JP3212002B2 - Low-nitrogen oxide alternating combustion method - Google Patents

Low-nitrogen oxide alternating combustion method

Info

Publication number
JP3212002B2
JP3212002B2 JP28123393A JP28123393A JP3212002B2 JP 3212002 B2 JP3212002 B2 JP 3212002B2 JP 28123393 A JP28123393 A JP 28123393A JP 28123393 A JP28123393 A JP 28123393A JP 3212002 B2 JP3212002 B2 JP 3212002B2
Authority
JP
Japan
Prior art keywords
combustion
fuel gas
heat storage
storage layer
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP28123393A
Other languages
Japanese (ja)
Other versions
JPH07133906A (en
Inventor
省 安岡
直人 斉木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Gas Co Ltd
Original Assignee
Tokyo Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Gas Co Ltd filed Critical Tokyo Gas Co Ltd
Priority to JP28123393A priority Critical patent/JP3212002B2/en
Publication of JPH07133906A publication Critical patent/JPH07133906A/en
Application granted granted Critical
Publication of JP3212002B2 publication Critical patent/JP3212002B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は窒素酸化物低発生交番燃
焼方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an alternating combustion method for producing low nitrogen oxides.

【0002】[0002]

【従来技術】蓄熱層を有する二ツのバーナ部を一組とし
て、交互に切換燃焼させる交番燃焼バーナは、一方が燃
焼した排ガスの顕熱を、他方の蓄熱層が回収し、次にそ
の蓄熱層を通過する燃焼用空気が回収された熱によって
充分に予熱されることで、間接式熱交換装置と比較して
高い予熱空気が得られ、非常に高いエネルギ効率が得ら
れる。
2. Description of the Related Art An alternating combustion burner in which two burners having a heat storage layer are alternately burned as a set is used. When the combustion air passing through the bed is sufficiently preheated by the recovered heat, higher preheated air is obtained as compared with the indirect heat exchanger, and very high energy efficiency is obtained.

【0003】[0003]

【発明が解決しようとする課題】前記した交番燃焼バー
ナに於ける燃焼法は、予熱空気温度が高く窒素酸化物
(NOx)の濃度が高くなる課題がある。これを解決す
るために、排ガス再循環法がある。かかる排ガス再循環
方法は、排ガスを強制的に空気導入部又は燃焼部に導入
して窒素分圧を低下させて燃焼させるが、これらは排ガ
ス導入のための諸設備が必然的になる上、再循環率が上
がるにつれて熱効率が低下するため、これの低下を防ぐ
ために、今度は再循環率制御が必要となるなどの様々の
課題がある。
The combustion method in the alternating combustion burner described above has a problem that the preheated air temperature is high and the concentration of nitrogen oxide (NOx) is high. To solve this, there is an exhaust gas recirculation method. Such exhaust gas recirculation method is to burn the exhaust gas forcibly lower the nitrogen partial pressure was introduced <br/> the air introducing portion or combustion part, these various facilities inevitably for exhaust gas introducing In addition, since the thermal efficiency decreases as the recirculation rate increases, there are various problems such as the necessity of controlling the recirculation rate in order to prevent the thermal efficiency from decreasing.

【0004】[0004]

【課題を解決するための手段】前記した課題を解決する
ために、本発明は、蓄熱層を有する二ツのバーナ部を一
組として交互に切換燃焼させる交番燃焼バーナの前記各
バーナ部の蓄熱層に、燃焼に供する燃料ガスのうちの一
部の燃料ガスを導入するための燃料ガス混入装置を装置
し、前記蓄熱層から炉内に至る燃焼ガス案内部に残余の
燃料ガスを導入するための残余燃料ガス噴出部を設け
燃料ガス混入装置から加熱状態下の蓄熱層内に全燃焼
量の10〜25%の燃料ガスを混入して、前記蓄熱層内
に流入してくる燃焼用空気と蓄熱希薄燃焼反応を生じさ
せた後、残余の燃料ガスを前記燃焼ガス案内部における
残余燃料ガス噴出部を介して燃焼ガス案内部に導入し
て、前記蓄熱希薄燃焼による燃焼ガスと残余燃料ガスと
混合させて燃焼を完結するようにしたことを特徴とする
ものである。
SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention provides a method of storing heat in each of the burners of an alternating combustion burner in which two burners having a heat storage layer are alternately switched and burned as a set. The layer contains one of the fuel gases
A fuel gas mixing device for introducing the fuel gas into the combustion gas guide section from the heat storage layer to the inside of the furnace.
Providing a residual fuel gas ejection part for introducing fuel gas ,
By mixing a 10% to 25% of the fuel gas of the total combustion amount in the heat storage layer under heating conditions from the fuel gas introducing device, cause heat accumulation lean combustion reaction and combustion air come to flow into the heat storage layer After that, the remaining fuel gas in the combustion gas guide section
The fuel gas is introduced into the combustion gas guide via the residual fuel gas ejection part, and the combustion gas and the residual fuel gas from the heat storage lean combustion are used.
It is characterized in that combustion is completed by mixing .

