JP3233923B2 - Air purification filter - Google Patents

Air purification filter

Info

Publication number
JP3233923B2
JP3233923B2 JP23656889A JP23656889A JP3233923B2 JP 3233923 B2 JP3233923 B2 JP 3233923B2 JP 23656889 A JP23656889 A JP 23656889A JP 23656889 A JP23656889 A JP 23656889A JP 3233923 B2 JP3233923 B2 JP 3233923B2
Authority
JP
Japan
Prior art keywords
activated carbon
fine particles
weight
filter
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP23656889A
Other languages
Japanese (ja)
Other versions
JPH0398611A (en
Inventor
栄治 田中
哲也 津島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Chemical Co Ltd
Original Assignee
Kuraray Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Chemical Co Ltd filed Critical Kuraray Chemical Co Ltd
Priority to JP23656889A priority Critical patent/JP3233923B2/en
Publication of JPH0398611A publication Critical patent/JPH0398611A/en
Application granted granted Critical
Publication of JP3233923B2 publication Critical patent/JP3233923B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は空気浄化用フィルターに係わり、詳しくは、
エアコン、クーラー、空気清浄器、灯油ストーブ、冷風
器、温風器などに装填されて、有害ガス、有臭ガスなど
を吸着除去することにより空気を清浄化する空気浄化用
フィルターに関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an air purification filter.
The present invention relates to an air purification filter that is installed in an air conditioner, a cooler, an air purifier, a kerosene stove, a cooler, a warmer, etc., and purifies air by adsorbing and removing harmful gases and odorous gases.

〔従来の技術〕[Conventional technology]

空気中に含まれる有害成分や臭気を有する成分などを
除去する目的で、エアコン、クーラーなどに空気浄化用
フィルターが用いられている。
Air purifying filters are used in air conditioners, coolers, and the like for the purpose of removing harmful components and odorous components contained in the air.

従来の空気浄化用フィルターにおいては、スポンジに
活性炭を含浸させたものや、活性炭ハニカム、活性炭繊
維紙コルゲートなどが吸着材として用いられていた。
In a conventional air purification filter, a sponge impregnated with activated carbon, an activated carbon honeycomb, an activated carbon fiber paper corrugate, or the like has been used as an adsorbent.

〔発明が解決しようとする課題〕 ところで、空気浄化用フィルターとしては、吸着能力
が大きくて、圧力損失(以下、「圧損」という)の小さ
いものが好ましい。
[Problems to be Solved by the Invention] As the air purification filter, a filter having a large adsorption capacity and a small pressure loss (hereinafter, referred to as “pressure loss”) is preferable.

しかしながら、従来においてはかかる理想的なフィル
ターは得られていない。表は活性炭粉末を吸着材として
用いた、従来のフィルターの活性炭含有量および圧損を
示したものであり、同表に示すように、活性炭含有量が
少ないもの、或いは、圧損が大きいものしか存在しなか
った。
However, such an ideal filter has not been obtained conventionally. The table shows the activated carbon content and pressure loss of a conventional filter using activated carbon powder as an adsorbent.As shown in the table, only those having a low activated carbon content or those having a large pressure loss exist. Did not.

活性炭含有量が多いフィルター(表中、500セルおよ
び300セルのハニカム)は、吸着能力が大きいため、フ
ィルターの寿命が長く、この点では好ましいものの、圧
損が0.90以上と大きい。このため、装置を駆動するため
に大きなファン動力を必要とし、運転音が大きいなどの
問題があった。
Filters with a high content of activated carbon (honeycomb with 500 cells and 300 cells in the table) have a large adsorption capacity and therefore a long filter life, which is preferable in this respect, but has a large pressure loss of 0.90 or more. For this reason, there has been a problem that a large fan power is required to drive the device, and the operation noise is loud.

