JP3172571B2 - Gas concentration measuring method and device using reference gas concentration adjusting method - Google Patents
Gas concentration measuring method and device using reference gas concentration adjusting methodInfo
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- JP3172571B2 JP3172571B2 JP8969592A JP8969592A JP3172571B2 JP 3172571 B2 JP3172571 B2 JP 3172571B2 JP 8969592 A JP8969592 A JP 8969592A JP 8969592 A JP8969592 A JP 8969592A JP 3172571 B2 JP3172571 B2 JP 3172571B2
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- Japan
- Prior art keywords
- gas
- concentration
- reference gas
- sample
- gas concentration
- Prior art date
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Description
【０００１】[0001]
【産業上の利用分野】本発明は流体変調・比較測定式の
非分散型赤外線ガス分析計を用いた基準ガス濃度調整方
式によるガス濃度測定方法およびその装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for measuring a gas concentration by a reference gas concentration adjusting method using a non-dispersive infrared gas analyzer of a fluid modulation / comparison measurement type.
【０００２】[0002]
【従来の技術】大気中のＣＯ2 濃度を測定する方法とし
て、流体変調方式による比較測定式の非分散型赤外線ガ
ス分析計を用いる方法が公知である。これは比較ガスラ
インとサンプルガスラインとによりそれぞれ基準ガスと
サンプルガスを光学系内に設けたセルに交互に導入し、
光源からセルに照射させた赤外線の透過光をそれぞれ検
出し、その検出差量に基づいてサンプルガスの濃度分析
をおこなうものである。 2. Description of the Related Art As a method for measuring the CO 2 concentration in the atmosphere, a method using a non-dispersive infrared gas analyzer of a comparative measurement type by a fluid modulation method is known. This is to introduce the reference gas and the sample gas alternately into the cell provided in the optical system by the comparison gas line and the sample gas line, respectively.
The infrared light transmitted from the light source to the cell is detected, and the concentration of the sample gas is analyzed based on the detected difference.
【０００３】[0003]
【発明が解決しようとする課題】しかるに、上述した流
体変調方式においても、例えば大気中のＣＯ2 のように
比較的広い範囲で濃度が変動する場合には、測定可能範
囲（フルスケール）を拡大しなければならないという技
術的課題があり、また、スパンドリフトが発生したり、
例えば気圧の変動等により発生するセル内のガス密度の
変化に起因する測定値への影響が無視できないという難
点もある。However, even in the above-mentioned fluid modulation method, when the concentration fluctuates in a relatively wide range such as CO 2 in the atmosphere, the measurable range (full scale) is expanded. Technical issues that must be performed,
For example, there is a disadvantage that the influence on the measured value due to a change in the gas density in the cell caused by a change in the atmospheric pressure or the like cannot be ignored.
【０００４】本発明はこのような実情に鑑みてなされ、
ガス分析計における測定範囲という概念が不要でスパン
ドリフトがなく、かつ感度の安定した基準ガス濃度調整
方式によるガス濃度測定方法およびその装置を提供する
ことを目的としている。[0004] The present invention has been made in view of such circumstances,
It is an object of the present invention to provide a gas concentration measuring method using a reference gas concentration adjusting method which does not require a concept of a measurement range in a gas analyzer, has no span drift, and has a stable sensitivity, and an apparatus therefor.
【０００５】[0005]
【課題を解決するための手段】本発明は上述の課題を解
決するための手段を以下のように構成している。すなわ
ち、第１の発明では、セルに対して基準ガスとサンプル
ガスとを一定周期かつ一定量交互に送給して光源から前
記セルに対して赤外線を照射させ、その透過光を検出器
で受光することによりサンプルガスの濃度分析をおこな
うようにした流体変調・比較測定式のガス分析計を用い
たガス濃度測定方法にあって、前記ガス分析計からの検
出出力がゼロとなるように基準ガスの濃度を調整し、そ
の基準ガスの濃度を以てサンプルガスの濃度となすこと
を特徴としている。According to the present invention, means for solving the above-mentioned problems are constituted as follows. That is, in the first invention, the reference gas and the sample gas are alternately supplied to the cell at a constant period and a constant amount, and the cell is irradiated with infrared rays from the light source, and the transmitted light is received by the detector. A gas concentration measurement method using a fluid modulation / comparison measurement type gas analyzer which performs a concentration analysis of a sample gas by performing a reference gas so that a detection output from the gas analyzer becomes zero. Is adjusted, and the concentration of the reference gas is used as the concentration of the sample gas.
