JP3209476B2 - Fabric ink ribbon - Google Patents
Fabric ink ribbonInfo
- Publication number
- JP3209476B2 JP3209476B2 JP13583694A JP13583694A JP3209476B2 JP 3209476 B2 JP3209476 B2 JP 3209476B2 JP 13583694 A JP13583694 A JP 13583694A JP 13583694 A JP13583694 A JP 13583694A JP 3209476 B2 JP3209476 B2 JP 3209476B2
- Authority
- JP
- Japan
- Prior art keywords
- ink
- fabric
- ink ribbon
- pigment
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Impression-Transfer Materials And Handling Thereof (AREA)
- Duplication Or Marking (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明はインパンクトプリンタな
どに使用するファブリックインクリボンに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric ink ribbon used for an impact printer or the like.
【０００２】[0002]
【従来の技術および発明が解決しようとする課題】従来
より、ワイヤドットプリンタ、タイプライタなどのイン
パクトプリンタには、着色剤および油剤からなる液状イ
ンクをファブリックリボン生地に含浸させたものが使用
されている。2. Description of the Related Art Conventionally, impact printers such as wire dot printers and typewriters have been used in which a fabric ink is impregnated with a liquid ink comprising a coloring agent and an oil agent. I have.
【０００３】このファブリックインクリボン用の液状イ
ンクには、着色剤として、有機または無機顔料を使用す
る顔料系、染料を使用する染料系、および顔料と染料を
併用する染顔料系がある。[0003] Liquid inks for fabric ink ribbons include, as coloring agents, pigments using organic or inorganic pigments, dyes using dyes, and dyes and pigments using pigments and dyes in combination.
【０００４】しかしながら、顔料系および染顔料系のイ
ンクを含浸させたファブリックインクリボンのばあい、
高温多湿の環境下で保存すると、インクの流動性が劣化
し、印字寿命が短かくなるという欠点があった。[0004] However, in the case of a fabric ink ribbon impregnated with pigment-based and dye-pigment-based inks,
When stored in a high-temperature and high-humidity environment, there is a disadvantage that the fluidity of the ink is deteriorated and the print life is shortened.
【０００５】本発明は、前記の点に鑑みて、高温多湿環
境下で保存してもインクの流動性が劣化せず、印字寿命
が影響を受けないファブリックインクリボンを提供する
ことを目的とする。SUMMARY OF THE INVENTION In view of the foregoing, it is an object of the present invention to provide a fabric ink ribbon in which the fluidity of ink does not deteriorate even when stored in a high-temperature and high-humidity environment and the printing life is not affected. .
【０００６】[0006]
【課題を解決するための手段】本発明は、少なくとも有
機および／または無機顔料を含む着色剤、および油剤を
必須成分として含有するインクがファブリックリボン生
地に含浸されてなるファブリックインクリボンにおい
て、前記インクがさらにフェノール樹脂を含有すること
を特徴とするファブリックインクリボンを提供する。According to the present invention, there is provided a fabric ink ribbon obtained by impregnating a fabric ribbon fabric with an ink containing at least a coloring agent containing an organic and / or inorganic pigment and an oil agent as essential components. Further comprises a phenolic resin.
【０００７】本発明はさらに、前記フェノール樹脂がパ
ラアルキルフェノール樹脂であるファブリックインクリ
ボンを提供する。The present invention further provides a fabric ink ribbon wherein the phenol resin is a paraalkylphenol resin.
【０００８】本発明はさらに、前記パラアルキルフェノ
ール樹脂のアルキル基がｔ−ブチル基であるファブリッ
クインクリボンを提供する。[0008] The present invention further provides a fabric ink ribbon wherein the alkyl group of the paraalkylphenol resin is a t-butyl group.
【０００９】[0009]
【作用および実施例】本発明のファブリックインクリボ
ンにおいては、そのインクとして、顔料を含む着色剤と
油剤に加えてフェノール樹脂を含有するものを使用す
る。このフェノール樹脂の作用効果はつぎのとおりであ
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS In the fabric ink ribbon of the present invention, an ink containing a phenol resin in addition to a coloring agent containing a pigment and an oil agent is used as the ink. The functions and effects of the phenol resin are as follows.
