JP3233141B2 - Granular material containing synthetic resin material, method for producing the same, and method for blowing granular material into furnace - Google Patents

Granular material containing synthetic resin material, method for producing the same, and method for blowing granular material into furnace

Info

Publication number
JP3233141B2
JP3233141B2 JP31301699A JP31301699A JP3233141B2 JP 3233141 B2 JP3233141 B2 JP 3233141B2 JP 31301699 A JP31301699 A JP 31301699A JP 31301699 A JP31301699 A JP 31301699A JP 3233141 B2 JP3233141 B2 JP 3233141B2
Authority
JP
Japan
Prior art keywords
blast furnace
synthetic resin
blowing
granular material
resin material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP31301699A
Other languages
Japanese (ja)
Other versions
JP2000198992A (en
Inventor
武史 小西
浩一 冨岡
信一 若松
周雄 寺田
謙一 根本
邦彦 丹下
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
Original Assignee
JFE Engineering Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JFE Engineering Corp filed Critical JFE Engineering Corp
Priority to JP31301699A priority Critical patent/JP3233141B2/en
Priority to TW89110542A priority patent/TW445202B/en
Priority to CNB00815001XA priority patent/CN1317116C/en
Priority to PCT/JP2000/003757 priority patent/WO2001032383A1/en
Priority to EP20000935609 priority patent/EP1236790A1/en
Priority to KR10-2002-7004786A priority patent/KR100478570B1/en
Publication of JP2000198992A publication Critical patent/JP2000198992A/en
Application granted granted Critical
Publication of JP3233141B2 publication Critical patent/JP3233141B2/en
Priority to US10/132,831 priority patent/US20030021991A1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、プラスチック特に
紙含有プラスチックフィルム等の合成樹脂類を高炉やス
クラップ溶解炉等の炉の吹込み燃料として使用する際
の、合成樹脂材を含む表面が溶融固化した粒状物、その
製造方法および粒状物の炉への吹き込み方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the use of synthetic resins such as plastics, especially paper-containing plastic films, as fuel for blowing in furnaces such as blast furnaces and scrap melting furnaces, and the surface containing the synthetic resin material is melted and solidified. The present invention relates to a granulated material, a method for producing the same, and a method for blowing the granular material into a furnace.

【0002】[0002]

【従来の技術】近年、産業廃棄物や一般廃棄物としての
プラスチック等の合成樹脂類が急増しており、その処理
が大きな社会問題となっている。なかでも高分子系の炭
化水素化合物であるプラスチックは燃焼時に発生する熱
量が高く、焼却処理した場合に焼却炉を傷めるために大
量処理が困難であり、その多くがごみ埋め立て地等に投
棄されているのが現状である。しかし、プラスチック等
の投棄は環境対策上好ましくなく、その大量処理方法の
開発が切望されている。
2. Description of the Related Art In recent years, synthetic resins such as plastics as industrial wastes and general wastes have been rapidly increasing, and their disposal has become a major social problem. Among these, plastics, which are high-molecular hydrocarbon compounds, generate a large amount of heat during combustion, and when incinerated, damage to the incinerator makes mass treatment difficult, and many of them are dumped in landfills. That is the current situation. However, dumping of plastics and the like is not preferable in terms of environmental measures, and development of a large-scale treatment method is eagerly desired.

【0003】このような背景の下、プラスチック等の合
成樹脂類を高炉等の補助燃料として用いる方法が提案さ
れている。これらの方法は、合成樹脂の粉砕物を羽口等
から高炉内に燃料として吹き込むもので、例えば前者に
おいては、炉内に吹き込まれる合成樹脂粉砕物の実質的
な条件として、粒径1〜10mm、嵩密度0.35以上
という条件が示されている。
Against this background, there has been proposed a method of using synthetic resins such as plastics as auxiliary fuel for blast furnaces and the like. In these methods, a synthetic resin pulverized material is blown into a blast furnace from a tuyere or the like as a fuel. For example, in the former, as a substantial condition of the synthetic resin pulverized material blown into the furnace, the particle size is 1 to 10 mm. , Bulk density of 0.35 or more.

【0004】しかしながら、プラスチック等の合成樹脂
類を高炉等の吹込み燃料として使用する場合、次のよう
な解決すべき問題点があることが明らかとなった。産業
廃棄物や一般廃棄物として廃棄されるプラスチックを形
態別に見た場合、概ね板材等の塊状プラスチックとフィ
ルム状プラスチックとに大別され、このうち後者のフィ
ルム状プラスチックも廃棄プラスチック全体の中で相当
量を占めている。しかしフィルム状のプラスチックの粉
砕物は搬送性や流動性が極めて悪く、燃料として用いる
際の取り扱いに大きな問題があることが判明した。
However, when synthetic resins such as plastics are used as blowing fuel for blast furnaces and the like, it has been found that there are the following problems to be solved. When plastics discarded as industrial waste or general waste are classified according to their forms, they are roughly classified into bulk plastics such as plate materials and film-like plastics. Occupy the amount. However, it has been found that the pulverized product of the film-shaped plastic has extremely poor transportability and fluidity, and has a serious problem in handling when used as a fuel.

【0005】従って、このような問題を解決しない限り
フィルム状プラスチックを高炉等の吹込み燃料として使
用することは事実上不可能であり、さらにはフィルム状
プラスチックが廃棄プラスチック全体の中で相当の割合
を占める状況を考慮すると、フィルム状プラスチックの
利用を可能としない限り、廃棄物たるプラスチックの大
量処理と有効利用というメリットが失われることは明ら
かである。
[0005] Therefore, it is practically impossible to use film-like plastic as a blowing fuel for a blast furnace or the like unless this problem is solved. It is clear that the advantages of mass processing and effective use of waste plastics will be lost unless film plastics can be used.

【0006】また、高炉に燃料としてプラスチックを吹
き込むためには、燃焼性等を確保するため粉砕処理した
プラスチックを用いる必要があるが、処理コストの面か
ら、粉砕できる粒径には限度があり、このため従来技術
に示されるように粒径1〜10mm程度が細粒化の限界
となる。しかし、塊状プラスチックをこの程度の粒径に
粉砕したものは高炉内での燃焼性が十分に得られない場
合があり、このため未燃焼のプラスチックがベットコー
クス内で融着して炉内の通気性を著しく阻害し、高炉の
操業に支障をきたす恐れがある。
In order to inject plastic as fuel into a blast furnace, it is necessary to use plastic that has been pulverized in order to ensure flammability and the like. However, from the viewpoint of processing cost, there is a limit to the particle size that can be pulverized. For this reason, as shown in the prior art, a grain size of about 1 to 10 mm is the limit of grain refinement. However, crushed lump plastics having such a particle size may not have sufficient flammability in a blast furnace, and unburned plastics may be fused in bed coke and ventilated in the furnace. The blast furnace operation may be severely impaired and the operation of the blast furnace may be hindered.

