JP3400213B2 - Pack fee - Google Patents
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- Publication number
- JP3400213B2 JP3400213B2 JP28672795A JP28672795A JP3400213B2 JP 3400213 B2 JP3400213 B2 JP 3400213B2 JP 28672795 A JP28672795 A JP 28672795A JP 28672795 A JP28672795 A JP 28672795A JP 3400213 B2 JP3400213 B2 JP 3400213B2
- Authority
- JP
- Japan
- Prior art keywords
- titanium oxide
- pack
- present
- rod
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- Cosmetics (AREA)
Description
【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、皮膚の角栓や老化
した角質を除去する効果に優れ、使用実感(さっぱり感
等)に優れたパック料に関する。さらに詳しくは、棒状
酸化チタンや微粒子金属酸化物を配合することで、これ
らの粉体を皮膚表面に吸着させ、角栓や老化した角質を
除去する効果を高めたパック料に関する。
【0002】
【従来の技術】本発明者らは、公技94−448号、特
願平6−204270号において、棒状酸化チタンなど
の棒状粉体を化粧料に配合する技術を開示した。中でも
棒状酸化チタンはラスティング性に優れているため、ア
イシャドウ等のメイクアップ製品で利用価値が高い。ま
た、微粒子金属酸化物の皮膚に対する付着性が高いこと
は一般に良く知られている。しかしながら、これらの粉
体はメイクアップ化粧料での使用が一般的であり、基礎
化粧品であるパック料に配合した場合の特性は明確でな
かった。
【0003】
【発明の解決しようとする課題】皮膚化粧料の一つとし
てのパック料は、皮膚血行の促進、皮膚の洗浄作用を目
的とするものであり、その製剤の形態としては、オイル
タイプ、ワックスタイプ、ピールオフタイプのものが通
常使用されている。しかしながら、従来のパック料は皮
膚表面の汚れの除去作用は充分とは言えず、特に毛包に
皮脂や角質が固化した状態である角栓を除去する能力に
劣っていた。すなわち、本発明は、優れた角栓除去能力
を有するパック料の開発を行うことを目的とする。
【0004】
【課題を解決するための手段】上記の目的を達成するた
めに、本発明のパック料は次のような構成をとる。すな
わち、(A)長径が1〜10μm、短径が0.01〜1
μmの範囲にある棒状酸化チタン、および(B)平均一
次粒子径が5〜100nmの範囲にある微粒子酸化チタ
ンおよび/又は微粒子無水珪酸を配合したパック料であ
って、バック料100重量部当たり(A)成分を0.0
5〜3重量部、(B)成分を0.5〜20重量部の濃度
で配合することを特徴とするパック料である。
【0005】本発明者らは、これらの粉体のパック料へ
の導入およびパック料としての特徴の把握について鋭意
研究した結果、これらの粉体が角栓や老化した角質に吸
着する傾向を有すること、角栓などの除去能力に非常に
優れていることを見いだした。
【0006】例えば、微粒子酸化チタンを配合した本発
明のパック料を用い、角栓や老化した角質を吸着した部
位のパック料の割断面を電子線マイクロアナライザーを
用いて評価した場合、角栓や老化した角質の周囲にチタ
ンが高濃度で集まっている様子が観察できる。これに対
して、ガラスプレート上に皮膜形成したパック料では、
このような状態は観察されない特徴がある。
【0007】そこで、これらの粉体の濃度と、角栓の除
去効果との比較を行うと、粉体濃度と除去効果の間に相
関関係が認められた。
【0008】すなわち、本発明はこれらの粉体の皮膚へ
の吸着性を利用することで、パック料の性能を向上させ
る技術に関するものである。
【0009】
【発明の実施の形態】以下、本発明の実施の形態につい
て詳述する。
【0010】本発明で用いる棒状酸化チタンおよび微粒
子金属酸化物の粒径の測定方法としては、電子顕微鏡観
察により得られるものを用いる。
【0011】本発明で用いる棒状酸化チタンは、皮膚へ
の吸着性が高い範囲にある、1〜10μmの長径を有す
ることが必要である。また、短径としては、(短径が小
さいほど皮膚への吸着性が高くなるので)0.01〜1
μmが好ましく、さらに好ましくは0.01〜0.5μ
mである。
【0012】本発明で用いる金属酸化物は、皮膚への吸
着性が高い範囲にある、5〜100nmの平均一次粒子
径を有する必要がある。本発明で用いる金属酸化物の種
類としては、酸化チタン、酸化亜鉛、酸化鉄、水酸化
鉄、無水珪酸、酸化アルミニウム、酸化ジルコニウム、
低次酸化チタン、鉄ドーピング酸化チタン、酸化セリウ
ム等が挙げられるが、特に酸化チタン、無水珪酸が好ま
しい。なお、本発明の粒子径の範囲内であれば、形状を
問わない。
【0013】本発明で用いる棒状酸化チタンおよび金属
酸化物は、未処理であっても、また酸化アルミニウム、
二酸化珪素等の無機表面処理やポリアクリル酸等の親水
性化合物を使用した親水性表面処理を行っていても構わ
ない。また、シリコーン、N−アシル化リジン、金属石
鹸、油剤、フッ素化合物等で表面処理されていても構わ
ないが、製剤の安定性などを考慮した場合、未処理もし
くは親水性の表面処理が好ましい。但し、この場合、粉
体のゼータ電位によっては系の安定性が損なわれること
があるため、凝集沈降の生じない範囲にて表面処理をコ
ントロールすることが好ましい。
【0014】本発明で用いる棒状酸化チタンおよび金属
酸化物の配合量としては、皮膚への吸着性が高く、角栓
除去効果の高い範囲にある、パック料100重量部に対
して、それぞれ0.05〜3重量部、0.5〜20重量
部が好ましい。
【0015】本発明のパック料の形態としては、本発明
の目的を達成するため、ピールオフタイプが好ましい。
【0016】本発明のパック料における、皮膜形成剤と
しては、ポリビニルアルコール、ポリビニルピロリド
ン、アルギン酸塩、およびこれらの素材を一部使用した
ポリビニルアルコール/アクリル酸共重合体などの従来
パック料に使用されたことのあるポリマーを使用するこ
