JP3300747B2 - Corrosion and heat resistant Ni-based alloy for waste incinerator - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to plastic workability, weldability, and the like, which exhibit excellent high-temperature corrosion resistance in an atmosphere in which dust containing chlorides, sulfates, oxides, etc., such as waste gas from a refuse incineration boiler exists. The present invention relates to a corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator having good high-temperature strength characteristics and good structural stability during long-term use at high temperatures.

[0002]

2. Description of the Related Art Municipal waste, industrial waste, and the like contain a wide variety of substances.
1, Na that generates and simultaneously contains SO ₂ ,
Alkaline or alkaline earth metals such as K and Ca or P
Reacts with heavy metals such as b and Zn to generate dust containing a mixed salt of chloride and sulfate having a low melting point. In the presence of such corrosive gas and attached dust, conventional low alloy steels, stainless steels, Ni-based alloys, and Co-based alloys exhibit large corrosion rates. Above all, the boiler for recovering the waste heat of the above-mentioned combustion furnace and generating electricity has severe corrosion damage to the boiler tube, and the boiler has been strongly promoted in terms of energy saving, resource saving and environmental protection. There is a demand for a high-temperature corrosion-resistant material for boiler tubes that exhibits excellent corrosion resistance.

For example, an existing Ni-based alloy 625 alloy (Alloy 625) is known to exhibit relatively good corrosion resistance in such an environment, but Al, Ti, N
b, which causes the precipitation of intermetallic compounds such as Ni ₃ Nb, resulting in high high-temperature strength, but poor tube formability and tube bending workability. Limited. Also, 500
When used at high temperatures over ℃ for a long period of time, precipitation of intermetallic compounds progresses, which tends to cause embrittlement, resulting in poor structural stability at high temperatures. . Further, the inclusion of a high concentration of Mo also causes deterioration of tube formability and an increase in cost.

On the other hand, as an alloy exhibiting good corrosion resistance under the above-mentioned environment, Cr-N containing relatively large amount of Si is used.
i-Fe alloys have been proposed (for example, Japanese Patent Publication No.
9977, JP-A-4-83842, etc.).
In alloys containing a large amount of Si, intermetallic compounds such as Ni ₃ Si generally precipitate, which deteriorates tube formability, workability, and weldability. In addition, when used for long periods at high temperatures, embrittlement and corrosion resistance deteriorate. There is no example of the use as a material, and it is necessary to devise a component.However, even the technology described in the above-mentioned publication considers such seamless tube formability and tissue stability during long-term use at high temperatures. Not.

In order to improve the accuracy of the corrosion resistance evaluation of materials used in a waste combustion environment, a laboratory condition simulating a dust atmosphere in which chlorides, sulfates, and oxides adhering to an actual machine are mixed. The evaluation in the lower part or in the actual machine is indispensable, but such evaluation is not made in the above-mentioned publication, and it is difficult to determine the corrosion resistance of the boiler tube.

[0006]

SUMMARY OF THE INVENTION In view of the circumstances of the prior art, the present invention provides excellent high-temperature corrosion resistance in an atmosphere where dust containing chlorides, sulfates, oxides and the like such as exhaust gas from a refuse incineration boiler exists. exhibits plastic workability, weldability, high temperature strength, structural stability is good dust at high temperature for a long time using
An object of the present invention is to provide a corrosion-resistant and heat-resistant Ni-based alloy for an incinerator .

[0007]

According to the present invention, the composition of the component (1) is as follows: C: 0.01 to 0.3% by weight, Si: 2 to 4.3% by weight.
%, P: 0.03% or less, S: 0.03% or less, Cr:
22 to 31%, Fe: 8 to 30%, Mn: 0.1 to 3
%, Nb and / or Ta: 0.1 to 1%, Ti: 0.0
3 to 0.6%, Al: 0.03 to 0.6%, B: 0.0
A corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator , characterized by comprising 0.01 to 0.01%, inevitable impurities and a balance of Ni;
(2) N, Mo, W is added to the corrosion-resistant and heat-resistant Ni-based alloy of (1).
And at least one element selected from the group consisting of Co and N by weight%: 0.05 to 0.5%, Mo: 0.3 to 5%,
W: 0.5 to 3%, Co: 0.5 to 3%, which is added in such a range as to be corrosion-resistant and heat-resistant Ni-based alloy for refuse incinerator , (3) the above (1) or Rare earth metal, alkaline earth metal and Zr
At least one element selected from the group consisting of: rare earth metal: 0.1% or less, alkaline earth metal: 0.1% by weight
In the following, Zr is added in a range of 0.2% or less, and the content ratio of the corrosion-resistant heat-resistant Ni-based alloy for a waste incinerator and (4) Si is 3.09 to 4.0. 3
Which is the (1) to (3) corrosion resistant Ni-based alloy metal for any one incineration device which is a%.

The corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator according to the present invention has been developed to develop a material having excellent high-temperature corrosion resistance that can be used under high-temperature corrosive conditions such as a waste combustion environment in order to solve the problems of the prior art. It was discovered as a result of intensive research. The components and compositions of the alloy of the present invention have the following characteristics as compared with conventional materials.

[0009] High-temperature corrosion occurring in an environment in which a combustion gas containing Cl or S and molten dust adhere is a complex corrosion in which a plurality of reactions occur simultaneously. The reactions include a chloride reaction by HCl, Cl ₂ or chloride, SOx, There are sulfurization reaction by H ₂ S or sulfate, oxidation reaction by O ₂ , H ₂ O, etc. and dissolution reaction to molten salt. Under the condition where these occur simultaneously, corrosion is optimized by optimizing the amounts of Cr, Si, Fe and Ni. It is necessary to suppress the reaction.

Austenitic stainless steel or Cr-N
In the i-Fe-Si alloy, Cr and Si are each Cr ₂ O.
₃ , a protective film forming element forming an oxide such as SiO ₂ or a composite oxide thereof, and has been confirmed to be effective for oxidation and sulfidation. Usually, Cr: 15% by weight or more. , Si: 2% by weight or more is added. On the other hand, Ni is effective for chloride, and usually N
i: 14% by weight or more is added. It has been observed that Cr, Si and Fe may be harmful depending on the amount of addition, but the optimum amount of addition has not yet been elucidated sufficiently.

The present inventors have conducted intensive studies on the range of components having the best corrosion resistance under the complex corrosion reaction, and found that Cr, N
It was found that by setting the component addition amounts of i, Fe, and Si within the above ranges, the combined addition effect of these four elements was exhibited, and an unprecedentedly high corrosion resistance was obtained. When Si is added in a large amount, problems such as instability of the structure at high temperatures, embrittlement, and difficulty in plastic working occur due to precipitation of intermetallic compounds such as Ni ₃ Si. In order to solve such problems, in the alloy of the present invention, the amount of chromium is increased to 22% by weight or more, and the amount of harmful intermetallic compounds is prevented from being precipitated by regulating the amount of Si to 4.3% by weight or less. However, the above characteristics were improved by forming an austenite single phase structure.

Si is a harmful element in terms of resistance to high-temperature cracking during welding and hot workability because it easily forms a low melting point eutectic with Ni, but a small amount of Mn, Nb and / or Ta, Mo These effects were prevented by adding.

Nb and / or Ta and Mo are effective elements for the corrosion resistance to Cl, and the corrosion resistance can be further improved by adding a small amount of these elements. In addition,
Since P and S are components harmful to weldability and corrosion resistance, it is preferable to use as little as possible.

In the alloy of the present invention, C, Nb and / or Ta, T,
A small amount of i, Al, B is added to enhance precipitation strengthening and solid solution strengthening by carbides and intermetallic compounds. Similar effects can be obtained by adding a small amount of N, Zr or the like.

[0015] The alloy of the present invention can be obtained by adding a small amount of element,
n and, if necessary, the addition of a small amount of Co, in particular, improves the workability of seamless pipes, thereby facilitating the production of thick-walled, small-diameter tubes such as boilers. Also, rare earth metals (La, Ce, Y, etc.), alkaline earth metals (Ca, M
g) contributes to the cleaning of the alloy, has an effect of improving the above properties, and is considered to be particularly effective for an oxidation reaction.

The heat treatment for homogenizing the alloy of the present invention is 1100 to 1100.
Performed at 1200 ° C, and forging and hot working were performed at 1000-
Optimally, it is performed in the range of 1200 ° C.

