JP3337045B2 - Liquid crystal display - Google Patents

Liquid crystal display

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Publication number
JP3337045B2
JP3337045B2 JP31416594A JP31416594A JP3337045B2 JP 3337045 B2 JP3337045 B2 JP 3337045B2 JP 31416594 A JP31416594 A JP 31416594A JP 31416594 A JP31416594 A JP 31416594A JP 3337045 B2 JP3337045 B2 JP 3337045B2
Authority
JP
Japan
Prior art keywords
liquid crystal
film
crystal display
pixel electrode
electrode film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP31416594A
Other languages
Japanese (ja)
Other versions
JPH08146448A (en
Inventor
実 中野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sony Corp
Original Assignee
Sony Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sony Corp filed Critical Sony Corp
Priority to JP31416594A priority Critical patent/JP3337045B2/en
Publication of JPH08146448A publication Critical patent/JPH08146448A/en
Application granted granted Critical
Publication of JP3337045B2 publication Critical patent/JP3337045B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、一つの表面にコモン電
極膜を有する基板と一つの表面の周辺部に周辺配線膜を
その内側に表示画素電極膜を有する基板とを上記各表面
どうしが対面する向きでその間に所定の間隔をもって周
辺部にて接着し、その基板間に生じた空間に液晶を封入
した液晶表示装置に関する。
BACKGROUND OF THE INVENTION The present invention relates to a substrate having a common electrode film on one surface and a peripheral wiring film on the periphery of one surface and a substrate having a display pixel electrode film inside the substrate. The present invention relates to a liquid crystal display device in which a liquid crystal is sealed in a space formed between substrates in a direction facing each other and adhered to a peripheral portion at a predetermined interval therebetween.

【0002】[0002]

【従来の技術】液晶表示装置として図4に示すものが知
られている。図面において、1はTFT基板で、その表
面部には薄膜トランジスタが形成され、更に、その表面
上には表示画素電極膜2、2、・・・と、それより外側
に位置する周辺配線膜3が形成されている。この周辺配
線膜3は例えば14Vの電源電圧ラインを成している。
4は後述するコモン電極膜(7)へ所定の電位を与える
ための中継点を成すコモン接続膜、5は上記表示画素電
極膜2、2、・・・上を覆うTFT側配向膜である。6
はCF基板で、その表面にはカラーフィルターが形成さ
れ、更に該カラーフィルターの表面には周辺部を除き略
全面的にコモン電極膜7が形成されている。8は該コモ
ン電極膜7の表面に形成されたCF側配向膜である。
2. Description of the Related Art FIG. 4 shows a known liquid crystal display device. In the drawing, reference numeral 1 denotes a TFT substrate on which a thin film transistor is formed, and further, display pixel electrode films 2, 2,..., And a peripheral wiring film 3 located outside thereof are formed on the surface thereof. Is formed. This peripheral wiring film 3 forms a power supply voltage line of, for example, 14V.
Reference numeral 4 denotes a common connection film serving as a relay point for applying a predetermined potential to a common electrode film (7) described later, and reference numeral 5 denotes a TFT-side alignment film that covers the display pixel electrode films 2, 2,. 6
Is a CF substrate, on the surface of which a color filter is formed, and on the surface of the color filter, a common electrode film 7 is formed on substantially the entire surface except for the peripheral portion. Reference numeral 8 denotes a CF-side alignment film formed on the surface of the common electrode film 7.

