JP3199070B2 - Rice taste evaluation device - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an apparatus for evaluating the taste of rice using near infrared rays.

[0002]

2. Description of the Related Art Conventional taste evaluation of brown rice is known in which proteins and amylose in components of brown rice are detected by near infrared rays, and the detected values are substituted into a predetermined taste estimation formula to estimate the taste. ing.

[0003]

However, in the conventional method for evaluating the taste of brown rice, the degree of influence of the unripe rice on the taste is not recognized, and the degree of contamination of the unripe rice or the degree of sizing is reflected in the determined taste. However, as a result, there has been a problem that the degree of influence of the degree of immature rice contamination on the taste evaluation value does not appear in the obtained value.

[0004]

According to the present invention, a spectrometer for analyzing the composition and quality of a rice sample can irradiate light having wavelengths in the visible region and the near-infrared region. The near-infrared region of the chlorophyll absorption band.
A rice taste evaluation device that corrects the taste evaluation value based on the absorbance of the region .

According to a second aspect of the present invention, there is provided a spectroscopic apparatus for analyzing components and quality of a rice sample, wherein the spectroscopic apparatus is configured to be capable of irradiating light having a wavelength ranging from a visible region to a near-infrared region. Absorbance in near infrared region
A rice taste evaluation device for correcting the taste evaluation value .

In the above, the spectral means of the spectrometer for analyzing the components and quality of the rice sample is provided with a filter for the wavelength in the near infrared region and a filter for the wavelength in the chlorophyll absorption band. Alternatively, it is assumed that the spectroscopy unit is configured by a diffraction grating that separates continuous wavelengths from the visible region to the near infrared region. The detector is constituted by a transmitted light detector or a reflected light detector.

[0007]

According to the present invention, immature rice contains chlorophyll, and the degree of contamination of immature rice can be determined from the detected amount of chlorophyll. Therefore, the visible wavelength and the near-infrared region can be irradiated with light wavelengths. Of the absorption band characteristic of chlorophyll, and by reflecting it on the taste evaluation value based on the absorbance in the near-infrared region, a highly accurate taste evaluation including the tendency of taste deterioration caused by immature rice can be achieved. I can do it.

The spectral means of the spectrometer for analyzing the components and quality of the rice sample is provided with a filter for the wavelength in the near infrared region and a filter for the wavelength in the chlorophyll absorption band, or a diffraction grating capable of spectrally separating continuous wavelengths. Then, the size or size of the device can be reduced.

[0009]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described with reference to the drawings. FIG. 1 illustrates the principle of obtaining an old rice index. In FIG. 1, reference numeral 1 denotes a light source for irradiating a rice sample, 2 denotes a condensing lens, and 3 denotes a slit. Place it on top. Reference numeral 4 denotes a chopper for transmitting and blocking light, and reference numeral 5 denotes a disk with a filter to which a plurality of filters 5A to 5F described later are attached. 6 is a reflection mirror, 7 is a sample set disk for setting a rice sample to be measured, and 8 is a photoelectric detector for detecting light.

The chopper 4 is a disk in which light passing portions 4A and light blocking portions 4B are alternately formed for passing and blocking light, and is configured to rotate at a predetermined speed during measurement by a motor (not shown). . The filter-equipped disk 5 has six holes at predetermined intervals at positions equidistant from the center of the disk, and filters 5A to 5F are attached to the holes.
The motor is intermittently rotated during measurement by a motor (not shown), and one of the filters 5A to 5F is positioned on the optical axis of the lens 2 when the motor is stopped.

The filters 5A to 5C are near-infrared transmitting filters that transmit near-infrared light having a predetermined wavelength in a region where fatty acids which are constituents of fat contained in a rice sample are absorbed. For example, the filter 5A transmits near-infrared light having a wavelength of 910 nm, and the filter 5B transmits light having a wavelength of 930 nm.
m which transmits near-infrared rays, and the filter 5C has a wavelength of 9
It shall transmit near-infrared rays of 50 nm.