[0017]

BEST MODE FOR CARRYING OUT THE INVENTION The alloy of the present invention is obtained by the combined effect of the main constituent elements Ni, Cr, Si, and Fe and the addition of a small amount of Mn, C, Nb and / or Ta, Ti, Al, B. Demonstrates excellent high-temperature corrosion resistance in the presence of Cl, S, prevents precipitation of a large amount of intermetallic compounds under long-term use at high temperatures, achieves stabilization of the metal structure, forgeability,
It exhibits excellent performance as a high-temperature corrosion-resistant material, especially as a boiler tube, such as improving the hot workability to improve the productivity of seamless tubes and the like, and preventing welding cracks. The effects of each element and the reasons for limiting the alloy element composition will be described below.

(1) Cr, Si, Fe: These elements are
Cr each_TwoO_Three, SiO_Two, Fe _ThreeO_Four(Fe_TwoO
_Three) As a source that forms a dense oxide film in combustion gas
Cr and Si are particularly SOx or H_TwoS or
Effective elements for corrosion resistance under high temperature corrosion environment by sulfate
It is known as However, these elements alone cause strong decay.
HCl or Cl with food properties_TwoAnd chloride-containing solutions
The corrosion resistance is not sufficiently exhibited when the molten dust adheres.

In the alloy of the present invention, the base material Ni contains 22 to 31% by weight of Cr, preferably 23 to 28% by weight,
From 2 to 4.3% by weight, preferably from 2.5 to 4% by weight,
e is added in an amount of 8 to 30% by weight, and preferably 9 to 28% by weight, so that the composite addition effect exerts much more excellent corrosion resistance than the conventional Ni-based alloy. If Cr is contained more than this component range, the corrosion resistance is deteriorated, and if it is small, many intermetallic compounds such as Ni ₃ Si appear, the hot workability is reduced, and the structure due to long-term use at high temperature is deteriorated. Destabilization,
Embrittlement of the material is promoted. On the other hand, the higher the content of Si, the higher the corrosion resistance, but the lower the workability and weldability, so the upper limit was made 4.3% by weight. Further, Fe is an essential element for improving corrosion resistance as an alloy component of the present invention, and exhibits the best corrosion resistance within the above range. Fe is 16% by weight or less in order to maintain good corrosion resistance regardless of the amount of Cl,
Preferably, the content should be 9 to 13% by weight.
Under the condition of low Cl and high S, even if it is increased to 30% by weight, good corrosion resistance is maintained as compared with the 625 alloy. Therefore, the upper limit of Fe is set to 30% by weight. Increasing the Fe content within the allowable range of corrosion resistance has the effect of improving plastic workability.

(2) Ni: Ni is an element indispensable for obtaining an austenitic single phase structure, is a base metal of the present alloy, and is an element indispensable for improving corrosion resistance to Cl. An amount of at least 52% by weight is required. The Ni content is preferably 35% by weight or more, and is preferably 52% by weight or more in order to maintain good corrosion resistance regardless of the amount of Cl.

(3) C: If the content of C is increased, corrosion resistance is degraded due to grain boundary precipitation of chromium carbide and the like, and this is a factor that promotes embrittlement. Therefore, the upper limit was made 0.3% by weight. On the other hand, the addition of a small amount is effective for improving the high temperature strength and the creep resistance, and the lower limit is set to 0.01% by weight. A preferred range is 0.01 to 0.05% by weight.

(4) P, S: P and S contained as impurities not only deteriorate corrosion resistance, but also reduce hot workability.
A smaller amount is preferable in order to deteriorate workability such as weldability, and the upper limit is set to 0.03% by weight.

(5) Nb, Ta: Nb and Ta are effective for stabilizing carbides, fixing C and improving corrosion resistance, but from the viewpoint of aging and structural stability, the total of both is 0.1 to 1 weight. %, Preferably 0.25 to 0.35% by weight.

(6) Mn: Mn has the effect of removing the harm caused by impurities due to the S-elimination effect and the like, and also has the effect of improving the corrosion resistance, workability and weldability by adding a small amount thereof. 0.1 to 3% by weight, preferably 0.5 to
A small amount of 1.5% by weight was added.