とができる。
【0017】本発明のパック料では、上記の各成分以外
に化粧品において従来公知である粉体類、油剤、樹脂、
界面活性剤、紫外線吸収剤、香料、防腐剤、殺菌剤、保
湿剤、粘剤、生理活性成分、溶剤、水等を同時に配合す
ることができる。
【0018】特に粉体類については、シリコーン、アク
リル、ウレタン、ナイロン、ポリスチレン、テフロン、
ポリエチレン、ポリプロピレン、メタクリル樹脂等の樹
脂粉体を配合することが可能である。
【0019】
【実施例】以下、実施例および比較例によって本発明を
詳細に説明する。
【0020】実施例および比較例で用いた化粧料の評価
は、女性計40名のパネラーに対して実施例および比較
例で作製したパック料を鼻の左右にそれぞれ使用しても
らい、乾燥し剥離したパック料の表面に紫外線を当て、
その像をCCDカメラに入力し、画像処理装置を用いて
角栓の数を数えることで評価した。なお、この方法は紫
外線下に角栓が黄色く発光することを利用している。ま
た、評価は表1に示す基準に従って、全パネラーの点数
の合計を人数で割った値を用いて行った。したがって、
値が高いほど角栓の除去効果に優れていることを示して
いる。
【0021】上記評価と共に、パネラーに対して感触面
でのアンケートを行った。分類した代表的な結果を表4
に示す。なお、表4における数字は、質問項目に対して
「はい」と回答したパネラーの割合(%)を示してい
る。
【0022】
【表1】
【0023】実施例1
表2の処方にてピールオフタイプのパック料を作製し
た。なお、配合量は重量%である。
【0024】
【表2】
【0025】ホリビニルアルコールを精製水に80℃の
加熱下に徐々に溶解させた後、各成分を撹拌下に投入し
た。ついで、湿式粉砕装置マイクロス(奈良機械製作所
製)を用いて900rpm で5分間粉砕を行い、脱気し、
チューブに充填して製品とした。
【0026】比較例1
実施例1の微粒子酸化チタン、棒状酸化チタン、シリコ
ーン架橋粉末の代わりに精製水を用いた他は全て同様に
して製品を得た。
【0027】比較例2
実施例1の微粒子酸化チタン、棒状酸化チタンの代わり
に平均一次粒子径0.24μmのシリカ処理酸化チタン
を使用した他は全て同様にして製品を得た。
【0028】比較例3
実施例1の微粒子酸化チタンの代わりに、実施例1で使
用しているものと同じ棒状酸化チタンを使用した他は全
て同様にして製品を得た。
【0029】比較例4
実施例1の棒状酸化チタンの代わりに、精製水を使用し
た他は全て同様にして製品を得た。
【0030】比較例5
実施例1の微粒子酸化チタンの代わりに平均一次粒子径
0.24μmのシリカ処理酸化チタンを使用した他は全
て同様にして製品を得た。
【0031】表3に、実施例1および比較例1〜5の、
角栓除去効果の評価結果を示す。また、表4に、前記の
感触面のアンケート結果を示す。
【0032】
【表3】【0033】
【表4】
【0034】表3の実施例1と比較例との比較から、本
発明の実施例は比較例に比べて優れた角栓除去効果を有
していることが判る。また、表4の結果より、実施例は
苦痛にならない程度の軽度の痛みを感じるが、さっぱり
感も有していることが判る。さらに、皮膚の血行促進効
果も充分にあった。
【0035】比較例1は粉体成分を除いた場合である
が、角栓除去効果に乏しかった。比較例2は微粒子酸化
チタン、棒状酸化チタンの代わりに顔料級酸化チタンを
使用した場合であるが、角栓除去効果、使用実感ともに
劣っていた。比較例3は微粒子酸化チタンを使用せず、
棒状酸化チタンのみを多く配合した例であるが、角栓除
去効果、使用実感ともに劣っていた。比較例4は微粒子
酸化チタンのみを配合した例であるが、実施例と比べて
角栓除去効果、使用実感(剥がす時に皮膚に苦痛になる
痛みを感じる)ともにやや劣っていた。また、比較例5
は微粒子酸化チタンを除いた場合であるが、角栓除去効
果、使用実感ともに劣っていた。
【0036】
【発明の効果】以上のことから、本発明は、角栓や老化
した角質を除去する効果に優れ、かつ使用実感(さっぱ
り感等)に優れたパック料を提供することは明かであ
る。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pack material which has an excellent effect of removing keratin plugs and aged keratin of the skin, and has an excellent practical feeling (such as a refreshing feeling). More specifically, the present invention relates to a pack material in which a rod-like titanium oxide or a fine metal oxide is blended to adsorb these powders on the skin surface to enhance the effect of removing keratin plugs and aged keratin. 2. Description of the Related Art The present inventors have disclosed in Japanese Patent Application Publication No. 94-448 and Japanese Patent Application No. 6-204270 a technique of blending a rod-like powder such as a titanium oxide rod into a cosmetic. Above all, rod-shaped titanium oxide is excellent in lasting properties, and thus has high utility value in makeup products such as eyeshadow. It is generally well known that the particulate metal oxide has high adhesion to the skin. However, these powders are generally used in make-up cosmetics, and their properties