスライムコントロール剤を併用することも可能で
ある。かかる併用可能な薬剤の例として、塩素系殺菌
剤、臭素系殺菌剤、イソチアゾロン化合物、グルタルア
ルデヒド、メチレンビスチオシアネートなどを挙げるこ
とができる。Further, another slime control agent can be used in combination with the algae control agent of the present invention. Examples of such agents that can be used in combination include chlorine-based bactericides, bromine-based bactericides, isothiazolone compounds, glutaraldehyde, and methylenebisthiocyanate.
【００１３】[0013]
（試験方法）２倍に希釈したデトマー（Detmer）培地中
に、前培養したクロレラsp. を１ml当たりの乾燥重量が
0.2 mg となるように懸濁し、Ｌ型試験管に 15 mlずつ
分注する。これに試験用の薬液を所定の濃度となるよう
に添加した後、これらを10000 lxの光を照射して30 rpm
で振とうしながら、30℃で７日間培養を行う。そして７
日後のクロレラsp. の色調を観察し、緑色が消失して微
黄白となる最低の濃度を求める。(Test method) The dry weight per ml of pre-cultured Chlorella sp. In Detmer medium diluted 2-fold.
Suspend to 0.2 mg and dispense 15 ml into L-shaped test tubes. After adding the test chemicals to this to a prescribed concentration, irradiate them with 10000 lx of light and 30 rpm.
Incubate for 7 days at 30 ° C with shaking. And 7
Observe the color tone of Chlorella sp. After a day to find the minimum density at which the green color disappears to give a slightly yellowish white color.
【００１４】ポリ〔オキシエチレン（ジメチルイミニ
オ）エチレン（ジメチルイミニオ）エチレンジクロリ
ド〕（Ａ成分）の１重量％水溶液と、ポリ（ヘキサメチ
レンビグアニド）塩酸塩（Ｂ成分）の１重量％水溶液と
を準備した。これらの溶液をそれぞれ単独、又は組み合
わせて前記のＬ型試験管に添加し、Ａ成分又はＢ成分の
濃度が０mg/lから２０mg/lまで多段階となるように調整
した後、前記の試験方法に従って培養を行い、クロレラ
sp. を殺藻するに必要な最低濃度（mg/l）を求めた。こ
うして得た結果を表１及び図１に示した。1% by weight aqueous solution of poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylenedichloride] (component A) and 1% by weight aqueous solution of poly (hexamethylene biguanide) hydrochloride (component B) Prepared. These solutions are added individually or in combination to the above-mentioned L-type test tube, and the concentration of the A component or the B component is adjusted so as to have multiple steps from 0 mg / l to 20 mg / l, and then the above-mentioned test method Culture according to
The minimum concentration (mg / l) required to kill algae was determined. The results thus obtained are shown in Table 1 and FIG.
【００１５】[0015]
【表１】
この結果をみると、Ａ成分とＢ成分との併用により顕著
な相乗効果があることがわかる。[Table 1] From these results, it can be seen that the combined use of the A component and the B component has a remarkable synergistic effect.
【００１６】[0016]
【発明の効果】本発明の藻類防除剤は、用水に対して低
濃度の使用でも充分な殺滅効果を発揮し、低毒性で安全
なため、使用し易く、長期の使用にも安定で、効果的に
藻類並びにスライムの発生を抑制することができる。EFFECTS OF THE INVENTION The algae control agent of the present invention exhibits a sufficient killing effect even when used at a low concentration in water, has low toxicity and is safe, and is easy to use and stable for long-term use. It is possible to effectively suppress the generation of algae and slime.
【図面の簡単な説明】[Brief description of drawings]
【図１】本発明の藻類防除剤を構成するＡ成分とＢ成分
のクロレラに対する殺藻力に関する相乗効果を示すグラ
フである。FIG. 1 is a graph showing the synergistic effect of the component A and the component B constituting the algae control agent of the present invention on chlorella with respect to algicidal activity.