【0007】さらに、塊状プラスチックを破砕処理した
ものは不規則で角ばった形状をしているため、1〜10
mm程度の粒径のものでは貯留サイロから切り出す際の
排出性や高炉に気送する際の流動性、搬送性が悪く、サ
イロの切出部や気送管系の途中で詰まりを生じ易いとい
う問題もあることが判明した。したがって、従来技術で
提案されているように単にプラスチックを1〜10mm
程度の粒径に粉砕して嵩密度の高い粒状体に加工し、こ
れを高炉に吹き込むということだけでは、廃棄物たるプ
ラスチックを工業規模で高炉等の吹込み燃料として利用
することは極めて難しい。
[0007] Furthermore, since the crushed lump of the bulk plastic has an irregular and square shape, it is 1-10.
With a particle size of about mm, the dischargeability when cutting out from the storage silo, the fluidity when transporting to the blast furnace, and the transportability are poor, and it is easy for clogging to occur in the silo cutout part and the middle of the pneumatic piping system It turned out that there was also a problem. Therefore, just as suggested in the prior art, plastics are simply 1-10 mm.
It is extremely difficult to use plastic as waste as a fuel for blowing into a blast furnace or the like on an industrial scale only by pulverizing to a particle size of about a degree and processing it into a granular material having a high bulk density and then blowing it into a blast furnace.

【0008】[0008]

【発明が解決しょうとする課題】上述した問題点を解決
するために、特開平09−137926号公報(以下、
「先行技術1」という)に炉への燃料吹込み方法が開示
されている。特開平09−137926号公報に開示さ
れている方法によると、廃棄合成樹脂類中のフィルム状
合成樹脂材の存在が合成樹脂類の炉燃料としての利用を
事実上不可能にしていることを指摘した上で、燃料に供
すべき合成樹脂類を、フィルム状合成樹脂類を主体とす
る合成樹脂類とそれ以外の合成樹脂類とに分別された状
態で加工処理設備に受け入れ、これらをそれぞれ異なる
工程で気送用固体燃料に適した粒状物に加工し、この加
工後の粒状合成樹脂を炉に気送する。
SUMMARY OF THE INVENTION In order to solve the above problems, Japanese Patent Laid-Open Publication No. 09-137926
"Prior art 1") discloses a method of injecting fuel into a furnace. According to the method disclosed in Japanese Patent Application Laid-Open No. 09-137926, it is pointed out that the presence of the film-like synthetic resin material in the waste synthetic resin makes the use of the synthetic resin as a furnace fuel practically impossible. After that, the synthetic resins to be supplied to the fuel are separated into synthetic resins mainly composed of film-like synthetic resins and other synthetic resins and received in the processing equipment, and these are subjected to different processes. To process into a granular material suitable for a solid fuel for pneumatic transport, and pneumatically transport the granular synthetic resin after the processing to a furnace.

【0009】しかしながら、先行技術1によると、フィ
ルム状合成樹脂材に紙、ダンボール等の溶融しない成分
が混入する(特に、10%以上)と、高炉吹込み時に、
タンク、配管で詰まる原因となるフラフ状異物が減容固
化で生じる。また、融点の異なるフィルムの混合物でも
同様に、フラフ状異物が減容固化で生じる。その結果、
高炉吹込み時に、タンク、配管で詰まりが生じるという
問題点がある。
However, according to Prior Art 1, if unmelted components such as paper and cardboard are mixed (especially, 10% or more) into the film-like synthetic resin material, when the blast furnace is blown,
Fluffy foreign substances that cause clogging in tanks and pipes are generated by volume reduction and solidification. Similarly, in the case of a mixture of films having different melting points, fluff-like foreign matter is generated by volume reduction and solidification. as a result,
When the blast furnace is blown, there is a problem that clogging occurs in tanks and pipes.

【0010】更に、特開平10−102110号公報
(以下、「先行技術2」という)に竪型炉への可燃性廃
棄物の吹込み方法が開示されている。特開平10−10
2110号公報に開示された方法によると、レースウェ
イ内におけるコークスや種々の補助燃料の燃焼状況を観
察、検討した結果、一定以上の粒径を有し強度の大きい
固形燃料の場合、レースウェイ内でコークスと同様に燃
焼効率よく燃焼させることが可能であることを指摘した
上で、粒径が10mm以上の可燃性廃棄物を、銑鉄を製
造する竪型炉のレースウェイ内へ送風羽口を介して吹き
込み燃焼している。
Furthermore, Japanese Patent Application Laid-Open No. 10-102110 (hereinafter referred to as "prior art 2") discloses a method for injecting combustible waste into a vertical furnace. JP-A-10-10
According to the method disclosed in Japanese Patent No. 2110, the combustion state of coke and various auxiliary fuels in the raceway was observed and examined. It was pointed out that combustible waste with a particle size of 10 mm or more can be burned into the raceway of a vertical furnace that manufactures pig iron by pointing out that it is possible to burn with high combustion efficiency like coke. Combustion is blowing through.

【0011】しかしながら、先行技術2によると、合成
樹脂含有率50%未満の可燃性廃棄物の成型、吹込みで
は、成型粒が崩壊し易く、先行技術1と同様に、フラフ
状異物が発生し易くなり、高炉吹込み時に、タンク、配
管で詰まりが生じるという問題点がある。
However, according to Prior Art 2, when molding or blowing flammable waste having a synthetic resin content of less than 50%, the molded particles are easily broken, and fluff-like foreign matter is generated as in Prior Art 1. Therefore, there is a problem that clogging occurs in tanks and pipes when the blast furnace is blown.

【0012】従って、この発明の目的は、従来の問題点
を解決して、フィルム状合成樹脂材に紙、ダンボール等
の溶融しない成分が10%以上混入した場合、合成樹脂
含有量50%未満の場合においても、高炉吹込み時にタ
ンク、配管で詰まる原因となるフラフ状異物を発生させ
ない、合成樹脂材を含む表面が溶融固化した粒状物、お
よび、粒状物の炉への吹き込み方法を提供することにあ
る。更にこの発明の目的は、溶融しない成分および融点
の異なる複数の成分からなる合成樹脂を一度に処理する
ことができる生産性の高い、合成樹脂材を含む表面が溶
融固化した粒状物の製造方法を提供することにある。
Accordingly, an object of the present invention is to solve the conventional problems, and when a non-melting component such as paper or cardboard is mixed in a film-like synthetic resin material by 10% or more, the synthetic resin content is less than 50%. Even in this case, there is provided a granular material whose synthetic resin material is melted and solidified, and a method of blowing the granular material into a furnace, which does not generate fluff-like foreign matter that causes clogging in a tank or piping when blowing a blast furnace. It is in. Further, an object of the present invention is to provide a method for producing a granular product having a surface containing a synthetic resin material melted and solidified, which can process a synthetic resin composed of a plurality of components having different melting points and a component that does not melt at a high productivity. To provide.

【0013】[0013]

【課題を解決するための手段】本発明者は、上述した従
来技術の問題点を解決すべく鋭意研究を重ねた。その結
果、50〜300℃の範囲内で異なる融点を有する複数
の成分からなるプラスチック等の合成樹脂材が10%以
上含有されるように、紙等の溶融しない成分を含む原料
を調製し、このように調製された原料を、すりつぶし、
および、圧縮押し出し工程を含むリングダイ式造粒機に
よって、合成樹脂材を含む表面が溶融固化した粒状物を
製造すると、粒状物は、紙等の溶融しない成分は圧密さ
れて中心部を形成し、溶融する成分が表面に溶融固化さ
れた状態になり、その結果、粒状物を高炉羽口に吹き込
むと、タンク、配管で詰まる原因となるフラフ状異物を
発生させないことを知見した。
Means for Solving the Problems The present inventor has made intensive studies to solve the above-mentioned problems of the prior art. As a result, a raw material containing a non-melting component such as paper is prepared so that a synthetic resin material such as plastic composed of a plurality of components having different melting points in the range of 50 to 300 ° C. is contained at 10% or more. Raw materials prepared as above,
And, when a granular material whose surface including a synthetic resin material is melt-solidified is produced by a ring die granulator including a compression extrusion process, the granular material is formed by consolidating unmelted components such as paper to form a central portion. It has been found that the components to be melted are melted and solidified on the surface, and as a result, when the particulate matter is blown into the tuyere of the blast furnace, fluff-like foreign matters that cause clogging in tanks and pipes are not generated.

