JP3195615B2 - Hair wash - Google Patents
Hair washInfo
- Publication number
- JP3195615B2 JP3195615B2 JP17332291A JP17332291A JP3195615B2 JP 3195615 B2 JP3195615 B2 JP 3195615B2 JP 17332291 A JP17332291 A JP 17332291A JP 17332291 A JP17332291 A JP 17332291A JP 3195615 B2 JP3195615 B2 JP 3195615B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- present
- protein
- smoothness
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【０００１】[0001]
【産業上の利用分野】本発明は、アルキロイルアルキル
タウリン型陰イオン界面活性剤と、リン脂質と、蛋白質
または蛋白質加水分解物またはそれらの誘導体とを含有
することを特徴とし、洗髪中および乾燥後の毛髪のしな
やかさ、なめらかさ等の使用性に優れ、しかも安全性と
毛髪保護性に優れた毛髪洗浄料に関する。BACKGROUND OF THE INVENTION The present invention is characterized by containing an alkyloylalkyltaurine-type anionic surfactant, a phospholipid, a protein or a protein hydrolyzate or a derivative thereof, and during washing and drying. The present invention relates to a hair cleansing agent which is excellent in usability such as suppleness and smoothness of the subsequent hair, and which is excellent in safety and hair protection.
【０００２】[0002]
【従来の技術】従来、毛髪洗浄料のコンディショニング
成分としてはリン脂質等の油分、蛋白質、蛋白分解物や
第４級窒素含有水溶性ポリマーが広く用いられている。
しかしながら、リン脂質等の油分、蛋白質、蛋白分解物
を含有する毛髪洗浄料は、未だ、髪に十分満足できるな
めらかさを付与するには至っていない。2. Description of the Related Art Conventionally, oils such as phospholipids, proteins, proteolysates, and quaternary nitrogen-containing water-soluble polymers have been widely used as conditioning components of hair cleansing agents.
However, hair cleansers containing oils such as phospholipids, proteins, and proteolysates have not yet been able to impart sufficiently satisfactory smoothness to hair.
【０００３】一方、第４級窒素含有水溶性ポリマーは、
すすぎ中のなめらかさは向上させることはできるが、タ
オルドライ後及び乾燥時については、髪のなめらかさ、
しなやかさ向上効果は認められず、逆にこれらの多量の
配合は乾燥時における髪のゴワツキ、ヘアフライ等につ
ながる傾向があり、その改善が望まれている。On the other hand, quaternary nitrogen-containing water-soluble polymers are:
The smoothness during rinsing can be improved, but after towel drying and when drying, the smoothness of hair,
No suppleness-improving effect is observed. Conversely, a large amount of these compounds tends to lead to hair stiffness, hair fry, and the like during drying, and such improvement is desired.
【０００４】また、洗浄剤には主に起泡洗浄剤としてア
ルキルサルフェート、アルキルエーテルサルフェート等
の陰イオン界面活性剤が配合されるが、これらの界面活
性剤のみでは、皮膚、毛髪に対する洗浄力は有している
ものの、頭皮、頭髪への刺激や手荒れが、懸念される。[0004] Further, anionic surfactants such as alkyl sulfate and alkyl ether sulfate are mainly blended in the detergent as a foaming detergent. However, these surfactants alone have a detergency for skin and hair. Although it has, there is concern about irritation and rough hands on the scalp and hair.
【０００５】[0005]
【発明が解決しようとする課題】本発明は上記のような
背景の下に見出されたもので洗浄剤をすすいでいる時の
なめらかさの向上に加えてタオルドライ後のなめらかな
感触及び完全ドライ後においても、ゴワツキ、ヘアフラ
イ等をおこすことなく、なめらかにしっとりと髪をおち
つかせることのできる、安全性および毛髪保護性の高い
毛髪洗浄料を提供するものである。DISCLOSURE OF THE INVENTION The present invention has been found under the above background, and in addition to improving smoothness when rinsing a detergent, has a smooth feel and completeness after towel drying. An object of the present invention is to provide a hair cleansing agent having a high safety and a high hair protection property, which can smooth and moisten the hair without causing stiffness or hair fly even after drying.