Ａ ポリ〔オキシエチレン（ジメチルイミニオ）エチ
レン（ジメチルイミニオ）エチレンジクロリド〕
Ｂ ポリ（ヘキサメチレンビグアニド）塩酸塩A poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylene dichloride] B poly (hexamethylene biguanide) hydrochloride
フロントページの続き (56)参考文献 特開 平８−188504（ＪＰ，Ａ) 特開 平６−256107（ＪＰ，Ａ) 特開 昭61−243006（ＪＰ，Ａ) 特開 昭56−97598（ＪＰ，Ａ) 特公 昭53−23377（ＪＰ，Ｂ１) 特公 昭57−61006（ＪＰ，Ｂ１) 国際公開第96／14092（ＷＯ，Ａ１) (58)調査した分野(Int.Cl.7，ＤＢ名) A01N 47/44 A01N 33/12 ＣＡ（ＳＴＮ) ＲＥＧＩＳＴＲＹ（ＳＴＮ) ＪＩＣＳＴファイル（ＪＯＩＳ)Continuation of front page (56) References JP-A-8-188504 (JP, A) JP-A-6-256107 (JP, A) JP-A-61-243006 (JP, A) JP-A-56-97598 (JP , A) JP-B-53-23377 (JP, B1) JP-B-57-61006 (JP, B1) WO 96/14092 (WO, A1) (58) Fields investigated (Int.Cl. 7 , DB) Name) A01N 47/44 A01N 33/12 CA (STN) REGISTRY (STN) JISST file (JOIS)
Claims (2)
オ）エチレン（ジメチルイミニオ）エチレンジクロリ
ド〕（Ａ）と、ポリ（ヘキサメチレンビグアニド）又は
その塩（Ｂ）とを、有効成分として含有することを特徴
とする、藻類防除剤。1. A composition containing poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylenedichloride] (A) and poly (hexamethylenebiguanide) or a salt thereof (B) as active ingredients. A characteristic algae control agent.
オ）エチレン（ジメチルイミニオ）エチレンジクロリ
ド〕（Ａ）と、ポリ（ヘキサメチレンビグアニド）又は
その塩（Ｂ）とを、藻類防除対象水系に対して添加する
ことを特徴とする、藻類防除方法。2. Poly [oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylenedichloride] (A) and poly (hexamethylenebiguanide) or a salt thereof (B) to an algae control target water system. A method for controlling algae, which comprises adding.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20997896A JP3400253B2 (en) | 1996-08-08 | 1996-08-08 | Algae controlling agent and algae controlling method |
| CN 97117316 CN1173967A (en) | 1996-08-08 | 1997-08-07 | Algae control agent and method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20997896A JP3400253B2 (en) | 1996-08-08 | 1996-08-08 | Algae controlling agent and algae controlling method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH1045514A JPH1045514A (en) | 1998-02-17 |
| JP3400253B2 true JP3400253B2 (en) | 2003-04-28 |
Family
ID=16581838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20997896A Expired - Fee Related JP3400253B2 (en) | 1996-08-08 | 1996-08-08 | Algae controlling agent and algae controlling method |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3400253B2 (en) |
| CN (1) | CN1173967A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001240507A (en) * | 1999-12-21 | 2001-09-04 | Nissan Chem Ind Ltd | Antiseptic, anti-fungal and anti-algal agent |
| WO2001093684A2 (en) * | 2000-06-02 | 2001-12-13 | Avecia Inc. | Treatment of circulating water systems |
| JP5638825B2 (en) * | 2010-03-31 | 2014-12-10 | アクアス株式会社 | Algae inhibitor and method for suppressing algae |
| WO2019070794A1 (en) | 2017-10-03 | 2019-04-11 | Bwa Water Additives Uk Limited | Treatment of circulating water systems including well treatment fluids for oil and gas applications |
| CN112724923B (en) * | 2020-12-29 | 2022-11-22 | 广州市白云化工实业有限公司 | Mildew-proof ketoxime-removing type organosilicon sealant and preparation method thereof |
-
1996
- 1996-08-08 JP JP20997896A patent/JP3400253B2/en not_active Expired - Fee Related
-
1997
- 1997-08-07 CN CN 97117316 patent/CN1173967A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN1173967A (en) | 1998-02-25 |
| JPH1045514A (en) | 1998-02-17 |
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