【0014】 この発明は、上記知見に基づいてなされ
たものであって、この発明の高炉吹込み用粒状物の第1
の態様は、合成樹脂材を含み、圧密され嵩密度が高い中
心部材と前記中心部材を覆う溶融固化している表面部材
とからなり、多数の穴があいた円筒形のダイリングの穴
から圧縮押し出されて製造されることを特徴とする高炉
吹込み用粒状物である。
The present invention has been made on the basis of the above-described findings, and is a first example of the blast furnace injection granular material of the present invention.
Embodiments, the synthetic resin material seen including, in a high bulk density is compacted
A melt-solidified surface member covering a core member and the center member
And a cylindrical die ring with many holes
Blast furnace characterized by being manufactured by compression extrusion from
Granules for blowing .

【0015】 この発明の高炉吹込み用粒状物の第2の
態様は、前記高炉吹込み用粒状物は、50〜300℃の
範囲内の融点を有する成分を10%以上含有しているこ
とを特徴とする
A second aspect of the granulated material for blowing blast furnace according to the present invention is that the granulated material for blowing blast furnace has a temperature of 50 to 300 ° C.
10% or more of components having a melting point within the range
And features .

【0016】 この発明の高炉吹込み用粒状物の第3の
態様は、前記合成樹脂材は、紙含有フィルム状プラスチ
ックを含有することを特徴とする
In a third aspect of the granulated material for blowing into a blast furnace according to the present invention, the synthetic resin material is a paper-containing film-like plastic.
It is characterized by containing a crack .

【0017】 この発明の高炉吹込み用粒状物の第4の
態様は、前記高炉吹込み用粒状物の粒径が40mm以下
であることを特徴とする
In a fourth aspect of the blast furnace blowing granules of the present invention, the particle size of the blast furnace blowing granules is 40 mm or less.
It is characterized by being .

【0018】 この発明の高炉吹込み用粒状物の第5の
態様は、前記合成樹脂材は、廃棄プラスチックであるこ
とを特徴とする
According to a fifth aspect of the granulated material for blowing into a blast furnace of the present invention, the synthetic resin material is a waste plastic.
And features .

【0019】 この発明の粒状物の高炉吹込み方法の第
1の態様は、合成樹脂材を含み、圧密され嵩密度が高い
中心部材と前記中心部材を覆う溶融固化している表面部
材とからなり、多数の穴があいた円筒形のダイリングの
穴から圧縮押し出されて製造される粒状物を気送して、
高炉に吹き込むことを特徴とする
In the method for blowing blast furnace of granular material according to the present invention,
One embodiment includes a synthetic resin material and is compacted and has a high bulk density.
A central member and a melt-solidified surface covering the central member
Of cylindrical die with many holes
Pneumatically push the granules produced by compression extrusion from the hole,
It is characterized by blowing into a blast furnace .

【0020】 この発明の粒状物の高炉吹込み方法の第
2の態様は、前記粒状物は、50〜300℃の範囲内の
融点を有する成分を10%以上含有していることを特徴
とする
In the method for blowing blast furnace of particulate matter according to the present invention,
In a second aspect, the granular material is in a range of 50 to 300 ° C.
It is characterized by containing 10% or more of components having melting point
And

【0021】 この発明の粒状物の高炉吹込み方法の第
3の態様は、紙含有フィルム状プラスチックを含有する
ことを特徴とする
The blast furnace blowing method for granular materials according to the present invention
The third embodiment contains a paper-containing film-like plastic.
It is characterized by the following .

【0022】 この発明の粒状物の高炉吹込み方法の第
4の態様は、前記粒状物の粒径が40mm以下であるこ
とを特徴とする。
In the method for blowing blast furnace of particulate matter according to the present invention,
In a fourth aspect, the particle size of the granular material is 40 mm or less.
And features.

【0023】 この発明の粒状物の高炉吹込み方法の第
5の態様は、前記合成樹脂材は、廃棄プラスチックであ
ることを特徴とする
According to a fifth aspect of the method for blowing blast furnace of particulate matter of the present invention, the synthetic resin material is a waste plastic.
It is characterized by that .

【0024】 この発明の高炉吹込み用粒状物の製造方
法の第1の態様は、合成樹脂材を含む原料を、リングダ
イ式造粒機を用いて、多数の穴があいた円筒形のダイリ
ングの穴から圧縮押し出し、圧密され嵩密度が高い中心
部材と前記中心部材を覆う溶融固化している表面部材と
からなる粒状物を製造することを特徴とする
Method for Producing Granules for Blast Furnace Injection of the Invention
In a first aspect of the method, a raw material containing a synthetic resin material is supplied to a ring ring.
Using a type granulator, a cylindrical die with many holes
Center with high bulk density
A melted and solidified surface member covering the member and the central member;
Characterized by producing a granular material comprising:

【0025】 この発明の高炉吹込み用粒状物の製造方
法の第2の態様は、前記原料は、50〜300℃の範囲
内の融点を有する成分を10%以上含有していることを
特徴とする
Method for Producing Granules for Blast Furnace Injection of the Invention
In a second aspect of the method, the raw material is in a range of 50 to 300 ° C.
Contains at least 10% of the component having the melting point
Features .

【0026】 この発明の高炉吹込み用粒状物の製造方
法の第3の態様は、前記合成樹脂材は、紙含有フィルム
状プラスチックを含有することを特徴とする。
Method for Producing Granules for Blast Furnace Injection of the Invention
In a third aspect of the method, the synthetic resin material is a paper-containing film.
It is characterized by containing a shaped plastic.

【0027】 この発明の高炉吹込み用粒状物の製造方
法の第4の態様は、前記粒状物の粒径が40mm以下で
あることを特徴とする
Method for Producing Granules for Blast Furnace Injection of the Invention
A fourth aspect of the method is that the particle size of the granular material is 40 mm or less.
There is a feature .

【0028】 この発明の高炉吹込み用粒状物の製造方
法の第5の態様は、前記リングダイ式造粒機は、円周上
に多数の穴があいた円筒形のダイリングと、そして、円
筒形のダイリングとの間の摩擦で回転する複数のロール
からなっており、前記粒状物は、前記原料を円筒形のダ
イリングと複数のロールとの間ですりつぶされ、円筒形
のダイリングの穴から連続的に圧縮押し出され、所定の
長さで切断されて製造されることを特徴とする
Method for Producing Granules for Blast Furnace Injection of the Invention
A fifth aspect of the method is that the ring die granulator is arranged on a circumference.
A cylindrical die ring with many holes in it and a circle
Multiple rolls rotating due to friction between cylindrical die ring
Wherein the granular material comprises a cylindrical
Grinding between the ring and multiple rolls, cylindrical
Continuously extruded from the hole of the die ring
It is characterized by being manufactured by being cut in length .