【０００６】[0006]
【課題を解決するための手段】すなわち本発明は、アル
キロイルアルキルタウリン型陰イオン界面活性剤の一種
または二種以上と、リン脂質の一種または二種以上と、
蛋白質、蛋白質加水分解物およびそれらの誘導体の一種
または二種以上とを配合することを特徴とする毛髪洗浄
料を提供するものである。That is, the present invention relates to an alkyloylalkyltaurine-type anionic surfactant, one or more of which, and one or more of phospholipids,
An object of the present invention is to provide a hair cleansing composition characterized by combining one or more of proteins, protein hydrolysates and derivatives thereof.
【０００７】以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be described in detail.
【０００８】本発明に用いられるアルキロイルアルキル
タウリン型陰イオン界面活性剤は、下記一般式(Ａ)で表
わされ、例えばアルキロイル基Ｒ1ＣＯ−としては、例
えばＣ11Ｈ23ＣＯ−、Ｃ13Ｈ27ＣＯ−、Ｃ15Ｈ31ＣＯ
−、Ｃ17Ｈ35ＣＯ−、Ｃ17Ｈ33ＣＯ−、ヤシ油脂肪酸か
ら得られる平均炭素数８ないし20の混合アルキロイル基
等が挙げられ、アルキル基Ｒ2 としてはＣＨ3 −、Ｃ2
Ｈ5 −、Ｃ3 Ｈ7 −が、また対イオンＭとしてはＬi 、
Ｋ、Ｎa 、モノエタノールアミン、ジエタノールアミ
ン、トリエタノールアミン等が挙げられる。The alkylloylalkyltaurine type anionic surfactant used in the present invention is represented by the following general formula (A). Examples of the alkylloyl group R1CO- include, for example, C11H23CO-, C13H27CO-, and C15H31CO.
-, C17H35CO-, C17H33CO-, and mixed alkylloyl groups having an average number of carbon atoms of 8 to 20 obtained from coconut oil fatty acids, and the like.
H5-and C3 H7-, and the counter ion M is Li,
K, Na, monoethanolamine, diethanolamine, triethanolamine and the like.
【０００９】[0009]
【化１】 Embedded image
【００１０】本発明においては、これらアルキロイルア
ルキルタウリン型陰イオン界面活性剤のうちの任意の一
種又は二種以上が選ばれて用いられる。配合量はとくに
限定されないが、毛髪洗浄料全量中、1〜20重量％で、
好ましくは３〜15重量％である。１重量％未満では、本
発明でいう効果は発揮されず、20重量％を超えて配合し
てもそれ以上の効果は期待できない。In the present invention, any one or more of these alkyloylalkyltaurine-type anionic surfactants are selected and used. Although the amount is not particularly limited, it is 1 to 20% by weight based on the total amount of the hair wash,
Preferably it is 3 to 15% by weight. If the amount is less than 1% by weight, the effect of the present invention is not exhibited, and even if the amount exceeds 20% by weight, no further effect can be expected.
【００１１】本発明において用いられるリン脂質として
は、フォスファチジルコリン、フォスファチジルイノシ
トール、フォスファチジルエタノールアミン、フォスフ
ァチジルセリン、スフィンゴミエリン等で、卵黄、大豆
等から抽出される卵黄レシチン、大豆レシチンおよびこ
れらの精製物、水素添加物等であり、また合成物として
はジパルミトイルフォスファチジルコリン等である。The phospholipids used in the present invention include phosphatidylcholine, phosphatidylinositol, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, etc., and yolk lecithin extracted from yolk, soybean, etc. Soy lecithin and purified products thereof, hydrogenated products and the like, and synthetic products thereof include dipalmitoyl phosphatidylcholine and the like.
【００１２】本発明に用いられるリン脂質の配合量は、
毛髪洗浄料全量中の0.001 〜10重量％で、好ましくは0.
01〜５重量％である。0.001 重量％未満ではリン脂質配
合の効果が発揮されず、10重量％を超えると粘度が上り
過ぎ、使用性上好ましくない。The amount of the phospholipid used in the present invention is as follows:
0.001 to 10% by weight of the total amount of the hair wash, preferably 0.1%.
01 to 5% by weight. If the amount is less than 0.001% by weight, the effect of blending the phospholipid is not exhibited.
