JP3383019B2 - Manufacturing method of non-ageing soft surface treated original sheet with excellent corrosion resistance after working by continuous annealing - Google Patents

Manufacturing method of non-ageing soft surface treated original sheet with excellent corrosion resistance after working by continuous annealing

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Publication number
JP3383019B2
JP3383019B2 JP20430093A JP20430093A JP3383019B2 JP 3383019 B2 JP3383019 B2 JP 3383019B2 JP 20430093 A JP20430093 A JP 20430093A JP 20430093 A JP20430093 A JP 20430093A JP 3383019 B2 JP3383019 B2 JP 3383019B2
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JP
Japan
Prior art keywords
temperature
continuous annealing
corrosion resistance
annealing
aging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP20430093A
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Japanese (ja)
Other versions
JPH06184644A (en
Inventor
田 輝 昭 山
田 昌 彦 織
連 和 哉 江
野 啓一郎 長
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Nippon Steel Corp
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Nippon Steel Corp
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Publication of JPH06184644A publication Critical patent/JPH06184644A/en
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Publication of JP3383019B2 publication Critical patent/JP3383019B2/en
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  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、錫メッキやクロム酸処
理などの表面処理が施される表面処理原板の硬さレベル
がテンパー度で1〜3の加工後の耐食性に優れた非時効
性表面処理用原板を連続焼鈍で製造する方法に関する。
BACKGROUND OF THE INVENTION The present invention is a non-aging agent which has excellent corrosion resistance after processing when the hardness of the surface-treated original plate which is subjected to surface treatment such as tin plating or chromic acid treatment is 1 to 3 in temper degree. The present invention relates to a method for producing a surface treatment original plate by continuous annealing.

【0002】軟質表面処理鋼板は、かなり厳しいプレス
加工を受ける缶に成形されることが少なくなく、この場
合、軟質表面処理原板に塗装が施された後、厳しいプレ
ス加工が行われる用途も多い。この様な用途に供される
場合、鋼板に要求される特性は、非時効性のみならず鋼
板の結晶粒度が細粒である必要がある。これは、結晶粒
度が大きいと、厳しい加工を受けた部位は、結晶粒径に
比例して肌荒れが発生し、メッキ層や耐食性を確保する
ために塗布された塗膜が損傷し、その部位の耐食性が著
しく劣化するようになる。その限界のG.Snoは、約
9.5番程度であり、この様な加工後の耐食性の劣化を
無くするには鋼板のG.Snoを9.5以上とする必要
がある。
[0002] A soft surface-treated steel sheet is often formed into a can that is subjected to considerably severe pressing, and in this case, the soft surface-treated original plate is often subjected to severe pressing after being coated. When used for such an application, the properties required of the steel sheet are not only the non-aging property, but also the crystal grain size of the steel sheet must be fine. This is because if the crystal grain size is large, the surface that has undergone severe processing will have rough skin in proportion to the crystal grain size, and the coating layer applied to secure the plating layer and corrosion resistance will be damaged, Corrosion resistance is significantly deteriorated. G. of that limit Sno is about 9.5, and in order to eliminate such deterioration of corrosion resistance after working, G.S. Sno needs to be 9.5 or more.

【0003】[0003]

【従来の技術】錫メッキやクロム酸処理などの表面処理
が施されるテンパー度で、1〜3(以下、「T−1〜T
−3」という)の非時効性軟質表面処理用原板は、これ
まで、焼鈍時間が2〜3日も掛かる箱焼鈍法で製造され
てきた。また、加工後の耐食性が要求される用途には焼
鈍温度を低めにするとか、C含有量を高めにする方法で
G.Snoを9.5〜11.0として製造してきた。し
かし、この方法は、バッチ式で且つ焼鈍に2〜3日も要
するため、生産性が極めて悪い欠点があった。
2. Description of the Related Art The degree of temper to which surface treatment such as tin plating or chromic acid treatment is applied is 1 to 3 (hereinafter, "T-1 to T
The non-aging soft surface treatment original plate (referred to as "-3") has been manufactured by a box annealing method which requires an annealing time of 2 to 3 days. For applications requiring corrosion resistance after working, the annealing temperature may be lowered or the C content may be increased. It has been manufactured with Sno as 9.5 to 11.0. However, this method has a drawback that the productivity is extremely poor because it is a batch method and requires 2 to 3 days for annealing.

【0004】生産性が比較的良好な連続焼鈍方式でT−
1〜T−3の非時効性の軟質表面処理原板を製造する方
法としては、極低炭素鋼にTiやNbのような炭化物形
成元素を添加した鋼を用いる方法がある。しかし、この
方法には、次の2つの大きな問題がある。
The continuous annealing method, which has relatively good productivity, is used for T-
As a method of producing the non-aging soft surface-treated original plate of 1 to T-3, there is a method of using steel in which a carbide forming element such as Ti or Nb is added to ultra-low carbon steel. However, this method has the following two major problems.

【0005】第1の問題は、この方法は、TiやNbで
Cを安定な炭化物として固定することにより完全非時効
とする方法であって、実験室レベルでは軟質で完全非時
効な材質が得られるのであるが、現在実用化されている
連続焼鈍設備(以下、「現CAL」という)で製造する
には、TiやNbを非時効性が得られる程度以上に添加
した鋼は、再結晶温度が著しく上昇し、現CALの製造
可能な焼鈍温度の上限を越えてしまうと言う大きな障害
がある。実用上は、TiやNbのような炭化物形成元素
を含有した鋼を用いており、現CAL方式で非時効の軟
質材の製造は、実質的には不可能である。現CALで
は、焼鈍温度を上昇させていくと、鋼板の温度の上昇と
共に鋼板強度が軟化し、炉内を通板させるために付与さ
れている張力によって鋼帯が延びたり、炉内に設置され
ているハースロールの部位で「絞り」と称される板の重
なりしわが発生したりして、炉内破断や、形状不良品が
発生するようになる。この様な不良が発生しない上限の
温度が、連続焼鈍炉の上限温度とされている。
The first problem is that this method is a method of completely non-aging by fixing C as a stable carbide with Ti or Nb. At the laboratory level, a soft and completely non-aging material is obtained. However, in order to manufacture it with continuous annealing equipment (hereinafter referred to as “current CAL”) that is currently in practical use, steel with Ti or Nb added in an amount higher than that at which non-aging is obtained has a recrystallization temperature. Significantly increases and exceeds the upper limit of the annealing temperature at which the current CAL can be manufactured, which is a major obstacle. Practically, steel containing carbide forming elements such as Ti and Nb is used, and it is practically impossible to manufacture a non-aging soft material by the current CAL method. In the current CAL, as the annealing temperature is increased, the strength of the steel sheet softens as the temperature of the steel sheet rises, and the tension applied to pass the steel sheet inside the furnace extends the steel strip or the steel sheet is installed in the furnace. At the portion of the hearth roll, overlapping wrinkles of plates called "throttle" may occur, causing fracture in the furnace and defective products. The upper limit temperature at which such defects do not occur is the upper limit temperature of the continuous annealing furnace.