【0003】上記TFT基板1とCF基板6とは、その
薄膜トランジスタ、表示画素電極膜2、2、・・・等及
びコモン電極膜7が形成された表面どうしが対面せしめ
られ、その間に数μm(例えば3.8μm)程度の間隙
が生じるように例えば熱硬化性樹脂を介して周縁部にて
接着され、その間に生じる空間に液晶9が封入されてい
る。この液晶表示装置は使用時にはCF基板6表面のコ
モン電極膜7に例えば5.6Vの直流の電位が与えられ
ている。そして、各表示画素電極膜2には非点灯の場合
には5.6Vの電位が与えられる。また、点灯の場合に
は5.6Vよりも例えば4.5V高い電位(即ち、1
0.1V)と、5.6Vよりも4.5V低い電位(即
ち、1.1V)との間で一定周期で変化する脈流的な電
位が与えられる。
In the TFT substrate 1 and the CF substrate 6, the surfaces on which the thin film transistors, the display pixel electrode films 2, 2,..., Etc. and the common electrode film 7 are formed are opposed to each other. For example, a thermosetting resin is adhered to the peripheral portion so as to form a gap of about 3.8 μm), and a liquid crystal 9 is sealed in a space formed therebetween. In this liquid crystal display device, a DC potential of, for example, 5.6 V is applied to the common electrode film 7 on the surface of the CF substrate 6 during use. Then, a potential of 5.6 V is applied to each display pixel electrode film 2 in the case of non-lighting. In the case of lighting, a potential higher than 5.6 V, for example, 4.5 V (that is, 1 V).
0.1V) and a pulsating potential that changes at a constant cycle between a potential 4.5V lower than 5.6V (i.e., 1.1V).

【0004】[0004]

【発明が解決しようとする課題】ところで、図4に示す
ような従来の液晶表示装置には、14Vの電源ラインを
成している周辺配線膜3と、コモン電極膜7との間に、
8.4Vの電位差が生じ、その結果、液晶層9の周辺配
線膜3上の部分に8.4Vの直流電圧が加わった状態に
なり、図5(A)に示すようにCF基板6側において配
向膜8とその液晶層9との間に電気二重層を生じて画質
品位が悪化し、図5(B)に示すように時間の経過(例
えば数時間)と共に電気に二重層が徐々に奥に広がると
いう問題があった。かかる電気二重層の延び1mm程度
で略飽和し、それ以上は延びないが、例えば、ビデオカ
メラのビューファインダーのように画面の小さなものに
用いる液晶表示装置の場合、1mmの幅が電気二重層に
より画質劣化を生じることは許されない。このような電
気二重層は液晶表示装置の温度が高くなると、例えば、
50〜70℃或いはそれ以上になるとより発生し易くな
る。
By the way, in the conventional liquid crystal display device as shown in FIG. 4, there is provided between the peripheral wiring film 3 forming a 14V power supply line and the common electrode film 7.
As a result, a potential difference of 8.4 V is generated, and as a result, a DC voltage of 8.4 V is applied to the portion of the liquid crystal layer 9 on the peripheral wiring film 3, and as shown in FIG. An electric double layer is formed between the alignment film 8 and the liquid crystal layer 9 to deteriorate the image quality. As shown in FIG. 5B, the electric double layer gradually becomes deeper with the passage of time (for example, several hours). There was a problem that spread. Such an electric double layer is substantially saturated when it extends about 1 mm, and does not extend any further. For example, in the case of a liquid crystal display device used for a small screen such as a view finder of a video camera, the width of 1 mm depends on Image quality degradation is not allowed. Such an electric double layer, when the temperature of the liquid crystal display device increases, for example,
When the temperature is 50 to 70 ° C. or higher, the temperature is more likely to occur.

【0005】本発明はこのような問題点を解決すべく為
されたものであり、一つの表面にコモン電極膜を有する
基板と一つの表面の周辺部に周辺配線膜をその内側に
示画素電極膜を有する基板とを上記各表面どうしが対面
する向きでその間に所定の間隔をもって周辺部にて接着
し、その基板間に生じた空間に液晶を封入した液晶表示
装置において、コモン電極膜の形成された基板側で、周
辺配線膜とコモン電極膜との間の電位差により液晶の表
示画素電極膜上の部分において電気二重層が生じて画質
劣化を生じることを防止することを目的とする。
[0005] The present invention has been made to solve the above problem, display the peripheral wiring film on the inside perimeter of the substrate and one surface with a common electrode film on one surface
In a liquid crystal display device in which a substrate having an indicator pixel electrode film is adhered to a peripheral portion thereof at a predetermined interval in a direction in which the respective surfaces face each other and a liquid crystal is sealed in a space generated between the substrates, On the substrate side on which the film is formed, an object is to prevent an electric double layer from being formed on a portion of the liquid crystal display pixel electrode film due to a potential difference between the peripheral wiring film and the common electrode film, thereby preventing image quality deterioration. I do.

