JP3341427B2 - Immersion membrane equipment - Google Patents

Immersion membrane equipment

Info

Publication number
JP3341427B2
JP3341427B2 JP34595693A JP34595693A JP3341427B2 JP 3341427 B2 JP3341427 B2 JP 3341427B2 JP 34595693 A JP34595693 A JP 34595693A JP 34595693 A JP34595693 A JP 34595693A JP 3341427 B2 JP3341427 B2 JP 3341427B2
Authority
JP
Japan
Prior art keywords
membrane
filtration
bubbles
diameter
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP34595693A
Other languages
Japanese (ja)
Other versions
JPH07185270A (en
Inventor
和夫 今井
繁樹 沢田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurita Water Industries Ltd
Original Assignee
Kurita Water Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kurita Water Industries Ltd filed Critical Kurita Water Industries Ltd
Priority to JP34595693A priority Critical patent/JP3341427B2/en
Publication of JPH07185270A publication Critical patent/JPH07185270A/en
Application granted granted Critical
Publication of JP3341427B2 publication Critical patent/JP3341427B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、平膜を複数枚積層し
た積層体や、中空糸膜を平面状、或いはすだれ状にした
膜エレメントを複数枚積層した積層体や、管状膜を複数
本並行に接続したものを膜ユニットとして用いた浸漬膜
装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a laminated body in which a plurality of flat membranes are laminated, a laminated body in which a plurality of hollow fiber membranes are formed in a planar or interdigital shape, and a plurality of tubular membranes. The present invention relates to an immersion membrane device using parallel-connected membrane units.

【0002】[0002]

【従来の技術】処理槽の液中に上述した膜ユニットを浸
漬し、膜ユニットの内部を吸引して膜を透過した濾過処
理水を得る浸漬膜装置は従来から公知である。この浸漬
膜装置を運転して膜濾過を行った場合、濾過の進行に伴
い膜面近傍に高分子溶存物質等の高濃度な濃度分極層、
或いはこれがゲル状になったゲル層などの非濾過物質が
存在するようになると共に、微細な粒子、生物フロッ
ク、金属水酸物等の非濾過物質からなるケーク層が膜面
に付着する。ケーク層の濾過抵抗の成長速度はゲル層と
比較して極めて緩やかであるが、厚い付着層を形成す
る。これらのゲル層やケーク層によって濾過抵抗が生
じ、濾過効率が低下する。そこで、一定時間、膜濾過を
行ったら、又は膜濾過運転中に一定濾過圧力になる毎に
運転を中止し、膜ユニットに下から気泡を浴びせ膜の間
を浮上する気泡と、上向水流とによりゲル層や、ケーク
層を膜面から剥離したのち逆洗を行い、濾過性能を回復
させる。尚、散気は逆洗の前だけでなく、逆洗の後にも
行うことがある。
2. Description of the Related Art An immersion membrane apparatus in which the above-mentioned membrane unit is immersed in a liquid in a treatment tank, and the inside of the membrane unit is suctioned to obtain filtered water permeated through the membrane is conventionally known. When the membrane filtration is performed by operating this immersion membrane device, a concentration-polarized layer having a high concentration of a polymer-dissolved substance or the like near the membrane surface as the filtration proceeds,
Alternatively, a non-filtration substance such as a gel layer formed from a gel thereof is present, and a cake layer made of a non-filtration substance such as fine particles, biological flocs, and metal hydroxides adheres to the membrane surface. The growth rate of the filtration resistance of the cake layer is much slower than that of the gel layer, but forms a thick adhesion layer. These gel layers and cake layers cause filtration resistance and reduce filtration efficiency. Therefore, after performing the membrane filtration for a certain period of time, or whenever the filtration pressure becomes constant during the membrane filtration operation, the operation is stopped, and the bubbles are applied to the membrane unit from below and float between the membranes, and the upward water flow. After the gel layer and the cake layer are peeled off from the membrane surface, back washing is performed to recover the filtration performance. Aeration may be performed not only before backwashing but also after backwashing.

【0003】[0003]

【発明が解決しようとする課題】しかし、従来は散気に
よって膜面からゲル層やケーク層を剥離、除去するのに
非常に時間がかゝる。従って、散気装置を駆動する動力
コストも非常に嵩む。
Conventionally, however, it takes a very long time to separate and remove the gel layer and the cake layer from the film surface by aeration. Therefore, the power cost for driving the air diffuser is very high.

【0004】[0004]

【課題を解決するための手段】そこで、本発明は、処理
槽の液中に膜ユニットを浸漬し、膜を透過した濾過処理
水を得る浸漬膜装置において、処理槽内の膜ユニットの
下方に直径10mm以上の粗大気泡の散気装置と、直径
3mm以下の微細気泡の散気装置を設けたことを特徴と
する。
SUMMARY OF THE INVENTION Accordingly, the present invention is directed to a submerged membrane apparatus in which a membrane unit is immersed in a liquid in a treatment tank to obtain filtered water permeated through the membrane. A diffuser for large bubbles with a diameter of 10 mm or more and a diameter
An air diffuser for fine bubbles of 3 mm or less is provided.