The filters 5D to 5F are visible light transmitting filters that transmit visible light of a predetermined wavelength in order to detect chlorophyll contained in a rice sample. For example, the filter 5D transmits visible light having a wavelength of 660 nm, the filter 5E transmits visible light having a wavelength of 680 nm,
The filter 5F transmits visible light having a wavelength of 700 nm.

In the sample set disk 7, two ceramic reflectors 9, 10 are arranged at predetermined positions on a circumference separated by a predetermined distance from the center of the disk, and the ceramic reflector 9 has a very small particle size. A transparent container 11 filled with a small crushed rice sample or a non-milled sample is detachably configured. Further, the sample set disk 7 rotates during the measurement, and when the sample
The structure is such that the ceramic reflector 9 or 10 is located on the reflected light from.

An amplifier 12 for amplifying a signal, an A / D converter 13 for A / D conversion, and a computing unit 14 comprising a one-chip microcomputer or the like are connected in series at the subsequent stage of the photoelectric detector 8. Connecting. The arithmetic unit 14 performs a predetermined arithmetic process based on the detection value of the photoelectric detector 8 as described later. The value processed by the arithmetic unit 14 is displayed on a display 15 constituted by a liquid crystal display or the like.

Next, an operation example of the embodiment configured as described above will be described. Now, it is assumed that the disk with filter 5 is in the state shown in FIG. 1 and the chopper 4 is rotating at a predetermined speed. At this time, the light emitted from the light source 1 is repeatedly passed and blocked by the chopper 4 via the lens 2 and the slit 3, and only the near-infrared ray having a wavelength of 910 nm is transmitted by the filter 5A. The transmitted light is reflected by the reflection mirror 6 and then applied to the ceramic reflection plate 10 of the sample set disk 7 waiting below.

The light reflected by the ceramic reflector 10 is received by the photoelectric detector 8 and is photoelectrically converted. The photoelectrically converted electric signal is amplified by an amplifier 12 and then A /
The data is A / D converted by the D converter 13 and input to the arithmetic unit 14. The reflected light from such a ceramic reflector 10 is
It is obtained intermittently each time light passes through the chopper 4. Therefore, the arithmetic unit 14 calculates the average value V01 based on a plurality of electric signals (corresponding to the intensity of the reflected light) output from the photoelectric detector 8.

Next, the sample set disk 7 is rotated, and the reflected light from the reflecting mirror 6 is applied to the ceramic reflecting plate 9.
Is irradiated to the transparent container 11 filled with the rice sample set in. In this state, the reflected light from the rice sample is intermittently obtained each time the light passes through the chopper 4. Therefore, the calculator 14 calculates the average value V1 based on a plurality of electric signals (corresponding to the intensity of the reflected light) output from the photoelectric detector 8.

Further, the filter-equipped disk 5 is rotated so that a filter 5B that transmits near infrared rays having a wavelength of 930 nm is set on the optical axis of the lens 2. Thereafter, the sample set disk 7 is rotated, and the reflected light from the reflection mirror 6 is reflected from the ceramic reflector 10 and from the rice sample in the transparent container 11 set on the ceramic reflector 9. State. And in each of these states,
Based on the electric signal output from the photoelectric detector 8, the arithmetic unit 14 corresponds to the average value V02 of the measured values corresponding to the reflected light from the ceramic reflector 10 and the reflected light from the rice sample as described above. An average value V2 of the measured values is calculated.

After that, the filter-equipped disk 5 is rotated to set a filter 5C, which transmits near-infrared light having a wavelength of 950 nm, on the optical axis of the lens 2, and then to the same state as described above.
In each state, the arithmetic unit 14 calculates the average value V0 of the measured values corresponding to the reflected light from the ceramic reflector 10 based on the electric signal output from the photoelectric detector 8 as described above.
3, and the average value V3 of the measured values corresponding to the reflected light from the rice sample is calculated.