【0029】[0029]

【0030】[0030]

【0031】[0031]

【発明の実施の形態】本発明の合成樹脂材を含む表面が
溶融固化した粒状物、その製造方法および粒状物の炉へ
の吹き込み方法の1つの態様を詳細に説明する。図1に
本発明の合成樹脂材を含む表面が溶融固化した粒状物の
製造方法の概要を示す。この発明の合成樹脂を含む表面
が溶融固化した粒状物の製造方法において、製造される
粒状物は、融点が50〜300℃の範囲内にある成分
(例えば、ポリエチレンフィルム)(以下、「A」とい
う)、および、その他の非溶融成分(例えば紙)(以
下、「B」という)からなっている。Aは造粒中のすり
つぶし、圧縮押し出しの工程における摩擦熱によって半
溶融して、造粒後に固化されるので、粒の強度を高め、
崩壊しにくくなる。Bは上述した造粒中のすりつぶし、
圧縮押し出しの工程において、圧密され、粒の嵩密度を
向上させる。その結果、吹込み量が増大する。なお、A
は、融点が50〜300℃の範囲内で異なる複数の成分
からなっていてもよい。更に、好ましくは、上述した成
分の融点は100〜280℃の範囲内である。融点が1
00〜280℃の範囲内であるとき、粒の強度が十分高
まり、崩壊しにくくなる。
BEST MODE FOR CARRYING OUT THE INVENTION One embodiment of a granular material containing a synthetic resin material of the present invention whose surface is melt-solidified, a method for producing the granular material, and a method for blowing the granular material into a furnace will be described in detail. FIG. 1 shows an outline of a method for producing a granular material including a synthetic resin material of the present invention whose surface is melted and solidified. In the method of the present invention for producing a granular material having a surface melted and solidified, the granular material to be produced is a component (for example, a polyethylene film) having a melting point in the range of 50 to 300 ° C. (hereinafter, “A”). ) And other non-melting components (for example, paper) (hereinafter, referred to as “B”). A is crushed during granulation, is semi-molten by frictional heat in the step of compression extrusion, and is solidified after granulation.
It is difficult to collapse. B is the grinding during granulation described above,
In the step of compression extrusion, it is compacted to improve the bulk density of the grains. As a result, the blowing amount increases. A
May be composed of a plurality of components having different melting points in the range of 50 to 300 ° C. More preferably, the melting points of the above-mentioned components are in the range of 100-280 ° C. Melting point is 1
When the temperature is in the range of 00 to 280 ° C, the strength of the grains is sufficiently increased, and the grains are hardly disintegrated.

【0032】本発明においては、50〜300℃の範囲
内の融点を有する成分が10%以上含有されるように、
プラスチック等の合成樹脂材を配合する。その理由は、
このように配合したものを、すりつぶし、および、圧縮
押し出し工程を含むリングダイ式造粒機にて粒状物を製
造すると、粒状物は、圧密され嵩密度が高い中心部材と
中心部材を覆う溶融固化している表面部材とからなり、
例えば、中身が圧縮成型され表面が溶融固化している円
柱状の粒に成型され、その結果、成型粒を高炉羽口に吹
き込むと、タンク、配管で詰まる原因となるフラフ状異
物を発生させないからである。本発明において、上述し
た50〜300℃の範囲内の融点を有する成分は、好ま
しくは50%以上含有されている。
In the present invention, a component having a melting point in the range of 50 to 300 ° C. is contained in an amount of 10% or more.
A synthetic resin material such as plastic is blended. The reason is,
When the granulated material thus produced is ground by a ring die granulator including a grinding and compression extrusion process, the granulated material is consolidated and melt-solidified to cover the central member having a high bulk density and the central member. Surface member
For example, the contents are molded into cylindrical particles whose surfaces are compression molded and the surface is melted and solidified.As a result, when the molded particles are blown into the blast furnace tuyere, they do not generate fluffy foreign substances that cause clogging in tanks and piping. It is. In the present invention, the above-mentioned component having a melting point in the range of 50 to 300 ° C is preferably contained by 50% or more.

【0033】50〜300℃の範囲内の融点を有する成
分が10%未満の場合には、表面の溶融固化が不十分と
なり、成型された粒が崩壊して、タンク、配管で詰まる
原因となるフラフ状異物が発生してしまう。
If the component having a melting point in the range of 50 to 300 ° C. is less than 10%, the surface is insufficiently melted and solidified, and the molded particles are broken and clogged in tanks and pipes. Fluffy foreign matter is generated.

【0034】粒状物の表面を溶融固化させる重要な理由
の1つに、粒状物の強度を上昇させることによって、粒
状物の燃焼効率を向上させることがある。即ち、粒状物
の表面が溶融固化すると、粒状物の強度が上昇する。粒
状物の強度が小さいときは、気送(搬送)中に、粒状物
が崩壊して、レースウエイの中に、崩壊した小さい形状
のまま送りこまれるので、レースウエイ中に滞留する時
間が極めて少なく、燃焼効率が悪くなってしまう。
One of the important reasons for melting and solidifying the surface of the granular material is to improve the burning efficiency of the granular material by increasing the strength of the granular material. That is, when the surface of the granular material is melted and solidified, the strength of the granular material increases. When the strength of the granular material is low, the granular material collapses during pneumatic transportation (conveyance) and is sent into the raceway with the collapsed small shape. Therefore, the residence time in the raceway is extremely short. However, the combustion efficiency is deteriorated.

【0035】更に詳細に述べると、羽口から吹き込まれ
た粒径の大きな合成樹脂材は、燃焼しつつ旋回状態でレ
ースウエイに長時間滞留して、ある程度小さくなるまで
その旋回状態を維持しつつレースウエイに滞留する。そ
の後、粒径がある程度小さくなると、レースウエイから
飛散していく。一方、粒径の小さな合成樹脂材は、羽口
から吹き込まれると、レースウエイに滞留することな
く、直ちに飛散してしまう。
More specifically, the synthetic resin material having a large particle diameter blown from the tuyere stays on the raceway in a swirling state for a long time while burning, and maintains the swirling state until it becomes small to some extent. Stay on the raceway. Thereafter, when the particle diameter becomes smaller to some extent, it scatters from the raceway. On the other hand, when the synthetic resin material having a small particle diameter is blown from the tuyere, it is immediately scattered without staying in the raceway.

【0036】一般的に、重力場あるいは遠心力場で流体
中を運動する粒子に作用する抵抗力が、粒子の推進力と
つりあったときの粒子速度が、いわゆる終末速度であ
る。羽口から吹き込まれた合成樹脂材のレースウエイ内
での終末速度が、このレースウエイ内から排出されるガ
スの流速よりも十分に大きい間は、この合成樹脂材は、
レースウエイから飛び出すことができず、この間、レー
スウエイ内を循環・滞留するので十分に燃焼することが
でき、合成樹脂材の燃焼効率が高くなる。上述したよう
に、本発明の合成樹脂材を含む表面が溶融固化した粒状
物は、高炉に吹き込まれたとき、強度が高いことに起因
して、その燃焼効率が高いことがわかる。
Generally, the so-called terminal velocity is the particle velocity when the resistance acting on the particles moving in the fluid in the gravitational field or the centrifugal field is balanced with the propulsive force of the particles. As long as the terminal velocity of the synthetic resin material blown from the tuyere in the raceway is sufficiently higher than the flow velocity of the gas discharged from the raceway, the synthetic resin material is
It is not possible to jump out of the raceway, and during this time, it circulates and stays in the raceway, so that it can be sufficiently burned and the combustion efficiency of the synthetic resin material increases. As described above, it can be seen that the granular material whose surface including the synthetic resin material of the present invention is melted and solidified has a high combustion efficiency due to its high strength when blown into a blast furnace.

