JP3345859B2 - PVC resin composition and soft sheet using the resin composition - Google Patents
PVC resin composition and soft sheet using the resin compositionInfo
- Publication number
- JP3345859B2 JP3345859B2 JP14215393A JP14215393A JP3345859B2 JP 3345859 B2 JP3345859 B2 JP 3345859B2 JP 14215393 A JP14215393 A JP 14215393A JP 14215393 A JP14215393 A JP 14215393A JP 3345859 B2 JP3345859 B2 JP 3345859B2
- Authority
- JP
- Japan
- Prior art keywords
- pvc
- layer
- resin composition
- weight
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
Description
【０００１】[0001]
【産業上の利用分野】本発明は、耐候性に優れたＰＶＣ
樹脂組成物及びその樹脂組成物を基布に積層した耐候性
に優れる軟質シートに関する。BACKGROUND OF THE INVENTION The present invention relates to a PVC having excellent weather resistance.
The present invention relates to a resin composition and a soft sheet excellent in weather resistance laminated on a base fabric.
【０００２】[0002]
【従来の技術】ポリ塩化ビニル系樹脂（ＰＶＣ）の可塑
剤として、一般にホスフェイト系やフタル酸系の添加物
を加えることは特開平３−３９０１３号公報等により知
られている。2. Description of the Related Art It is known from JP-A-3-39013 or the like that a phosphate or phthalic acid-based additive is generally added as a plasticizer for a polyvinyl chloride resin (PVC).
【０００３】[0003]
【発明が解決しようとする課題】しかし、従来の基布層
にＰＶＣ樹脂組成物を積層した軟質シートからなる製
品、例えば基布層表面に施したプリント層を保護するた
めプリント層上面にＰＶＣ透明層を積層してなる車両用
サドル等（オートバイ用など）では、充分な耐候性が得
られず過酷な自然環境により表面がべたついてしまうと
いう不具合があった。However, a conventional product made of a soft sheet in which a PVC resin composition is laminated on a base fabric layer, for example, a PVC transparent film is formed on the upper surface of the print layer to protect the print layer applied to the surface of the base fabric layer. In a saddle for a vehicle or the like (for motorcycles, etc.) formed by laminating layers, there is a problem that sufficient weather resistance cannot be obtained and the surface becomes sticky due to a severe natural environment.
【０００４】本発明は、従来技術の有するこのような問
題点に鑑みなされたものであり、その目的とするところ
は、耐候性に優れたＰＶＣ樹脂組成物およびその樹脂組
成物を使用した軟質シートを提供することである。The present invention has been made in view of the above-mentioned problems of the prior art, and has as its object to provide a PVC resin composition having excellent weather resistance and a soft sheet using the resin composition. It is to provide.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
に本発明がなした技術的手段は、ＰＶＣ樹脂を主原料と
し、これにホスフェイト系二次可塑剤，可塑剤および安
定剤を添加して構成し、上記可塑剤は炭素数を主として
１０〜１４で、直鎖率が６０モル％〜８０モル％にブレ
ンドされたアルコールと、フタル酸とのエステルであ
り、かつその割合をＰＶＣ樹脂１００重量部に対して６
０重量部〜８５重量部の範囲内とし、上記ホスフェイト
系二次可塑剤の割合をＰＶＣ樹脂１００重量部に対して
７重量部として耐候性に優れるＰＶＣ樹脂組成物を構成
したことである。In order to achieve the above object, the technical means of the present invention is to use a PVC resin as a main raw material, to which a phosphate secondary plasticizer, a plasticizer and a stabilizer are added. The plasticizer is an ester of phthalic acid and an alcohol blended mainly with 10 to 14 carbon atoms and having a linear chain ratio of 60 mol% to 80 mol%, and the proportion thereof is defined as 100% of PVC resin. 6 parts by weight
It is within the range of 0 to 85 parts by weight, and the proportion of the phosphate secondary plasticizer is 7 parts by weight with respect to 100 parts by weight of the PVC resin to constitute a PVC resin composition having excellent weather resistance.