when blended in packs, which are basic cosmetics, were not clear. [0003] Packs as one of the skin cosmetics are intended to promote skin blood circulation and cleanse the skin. , Wax type and peel-off type are usually used. However, the conventional packing material was not sufficiently effective in removing dirt from the skin surface, and in particular, was inferior in the ability to remove keratin plugs in which sebum and keratin were solidified in the hair follicle. That is, an object of the present invention is to develop a pack material having excellent keratotic plug removal ability. [0004] In order to achieve the above object, the pack fee of the present invention has the following structure. (A) The major axis is 1 to 10 μm and the minor axis is 0.01 to 1
rod-shaped titanium oxide is in the range of [mu] m, and (B) having an average primary particle size of fine titanium oxide in the range of 5~100nm
Pack fee der blended with down and / or particulates silicic anhydride
The amount of the component (A) is 0.0
5 to 3 parts by weight, 0.5 to 20 parts by weight of the component (B)
It is a pack charge characterized by being blended in . The inventors of the present invention have conducted intensive studies on the introduction of these powders into the packing material and the understanding of the characteristics of the packing material. As a result, these powders have a tendency to be adsorbed on keratin plugs and aged keratin. It was found to be very good at removing corn plugs. For example, when a pack of the present invention containing fine-particle titanium oxide is used and the cut surface of the plug at the site where keratin plugs or aged keratin is adsorbed is evaluated using an electron beam microanalyzer, A high concentration of titanium can be observed around the aged keratin. On the other hand, in the case of a pack material with a film formed on a glass plate,
There is a characteristic that such a state is not observed. [0007] Then, when the concentration of these powders was compared with the effect of removing the plug, a correlation was found between the powder concentration and the removal effect. That is, the present invention relates to a technique for improving the performance of a pack material by utilizing the adsorptivity of these powders to the skin. Embodiments of the present invention will be described below in detail. As a method for measuring the particle diameter of the rod-shaped titanium oxide and the fine metal oxide used in the present invention, a method obtained by observation with an electron microscope is used. The rod-shaped titanium oxide used in the present invention needs to have a long diameter of 1 to 10 μm which has a high range of adsorptivity to the skin. The minor axis is 0.01 to 1 (because the smaller the minor axis, the higher the adsorptivity to the skin).
