JP3250042B2 - Wastewater treatment equipment - Google Patents

Wastewater treatment equipment

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Publication number
JP3250042B2
JP3250042B2 JP8245692A JP8245692A JP3250042B2 JP 3250042 B2 JP3250042 B2 JP 3250042B2 JP 8245692 A JP8245692 A JP 8245692A JP 8245692 A JP8245692 A JP 8245692A JP 3250042 B2 JP3250042 B2 JP 3250042B2
Authority
JP
Japan
Prior art keywords
microorganism
treatment
adhered particles
biofilm
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP8245692A
Other languages
Japanese (ja)
Other versions
JPH05285489A (en
Inventor
千明 丹羽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimizu Corp
Original Assignee
Shimizu Corp
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Filing date
Publication date
Application filed by Shimizu Corp filed Critical Shimizu Corp
Priority to JP8245692A priority Critical patent/JP3250042B2/en
Publication of JPH05285489A publication Critical patent/JPH05285489A/en
Application granted granted Critical
Publication of JP3250042B2 publication Critical patent/JP3250042B2/en
Anticipated expiration legal-status Critical
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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Biological Treatment Of Waste Water (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、有機性廃水を好気性微
生物によって浄化処理するための流動床式の廃水処理装
置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fluidized bed type wastewater treatment apparatus for purifying organic wastewater with aerobic microorganisms.

【0002】[0002]

【従来の技術】従来、有機性廃水の処理装置としては、
微生物付着粒子が散在せしめられた処理液を曝気するこ
とにより循環流動化させ処理液中の有機物を減少させ
る、いわゆる流動床式の処理装置が多用されている。図
6は、このような廃水処理装置の一例を示すもので、図
中符号1は、廃水処理装置である。この廃水処理装置1
は、処理槽2と、処理槽2内の中央に立設されたドラフ
トチューブ3と、処理槽2の上部内壁に形成された越流
部(取出部)4と、処理槽2内の上部に設置された固液
分離円筒5と、散気装置6と、処理対象となす廃液を処
理槽2に導入する導入管(流入部)7とからなるもので
ある。処理槽2は、処理液Aと微生物付着粒子とを保有
するもので、底部が逆錐状の容器である。ドラフトチュ
ーブ3は、処理槽2内の処理液Aと微生物付着粒子を効
率よく循環させるためのもので、処理槽2内の中央に縦
方向に設置された略筒状体で、その下端が処理槽2の底
部より上方に位置し、上端が水面より下方に位置するも
のある。越流部4は、処理槽2内を流動し浄化された処
理液Aが越流するもので、処理槽2上端近くの内壁に形
成されたものである。固液分離円筒5は、処理液A中の
微生物付着粒子をその内側に留めて越流部4側へ移動し
ないようにするもので、円筒状のものである。散気装置
6は、処理槽2の下部中央から空気を放ち処理液Aの溶
存酸素を増加させるものである。導入管7は、処理液A
を処理槽2に導入するものである。処理液Aは、有機性
廃水で、好気性微生物にとっての栄養であるC、H、N
などが酸化分解され減少するものである。微生物付着粒
子は、珪藻土等からなる担体と、担体周囲の生物膜とか
らなるものである。
2. Description of the Related Art Conventionally, organic wastewater treatment apparatuses include:
BACKGROUND ART A so-called fluidized bed type processing apparatus has been widely used, in which a processing liquid in which microorganism-adhered particles are scattered is circulated and fluidized by aeration to reduce organic substances in the processing liquid. FIG. 6 shows an example of such a wastewater treatment apparatus, and reference numeral 1 in the figure denotes a wastewater treatment apparatus. This wastewater treatment device 1
The processing tank 2, a draft tube 3 erected in the center of the processing tank 2, an overflow part (extraction part) 4 formed on the upper inner wall of the processing tank 2, and an upper part of the processing tank 2. It comprises an installed solid-liquid separation cylinder 5, a diffuser 6, and an introduction pipe (inflow section) 7 for introducing waste liquid to be treated into the treatment tank 2. The processing tank 2 holds the processing liquid A and the microorganism-adhered particles, and is a container having an inverted pyramid bottom. The draft tube 3 is used for efficiently circulating the processing solution A and the microorganism-adhered particles in the processing tank 2, and is a substantially cylindrical body vertically installed at the center of the processing tank 2, and the lower end thereof is used for processing. Some are located above the bottom of the tank 2 and the top is below the water surface. The overflow portion 4 is a portion in which the processing liquid A that has flowed and purified in the processing tank 2 overflows, and is formed on an inner wall near the upper end of the processing tank 2. The solid-liquid separation cylinder 5 is a cylindrical one that keeps the microorganism-adhered particles in the treatment liquid A from moving to the overflow section 4 side by keeping it inside. The air diffuser 6 releases air from the lower center of the processing tank 2 to increase the dissolved oxygen of the processing liquid A. The introduction pipe 7 is provided with the processing solution A
Is introduced into the processing tank 2. Treatment solution A is an organic wastewater, which is a nutrient for aerobic microorganisms C, H, N
Are oxidatively decomposed and reduced. The microorganism-adhered particles are composed of a carrier made of diatomaceous earth or the like and a biofilm around the carrier.

【0003】このような構成の廃水処理装置1は、処理
槽2下部中央の散気装置6が放つ空気により、処理液A
と微生物付着粒子が、ドラフトチューブ3内を上昇しド
ラフトチューブ3外を下降して処理槽2内を循環する。
そして、処理液Aが処理槽2内を循環するうちに、主に
微生物付着粒子の生物膜によって浄化され、浄化された
処理液Aが、越流部4を乗り越え流出する。
In the wastewater treatment apparatus 1 having such a structure, the treatment liquid A is discharged by the air emitted from the air diffuser 6 in the lower center of the treatment tank 2.
The microorganism-adhered particles rise in the draft tube 3, descend outside the draft tube 3, and circulate in the treatment tank 2.
Then, while the treatment liquid A circulates in the treatment tank 2, the treatment liquid A is mainly purified by the biofilm of the microorganism-attached particles, and the purified treatment liquid A flows over the overflow section 4 and flows out.