【０００６】[0006]
【実施例】以下、本発明の実施例を説明する。図面は、
布層１の上面に所望構成のＰＶＣ下地層２を積層し、次
いでそのＰＶＣ下地層２の上面に所望構成のプリント層
３を積層し、そしてそのプリント層３の上面に上記構成
のＰＶＣ透明層４を積層して、そのＰＶＣ透明層４を表
面層とした軟質シートＡを形成し、そしてその軟質シー
トＡにて形成されたオートバイ用サドルａの一例を示
す。尚、図面では軟質シートＡの表面に絞５を設けたも
のを示すが、一例にすぎず任意であり、またＰＶＣ透明
層４の上に表面処理することも任意である。Embodiments of the present invention will be described below. The drawing is
A PVC underlayer 2 having a desired configuration is laminated on the upper surface of the cloth layer 1, a print layer 3 having a desired configuration is laminated on the upper surface of the PVC underlayer 2, and a PVC transparent layer having the above configuration is disposed on the upper surface of the print layer 3. 4 are laminated to form a soft sheet A having the PVC transparent layer 4 as a surface layer, and an example of a motorcycle saddle a formed of the soft sheet A is shown. In the drawings, the flexible sheet A is provided with a squeezer 5 on the surface, but this is merely an example and is optional. The surface treatment on the PVC transparent layer 4 is also optional.
【０００７】ＰＶＣ樹脂組成物は、表１の実施例１，２
および比較例１に示す配合で、その配合からなるＰＶＣ
樹脂組成物にてＰＶＣ透明樹脂層４を形成し、プリント
層３，ＰＶＣ下地層２，布層１からなる積層のプリント
層３の上面に各ＰＶＣ透明層４…を積層して軟質シート
Ａ〜Ｅを形成し、耐候性（べたつき）を試験した。その
結果を表２に示す。尚、ＰＶＣ下地層２には白色に着色
したものを、またプリント層３には、例えば、フタロシ
アニンブルー（青），フタロシアニングリーン（緑），
ポリアゾレッド（赤），ベンガラ（茶），クロムバーミ
リオン（黄），酸化チタン（白），カーボン（黒）等を
担体に混合したインキで、１．５〜２．５ｇ／ｍ２（dr
y 時ベタ塗り部のみ取り上げての平均値），０．６〜
１．２ｇ／ｍ２（dry 時雲柄の平均値）等の所望目付で
花柄にプリントしたものを用いた。The PVC resin compositions are shown in Examples 1 and 2 in Table 1.
And the PVC shown in Comparative Example 1
A PVC transparent resin layer 4 is formed from a resin composition, and each of the PVC transparent layers 4 is laminated on the upper surface of a printed layer 3 composed of a printed layer 3, a PVC underlayer 2, and a cloth layer 1. An E was formed and tested for weather resistance (stickiness). Table 2 shows the results. The PVC underlayer 2 is colored white, and the print layer 3 is, for example, phthalocyanine blue (blue), phthalocyanine green (green), or the like.
1.5 to 2.5 g / m 2 (dr) is an ink in which polyazo red (red), red bengara (brown), chrome vermillion (yellow), titanium oxide (white), carbon (black) and the like are mixed in a carrier.
Average value when only the solid painted part is taken at y), 0.6 ~
A flower pattern printed with a desired basis weight such as 1.2 g / m 2 (average value of cloud pattern in dry state) was used.
【０００８】[0008]
【表１】 [Table 1]
【０００９】[0009]
【表２】 [Table 2]
【００１０】ホスフェイト系二次可塑剤は、ＴＣＰ等
で、その添加割合はＰＶＣ樹脂１００重量部に対して７
重量部とする。（５重量部では不足気味であり、１０重
量部では加工時の熱履歴に起因すると思われる劣化が表
れる）The phosphate-based secondary plasticizer is TCP or the like, and its addition ratio is 7 parts per 100 parts by weight of the PVC resin.
Parts by weight. (5 parts by weight are not enough, and 10 parts by weight show deterioration considered to be due to heat history during processing.)