【0005】また、本発明は、燃料ガス混入装置を、加
熱下の蓄熱層に於いて温度の低い位置に設けて燃料ガス
を導入させることを特徴とするものである。
[0005] Further, the present invention provides a fuel gas mixing device,
The fuel gas is installed at a low temperature in the heat storage layer under heat.
Is introduced .

【0006】[0006]

【作用】加熱された蓄熱層に、その下部から燃焼用空気
が導入されると同時に燃焼に供する全燃料ガスのうちの
例えば10%が導入されると、燃料ガスと空気は良好に
混合しながら上昇し、700℃付近の高温部で蓄熱希薄
燃焼反応が開始する。発生した燃焼ガスは、蓄熱層から
炉内に至る燃焼ガス案内部に設置した残余燃料ガス噴出
部から噴出する残余燃料ガスと良好に混合燃焼しつつ炉
内に導入され燃焼を完結する。
When the combustion air is introduced into the heated heat storage layer from the lower portion and at the same time , for example, 10% of the total fuel gas used for combustion is introduced, the fuel gas and the air are good. The heat storage lean combustion reaction starts at a high temperature portion around 700 ° C. Combustion gases generated from the heat storage layer
The fuel is introduced into the furnace while being mixed and burnt well with the remaining fuel gas ejected from the remaining fuel gas ejecting portion provided in the combustion gas guide portion leading to the inside of the furnace to complete the combustion.

【0007】[0007]

【実施例】符号1は蓄熱層2を有する二ツのバーナ部を
一組として交互に切換燃焼させる交番燃焼バーナであ
る。この交番燃焼バーナの前記各バーナ部A,Bの蓄熱
層2には燃料ガス混入装置3を設置する。符号4は前記
蓄熱層2の下流側の燃焼ガス案内部5に設置した残余
ガス噴出部である。燃料ガス混入装置3は、蓄熱層2
の温度の低い位置に設置すると、燃焼領域である高温部
6に達するまでに燃料ガスと空気が良好に混合しながら
予熱される。また、残余燃料ガス噴出部4を燃焼ガス案
内部5に設置すると、残余燃料ガスは、燃焼ガスと良好
に混合されつつ燃焼しながら炉内7に導入される。この
ときの燃焼は、一段目の燃焼により酸素分圧が下がって
いるため、排ガス再循環の燃焼と同様の低NOx効果が
発揮できる。しかして、燃料ガス混入装置3からは、全
燃焼量の10%〜25%の燃料ガスを導入する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Reference numeral 1 denotes an alternating combustion burner for alternately switching and burning two burners having a heat storage layer 2 as a set. A fuel gas mixing device 3 is installed in the heat storage layer 2 of each of the burner portions A and B of the alternating combustion burner. Reference numeral 4 denotes a residual fuel installed in the combustion gas guide 5 on the downstream side of the heat storage layer 2.
This is the gas outlet. The fuel gas mixing device 3 includes the heat storage layer 2
If the fuel gas and the air are installed in a position where the temperature is low, the fuel gas and the air are preheated while being mixed well before reaching the high temperature part 6 which is the combustion area. In addition, when the residual fuel gas ejection part 4 is installed in the combustion gas guide part 5, the residual fuel gas is introduced into the furnace 7 while being satisfactorily mixed with the combustion gas and burning. In the combustion at this time, since the oxygen partial pressure is lowered by the first stage combustion, the same low NOx effect as the combustion in the exhaust gas recirculation can be exhibited. Thus, from the fuel gas mixing device 3, to introduce the entire amount of combustion 10% to 25% of the fuel gas.