【0006】第2の問題は、この方法の上記第1の問題
を少しでも緩和するには、C含有量を可能な限り低下さ
せた極低炭素鋼に非時効化に必要な最小限のTiやNb
を添加し、再結晶温度を少しでも低減させる必要がある
が、この極低炭素鋼にTiやNbを添加した現CAL方
式で焼鈍した表面処理原板は、G.Snoが8.0〜1
0.0と加工後の耐食性を確保するには大きすぎるとい
う問題である。
The second problem is that in order to alleviate the above-mentioned first problem of this method, the minimum Ti necessary for non-aging is applied to the ultra-low carbon steel whose C content is reduced as much as possible. Or Nb
Although it is necessary to reduce the recrystallization temperature as much as possible by adding G., the surface-treated original plate annealed by the current CAL method in which Ti or Nb is added to this ultra-low carbon steel is G. Sno is 8.0-1
The problem is that the value is 0.0, which is too large to secure the corrosion resistance after processing.

【0007】本発明のような超短時間連続焼鈍法につい
て、従来から研究がなされており、特公昭36−100
52号公報、特公昭36−21155号公報、特公昭4
0−3020号公報、特公昭46−19781号公報に
開示されている。しかし、上記特公昭36−21155
号公報は、200〜300℃でコイルとして巻き取らね
ばならず酸化の問題、巻き取り設備の問題、巻き取った
コイルの冷却方法或いは冷却時のコイル内外周の不均一
冷却の問題がある。また、上記特公昭36−10052
号公報、特公昭40−3020号公報、特公昭46−1
9781号公報、特公昭40−3020号公報は、何れ
も非時効性のT−1〜T−3の軟質表面処理原板の製造
が不可能である。
The ultra-short continuous annealing method according to the present invention has been studied so far, and is disclosed in Japanese Examined Patent Publication No. 36-100.
52, Japanese Patent Publication No. 36-21155, Japanese Patent Publication No. 4
It is disclosed in Japanese Patent Publication No. 0-3020 and Japanese Patent Publication No. 46-19781. However, the above Japanese Patent Publication No. 36-21155
Japanese Patent Laid-Open Publication No. 2003-242242 has a problem that it must be wound as a coil at 200 to 300 ° C., there is a problem of oxidation, a problem of winding equipment, a cooling method of a wound coil, or a problem of uneven cooling of the inner and outer circumferences of the coil during cooling. In addition, the above Japanese Patent Publication No. 36-10052
Publication, Japanese Patent Publication No. 40-3020, Japanese Publication No. 46-1
In both 9781 and Japanese Patent Publication No. 40-3020, it is impossible to manufacture non-aging soft surface-treated original plates T-1 to T-3.

【0008】[0008]

【発明が解決しようとする課題】本発明は、生産上の障
害も無く、生産性の良い連続焼鈍法によるT−1〜T−
3の加工後の耐食性に優れた、非時効性軟質表面処理原
板の製造方法を提供することを目的としている。
DISCLOSURE OF THE INVENTION The present invention has no problems in production and has good productivity in continuous annealing by T-1 to T-.
It is an object of the present invention to provide a method for producing a non-aging soft surface-treated original plate having excellent corrosion resistance after processing of item 3.

【0009】[0009]

【課題を解決するための手段】本発明者等は、上記課題
を解決するため、鋼成分、熱延条件、冷間圧延条件、連
続焼鈍条件について総合的に検討し、本発明の製造方法
を見い出したものであって、本発明の要旨は下記の通り
である。 (1) C:0.0005〜0.0050%、Mn:
0.05〜0.60%、P:0.001〜0.025
%、S:0.001〜0.025%、solAl:0.
030〜0.120%、N:0.0060超〜0.01
70%、Nb:{7.75×〔C(%)−0.000
4〕×0.65}%〜0.023%、T.O:≦0.0
070%、残部不可避的不純物及び鉄よりなる鋼片を、
通常の条件で加熱し、熱間圧延を行い、640〜750
℃で巻き取り熱延鋼帯とし、85%以上の冷間圧延を行
い、その後、連続焼鈍にて少なくとも500℃以上の温
度域を100℃/s以上で再結晶温度〜850℃に加熱
し3秒以下の保持を行い、その後室温まで冷却する再結
晶焼鈍を行い、次いで、調質圧延を0.6〜3.5%の
範囲で施すことを特徴とする連続焼鈍による加工後の耐
食性に優れた非時効性軟質表面処理原板の製造方法。 (2) 前項(1)の方法に於いて、熱間圧延に際し、
1000〜1180℃に加熱し、通常の条件で熱間圧延
を行うことを特徴とする連続焼鈍による表面処理原板の
製造方法。
In order to solve the above-mentioned problems, the inventors of the present invention comprehensively studied the steel composition, hot rolling conditions, cold rolling conditions, and continuous annealing conditions, and conducted the manufacturing method of the present invention. The present invention has been found and the gist of the present invention is as follows. (1) C: 0.0005 to 0.0050%, Mn:
0.05-0.60%, P: 0.001-0.025
%, S: 0.001 to 0.025%, solAl: 0.
030 to 0.120%, N: more than 0.0060 to 0.01
70%, Nb: {7.75 x [C (%)-0.000
4] × 0.65}% to 0.023%, T.I. O: ≤0.0
070%, the balance unavoidable impurities and steel slab consisting of iron,
Heating under normal conditions, hot rolling, 640-750
Rolled hot-rolled steel strip at 80 ° C., cold rolled at 85% or more, and then continuously annealed at a temperature range of at least 500 ° C. at a recrystallization temperature of up to 850 ° C. at 100 ° C./s or more. Excellent corrosion resistance after processing by continuous annealing characterized by holding for less than a second, then performing recrystallization annealing to cool to room temperature, and then performing temper rolling in the range of 0.6 to 3.5% Method for producing non-aging soft surface-treated original plate. (2) In the method of (1) above, in hot rolling,
A method for producing a surface-treated original plate by continuous annealing, which comprises heating to 1000 to 1180 ° C. and hot rolling under normal conditions.

【0010】以下に、本発明について詳細に述べる。本
発明者等は、安定した非時効化が達成でき、且つ表面処
理原板の耐食性を阻害する介在物(製鋼での脱酸生成
物)の生成の懸念の無いNbを添加する極低炭素鋼を用
いて、生産上の障害も無く、生産性の良い連続焼鈍法に
よるT−1〜T−3の加工後の耐食性に優れた非時効性
軟質表面処理原板の製造法について種々検討した。
The present invention will be described in detail below. The inventors of the present invention have developed an extremely low carbon steel containing Nb that can achieve stable non-aging and does not cause the formation of inclusions (deoxidation products in steelmaking) that inhibit the corrosion resistance of the surface-treated original plate. Using this, various studies were made on a method for producing a non-aging soft surface-treated original plate having excellent corrosion resistance after processing of T-1 to T-3 by a continuous annealing method with good productivity without any problems in production.