【0037】プラスチック等の合成樹脂材を配合して原
料を調製し、このように調製された原料を粒状物に製造
するときに用いるリングダイ式造粒機は、すりつぶし、
および、圧縮押し出し工程を含むものであればよい。例
えば、円周上に多数の穴があいた円筒形のダイリング
と、そして、円筒形のダイリングとの間の摩擦で回転す
る複数のロールからなっており、上述した原料を円筒形
のダイリングと複数のロールとの間ですりつぶし、円筒
形のダイリングの穴から連続的に圧縮押し出されるもの
であればよい。上述したすりつぶし、圧縮押し出しの工
程の間に、圧密され嵩密度が高い中心部材と中心部材を
覆う溶融固化している表面部材とからなる粒状物が製造
される。なお、粒状物の製造に際しては、連続的に圧縮
押し出されたものは所定の長さに切断される。所定の長
さは、40mm以下であり、好ましくは、15mm以下
である。
A ring-die granulator used when a raw material is prepared by blending a synthetic resin material such as plastic, and the raw material thus prepared is manufactured into granules, is ground,
And what is necessary is just to include a compression extrusion process. For example, a cylindrical die ring having a number of holes on its circumference, and a plurality of rolls that rotate due to friction between the cylindrical die ring, the raw material described above is a cylindrical die ring And a plurality of rolls, as long as the material is continuously compressed and extruded from a hole of a cylindrical die ring. During the grinding and compression extrusion steps described above, a granulate is produced comprising a central member that is compacted and of high bulk density and a melt-solidified surface member that covers the central member. In the production of the granular material, the continuously extruded material is cut into a predetermined length. The predetermined length is 40 mm or less, preferably 15 mm or less.

【0038】この発明の合成樹脂材は、紙含有フィルム
状プラスチックを含有するものであってもよい。即ち、
搬送性や流動性が極めて悪く、燃料として用いる際の取
り扱いに大きな問題のあるフィルム状プラスチックだけ
でなく、紙、ダンボール等を含有してもよい。
The synthetic resin material of the present invention may contain a paper-containing film plastic. That is,
It may contain paper, cardboard, and the like, as well as film-like plastic, which has extremely poor transportability and fluidity and has a significant problem in handling when used as a fuel.

【0039】この発明においては、成型粒(粒状物)の
表面が溶融固化していることが必要である。即ち、成型
粒は、圧密され嵩密度が高い中心部材と前記中心部材を
覆う溶融固化している表面部材とからなっていることが
重要である。上述した中心部材の平均嵩密度は、好まし
くは、0.25g/cm3以上である。更に、溶融固化
している表面部材の厚さは、好ましくは、1mm以上で
ある。
In the present invention, it is necessary that the surface of the molded particles (granules) is melted and solidified. That is, it is important that the molded grains include a central member that is compacted and has a high bulk density and a melted and solidified surface member that covers the central member. The above-mentioned center member preferably has an average bulk density of 0.25 g / cm 3 or more. Further, the thickness of the melted and solidified surface member is preferably 1 mm or more.

【0040】この発明においては、成型粒の粒径は40
mm以下、好ましくは、5〜10mmである。
In the present invention, the particle size of the molded particles is 40
mm or less, preferably 5 to 10 mm.

【0041】この発明の合成樹脂材を含む表面が溶融固
化した粒状物は、炉、特に高炉羽口への吹込みに適して
いる。特に、この発明の表面が溶融固化した粒状物は、
気送に際して、粒状物が崩壊することなく、また、熱効
率にも優れている。
The granular material containing the synthetic resin material of the present invention whose surface is melted and solidified is suitable for blowing into a furnace, especially a tuyere of a blast furnace. In particular, the granular material whose surface of the present invention is melted and solidified is
At the time of pneumatic transport, the granular material does not collapse and has excellent thermal efficiency.

【0042】上述したように、この発明の方法による
と、圧密され嵩密度が高い中心部材と中心部材を覆う溶
融固化している表面部材とからなる成型粒が製造され、
高炉等に吹き込まれるので、タンク、配管において詰ま
る原因となるフラフ状異物が生じない。
As described above, according to the method of the present invention, molded particles comprising a central member that is compacted and high in bulk density and a surface member that is melted and solidified and that covers the central member are produced.
Since it is blown into a blast furnace or the like, fluff-like foreign matter that causes clogging in tanks and pipes does not occur.

【0043】図2にこの発明の粒状物の拡大図を示す。
粒状物6は円柱形状からなっており、中心部に紙または
高融点プラスチック等10が圧密された状態で位置し、
その一部10が粒状物の表面に露出している。溶融固化
した表面部材9の厚さ11は1mm以上である。溶融固
化した表面部材が粒状物の表面積の10%以上、好まし
くは50%以上である。
FIG. 2 is an enlarged view of the granular material of the present invention.
The granular material 6 is formed in a cylindrical shape, and a paper or high-melting-point plastic or the like 10 is located at a central portion in a state of being compacted,
A part 10 thereof is exposed on the surface of the granular material. The thickness 11 of the melted and solidified surface member 9 is 1 mm or more. The melted and solidified surface member accounts for at least 10%, preferably at least 50%, of the surface area of the granular material.

【0044】[0044]

【実施例】この発明の方法を、比較例と比較しながら説
明する。先ず、この発明の粒状物と、従来の溶融造粒法
による粒状物を比較した。従来の溶融造粒法、即ち、合
成樹脂類を高速回転する回転刃で裁断または破砕すると
ともに、裁断または破砕による摩擦熱によって合成樹脂
材を半溶融化させ、この半溶融化した合成樹脂材を更に
急冷することによって収縮固化させ、上述した収縮固化
と同時に回転刃によって粉砕処理する方法、によって得
られた粒状物を高炉羽口から吹き込んだところ、粒状物
の強度が小さいために、レースウエイ内に滞留する時間
が極めて短く、燃焼効率が悪かった。これに対して、こ
の発明の合成樹脂材を含む表面が溶融固化した粒状物
は、強度が高いので、レースウエイ内に長時間滞留し、
熱効率が良かった。
The method of the present invention will be described in comparison with a comparative example. First, the granular material of the present invention was compared with a granular material obtained by a conventional melt granulation method. Conventional melt granulation method, that is, synthetic resin is cut or crushed by a rotary blade rotating at high speed, and the synthetic resin material is semi-molten by friction heat due to cutting or crushing, and the semi-melted synthetic resin material is Further, the solidified material is shrunk and solidified by rapid cooling, and the granular material obtained by the method of crushing with a rotary blade at the same time as the shrinking and solidifying described above is blown from a blast furnace tuyere. The residence time was extremely short, and the combustion efficiency was poor. On the other hand, the granular material whose surface including the synthetic resin material of the present invention is melted and solidified has a high strength, and thus stays in the raceway for a long time,
Thermal efficiency was good.