【0004】このような廃水処理装置1は、処理槽2中
の担体の表面積が、処理槽の一定容積当りで比較する
と、例えば接触曝気法の廃水処理装置に用いられる接触
材表面積に比べ、20倍以上と極めて大きく、一定容積
当りの生物膜面積が広いものである。ところで、生物膜
による浄化作用は、図7から解かるように溶存酸素濃度
(DO)が2ppm以下の場合、生物膜内のDO拡散が
律速になっている。そのため、高効率の浄化作用のため
には、生物膜と処理液との境膜抵抗を減少させ、生物膜
と処理液とを十分接触させる必要がある。上記のような
流動床式の廃水処理装置1においては、微生物付着粒子
の表面に酸素および有機物が効率よく接し、浄化作用が
効率よく行われる。これらの理由により、上記の廃水処
理装置1は、表1に示すように他の手法(標準活性汚泥
法、長時間曝気法、接触曝気法)の廃水処理装置に比
べ、BOD容積負荷で3〜10倍高効率で廃水を処理す
ることができ、処理槽を小型にできる。
In such a wastewater treatment apparatus 1, when the surface area of the carrier in the treatment tank 2 is compared with a certain volume of the treatment tank, for example, the surface area of the contact material used in the wastewater treatment apparatus of the contact aeration method is 20%. It is extremely large, twice or more, and has a large biofilm area per fixed volume. Incidentally, as shown in FIG. 7, when the dissolved oxygen concentration (DO) is 2 ppm or less, diffusion of DO in the biofilm is rate-limiting. Therefore, for high-efficiency purification, it is necessary to reduce the film resistance between the biofilm and the treatment liquid, and to bring the biofilm and the treatment liquid into sufficient contact. In the fluidized-bed wastewater treatment apparatus 1 as described above, oxygen and organic substances come into contact with the surface of the microorganism-attached particles efficiently, and the purification action is performed efficiently. For these reasons, as shown in Table 1, the above wastewater treatment apparatus 1 has a BOD volume load of 3 to 3 times as compared with wastewater treatment apparatuses of other methods (standard activated sludge method, long-time aeration method, contact aeration method). Wastewater can be treated 10 times more efficiently, and the treatment tank can be made smaller.

【表1】 [Table 1]

【0005】また、上記のような流動床式の廃水処理装
置1においては、廃水の負荷が一定範囲内にあり、かつ
操作が適切に行われているとき、生物が増殖して生物膜
の厚みが増加するのと、水流の剪断力による剥離などで
生物膜の厚みが減少するのとが同量になり、浄化効率の
よい膜厚を持続させることができるものである。また、
他の手法の廃水処理装置が返送汚泥を要することに対
し、上述の廃水処理装置1は、返送汚泥を必要としない
ため、汚泥のバルキングが起きず、また汚泥の沈降性に
注意を払う必要がなく、操作が容易である。
In the fluidized-bed type wastewater treatment apparatus 1 as described above, when the load of the wastewater is within a certain range and the operation is performed properly, organisms grow and the thickness of the biofilm increases. Is increased, and the amount of decrease in the thickness of the biofilm due to separation due to the shear force of the water flow is the same, and a film thickness with good purification efficiency can be maintained. Also,
On the other hand, the wastewater treatment apparatus 1 of the other method requires return sludge, whereas the wastewater treatment apparatus 1 described above does not require return sludge, so that bulking of sludge does not occur and attention must be paid to the sedimentation of sludge. Operation is easy.

【0006】[0006]

【発明が解決しようとする課題】しかしながら、このよ
うな構成の廃水処理装置1は、廃水の量の変化や有機物
濃度のばらつきならびに汚泥転換率の高い有機物の増
加、曝気の操作不良などにより、微生物付着粒子が肥大
化して流出してしまう問題がある。例えば、生活排水の
処理において、流動性を考慮して、担体のかさ比重を2
以下、担体粒子径を0.4mm以下、BOD容積負荷を2K
g/m3/日とすると、1年間に40〜50%の微生物付
着粒子が流出してしまう。微生物付着粒子が流出し生物
膜面積が減少すると、浄化能力が低下する。浄化能力が
低下しないように担体を補充していくと、ランニングコ
ストが高くなる。また、好気性処理において、生物膜内
への酸素の拡散速度の関係から、有効に働くのは生物膜
の表面から100〜150μmである。したがって、肥
大化すると有効に働かない部分が増加する。また、微生
物膜厚が増加すると図8から解かるように微生物付着粒
子の沈降速度が減少し、固液分離円筒5による微生物付
着粒子の分離が難しくなる。ところで、このような好気
性微生物を用いた廃水処理装置1においては、微生物付
着粒子の生物膜の一部が剥離した浮遊汚泥が、処理槽2
から越流する処理液Aに伴われて次の沈殿槽へと送ら
れ、沈殿槽から余剰汚泥として引き抜き処理される。上
記の問題を解決するために、処理槽2から流出した微生
物付着粒子を沈殿槽から回収することが考えられるが、
このようにした場合には、微生物付着粒子と大量の汚泥
とが混合しているため、回収作業に莫大な費用がかか
り、現実的ではない。一方、有機性廃水の浄化作用に係
わる好気性微生物は、細菌などの他に原生動物も重要な
役割を担っている。上記の問題を解決するために、処理
槽2内の全ての微生物付着粒子を一度に水エジェクタな
どにより処理し、微生物付着粒子の生物膜の一部を剥離
し、例えば処理槽2内の微生物濃度をMLVSSとして
6000mg/lから4000mg/lへ低下させるこ
とが考えられる。しかしながら、このようすると、微生
物担体の生物膜表層に固着棲息する原生動物類が全て剥
離してしまい、極めて好ましくない。
However, the wastewater treatment apparatus 1 having such a configuration has a problem in that the microorganisms are changed due to a change in the amount of wastewater, a variation in the concentration of organic substances, an increase in organic substances having a high sludge conversion rate, and a poor aeration operation. There is a problem that the attached particles are enlarged and flow out. For example, in the treatment of domestic wastewater, the bulk specific gravity of the carrier is set to 2 in consideration of fluidity.
Hereinafter, the carrier particle diameter is 0.4 mm or less, and the BOD volume load is 2K.
At g / m 3 / day, 40 to 50% of microorganism-adhered particles flow out in one year. As the biofilm area decreases due to the outflow of the microorganism-adhered particles, the purification ability decreases. If the carrier is replenished so that the purification ability does not decrease, the running cost increases. Further, in the aerobic treatment, the effective function is 100 to 150 μm from the surface of the biofilm due to the rate of diffusion of oxygen into the biofilm. Therefore, when it enlarges, the part which does not work effectively increases. In addition, as the thickness of the microorganism increases, the sedimentation speed of the microorganism-adhered particles decreases as shown in FIG. 8, and it becomes difficult to separate the microorganism-adhered particles by the solid-liquid separation cylinder 5. By the way, in the wastewater treatment apparatus 1 using such aerobic microorganisms, the suspended sludge from which a part of the biofilm of the microorganism-attached particles has separated is treated in the treatment tank 2.
It is sent to the next sedimentation tank along with the processing liquid A overflowing from the tank, and is extracted from the sedimentation tank as excess sludge. In order to solve the above problem, it is conceivable to collect the microorganism-adhered particles flowing out of the treatment tank 2 from the sedimentation tank.
In such a case, since the microorganism-adhered particles and a large amount of sludge are mixed, an enormous cost is required for the recovery operation, which is not practical. On the other hand, protozoa as well as bacteria play an important role in aerobic microorganisms involved in the purification of organic wastewater. In order to solve the above problem, all the microorganism-adhered particles in the treatment tank 2 are treated at once by a water ejector or the like, and a part of the biofilm of the microorganism-adhered particles is peeled off. Is considered to be reduced from 6000 mg / l to 4000 mg / l as MLVSS. However, in this case, all the protozoa fixed and living on the surface of the biofilm of the microorganism carrier are detached, which is extremely undesirable.