【０００６】第２の発明では、セルに対して基準ガスと
サンプルガスとを一定周期かつ一定量交互に送給して光
源から前記セルに対して赤外線を照射させ、その透過光
を検出器で受光することによりサンプルガスの濃度分析
をおこなうようにした流体変調・比較測定方式のガス分
析計を備えたガス濃度測定装置にあって、前記ガス分析
計からの検出信号を受信しその検出値がゼロとなるよう
に基準ガスの濃度を可変調整する基準ガス調整手段が基
準ガス送給ラインに設けられ、その基準ガス調整手段で
調整した基準ガスの濃度を以てサンプルガスの濃度とな
すことを特徴としている。In the second invention, a reference gas and a sample gas are alternately supplied to a cell at a constant period and a constant amount, and the cell is irradiated with infrared rays from a light source, and the transmitted light is detected by a detector. In a gas concentration measurement device provided with a gas analyzer of a fluid modulation / comparison measurement system which performs concentration analysis of a sample gas by receiving light, a detection signal from the gas analyzer is received, and a detection value thereof is received. Reference gas adjusting means for variably adjusting the concentration of the reference gas to be zero is provided in the reference gas supply line, and the concentration of the reference gas adjusted by the reference gas adjusting means is used as the concentration of the sample gas. I have.
【０００７】[0007]
【作用】流体変調方式による比較測定式のガス分析計で
は、サンプルガスの濃度と基準ガス（比較ガス）の濃度
が等しくなると、ガス分析計からの検出値がゼロになる
という特性がある。よって、基準ガス調整手段により、
ガス分析計からの検出値がゼロとなるように基準ガスの
濃度を調整すれば、その時点における基準ガスの濃度が
サンプルガスの濃度と等しくなり、その値を以てサンプ
ルガスの濃度とすることができる。The gas analyzer of the comparative measurement type based on the fluid modulation method has a characteristic that when the concentration of the sample gas is equal to the concentration of the reference gas (comparison gas), the detected value from the gas analyzer becomes zero. Therefore, by the reference gas adjusting means,
If the concentration of the reference gas is adjusted so that the detected value from the gas analyzer becomes zero, the concentration of the reference gas at that time becomes equal to the concentration of the sample gas, and the value can be used as the concentration of the sample gas. .
【０００８】この場合、いわゆるフルスケールなる概念
そのものが存在せず、ガス分析計の測定可能範囲に関係
なく、基準ガス調整手段の能力により測定範囲が決定さ
れ、ガス分析計の測定可能範囲拡大という技術的課題が
存在しなくなる。In this case, the concept of the so-called full scale itself does not exist, and the measurement range is determined by the capability of the reference gas adjusting means regardless of the measurable range of the gas analyzer. There will be no technical issues.
【０００９】また、基準ガス調整手段によりガス分析計
からの検出値をゼロにするような調整をおこなうため、
ガス分析計のスパンドリフトそのものがなく、その測定
値への影響がなくなる。Further, in order to make the detection value from the gas analyzer zero by the reference gas adjusting means,
There is no span drift of the gas analyzer itself, and the measured value is not affected.
【００１０】さらに、セル内の両ガスの濃度を一致させ
るため、気圧変化や濃度変化があってもガス密度の変化
に起因する測定値への影響もなくなる。[0010] Further, since the concentrations of both gases in the cell are matched, even if there is a change in atmospheric pressure or concentration, there is no influence on the measured value due to the change in gas density.
【００１１】[0011]
【実施例】以下に本発明の実施例を図面に基づいて詳細
に説明する。図１は本発明の基準ガス濃度調整方式によ
るガス濃度測定方法を実施するための測定装置で、符号
１は測定対象となるガスを送給するためのサンプルガス
ライン、２は基準ガスを送給するための比較ガスライン
で、その比較ガスライン２はゼロガス精製器３と標準ガ
スボンベ４に接続された基準ガス調整手段５から基準ガ
スの供給を受け、両ガスライン１，２は共に一定周期で
ガス流路の切り換えをおこなうロータリーバルブ又は電
磁弁等からなる流路切換手段６と２本の接続管７，８を
介して一対のセル９，10のガス導入口に接続される一
方、各セル９，10のガス導出口は排気ライン11に接続さ
れている。Embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 shows a measuring apparatus for carrying out a gas concentration measuring method according to the reference gas concentration adjusting method of the present invention. Reference numeral 1 denotes a sample gas line for supplying a gas to be measured, and 2 denotes a reference gas. The comparison gas line 2 receives the supply of the reference gas from the zero gas purifier 3 and the reference gas adjusting means 5 connected to the standard gas cylinder 4, and both the gas lines 1 and 2 have a constant period. Each of the cells is connected to a gas inlet of a pair of cells 9 and 10 via flow path switching means 6 including a rotary valve or an electromagnetic valve for switching a gas flow path and two connection pipes 7 and 8. The gas outlets 9 and 10 are connected to an exhaust line 11.
