JP3220657B2 - Sunscreen cosmetics - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to sunscreen cosmetics. More specifically, the present invention relates to a sunscreen cosmetic composition which comprises a specific ester compound and an ultraviolet absorber, protects the skin from ultraviolet rays, suppresses the occurrence of inflammation of the skin due to the ultraviolet rays, and is excellent in a feeling of use.

[0002]

2. Description of the Related Art Many people want to tan their skin brown or tan to express their health and beauty, or especially for young people who are conscious of fashion. Exposure of skin under intense sunlight.

On the other hand, in recent years, awareness of protecting the skin from ultraviolet rays has increased, and in order to protect the skin from ultraviolet rays that cause blisters, erythema and the like, an ultraviolet absorber is added to the cosmetic to absorb the ultraviolet rays. And sunscreen cosmetics containing a powder having ultraviolet scattering ability have been developed.

[0004] However, not only those who are sensitive to ultraviolet light and those who have not exposed their skin to sunlight for a long time,
In order for healthy people to enjoy a proper sunburn in intense sunlight in the middle of summer, it is necessary to incorporate a large amount of an ultraviolet absorber into sunscreen cosmetics.

[0005]

However, there is a problem that it is difficult to highly blend an ultraviolet absorber in oil or the like due to its polarity.

The present inventors have conducted intensive studies to solve the above problems, and as a result, when a specific ester compound is added to a sunscreen cosmetic containing an ultraviolet absorber, a highly polar ultraviolet absorber can be stabilized. To protect the skin from ultraviolet rays, suppress the occurrence of inflammation of the skin due to ultraviolet rays, and find that a sunscreen cosmetic with an excellent feeling in use can be obtained, leading to the completion of the present invention. .

The present invention can stably and highly blend a highly polar ultraviolet absorber, protects the skin from ultraviolet rays, suppresses the occurrence of skin inflammation due to ultraviolet rays, and has a superior feeling in use as compared with conventional sunscreen cosmetics. It aims to provide a new sunscreen cosmetic.

[0008]

That is, the present invention relates to an ester compound obtained by esterifying the following components (1), (2) and (3) (provided that glycerin and C1
A sunscreen cosmetic comprising a fatty acid having 4 or more fatty acids and a compound obtained by esterifying a dicarboxylic acid having up to 12 carbon atoms), and an ultraviolet absorber. (1) glycerin, trimethylolpropane, pentae
Rislit, glycerin condensate, sorbit, trimethyl
Any polyhydric alcohol of roll ethane (2) straight chain fatty acids having 8 to 30 carbon atoms , branched fatty acids,
Saturated fatty acid or hydroxy fatty acid (3) linear or branched dicarboxylic acid having 12 to 30 carbon atoms
acid

Further, the present invention provides the above-mentioned ester compound,
It is an ester compound obtained by esterifying glycerin, behenic acid and eicosane diacid, and provides the above-mentioned sunscreen cosmetic.

Further, in the present invention, the sunscreen cosmetic is a water-in-oil emulsion composition.
Or the sunscreen cosmetic according to 2.

[0011]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.

The ester compound used in the present invention comprises a polyhydric alcohol, a linear, branched, unsaturated or hydroxy fatty acid having 8 to 30 carbon atoms and a linear or branched dibasic acid having 12 to 30 carbon atoms. The resulting ester compound is obtained by charging these components at an arbitrary ratio and esterifying the mixture by a known method. This ester compound has a function of gelling highly polar oil, and this function makes it possible to stably blend a highly polar ultraviolet absorber.

Examples of the polyhydric alcohol include glycerin, trimethylolpropane, pentaerythritol,
Glycerin condensate, sorbit, trimethylolethane, and the like are included.

Examples of the straight, branched, unsaturated or hydroxy fatty acid having 8 to 30 carbon atoms include caprylic acid,
Lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, cerotic acid, montanic acid, melicic acid,
Examples include isostearic acid, oleic acid, 2-ethylhexanoic acid, 12-hydroxystearic acid, and the like.

The linear or branched dibasic acids having 12 to 30 carbon atoms include dodecane diacid, eicosane diacid, 1-,
10-decamethylene diacid, 1-, 12-dodecamethylene diacid, 1-, 15-pentadecamethylene diacid, 1-, 2
8-octacosamethylene diacid, 7-ethyloctadecane diacid, and the like.