【0011】先ず、事前検討として、先に述べた連続焼
鈍法に於いて高温焼鈍が困難であることの原因はハース
ロールに鋼板が接触することに起因するものと考え、高
温域での滞在時間を短くする方法、即ち、現CALと同
じ加熱速度で均熱時間をほぼゼロにして再結晶焼鈍を行
う方法について検討した。しかし、均熱時間がほぼゼロ
の時のNb添加極低炭素鋼の再結晶温度は、均熱時間が
20sec 程度ある場合に比べて著しく上昇することが分
り、実機化が困難であることが判明した。
First, as a preliminary study, it is considered that the difficulty of high temperature annealing in the continuous annealing method described above is caused by the contact of the steel sheet with the hearth roll, and the residence time in the high temperature region is considered. Was investigated, that is, a method of performing recrystallization annealing at the same heating rate as the current CAL with the soaking time being substantially zero. However, it was found that the recrystallization temperature of Nb-added ultra-low carbon steel when the soaking time was almost zero was significantly higher than that when the soaking time was about 20 seconds, making it difficult to put into practical use. did.

【0012】更に、種々の方法について検討し、Nb添
加極低炭素鋼の再結晶温度が、1000℃/s程度の超
急速加熱を行った場合に顕著に低下するという実験結果
を得た。そこで、このことを更に詳細に検討するため、
Nb添加極低炭素鋼の再結晶温度について、成分含有
量、熱延条件、冷間圧延条件、連続焼鈍条件について総
合的に検討し、「C:0.0005〜0.0050%、
Nb:{7.75×〔C(%)−0.0004〕×0.
65}%−0.023%、連続焼鈍にて少なくとも50
0℃以上の温度域を100℃/s以上で再結晶温度〜8
50℃に加熱し、3秒以下の焼鈍を行うこと」を主ポイ
ントとする連続焼鈍による非時効性軟質表面処理原板の
製造が可能となることを見い出した。
Further, various methods were examined, and experimental results were obtained in which the recrystallization temperature of the Nb-added ultra-low carbon steel was remarkably lowered when ultra-rapid heating at about 1000 ° C./s was performed. Therefore, in order to examine this in more detail,
Regarding the recrystallization temperature of the Nb-added ultra-low carbon steel, the content of components, hot rolling conditions, cold rolling conditions, and continuous annealing conditions were comprehensively examined, and "C: 0.0005 to 0.0050%,
Nb: {7.75 x [C (%)-0.0004] x 0.
65}%-0.023%, at least 50 in continuous annealing
Recrystallization temperature in the temperature range of 0 ° C or higher at 100 ° C / s or higher to 8
It has been found that it is possible to manufacture a non-aging soft surface-treated original plate by continuous annealing whose main point is to "heat to 50 ° C. and anneal for 3 seconds or less".

【0013】しかし、得られた鋼板のG.Snoは、
8.5〜10.0で、本発明が目標とする加工後の耐食
性を確保するのに必要なG.Sno:9.5番以上は確
保できなかった。そこで、本発明者等は、非時効性で且
つG.Sno:≧9.5が確保できる条件について種々
検討し、N含有量を0.0050%以上とすることによ
り、G.Sno:≧9.5に細粒化が出来ることを見い
出した。
However, the G.V. Sno is
In the range of 8.5 to 10.0, the G.V. required to secure the corrosion resistance after processing, which is the target of the present invention. Sno: We couldn't secure more than 9.5. Therefore, the present inventors have found that G. Sno: ≧ 9.5, various examinations have been made on the conditions under which the N content is 0.0050% or more. It was found that Sno: ≧ 9.5 can be made into fine particles.

【0014】図1は、本発明のポイントの「連続焼鈍の
加熱に於いて少なくとも500℃以上の温度域を100
℃/s以上で再結晶温度〜850℃に加熱すること」の
効果を示した図である。本発明の方法で製造したC:
0.0022%、Nb:0.019%、solAl:
0.067%、N:0.0075%、スラブ加熱温度
(以下、「SRT」という):1140℃、C.T:6
30℃、冷間圧延率:90%で圧延した0.25mmの冷
延鋼板を、図2に示すヒートサイクルで加熱速度
(αH )と均熱温度(T)を変え、時間(t)を0.1
sec 、冷却速度(αc )を200℃/sとし、熱処理を
行った鋼板の組織を調査し、再結晶の完了する温度を求
めた。その結果を、図1に示す。
FIG. 1 shows that the temperature range of at least 500.degree.
It is the figure which showed the effect of "heating to a recrystallization temperature-850 degreeC above (degreeC) / s." C produced by the method of the present invention:
0.0022%, Nb: 0.019%, solAl:
0.067%, N: 0.0075%, slab heating temperature (hereinafter referred to as “SRT”): 1140 ° C., C.I. T: 6
For a 0.25 mm cold rolled steel sheet rolled at 30 ° C. and a cold rolling rate of 90%, the heating rate (α H ) and the soaking temperature (T) were changed by the heat cycle shown in FIG. 0.1
sec, the cooling rate (α c ) was set to 200 ° C./s, the structure of the heat-treated steel sheet was investigated, and the temperature at which recrystallization was completed was determined. The result is shown in FIG.

【0015】図1から、加熱速度が現CALのような2
0℃/sの場合は、先に述べたように、再結晶温度が顕
著に上昇することが分った。この実験結果は、たとえ、
均熱時間が無くとも、あまりにも再結晶温度が高いので
鋼板の強度の低下が著しくなり、高温部を良好な形状で
通板することは困難であることが容易に予測させ得るも
のである。
From FIG. 1, the heating rate is 2 as in the current CAL.
At 0 ° C./s, it was found that the recrystallization temperature remarkably rises, as described above. The result of this experiment is
Even if there is no soaking time, since the recrystallization temperature is too high, the strength of the steel sheet is significantly reduced, and it can be easily predicted that it is difficult to pass the high temperature portion in a good shape.

【0016】一方、本発明の範囲の100℃/s以上の
超急速加熱速度であれば、Nを多量に含有する鋼率であ
っても、保定時間が殆ど無い条件でも再結晶完了温度の
顕著な低下が得られることが分った。この実験結果によ
って、本発明によれば、生産上の障害も無くT−1〜T
−3の軟質表面処理原板の製造が可能になることが明ら
かになった。
On the other hand, at the ultra-rapid heating rate of 100 ° C./s or more within the range of the present invention, the recrystallization completion temperature is remarkable even at a steel ratio containing a large amount of N and under conditions with little holding time. It was found that a significant decrease was obtained. From this experimental result, according to the present invention, T-1 to T-
It became clear that it is possible to manufacture a soft surface-treated original plate of No. -3.