一方、圧損が比較的小さいフィルター(表中、HR−08
(ブリジストン社製、商品コード)、HR−10(同)、コ
ルゲート)は、活性炭含有量が少ない。このため、吸着
能力が小さいとともに、フィルター寿命が短いためフィ
ルター交換を頻繁に行う必要があるという問題があっ
た。
On the other hand, a filter with a relatively small pressure loss (HR-08 in the table)
(Bridgestone, product code), HR-10 (same as above, corrugate) have low activated carbon content. Therefore, there is a problem that the adsorption capacity is small and the filter life is short, so that the filter needs to be frequently replaced.

なお、活性炭含有量を多くするために活性炭粉末に代
えて、粒状活性炭を用いることも考えられるが、それで
は圧損が大きくなってしまう。
In order to increase the content of activated carbon, it is conceivable to use granular activated carbon instead of activated carbon powder, but this increases the pressure loss.

また、スポンジシートに活性炭を添着したものもある
が、添着量に限界があるため、活性炭含有量の多いフィ
ルターを得ることはできない。
Some sponge sheets have activated carbon impregnated. However, since the amount of impregnation is limited, a filter having a high activated carbon content cannot be obtained.

表中の活性炭コルゲートは、穴を小径化することによ
り活性炭含有量を多くすることができるものの、そうす
ると目詰まりが起きて圧損が大きくなってしまうという
問題が生じる。
Activated carbon corrugates in the table can increase the content of activated carbon by reducing the diameter of the hole, but this causes a problem that clogging occurs and pressure loss increases.

本発明は以上の事情に鑑みなされたものであって、そ
の目的とするところは、フィルター寿命が長く、しかも
圧損の小さい、優れた吸着能力を有する空気浄化用フィ
ルターを提供するにある。
The present invention has been made in view of the above circumstances, and it is an object of the present invention to provide an air purification filter having a long filter life, a small pressure loss, and an excellent adsorption capacity.

〔課題を解決するための手段〕[Means for solving the problem]

本発明の空気浄化用フィルターは上記の課題を達成す
るために開発されたもので、活性炭微粒子100重量部
に、50重量部を越えない量の熱可塑性樹脂またはメソフ
ェースピッチの微粒子を加えた配合物を、加熱加圧成形
法によって成形した厚さが0.1mm以上であり、且つ、3mm
以下であるシート状成形体を切断した短冊状の吸着材素
子が、互いに平行に配列された状態で装填されているこ
とを特徴とするフィルターである。更に、前記の活性炭
微粒子及び熱可塑性樹脂またはメソフェースピッチの微
粒子からなる配合物に、ガラス繊維を加えて前記と同様
に作製したフィルターも本発明に含まれている。
The air purification filter of the present invention has been developed in order to achieve the above object, and is a blend of 100 parts by weight of activated carbon fine particles and a thermoplastic resin or mesoface pitch fine particle in an amount not exceeding 50 parts by weight. Thickness formed by heating and pressing molding method is 0.1mm or more, and 3mm
A filter characterized in that strip-shaped adsorbent elements obtained by cutting the following sheet-shaped molded body are loaded in a state of being arranged in parallel with each other. Further, the present invention also includes a filter prepared by adding glass fibers to a blend comprising the above-mentioned activated carbon fine particles and thermoplastic resin or mesoface pitch fine particles in the same manner as described above.

本発明の空気浄化用フィルターに使用する吸着剤には
活性炭の微粒子を使用する必要がある。活性炭微粒子は
生活空間に含まれる殆どの有害成分や悪臭を有する成分
を吸着・除去する能力が優れている。
It is necessary to use fine particles of activated carbon as the adsorbent used in the air purification filter of the present invention. Activated carbon fine particles have excellent ability to adsorb and remove most harmful components and components having bad odors contained in the living space.

活性炭微粒子の粒度は、特に限定しないが、通常1μ
mm〜0.3mm程度の粒径の微粒子が好ましい。
The particle size of the activated carbon fine particles is not particularly limited, but is usually 1 μm.
Fine particles having a particle diameter of about mm to 0.3 mm are preferred.