Thus, the signal processing based on near-infrared light having a predetermined wavelength in the region where the fatty acid contained in the rice sample is absorbed is completed. Next, in order to detect chlorophyll in the rice sample, the filter-equipped disk 5 is rotated so that each filter is placed on the optical axis of the lens 2 in the order of filters 5D, 5E, and 5F. Then, as described above, the filters 5D,
5E and 5F, the average value V0 of the measured values corresponding to the reflected light from the ceramic reflector 10 according to the visible light transmitted through the ceramic reflector 10.
4, V05, and V06, and average values V4, V5, and V6 of the measured values corresponding to the reflected light from the rice sample.
Are calculated respectively.

Next, each of the average values V thus obtained is
01 to V06 and V1 to V6,
Performs the following operation. R1 = V1 / V01 (1) R2 = V2 / V02 (2) R3 = V3 / V03 (3) R4 = V4 / V04 (4) R5 = V5 / V05 (5) R6 = V6 / V06 (6) , R1, R2, and R3 have wavelengths of 910 nm and 93
The near-infrared reflectance at 0 nm and 950 nm. R4, R5 and R6 have wavelengths of 660 nm and 6
It is each reflectance of each visible light in 80 nm and 700 nm.

Next, the reflectances R1, R2, and R3 relating to the content of the fatty acid which is a constituent component of the fat thus obtained are described.
Using R3, the fatty acid degree AF in the rice sample is calculated. Further, using the respective reflectances R4, R5, and R6 regarding the content of chlorophyll obtained at the same time, the immature rice mixing ratio CG in the rice sample is calculated. The reason that immature rice contamination rate can be calculated from chlorophyll is that immature rice contains chlorophyll,
This is because the immature rice contamination rate can be determined from the detected amount of chlorophyll.

By the way, the fatty acid content AF thus detected is 5 to 10 mg KOH / 100 g with brown rice at the time of harvest.
As for the dry weight, the fatty acid degree AF generally increases to 15 to 20 mg KOH / 100 g dry weight when the rice has passed for 1 to 2 months. In addition, when comparing the fatty acid degree of immature rice (blue rice) and the fatty acid degree of sized rice at this time, it is general that immature rice is about 1.3 to 2 times as large as sized rice. It is. Therefore, even if the fatty acid content is as low as 20 mg or less, if the mixing ratio of immature rice is high, the state is close to old rice.

Therefore, the fatty acid degree A calculated as described above
F and immature rice mixing ratio CG are substituted into the following equation (7),
An old rice index F is obtained as an index of the degree of rice deterioration. F = (CG / 10 + 0.5) (AF / 10-1) (7) Here, when AF <20, F = 0, and AF ≧ 20
In this case, F takes various values as shown in FIG. 2, for example.

In the embodiment described above, since the degree of old rice conversion can be quantitatively grasped by the numerical values as described above, by using the calculation result, it is possible to contribute to the improvement of the accuracy of rice quality judgment, and This is convenient for setting rice polishing conditions and blending conditions for rice of different varieties. Next, an embodiment of the taste analyzer will be described with reference to the drawings.

Referring to FIG. 3, this embodiment includes a spectroscopic device main body 21 composed of various components described below and a detection unit 22 composed of various components described below. The spectroscopic device body 21 includes a light source 23, a reflecting mirror 24, and a diffraction grating 26 driven by a diffraction grating driving motor 25 as shown in the figure, and has a control circuit 27 for controlling each unit.

The detection unit 22 includes a mounting unit 28 for mounting a sample container containing a ground or unground brown rice sample to be measured at the time of measurement, a transmitted light detector 29 for detecting transmitted light of the sample, a sample And a reflected light detector 30 for detecting the reflected light from the. In the detection unit 22, when the transmitted light detector 29 detects transmitted light, a transparent sample container is mounted on the mounting portion 28, and when the reflected light detector 30 detects reflected light, The container has a reflective part and the mounting part 2
Attach to 8.

Next, the control processing system of this embodiment will be described.
This will be described with reference to FIG. The control circuit 27 connects the transmitted light detector 29, the reflected light detector 30, and the like to the input side thereof. Further, a light source 23, a diffraction grating driving motor 25, and the like are connected to the output side of the control circuit 27. Control circuit 27
Is connected to the CPU 31 of the computer via a communication input / output unit (not shown). The CPU 31 has a memory 32
In addition, a keyboard 33 is connected as an input device, and a display device 34 is connected as an output device.