【００１３】本発明に用いられる蛋白質、蛋白質加水分
解物またはそれらの誘導体としては、コラーゲン、コラ
ーゲン加水分解物、カチオン化加水分解コラーゲン、ヤ
シ油脂肪酸加水分解コラーゲン、ケラチン、ケラチン加
水分解物、カチオン化加水分解ケラチン、エラスチン、
エラスチン加水分解物、カゼイン、カゼインナトリウ
ム、カゼイン加水分解物、ゼラチン、ゼラチン加水分解
物、その他大豆蛋白、小麦蛋白、グルテリン、ホエー粉
末、フィブロイン、グルカゴン、卵白、非熱凝固卵白、
卵白リゾチーム、アルブミンフィブリノーゲン、ヘモグ
ロビン、グロブリンおよびこれらの加水分解物等であ
る。The protein, protein hydrolyzate or derivatives thereof used in the present invention include collagen, collagen hydrolyzate, cationized hydrolyzed collagen, coconut oil fatty acid hydrolyzed collagen, keratin, keratin hydrolyzate, and cationized hydrolyzate. Hydrolyzed keratin, elastin,
Elastin hydrolyzate, casein, casein sodium, casein hydrolysate, gelatin, gelatin hydrolysate, other soybean proteins, wheat protein, glutelin, whey powder, fibroin, glucagon, egg white, non-coagulated egg white,
Examples include egg white lysozyme, albumin fibrinogen, hemoglobin, globulin, and hydrolysates thereof.
【００１４】本発明に用いられる蛋白質、蛋白質加水分
解物またはそれらの誘導体の配合量は、毛髪洗浄料全量
中の0.001 〜10重量％で、好ましくは0.01〜５重量％で
ある。0.001 重量％未満では蛋白質配合の効果が発揮さ
れず、10重量％を超えると粘度が上り過ぎ、使用性上好
ましくない。The amount of the protein, protein hydrolyzate or derivative thereof used in the present invention is 0.001 to 10% by weight, preferably 0.01 to 5% by weight, based on the total amount of the hair washing composition. If the amount is less than 0.001% by weight, the effect of the compounding of the protein is not exerted.
【００１５】本発明の毛髪洗浄料には、上記の必須成分
に加えて洗浄剤に常用されている成分や添加剤を配合す
ることも可能である。即ち、高級アルコール、シリコー
ン油、流動パラフィン、エステル油等の油分、プロピレ
ングリコール、グリセリン、ポリグリセリン、ポリエチ
レングリコール等の保湿剤成分、メチルセルロース、ヒ
ドロキシエチルセルロース等の水溶性高分子、ポリオキ
シエチレン（以下、ＰＯＥという）硬化ヒマシ油、ＰＯ
Ｅアルキルエーテル等の非イオン性界面活性剤、カチオ
ン性界面活性剤、動植物の天然エキスおよびその誘導
体、クエン酸、乳酸等の有機酸、塩化ナトリウム、塩化
カリウム等の無機塩、香料、色剤、酸化防止剤、防腐
剤、キレート剤、紫外線吸収剤等を本発明の効果を損な
わない範囲で適宜配合できる。The hair cleansing composition of the present invention may contain, in addition to the above essential components, components and additives commonly used in cleaning products. That is, higher alcohols, silicone oils, liquid paraffin, oils such as ester oils, humectant components such as propylene glycol, glycerin, polyglycerin, and polyethylene glycol; water-soluble polymers such as methylcellulose and hydroxyethylcellulose; Hardened castor oil, PO
E non-ionic surfactants such as alkyl ethers, cationic surfactants, natural extracts of plants and animals and their derivatives, organic acids such as citric acid and lactic acid, inorganic salts such as sodium chloride and potassium chloride, flavors, coloring agents, An antioxidant, a preservative, a chelating agent, an ultraviolet absorber and the like can be appropriately compounded within a range that does not impair the effects of the present invention.
【００１６】[0016]
【発明の効果】本発明の毛髪洗浄料は、洗髪中および乾
燥後の毛髪のしなやかさ、なめらかさ等の使用性に優
れ、しかも安全性と毛髪保護性に優れるものである。The hair cleansing composition of the present invention has excellent usability such as suppleness and smoothness of hair during and after washing and is excellent in safety and hair protection.
【００１７】[0017]
【実施例】次に実施例によって本発明を更に詳細に説明
するが、本発明はこれにより限定されるものではない。
なお、これに先立ち各実施例で採用した試験法、評価法
を説明する。Next, the present invention will be described in more detail by way of examples, which should not be construed as limiting the present invention.
Prior to this, test methods and evaluation methods adopted in each example will be described.