In the present invention, glycerin-behenic acid eicosandicarboxylic acid, an ester compound obtained by esterifying glycerin with behenic acid and eicosane diacid, is particularly preferably used in terms of usability and stability over time. Glycerin behenic acid eicosane dicarboxylic acid is mixed with glycerin, behenic acid and eicosane diacid at an optional charge ratio and esterified, thereby giving various glycerin units, behenic acid units and eicosane diacid units. It is obtained in the form of a mixture of ester compounds.

The amount of the ester compound in the present invention is 0.1 to 20% by weight, preferably 0.5 to 5% by weight based on the total amount of the sunscreen cosmetic. If the amount is less than 0.1% by weight, there is a problem in stability at high temperatures, and if it exceeds 20% by weight, it becomes too hard to use.

The UV absorber used in the present invention may be any UV absorber conventionally used in cosmetics, and may include, for example, the following UV absorbers. (A) Benzoic acid-based ultraviolet absorber para-aminobenzoic acid (hereinafter abbreviated as PABA), PABA
Monoglycerin ester, N, N-dipropoxy PAB
A ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N
-Dimethyl PABA butyl ester, N, N-dimethyl PABA amyl ester, N, N-dimethyl PABA octyl ester (b) anthranilic acid-based ultraviolet absorber homomenthyl-N-acetylanthranilate (c) salicylic acid-based ultraviolet absorber amyl salicylate Menthyl salicylate, homomethyl salicylate, octyl salicylate, phenyl salicylate, benzal salicylate, p-isopropanol phenyl salicylate (d) cinnamic acid ultraviolet absorber octylcinnamate, ethyl-4-isopropylcinnamate, methyl-2,5- Diisopropyl cinnamate, ethyl 2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl
p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate Mate, cyclohexyl-
p-methoxycinnamate, ethyl-α-cyano-β-
Phenylcinnamate, 2-ethoxyethyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-
Ethylhexanoyl-diparamethoxycinnamate (E) benzophenone ultraviolet absorber 2,4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone ,
2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone,
-Hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-
5-sulfonate, 4-phenylbezophenone, 2-ethylhexyne-4′-phenyl-benzophenone-2-
Carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone (f) Silicone cinnamic acid derivative UV absorber Siloxane having at least one unit represented by the following Chemical Formula 1 Wherein the other units which may be present in the siloxanes are represented by the formula (2):

Embedded image

Embedded image (In the “Chemical Formula 1” and “Chemical Formula 2”, R 1 has 1 to 4 carbon atoms.
R2 is a divalent hydrocarbon group having at least 2 carbon atoms, n is an integer of 0 to 3, a is an integer of 2 or 3, R3 is an alkyl group of 1 to 4 carbon atoms Or, a phenyl group, m represents an integer of 0 to 3. (G) Other ultraviolet absorbers 3- (4'methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor, urocanic acid, urocanic acid ethyl ester, 2-phenyl-5
-Methylbenzoxazal, 2,2'-hydroxy-5
-Methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2- (2'-hydroxy-5'-methylphenyl) benzotriazole, dibenzarazin, dianisylmethane, 4- Methoxy-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one

As the ultraviolet absorber used in the present invention, for example, one or more of the above ultraviolet absorbers are selected and blended. The amount is not particularly limited, and is usually 0.05 to 30% by weight, preferably 0.1 to 20% by weight based on the sunscreen cosmetic. % Is particularly useful when the content is high.

In the sunscreen cosmetic of the present invention, in addition to the essential components described above, other components usually used in external preparations such as cosmetics and pharmaceuticals, such as oils and humectants, as long as the effects of the present invention are not impaired. , Antioxidants, surfactants, preservatives,
A humectant, an amino acid, a fragrance, water, alcohol, a thickener, a coloring agent, a powder, a drug, and the like can be appropriately compounded as needed.

The sunscreen cosmetic of the present invention may have any dosage form, but the ester compound as an essential component can be stably blended by gelling a highly polar ultraviolet absorber and its usability. In view of the above, a water-in-oil emulsion composition is preferred, and a sunscreen cosmetic in the form of a cream or an emulsion is particularly preferred.

[0022]

Next, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto. The compounding amount is% by weight.

"Examples 1 to 6", "Comparative Examples 1 to 3" Examples 1 to 6 in which an ester compound and an ultraviolet absorber as essential components were blended, and only the ester compound were not blended according to the formulations shown in Table 2. The creams of Comparative Examples 1 to 3 having the same formulation were prepared by the following production method, and effect tests shown below were performed. The test results are shown in “Table 3” and “Table 4”.