【0007】本発明は、前記事情に鑑みてなされたもの
で、その目的とするところは、微生物付着粒子が肥大化
して流出するのを抑さえることのできる流動床式の廃水
処理装置を提供することにある。
The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a fluidized bed type wastewater treatment apparatus capable of suppressing the growth and outflow of microorganism-adhered particles. It is in.

【0008】[0008]

【課題を解決するための手段】前記課題を解決するため
に本発明の廃水処理装置は、処理対象となる廃水の流入
部と処理液の取出部とを有し、その内部に微生物付着粒
子が散在せしめられた処理液を保有するよう構成された
処理槽と、この処理槽内を曝気する散気装置と、該処理
槽内の微生物付着粒子および処理液を導入して微生物付
着粒子の生物膜厚を判定し、生物膜厚が一定厚未満の微
生物付着粒子および処理液を判定粒子戻し部を通して前
記処理槽に戻す生物膜厚判定装置と、この生物膜厚判定
装置で判定された生物膜厚が一定厚以上の微生物付着粒
子および処理液を導入して該微生物付着粒子の生物膜を
剥離する生物膜剥離装置と、この生物膜剥離装置により
処理され生物膜が剥離された微生物付着粒子および処理
液を前記処理槽に戻す回収手段とを具備してなるもので
ある。
In order to solve the above-mentioned problems, a wastewater treatment apparatus according to the present invention has an inflow portion of wastewater to be treated and a takeout portion of a treatment liquid, in which microorganism-adhered particles are contained. A treatment tank configured to hold the scattered treatment liquid, an air diffuser for aerating the inside of the treatment tank, and a biofilm of the microorganism-attached particles by introducing the microorganism-adhered particles and the treatment liquid in the treatment tank. A biological film thickness determination device that determines the thickness and returns the microorganism-adhered particles and the processing liquid having a biological film thickness less than a certain thickness to the processing tank through the determination particle return unit, and a biological film thickness determined by the biological film thickness determination device. A biofilm peeling device that removes a biofilm of the microorganism-adhered particles by introducing a microorganism-adhered particle and a treatment liquid having a certain thickness or more, Liquid into the processing tank Those formed by and a to recovery means.

【0009】[0009]

【作用】本発明の廃水処理装置によれば、処理槽内の微
生物付着粒子および処理液が生物膜判定装置に導入され
生物膜厚が判定される。そして、生物膜厚が一定厚以上
の微生物付着粒子が生物膜剥離装置に導入され剥離処理
され、剥離処理された微生物付着粒子が処理槽に戻され
る。したがって、微生物付着粒子が処理槽内から失われ
るのを抑さえることができる。
According to the wastewater treatment apparatus of the present invention, the microorganism-adhered particles in the treatment tank and the treatment liquid are introduced into the biofilm judging device, and the thickness of the biofilm is judged. Then, the microorganism-adhered particles having a biological film thickness of a certain thickness or more are introduced into the biofilm peeling device, subjected to the peeling treatment, and the microorganism-adhered particles subjected to the peeling treatment are returned to the treatment tank. Therefore, loss of the microorganism-adhered particles from within the treatment tank can be suppressed.

【0010】[0010]

【実施例】以下、本発明の廃水処理装置について、実施
例によって詳しく説明する。図1ないし図3は本発明の
廃水処理装置の実施例を示す図であり、この図において
符号11は廃水処理装置である。この廃水処理装置11
は、処理液Aと微生物付着粒子を保有する処理槽12
と、処理槽12内の中央に立設されたドラフトチューブ
13と、処理槽12の上部内壁に形成された越流部(取
出部)14と、処理槽12内の上部に設置された固液分
離円筒15と、散気装置16と、処理対象となす廃液を
処理槽12に導入する導入管(流入部)17と、生物膜
厚判定装置18((回収手段)以下、判定装置と略称す
る)と、生物膜剥離装置19(以下、剥離装置と略称す
る)と、回収手段20を構成する貯水容器20a,送水
管20b,送水管20c,ポンプ20dとからなるもので
ある。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The wastewater treatment apparatus of the present invention will be described below in detail with reference to embodiments. FIGS. 1 to 3 show an embodiment of a wastewater treatment apparatus according to the present invention. In this figure, reference numeral 11 denotes a wastewater treatment apparatus. This wastewater treatment device 11
Is a processing tank 12 holding the processing liquid A and the microorganism-adhered particles.
A draft tube 13 erected in the center of the processing tank 12, an overflow section (extraction section) 14 formed on an upper inner wall of the processing tank 12, and a solid-liquid installed at an upper part of the processing tank 12. A separation cylinder 15, an aeration device 16, an introduction pipe (inflow portion) 17 for introducing waste liquid to be treated into the treatment tank 12, and a biological film thickness determination device 18 ((recovery means)). ), A biofilm stripping device 19 (hereinafter, abbreviated as a stripping device), and a water storage container 20a, a water pipe 20b, a water pipe 20c, and a pump 20d which constitute the recovery means 20.