本発明で使用される熱可塑性樹脂は特に限定しない
が、例えば、ポリエチレン、ポリプロピレン、ABS、PE
T、ナイロン、PBT、エチレンアクリル樹脂、PMMA樹脂等
の微粒子を用いることができる。熱可塑性樹脂の他メソ
フェースピッチも使用できる。
The thermoplastic resin used in the present invention is not particularly limited, for example, polyethylene, polypropylene, ABS, PE
Fine particles such as T, nylon, PBT, ethylene acrylic resin, and PMMA resin can be used. Mesoface pitch other than thermoplastic resin can also be used.

本発明においては、活性炭微粒子100重量部に対し
て、50重量部を越えない量の熱可塑性樹脂またはメソフ
ェースピッチの微粒子を用いる必要がある。50重量部を
越えた場合、活性炭含有量の減少による吸着能の低下が
生じるからである。活性炭微粒子の粒度や比重によって
異なるが、通常2〜50重量部の熱可塑性樹脂等を用いる
ことが好ましい。成形体が破損、破壊しない程度の必要
最小限の熱可塑性樹脂等を用いることが活性炭の含有率
を高くする意味からより好ましい。
In the present invention, it is necessary to use thermoplastic resin or mesoface pitch fine particles in an amount not exceeding 50 parts by weight based on 100 parts by weight of activated carbon fine particles. If the amount exceeds 50 parts by weight, the adsorptivity will decrease due to the decrease in the activated carbon content. Although it depends on the particle size and specific gravity of the activated carbon fine particles, it is usually preferable to use 2 to 50 parts by weight of a thermoplastic resin or the like. From the viewpoint of increasing the content of activated carbon, it is more preferable to use a minimum necessary thermoplastic resin or the like that does not break or break the molded body.

本発明に用いるシート状成形体のシート厚は0.1mm以
上であり、且つ、3mm以下である必要がある。これはシ
ート厚が0.1mm以下の場合、シート状成形体の強度が低
く、フィルター枠に装填することが困難になるからであ
り、またシート厚が3mm以上である場合、圧損が大きく
なり空気の流通速度が低下するため、活性炭含有量が多
いにもかかわらず、吸着速度が高いフィルターを得るこ
とが困難になるからである。
The sheet thickness of the sheet-shaped molding used in the present invention needs to be 0.1 mm or more and 3 mm or less. This is because when the sheet thickness is 0.1 mm or less, the strength of the sheet-like molded body is low, and it becomes difficult to load the filter into the filter frame.When the sheet thickness is 3 mm or more, the pressure loss increases and air This is because, since the flow rate is reduced, it is difficult to obtain a filter having a high adsorption rate despite a large content of activated carbon.

次に、本発明に係る空気浄化用フィルターの製造方法
について説明する。
Next, a method for manufacturing the air purification filter according to the present invention will be described.

先ず、活性炭微粒子と熱可塑性樹脂等とを所定の比率
で混合する。この混合は従来既知の種々の混合機を用い
て行うことができ、例えばミキサー、リボンミキサー、
スタティックミキサー、ボールミル、サンプルミル、ニ
ーダーなどを用いることができる。
First, activated carbon fine particles and a thermoplastic resin or the like are mixed at a predetermined ratio. This mixing can be performed using various conventionally known mixers, for example, a mixer, a ribbon mixer,
A static mixer, a ball mill, a sample mill, a kneader, or the like can be used.

なお、混合するだけでも活性炭微粒子と熱可塑性樹脂
等の微粒子とを接着させることができるが、両者の接着
をより強固にして脱落を防止するためには、加熱混合す
ることが好ましい。この場合の加熱方法としては、例え
ば静電気をかけたり、マイクロ波、赤外線、遠赤外線、
高周波等を照射したりする方法がある。
The activated carbon fine particles and the fine particles of a thermoplastic resin or the like can be adhered to each other only by mixing. However, in order to further strengthen the adhesion between the two and prevent the particles from falling off, it is preferable to heat and mix. Examples of the heating method in this case include applying static electricity, microwaves, infrared rays, far infrared rays,
There is a method of irradiating a high frequency or the like.