【0017】このように100℃/s以上で加熱するこ
とにより、従来の20℃/sより再結晶温度が低下する
メカニズムについては必ずしも充分に解明されていない
が、下記AおよびBの効果によるものではないかと推察
される。これらA,Bの効果は、連続焼鈍の加熱に於い
て少なくとも500℃以上の温度域を100℃/s以上
で再結晶温度〜850℃に加熱することにより得られ
た。
Although the mechanism of lowering the recrystallization temperature by heating at 100 ° C./s or more as compared with the conventional 20 ° C./s has not been sufficiently clarified, it is due to the effects of A and B below. It is speculated that it may be. These effects of A and B were obtained by heating at a temperature range of at least 500 ° C. or higher at a recrystallization temperature of 850 ° C. to 850 ° C. at a temperature of 100 ° C./s or higher in heating in continuous annealing.

【0018】A.超急速加熱の場合は、再結晶〜粒成長
の間の時間が余りにも短いので再結晶前、途中、粒成長
の段階に於いてNbCやAlNの微細析出が殆ど起こら
なくなる。その結果、Nb添加の極低炭素鋼を20℃/
s程度のゆっくりした加熱速度で加熱した場合にみられ
る再結晶温度の顕著な上昇がなくなり、超急速加熱を行
うことにより再結晶がより低温で起こるとともに、粒成
長も容易となり軟質材が得られるようになる。 B.超急速加熱の場合は、再結晶のスタート時に於ける
サブグレインの粒界の移動速度並びに粒成長時の粒界の
移動速度が極めて速いので、粒界への偏析元素の粒界へ
の移動が追従しなくなり、粒界の移動を妨げる偏析元素
が少なくなる。その結果、超急速加熱を行うことによ
り、再結晶がより低温で起こるとともに粒成長も容易と
なり、より軟質材が得られるようになった。なお、冷間
圧延率、成分等は、このサブグレインの生成及び大きさ
等に影響を与えているのではないかと考えられる。
A. In the case of ultra-rapid heating, since the time between recrystallization and grain growth is too short, fine precipitation of NbC or AlN hardly occurs during grain growth before or during recrystallization. As a result, Nb-added ultra-low carbon steel was
The remarkable increase in recrystallization temperature observed when heating at a slow heating rate of about s is eliminated, and by performing ultra-rapid heating, recrystallization occurs at a lower temperature and grain growth is facilitated to obtain a soft material. Like B. In the case of ultra-rapid heating, the movement speed of the grain boundaries of the subgrains at the start of recrystallization and the movement speed of the grain boundaries during grain growth are extremely fast, so that the segregation elements move to the grain boundaries. It does not follow and segregation elements that hinder the movement of grain boundaries are reduced. As a result, by performing ultra-rapid heating, recrystallization occurs at a lower temperature, grain growth is facilitated, and a softer material can be obtained. It is considered that the cold rolling rate, components, etc. may affect the generation and size of this subgrain.

【0019】図3は、本発明の目的である非時効性のT
−1〜T−3の軟質表面処理原板を得る方法についての
主要ポイントを示した図である。本発明者等は、本発明
で製造したNを約75ppm 含有する種々のC含有量の熱
延板を用い、90%の冷間圧延率で0.25mmの冷延板
を製造した。次いで、図3に示すヒートサイクルで加熱
速度(αH )を1000℃/s、均熱温度(T)を75
0℃、時間(t)を0.1sec 、冷却速度(αc )を2
50℃/sとし、熱処理を行った焼鈍板に、1.5%の
調質圧延率で調質圧延を行い表面処理原板を製造し、こ
れに錫メッキを施しブリキを製造し、非時効性、硬度並
びに光学顕微鏡での組織を調査した。
FIG. 3 shows the non-aging T which is the object of the present invention.
It is the figure which showed the main points about the method of obtaining the soft surface treatment original plate of -1 to T-3. The present inventors have produced cold-rolled sheets of 0.25 mm at 90% cold rolling rate using the hot-rolled sheets of various C contents containing about 75 ppm of N produced in the present invention. Then, in the heat cycle shown in FIG. 3, the heating rate (α H ) was 1000 ° C./s and the soaking temperature (T) was 75.
0 ° C., time (t) 0.1 sec, cooling rate (α c ) 2
A heat-treated annealed plate at 50 ° C / s is temper-rolled at a temper rolling ratio of 1.5% to produce a surface-treated original plate, which is tin-plated to produce a tin plate, which is non-aging , Hardness and texture under an optical microscope were investigated.

【0020】非時効性の評価は、得られた種々のブリキ
板を塗装焼き付け相当の200℃×30min の熱処理を
施し、引張り試験を行ってYP−E1を測定し、YP−
E1が0.5%未満であるものを非時効性とした。
The non-aging evaluation was performed by subjecting the various tin plates thus obtained to a heat treatment at 200 ° C. for 30 minutes, which is equivalent to baking by coating, and performing a tensile test to measure YP-E1 and YP-E1.
Those with E1 of less than 0.5% were regarded as non-aging.

【0021】また、硬度(HR30T)の測定を行い、T−
1〜T−3の軟質材が得られたか否かの評価を行うと共
に、光学顕微鏡による組織調査で未済結晶粒の有無の調
査も行った。その結果、完全に再結晶が完了したもの
は、本実験範囲内では全てT−3以下の軟質な硬度が得
られた。
Further, the hardness ( HR30T ) was measured and T-
It was evaluated whether or not the soft materials 1 to T-3 were obtained, and the presence or absence of uncompleted crystal grains was also examined by the structure examination with an optical microscope. As a result, all of the completely recrystallized products had a soft hardness of T-3 or less within the range of the present experiment.

【0022】以上の調査結果に基づいて、非時効性が確
保できる条件に付いて整理すると、C含有量が5〜50
ppm の範囲では、Nb含有量を{7.75×〔C(%)
−0.0004〕×0.65}%以上とすると、良好な
加工後の耐食性に優れた非時効性が得られることが明ら
かになった。その適用範囲を、図3に示す。また、未済
結晶粒の残存もなくT−1〜T−3の軟質な材質が得ら
れる範囲は、本発明の条件内では、Nb含有量が、0.
023%を越えると超急速加熱法で再結晶焼鈍を行って
も未再結晶粒が残存するようになり、T−3以下の軟質
な材質が得られなくなるので、図3にNb含有量の上限
として示した。
Based on the above survey results, the conditions for ensuring non-aging can be summarized and the C content is 5 to 50.
In the ppm range, the Nb content is {7.75 × [C (%)
It has been clarified that when the content is −0.0004] × 0.65}% or more, good non-aging resistance with excellent corrosion resistance after processing can be obtained. The applicable range is shown in FIG. Further, in the range where the soft material of T-1 to T-3 can be obtained without remaining unfinished crystal grains, the Nb content is 0.
If it exceeds 023%, unrecrystallized grains will remain even if recrystallization annealing is performed by the ultra-rapid heating method, and a soft material of T-3 or less cannot be obtained. Therefore, the upper limit of the Nb content is shown in FIG. Indicated as.