【0008】しかして、一ツのバーナ部Aで燃焼した排
ガスは、他のバーナ部Bから排出される際、その顕熱
を、バーナ部Bの蓄熱層2が回収する。そして燃焼がバ
ーナ部Aからバーナ部Bへ切替わると、バーナ部Bの蓄
熱層2にその下部から空気が導入されると同時にその蓄
熱層2には全燃焼量の、例えば10%の燃料ガスが燃料
ガス混入装置3から蓄熱層2内に導入される。蓄熱層2
は加熱状態にあり、燃料ガスと空気は上昇しながら良好
に混合予熱されて、高温部6の700℃付近で燃焼反応
が開始する。燃焼ガスは、蓄熱層2から炉内7に至る燃
焼ガス案内部5における残余燃料ガス噴出部4から残余
の燃料ガスの供給を受け、混合しながら燃焼しつつ炉内
7に導入され、炉内7に於いて燃焼を完結して他のバー
ナ部Aの蓄熱層2で顕熱の回収をされながら排出され
る。かかる燃焼を、例えば60秒毎に繰り返す。かかる
際、燃料ガス混入装置3は、蓄熱層2の温度の低い位置
に設置すると、燃焼領域である高温部6に達するまでに
燃料ガスと空気が良好に混合しながら予熱される。ま
た、残余燃料ガス噴出部4を燃焼ガス案内部5に設置す
ると、残余燃料ガスは、燃焼ガスと良好に混合されつつ
燃焼しながら炉内7に導入され、前記したように、排ガ
ス再循環効果と同様の効果によりNOx低減効果を助長
する。しかして、燃料ガス混入装置3からは、全燃焼量
の10%〜25%の燃料ガスを導入する。燃料ガス混入
装置3から導入する燃料ガス量を全燃焼量の10%とし
た場合には、約50%の排出の際のNOx低減率が達成
でき、20%の導入で約70%の低減率が達成できた。
ただし、導入率を25%以上としたり、片寄ったりする
と煤の発生が生じ好ましくない。本発明は、以上のよう
に、希薄燃焼を蓄熱層2内で実現し、その燃焼ガスと共
に残余の燃料ガスを燃焼させるので、いわゆる排ガス再
循環燃焼と同様の低酸素分圧下での燃焼を効果的に実行
していることになり、燃焼効率を低下させることなく、
NOxの発生を大巾に抑制することができるのである。
When the exhaust gas burned in one burner section A is discharged from another burner section B, the sensible heat is recovered by the heat storage layer 2 of the burner section B. When the combustion is switched from the burner section A to the burner section B, air is introduced into the heat storage layer 2 of the burner section B from the lower portion thereof, and at the same time, the fuel gas of 10% of the total combustion amount is supplied to the heat storage layer 2. Is introduced into the heat storage layer 2 from the fuel gas mixing device 3. Thermal storage layer 2
Is in a heated state, the fuel gas and the air are mixed and preheated satisfactorily while rising, and the combustion reaction starts around 700 ° C. in the high temperature section 6. The combustion gases, fuel reaching the furnace 7 from the heat storage layer 2
The remaining fuel gas is supplied from the remaining fuel gas ejection section 4 in the combustion gas guide section 5 and is introduced into the furnace 7 while burning while mixing, and the combustion is completed in the furnace 7 to complete the other burner sections. The heat is discharged while the sensible heat is recovered in the heat storage layer 2 of A. Such combustion is repeated, for example, every 60 seconds. At this time, when the fuel gas mixing device 3 is installed at a position where the temperature of the heat storage layer 2 is low, the fuel gas and the air are premixed and satisfactorily heated before reaching the high temperature portion 6 which is the combustion region. In addition, when the residual fuel gas jetting section 4 is installed in the combustion gas guide section 5, the residual fuel gas is introduced into the furnace 7 while burning while being well mixed with the combustion gas, and as described above, the exhaust gas recirculation effect is obtained. The same effect as described above promotes the NOx reduction effect. Thus, from the fuel gas mixing device 3, to introduce the entire amount of combustion 10% to 25% of the fuel gas. When the fuel gas amount introduced from the fuel gas mixing device 3 is 10% of the total combustion amount, a NOx reduction rate at the time of emission of about 50% can be achieved, and a reduction rate of about 70% by introducing 20%. Was achieved.
However, if the introduction rate is set to 25% or more or is offset, soot is generated, which is not preferable. As described above, the present invention realizes the lean combustion in the heat storage layer 2 and burns the remaining fuel gas together with the combustion gas, so that the combustion under the low oxygen partial pressure similar to the so-called exhaust gas recirculation combustion is effective. And without reducing the combustion efficiency,
The generation of NOx can be greatly suppressed.

【0009】[0009]

【発明の効果】本発明は以上の通りであるので、次の諸
効果がある。排ガス再循環設備が不要でNOxを同レ
ベルに抑制することができる、排ガス再循環燃焼は効
率の低下があるが、本発明は蓄熱層内での燃焼であるの
で、熱効率の低下がない、本発明は完全予熱混合蓄熱
燃焼であるので、排ガスが均等であり、排ガス再循環効
果が完全に得られる。
As described above, the present invention has the following effects. Exhaust gas recirculation combustion does not require an exhaust gas recirculation facility and can suppress NOx to the same level. Exhaust gas recirculation combustion has a decrease in efficiency. However, since the present invention is combustion in a heat storage layer, there is no decrease in thermal efficiency. Since the invention is a complete preheating mixed regenerative combustion, the exhaust gas is uniform and the exhaust gas recirculation effect is completely obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】全体の説明図である。FIG. 1 is an overall explanatory diagram.