【0045】次に、リングダイ式造粒機によって、製造
したこの発明の粒状物と、この発明の範囲外の粒状物を
比較した。即ち、表1に示すように、融点が50〜30
0℃の範囲内にある成分A(梱包用ポリエチレンフィル
ム破砕屑)、および、その他の非溶融成分B(ダンボー
ル屑)の混合割合を、0/100、3/97、8
/92、10/90、15/85、50/50、
95/5、100/0と変化させて配合して原料を
調製した。
Next, the granules of the present invention produced by a ring die granulator were compared with granules outside the scope of the present invention. That is, as shown in Table 1, the melting point is 50-30.
The mixing ratio of the component A (crushed polyethylene film debris for packing) and the other non-melted component B (cardboard debris) within the range of 0 ° C. is 0/100, 3/97, 8
/ 92, 10/90, 15/85, 50/50,
Raw materials were prepared by changing the ratio to 95/5 and 100/0.

【0046】次いで、このように調製された原料を使用
して、すりつぶし、および、圧縮押し出し工程を含むリ
ングダイ式造粒機によって成型粒(粒状物)を製造し
た。そのときの成型温度は100℃であった。製造され
た成型粒の粒強度(の粒強度を100としたときの強
度を示した)、嵩密度(T/m3)を調査し、その結果
を表1に合わせて示した。成型粒(粒状物)の粒径は、
6mm、長さは10mmであった。更に、溶融固化した
表面部材の厚さは、それぞれ、:0mm、:0.1
mm、:0.5mm、:1.0mm、:1.5m
m、:2.0mm、:2.3mm、:3.0mm
であった。
Next, using the raw materials thus prepared, molded granules (granules) were produced by a ring die granulator including grinding and compression extrusion steps. The molding temperature at that time was 100 ° C. The grain strength (the strength when the grain strength was taken as 100) and the bulk density (T / m 3 ) of the produced molded grains were examined. The results are shown in Table 1. The particle size of the molded particles (granules)
The length was 6 mm and the length was 10 mm. Further, the thicknesses of the melted and solidified surface members are respectively: 0 mm,: 0.1
mm,: 0.5mm,: 1.0mm,: 1.5m
m, 2.0 mm, 2.3 mm, 3.0 mm
Met.

【0047】このように製造した成型粒を、気送供給設
備を経て、操業中の高炉羽口から吹き込んで設備内の詰
まり等のトラブルの発生状況を調べた。 (a)即ち、貯留サイロに装入された上述した成型粒を
サイロから定量的に切出し、これを気送供給設備まで移
送し、気送供給設備から下記条件で高炉羽口部に成型粒
を気送し、炉内に吹き込んだ。 気送ガス:空気 気送ガス吹込み量:1200Nm3/hr 成型粒の吹込み量:62.5kg/min 固気比:2.4kg/kg
The molded particles produced in this way were blown from the tuyere during operation through a pneumatic supply facility, and the occurrence of troubles such as clogging in the facility was examined. (A) That is, the above-mentioned formed granules charged in the storage silo are quantitatively cut out from the silo, transferred to a pneumatic supply facility, and the formed granules are transferred from the pneumatic supply facility to the tuyere of the blast furnace under the following conditions. Pneumatically blown into the furnace. Pneumatic gas: air Pneumatic gas blowing amount: 1200 Nm 3 / hr Blowing amount of molded particles: 62.5 kg / min Solid-gas ratio: 2.4 kg / kg

【0048】(b)このときの高炉操業条件は次の通り
であった。 出銑量:9000t/日 送風量:7260Nm3/hr 酸素富化率:4% 送風温度:1200℃ コークス比:447kg/t.pig 微粉炭吹込み量:100kg/t.pig 成型粒の吹込み量:10kg/t.pig 上述した成型粒の炉内吹込みを2日間実施した。
(B) The blast furnace operating conditions at this time were as follows. Tapping rate: 9000 t / day Blast rate: 7260 Nm 3 / hr Oxygen enrichment rate: 4% Blast temperature: 1200 ° C. Coke ratio: 447 kg / t. pig Pulverized coal injection amount: 100 kg / t. pig Injection of molded particles: 10 kg / t. pig Injection of the above-mentioned shaped particles in the furnace was performed for 2 days.

【0049】その結果、融点が50〜300℃の範囲内
にある成分A(梱包用ポリエチレンフィルム破砕屑)を
含まないの成型粒を使用したときは、嵩密度は0.7
9と高いものの、粒強度が25と低く、1時間の間に1
回以上詰まりが生じた。融点が50〜300℃の範囲内
にある成分A(梱包用ポリエチレンフィルム破砕屑)を
3%含有するの成型粒を使用したときにおいても、粒
強度は35と低く、6時間の間に1回以上の詰まりが生
じた。更に、融点が50〜300℃の範囲内にある成分
A(梱包用ポリエチレンフィルム破砕屑)を8%含有す
るの成型粒を使用したときにおいても、粒強度は60
と低く、12時間の間に1回以上の詰まりが生じた。上
述した〜の成型粒においては、溶融固化した表面部
材の厚さが1mm未満であった。
As a result, when molded grains containing no component A (crushed polyethylene film for packing) having a melting point in the range of 50 to 300 ° C. were used, the bulk density was 0.7%.
Grain strength is as low as 25, but high as 9
More than one clogging occurred. Even when molded grains containing 3% of component A (crushed polyethylene film for packing) having a melting point in the range of 50 to 300 ° C are used, the grain strength is as low as 35, and once every 6 hours. The above clogging occurred. Further, even when a molded particle containing 8% of the component A (crushed polyethylene film for packaging) having a melting point in the range of 50 to 300 ° C. is used, the particle strength is still 60%.
And clogging occurred one or more times in 12 hours. In the above-described molded particles, the thickness of the melted and solidified surface member was less than 1 mm.

【0050】これに対して、融点が50〜300℃の範
囲内にある成分A(梱包用ポリエチレンフィルム破砕
屑)を、本発明の範囲の下限値である10%含有する
を使用したときには、粒強度が75と比較的強くなり、
詰まりは12時間の間に1回以下と低くなった。融点が
50〜300℃の範囲内にある成分A(梱包用ポリエチ
レンフィルム破砕屑)を15%含有するを使用したと
きには、粒強度が80と強くなり、詰まりは1日の間に
1回以下と低くなった。融点が50〜300℃の範囲内
にある成分A(梱包用ポリエチレンフィルム破砕屑)を
50%含有するを使用したときには、粒強度は90と
強くなり、詰まりは2日間の間に1回以下と極めて少な
かった。また、高炉の操業自体にも全く支障は生じなか
った。融点が50〜300℃の範囲内にある成分A(梱
包用ポリエチレンフィルム破砕屑)を95%含有する
を使用したときには、粒強度は98と更に強くなり、詰
まりは2日間の間に1回以下と極めて少なかった。ま
た、高炉の操業自体にも全く支障は生じなかった。更
に、融点が50〜300℃の範囲内にある成分A(梱包
用ポリエチレンフィルム破砕屑)を100%含有する
を使用したときには、粒強度は100であり、詰まりは
2日間の間に1回以下と極めて少なかった。なお、嵩密
度は、0.30、0.33の場合においても、融点に関
する条件をみたす限り、詰まりを生じる回数は極めて少
なかった。
On the other hand, when 10%, which is the lower limit of the range of the present invention, of component A (crushed polyethylene film for packing) having a melting point in the range of 50 to 300 ° C. The strength is relatively strong at 75,
The clogging was reduced to less than once within 12 hours. When 15% of component A (crushed polyethylene film for packing) having a melting point in the range of 50 to 300 ° C. is used, the grain strength becomes as high as 80, and the clogging is reduced to once or less in one day. Got lower. When 50% of the component A (crushed polyethylene film for packing) having a melting point in the range of 50 to 300 ° C. is used, the grain strength becomes as high as 90, and the clogging is reduced to once or less within two days. Very few. The operation of the blast furnace itself was not affected at all. When 95% of component A (crushed polyethylene film for packaging) having a melting point in the range of 50 to 300 ° C. is used, the grain strength is further increased to 98, and clogging is not more than once in two days. And very few. The operation of the blast furnace itself was not affected at all. Furthermore, when 100% of the component A (crushed polyethylene film for packing) having a melting point in the range of 50 to 300 ° C. is used, the grain strength is 100, and clogging is not more than once in two days. And very few. In addition, even when the bulk density was 0.30 or 0.33, the number of times of clogging was extremely small as long as the conditions regarding the melting point were satisfied.