【0023】図4は、本発明の目的である加工後の耐食
性を向上させるNを60ppm 超以上含有せしめる効果を
示した図である。本発明で製造した種々のN含有量の熱
延板を用い、90%の冷間圧延率で0.25mmの冷延板
を製造した。次いで、図3に示すヒートサイクルで加熱
速度(αH )を1000℃/s、均熱温度(T)を75
0℃、時間(t)を0.1sec 、冷却速度(αc )を2
50℃/sとし、熱処理を行い、焼鈍板を得、次いで光
学顕微鏡で組織を調査した結果を、図4に示す。
FIG. 4 is a diagram showing the effect of adding N in excess of 60 ppm to improve the corrosion resistance after working, which is the object of the present invention. Using the hot-rolled sheets with various N contents produced according to the present invention, cold-rolled sheets of 0.25 mm were produced at a cold rolling rate of 90%. Then, in the heat cycle shown in FIG. 3, the heating rate (α H ) was 1000 ° C./s and the soaking temperature (T) was 75.
0 ° C., time (t) 0.1 sec, cooling rate (α c ) 2
FIG. 4 shows the results of examining the structure with an optical microscope after heat treatment was performed at 50 ° C./s to obtain an annealed plate.

【0024】焼鈍板のG.Snoは、N含有量の増加と
共に番号が大きくなり、顕著に細粒化する。加工後の優
れた耐食性を確保するには、N含有量を60ppm 超以上
とすれば良いことが明らかになった。
G. of annealed sheet The number of Sno increases as the N content increases, and the particles become significantly finer. It has been clarified that the N content should be more than 60 ppm or more to secure the excellent corrosion resistance after processing.

【0025】以下に、製造条件について詳細に述べる。
Cは、図3に示すように、非時効性に大きく影響する元
素である。C含有量が増加するにつれて非時効化に必要
なNb量は顕著に増加し、C含有量が50ppm超になる
と、未再結晶粒が残存するようになり、軟質な材質が得
られなくなるので上限のC量を50ppm とした。また、
C量が0.0005%未満のときは通常の製鋼の真空脱
ガス法では製造が困難となるので、下限のC含有量を
0.0005%とした。
The manufacturing conditions will be described in detail below.
As shown in FIG. 3, C is an element that greatly affects the non-aging property. The amount of Nb required for non-aging significantly increases as the C content increases, and when the C content exceeds 50 ppm, unrecrystallized grains remain and a soft material cannot be obtained. C content of 50 ppm. Also,
When the C content is less than 0.0005%, it becomes difficult to manufacture the steel by a vacuum degassing method for ordinary steelmaking. Therefore, the lower limit C content is set to 0.0005%.

【0026】Mn、P、Sは、材質を硬質化するばかり
ではなく、これらの元素が増加すると鋼板の耐食性を劣
化させるので、それぞれの元素の上限値を0.60%、
0.025%、0.025%とした。尚、Mn、P、S
の各々の下限値は、通常の製造法で得られる範囲をもっ
て下限値とした。
Mn, P, and S not only harden the material but also deteriorate the corrosion resistance of the steel sheet when these elements increase, so the upper limit of each element is 0.60%,
It was set to 0.025% and 0.025%. Incidentally, Mn, P, S
The lower limit of each of the above was defined as the lower limit of the range obtained by the usual production method.

【0027】solAl量は、非時効化を達成するため
にNをAlNとして固定し、N時効を防止する必要があ
り、少なくとも0.030%は含有させる必要がある。
また、solAlは、多量に含有すると材質を硬質化す
るばかりではなく、鋼板の耐食性を劣化させるので、上
限値を0.120%とした。
In order to achieve non-aging, the amount of solAl must be fixed as N by fixing N as AlN, and at least 0.030% must be contained.
In addition, solAl not only hardens the material when it is contained in a large amount, but also deteriorates the corrosion resistance of the steel sheet, so the upper limit was made 0.120%.

【0028】Nは、熱間圧延時にAlNとして析出し、
熱延板の結晶粒径を細粒化することによる再結晶焼鈍に
おける細粒化効果、並びに、熱延板に析出していたAl
Nによる再結晶焼鈍における細粒化効果、更には、焼鈍
中に析出するAlNによる細粒化効果等により焼鈍板を
細粒化、加工後の耐食性を向上させる働きをする。N含
有量を0.0060%超以上添加することによりG.S
noを9.7以上にすることができる。尚、N含有量が
0.0170%超になると鋳片にN起因の気泡が発生
し、表面処理鋼板の耐食性を阻害するようになるのでN
の上限含有量を0.0170%とした。
N is precipitated as AlN during hot rolling,
The grain refining effect in recrystallization annealing by refining the crystal grain size of the hot rolled sheet, and the Al deposited on the hot rolled sheet
The N grain refinement effect in the recrystallization annealing by N, further the grain refinement effect by AlN precipitated during annealing, and the like serve to refine the annealed plate and improve the corrosion resistance after working. When the N content exceeds 0.0060%, the G. S
No can be 9.7 or more. If the N content exceeds 0.0170%, bubbles due to N are generated in the slab, and the corrosion resistance of the surface-treated steel sheet is impaired.
The upper limit content of was set to 0.0170%.

【0029】Nbは、CをNbCとして固定し、非時効
化を達成するのに重要な元素である。Nb含有量を
{7.75×〔C(%)−0.0004〕×0.65}
%以上とすると優れた非時効性が得られる。また、Nb
含有量が、0.023%を越えると本発明の超急速加熱
法で再結晶焼鈍を行っても未再結晶粒が残存するように
なり、T−3以下の軟質な材質が得られなくなるので、
0.023%を上限値とした。
Nb is an important element for fixing C as NbC and achieving non-aging. The Nb content is {7.75 × [C (%) − 0.0004] × 0.65}
% Or more, excellent non-aging property can be obtained. Also, Nb
If the content exceeds 0.023%, unrecrystallized grains will remain even if recrystallization annealing is performed by the ultra-rapid heating method of the present invention, and a soft material of T-3 or less cannot be obtained. ,
The upper limit was 0.023%.

【0030】T.O含有量は、0.0070%超になる
とスラブの表層付近に気泡が発生し、メッキ原板の表面
傷などが増え、良好な製品が得られなくなるばかりでな
く、軟質な材質も得られなくなるので0.0070%を
上限値とした。尚、下限値は、特に規制する必要がない
ので規制しない。
T. If the O content exceeds 0.0070%, air bubbles are generated near the surface layer of the slab, surface scratches on the plating base plate increase, and not only a good product cannot be obtained, but also a soft material cannot be obtained. The upper limit was 0.0070%. The lower limit value is not restricted because it does not need to be restricted.