【0006】[0006]

【課題を解決するための手段】請求項1の液晶表示装置
は、上記周辺配線膜と、上記表示画素電極膜との間に信
号電圧を受けず電気的にフローティングなダミー画素電
極膜を設けてなことを特徴とする。
Means for Solving the Problems] The liquid crystal display device according to claim 1, provided with the peripheral wiring film, an electrically floating dummy pixel electrode film not receive a signal voltage between the display pixel electrode film and wherein the Do that.

【0007】請求項2の液晶表示装置は、請求項1記載
の液晶表示装置において、上記ダミー画素電極膜がそれ
が形成された基板の中央部から外側に至る断面で視て複
数あることを特徴とする。
According to a second aspect of the present invention, there is provided the liquid crystal display device according to the first aspect, wherein a plurality of the dummy pixel electrode films are viewed in a cross section extending from the center to the outside of the substrate on which the dummy pixel electrode film is formed. And

【0008】[0008]

【作用】請求項1の液晶表示装置によれば、上記表示画
素電極膜と上記周辺配線膜との間に電気的にフローティ
ングな上記ダミー画素電極膜が設けられているので、そ
のダミー画素電極膜によって液晶に電気二重層が生じる
のが阻まれ、それによる画質劣化が生じない。
SUMMARY OF] According to the liquid crystal display device according to claim 1, since the electrically floating the dummy pixel electrode film is provided between the display pixel electrode film and the peripheral wiring film, the dummy pixel electrode film This prevents the formation of an electric double layer in the liquid crystal, thereby preventing the image quality from deteriorating.

【0009】請求項2の液晶表示装置によれば、上記
示画素電極膜と上記周辺配線膜との間に存在する電気的
にフローティングな上記ダミー画素電極膜の数が複数な
ので、より有効に電気二重層の発生を阻み、電気二重層
による画質劣化を防止することができる。
[0009] According to the liquid crystal display device according to claim 2, the number of electrically floating the dummy pixel electrode film present between the table <br/>示画pixel electrode film and the peripheral wiring film is more Thus, generation of an electric double layer can be more effectively prevented, and image quality deterioration due to the electric double layer can be prevented.

【0010】[0010]

【実施例】以下、本発明を図示実施例に従って詳細に説
明する。図1は本発明液晶表示装置の一つの実施例を示
す断面図である。本液晶表示装置は、図4に示した従来
の液晶表示装置とは、周辺配線膜3が絶縁膜(10)を
介してシールド配線膜(11)で覆われ、該シールド配
線膜(11)がコモン電極膜7と電気的に接続されてい
る点で大きく相違するが、それ以外の点では共通し、そ
の共通点については既に説明済みであるので、その説明
は省略し相違する点についてのみ説明することとする。
また、全図を通して共通する部分には共通の符号を付し
た。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail with reference to the illustrated embodiments. FIG. 1 is a sectional view showing one embodiment of the liquid crystal display device of the present invention. This liquid crystal display device is different from the conventional liquid crystal display device shown in FIG. 4 in that the peripheral wiring film 3 is covered with a shield wiring film (11) via an insulating film (10), and the shield wiring film (11) is Although they are greatly different in that they are electrically connected to the common electrode film 7, they are common in other points, and the common points have already been described. Therefore, the description is omitted, and only the differences are described. I decided to.
In addition, common portions are denoted by common reference numerals throughout the drawings.