【００１１】可塑剤は、通常使用されるＤＯＰより直鎖
率が高く、分子量の大きいもので、詳しくは炭素数が主
として１０〜１４で、直鎖率が６０モル％〜８０モル％
にブレンドされたアルコールと、フタル酸とのエステル
であり、好ましくは上記直鎖率が７０モル％である。ま
た、その添加割合はＰＶＣ樹脂１００重量部に対して、
６０重量部〜８５重量部の範囲内で、好ましくは６１重
量部である（直鎖率が低い場合ベタツキ易く、高い場合
ブルームが見られる）。The plasticizer has a higher linearity and a higher molecular weight than a commonly used DOP. More specifically, the plasticizer mainly has 10 to 14 carbon atoms and a linearity of 60 to 80 mol%.
And an ester of phthalic acid, preferably the above-mentioned linearity is 70 mol%. In addition, the addition ratio is 100 parts by weight of the PVC resin,
It is in the range of 60 to 85 parts by weight, preferably 61 parts by weight (stickiness is easy when the linearity is low, and bloom is seen when the linearity is high).
【００１２】安定剤は、例えば有機Ｂａ−Ｚｎ塩系で、
ＰＶＣ樹脂１００重量部に対して、０．３重量部〜２重
量部の範囲内で、好ましくは１．８重量部である。The stabilizer is, for example, an organic Ba—Zn salt system.
The amount is preferably from 0.3 to 2 parts by weight, and more preferably 1.8 parts by weight, based on 100 parts by weight of the PVC resin.
【００１３】また、上記配合と共に他の添加物、例えば
ホスファイト及びホスファイト系金属塩，ヒンダードフ
ェノール系及びビスフェノール系抗酸化剤，ベンゾトリ
アゾール系紫外線吸収剤およびＨＡＬＳ等を主原料に対
して所望割合配合するものとしてもよい。Further, other additives such as phosphites and phosphite-based metal salts, hindered phenol-based and bisphenol-based antioxidants, benzotriazole-based ultraviolet absorbers, and HALS, etc., are preferably added to the main raw material in addition to the above composition. It is good also as what mixes in proportion.
【００１４】そして、布層，ＰＶＣ下地層，プリント層
およびＰＶＣ透明層からなる積層で、該ＰＶＣ透明層を
表面層とする軟質シートにおいて、上記ＰＶＣ樹脂組成
物よりＰＶＣ透明層を構成することで耐候性に大変優れ
る軟質シートとなる。[0014] Then, in a soft sheet having the PVC transparent layer as a surface layer, the PVC transparent layer is constituted by the above-mentioned PVC resin composition in a laminate comprising a cloth layer, a PVC underlayer, a print layer and a PVC transparent layer. It becomes a soft sheet with very excellent weather resistance.
【００１５】さらに、上記ＰＶＣ下地層は特別その配合
は限定されないが、上記ＰＶＣ透明層と共に同様構成の
ＰＶＣ樹脂組成物により構成してもよく、デザイン上の
要求により任意に着色される。Further, the composition of the above-mentioned PVC underlayer is not particularly limited, but it may be composed of the same composition as the above-mentioned PVC transparent layer, and may be arbitrarily colored according to design requirements.
【００１６】また、ＰＶＣ透明層は上記記載のＰＶＣ樹
脂組成物より構成し、ＰＶＣ下地層は、主原料のＰＶＣ
樹脂に添加される可塑剤をＤＯＰ、そして安定剤を有機
Ｂａ−Ｚｎ塩系としたＰＶＣ樹脂組成物によって構成し
た軟質シートとすれば布層に対しての接着性がよい。こ
のＰＶＣ下地層を構成するＰＶＣ樹脂組成物の一配合例
をここで示すと、ＰＶＣ樹脂組成物１００重量部に対
し、ＤＯＰ７５重量部，有機Ｂａ−Ｚｎ塩系１．０重量
部，ホスファイト０．５重量部，フェノール系抗酸化剤
０．１重量部であり、この軟質シートは、ＰＶＣ下地層
を上記ＰＶＣ透明層と同様構成のＰＶＣ樹脂組成物によ
り構成した前記シートの場合に比して、加工時に熱履歴
が少なくて済み耐候性に優れる。Further, the transparent PVC layer is composed of the above-mentioned PVC resin composition, and the PVC underlayer is made of the main material PVC.