【0011】この廃水処理装置11は、処理槽12、ド
ラフトチューブ13、越流部14、固液分離円筒15、
散気装置16、および導入管17が、従来の廃水処理装
置1と同様のものである。また、従来例と同様に処理液
Aが、好気性微生物にとっての栄養であるC、H、Nな
どが酸化分解され減少するものであり、また微生物付着
粒子B…が、珪藻土等からなる担体と、担体周囲の生物
膜とからなるものである。
The wastewater treatment apparatus 11 includes a treatment tank 12, a draft tube 13, an overflow section 14, a solid-liquid separation cylinder 15,
The air diffuser 16 and the introduction pipe 17 are the same as those of the conventional wastewater treatment apparatus 1. Further, similarly to the conventional example, the treatment liquid A is one in which C, H, N, etc., which are nutrients for aerobic microorganisms, are oxidized and decomposed and reduced. , And a biofilm around the carrier.

【0012】判定装置18は、処理槽12の上方に設置
されたものであり、図2に示すように判定装置本体21
と、集液部22と、判定粒子戻し部23と、導入部24
と、再導入部25と、多孔板26とからなるものであ
る。この判定装置18には、ポンプ24bを動力源と
し、導入部24を含む送水管24aを通じて処理槽12
内の処理液の一部が導入されるようになっている。判定
装置本体21は、沈降速度の速い微生物付着粒子B…の
みを下部に集めるもので、上部の胴体部21aと、下部
の粒子集め部21bとからなるものである。胴体部21a
は、円筒形であり、内部に微生物付着粒子B…および処
理液Aが満たされ、上昇水流を有し、沈降速度の速い微
生物付着粒子のみを降下させるものである。粒子集め部
21bは、その下部に沈降速度の速い微生物付着粒子を
集めるもので、漏斗状のものである。集液部22は、図
2、3に示すように判定装置本体21から越流した微生
物付着粒子B…と処理液Aを集め剥離装置19へと送り
出すもので、傾斜した底を有する有底円筒体で、傾斜し
た底の下端部から下方に送り部22aが形成されている
ものである。判定粒子戻し部23は、処理槽12の上方
において固液分離円筒15内に臨むように位置してお
り、図2に示すように判定装置本体21の下端部に取り
付けられたバルブ23aとバルブ23aの下方に取り付け
られた粒子戻し管23bとからなるものである。このバ
ルブ23aは、粒子集め部21bの下部に集められた微生
物付着粒子B…を処理槽12に戻す際に開くものであ
る。導入部24は、処理槽12内からポンプ24bで揚
水した微生物付着粒子B…および処理液Aを判定装置本
体21に導入するもので、判定装置本体21内の端部の
形状が微生物付着粒子B…および処理液Aをほぼ水平方
向放射状に放出する構造となっているものである。再導
入部25は、剥離装置19で処理された微生物付着粒子
B…および処理液Aを判定装置本体21に導入する送水
管20cの一部であり、その端部が粒子集め部21bの上
部に配置されており、上方の胴体部21aに向けて微生
物付着粒子B…および処理液Aを放出する孔が多数設け
られたものである。多孔板26は、剥離装置19で処理
された微生物付着粒子B…および処理液Aが導入される
ことによる胴体部21a内の偏流を防止するもので、判
定装置本体21内の再導入部25の上方に取り付けられ
たものである。
The judging device 18 is installed above the processing tank 12, and as shown in FIG.
, A liquid collecting unit 22, a determination particle returning unit 23, and an introducing unit 24.
And a re-introduction section 25 and a perforated plate 26. The determination device 18 uses a pump 24b as a power source, and a processing tank 12 through a water supply pipe 24a including an introduction portion 24.
A part of the processing solution is introduced therein. The determination device main body 21 collects only the microorganism-attached particles B having a high sedimentation speed at the lower portion, and includes an upper body portion 21a and a lower particle collecting portion 21b. Body part 21a
Is a cylindrical shape, is filled with the microorganism-attached particles B ... and the treatment liquid A, has a rising water flow, and drops only the microorganism-adhered particles having a high sedimentation speed. The particle collecting portion 21b collects microorganism-adhered particles having a high sedimentation speed at a lower portion thereof, and has a funnel shape. The liquid collecting part 22 collects the microorganism-attached particles B flowing over from the judging device main body 21 and the processing liquid A and sends out the processing liquid A to the peeling device 19 as shown in FIGS. The body has a feed portion 22a formed downward from the lower end of the inclined bottom. The determination particle return portion 23 is located above the processing tank 12 so as to face the solid-liquid separation cylinder 15, and as shown in FIG. 2, a valve 23 a and a valve 23 a attached to a lower end portion of the determination device main body 21. And a particle return pipe 23b attached below the bottom of the container. The valve 23a is opened when returning the microorganism-adhered particles B collected in the lower part of the particle collecting section 21b to the processing tank 12. The introduction unit 24 introduces the microorganism-attached particles B ... pumped from the treatment tank 12 by the pump 24b and the treatment liquid A into the determination device main body 21. ... and the processing liquid A is emitted in a substantially horizontal radial direction. The re-introduction section 25 is a part of a water pipe 20c for introducing the microorganism-attached particles B and the treatment liquid A treated by the peeling apparatus 19 into the determination apparatus main body 21, and the end thereof is located above the particle collection section 21b. It is provided with a large number of holes for releasing the microorganism-attached particles B and the treatment liquid A toward the upper body 21a. The perforated plate 26 prevents the drift in the body 21 a due to the introduction of the microorganism-attached particles B and the treatment liquid A that have been treated by the peeling device 19. It is attached above.