【0011】10は電源ラインを成す周辺配線膜3を覆
う絶縁膜、11は該絶縁膜10を介して周辺配線膜3を
覆うシールド配線膜で、CF基板6のコモン電極膜7と
電気的に接続されている。このような液晶表示装置によ
れば、液晶9の周辺配線膜3上の部分はその下側がシー
ルド3と接し、上側のコモン電極膜3と略同電位なの
で、上下間における電位差が生じない。従って、電気二
重層が生じるおそれがなく、画面周辺部で画質劣化の生
じるおそれがない。
Reference numeral 10 denotes an insulating film that covers the peripheral wiring film 3 forming a power supply line. Reference numeral 11 denotes a shield wiring film that covers the peripheral wiring film 3 via the insulating film 10 and electrically connects with the common electrode film 7 of the CF substrate 6. It is connected. According to such a liquid crystal display device, the lower portion of the liquid crystal 9 on the peripheral wiring film 3 is in contact with the shield 3 and has substantially the same potential as the upper common electrode film 3, so that there is no potential difference between the upper and lower portions. Therefore, there is no possibility that an electric double layer is formed, and there is no possibility that image quality is deteriorated in a peripheral portion of the screen.

【0012】図2は本発明液晶表示装置の第2の実施例
を示す断面図である。本液晶表示装置についても従来の
液晶表示装置と相違する点についてのみ説明する。本液
晶表示装置はCF基板6表面(液晶側の面)のコモン電
極膜8が表示画素電極膜2、2、・・・の形成領域と対
応する位置からほとんど食み出ないように形成されてい
る。具体的には、周辺配線膜7の周縁と、該周縁と対応
する表示画素電極膜2の外側面とでは、周辺配線膜7周
縁の方がやや外側に位置しており、そのずれdは100
μm以下である。
FIG. 2 is a sectional view showing a second embodiment of the liquid crystal display device of the present invention. The present liquid crystal display device will also be described only for the points different from the conventional liquid crystal display device. The present liquid crystal display device is formed such that the common electrode film 8 on the surface of the CF substrate 6 (the surface on the liquid crystal side) hardly protrudes from a position corresponding to the formation region of the display pixel electrode films 2, 2,. I have. Specifically, between the peripheral edge of the peripheral wiring film 7 and the outer surface of the display pixel electrode film 2 corresponding to the peripheral edge, the peripheral edge of the peripheral wiring film 7 is located slightly outside, and the deviation d is 100
μm or less.

【0013】本液晶表示装置は、コモン電極膜8を表示
画素電極膜2、2、・・・の形成領域と対応する位置か
らほとんど食み出ないように形成したので、CF基板6
の周辺配線膜3と対応する位置にはコモン電極膜7が存
在していない。従って、液晶9の周辺配線膜3上におけ
る部分にはコモン電極膜8と周辺配線膜3との電位差が
加わらない。依って、電気二重層が生じるおそれがな
く、延いては、画面周辺部で画質劣化の生じるおそれが
ない。
In the present liquid crystal display device, the common electrode film 8 is formed so as to hardly protrude from a position corresponding to the formation region of the display pixel electrode films 2, 2,.
The common electrode film 7 does not exist at a position corresponding to the peripheral wiring film 3 of FIG. Therefore, the potential difference between the common electrode film 8 and the peripheral wiring film 3 is not applied to the portion of the liquid crystal 9 on the peripheral wiring film 3. Therefore, there is no possibility that an electric double layer is formed, and thus there is no possibility that image quality is deteriorated in the peripheral portion of the screen.

【0014】図3は本発明液晶表示装置の第3の実施例
を示す断面図である。本液晶表示装置についても従来の
液晶表示装置と相違する点についてのみ説明する。本液
晶表示装置は、表示画素電極膜2、2、・・・のうち周
辺配線膜3に最も近い外側の表示画素電極膜2をダミー
画素電極膜2aとし、表示に使用しない。即ち、表示す
る電圧をそのダミー画素電極膜2aには印加しない。具
体的には電気的にフローティングにする。従って、有効
画素はそれより内側に存在する。
FIG. 3 is a sectional view showing a third embodiment of the liquid crystal display device of the present invention. The present liquid crystal display device will also be described only for the points different from the conventional liquid crystal display device. In the present liquid crystal display device, of the display pixel electrode films 2, 2,..., The outer display pixel electrode film 2 closest to the peripheral wiring film 3 is a dummy pixel electrode film 2a and is not used for display. That is, the display voltage is not applied to the dummy pixel electrode film 2a. Specifically, it is made electrically floating. Therefore, the effective pixel exists inside it.