【００１０】本発明者らが、従来のファブリックインク
リボンを高温多湿の環境下で保存したばあいにインクの
流動性が劣下する原因を考察したところ、高温多湿の環
境下では親水性基を有する顔料粒子の表面に水分が付着
され、それが原因で顔料粒子同士が凝集し、流動性が劣
下するものと推察された。The inventors of the present invention have considered the cause of the deterioration of the fluidity of the ink when the conventional fabric ink ribbon is stored in a high-temperature and high-humidity environment. It was presumed that moisture was attached to the surface of the pigment particles having the pigment particles, which caused the pigment particles to aggregate with each other, resulting in poor fluidity.
【００１１】しかるに、前記インク中にフェノール樹脂
を配合せしめることによって、該フェノール樹脂はその
親水部が親水性基を有する顔料粒子の表面に対して親和
性が高いため、顔料粒子表面に付着し、顔料粒子表面を
包み込んでしまう。この包み込みにより顔料粒子の表面
はフェノール樹脂の親油性基で覆われ、それにより水分
の顔料粒子表面への付着が防止されるため、顔料粒子同
士が凝集するのが防止され、もってインクの流動性の劣
化が防止されるものと推定されている。However, by incorporating a phenolic resin into the ink, the phenolic resin has a high affinity for the surface of the pigment particles having a hydrophilic group, so that the phenolic resin adheres to the surface of the pigment particles, It wraps around the pigment particle surface. This encapsulation covers the surface of the pigment particles with the lipophilic group of the phenolic resin, thereby preventing the adhesion of water to the surface of the pigment particles. It is presumed that the deterioration of is prevented.
【００１２】本発明に用いるフェノール樹脂としては、
レゾール型のものが好ましく、顔料との親和性が高くか
つ油剤との相溶性が良好な点からレゾール型パラアルキ
ルフェノール樹脂がとくに好ましい。このレゾール型パ
ラアルキルフェノール樹脂はたとえば一般式（Ｉ）：The phenolic resin used in the present invention includes:
The resol type is preferred, and the resole type paraalkyl phenol resin is particularly preferred because of its high affinity with the pigment and good compatibility with the oil agent. This resole-type paraalkylphenol resin has, for example, the general formula (I):
【００１３】[0013]
【化１】 Embedded image
【００１４】（式中、Ｒは炭素原子数が１〜４個の直鎖
または分岐状アルキル基、ｎは５〜３０の整数である）
で示されるものである。Ｒで表わされるアルキル基とし
ては、メチル、エチル、ｎ−プロピル、イソプロピル、
ｎ−ブチル、イソブチル、ｔ−ブチルなどがあげられ
る。Wherein R is a linear or branched alkyl group having 1 to 4 carbon atoms, and n is an integer of 5 to 30.
It is shown by. Examples of the alkyl group represented by R include methyl, ethyl, n-propyl, isopropyl,
n-butyl, isobutyl, t-butyl and the like.
【００１５】これらレゾール型パラアルキルフェノール
樹脂は単独で使用してもよく、混合して使用してもよ
い。These resole-type paraalkylphenol resins may be used alone or in combination.
【００１６】前記レゾール型パラアルキルフェノール樹
脂の中でも、レゾール型パラ−ｔ−ブチルフェノール樹
脂がとくに好ましい。Among the resole-type para-alkylphenol resins, a resole-type para-t-butylphenol resin is particularly preferred.
【００１７】前記フェノール樹脂のインク中における含
有量は３〜３０％（重量％、以下同様）の範囲が好まし
い。フェノール樹脂の含有量が前記範囲より少ないと、
顔料の表面を充分に包み込むことができず、高温多湿条
件下で顔料が凝集し、インクの粘度が高くなる傾向にあ
る。一方前記範囲より多いと、インクの初期粘度が高く
なりすぎ、インクリボン用のインクとして適さなくなる
傾向にある。The content of the phenol resin in the ink is preferably in the range of 3 to 30% (% by weight, the same applies hereinafter). If the content of the phenolic resin is less than the above range,
The surface of the pigment cannot be sufficiently wrapped, and the pigment tends to aggregate under high-temperature and high-humidity conditions, thereby increasing the viscosity of the ink. On the other hand, if it is more than the above range, the initial viscosity of the ink tends to be too high, and it tends to be unsuitable as ink for an ink ribbon.