【0013】次に、上記の構成からなる廃水処理装置1
1の作用について説明する。処理槽12内の処理液の一
部は、ポンプ24bによって揚水され、送水管24aの導
入部24から判定装置18の判定装置本体21内に導入
される。判定装置18において、導入部24と後述する
再導入部25により導入される処理液Aによって胴体部
21a内に上昇水流が生じる。そして、沈降速度の遅い
微生物付着粒子B…が、胴体部21a上端から越流する
処理液Aとともに集液部22へと移動し、沈降速度の速
い微生物付着粒子B…が、粒子集め部21b下部に集ま
る。そして、粒子集め部21bの微生物付着粒子B…
が、判定粒子戻し部23によって処理槽12に戻され
る。また、図8から解かるように微生物付着粒子は、生
物膜が厚くなるほど、水の抵抗が増えるとともに、生物
膜の比重が担体の比重に比べて小さいことにより粒子全
体の比重が小さくなり、沈降速度が遅くなるものであ
る。このため、沈降速度を判定することは、生物膜厚を
判定することとなる。
Next, the wastewater treatment apparatus 1 having the above configuration
1 will be described. A part of the processing liquid in the processing tank 12 is pumped up by the pump 24b, and is introduced into the determination device main body 21 of the determination device 18 from the introduction portion 24 of the water pipe 24a. In the determination device 18, a rising water flow is generated in the body 21 a by the processing liquid A introduced by the introduction unit 24 and a reintroduction unit 25 described below. Then, the microorganism-attached particles B having a low sedimentation speed move to the liquid collecting portion 22 together with the processing liquid A flowing from the upper end of the body portion 21a, and the microorganism-attached particles B having a fast sedimentation speed are moved to the lower portion of the particle collecting portion 21b. Gather in Then, the microbe-attached particles B in the particle collecting part 21b ...
Is returned to the processing tank 12 by the determination particle return unit 23. In addition, as can be seen from FIG. 8, the microorganism-adhered particles have a greater water resistance as the biofilm is thicker, and the specific gravity of the biofilm is smaller than the specific gravity of the carrier. The speed becomes slow. Therefore, judging the sedimentation velocity means judging the biological film thickness.

【0014】一方、判定装置18の集液部22の微生物
付着粒子B…および処理液Aは、剥離装置19内に導入
されこの装置内で、微生物付着粒子B…の生物膜が剥離
される。この場合、剥離装置19としては、駆動水によ
り内部室が低圧となり混合される水エジェクターや、撹
拌翼が高速で回転する撹拌機等が用いられる。
On the other hand, the microorganism-adhered particles B and the treatment liquid A in the liquid collecting section 22 of the judging device 18 are introduced into a peeling device 19, in which the biofilm of the microorganism-adhered particles B is peeled. In this case, as the peeling device 19, a water ejector in which the internal pressure is reduced by driving water to mix the internal chamber, a stirrer in which the stirring blade rotates at a high speed, and the like are used.

【0015】剥離装置19で処理され生物膜が剥離され
た微生物付着粒子B…および処理液Aは、送水管20b
を通じて貯水容器20a内に導入される。貯水容器20a
内の前記微生物付着粒子B…および処理液Aは、ポンプ
20dにより揚水され、送水管20cの再導入部25を通
じて判定装置18内に導入され、この判定装置18内
で、微生物付着粒子B…の再判定が行われる。
The microorganism-adhered particles B and the treatment liquid A, which have been treated by the detaching device 19 and from which the biofilm has been detached, are supplied to the water pipe 20b.
Through the water storage container 20a. Water storage container 20a
And the treatment liquid A are pumped up by a pump 20d and introduced into the judging device 18 through the re-introduction section 25 of the water pipe 20c, where the microorganism adhering particles B ... Redetermination is performed.