【0031】熱延条件は、多量に含有するNによるN時
効を防止するために、前記(1)の方法においては「通
常の条件で加熱し、熱間圧延を行い、640〜750℃
で巻き取り熱延鋼帯とする」、また、前記(2)の方法
においては「1000〜1180℃に加熱し、通常の条
件で熱間圧延を行い、巻き取り熱延鋼帯とする」、こと
が重要である。
In order to prevent N aging due to a large amount of N contained in the hot rolling condition, in the above method (1), "heating under normal conditions and hot rolling are performed at 640 to 750 ° C.
In addition, in the method of (2), "heated to 1000 to 1180 ° C. and hot-rolled under normal conditions to obtain a rolled hot rolled steel strip". This is very important.

【0032】前記(1)の方法は、640〜750℃で
巻き取ることにより多量のNの大部分をAlNとして析
出させることができ、また残りの少量の固溶Nは、焼鈍
中に析出させることにより、N時効を防止する方法であ
る。巻き取り温度が640℃未満では、熱延板中のAl
Nの析出が不十分となり、N時効を防止できなくなるの
で640℃を下限とした。また、巻き取り温度が、75
0℃超になるとスケールが非常に厚くなり、酸洗時にス
ケールが取りきれずスケール疵となり、表面処理鋼板の
耐食性を劣化させるようになるので上限の巻き取り温度
を750℃とした。
In the method (1), most of a large amount of N can be precipitated as AlN by winding at 640 to 750 ° C., and the remaining small amount of solute N is precipitated during annealing. This is a method of preventing N aging. When the winding temperature is lower than 640 ° C, Al in the hot rolled sheet
Precipitation of N becomes insufficient and N aging cannot be prevented, so 640 ° C. was made the lower limit. The winding temperature is 75
If the temperature exceeds 0 ° C, the scale becomes very thick, and the scale cannot be completely removed during pickling, resulting in scale defects, which deteriorates the corrosion resistance of the surface-treated steel sheet. Therefore, the upper limit of the coiling temperature was set to 750 ° C.

【0033】前記(2)の方法は、1000〜1180
℃に加熱し、通常の条件で熱間圧延を行うことにより多
量のNの大部分を、AlNとして析出した状態とするこ
とができ、同様に、残りの小量の固溶Nを焼鈍中に析出
させることにより、N時効を防止する方法である。スラ
ブ加熱温度が1180℃超では、スラブ加熱時のAlN
の再固溶が多くなり、また熱延板中のAlNの析出量が
不十分となり、N時効を防止できなくなるので1180
℃を上限とした。また、スラブ加熱温度が、1000℃
未満では仕上げ圧延の温度が確保できなくなるので、下
限のスラブ加熱温度を1000℃とした。
The method (2) is 1000 to 1180.
A large amount of a large amount of N can be precipitated as AlN by heating to ℃ and hot rolling under normal conditions. Similarly, the remaining small amount of solid solution N is annealed during annealing. It is a method of preventing N aging by precipitating. If the slab heating temperature exceeds 1180 ° C, AlN during slab heating
1180 because the amount of re-dissolved solid solution of Al increases and the precipitation amount of AlN in the hot-rolled sheet becomes insufficient and N aging cannot be prevented.
The upper limit was ℃. The slab heating temperature is 1000 ° C.
If it is less than 100%, the temperature for finish rolling cannot be secured, so the lower limit slab heating temperature is set to 1000 ° C.

【0034】他の熱延条件は、特に規制する必要がなく
通常の熱延条件でよい。冷間圧延時の冷間圧延率は、低
いと再結晶焼鈍時の再結晶温度が高く材質が硬くなり、
T−1〜T−3が得られ難くなると共にメッキ製品は、
板厚が薄いので85%未満の冷間圧延率では熱延板の板
厚が薄くなりすぎ熱間圧延が困難となるので、下限値を
85%とした。また、上限値は、特に規制する必要がな
いので規制しなかった。
The other hot rolling conditions do not need to be particularly restricted and may be ordinary hot rolling conditions. When the cold rolling ratio during cold rolling is low, the recrystallization temperature during recrystallization annealing is high and the material becomes hard,
It becomes difficult to obtain T-1 to T-3, and plated products are
Since the plate thickness is thin, a cold rolling ratio of less than 85% makes the plate thickness of the hot-rolled plate too thin and makes hot rolling difficult. Therefore, the lower limit value was set to 85%. The upper limit is not regulated because it does not need to be regulated.

【0035】連続焼鈍時の再結晶焼鈍の加熱速度は、本
発明の最も重要なポイントであって、その効果及びメカ
ニズムは、先に推察した通りである。加熱速度が300
℃/s未満では超急速加熱効果が得られず、材質が硬化
しT−1〜T−3の硬度が得られなくなるので100℃
/sを下限値とした。
The heating rate of recrystallization annealing during continuous annealing is the most important point of the present invention, and its effect and mechanism are as previously inferred. Heating rate is 300
If the temperature is less than ℃ / s, the ultra-rapid heating effect cannot be obtained, and the material is hardened so that the hardness of T-1 to T-3 cannot be obtained.
The lower limit value was / s.

【0036】再結晶焼鈍時の焼鈍温度は、本発明の条件
の鋼であり、完全に再結晶が完了していれば、T−3以
下の軟質な材質が得られるので再結晶温度を下限値とし
た。また、焼鈍温度が850℃超になると再結晶焼鈍時
に結晶粒成長が多くなりG.Sno:9.5の結晶粒よ
り大きくなるので850℃を上限値とした。
The annealing temperature at the time of recrystallization annealing is the steel under the conditions of the present invention, and if recrystallization is completely completed, a soft material of T-3 or less can be obtained. And Further, when the annealing temperature exceeds 850 ° C., the crystal grain growth increases during recrystallization annealing, and G. Sno: Since it becomes larger than the crystal grain of 9.5, 850 ° C. was made the upper limit value.

【0037】再結晶焼鈍時の均熱時間は、超急速加熱焼
鈍では均熱時間がなくとも充分な再結晶と粒成長が生
じ、T−1〜T−3の硬度が得られるので均熱時間の下
限値を、規制する必要がない。均熱時間の上限を3sec
としたのは、本発明の目的である「設備費が大きく軽減
し得る極めてコンパクトな連続焼鈍設備でT−1〜T−
3の製造が可能な連続焼鈍による加工後の耐食性に優れ
た非時効性表面処理原板を製造する方法」の思想から外
れるからである。
The soaking time during the recrystallization annealing is such that in the ultra-rapid heating annealing, sufficient recrystallization and grain growth occur even if there is no soaking time, and a hardness of T-1 to T-3 can be obtained. There is no need to regulate the lower limit value of. Upper limit of soaking time is 3 seconds
That is, the purpose of the present invention is to provide an extremely compact continuous annealing equipment that can significantly reduce equipment costs, such as T-1 to T-
3 is a method for producing a non-aging surface-treated original plate having excellent corrosion resistance after working by continuous annealing that can be produced in No. 3 ”.