<Production method> 1) to 7) are mixed, heated and dissolved, and kept at 70 ° C. to obtain an oil phase. Separately, 8) to 13) are heated and dissolved to obtain an aqueous phase. The aqueous phase is added to the oil phase and sufficiently emulsified by an emulsifier. After the emulsification, the mixture was cooled while being stirred, and when the temperature became 35 ° C. or lower, the mixture was poured into a container and allowed to cool to solidify, thereby obtaining a cream.

The ester compound used in the examples was
It is a mixture of glycerin behenic acid eicosane dicarboxylic acid obtained by esterifying glycerin, behenic acid and eicosane diacid at a charging ratio of glycerin: behenic acid: eicosane diacid = 10: 15: 7.

The evaluation items and evaluation criteria for the effect test are as follows. <Stability evaluation test> Each cream was prepared at -10 ° C, 0 ° C,
Store in a thermostat at 5 ℃ and 40 ℃ for 3 months, color, smell,
Changes in appearance properties and feeling of use were evaluated according to the following criteria. [Evaluation Criteria] A: There is no change in any of the color tone, odor, appearance properties and feeling of use. X: Change was seen in any of color tone, smell, appearance properties, and feeling of use.

<Sensory Evaluation Test of Usability> Ten creams were used by 10 panelists, and the moistness, body, smoothness and stickiness were evaluated according to the following criteria.

[Table 1] [Evaluation points] ------------------------------------------ --------------- Usability Somewhat no ------------------ ---------------------------- Moistness 2 1 0 Body 2 1 0 Smoothness 2 1 0 Sticky 0 1 2 ---- -------------------------------------------------- --- [Evaluation criteria] ○: Average of evaluation points 1.5 or more △: Average of evaluation points 0.5 or more and less than 1.5 ×: Average of evaluation points less than 0.5

<Ultraviolet Absorbing Effect> A practical use test on the beach was conducted using Example 6 in which the ultraviolet absorber was stably added in a high amount and Comparative Example 1 in which there was no problem in stability. went. The test method was to divide the backs of the 10 panelists in half, apply an appropriate amount of the cream of Example 6 to one, and apply the same amount of the cream of Comparative Example 1 to the other, and then exposed to the sun outdoors for 6 hours. The degree of sunburn was evaluated according to the following criteria. ：: Almost no sunburn symptoms were observed. Δ: Mild sunburn symptom was observed. X: Strong sunburn symptoms were observed.

[0029]

[Table 2]

[0030]

[Table 3]

[0031]

[Table 4]

From Tables 3 and 4, it can be seen that the creams of the examples, which are the sunscreen cosmetics of the present invention, are much more stable than the creams of the comparative examples in terms of stability, usability and ultraviolet absorption effect. It turns out that it is excellent.

[0033]

Industrial Applicability According to the present invention, a sunscreen cosmetic which can stably contain a highly polar ultraviolet absorber, protects the skin from ultraviolet rays, suppresses the occurrence of inflammation of the skin due to ultraviolet rays, and is excellent in use feeling. Can be provided.

────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Tomiyuki Namba 1050 Nippa-cho, Kohoku-ku, Yokohama-shi, Kanagawa Prefecture Shiseido First Research Center Co., Ltd. (56) References JP-A-10-175819 (JP, A) JP-A-56-104807 (JP, A) JP-A-59-27807 (JP, A) JP-A-59-62511 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) A61K7 / 00-7/50 CA (STN) REGISTRY (STN)

Claims (3)

(57) [Claims] An ester compound obtained by esterifying the following components (1), (2) and (3), wherein glycerin, a fatty acid having 14 or more carbon atoms, and a dicarboxylic acid having up to 12 carbon atoms are esterified. And a UV absorber. (1) glycerin, trimethylolpropane, pentae
Rislit, glycerin condensate, sorbit, trimethyl
Any polyhydric alcohol of roll ethane (2) straight chain fatty acids having 8 to 30 carbon atoms , branched fatty acids,
Saturated fatty acid or hydroxy fatty acid (3) linear or branched dicarboxylic acid having 12 to 30 carbon atoms
acid 2. The sunscreen cosmetic according to claim 1, wherein the ester compound is an ester compound obtained by esterifying glycerin with behenic acid and eicosane diacid. 3. The sunscreen cosmetic according to claim 1, wherein the sunscreen cosmetic is a water-in-oil emulsion composition.