【００１８】（使用感） （１）洗髪後のなめらかさの評価 テスターが実際に洗髪して、すすいだ後及び自然乾燥後
の髪のなめらかさについて官能評価した。 ○・・・なめらか △・・・少しなめらか ×・・・なめらかでない として表示した。(Feeling of use) (1) Evaluation of smoothness after shampoo The tester actually washed the hair, and organoleptically evaluated the smoothness of the hair after rinsing and after natural drying.・ ・ ・: Smooth △: Slightly smooth ×: Not smooth
【００１９】（皮膚刺激性）皮膚に対する刺激は、界面
活性剤や界面活性剤組成物の蛋白質変性力の強弱（蛋白
質変性率）により評価できることが知られており（特公
昭59-42038号公報）、本発明組成物の皮膚刺激性はこの
評価法に基づき蛋白質変性率により評価した。(Skin irritation) It is known that irritation to the skin can be evaluated by the degree of protein denaturing power (protein denaturation rate) of surfactants and surfactant compositions (Japanese Patent Publication No. 59-42038). The skin irritation of the composition of the present invention was evaluated by the protein denaturation rate based on this evaluation method.
【００２０】（２）蛋白質変性率 水系高速液体クロマトグラフィを利用し、卵白アルブミ
ンｐＨ緩衝溶媒に、試料濃度１％になるように試料を加
えた場合の、卵白アルブミン変性率を２２０ｎｍの吸収
ピークを用いて測定した。 Ｈｏ：卵白アルブミンの220nm 吸収ピークの高さ Ｈｓ：卵白アルブミン緩衝溶媒に試料を加えた時の220n
m 吸収ピークの高さ評価は以下の4 段階評価で行った。 ◎……皮膚刺激性が非常に少ない−卵白アルブミン変性
率30％未満 ○……皮膚刺激性が少ない−卵白アルブミン変性率30％
以上60％未満 △……皮膚刺激性が中程度−卵白アルブミン変性率60％
以上80％未満 ×……皮膚刺激性が強い−卵白アルブミン変性率80％以
上(2) Protein denaturation rate The density of egg white albumin denaturation in the case where a sample was added to an ovalbumin pH buffered solvent at a sample concentration of 1% using aqueous high performance liquid chromatography was determined using the absorption peak at 220 nm. Measured. Ho: Height of the 220 nm absorption peak of ovalbumin Hs: 220 n when the sample was added to the ovalbumin buffered solvent
m The height of the absorption peak was evaluated by the following four-step evaluation. ◎: Very low skin irritation-less than 30% ovalbumin denaturation ○: Low skin irritation-30% ovalbumin denaturation
Not less than 60% △: Moderate skin irritation-60% ovalbumin denaturation
Not less than 80% ×: strong skin irritation-80% or more ovalbumin denaturation rate
【００２１】（毛髪保護性） （３）キューティクル剥離性 化学的な処理を受けていない毛髪の根元から３ｃｍの部
分を１〜1.5 ｃｍにカットし、10％試料溶液中で25〜45
℃にて３時間超音波により強制的に損傷させた。その後
損傷を受けた毛髪の断面を、電子顕微鏡により観察しキ
ューティクルの枚数を計測した。処理前後の、毛髪10本
の平均値から平均キューティクル枚数減少率を求め、キ
ューティクル剥離性を４段階で表示した。 ◎：平均キューティクル減少率20% 未満 ○：平均キューティクル減少率20% 以上50% 未満 △：平均キューティクル減少率50% 以上80% 未満 ×：平均キューティクル減少率80% 以上(Hair Protective Property) (3) Cuticle Peeling Property A 3 cm portion from the root of hair that has not been chemically treated is cut into 1-1.5 cm, and 25-45 in a 10% sample solution.
The cells were forcibly damaged by ultrasonic waves at 3 ° C. for 3 hours. Thereafter, the cross section of the damaged hair was observed with an electron microscope, and the number of cuticles was counted. The average cuticle sheet number reduction rate was determined from the average value of 10 hairs before and after the treatment, and the cuticle peeling property was displayed in four levels. ◎: Average cuticle reduction rate of less than 20% ○: Average cuticle reduction rate of 20% or more and less than 50% △: Average cuticle reduction rate of 50% or more and less than 80% ×: Average cuticle reduction rate of 80% or more
【００２２】実施例１〜４、比較例１〜５ ( 表−１) 内に記載した配合組成よりなるシャンプー組
成物を調製し、その使用性、皮膚刺激性、及び毛髪保護
性を(表−１) に比較例とともに示した。また、添加剤
等を配合した実施例もあわせて記載した。Examples 1 to 4 and Comparative Examples 1 to 5 A shampoo composition having the composition described in (Table 1) was prepared, and its usability, skin irritation and hair protection properties were determined as shown in Table 1. 1) is shown together with a comparative example. Examples in which additives and the like are blended are also described.