Next, an example of the operation of the embodiment configured as described above will be described. First, a brown rice sample to be measured is crushed or filled into a sample container without being crushed, and then the sample container is attached to the mounting unit 2 of the detection unit 22.
Attach to 8. Next, the spectroscopic device main body 21 and the detection unit 22 are brought into an operating state. Then, light in the visible region and near-infrared region emitted from the light source 23 is reflected by the reflecting mirror 24.
, Reaches the diffraction grating 26, where the light is split and transmitted through the sample, and the transmitted light is detected by the transmitted light detector 29.

On the other hand, the wavelength of the light passing through the sample changes with the rotation of the diffraction grating 26, so that the transmitted light detector 29
, A signal corresponding to the wavelength is continuously detected. Here, the wavelength of the light is, for example, in a visible and near-infrared region of 400 nm to 2500 nm. Next, the transmitted light detector 2
After obtaining the absorbance (absorption spectrum) for each wavelength of light based on the detection result of No. 9, the primary differential absorbance obtained by first differentiating the absorbance, or the second differential absorbance obtained by secondarily differentiating the absorbance is calculated. Then, of the calculated second derivative absorbances, the wavelength which is an index of the protein content is 2
The absorbance at 180 nm and the wavelength as an index of the amylose content in the calculated second derivative absorbance are 1800 n.
The absorbance of m is substituted into a previously calculated taste calculation formula to calculate a taste value.

By the way, immature rice has a significantly higher water content than the average water value of the whole rice at the time of harvesting.
Since there is heat damage during drying in a grain dryer, it is easier to make old rice than sized rice. Further, in the unripe rice, in the storage state after the end of drying, the water content becomes higher than the average moisture value due to the hysteresis effect, so that the deterioration during storage is faster than that of the sized rice as shown in FIG. Therefore, the content of immature rice is, for example, 10
%, The effect appears on the taste of cooked rice.

For example, when the number of storage months is eight months,
As can be seen from FIGS. 5 and 6, the degree of fatty acid is 20 to 22.5 mg with respect to the change in the percentage of immature rice, but the content is such that immature rice with a degree of fatty acid of 30 mg is mixed at the ratio of the percentage of immature rice. It can be said that this is equivalent to a new rice blended with old rice. Therefore, when evaluating the taste of brown rice, it is highly accurate to consider the mixing ratio of immature rice.

Therefore, of the absorbances calculated as described above, the absorbance at a specific wavelength relating to the fatty acids in the brown rice component is as follows:
The absorbance at a wavelength related to chlorophyll, which is an index of the content of immature rice, is determined. Next, the fatty acid degree AF and the mixing ratio CG of immature rice are calculated from the respective absorbances, and for example, a correction coefficient K as shown in FIG. 7 is obtained from the calculation results. Then, the correction coefficient K is used as a coefficient when the taste value is obtained by the above-described taste calculation formula, and the taste value is calculated.

More specifically, when the immature rice mixing ratio CG increases to 5%, 10%, and 15%, the fatty acid degree AF becomes 1
Under 5 mgKOH / 100 g dry weight, the correction coefficient is 1.0, 0.95.0.90 in order, and the immature rice contamination rate C
The correction coefficient value decreases as G increases, that is, the taste value decreases as the immature rice mixing ratio CG increases. Fatty acid degree AF is 25mgKOH / 100g dry weight, AF3
The same tendency applies to the case of 5 mg KOH / 100 g dry weight.

As described above, in this embodiment, in evaluating the taste of brown rice, in addition to the taste evaluation component in the brown rice component, the immature rice contamination rate is taken into consideration, and the tendency of the deterioration of the taste caused by the unripe rice is evaluated in the taste evaluation. Reflected, it can contribute to improving the accuracy of rice taste evaluation. In the above embodiment, the correction coefficient K is determined from the fatty acid degree AF and the immature rice mixing rate CG calculated as described above. Instead, the correction coefficient K is calculated from the fatty acid degree AF and the immature rice mixing rate CG. An old rice conversion index F which is an index of old rice conversion may be obtained by the following equation (8), and the obtained old rice conversion index F may be used when obtaining the above-mentioned taste value.