μm, more preferably 0.01 to 0.5 μm
m. The metal oxide used in the present invention needs to have an average primary particle diameter of 5 to 100 nm within a range having a high adsorptivity to the skin. The types of metal oxides used in the present invention include titanium oxide, zinc oxide, iron oxide, iron hydroxide, silicic anhydride, aluminum oxide, zirconium oxide,
Examples thereof include low-order titanium oxide, iron-doped titanium oxide, and cerium oxide, and titanium oxide and silicic anhydride are particularly preferable. The shape is not limited as long as it is within the range of the particle diameter of the present invention. The rod-shaped titanium oxide and the metal oxide used in the present invention may be untreated, aluminum oxide,
An inorganic surface treatment such as silicon dioxide or a hydrophilic surface treatment using a hydrophilic compound such as polyacrylic acid may be performed. The surface may be treated with silicone, N-acylated lysine, a metal soap, an oil agent, a fluorine compound, or the like. However, in consideration of the stability of the preparation, an untreated or hydrophilic surface treatment is preferable. However, in this case, the stability of the system may be impaired depending on the zeta potential of the powder. Therefore, it is preferable to control the surface treatment within a range in which coagulation and sedimentation does not occur. The amount of the titanium oxide rod and the metal oxide to be used in the present invention is preferably 0.1 to 100 parts by weight of the pack material, which has a high adsorptivity to the skin and a high keratotic plug removing effect. It is preferably from 0.5 to 3 parts by weight and from 0.5 to 20 parts by weight. The form of the pack charge of the present invention is preferably a peel-off type in order to achieve the object of the present invention. As the film-forming agent in the packing material of the present invention, polyvinyl alcohol, polyvinylpyrrolidone, alginate, and conventional packing materials such as a polyvinyl alcohol / acrylic acid copolymer partially using these materials are used. A polymer which has been used can be used. In the packing material of the present invention, in addition to the above-mentioned components, powders, oils, resins and the like conventionally known in cosmetics are used.
Surfactants, ultraviolet absorbers, fragrances, preservatives, bactericides, humectants, adhesives, physiologically active ingredients, solvents, water and the like can be simultaneously added. Particularly for powders, silicone, acrylic, urethane, nylon, polystyrene, Teflon,
It is possible to mix resin powders such as polyethylene, polypropylene and methacrylic resin. The present invention will be described below in detail with reference to examples and comparative examples. The evaluation of the cosmetics used in the examples and comparative examples was conducted by asking the panelists of a total of 40 women to use the pack materials prepared in the examples and comparative examples on the left and right sides of the nose, and then drying and peeling. UV light is applied to the surface of the pack
The image was input to a CCD camera and evaluated by counting the number of horn plugs using an image processing device. This method utilizes the fact that the plug emits yellow light under ultraviolet rays. In addition, the evaluation was performed using the value obtained by dividing the total score of all panelists by the number of people according to the criteria shown in Table 1. Therefore,
The higher the value, the better the keratotic plug removal effect. Along with the above evaluation, a questionnaire was given to the panelists on the touch surface. Table 4 shows representative results of classification.
Shown in The numbers in Table 4 indicate the percentage (%) of panelists who answered "Yes" to the question items. [Table 1] Example 1 A peel-off type pack was prepared according to the formulation shown in Table 2. In addition, the compounding amount is weight%. [Table 2] After gradually dissolving the polyvinyl alcohol in purified water under heating at 80 ° C., each component was charged with stirring. Then, the mixture was pulverized for 5 minutes at 900 rpm using a wet pulverizer Micros (manufactured by Nara Machinery Co., Ltd.), and degassed.