【0016】以上のような廃水処理装置11によれば、
処理槽12内の微生物付着粒子B…および処理液Aを導
入して微生物付着粒子B…の生物膜厚を判定する判定装
置18と、微生物付着粒子B…の生物膜を剥離する剥離
装置19と、この剥離装置19により処理された微生物
付着粒子B…を再び判定装置18に導入する第一の回収
手段20と、生物膜が一定厚以下の微生物付着粒子B…
のみを処理槽12内に戻す粒子戻し部23とを具備して
いるので、沈降速度の遅い微生物付着粒子B…が、判定
装置18から剥離装置19に導入され剥離処理され、処
理槽12に戻されることにより、処理槽12から流出す
ることがない。このため、処理槽12内の生物膜面積の
減少による処理能力の低下がなく、また担体の補給の必
要がないためランニングコストが下がる。また、沈降速
度の遅い微生物付着粒子B…のみを剥離装置19に導入
するので、剥離処理が合理的、経済的であり、かつ処理
槽12内の微生物体系を維持することができる。また、
微生物付着粒子B…の流出を抑さえることができ、かつ
生物膜を一定厚以下に制御することができるので、処理
槽12内の微生物量を効果的に制御することができる。
また、微生物付着粒子B…の沈降速度のばらつきの二要
因のうちの生物膜の厚みを一定厚以下にすることができ
るので、他の一要因である担体の粒径のばらつきの許容
範囲が広がり、担体の調達コストが下がる。また、微生
物付着粒子B…が、生物膜が緻密でなく浄化作用の少な
い部分が減少し、担体に浄化作用の高い生物膜のみが付
着した小さい粒子となり、容積当りの生物膜面積が高い
装置となりうる。また、剥離装置19から再び判定装置
18に導入し、生物膜が一定厚以下の微生物付着粒子B
…のみを処理槽2内に戻すので、判定が厳密になるとと
もに、微生物付着粒子B…が一箇所に集められることに
より操作が容易になる。また、判定装置18の判定粒子
戻し部23が処理槽12の上方に配置されているので、
微生物付着粒子B…を重力により処理槽内に導入するこ
とができ、配管やポンプ内に微生物付着粒子B…が滞る
ことがない。また、微生物付着粒子の判定と剥離操作と
を同時に行い連続運転とすると、操作の手間が大幅に減
少し、運転操作が容易である。
According to the wastewater treatment apparatus 11 as described above,
A judging device 18 for introducing the microbe-attached particles B ... in the treatment tank 12 to determine the biological film thickness of the microbe-adhered particles B by introducing the treatment liquid A; A first collecting means 20 for introducing the microorganism-attached particles B treated by the stripping device 19 back into the judging device 18, and a microorganism-adhered particle B having a biofilm of a certain thickness or less.
Is provided with a particle return portion 23 for returning only the microorganisms B into the processing tank 12, so that the microorganism-attached particles B having a low sedimentation speed are introduced from the determination device 18 into the separation device 19, subjected to the separation processing, and returned to the processing tank 12. As a result, it does not flow out of the processing tank 12. For this reason, there is no reduction in the processing capacity due to the decrease in the biofilm area in the processing tank 12, and the running cost is reduced because there is no need to replenish the carrier. In addition, since only the microorganism-attached particles B having a low sedimentation speed are introduced into the peeling device 19, the peeling treatment is rational and economical, and the microorganism system in the treatment tank 12 can be maintained. Also,
Since the outflow of the microorganism-attached particles B can be suppressed and the biofilm can be controlled to a certain thickness or less, the amount of microorganisms in the treatment tank 12 can be effectively controlled.
In addition, since the thickness of the biofilm, which is one of the two factors of the dispersion of the sedimentation speed of the microorganism-adhered particles B, can be reduced to a certain thickness or less, the allowable range of the dispersion of the particle size of the carrier, which is another factor, is expanded. In addition, carrier procurement costs are reduced. In addition, the microbe-adhered particles B are small particles in which the biofilm is not dense and the purification action is small, and the biofilm has a high purification action attached to the carrier. sell. Further, the microorganism B is re-introduced from the stripping device 19 to the determination device 18 and the biofilm is attached to the microorganism-adhered particles B having a certain thickness or less.
.. Are returned to the processing tank 2, the determination becomes strict, and the operation becomes easy because the microorganism-attached particles B are collected in one place. Further, since the determination particle return unit 23 of the determination device 18 is disposed above the processing tank 12,
The microorganism-adhered particles B can be introduced into the treatment tank by gravity, and the microorganism-adhered particles B do not stay in the piping or the pump. Further, when the determination of the microorganism-adhered particles and the peeling operation are performed simultaneously to perform continuous operation, the operation labor is greatly reduced, and the driving operation is easy.

【0017】図4、5は、本発明の廃水処理装置の判定
装置の別の例を示す図である。図4において、図中符号
30は、判定装置である。判定装置30は、判定装置本
体31と、集液部32と、判定粒子戻し部33と、導入
部34と、再導入部35と、多孔板36と、サイドカッ
ト管37,37とからなるもので、前記判定装置18と
異なるところは、サイドカット管37,37が取り付け
られていることである。
FIGS. 4 and 5 are diagrams showing another example of the determination apparatus of the wastewater treatment apparatus according to the present invention. In FIG. 4, reference numeral 30 denotes a determination device. The determination device 30 includes a determination device main body 31, a liquid collecting unit 32, a determination particle return unit 33, an introduction unit 34, a reintroduction unit 35, a perforated plate 36, and side cut tubes 37, 37. The difference from the determination device 18 is that side cut tubes 37, 37 are attached.

【0018】サイドカット管37,37は、判定装置本
体31内の微生物付着粒子B…および処理液Aを抜き取
り処理槽12へと送り、胴体部31a内の流速を上部へ
行くほど遅くするもので、それぞれの端部が胴体部31
aのほぼ中央部に上下方向に間隔をおいて配置され、抜
き取り量を調節するためのバルブが取り付けられたもの
である。なお、サイドカット管37は、その本数が2本
に限られるものではなく、また胴体部31a内の流速を
センサによって感知して、サイドカット管による抜き取
り量を自動調節するバルブが取り付けられたものとして
もよい。
The side cut pipes 37, 37 extract the microorganism-attached particles B... And the processing solution A in the judging device main body 31 and send them to the processing tank 12, so that the flow velocity in the body 31a is made lower as going upward. , Each end is a body part 31
A valve is arranged at a substantially central portion of a at a distance in the vertical direction, and a valve for adjusting a withdrawal amount is attached. The number of the side cut pipes 37 is not limited to two, and a valve provided with a sensor that senses the flow velocity in the body 31a by a sensor and automatically adjusts the extraction amount by the side cut pipes. It may be.

【0019】このような構成の判定装置30は、胴体部
31a内に流速の分布があり、沈降速度の遅い微生物付
着粒子B…のみが、胴体部31a上端から越流する処理
液Aとともに集液部32へと移動し、沈降速度の速い微
生物付着粒子B…が、粒子集め部31b下部に集まるも
のである。
In the determination device 30 having such a configuration, only the microorganism-attached particles B having a low flow velocity in the body 31a and having a low sedimentation velocity are collected together with the processing liquid A flowing over the upper end of the body 31a. The microorganism-attached particles B having a high sedimentation speed move to the portion 32 and collect at the lower portion of the particle collecting portion 31b.