If the soft sheet is made of a PVC resin composition in which the plasticizer added to the resin is DOP and the stabilizer is an organic Ba-Zn salt system, the adhesiveness to the cloth layer is good. One example of the composition of the PVC resin composition constituting the PVC underlayer is shown below. For 100 parts by weight of the PVC resin composition, 75 parts by weight of DOP, 1.0 part by weight of an organic Ba-Zn salt system, and 0 parts by weight of phosphite are used. 0.5 parts by weight and 0.1 parts by weight of a phenolic antioxidant. This soft sheet is different from the sheet in which the PVC underlayer is made of a PVC resin composition having the same structure as the above-mentioned PVC transparent layer. Excellent heat resistance due to low heat history during processing.
【００１７】従って、従来のＰＶＣ軟質シートにて形成
されたもので屋外に晒されるもの、例えば上記従来の軟
質シートによって形成されたオートバイ用サドル等を本
考案構成の軟質シートにて構成すれば、過酷な自然環境
によって表面がべたつくという従来抱えていた不具合が
充分に解消されるため、結果としてプリント面の保護が
従来どおりに図れ、かつ表面のべたつきのない優れた製
品の提供が図れる。Therefore, if a conventional soft sheet made of a conventional PVC sheet and exposed to the outdoors, for example, a motorcycle saddle formed by the above-mentioned conventional soft sheet, is constituted by the soft sheet of the present invention, Since the conventional problem that the surface is sticky due to the harsh natural environment is sufficiently solved, the printed surface can be protected as before, and an excellent product with no surface stickiness can be provided.
【００１８】[0018]
【発明の効果】以上で明らかな様に本発明によれば、耐
候性に優れた、特にべたつきの発生を解消し得るＰＶＣ
樹脂組成物を提供することができる。また、この樹脂組
成物によりＰＶＣ透明層をプリント層の上面に形成した
軟質シート材の耐久性も向上することができる。As apparent from the above, according to the present invention, PVC excellent in weather resistance, particularly capable of eliminating the occurrence of stickiness.
A resin composition can be provided. Further, the durability of the flexible sheet material having the transparent PVC layer formed on the upper surface of the print layer can be improved by the resin composition.
【図１】オートバイ用サドルの一部を切欠くと共に拡大
して示す。FIG. 1 is a cutaway and enlarged view of a portion of a motorcycle saddle.
Ａ：軟質シート ａ：オートバイ用
サドル １：布層 ２：ＰＶＣ下地層 ３：プリント層 ４：ＰＶＣ透明層A: Soft sheet a: Motorcycle saddle 1: Cloth layer 2: PVC base layer 3: Print layer 4: PVC transparent layer
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｃ０８Ｋ 5/521 Ｃ０８Ｋ 5/521 (72)発明者 松浦 昇 神奈川県川崎市中原区木月717−５ (72)発明者 垣内 泰三 埼玉県鶴ケ島市富士見３−８−605 (72)発明者 米澤 明男 神奈川県横浜市戸塚区秋葉町317−１ サンコート東戸塚205 (72)発明者 藤高 信男 埼玉県和光市中央１丁目４番１号 株式 会社本田技術研究所内 (72)発明者 古賀 美弥子 埼玉県和光市中央１丁目４番１号 株式 会社本田技術研究所内 (56)参考文献 特開 昭58−129040（ＪＰ，Ａ) 特開 昭61−16951（ＪＰ，Ａ) 特開 昭61−190543（ＪＰ，Ａ) 特開 平４−261452（ＪＰ，Ａ) 特開 昭61−243845（ＪＰ，Ａ) 特開 平６−1862（ＪＰ，Ａ) 特開 平６−1858（ＪＰ，Ａ) 特開 平５−306343（ＪＰ，Ａ) 特開 平５−148392（ＪＰ，Ａ) 特開 平５−194810（ＪＰ，Ａ) 特開 平３−172336（ＪＰ，Ａ) 