【符号の説明】[Explanation of symbols]

1 交番燃焼バーナ 2 蓄熱層 3 燃料ガス混入装置 4 残余燃料ガス噴出部 5 燃焼ガス案内部 6 高温部 7 炉内DESCRIPTION OF SYMBOLS 1 Alternating combustion burner 2 Heat storage layer 3 Fuel gas mixing device 4 Residual fuel gas ejection part 5 Combustion gas guide part 6 High temperature part 7 Furnace

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) F23C 11/00 F23D 14/66 F23L 15/02 F23D 23/00 F23C 7/06 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int. Cl. 7 , DB name) F23C 11/00 F23D 14/66 F23L 15/02 F23D 23/00 F23C 7/06

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 蓄熱層を有する二ツのバーナ部を一組
として交互に切換燃焼させる交番燃焼バーナの前記各バ
ーナ部の蓄熱層に、燃焼に供する燃料ガスのうちの一部
の燃料ガスを導入するための燃料ガス混入装置を装置
し、前記蓄熱層から炉内に至る燃焼ガス案内部に残余の
燃料ガスを導入するための残余燃料ガス噴出部を設け
燃料ガス混入装置から加熱状態下の蓄熱層内に全燃焼
量の10〜25%の燃料ガスを混入して、前記蓄熱層内
に流入してくる燃焼用空気と蓄熱希薄燃焼反応を生じさ
せた後、残余の燃料ガスを前記燃焼ガス案内部における
残余燃料ガス噴出部を介して燃焼ガス案内部に導入し
て、前記蓄熱希薄燃焼による燃焼ガスと残余燃料ガスと
混合させて燃焼を完結するようにしたことを特徴とする
窒素酸化物低発生交番燃焼方法。
1. A part of fuel gas to be provided for combustion in a heat storage layer of each burner part of an alternating combustion burner in which two burners having a heat storage layer are alternately switched and burned as a set.
A fuel gas mixing device for introducing the fuel gas is provided, and the remaining combustion gas guide portion from the heat storage layer to the inside of the furnace is provided.
Providing a residual fuel gas ejection part for introducing fuel gas ,
By mixing a 10% to 25% of the fuel gas of the total combustion amount in the heat storage layer under heating conditions from the fuel gas introducing device, cause heat accumulation lean combustion reaction and combustion air come to flow into the heat storage layer After that, the remaining fuel gas in the combustion gas guide section
The fuel gas is introduced into the combustion gas guide via the residual fuel gas ejection part, and the combustion gas and the residual fuel gas from the heat storage lean combustion are used.
An alternating combustion method for producing low nitrogen oxides, wherein the combustion is completed by mixing .
【請求項2】 前記燃料ガス混入装置を、加熱下の蓄
熱層に於いて温度の低い位置に設けて燃料ガスを導入さ
せることを特徴とする第1項記載の窒素酸化物低発生交
番燃焼方法。
Wherein said fuel gas introducing device,蓄under heat
Fuel gas is introduced at a low temperature in the thermal layer.
2. The method according to claim 1, wherein the alternating combustion is performed with low nitrogen oxides.
JP28123393A 1993-11-10 1993-11-10 Low-nitrogen oxide alternating combustion method Expired - Fee Related JP3212002B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28123393A JP3212002B2 (en) 1993-11-10 1993-11-10 Low-nitrogen oxide alternating combustion method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28123393A JP3212002B2 (en) 1993-11-10 1993-11-10 Low-nitrogen oxide alternating combustion method

Publications (2)

Publication Number Publication Date
JPH07133906A JPH07133906A (en) 1995-05-23
JP3212002B2 true JP3212002B2 (en) 2001-09-25

Family

ID=17636225

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28123393A Expired - Fee Related JP3212002B2 (en) 1993-11-10 1993-11-10 Low-nitrogen oxide alternating combustion method

Country Status (1)

Country Link
JP (1) JP3212002B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2916404B2 (en) * 1995-12-29 1999-07-05 中外炉工業株式会社 Panel integrated regenerative combustion device
JP2011072919A (en) * 2009-09-30 2011-04-14 Toyobo Co Ltd System for treating gas containing organic solvent

Also Published As

Publication number Publication date
JPH07133906A (en) 1995-05-23

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