次に、上記配合物をシート状に成形してシート厚0.1
〜3mmのシート状成形体を作製する。シート成形におい
ては、乾式プレス、ロールプレス、ベルトプレ、ドクタ
ーブレード等の従来既知の種々の加圧成形機を用いるこ
とができる。ここで前記の加熱・加圧成形時の加熱温度
は、熱可塑性樹脂の軟化〜溶融温度の範囲内であり、ガ
ラス繊維の軟化・溶融温度よりは遙かに低い温度範囲で
ある。従って、成形体に含まれるガラス繊維の形状が変
形するおそれはない。
Next, the above-mentioned composition was formed into a sheet, and the sheet thickness was 0.1 mm.
A sheet-shaped molded product of about 3 mm is produced. In the sheet forming, various conventionally known pressure forming machines such as a dry press, a roll press, a belt press, a doctor blade and the like can be used. Here, the heating temperature at the time of the above-mentioned heating and pressure molding is in the range of softening to melting temperature of the thermoplastic resin, and is much lower than the softening and melting temperature of glass fiber. Therefore, there is no possibility that the shape of the glass fiber contained in the molded body is deformed.

最後に、得られたシート状吸着材を適宜の帯巾、通常
10mm程度の帯巾の帯状物に裁断した後、フィルター枠に
適宜の固定手段を用いて固定する。適宜の帯巾の帯状物
を用いることにより、適宜の厚みのフィルターを容易に
作製することができる。
Finally, apply the obtained sheet-shaped adsorbent to an appropriate band width, usually
After cutting into a band having a band width of about 10 mm, it is fixed to the filter frame by using an appropriate fixing means. By using a strip having an appropriate width, a filter having an appropriate thickness can be easily produced.

上記で短冊状に裁断された吸着材素子は、第1図
(イ)または(ロ)の空気浄化用フィルターの断面図に
示すように、短冊状の吸着材素子(5)を複数枚、素子
の表面が互に平行になるようにフィルター枠に配置する
必要がある。
As shown in the cross-sectional view of the air purification filter shown in FIG. 1 (a) or (b), the adsorbent element cut into strips is a plurality of strip-shaped adsorbent elements (5). Must be arranged on the filter frame so that the surfaces of the filters are parallel to each other.

〔作用〕[Action]

本発明にかかる空気浄化用フィルターにおいて、空気
を短冊状の吸着材素子の表面に平行に流通させると、シ
ート厚が薄いので、空気は小さな圧損失で流通するとと
もに、シート状成形体の活性炭含有量が多いため、空気
中の有害成分や臭気を有する成分などが効率よく除去さ
れる。
In the air purifying filter according to the present invention, when air is allowed to flow in parallel to the surface of the strip-shaped adsorbent element, the sheet is thin, so that the air flows with a small pressure loss and the sheet-like molded body contains activated carbon. Since the amount is large, harmful components and components having an odor in the air are efficiently removed.

〔実施例〕〔Example〕

以下、本発明を実施例に基づいてさらに詳細に説明す
るが、本発明は下記実施例に限定されるものではなく、
その要旨を変更しない範囲において適宜変更実施可能な
ものである。
Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to the following examples,
Changes can be made as appropriate without departing from the gist of the invention.

(実施例1) 中心粒径(試料の50重量%が篩い落とされる際の粒
径)20μmのポリエチレン20重量部と、粒径50μmの椰
子殻活性炭100重量部とをミキサーに入れて10分間攪拌
混合した後、これを縦、横各50mm、高さ1.5mmの内寸の
型枠内に流し込み、温度100℃、圧力10kg/cm2で30分
間、加圧成形した。冷却後この成形物のベンゼン吸着能 ((ベンゼン吸着量g/活性炭量g)×100) を測定したところ、55%であった。
(Example 1) 20 parts by weight of polyethylene having a central particle diameter (particle diameter when 50% by weight of a sample is sieved) and 100 parts by weight of coconut shell activated carbon having a particle diameter of 50 μm are put into a mixer and stirred for 10 minutes. After mixing, the mixture was poured into a mold having an inner size of 50 mm in length and width, and 1.5 mm in height, and pressure-formed at a temperature of 100 ° C. and a pressure of 10 kg / cm 2 for 30 minutes. After cooling, the molded product was measured for benzene adsorption capacity ((benzene adsorption amount g / activated carbon amount g) × 100) to be 55%.