特開 平２−133453（ＪＰ，Ａ) 特開 昭63−340（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) C08L 27/06 B32B 27/12 B32B 27/18 - 27/26 B32B 27/30 ────────────────────────────────────────────────── ─── Continued on the front page (51) Int.Cl. 7 Identification code FI C08K 5/521 C08K 5/521 (72) Inventor Noboru Matsuura 717-5 Kizuki, Nakahara-ku, Kawasaki City, Kanagawa Prefecture (72) Inventor Kakiuchi Taizo 3-8-605 Fujimi, Tsurugashima-shi, Saitama Prefecture (72) Inventor Akio Yonezawa 311-1 Akiha-cho, Totsuka-ku, Yokohama-shi, Kanagawa Prefecture 205 Suncoat Higashi-Totsuka (72) Inventor Nobuo Fujitaka 1-4-1 Chuo, Wako-shi, Saitama Prefecture No. Inside Honda R & D Co., Ltd. (72) Inventor Miyako Koga 1-4-1 Chuo, Wako-shi, Saitama Pref. Inside Honda R & D Co., Ltd. (56) References JP-A-58-129040 (JP, A) JP-A Sho JP-A-61-16951 (JP, A) JP-A-61-190543 (JP, A) JP-A-4-261452 (JP, A) JP-A-61-243845 (JP, A) JP-A-6-1862 (JP, A A) JP-A-6-1 858 (JP, A) JP-A-5-306343 (JP, A) JP-A-5-148392 (JP, A) JP-A-5-194810 (JP, A) JP-A-3-172336 (JP, A) JP-A-2-133453 (JP, A) JP-A-63-340 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C08L 27/06 B32B 27/12 B32B 27/18 -27/26 B32B 27/30
Claims (4)
イト系二次可塑剤，可塑剤および安定剤を添加して構成
し、上記可塑剤は炭素数を主として１０〜１４で、直鎖
率が６０モル％〜８０モル％にブレンドされたアルコー
ルと、フタル酸とのエステルであり、かつその割合をＰ
ＶＣ樹脂１００重量部に対して６０〜８５重量部の範囲
内とし、上記ホスフェイト系二次可塑剤の割合をＰＶＣ
樹脂１００重量部に対して７重量部としたことを特徴と
するＰＶＣ樹脂組成物。1. A plastic resin is used as a main material, and a phosphate-based secondary plasticizer, a plasticizer and a stabilizer are added thereto, and the plasticizer mainly has 10 to 14 carbon atoms and a linear ratio. An ester of phthalic acid and an alcohol blended at 60 mol% to 80 mol%,
The proportion of the phosphate-based secondary plasticizer is set in the range of 60 to 85 parts by weight with respect to 100 parts by weight of the VC resin.
A PVC resin composition comprising 7 parts by weight per 100 parts by weight of a resin.
ＶＣ透明層からなる積層で、該ＰＶＣ透明層を表面層と
する軟質シートであって、上記ＰＶＣ透明層が請求項１
記載のＰＶＣ樹脂組成物より構成されていることを特徴
とする軟質シート。2. A fabric layer, a PVC underlayer, a print layer, and a P layer.
2. A flexible sheet having a laminate comprising a VC transparent layer and having the PVC transparent layer as a surface layer, wherein the PVC transparent layer is a flexible sheet.
A flexible sheet comprising the PVC resin composition as described above.
１記載のＰＶＣ樹脂組成物より構成されていることを特
徴とする請求項２記載の軟質シート。3. The flexible sheet according to claim 2, wherein the PVC transparent layer and the PVC underlayer are made of the PVC resin composition according to claim 1.
ＶＣ透明層からなる積層で、該ＰＶＣ透明層を表面層と
する軟質シートであって、上記ＰＶＣ透明層が請求項１
記載のＰＶＣ樹脂組成物より構成され、ＰＶＣ下地層
が、ＰＶＣ樹脂を主原料とし、これに可塑剤と安定剤を
添加して構成し、可塑剤がＤＯＰ，安定剤が有機Ｂａ-
Ｚｎ塩系であることを特徴とする軟質シート。4. A fabric layer, a PVC underlayer, a print layer and a P layer.