【0038】再結晶焼鈍後の冷却条件は、本発明の鋼成
分範囲内では材質に特に影響を与えないので規制する必
要がなく、徐冷となる通常のガスジェット冷却法や30
0℃/sのような強力なガスジェット冷却法等で室温ま
で冷却すればよい。また、300〜500℃付近で数秒
から数分の過時効処理は材質に殆ど影響を及ぼさないの
で過時効処理の効果がないが、過時効処理を施しても差
し支えがない。
The cooling conditions after recrystallization annealing do not have to be restricted within the range of the steel composition of the present invention because they have no particular effect on the material, and there is no need to control the cooling conditions.
It may be cooled to room temperature by a strong gas jet cooling method such as 0 ° C./s. Further, overaging treatment for a few seconds to several minutes at around 300 to 500 ° C. has almost no effect on the material, so there is no effect of overaging treatment, but overaging treatment can be performed.

【0039】調質圧延は、調質圧延の効果を安定して得
るには少なくとも0.6%以上の調質圧延を行う必要が
あるので、0.6%を下限の調質圧延率とした。また、
表面処理原板の調質圧延は、通常ドライ調質圧延が行わ
れ、ドライ調質圧延では3.5%が限界であるので3.
5%を上限とした。
In temper rolling, it is necessary to perform at least 0.6% temper rolling in order to stably obtain the effect of temper rolling. Therefore, 0.6% is the lower limit temper rolling rate. . Also,
2. The temper rolling of the surface-treated original plate is usually dry temper rolling, and the limit of 3.5% is the limit in dry temper rolling.
The upper limit was 5%.

【0040】[0040]

【実施例】以下に、本発明を実施例に基づいてさらに説
明する。表1に示す成分を有する鋼を、表2に示す熱延
条件で2.5mmの熱延鋼帯を製造し、冷間圧延率90%
で0.25mmの冷延鋼板を得た。次いで、図2に示すヒ
ートサイクルで、表2に示す温度、時間条件で連続焼鈍
並びに1.6%の調質圧延を施し、表面処理原板を得、
これに錫メッキを施し、ブリキ板を製造した。得られた
ブリキ板の硬度(HR30T)と結晶粒度番号を測定し、そ
の結果を、表2に示す。非時効性の評価は、得られた種
々のブリキ板を塗装焼き付け相当の200℃×30min
の熱処理を施し、引張り試験を行いYP−E1を測定
し、YP−E1が0.5%未満であったものを非時効性
とした。非時効性が確保できたものは○、確保できなか
ったものは×として、表2に示す。
EXAMPLES The present invention will be further described below based on examples. A steel having the components shown in Table 1 was manufactured into a hot rolled steel strip of 2.5 mm under the hot rolling conditions shown in Table 2, and the cold rolling rate was 90%.
A cold rolled steel sheet of 0.25 mm was obtained. Then, in the heat cycle shown in FIG. 2, continuous annealing and 1.6% temper rolling were performed under the temperature and time conditions shown in Table 2 to obtain a surface-treated original plate,
This was tin-plated to produce a tin plate. The hardness ( HR30T ) and the grain size number of the obtained tin plate were measured, and the results are shown in Table 2. The evaluation of non-aging is carried out by painting various tin plates obtained by painting and baking at 200 ° C for 30 min.
Was subjected to a heat treatment, a tensile test was performed, and YP-E1 was measured, and those in which YP-E1 was less than 0.5% were regarded as non-aging. Table 2 shows the non-aging properties as ◯, and the non-aging properties as x.

【0041】鋼A,B,C,D,Eは、いずれも本発明
の範囲内の成分の鋼である。鋼A,B,Cは、それぞ
れ、C含有量を12、25、36ppm 、Nb含有量を
0.017、0.017、0.021%と変化させたも
のである。また、鋼Dは、硬度アップのためにMnを
0.52%添加したもの、鋼Eは、Nを0.0120%
添加したものである。
All of the steels A, B, C, D and E are steels having a composition within the scope of the present invention. Steels A, B, and C have different C contents of 12, 25, and 36 ppm, and Nb contents of 0.017, 0.017, and 0.021%, respectively. Steel D has 0.52% Mn added to increase hardness, and Steel E has 0.0120% N.
It was added.

【0042】鋼Fは、N含有量が0.0018%と低く
外れた本発明の範囲外の成分のものである。鋼Gは、C
含有量が0.0075%と高く外れ、Nb含有量も0.
016%と非時効化に必要な下限のNb含有量の下方に
外れた本発明の範囲外の成分のものである。鋼Hは、N
b含有量が0.033%と上限を外れた本発明の範囲外
の成分のものである。
Steel F has a N content as low as 0.0018%, which is outside the scope of the present invention. Steel G is C
The content is as high as 0.0075%, and the Nb content is 0.
016%, which is below the lower limit of Nb content necessary for non-aging, and is outside the scope of the present invention. Steel H is N
The content of b is 0.033%, which is outside the upper limit of the present invention and is out of the upper limit.

【0043】[0043]

【表1】 [Table 1]

【0044】[0044]

【表2】 [Table 2]

【0045】試料1、2、3、4、5、6、7は、本発
明の実施例である。何れもT−1〜T−3の硬度範囲
(HR30T=49±3〜57±3)で非時効性と加工後の
耐食性の確保に必要な焼鈍板のG.Sno:9.5以上
が確保できている。本発明によれば、コンパクトで設備
費の小さい超急速加熱短時間焼鈍法により加工後の耐食
性に優れた非時効性で軟質なT−1〜T−3の製造が可
能であることが分る。
Samples 1, 2, 3, 4, 5, 6, 7 are examples of the present invention. In both cases, the G.I. of the annealed sheet required for ensuring non-aging property and corrosion resistance after working in the hardness range of T-1 to T-3 (H R30T = 49 ± 3 to 57 ± 3). Sno: 9.5 or more is secured. According to the present invention, it is found that it is possible to manufacture non-aging and soft T-1 to T-3 that are excellent in corrosion resistance after processing by the ultra-rapid heating short-time annealing method that is compact and has low equipment cost. .

【0046】試料6は、Mnを0.52%と高くし、硬
さレベルをT−2.5の範囲にした本発明のものであっ
て、非時効性と細粒化も確保できている。試料8、9、
10は、それぞれ、N量、C量、Nb量が本発明の範囲
から外れた比較例である。試料8は、G.Snoが8.
9と粗粒となり、試料9は、非時効性が確保できず、試
料10は、未再結晶粒が残留し硬くなっている。
Sample 6 is the one of the present invention in which Mn is as high as 0.52% and the hardness level is in the range of T-2.5, and the non-aging property and the grain refining can be secured. . Samples 8, 9,
No. 10 is a comparative example in which the amounts of N, C and Nb were out of the range of the present invention. Sample 8 is a G.I. Sno is 8.
9 and coarse grains, Sample 9 cannot secure non-aging property, and Sample 10 is hard because unrecrystallized grains remain.