(7) Al, Ti: Al and Ti are generally used as deoxidizing agents, but if they are added in large amounts, intermetallic compounds are formed, and the structure stability and plastic workability deteriorate. 0.6% by weight. On the other hand, Ni
_{3 In} order to impart an effect of improving high-temperature strength by precipitation of (Al, Ti) or the like, it is necessary to add 0.03% by weight or more. The preferred range is 0.05 to 0.4% by weight.

(8) B: The addition of a small amount of B is effective for strengthening the crystal grain boundaries, but the addition of a large amount leads to embrittlement due to precipitation of intermetallic compounds and deterioration of workability.
01% by weight.

Further , the corrosion-resistant heat-resistant N for the refuse incinerator of the present invention is used.
The i-base alloy contains the above-mentioned element as a basic component, but the properties of the above-mentioned basic composition alloy can be improved by adding a small amount or a small amount of the following element according to the purpose.

(9) N: N is effective for improving high-temperature strength by precipitation of nitride. Further, it is effective for stabilizing the austenite phase and preventing intergranular corrosion, but is added in an amount of 0.05 to 0.5% by weight in order to promote embrittlement and aging of the material by adding a large amount.

(10) Mo: Mo is an element that contributes to the improvement of corrosion resistance and strength in addition to the addition of Cr. However, when added in a large amount, plastic workability deteriorates, so the upper limit was set to 5% by weight. On the other hand, to improve properties such as weldability and corrosion resistance, it is necessary to add 0.3% by weight or more. A preferred range is 0.5 to 3% by weight.

(11) W: W is an element having the same effect as Mo. However, since addition of a large amount is harmful to machinability, it is preferable to add a small amount of 0.5 to 3% by weight.

(12) Co: Co has an effect of improving the plastic workability without deteriorating the corrosion resistance and can be added in the range of 0.5 to 3% by weight.

(13) Rare earth elements: La, Ce, Y, H
rare earth elements such as f improve the adhesion of the oxide film,
It is effective for improving sulfuration resistance and oxidation resistance, and is also effective for cleaning materials. Therefore, it can be added in a range of 0.1% by weight or less that does not significantly change mechanical properties.

(14) Zr, alkaline earth metal: Zr and alkaline earth metal such as Ca and Mg strengthen the crystal grain boundary of the Ni-based alloy, and when it is necessary to improve creep resistance and the like, Zr is used. A trace amount of 0.2% by weight or less and an alkaline earth metal of 0.1% by weight or less can be added.

The corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator according to the present invention is used for burning inhomogeneous waste such as municipal waste, industrial waste, and sludge, as well as boilers, metal parts, grate and the like attached thereto. It can be suitably applied to members requiring high-temperature corrosion resistance. In addition, it exhibits excellent corrosion resistance, heat resistance, and structural stability as a high-temperature corrosion-resistant material for fossil fuel combustion devices, chemical plants, and general equipment placed in a similar high-temperature atmosphere containing Cl and S. The corrosion resistant heat-resistant Ni-based alloy may be used in a seamless tube, a rolled plate, a casting, a clad tube, or the like. In addition, by producing powder, it can be used as thermal spray, overlay, powder molded product, and the like.

[0035]

[Experimental example 1]

In order to determine the component ranges of Cr, Fe, and Si, which are the main components in the corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator of the present invention, and Mo, which is an optional additive component, the respective components were added to the Ni-based alloy, and the amount added. The relationship with the corrosion weight loss was investigated. For the samples, test pieces were prepared in the same manner as in Example 1 described later, using raw materials having the respective compositions. The test method was also the same as in Example 1 described later.

FIG. 3 shows the effect of adding Cr to the 4Si-10Fe-Ni-based alloy. In the case of ash A, the amount of corrosion becomes the minimum when the amount of Cr is 22 to 31% by weight. On the other hand, in ash B, there is no significant difference depending on the amount of Cr. The above ranges were determined as the component ranges that exhibited good corrosion resistance for both ashes.