【００２３】[0023]
【表１】 この結果から比較例に比べて、本発明の毛髪洗浄料は、
すすいだ後および乾燥後の毛髪のなめらかさ優れ、しか
も安全性と毛髪保護性に優れるものである。[Table 1] From these results, compared to the comparative example, the hair cleansing agent of the present invention is:
It is excellent in smoothness of hair after rinsing and after drying, and is also excellent in safety and hair protection.
【００２４】実施例５ 次の配合組成よりなる毛髪用洗浄料を調製し、実施例１
〜４と同様の方法にて評価した。 この毛髪用洗浄料は、洗髪中、すすいだ後、乾燥後のい
ずれにおいても毛髪になめらかさを付与し、しかも刺激
が少なく、毛髪に対する保護効果に優れたものであっ
た。Example 5 A hair cleansing composition having the following composition was prepared.
-4 were evaluated in the same manner. This hair cleansing agent imparted smoothness to the hair during washing, after rinsing, and after drying, was less irritating, and had an excellent protective effect on hair.
【００２５】実施例６ 次の配合組成よりなる毛髪用洗浄料を調製し、実施例１
〜５と同様の方法にて評価した。 この毛髪用洗浄料は、洗髪中、すすいだ後、乾燥後の
いずれにおいても毛髪になめらかさを付与し、しかも刺
激が少なく、毛髪に対する保護効果に優れたものであっ
た。Example 6 A hair cleansing composition having the following composition was prepared.
To 5 were evaluated in the same manner. This hair cleansing agent imparted smoothness to the hair during washing, after rinsing, and after drying, was less irritating, and had an excellent protective effect on hair.
【００２６】実施例７ 次の配合組成よりなる毛髪用洗浄料を調製し実施例１〜
６と同様の方法にて評価した。 この毛髪用洗浄料は、洗髪中、すすいだ後、乾燥後のい
ずれにおいても毛髪になめらかさを付与し、しかも刺激
が少なく、毛髪に対する保護効果に優れたものであっ
た。Example 7 A hair cleansing composition having the following composition was prepared.
6 and evaluated in the same manner. This hair cleansing agent imparted smoothness to the hair during washing, after rinsing, and after drying, was less irritating, and had an excellent protective effect on hair.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/00 - 7/50 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7/ 00-7/50
Claims (1)
界面活性剤の一種または二種以上と、リン脂質の一種ま
たは二種以上と、蛋白質、蛋白質加水分解物およびそれ
らの誘導体の一種または二種以上とを配合することを特
徴とする毛髪洗浄料。(1) One or more of an alkylloylalkyltaurine-type anionic surfactant, one or more of a phospholipid, and one or more of a protein, a protein hydrolyzate and a derivative thereof. A hair cleansing agent characterized by comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17332291A JP3195615B2 (en) | 1991-06-19 | 1991-06-19 | Hair wash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17332291A JP3195615B2 (en) | 1991-06-19 | 1991-06-19 | Hair wash |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05927A JPH05927A (en) | 1993-01-08 |
| JP3195615B2 true JP3195615B2 (en) | 2001-08-06 |
Family
ID=15958288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17332291A Expired - Fee Related JP3195615B2 (en) | 1991-06-19 | 1991-06-19 | Hair wash |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3195615B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19639598A1 (en) * | 1996-09-26 | 1998-04-02 | Henkel Kgaa | Body cleanser |
| DE19709360A1 (en) * | 1997-03-07 | 1998-09-10 | Dragoco Gerberding Co Gmbh | Protein extract from cereal gluten, its preparation and its use for hair care |
| WO2003040280A1 (en) * | 2001-11-08 | 2003-05-15 | Green & Clean, Inc. | Active natural cleaning material using soybean fatty acids and its manufacture |
| US7247607B2 (en) | 2001-11-08 | 2007-07-24 | Green & Clean, Inc. | Active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof |
| KR20040008916A (en) * | 2002-07-19 | 2004-01-31 | 주식회사 바이오썸 | Hair soap containing ingredients which prevent hair-loss or accelerate hair-growth |
| JP6620623B2 (en) | 2015-03-31 | 2019-12-18 | 日油株式会社 | Hair cleaning composition |
-
1991
- 1991-06-19 JP JP17332291A patent/JP3195615B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05927A (en) | 1993-01-08 |
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