【0047】[0047]

【発明の効果】本発明によれば、高温焼鈍が可能で、コ
ンパクトで設備費の小さい超急速加熱短時間の連続焼鈍
設備により、T−1〜T−3の加工後の耐食性に優れた
非時効性表面処理原板の製造が可能となる。
EFFECTS OF THE INVENTION According to the present invention, the continuous annealing equipment capable of high-temperature annealing, compact and low equipment cost, and ultra-rapid heating for a short time provides excellent corrosion resistance after processing T-1 to T-3. It becomes possible to manufacture an aging surface-treated original plate.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の連続焼鈍の加熱速度と再結晶温度との
関係を示した説明図。
FIG. 1 is an explanatory diagram showing the relationship between the heating rate and the recrystallization temperature in continuous annealing according to the present invention.

【図2】本発明の連続焼鈍のヒートサイクルを示した説
明図。
FIG. 2 is an explanatory view showing a heat cycle of continuous annealing according to the present invention.

【図3】本発明における非時効性でT−1〜T−3の軟
質材が確保できたC含有量とNb含有量の領域を示す説
明図。
FIG. 3 is an explanatory view showing regions of C content and Nb content in which the soft materials T-1 to T-3 could be secured by the non-aging property in the present invention.

【図4】本発明におけるN含有量と焼鈍板のG.Sno
との関係を示す図。
FIG. 4 is a graph showing the N content and G. Sno
FIG.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 長 野 啓一郎 兵庫県姫路市広畑区富士町1番地 新日 本製鐵株式会社 広畑製鐵所内 (56)参考文献 特開 平6−184643(JP,A) (58)調査した分野(Int.Cl.7,DB名) C21D 9/46 C21D 8/02 C22C 38/00 301 C22C 38/12 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Keiichiro Nagano 1 Fuji-machi, Hirohata-ku, Himeji-shi, Hyogo Nippon Steel Co., Ltd. Hirohata Works (56) References Japanese Patent Laid-Open No. 6-184643 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) C21D 9/46 C21D 8/02 C22C 38/00 301 C22C 38/12

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】C:0.0005〜0.0050%、M
n:0.05〜0.60%、P:0.001〜0.02
5%、S:0.001〜0.025%、solAl:
0.030〜0.120%、N:0.0060超〜0.
0170%、Nb:{7.75×〔C(%)−0.00
04〕×0.65}%〜0.023%、T.O:≦0.
0070%、残部不可避的不純物及び鉄からなる鋼片
を、通常の条件で加熱し、熱間圧延を行い、640〜7
50℃で巻き取り熱延鋼帯とし、85%以上の冷間圧延
を行い、その後、連続焼鈍にて少なくとも500℃以上
の温度域を100℃/s以上で再結晶温度〜850℃に
加熱し、3秒以下の保持を行い、その後室温まで冷却す
る再結晶焼鈍を行い、次いで、調質圧延を0.6〜3.
5%の範囲で施すことを特徴とする連続焼鈍による加工
後の耐食性に優れた非時効性軟質表面処理原板の製造方
法。
1. C: 0.0005 to 0.0050%, M
n: 0.05 to 0.60%, P: 0.001 to 0.02
5%, S: 0.001-0.025%, solAl:
0.030-0.120%, N: more than 0.0060-0 .
0170%, Nb: {7.75 x [C (%)-0.00
04] × 0.65}% to 0.023%, T.O. O: ≤0.
A steel slab consisting of 0070% and the balance unavoidable impurities and iron is heated under normal conditions and hot rolled to give 640 to 7
A hot-rolled steel strip is taken up at 50 ° C., cold-rolled at 85% or more, and then heated at a temperature range of at least 500 ° C. at 100 ° C./s or more to a recrystallization temperature to 850 ° C. by continuous annealing. Hold for 3 seconds or less, then perform recrystallization annealing to cool to room temperature, and then temper rolling 0.6 to 3.
A method for producing a non-aging soft surface-treated original plate having excellent corrosion resistance after working by continuous annealing, which is characterized by being applied in a range of 5%.
【請求項2】C:0.0005〜0.0050%、M
n:0.05〜0.60%、P:0.001〜0.02
5%、S:0.001〜0.025%、solAl:
0.040〜0.120%、N:0.0060超〜0.
0170%、Nb:{7.75×〔C(%)−0.00
04〕×0.65}%〜0.023%、T.O:≦0.
0070%、残部不可避的不純物及び鉄よりなる鋼片
を、1000〜1180℃に加熱し、通常の条件で熱間
圧延を行い、巻き取り熱延鋼帯とし、85%以上の冷間
圧延を行い、その後、連続焼鈍にて少なくとも500℃
以上の温度域を100℃/s以上で再結晶温度〜850
℃に加熱し、3秒以下の保持を行い、その後室温まで冷
却する再結晶焼鈍を行い、次いで、調質圧延を0.6〜
3.5%の範囲で施すことを特徴とする連続焼鈍による
加工後の耐食性に優れた非時効性軟質表面処理原板の製
造方法。
2. C: 0.0005 to 0.0050%, M
n: 0.05 to 0.60%, P: 0.001 to 0.02
5%, S: 0.001-0.025%, solAl:
0.040-0.120%, N: more than 0.0060-0 .
0170%, Nb: {7.75 x [C (%)-0.00
04] × 0.65}% to 0.023%, T.O. O: ≤0.
A steel slab consisting of 0070% and the balance unavoidable impurities and iron is heated to 1000 to 1180 ° C., hot rolled under normal conditions to obtain a rolled hot rolled steel strip, and cold rolled to 85% or more. , Then at least 500 ℃ in continuous annealing
Recrystallization temperature up to 850 at 100 ° C / s or more in the above temperature range
Recrystallization annealing is performed by heating to 0 ° C, holding for 3 seconds or less, and then cooling to room temperature, and then temper rolling 0.6 to.
A method for producing a non-aging soft surface-treated original plate having excellent corrosion resistance after processing by continuous annealing, which is characterized by being applied in a range of 3.5%.
JP20430093A 1992-08-28 1993-08-18 Manufacturing method of non-ageing soft surface treated original sheet with excellent corrosion resistance after working by continuous annealing Expired - Fee Related JP3383019B2 (en)

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Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP23014292 1992-08-28
JP4-230142 1992-08-28
JP20430093A JP3383019B2 (en) 1992-08-28 1993-08-18 Manufacturing method of non-ageing soft surface treated original sheet with excellent corrosion resistance after working by continuous annealing

Publications (2)

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JPH06184644A JPH06184644A (en) 1994-07-05
JP3383019B2 true JP3383019B2 (en) 2003-03-04

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