【００１８】本発明における着色剤としては有機および
／または無機の顔料が使用される。顔料に加えて染料を
併用してもよい。As the coloring agent in the present invention, organic and / or inorganic pigments are used. A dye may be used in combination with the pigment.
【００１９】無機顔料としては、たとえばカーボンブラ
ック、四三酸化鉄などがあげられる。有機顔料として
は、たとえばシアニンブルー、フタロシアニンブルー、
ビクトリアブルーベース、ハンザイエロー、ベンジジン
イエロー、レーキレッド、パーマネントカーミン、ペリ
レンレッド、アニリンブラック、ペリレンブラックなど
があげられる。これら有機、無機の顔料は単独でまたは
混合して使用できる。染料としてはニグロシンベース、
メチルバイオレット、オイルブルー、オイルイエローな
どの油溶性染料の１種または２種以上が使用できる。Examples of the inorganic pigment include carbon black and triiron tetroxide. As organic pigments, for example, cyanine blue, phthalocyanine blue,
Victoria Blue Base, Hansa Yellow, Benzidine Yellow, Lake Red, Permanent Carmine, Perylene Red, Aniline Black, Perylene Black and the like. These organic and inorganic pigments can be used alone or as a mixture. Nigrosine base as dye,
One or more oil-soluble dyes such as methyl violet, oil blue and oil yellow can be used.
【００２０】本発明における油剤としては、たとえばナ
タネ油、ヒマシ油、大豆油、牛脂油などの動植物油、ビ
トリアオイル、パラフィン系オイルなどの鉱油、イソス
テアリン酸、オレイン酸などの高級脂肪酸、ジオクチル
アゼレート、ジオクチルフタレートなどの可塑剤などの
１種または２種以上が使用できる。Examples of the oil agent in the present invention include animal and vegetable oils such as rapeseed oil, castor oil, soybean oil, tallow oil, mineral oils such as vitria oil and paraffin oil, higher fatty acids such as isostearic acid and oleic acid, and dioctyl azelate. And one or more plasticizers such as dioctyl phthalate.
【００２１】本発明においては前記成分に加えて顔料分
散剤を配合してもよい。顔料分散剤としては、たとえば
ソルビタン脂肪酸エステル、リン酸エステルなどの非イ
オン性界面活性剤、レシチン、ポリエステル系分散剤な
どがあげられる。In the present invention, a pigment dispersant may be blended in addition to the above components. Examples of the pigment dispersant include nonionic surfactants such as sorbitan fatty acid ester and phosphate ester, lecithin, polyester dispersant and the like.
【００２２】本発明におけるインクは、前記各成分をイ
ンク全量に対して、つぎに示す割合（％）で配合するの
が好ましい。In the ink according to the present invention, it is preferable to mix the above-mentioned components in the following ratios (%) with respect to the total amount of the ink.
【００２３】 成 分 ％ 顔料 ３〜３０ 染料 ０〜１５ 油剤 ３０〜９０ フェノール樹脂 ３〜３０ 顔料分散剤 ０〜１０ （好ましくは１〜６） 前記インクには、本発明の目的を損なわない範囲内で、
防腐剤、防カビ剤などの添加剤を適宜配合することがで
きる。Component% Pigment 3 to 30 Dye 0 to 15 Oil 30 to 90 Phenolic resin 3 to 30 Pigment dispersant 0 to 10 (preferably 1 to 6) The ink is contained within a range that does not impair the object of the present invention. so,
Additives such as preservatives and fungicides can be appropriately compounded.
【００２４】前記インクは、通常の調製法で調製でき、
たとえば前記成分をロールミル、サンドミルなどで混練
することにより調製できる。The ink can be prepared by a usual preparation method,
For example, it can be prepared by kneading the above components with a roll mill, a sand mill or the like.
【００２５】本発明のファブリックインクリボンは前記
インクをファブリックリボン生地に含浸させたものであ
るが、ファブリックリボン生地としては、ナイロン６、
ナイロン６６、ポリエステル、絹、綿などの繊維の織布
で、坪量３０〜８０ｇ／ｍ2程度のものが好ましく使用
できる。インクの含浸量は通常５〜２５ｇ／ｍ2 程度が
適当である。The fabric ink ribbon of the present invention is obtained by impregnating the above-mentioned ink into a fabric ribbon fabric.