【0005】[0005]

【実施例】図示の実施例において、10は処理槽で、処
理槽の液中には膜ユニット11が浸漬してあり、ポンプ
12を接続した吸引管13が膜ユニットの内部を吸引
し、処理槽内の原液中、膜ユニット11を透過したもの
を濾過処理水として採水する。膜ユニットは、前述した
ように平膜の複数枚の積層体、又は中空糸膜を平面状、
或いはすだれ状にした膜エレメントの複数枚の積層体、
又は管状膜を複数本並行に接続したものである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS In the illustrated embodiment, reference numeral 10 denotes a processing tank, in which a membrane unit 11 is immersed in the liquid in the processing tank, and a suction pipe 13 connected to a pump 12 sucks the inside of the membrane unit to process. The undiluted solution in the tank that has passed through the membrane unit 11 is sampled as filtered water. The membrane unit is formed by stacking a plurality of flat membranes or hollow fiber membranes as described above,
Alternatively, a plurality of laminated bodies of interleaved membrane elements,
Alternatively, a plurality of tubular membranes are connected in parallel.

【0006】濾過の進行に伴い濾過抵抗を生じさせる前
述の濃度分極層ないしゲル層と、ケーク層を気泡により
膜面から効果的に剥離すべく、気泡の大きさと、その効
果の関係に付いて研究した結果、以下のことが明らかに
なった。先ず濃度分極層ないしゲル層の抑制には、処理
槽内の液に膜面沿いの大流速を与えることが効果的であ
り、それには直径3mm以下の微小気泡による方が効果
が高い。これは、微小気泡の方がホールドアップ(気泡
混合部の気体の割合い)が大きくなり、エアリフト循環
流量が増大するためであって、粗大気泡で同じ効果を得
るには散気量を大幅に増す必要があり、エネルギー消費
が大になる。
[0006] In order to effectively separate the above-mentioned concentration-polarized layer or gel layer, which causes filtration resistance as the filtration proceeds, and the cake layer from the membrane surface with the bubbles, the relationship between the size of the bubbles and the effect thereof is described. The study revealed the following: First, to suppress the concentration polarization layer or the gel layer, it is effective to apply a large flow velocity along the membrane surface to the liquid in the treatment tank, and the effect is more enhanced by microbubbles having a diameter of 3 mm or less. This is because the hold-up (the proportion of gas in the bubble mixing section) of the microbubbles becomes larger and the circulation flow rate of the air lift increases. Need to be increased, and energy consumption will be large.

【0007】又、膜面に付着するケーク層を剥離するに
は、直径10mm以上の粗大気泡を膜面に衝突させるこ
とが効果的である。これはケーク層の剥離が気泡の界面
での剪断力に起因するため、或る程度大きな気泡でない
と剥離に寄与しないからである。逆にいうと微小な気泡
をいくら散気し、膜面に衝突させてもケーク層は剥離し
ないということである。要するに、微小気泡のみを散気
した場合には濃度分極層の抑制には効果的ではあるが、
ケーク層を剥離することはできないため濾過抵抗が経時
的に増大し、膜面を透過する濾過流速は低下する。又、
粗大気泡のみを散気した場合は膜面流速を与えるために
は多大の散気量を必要とし、エネルギーロスが大にな
る。
In order to peel off the cake layer adhering to the film surface, it is effective to cause large bubbles having a diameter of 10 mm or more to collide with the film surface. This is because the peeling of the cake layer is caused by the shearing force at the interface between the bubbles, and the cake layer does not contribute to the peeling unless the bubbles are somewhat large. In other words, the cake layer does not peel off even if small bubbles are scattered and collided with the film surface. In short, when only microbubbles are diffused, it is effective in suppressing the concentration polarization layer,
Since the cake layer cannot be peeled off, the filtration resistance increases with time, and the filtration flow rate permeating the membrane surface decreases. or,
When only coarse bubbles are diffused, a large amount of gas diffusion is required to give a film surface flow velocity, resulting in a large energy loss.

【0008】このため、濾過槽内の、膜ユニット11の
下方に、膜ユニットの下面全体に気泡を作用させるため
の散気孔が大きな直径10mm以上の粗大気泡用の散気
装置14と、散気孔が小さい直径3mm以下の微小気泡
用の散気装置が設けてあり、この実施例では共通のブロ
ワ16で給気するようになっている。
For this reason, in the filtration tank, below the membrane unit 11, a diffuser 14 for large bubbles having a large diameter of 10 mm or more, which has a large diffuser hole for allowing bubbles to act on the entire lower surface of the membrane unit, Is provided with an air diffuser for small air bubbles having a diameter of 3 mm or less . In this embodiment, air is supplied by a common blower 16.