次いで、上記成形物を巾10mmに裁断し、第1図(イ)
にその断面を示す空気浄化用フィルター(1)を作製し
た。このフィルターの活性炭含有量は292g/で圧損は
0.088mmaq.であった。
Next, the molded product was cut to a width of 10 mm, and FIG.
An air purification filter (1) showing the cross section was prepared. Activated carbon content of this filter is 292g /
0.088 mmaq.

(実施例2) 中心粒径80μmの活性炭100重量部、中心粒径20μm
のポリエチレン20重量部、ガラス繊維3重量部、水100
重量部をミキサーに入れ10分間攪拌混合した。次いで、
この混合物をドクターブレードを用いて、シート状に成
形した。この成形物を乾燥して加熱圧着し、厚さ1.5mm
のシートを得た。得られたシートを巾10mmに裁断した
後、その複数枚をフィルター枠に装填し、第1図(ロ)
にその断面を示す空気浄化用フィルター(2)を作製し
た。このフィルターの活性炭含有量は246g/であり、
圧損は0.028mmaq.であった。
(Example 2) 100 parts by weight of activated carbon having a central particle diameter of 80 μm, and a central particle diameter of 20 μm
20 parts by weight of polyethylene, 3 parts by weight of glass fiber, 100 parts of water
The parts by weight were put in a mixer and mixed with stirring for 10 minutes. Then
This mixture was formed into a sheet using a doctor blade. This molded product is dried, heat-pressed, and has a thickness of 1.5 mm.
Sheet was obtained. After cutting the obtained sheet to a width of 10 mm, a plurality of the sheets were loaded into a filter frame, and FIG. 1 (b)
An air purification filter (2) showing the cross section was prepared. The activated carbon content of this filter is 246 g /
The pressure loss was 0.028 mmaq.

〔発明の効果〕〔The invention's effect〕

以上詳細に説明したように、本発明にかかる空気浄化
用フィルターは、吸着能力が大きく、しかも圧損失が小
さいため、効率よく空気中に含まれる有害成分や臭気を
有する成分などを除去することができる等、優れた特有
の効果を奏する。
As described in detail above, the air purification filter according to the present invention has a large adsorption capacity and a small pressure loss, so that it is possible to efficiently remove harmful components and components having an odor contained in the air. It has excellent unique effects such as being able to.

【図面の簡単な説明】[Brief description of the drawings]

図1は本発明にかかる空気浄化用フィルーの一態様の断
面図を示す。同図(イ)および(ロ)は帯状シートを切
断した短冊状の吸着素子を、複数枚平行に配置して枠に
装填した状態を示す。 (1)、(2)……空気浄化用フィルー (5)……短冊状の吸着材素子 (6)……フィルーの枠
FIG. 1 is a cross-sectional view of one embodiment of the air purifying filter according to the present invention. FIGS. 7A and 7B show a state in which a plurality of strip-shaped suction elements obtained by cutting a strip-shaped sheet are arranged in parallel and loaded in a frame. (1), (2) ... air purifying filter (5) ... strip-shaped adsorbent element (6) ... filter frame