The product was filled in a tube. Comparative Example 1 A product was obtained in the same manner as in Example 1, except that purified water was used instead of the fine particle titanium oxide, rod-shaped titanium oxide, and silicone crosslinked powder. Comparative Example 2 A product was obtained in the same manner as in Example 1 except that the silica-treated titanium oxide having an average primary particle diameter of 0.24 μm was used instead of the fine particle titanium oxide and the rod-shaped titanium oxide. Comparative Example 3 A product was obtained in the same manner as in Example 1 except that the rod-shaped titanium oxide used in Example 1 was used instead of the fine particle titanium oxide. Comparative Example 4 A product was obtained in the same manner as in Example 1, except that purified water was used instead of the rod-shaped titanium oxide. Comparative Example 5 A product was obtained in the same manner as in Example 1, except that silica-treated titanium oxide having an average primary particle diameter of 0.24 μm was used instead of the finely divided titanium oxide. Table 3 shows that Example 1 and Comparative Examples 1 to 5
The evaluation result of the keratotic plug removal effect is shown. Table 4 shows the results of the questionnaire on the touch surface. [Table 3] [Table 4] From the comparison between Example 1 in Table 3 and Comparative Example, it can be seen that the Example of the present invention has an excellent keratotic plug removal effect as compared with Comparative Example. Further, from the results in Table 4, it can be seen that the example feels a slight pain that does not cause pain, but also has a refreshing feeling. Furthermore, the blood circulation promoting effect of the skin was also sufficient. Comparative Example 1 was a case where the powder component was removed, but had a poor keratotic plug removing effect. Comparative Example 2 was a case where pigment-grade titanium oxide was used instead of the fine particle titanium oxide and the rod-shaped titanium oxide. Comparative Example 3 did not use fine particle titanium oxide,
In this example, only the rod-shaped titanium oxide was added in a large amount, but the keratotic plug removing effect and the feeling of use were inferior. Comparative Example 4 was an example in which only the fine particle titanium oxide was blended, but had a slightly inferior effect on the keratotic plug removal effect and practical feeling (feeling pain to the skin when peeled off) as compared with the examples. Comparative Example 5
In the case where the fine particle titanium oxide was removed, the keratotic plug removing effect and the feeling in use were inferior. From the above, it is apparent that the present invention provides a pack material having an excellent effect of removing keratotic plugs and aged keratin and an excellent practical feeling (such as a refreshing feeling). is there.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭60−67404(JP,A) 特開 昭57−112314(JP,A) 特開 昭57−56408(JP,A) 特開 平8−245361(JP,A) 特開 平8−48614(JP,A) 特開 平8−48613(JP,A) 特開 平5−286842(JP,A) 特開 平5−97627(JP,A) 特開 平7−187983(JP,A) 特開 平8−169809(JP,A) 特開 平7−277915(JP,A) 特開 平4−360834(JP,A) (58)調査した分野(Int.Cl.7,DB名) A61K 7/00 - 7/50 CA(STN) REGISTRY(STN)──────────────────────────────────────────────────続 き Continuation of front page (56) References JP-A-60-67404 (JP, A) JP-A-57-112314 (JP, A) JP-A-57-56408 (JP, A) JP-A-8-48614 (JP, A) JP-A-8-48613 (JP, A) JP-A-5-286842 (JP, A) JP-A-5-97627 (JP, A) JP-A-7-187983 (JP, A) JP-A-8-169809 (JP, A) JP-A-7-277915 (JP, A) JP-A-4-360834 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) A61K 7/ 00-7/50 CA (STN) REGISTRY (STN)
Claims (1)
01〜1μmの範囲にある棒状酸化チタン、および
(B)平均一次粒子径が5〜100nmの範囲にある微
粒子酸化チタンおよび/又は微粒子無水珪酸を配合した
パック料であって、バック料100重量部当たり(A)
成分を0.05〜3重量部、(B)成分を0.5〜20
重量部の濃度で配合することを特徴とするパック料。 (57) [Claims 1] (A) The major axis is 1 to 10 μm and the minor axis is 0.1 μm.
Rod- shaped titanium oxide in the range of 01 to 1 μm , and
(B) Fine particles having an average primary particle diameter in the range of 5 to 100 nm;
A pack material containing particulate titanium oxide and / or fine particle silicic acid anhydride, and per 100 parts by weight of a back material (A)
Component is 0.05 to 3 parts by weight, component (B) is 0.5 to 20 parts by weight.
A pack charge characterized by being formulated at a concentration of parts by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28672795A JP3400213B2 (en) | 1995-10-05 | 1995-10-05 | Pack fee |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28672795A JP3400213B2 (en) | 1995-10-05 | 1995-10-05 | Pack fee |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH09104615A JPH09104615A (en) | 1997-04-22 |
JP3400213B2 true JP3400213B2 (en) | 2003-04-28 |
Family
ID=17708242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP28672795A Expired - Lifetime JP3400213B2 (en) | 1995-10-05 | 1995-10-05 | Pack fee |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3400213B2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20000002208A (en) * | 1998-06-17 | 2000-01-15 | 차동천 | Cosmetic composition of sheet type |
KR100376325B1 (en) * | 2000-12-07 | 2003-03-17 | 주식회사 엘지생활건강 | The composition of the sheet pack for removing clog |
WO2004045565A1 (en) * | 2002-11-18 | 2004-06-03 | Kose Corporation | Cosmetic pack preparation |
US9364689B2 (en) | 2009-12-22 | 2016-06-14 | Avon Products, Inc. | Cosmetic compositions comprising fibrous pigments |
-
1995
- 1995-10-05 JP JP28672795A patent/JP3400213B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH09104615A (en) | 1997-04-22 |
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