【0020】図5の判定装置40は、判定装置本体41
と、集液部42と、判定粒子戻し部43と、導入部44
とからなるものである。判定装置本体41は、内部に微
生物付着粒子B…および処理液Aが満たされ、沈降速度
の速い微生物付着粒子B…をその下部に集めるもので、
下端から上端につれて太く形成された略円錐形のもので
ある。集液部42は、前記判定装置18の集液部22と
同様の構造で、判定装置本体41から越流した微生物付
着粒子B…と処理液Aが集められ剥離装置19へと送り
出すものである。判定粒子戻し部43は、前記判定装置
18の判定粒子戻し部23と同様の構造で、判定装置本
体41の下端部に取り付けられたバルブ43aとバルブ
43aの下方に取り付けられた粒子戻し管43bとからな
るものである。導入部44は、処理槽2内からポンプで
揚水した微生物付着粒子B…および処理液Aを判定装置
本体41に導入するもので、その端部が判定装置本体4
1内の下部に位置しており、端部の形状が微生物付着粒
子B…および処理液Aをほぼ水平方向放射状に放出する
構造となっているものである。
The judging device 40 shown in FIG.
, A liquid collecting section 42, a determination particle returning section 43, and an introducing section 44.
It consists of: The judging device main body 41 is filled with the microorganism-attached particles B and the treatment liquid A therein, and collects the microorganism-attached particles B having a high sedimentation speed at a lower portion thereof.
It is a substantially conical shape that is formed thicker from the lower end to the upper end. The liquid collecting part 42 has the same structure as the liquid collecting part 22 of the judging device 18, and collects the microorganism-attached particles B flowing from the judging device main body 41 and the treatment liquid A and sends them to the peeling device 19. . The determination particle return unit 43 has the same structure as the determination particle return unit 23 of the determination device 18, and includes a valve 43 a attached to the lower end of the determination device main body 41 and a particle return tube 43 b attached below the valve 43 a. It consists of The introduction unit 44 introduces the microorganism-attached particles B and the processing liquid A pumped from the processing tank 2 by the pump into the determination device main body 41, and has an end portion thereof.
1 and has a structure in which the shape of the end is such that the microorganism-attached particles B and the treatment liquid A are emitted in a substantially horizontal radial direction.

【0021】このような構成の判定装置40は、判定装
置本体41内の上昇水流が上部に行くほど遅いものであ
る。そのため、沈降速度の遅い微生物付着粒子B…のみ
が、判定装置本体41上端から越流する処理液Aととも
に集液部42へと移動し、沈降速度の速い微生物付着粒
子B…が、判定装置本体41下部に集まるものである。
In the judging device 40 having such a configuration, the upward water flow in the judging device main body 41 is slower as going upward. Therefore, only the microorganism-attached particles B having a low sedimentation speed move to the collecting section 42 together with the processing liquid A flowing from the upper end of the determination device main body 41, and the microorganism-adhered particles B having a fast sedimentation speed are removed from the determination device main body. 41 gather at the bottom.

【0022】[0022]

【発明の効果】本発明の請求項1記載の廃水処理装置に
よれば、処理槽内の微生物付着粒子および処理液を導入
して微生物付着粒子の生物膜厚を判定し、生物膜厚が一
定厚未満の微生物付着粒子を前記処理槽に戻す生物膜厚
判定装置と、この生物膜厚判定装置で判定された生物膜
厚が一定厚以上の微生物付着粒子および処理液を導入し
て該微生物付着粒子の生物膜を剥離する生物膜剥離装置
と、この生物膜剥離装置により処理された微生物付着粒
子および処理液を前記処理槽に戻す回収手段とを具備し
ているので、微生物付着粒子が判定装置で判定されて剥
離装置に導入され、剥離処理され、処理槽に戻されるこ
とにより、処理槽から流出することを抑さえることがで
きる。このため、生物膜面積の減少による処理能力の低
下がなく、また担体の補給の必要がなないためランニン
グコストが下がる。また、微生物付着粒子の流出を抑さ
えることができ、かつ生物膜の厚みを制御することがで
きるので、処理槽内の微生物量を効果的に制御すること
ができる。また、生物膜の厚みを一定厚以下にすること
ができるので、微生物付着粒子流出の他の一要因である
担体の粒径のばらつきの許容範囲が広がり、担体の調達
コストが下がる。また、剥離処理後の微生物付着粒子
が、廃水の浄化作用にとって良好な生物体系が維持され
ている処理槽内に戻されることにより、良好な微生物体
系を取り戻すことができる。そのため、処理槽内の微生
物体系を維持することができる。また、担体に浄化作用
の高い生物膜のみが付着した小さい粒子とすることがで
き、容積当りの生物膜面積が高い装置となりうる。
According to the wastewater treatment apparatus of the first aspect of the present invention, the biological film thickness of the microorganism-adhered particles is determined by introducing the microorganism-adhered particles and the treatment liquid in the treatment tank, and the biological film thickness is kept constant. A biological film thickness judging device for returning the microorganism-adhered particles having a thickness smaller than the thickness to the treatment tank; A biofilm stripping device for stripping the biofilm of particles, and a collecting means for returning the microorganism-adhered particles and the treatment liquid treated by the biofilm stripping device to the treatment tank; By being introduced into the stripping device, being stripped, and returned to the processing tank, it is possible to suppress the outflow from the processing tank. As a result, there is no decrease in the processing capacity due to a decrease in the biofilm area, and there is no need to replenish the carrier, so that the running cost is reduced. Further, the outflow of the microorganism-adhered particles can be suppressed, and the thickness of the biofilm can be controlled, so that the amount of microorganisms in the treatment tank can be effectively controlled. In addition, since the thickness of the biofilm can be reduced to a certain thickness or less, the allowable range of the variation in the particle size of the carrier, which is another factor of the outflow of the microorganism-adhered particles, is widened, and the cost of procuring the carrier is reduced. In addition, the microorganism-adhered particles after the stripping treatment are returned to the treatment tank in which a biological system favorable for the purification action of the wastewater is maintained, whereby a favorable microorganism system can be recovered. Therefore, the microorganism system in the processing tank can be maintained. In addition, it is possible to make small particles in which only a biofilm having a high purification action adheres to the carrier, and the device can have a high biofilm area per volume.

【0023】また、剥離装置から再び判定装置に導入
し、生物膜が一定厚以下の微生物付着粒子のみを処理槽
内に戻すので、判定が厳密になるとともに、微生物付着
粒子が一箇所に集められることにより操作が容易であ
る。
[0023] Further , since the biofilm is introduced again into the judging device from the peeling device and only the microorganism-adhered particles having a biofilm of a certain thickness or less are returned to the treatment tank, the judgment becomes strict and the microorganism-adhered particles are collected at one place. This facilitates operation.

【0024】また、請求項2記載の廃水処理装置にあっ
ては、判定装置の判定粒子戻し部が処理槽の上方に配置
されているので、微生物付着粒子を重力により処理槽内
に導入することができ、判定装置の下部に集められた微
生物付着粒子を処理槽に戻す作業が容易である。
In the wastewater treatment apparatus according to the second aspect of the present invention, since the determination particle return portion of the determination device is disposed above the treatment tank, the microorganism-adhered particles are introduced into the treatment tank by gravity. It is easy to return the microorganism-adhered particles collected in the lower part of the determination device to the treatment tank.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の廃水処理装置の第一実施例を示す概略
図である。
FIG. 1 is a schematic diagram showing a first embodiment of a wastewater treatment apparatus of the present invention.