【0015】有効画素と周辺配線膜3との間にダミー画
素電極膜2aがあるので、有効画素となる表示画素電極
膜2、2、・・・のうち最も周辺配線膜3に近い表示画
素電極膜2でも周辺配線膜3との間に100μm程度の
距離ができ、その結果、液晶9の直流印加部分が有効画
素から遠くなり、電気二重層による有効画素領域への影
響も生じにくくなる。依って、本液晶表示装置によれ
ば、画面周辺部で画質劣化の生じるおそれが少ない。
Since there is a dummy pixel electrode film 2a between the effective pixel and the peripheral wiring film 3, the display pixel electrode closest to the peripheral wiring film 3 among the display pixel electrode films 2, 2,. The film 2 also has a distance of about 100 μm between the film 2 and the peripheral wiring film 3. As a result, the DC applied portion of the liquid crystal 9 is far from the effective pixels, and the electric double layer hardly affects the effective pixel region. Therefore, according to the present liquid crystal display device, there is little possibility that the image quality is deteriorated in the peripheral portion of the screen.

【0016】尚、周辺配線膜3に最も近い表示画素電極
膜2だけでなく、図3の2点鎖線の引出線で示すよう
に、その内側の表示画素電極膜2をも電気的にフローテ
ィングなダミー画素電極膜2aとしても良い。すると、
有効画素となる表示画素電極膜2、2、・・・のうち最
も周辺配線膜3に近い表示画素電極膜2でも周辺配線膜
3との間に約200μm程度もの距離ができるので、よ
り電気二重層による有効画素領域への影響が及びにくく
なり、画質劣化防止効果を高めることができる。
It is noted that not only the display pixel electrode film 2 closest to the peripheral wiring film 3 but also the display pixel electrode film 2 on the inner side thereof is electrically floating as shown by a two-dot chain line in FIG. The dummy pixel electrode film 2a may be used. Then
Since the display pixel electrode film 2 closest to the peripheral wiring film 3 among the display pixel electrode films 2, 2,... The effect on the effective pixel area due to the multilayer is less likely to occur, and the effect of preventing image quality deterioration can be enhanced.

【0017】[0017]

【発明の効果】請求項1の液晶表示装置によれば、上記
表示画素電極膜と上記周辺配線膜との間に電気的にフロ
ーティングなダミー画素電極膜が設けられているので、
そのダミー画素電極膜によって液晶に電気二重層が生じ
るのが阻まれ、それによる画質劣化が生じない。
According to the liquid crystal display device according to claim 1, according to the present invention, since an electrically floating dummy pixel electrode film between the <br/> display pixel electrode film and the peripheral wiring film is provided,
The formation of an electric double layer in the liquid crystal is prevented by the dummy pixel electrode film, and the image quality does not deteriorate due to the electric double layer.

【0018】請求項2の液晶表示装置によれば、上記
示画素電極膜と上記周辺配線膜との間に存在する電気的
にフローティングな上記ダミー画素電極膜の数が複数な
ので、より有効に電気二重層の発生を阻み、電気二重層
による画質劣化を防止することができる。
According to the liquid crystal display device according to claim 2, the number of electrically floating the dummy pixel electrode film present between the table <br/>示画pixel electrode film and the peripheral wiring film is more Thus, generation of an electric double layer can be more effectively prevented, and image quality deterioration due to the electric double layer can be prevented.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明液晶表示装置の第1の実施例を示す断面
図である。
FIG. 1 is a sectional view showing a first embodiment of the liquid crystal display device of the present invention.

【図2】本発明液晶表示装置の第2の実施例を示す断面
図である。
FIG. 2 is a sectional view showing a second embodiment of the liquid crystal display device of the present invention.

【図3】本発明液晶表示装置の第3の実施例を示す断面
図である。
FIG. 3 is a sectional view showing a third embodiment of the liquid crystal display device of the present invention.

【図4】液晶表示装置の従来例を示す断面図である。FIG. 4 is a sectional view showing a conventional example of a liquid crystal display device.