2. A flexible sheet having a laminate comprising a VC transparent layer and having the PVC transparent layer as a surface layer, wherein the PVC transparent layer is a flexible sheet.
The PVC underlayer comprises a PVC resin as a main raw material and a plasticizer and a stabilizer added thereto, wherein the plasticizer is DOP and the stabilizer is organic Ba-.
A soft sheet characterized by being a Zn salt type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14215393A JP3345859B2 (en) | 1993-06-14 | 1993-06-14 | PVC resin composition and soft sheet using the resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14215393A JP3345859B2 (en) | 1993-06-14 | 1993-06-14 | PVC resin composition and soft sheet using the resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06345928A JPH06345928A (en) | 1994-12-20 |
| JP3345859B2 true JP3345859B2 (en) | 2002-11-18 |
Family
ID=15308598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14215393A Expired - Fee Related JP3345859B2 (en) | 1993-06-14 | 1993-06-14 | PVC resin composition and soft sheet using the resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3345859B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101810374B1 (en) | 2017-09-27 | 2018-01-18 | 류호철 | Composition for PVC sheet |
| KR101841881B1 (en) | 2017-09-27 | 2018-03-23 | 류호철 | Method for PVC sheet |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892449A (en) * | 1994-09-20 | 1996-04-09 | Tsutsunaka Plast Ind Co Ltd | Waterproof sheet made from plasticized polyvinyl chloride resin |
| AU2001267585A1 (en) | 2000-07-05 | 2002-01-14 | Basf Aktiengesellschaft | Method for producing blends of phthalic acid diesters, decanols and tridecanols |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58129040A (en) * | 1982-01-27 | 1983-08-01 | Nippon Carbide Ind Co Ltd | Agricultural vinyl chloride resin film |
| JPS6116951A (en) * | 1984-07-03 | 1986-01-24 | Mitsubishi Kasei Vinyl Co | Non-rigid vinyl chloride resin film for agriculture |
| JPS61190543A (en) * | 1985-02-18 | 1986-08-25 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin film for agricultural use |
| JPS61243845A (en) * | 1985-04-19 | 1986-10-30 | Mitsubishi Gas Chem Co Inc | Polyvinyl chloride resin composition |
| JPH072880B2 (en) * | 1986-06-19 | 1995-01-18 | チッソ株式会社 | Abrasion resistant soft vinyl chloride resin composition |
| JP2683257B2 (en) * | 1988-11-14 | 1997-11-26 | 旭電化工業株式会社 | Vinyl chloride resin composition for agriculture |
| JP2849138B2 (en) * | 1989-12-01 | 1999-01-20 | 旭電化工業株式会社 | Vinyl chloride resin composition for powder molding |
| JPH04261452A (en) * | 1991-02-15 | 1992-09-17 | Asahi Denka Kogyo Kk | Agricultural vinyl chloride-based resin composition |
| JPH05148392A (en) * | 1991-05-09 | 1993-06-15 | Shin Etsu Chem Co Ltd | Plasticized vinyl chloride resin composition |
| JPH05194810A (en) * | 1992-01-20 | 1993-08-03 | Chisso Corp | Vinyl chloride resin film for agriculture |
| JP2520345B2 (en) * | 1992-04-30 | 1996-07-31 | 筒中プラスチック工業株式会社 | Soft polyvinyl chloride resin waterproof sheet |
| JP3132163B2 (en) * | 1992-06-18 | 2001-02-05 | チッソ株式会社 | Architectural interior materials made of vinyl chloride resin |
| JP3132164B2 (en) * | 1992-06-18 | 2001-02-05 | チッソ株式会社 | PVC resin waterproof products |
-
1993
- 1993-06-14 JP JP14215393A patent/JP3345859B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101810374B1 (en) | 2017-09-27 | 2018-01-18 | 류호철 | Composition for PVC sheet |
| KR101841881B1 (en) | 2017-09-27 | 2018-03-23 | 류호철 | Method for PVC sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06345928A (en) | 1994-12-20 |
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