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭62−72509(JP,A) 特開 昭48−7051(JP,A) 特開 昭55−13160(JP,A) 特開 昭61−134232(JP,A) 特開 平2−129239(JP,A) 実開 昭50−59333(JP,U) 実開 昭54−100941(JP,U) 特表 平4−505933(JP,A) (58)調査した分野(Int.Cl.7,DB名) B01D 53/04 B01J 20/28 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-62-72509 (JP, A) JP-A-48-7051 (JP, A) JP-A-55-13160 (JP, A) JP-A 61-72 134232 (JP, A) JP-A-2-129239 (JP, A) JP-A 50-59333 (JP, U) JP-A 54-100941 (JP, U) JP-A-4-505933 (JP, A) (58) Field surveyed (Int. Cl. 7 , DB name) B01D 53/04 B01J 20/28

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】活性炭微粒子100重量部に、50重量部を越
えない量の熱可塑性樹脂またはメソフェースピッチの微
粒子を加えた配合物を、加熱加圧成形法によって成形し
た厚さが0.1mm以上であり、且つ、3mm以下であるシート
状成形体を切断した短冊状の吸着材素子が、互いに平行
に配列された状態で装填されていることを特徴とする空
気浄化用フィルター。
1. A composition obtained by adding a thermoplastic resin or mesoface pitch fine particles in an amount not exceeding 50 parts by weight to 100 parts by weight of activated carbon fine particles, and having a thickness of 0.1 mm or more formed by a heat and pressure molding method. And a strip-shaped adsorbent element obtained by cutting a sheet-shaped molded body of 3 mm or less is loaded in a state of being arranged in parallel with each other.
【請求項2】活性炭微粒子100重量部に50重量部を越え
ない量の熱可塑性樹脂の微粒子と更にガラス繊維を加え
た配合物を、加熱加圧成形法によって成形してなる厚さ
が0.1mm以上であり、3mm以下であるシート状成形体を切
断した短冊状の吸着材素子が、互いに平行に配列された
状態で装填されていることを特徴とする空気浄化用フィ
ルター。
2. A mixture of 100 parts by weight of activated carbon fine particles and thermoplastic resin fine particles in an amount not exceeding 50 parts by weight and glass fibers further molded by a heat and pressure molding method to a thickness of 0.1 mm. An air purification filter, characterized in that strip-shaped adsorbent elements obtained by cutting a sheet-shaped molded body of 3 mm or less are loaded in a state of being arranged in parallel with each other.
JP23656889A 1989-09-12 1989-09-12 Air purification filter Expired - Fee Related JP3233923B2 (en)

Priority Applications (1)

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JP23656889A JP3233923B2 (en) 1989-09-12 1989-09-12 Air purification filter

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Application Number Priority Date Filing Date Title
JP23656889A JP3233923B2 (en) 1989-09-12 1989-09-12 Air purification filter

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JPH0398611A JPH0398611A (en) 1991-04-24
JP3233923B2 true JP3233923B2 (en) 2001-12-04

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Cited By (3)

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KR101808561B1 (en) 2016-03-23 2017-12-13 주식회사 산청 Absorbent for cbrn-agent and adsorption filter for toxic agent thereby, and protective suit for toxic-agent and filter manufacturing method therefor
JP7228132B2 (en) 2018-09-05 2023-02-24 王子ホールディングス株式会社 Metal layer-integrated polypropylene film, film capacitor, and metal layer-integrated polypropylene film production method
JP7256960B2 (en) 2018-08-29 2023-04-13 王子ホールディングス株式会社 Manufacturing method of metal layer integrated polypropylene film

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Publication number Priority date Publication date Assignee Title
SG77254A1 (en) * 1997-01-31 2000-12-19 Takasago Thermal Engineering Air cleaning apparatus air filter and method for manufacturing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101808561B1 (en) 2016-03-23 2017-12-13 주식회사 산청 Absorbent for cbrn-agent and adsorption filter for toxic agent thereby, and protective suit for toxic-agent and filter manufacturing method therefor
JP7256960B2 (en) 2018-08-29 2023-04-13 王子ホールディングス株式会社 Manufacturing method of metal layer integrated polypropylene film
JP7228132B2 (en) 2018-09-05 2023-02-24 王子ホールディングス株式会社 Metal layer-integrated polypropylene film, film capacitor, and metal layer-integrated polypropylene film production method

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