【図5】(A)、(B)は従来の液晶表示装置の問題点
を示す断面図である。
FIGS. 5A and 5B are cross-sectional views showing problems of a conventional liquid crystal display device.

【符号の説明】[Explanation of symbols]

1 TFT基板 2 表示画素電極膜 2a ダミー画素電極膜 3 周辺配線膜 6 CF基板 7 コモン電極膜 9 液晶 10 絶縁膜 11 シールド配線膜 Reference Signs List 1 TFT substrate 2 display pixel electrode film 2a dummy pixel electrode film 3 peripheral wiring film 6 CF substrate 7 common electrode film 9 liquid crystal 10 insulating film 11 shield wiring film

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) G02F 1/1345 G02F 1/1368 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 7 , DB name) G02F 1/1345 G02F 1/1368

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 一つの表面にコモン電極膜を有する基板
と一つの表面の周辺部に周辺配線膜をその内側に表示画
素電極膜を有する基板とを上記各表面どうしが対面する
向きでその間に所定の間隔をもって周辺部にて接着し、
その基板間に生じた空間に液晶を封入した液晶表示装置
において、上記 周辺配線膜と、上記表示画素との間に信号電圧を受
けず電気的にフローティングなダミー画素電極膜を設け
てなることを特徴とする液晶表示装置
1. A substrate having a common electrode film on one surface and a peripheral wiring film on a peripheral portion of the one surface inside a display image.
A substrate having an element electrode film is adhered at a peripheral portion with a predetermined interval between the surfaces in a direction facing each other,
In the liquid crystal display device in which liquid crystal is sealed space formed between the substrate and the peripheral wiring film, an electrically be provided floating dummy pixel electrode film not receive a signal voltage between the display pixel Characteristic liquid crystal display
【請求項2】 上記ダミー画素電極膜がそれが形成され
た基板の中央部から外側に至る断面で視て複数あること
を特徴とする請求項1記載の液晶表示装置
2. The liquid crystal display device according to claim 1, wherein there are a plurality of said dummy pixel electrode films as viewed in a cross section extending from the center to the outside of the substrate on which said dummy pixel electrode films are formed.
JP31416594A 1994-11-22 1994-11-22 Liquid crystal display Expired - Lifetime JP3337045B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP31416594A JP3337045B2 (en) 1994-11-22 1994-11-22 Liquid crystal display

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP31416594A JP3337045B2 (en) 1994-11-22 1994-11-22 Liquid crystal display

Publications (2)

Publication Number Publication Date
JPH08146448A JPH08146448A (en) 1996-06-07
JP3337045B2 true JP3337045B2 (en) 2002-10-21

Family

ID=18050033

Family Applications (1)

Application Number Title Priority Date Filing Date
JP31416594A Expired - Lifetime JP3337045B2 (en) 1994-11-22 1994-11-22 Liquid crystal display

Country Status (1)

Country Link
JP (1) JP3337045B2 (en)

Cited By (2)

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US9557605B2 (en) 2010-10-14 2017-01-31 Merck Patent Gmbh Method of producing liquid crystal display device
US9798179B2 (en) 2010-10-14 2017-10-24 Merck Patent Gmbh Liquid crystal display device

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Publication number Priority date Publication date Assignee Title
GB0205479D0 (en) * 2002-03-08 2002-04-24 Koninkl Philips Electronics Nv Matrix display devices
GB0228269D0 (en) * 2002-12-04 2003-01-08 Koninkl Philips Electronics Nv Active matrix display devices
CN102257548A (en) * 2009-05-15 2011-11-23 夏普株式会社 Display panel and display device provided with this
JP4713659B2 (en) * 2009-09-15 2011-06-29 シャープ株式会社 Liquid crystal display device
JP5895473B2 (en) * 2011-11-22 2016-03-30 セイコーエプソン株式会社 Liquid crystal device and electronic device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9557605B2 (en) 2010-10-14 2017-01-31 Merck Patent Gmbh Method of producing liquid crystal display device
US9798179B2 (en) 2010-10-14 2017-10-24 Merck Patent Gmbh Liquid crystal display device

Also Published As

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