【0051】上述したところから明らかなように、詰ま
りの生じる頻度は、融点が50〜300℃の範囲内にあ
る成分Aの含有量によって大きく影響を受ける。
As is clear from the above description, the frequency of clogging is greatly affected by the content of the component A having a melting point in the range of 50 to 300 ° C.

【0052】[0052]

【発明の効果】上述したように、この発明の合成樹脂材
を含む表面が溶融固化した粒状物、その製造方法および
粒状物の炉への吹き込み方法によると、プラスチック等
の合成樹脂類をその形態に拘わりなく高炉等の吹込み燃
料として供給することができ、このため廃棄物たる合成
樹脂類の大量処理と有効利用をはかることができる。ま
た、高炉等の燃料コストを大幅に低減させることができ
る。更に、高炉吹込み時に、タンク、配管で詰まる原因
となるフラフ状異物を発生させないので、炉に供給され
る合成樹脂類の流動性や搬送性および燃焼性を効果的に
高めることができ、高炉等において炉の操業に支障を来
すこと無く合成樹脂材を燃料として炉内に適切に供給す
ることができる。
As described above, according to the method of the present invention for producing a granular material containing a synthetic resin material whose surface has been melted and solidified, a method for producing the granular material, and a method for blowing the granular material into a furnace, plastics and other synthetic resins are used in the form thereof. Regardless of the above, the fuel can be supplied as blown fuel for a blast furnace or the like, so that a large amount of waste synthetic resin can be treated and effectively used. Further, the fuel cost of a blast furnace or the like can be significantly reduced. Furthermore, when blowing into the blast furnace, fluff-like foreign substances that cause clogging in tanks and pipes are not generated, so that the fluidity, transportability and combustibility of the synthetic resin supplied to the furnace can be effectively improved, and In such cases, the synthetic resin material can be appropriately supplied into the furnace as fuel without hindering the operation of the furnace.

【図面の簡単な説明】[Brief description of the drawings]

【図1】図1は、本発明の方法の概要を示す図である。FIG. 1 is a diagram showing an outline of a method of the present invention.

【図2】図2は、本発明の粒状物の拡大図である。FIG. 2 is an enlarged view of the granular material of the present invention.

【図3】図3は、原料混合比別の吹込みトラブル、成型
粒の性状を示す表1である。
FIG. 3 is a table 1 showing a blowing trouble and a property of a molded particle according to a raw material mixing ratio.

【符号の説明】[Explanation of symbols]

1.ダンボール 2.フィルム状プラスチック 3.ダンボール屑 4.フィルム状プラスチック片 5.リングダイ式造粒機 6.粒状物 7.ロール 8.円筒形のダイリング 9.成型粒の溶融固化した表面 10.圧縮成型された中心部材 11.溶融固化した表面部材の厚さ 1. Cardboard 2. 2. film plastic Cardboard waste 4. 4. Film-shaped plastic pieces Ring die granulator 6. Granules 7. Roll 8. 8. Cylindrical die ring 9. Melted solidified surface of molded particles 10. Compression molded center member Thickness of melt-solidified surface member

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI // F23G 7/12 ZAB F23G 7/12 ZABZ (72)発明者 寺田 周雄 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (72)発明者 根本 謙一 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (72)発明者 丹下 邦彦 東京都千代田区丸の内一丁目1番2号 日本鋼管株式会社内 (56)参考文献 特開 平10−130422(JP,A) 特開 昭62−591(JP,A) 特開 平2−160088(JP,A) 特開 平9−137926(JP,A) 特開 平10−102110(JP,A) 特開 昭60−235632(JP,A) (58)調査した分野(Int.Cl.7,DB名) C08J 3/12 - 3/16 C10L 5/48 C21B 5/00 F23K 3/02 F23G 7/12 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI // F23G 7/12 ZAB F23G 7/12 ZABZ (72) Inventor Shuo Terada 1-2-1 Marunouchi, Chiyoda-ku, Tokyo Nippon Kokan Inside (72) Inventor Kenichi Nemoto 1-2-1, Marunouchi, Chiyoda-ku, Tokyo Nippon Kokan Co., Ltd. (72) Inventor Kunihiko Tange 1-2-1, Marunouchi, Chiyoda-ku, Tokyo Nippon Kokan Co., Ltd. ( 56) References JP-A-10-130422 (JP, A) JP-A-62-591 (JP, A) JP-A-2-160088 (JP, A) JP-A-9-137926 (JP, A) Hei 10-102110 (JP, A) JP-A-60-235632 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C08J 3/12-3/16 C10L 5/48 C21B 5 / 00 F23K 3/02 F23G 7/12