A woven fabric of fibers such as nylon 66, polyester, silk, and cotton, having a basis weight of about 30 to 80 g / m 2 can be preferably used. The appropriate amount of ink impregnation is usually about 5 to 25 g / m 2 .
【００２６】つぎに実施例をあげて本発明を説明する。Next, the present invention will be described with reference to examples.
【００２７】実施例１〜４および比較例１ 表１に示す処方に従って各材料を混合し、３本ロールミ
ルで混練してインクを調製した。Examples 1 to 4 and Comparative Example 1 Inks were prepared by mixing the respective materials according to the formulation shown in Table 1 and kneading them with a three-roll mill.
【００２８】えられた各インクを６５℃、９０％ＲＨの
環境下で９６時間保存した。この保存処理の前後におけ
るインクの粘度を測定し、さらに保存処理前の粘度に対
する保存処理後の粘度の増加率（％）を求めた。インク
の粘度はロドビスコ粘度計で測定した。結果を表１に示
す。Each of the obtained inks was stored for 96 hours in an environment of 65 ° C. and 90% RH. The viscosity of the ink before and after the preservation treatment was measured, and the rate of increase (%) of the viscosity after the preservation treatment relative to the viscosity before the preservation treatment was determined. The viscosity of the ink was measured with a Rhodovisco viscometer. Table 1 shows the results.
【００２９】また前記調製直後の各インクを幅１３ｍ
ｍ、坪量６５ｇ／ｍ2 のナイロン６６生地に１３ｇ／ｍ
2 の割合で含浸させ、６０ｍのメビウス環としたものを
リボンカッセトに装填し、６５℃、９０％ＲＨの環境下
で９６時間保存した。この保存処理の前後のインクリボ
ンを用いて印字を行ない、印字寿命を求めた。印字寿命
は印字濃度（ＰＣＳ値）が０．４になるまでに印字でき
た文字数で表わした。印字は２４ピンワイヤドットプリ
ンタで白色連票紙に行ない、印字濃度（ＰＣＳ値）はマ
クベス社製濃度計ＰＣＭ−IIを用いて測定した。結果を
表１に示す。Each of the inks immediately after the preparation was applied to a width of 13 m.
m, 13 g / m on nylon 66 cloth with a basis weight of 65 g / m 2
Impregnated at a ratio of 2 and formed into a 60 m Mobius ring was loaded into a ribbon cassette and stored at 65 ° C. and 90% RH for 96 hours. Printing was performed using the ink ribbon before and after the storage processing, and the printing life was determined. The print life was represented by the number of characters that could be printed until the print density (PCS value) reached 0.4. Printing was performed on white continuous paper with a 24-pin wire dot printer, and the print density (PCS value) was measured using a densitometer PCM-II manufactured by Macbeth. Table 1 shows the results.
【００３０】[0030]
【表１】 [Table 1]
【００３１】表１の結果から明らかなように、フェノー
ル樹脂を含有するインク（実施例１〜４）のばあいは、
高温多湿条件下での保存処理によるインク粘度の増加率
が４〜１０％程度であり、印字寿命に変化がないのに対
して、フェノール樹脂を含有しないインク（比較例１）
のばあいは保存処理によるインク粘度の増加率が５４％
であり、印字寿命が短かくなった。なお、保存処理によ
るインク粘度の増加率が１０％程度以下であれば印字寿
命にほとんど影響がない。As is apparent from the results in Table 1, in the case of the ink containing the phenol resin (Examples 1 to 4),
An ink that does not contain a phenolic resin, while the increase rate of the ink viscosity by storage treatment under high temperature and high humidity conditions is about 4 to 10%, and there is no change in print life (Comparative Example 1)
In case of, the increase rate of ink viscosity by preservation processing is 54%
And the printing life was shortened. If the rate of increase in ink viscosity due to the preservation process is about 10% or less, there is almost no effect on the printing life.