FIG. 4 shows the effect of adding Fe to the 20Cr-4Si-Ni base alloy. In both ashes A and B, the minimum value of the corrosion weight loss was observed at Fe 10% by weight, and even in ash B having a small difference from the existing alloy 625,
Good corrosion resistance is exhibited when the amount is in the range of 8 to 16% by weight. From the tendency shown in FIG. 3, it is apparent that the corrosion loss at 10% by weight of Fe is further reduced by setting the amount of Cr at 25% by weight, and good corrosion resistance is obtained. On the other hand, C
The ash A with a small l shows good corrosion resistance with less than half the corrosion loss compared to the 625 alloy up to about 30% by weight of Fe. However, when the amount of Cr is large, Fe
When the amount exceeds 30% by weight, when used at a high temperature of 550 ° C. or more for a long time, different phases such as α phase and σ phase are apt to precipitate, and deterioration of performance such as deterioration of corrosion resistance and embrittlement increases.

FIG. 5 is a graph showing the relationship between Si and a 20Cr--Ni base alloy.
Shows the effect of adding. In this case, the tendency depending on the amount of Si is opposite for both A and B ash,
When i is 2% by weight or more, the corrosion resistance is more improved than that of Inconel 625 (625 alloy). 4.3 upper limit of Si content
The weight% was determined based on the high-temperature structure stability described below.

FIG. 6 shows the effect of adding Mo to a 20Cr-4Si-Ni base alloy. Mo is effective in improving the corrosion resistance of both ash, but when added in excess of 5% by weight, the precipitation of the σ phase and the like is promoted, so that the material becomes brittle or the plastic workability deteriorates, so the upper limit is 5% by weight. %.

The alloys shown in Table 2 below were made of the above Cr, F
C, Mn, N
b and / or Ta, Al, Ti and B are added, and if necessary, a small amount of one or more selected from the group consisting of N, Mo, W, Co, rare earth metal, alkaline earth metal and Zr is added. And the effects of these small addition elements are as described above.

Example 1 In order to evaluate the corrosion resistance of a corrosion-resistant heat-resistant Ni-based alloy for a waste incinerator of the present invention in a combustion gas environment of a waste incinerator, a corrosion test was performed in a laboratory simulated environment. As shown in FIG. 1, a test piece 3 was buried in an ash (ash A or ash B in Table 1) 2 filled in a magnetic crucible 1 as shown in FIG. After holding at 100 ° C. for 100 hours in an environment of flowing 600 ml / min, the measurement was performed by measuring the corrosion loss and the intergranular corrosion depth. For the test piece, a raw material having a composition shown in Table 2 was used, and 20 kg of the raw material was melted in vacuum to produce an ingot, which was subjected to a homogenizing heat treatment at 1150 ° C. A small test piece having a length of 14 mm, a width of 14 mm, and a thickness of 3 mm was processed from a 20 mm-thick plate-shaped test material obtained by performing a solution treatment at a temperature of ° C., and used. Table 3 shows the test results.

From the results shown in Table 3, the test material No. Nos. 1 to 8 show no cracking during hot forging, have good forgeability, and contain Cl collected from an actual machine.
Under the adhesion conditions of ashes A and B of 24% by weight and 10.1% by weight, for example, existing alloy 625 (test material No.
It can be seen that the corrosion weight loss is very small as compared with 2), and that it has excellent corrosion resistance as compared with the conventional comparative alloy. On the other hand, the test material No. In Examples 9 and 10, the corrosion resistance is superior to that of the existing alloy under the condition of ash A, and it is considered that the alloy has high durability under the actual conditions of low Cl. In addition, the occurrence of local corrosion such as intergranular corrosion which is often observed in this kind of environment is hardly recognized.

[0043]

[Table 1]

[0044]

[Table 2]

[0045]

[Table 3]

Example 2 In order to investigate the structural stability of the alloy of the present invention during long-term use at high temperature and the tendency to precipitate intermetallic compounds, a test piece having the composition shown in Table 2 was used at 550 ° C.
A heating test for 000 hours was performed to examine a change in hardness. The test was performed according to Example 1 with a length of 14 mm and a width of 1 mm.
The test was performed using a test piece having a thickness of 4 mm and a thickness of 3 mm. The test results are shown in Table 4, which shows that in the composition range of the alloy of the present invention, the change in hardness is small (about HV 170 or less) and the structural stability is excellent. On the other hand, the comparative alloy shows a large change in hardness due to precipitation of an intermetallic compound of about HV250 or more.