Claims (15)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 合成樹脂材を含み、圧密され嵩密度が高
い中心部材と前記中心部材を覆う溶融固化している表面
部材とからなり、多数の穴があいた円筒形のダイリング
の穴から圧縮押し出されて製造されることを特徴とする
高炉吹込み用粒状物
1. A material containing a synthetic resin material, which is compacted and has a high bulk density.
A central member and a melt-solidified surface covering the central member
Cylindrical die ring with many holes
Characterized by being manufactured by compression extrusion through holes
Granules for blast furnace injection .
【請求項2】 前記高炉吹込み用粒状物は、50〜30
0℃の範囲内の融点を有する成分を10%以上含有して
いることを特徴とする請求項1に記載の高炉吹込み用粒
状物
2. The blast furnace blowing granules are preferably 50 to 30.
Containing at least 10% of a component having a melting point in the range of 0 ° C.
The blast furnace injection particles according to claim 1, wherein
Stuff
【請求項3】 前記合成樹脂材は、紙含有フィルム状プ
ラスチックを含有することを特徴とする請求項1または
2に記載の高炉吹込み用粒状物
3. The synthetic resin material is a paper-containing film-like plastic.
The composition according to claim 1, wherein the composition contains a plastic.
3. Granules for blast furnace injection according to 2 .
【請求項4】 前記高炉吹込み用粒状物の粒径が40m
m以下であることを特徴とする請求項1から3のうちの
何れか1つに記載の高炉吹込み用粒状物
4. A particle size of the granulated particles for blowing into a blast furnace is 40 m.
m or less.
The granules for blowing into a blast furnace according to any one of the above .
【請求項5】 前記合成樹脂材は、廃棄プラスチックで
あることを特徴とする請求項1から4のうちの何れか1
つに記載の高炉吹込み用粒状物。
5. The synthetic resin material is a waste plastic.
5. The method as claimed in claim 1, wherein:
4. A granulated product for blast furnace injection according to any one of the above.
【請求項6】 合成樹脂材を含み、圧密され嵩密度が高
い中心部材と前記中心部材を覆う溶融固化している表面
部材とからなり、多数の穴があいた円筒形のダイリング
の穴から圧縮押し出されて製造される粒状物を気送し
て、高炉に吹き込むことを特徴とする粒状物の高炉吹込
み方法。
6. A material containing a synthetic resin material, which is compacted and has a high bulk density.
A central member and a melt-solidified surface covering the central member
Cylindrical die ring with many holes
Pneumatically extruded granules produced by compression extrusion through holes
Blast furnace, characterized by being blown into the blast furnace
Only way.
【請求項7】 前記粒状物は、50〜300℃の範囲内
の融点を有する成分を10%以上含有していることを特
徴とする請求項6に記載の高炉吹込み方法
7. The method according to claim 1, wherein the granular material is in the range of 50 to 300 ° C.
Containing at least 10% of a component having a melting point of
The blast furnace blowing method according to claim 6, which is characterized in that:
【請求項8】 前記合成樹脂材は、紙含有フィルム状プ
ラスチックを含有することを特徴とする請求項6または
7に記載の粒状物の高炉吹込み方法
8. A paper-containing film-shaped plastic resin.
7. The composition according to claim 6, which contains a plastic.
8. A method for blowing blast furnace into particulate matter according to 7 .
【請求項9】 前記粒状物の粒径が40mm以下である
ことを特徴とする請求項6から8のうちの何れか1つに
記載の粒状物の高炉吹込み方法。
9. The particle size of the granular material is 40 mm or less.
The method according to any one of claims 6 to 8, wherein
A blast furnace blowing method for the particulate matter described in the above.
【請求項10】 前記合成樹脂材は、廃棄プラスチック
であることを特徴とする請求項6から9のうちの何れか
1つに記載の高炉吹込み方法。
10. The synthetic resin material is a waste plastic.
10. The method according to claim 6, wherein:
The blast furnace blowing method according to one of the above.
【請求項11】 合成樹脂材を含む原料を、リングダイ
式造粒機を用いて、多数の穴があいた円筒形のダイリン
グの穴から圧縮押し出し、圧密され嵩密度が高い中心部
材と前記中心部材を覆う溶融固化している表面部材とか
らなる粒状物を 製造することを特徴とする高炉吹込み用
粒状物の製造方法。
11. A raw material containing a synthetic resin material is supplied to a ring die.
Cylindrical dielin with many holes using a granulator
The center part is compressed and extruded from the hole of
Such as surface material that has been melted and solidified to cover the material and the central member
For blast furnace injection, characterized by producing granular materials consisting of
A method for producing a granular material.
【請求項12】 前記原料は、50〜300℃の範囲内
の融点を有する成分を10%以上含有していることを特
徴とする請求項11に記載の高炉吹込み用粒状物の製造
方法。
12. The method according to claim 11, wherein said raw material is in the range of 50 to 300 ° C.
Containing at least 10% of a component having a melting point of
Production of granules for blast furnace injection according to claim 11
Method.
【請求項13】 前記合成樹脂材は、紙含有フィルム状
プラスチックを含有することを特徴とする請求項11ま
たは12に記載の高炉吹込み用粒状物の製造方法
13. The synthetic resin material is in the form of a paper-containing film.
12. The composition according to claim 11, further comprising a plastic.
13. The method for producing granulated material for blast furnace blowing according to item 12 .
【請求項14】 前記粒状物の粒径が40mm以下であ
ることを特徴とする請求項11から13のうちの何れか
1つに記載の高炉吹込み用粒状物の製造方法。
14. A particle having a particle size of 40 mm or less.
14. The method according to claim 11, wherein:
A method for producing a granulated material for blast furnace injection according to one of the above aspects.
【請求項15】 前記リングダイ式造粒機は、円周上に
多数の穴があいた円筒形のダイリングと、そして、円筒
形のダイリングとの間の摩擦で回転する複数のロールか
らなっており、前記粒状物は、前記原料を円筒形のダイ
リングと複数のロールとの間ですりつぶされ、円筒形の
ダイリングの穴から連続的に圧縮押し出され、所定の長
さで切断されて製造されることを特徴とする請求項11
に記載の高炉吹込み用粒状物の製造方法
15. The ring die granulator is arranged on a circumference.
Cylindrical die ring with many holes and cylindrical
Multiple rolls rotating due to friction between the shape die ring
The granular material is obtained by converting the raw material into a cylindrical die.
Grinding between the ring and the rolls, the cylindrical
It is continuously compressed and extruded from the hole of the die ring,
12. The semiconductor device according to claim 11, which is manufactured by being cut at a distance.
2. The method for producing granulated material for blowing into a blast furnace according to item 1 .
JP31301699A 1998-11-05 1999-11-02 Granular material containing synthetic resin material, method for producing the same, and method for blowing granular material into furnace Expired - Fee Related JP3233141B2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP31301699A JP3233141B2 (en) 1998-11-05 1999-11-02 Granular material containing synthetic resin material, method for producing the same, and method for blowing granular material into furnace
TW89110542A TW445202B (en) 1999-11-02 2000-05-31 Molded lump and its production method thereof
PCT/JP2000/003757 WO2001032383A1 (en) 1999-11-02 2000-06-09 Molded lump and production method therefor
EP20000935609 EP1236790A1 (en) 1999-11-02 2000-06-09 Molded lump and production method therefor
CNB00815001XA CN1317116C (en) 1999-11-02 2000-06-09 Molded lump and production method therefor
KR10-2002-7004786A KR100478570B1 (en) 1999-11-02 2000-06-09 Molded lump and production method therefor
US10/132,831 US20030021991A1 (en) 1999-11-02 2002-04-25 Pellets and method for producing the same

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP10-314648 1998-11-05
JP31464898 1998-11-05
JP31301699A JP3233141B2 (en) 1998-11-05 1999-11-02 Granular material containing synthetic resin material, method for producing the same, and method for blowing granular material into furnace

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JP3733045B2 (en) * 2001-09-21 2006-01-11 新日本製鐵株式会社 Method for producing waste plastic granulated product and thermal decomposition method thereof
JP4732740B2 (en) * 2003-11-27 2011-07-27 Jfeスチール株式会社 Method of blowing used plastic into furnace, used plastic particles for blowing furnace, and method for producing the same
JP4608899B2 (en) * 2004-02-05 2011-01-12 Jfeスチール株式会社 Method of blowing used plastic into the furnace
JP2012219239A (en) * 2011-04-13 2012-11-12 Sagan:Kk Manufacturing technique of solid fuel by which stabilization of initial fire power, stabilization of burning characteristic and stabilization of property during manufacture or during storage are enabled by impregnation coating of outer periphery of conventional solid fuel with waste plastic
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