【0009】従って、膜濾過を一定時間行ったら、又は
膜濾過の運転中に一定濾過圧力に達したら、運転を中止
し、逆洗を行う前後に、両散気装置14,15を同時に
連続的、或いは間欠的に作動するか、直径3mm以下の
微小気泡の散気装置15のみ連続的に作動し、直径10
mm以上の粗大気泡の散気装置14は間欠的に作動させ
るか、又は両散気装置14,15を共に間欠的に作動さ
せるが、粗大気泡の散気装置の散気時間を短く(散気の
中断間隔を長くすることを含む)するといった具合に両
散気装置を運転し、直径10mm以上の粗大気泡と、
径3mm以下の微小気泡を膜ユニットの膜面に作用さ
、直径10mm以上の粗大気泡で膜面に付着するケー
ク層を効果的に剥離し、膜面に付着するゲル層を直径3
mm以下の微小気泡で効果的に剥離する。尚、散気に付
いて実施例では膜の運転を中止した後に行う逆洗の前後
に行うもので説明したが、これに限らず膜の運転中に常
時行うものでもよい。
Therefore, when the membrane filtration is performed for a certain period of time or when a certain filtration pressure is reached during the operation of the membrane filtration, the operation is stopped, and before and after the backwashing, the two air diffusers 14 and 15 are simultaneously and continuously operated. , Or intermittently, or only the microbubble diffuser 15 having a diameter of 3 mm or less is continuously operated, and has a diameter of 10 mm.
The diffuser 14 for coarse bubbles having a diameter of not less than 1 mm is operated intermittently, or both diffusers 14 and 15 are operated intermittently. of driving both air diffuser in so on the included) to be prolonged interruption interval, the more coarse bubble diameter 10 mm, straight
A microbubble having a diameter of 3 mm or less acts on the membrane surface of the membrane unit, and a large bubble having a diameter of 10 mm or more adheres to the membrane surface.
The gel layer adhered to the film surface was effectively peeled off with a diameter of 3 mm.
mm effectively peeling in the following micro-bubbles. In the embodiment, the air diffusion is described as being performed before and after the backwashing performed after the operation of the membrane is stopped. However, the invention is not limited to this and may be performed constantly during the operation of the membrane.

【0010】[0010]

【発明の効果】これにより、最小のエネルギーでもって
膜面に付着するゲル層を直径3mm以 下の微小気泡で
ケーク層を直径10mm以上の粗大気泡で、夫々効果的
に膜面から剥離し、濾過に寄与する有効膜面積を大きく
とれるため膜面を透過する濾過流束を常時、最良の状態
に保ち、低エネルギーで濾過を行うことができる。
EFFECT OF THE INVENTION] This minimum gel layer adheres to <br/> film surface with an energy of at microbubbles under 3mm diameter than,
The cake layer is effectively separated from the membrane surface by coarse bubbles with a diameter of 10 mm or more , and the effective membrane area contributing to filtration can be increased, so that the filtration flux passing through the membrane surface is always kept in the best condition, Filtration can be performed with energy.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施例の断面図である。FIG. 1 is a sectional view of one embodiment of the present invention.

【符号の説明】[Explanation of symbols]

10 処理槽 11 膜ユニット 12 ポンプ 13 吸引管 14 粗大気泡用の散気装置 15 微小気泡用の散気装置 16 ブロワー DESCRIPTION OF SYMBOLS 10 Processing tank 11 Membrane unit 12 Pump 13 Suction pipe 14 Air diffuser for coarse bubbles 15 Air diffuser for fine bubbles 16 Blower

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 処理槽の液中に膜ユニットを浸漬し、膜
を透過した濾過処理水を得る浸漬膜装置において、処理
槽内の膜ユニットの下方に直径10mm以上の粗大気泡
の散気装置と、直径3mm以下の微細気泡の散気装置を
設けたことを特徴とする浸漬膜装置。
1. An immersion membrane apparatus for immersing a membrane unit in a liquid in a processing tank to obtain filtered water permeated through the membrane, wherein a diffuser for coarse bubbles having a diameter of 10 mm or more is provided below the membrane unit in the processing tank. And an air diffusion device for fine bubbles having a diameter of 3 mm or less .
JP34595693A 1993-12-24 1993-12-24 Immersion membrane equipment Expired - Fee Related JP3341427B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34595693A JP3341427B2 (en) 1993-12-24 1993-12-24 Immersion membrane equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34595693A JP3341427B2 (en) 1993-12-24 1993-12-24 Immersion membrane equipment

Publications (2)

Publication Number Publication Date
JPH07185270A JPH07185270A (en) 1995-07-25
JP3341427B2 true JP3341427B2 (en) 2002-11-05

Family

ID=18380149

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34595693A Expired - Fee Related JP3341427B2 (en) 1993-12-24 1993-12-24 Immersion membrane equipment

Country Status (1)

Country Link
JP (1) JP3341427B2 (en)

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