F = {(CG-5) / 10 + 1} (AF-10) / 10 = (CG / 10 + 0.5) (AF / 10-1) (8) Next, a grain storage device related to the present invention. Temperature control will be described. This grain storage device takes a grain sample prior to storage, detects a moisture value and a rate of immature rice contamination from the sample, and determines a target temperature in the storage room based on both the detected values. During storage, the control device controls the refrigerating compressor motor, which is a cooling source, so that the temperature in the storage room becomes the determined target temperature. When the storage conditions are changed according to the immature rice mixing ratio and stored, the temperature in the storage room becomes appropriate and the deterioration of grain quality can be prevented.

[Brief description of the drawings]

FIG. 1 is a diagram showing an overall configuration of a principle explanation example.

FIG. 2 is a table showing an example of an old rice index.

FIG. 3 is a diagram showing an entire configuration.

FIG. 4 is a block diagram illustrating an example of a control processing system according to the embodiment.

FIG. 5 is a graph showing the relationship between the number of months of storage and the fatty acid level in brown rice.

FIG. 6 is a graph showing the relationship between immature rice mixing ratio and fatty acid level in brown rice when the storage month is 8 months.

FIG. 7 is a table showing an example of a correction coefficient.

[Explanation of symbols]

1 ... light source, 2 ... lens, 3 ... slit, 4 ... chopper,
Reference numeral 5: disk, 5A to 5F: filter, 7: sample set disk, 8: photoelectric detector, 9, 10: ceramic reflector, 11: transparent container, 12: amplifier, 13: A / D converter, 14: operation Device, 15 display, 21 spectroscopic device main body, 22 detection unit, 23 light source, 24 reflecting mirror, 25 diffraction grating driving motor, 26 diffraction grating, 2
7 control circuit, 28 mounting part, 29 transmitted light detector, 3
0: reflected light detector, 31: CPU, 32: memory, 33
... keyboard, 34 ... display device

────────────────────────────────────────────────── ─── Continuation of front page (56) References JP-A-5-60688 (JP, A) JP-A-64-13456 (JP, A) JP-A-3-59443 (JP, A) Research report of Tohoku Agricultural Experiment Station No. 48 (1974) pp. 123-206 Hongdae Agricultural News, No. 22 (1974) pp. 61-71 Proceedings of the Crop Science Society of Japan, Vol. 54, Annex 1 (1985) pp. 136-137 (58) Fields investigated (Int. Cl. ⁷ , DB name) G01N 21/00-21/01 G01N 21/17-21/61

Claims (5)

(57) [Claims] 1. A spectrometer for analyzing components and quality of rice samples were irradiated configured to be able to light of a wavelength of a visible region and near-infrared region, near-infrared absorbance of chlorophyll absorption band
Rice taste evaluation device that corrects the taste evaluation value based on the absorbance of the region . 2. A spectrometer for analyzing components and quality of a rice sample, which is configured to be capable of irradiating light having a wavelength ranging from a visible region to a near-infrared region, and having a near-infrared absorbance in a chlorophyll absorption band.
Rice taste evaluation device that corrects the taste evaluation value based on the absorbance in the infrared region . 3. The taste of rice according to claim 1, wherein a spectral filter of a spectrometer for analyzing the components and quality of the rice sample is provided with a filter for a wavelength in a near infrared region and a filter for a wavelength in a chlorophyll absorption band. Evaluation device. 4. The rice taste evaluation device according to claim 2, wherein the spectroscopic means of the spectroscopic device for analyzing the components and quality of the rice sample is constituted by a diffraction grating for separating continuous wavelengths from a visible region to a near-infrared region. . 5. The rice taste evaluation device according to claim 3, wherein the detector of the spectroscopic device for analyzing the components and quality of the rice sample comprises a transmitted light detector or a reflected light detector.