【００３２】[0032]
【発明の効果】ファブリックインクリボンにおいて、イ
ンクにフェノール樹脂を配合することによって、高温多
湿環境下で保存してもインクの流動性が劣下せず、印字
寿命が影響を受けない。By mixing a phenolic resin with the ink in the fabric ink ribbon, the fluidity of the ink does not deteriorate even when stored under a high-temperature and high-humidity environment, and the printing life is not affected.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭64−45680（ＪＰ，Ａ) 特開 平４−65279（ＪＰ，Ａ) 特開 昭63−233876（ＪＰ，Ａ) 特開 昭62−13387（ＪＰ，Ａ) 特開 昭60−40297（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) B41J 31/02 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-64-45680 (JP, A) JP-A-4-65279 (JP, A) JP-A-63-233876 (JP, A) JP-A-62 13387 (JP, A) JP-A-60-40297 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) B41J 31/02
Claims (3)
を含む着色剤、および油剤を必須成分として含有するイ
ンクがファブリックリボン生地に含浸されてなるファブ
リックインクリボンにおいて、前記インクがさらにフェ
ノール樹脂を含有することを特徴とするファブリックイ
ンクリボン。1. A fabric ink ribbon in which a fabric ribbon fabric is impregnated with an ink containing a colorant containing at least an organic and / or inorganic pigment and an oil as essential components, wherein the ink further contains a phenolic resin. Fabric ink ribbon.
ノール樹脂である請求項１記載のファブリックインクリ
ボン。2. The fabric ink ribbon according to claim 1, wherein said phenol resin is a paraalkylphenol resin.
キル基がｔ−ブチル基である請求項２記載のファブリッ
クインクリボン。3. The fabric ink ribbon according to claim 2, wherein the alkyl group of the paraalkylphenol resin is a t-butyl group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13583694A JP3209476B2 (en) | 1994-06-17 | 1994-06-17 | Fabric ink ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13583694A JP3209476B2 (en) | 1994-06-17 | 1994-06-17 | Fabric ink ribbon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH082099A JPH082099A (en) | 1996-01-09 |
| JP3209476B2 true JP3209476B2 (en) | 2001-09-17 |
Family
ID=15160907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13583694A Expired - Lifetime JP3209476B2 (en) | 1994-06-17 | 1994-06-17 | Fabric ink ribbon |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3209476B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7678462B2 (en) | 1999-06-10 | 2010-03-16 | Honeywell International, Inc. | Spin-on-glass anti-reflective coatings for photolithography |
| US8557877B2 (en) | 2009-06-10 | 2013-10-15 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
| US8642246B2 (en) | 2007-02-26 | 2014-02-04 | Honeywell International Inc. | Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof |
| US8864898B2 (en) | 2011-05-31 | 2014-10-21 | Honeywell International Inc. | Coating formulations for optical elements |
| US8992806B2 (en) | 2003-11-18 | 2015-03-31 | Honeywell International Inc. | Antireflective coatings for via fill and photolithography applications and methods of preparation thereof |
| US9069133B2 (en) | 1999-06-10 | 2015-06-30 | Honeywell International Inc. | Anti-reflective coating for photolithography and methods of preparation thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102186862B (en) * | 2008-11-12 | 2017-10-17 | 阿彻丹尼尔斯米德兰德公司 | The composition and method of lecithin and plasticizer |
-
1994
- 1994-06-17 JP JP13583694A patent/JP3209476B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7678462B2 (en) | 1999-06-10 | 2010-03-16 | Honeywell International, Inc. | Spin-on-glass anti-reflective coatings for photolithography |
| US9069133B2 (en) | 1999-06-10 | 2015-06-30 | Honeywell International Inc. | Anti-reflective coating for photolithography and methods of preparation thereof |
| US8992806B2 (en) | 2003-11-18 | 2015-03-31 | Honeywell International Inc. | Antireflective coatings for via fill and photolithography applications and methods of preparation thereof |
| US8642246B2 (en) | 2007-02-26 | 2014-02-04 | Honeywell International Inc. | Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof |
| US8557877B2 (en) | 2009-06-10 | 2013-10-15 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
| US8784985B2 (en) | 2009-06-10 | 2014-07-22 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
| US8864898B2 (en) | 2011-05-31 | 2014-10-21 | Honeywell International Inc. | Coating formulations for optical elements |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH082099A (en) | 1996-01-09 |
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