In particular, Cr and Si are important for the structural stability. Cr in 14 to 16: 20.1% by weight or less, Si: 4.34% by weight
Above, the increase in hardness due to precipitation of intermetallic compounds is large.
Therefore, the lower limit of Cr is 22% by weight, and the upper limit of Si is 4.
3% by weight.

[0048]

[Table 4]

Example 3 Welding tests were performed on representative test materials used in Example 2. In the test, as shown in FIG. 2, a 20 mm thick plate-shaped test piece was welded by TIG, and MAG welding using a 625 filler was performed to check welding defects and weld cracks on the surface and cross section. The results are as shown in Table 5, and it was confirmed that no harmful defects were found in the weld bead and the HAZ portion, and that the weld had good weldability.

[0050]

[Table 5]

[0051]

The corrosion-resistant and heat-resistant Ni-based alloy for a waste incinerator according to the present invention has excellent high-temperature corrosion resistance in a high-temperature corrosion environment containing a large amount of Cl and S, such as in a combustion gas of a waste incinerator, and has a high temperature resistance. It is a corrosion-resistant and heat-resistant Ni-based alloy with excellent structure stability, weldability and plastic workability when used for a long time. This Ni-based alloy can be supplied at low cost in any form such as a seamless tube, a clad tube, or a powder.

[Brief description of the drawings]

FIG. 1 is an explanatory diagram showing a state of a corrosion test in Example 1.

FIG. 2 is an explanatory diagram showing a state of a welding test in Example 3.

FIG. 3 is a diagram showing the relationship between the Cr content and the corrosion loss of a 4Si-10Fe-Ni-based alloy.

FIG. 4 is a diagram showing the relationship between the Fe content and the corrosion loss of a 20Cr-4Si-Ni-based alloy.

FIG. 5 is a graph showing the relationship between the Si content of a 20Cr—Ni alloy and the weight loss due to corrosion.

FIG. 6 is a graph showing the relationship between the Mo content of a 20Cr-4Si-Ni alloy and the weight loss due to corrosion.

──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Shizuo Yasuda 12 Nishikicho, Naka-ku, Yokohama-shi, Kanagawa Prefecture Mitsubishi Heavy Industries, Ltd.Yokohama Works (72) Inventor Yuji Nakagawa 12 Nishikicho, Naka-ku, Yokohama-shi, Kanagawa Prefecture Mitsubishi Heavy Industries (56) References JP-A-3-100134 (JP, A) JP-A-5-320795 (JP, A) JP-A-7-242971 (JP, A) JP-A-7-216483 (JP, A) JP-A-5-148587 (JP, A) JP-B-1-52465 (JP, B2) (58) Fields investigated (Int. Cl. ⁷ , DB name) C22C 19/05 F28F 21 / 08

Claims (4)

(57) [Claims] (1) The composition of a component is expressed by weight% as C: 0.01 to 0.1%.
3%, Si: 2 to 4.3%, P: 0.03% or less, S:
0.03% or less, Cr: 22 to 31%, Fe: 8 to 30
%, Mn: 0.1 to 3%, Nb and / or Ta: 0.1
１1%, Ti: 0.03 to 0.6%, Al: 0.03 to
0.6%, B: 0.001 to 0.01%, inevitable impurities and the balance being Ni. <br/> A corrosion-resistant and heat-resistant Ni-based alloy for a waste incinerator . 2. The corrosion-resistant and heat-resistant Ni-based alloy according to claim 1,
one or more elements selected from the group consisting of o, W and Co, by weight% N: 0.05-0.5%, Mo: 0.3-
A refuse incinerator characterized by being added in a range of 5%, W: 0.5-3%, and Co: 0.5-3%.
Use corrosion resistant Ni-based alloy. 3. The corrosion-resistant and heat-resistant Ni-base alloy according to claim 1, wherein at least one element selected from the group consisting of a rare earth metal, an alkaline earth metal and Zr is added in an amount of 0.
1% or less, alkaline earth metal: 0.1% or less, Zr:
A corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator characterized by being added in an amount not exceeding 0.2%. 4. A Si content ratio of Si: 3.09 to 4.0.
4. The method according to claim 1, wherein the amount is 3%.
The corrosion-resistant and heat-resistant Ni-based alloy for a refuse incinerator according to the above item.