【図2】図1に示した廃水処理装置の判定装置の説明図
である。
FIG. 2 is an explanatory diagram of a determination device of the wastewater treatment device shown in FIG.

【図3】図2に示した判定装置の平面図である。FIG. 3 is a plan view of the determination device shown in FIG.

【図4】判定装置の第二実施例を示す概略図である。FIG. 4 is a schematic diagram showing a second embodiment of the determination device.

【図5】判定装置の第三実施例を示す概略図である。FIG. 5 is a schematic diagram showing a third embodiment of the determination device.

【図6】従来の廃水処理装置の一例を示す概略図であ
る。
FIG. 6 is a schematic diagram showing an example of a conventional wastewater treatment device.

【図7】生物膜による浄化速度を示す図である。FIG. 7 is a diagram showing a purification speed by a biofilm.

【図8】微生物付着粒子の沈降速度を示す図である。FIG. 8 is a graph showing the sedimentation speed of microorganism-adhered particles.

【符号の説明】[Explanation of symbols]

11 廃水装置 12 処理槽 13 ドラフトチューブ 14 越流部(取出部) 16 散気装置 17 導入管(流入部) 18 生物膜厚判定装置(第二の回収手段) 23 判定粒子戻し部 19 生物膜剥離装置 20 第一の回収手段 A 処理液 B 微生物付着粒子 DESCRIPTION OF SYMBOLS 11 Wastewater apparatus 12 Treatment tank 13 Draft tube 14 Overflow part (extraction part) 16 Air diffuser 17 Inlet pipe (inflow part) 18 Biofilm thickness determination device (second recovery means) 23 Determination particle return part 19 Biofilm peeling Apparatus 20 First recovery means A Treatment liquid B Microorganism-adhered particles

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 有機性廃水を微生物によって浄化処理す
る廃水処理装置であって、 処理対象となる廃水の流入部と処理液の取出部とを有
し、その内部に微生物付着粒子が散在せしめられた処理
液を保有するよう構成された処理槽と、 この処理槽内を曝気する散気装置と、 該処理槽内の微生物付着粒子および処理液を導入して微
生物付着粒子の生物膜厚を判定し、生物膜厚が一定厚未
満の微生物付着粒子および処理液を判定粒子戻し部を通
して前記処理槽に戻す生物膜厚判定装置と、 この生物膜厚判定装置で判定された生物膜厚が一定厚以
上の微生物付着粒子および処理液を導入して該微生物付
着粒子の生物膜を剥離する生物膜剥離装置と、 この生物膜剥離装置により処理され生物膜が剥離された
微生物付着粒子および処理液を前記処理槽に戻す回収手
段とを具備してなり、 前記回収手段は、前記生物膜剥離装置で処理された微生
物付着粒子および処理液を前記生物膜厚判定装置に送る
第一の回収手段と、この第一の回収手段により送られた
微生物付着粒子および処理液を再度判定して生物膜厚が
一定厚未満の微生物付着粒子および処理液を前記処理槽
に戻す前記生物膜厚判定装置からなる第二の回収手段と
からなることを特徴とする廃水処理装置。
1. A wastewater treatment apparatus for purifying organic wastewater with microorganisms, comprising a wastewater inflow part to be treated and a treatment liquid takeout part, in which microorganism-adhered particles are scattered. A treatment tank configured to hold the treated liquid, a diffuser for aerating the inside of the treatment tank, and introducing the microorganism-adhered particles and the treatment liquid in the treatment tank to determine the biological film thickness of the microorganism-adhered particles. A biological film thickness determining device for returning the microorganism-adhered particles and the treatment liquid having a biological film thickness less than a certain thickness to the treatment tank through a determination particle returning unit; and a biological film thickness determined by the biological film thickness determining device is a certain thickness. A biofilm peeling device for removing the biofilm of the microorganism-adhered particles by introducing the above-mentioned microorganism-adhered particles and a treatment liquid, and In processing tank Ri Na and and a to collecting means, said collecting means, microorganisms treated with the biofilm peeling device
The particles attached to the substance and the treatment liquid to the biological film thickness determination device
First collection means and sent by this first collection means
The microbe-adhered particles and the processing solution are judged again and the biofilm thickness is reduced.
The treatment tank is adapted to remove the microorganism-adhered particles and the treatment liquid having a thickness smaller than a certain thickness.
A second recovery means comprising the biological film thickness determination device
A wastewater treatment device comprising:
【請求項2】 請求項1記載の廃水処理装置において、
前記判定粒子戻し部が前記処理槽の上方に配置されてい
ることを特徴とする廃水処理装置。
2. The wastewater treatment apparatus according to claim 1 ,
The wastewater treatment apparatus according to claim 1, wherein the determination particle return unit is disposed above the treatment tank.
JP8245692A 1992-04-03 1992-04-03 Wastewater treatment equipment Expired - Fee Related JP3250042B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8245692A JP3250042B2 (en) 1992-04-03 1992-04-03 Wastewater treatment equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8245692A JP3250042B2 (en) 1992-04-03 1992-04-03 Wastewater treatment equipment

Publications (2)

Publication Number Publication Date
JPH05285489A JPH05285489A (en) 1993-11-02
JP3250042B2 true JP3250042B2 (en) 2002-01-28

Family

ID=13775018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8245692A Expired - Fee Related JP3250042B2 (en) 1992-04-03 1992-04-03 Wastewater treatment equipment

Country Status (1)

Country Link
JP (1) JP3250042B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4139415B2 (en) * 2006-05-16 2008-08-27 前澤工業株式会社 Fluidized bed wastewater treatment equipment
CN103663688B (en) * 2013-12-30 2015-01-07 天津科技大学 Method for processing anaerobic reaction by using anaerobic fluidized bed bioreactor

Also Published As

Publication number Publication date
JPH05285489A (en) 1993-11-02

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