【００１２】上述のゼロガス精製器３は、赤外線吸収の
ないガス例えばＮ2 ガスを精製・送給するもので、標準
ガスボンベ４には例えば所定の高濃度なＣＯ2 ガスが充
填されており、基準ガス調整手段５により後述するよう
に検出器16からの検出信号値がゼロとなるように両ガス
（Ｎ2 ，ＣＯ2 ）が混合され、その濃度がサンプルガス
中のＣＯ2 濃度として指示計21に表示されるようになっ
ている。なお、前記ゼロガス精製器３としてはＮ2 ボン
ベを用いてもよく、また、サンプルガスから測定対象成
分（ＣＯ2 ）を除去する吸着剤等を備えたものでもよ
い。その場合は、サンプルガスからゼロガスが精製され
る。The above-mentioned zero gas purifier 3 purifies and supplies a gas having no infrared absorption, for example, N 2 gas. The standard gas cylinder 4 is filled with, for example, a predetermined high-concentration CO 2 gas. As described later, both gases (N 2 , CO 2 ) are mixed by the gas adjusting means 5 so that the detection signal value from the detector 16 becomes zero, and the concentration is determined as the CO 2 concentration in the sample gas by the indicator 21. Is displayed. The zero gas purifier 3 may be an N 2 cylinder, or may be an apparatus provided with an adsorbent for removing a component to be measured (CO 2 ) from a sample gas. In that case, zero gas is purified from the sample gas.
【００１３】上述の各セル９，10の一端側には光源14，
15が設けられ、各セル９，10内に導入されたガスに赤外
線を照射させ、その透過光量の差を他端側に設けたコン
デンサマイクロフォン型の検出器16で周期的に重畳させ
た差圧として検出し、その検出差量を増幅器19で増幅し
て検出信号として出力できるようになっている。なお、
符号17はコンデンサ膜、18は固定極で、一点鎖線で囲ま
れる部分が流体変調方式による比較測定式のガス分析計
20を示している。A light source 14 is provided at one end of each of the cells 9 and 10 described above.
15 is provided, a gas introduced into each of the cells 9 and 10 is irradiated with infrared rays, and a difference in the amount of transmitted light is periodically superimposed by a condenser microphone type detector 16 provided on the other end side. , And the detection difference amount can be amplified by the amplifier 19 and output as a detection signal. In addition,
Reference numeral 17 denotes a condenser membrane, reference numeral 18 denotes a fixed electrode, and a portion surrounded by a chain line is a gas analyzer of a comparative measurement type using a fluid modulation method.
20 is shown.
【００１４】そして、その検出器16からの検出信号は前
述の基準ガス調整手段５に入力され、その基準ガス調整
手段５では、その検出信号値がゼロとなるように、ゼロ
ガス精製器３からのゼロガスおよび標準ガスボンベ４か
らの標準ガスの流量をフィードバック調整し、その基準
ガスの濃度をその時点におけるサンプルガス中のＣＯ2
濃度として指示計21に表示するようにしている。The detection signal from the detector 16 is input to the above-mentioned reference gas adjusting means 5, and the reference gas adjusting means 5 outputs the signal from the zero gas purifier 3 so that the detection signal value becomes zero. The flow rates of the zero gas and the standard gas from the standard gas cylinder 4 are feedback-adjusted, and the concentration of the reference gas is adjusted to the CO 2 in the sample gas at that time.
The density is displayed on the indicator 21.
【００１５】つまり、流体変調方式による比較測定式の
ガス分析計20ではサンプルガスの濃度と基準ガス（比較
ガス）の濃度が等しくなると、そのガス分析計20からの
検出信号値がゼロになるという特性があり、その特性を
利用して上述のように、基準ガスの濃度をサンプルガス
の濃度と等しくなるように調整することにより、その基
準ガスの濃度を以てサンプルガスの濃度とすることがで
きるのである。That is, in the gas analyzer 20 of the comparative measurement type using the fluid modulation method, when the concentration of the sample gas becomes equal to the concentration of the reference gas (comparison gas), the detection signal value from the gas analyzer 20 becomes zero. There is a characteristic, and as described above, by adjusting the concentration of the reference gas to be equal to the concentration of the sample gas using the characteristic, the concentration of the reference gas can be used as the concentration of the sample gas. is there.
【００１６】このような基準ガスの濃度調整をおこなう
基準ガス調整手段５としては、２つのガス流路にそれぞ
れ設けた例えば特公昭５９−４１１２６号公報に示すマ
スフローメータ、および両ガス流路から離間して設けら
れた演算部（ＣＰＵ）を有し、かつその両ガス流路が合
流して比較ガスライン２に接続されるとともに、ゼロガ
スによって希釈された標準ガスの濃度つまりその時点に
おける基準ガスの濃度を換算して指示計21に信号を出力
できるように構成したものを用いる。The reference gas adjusting means 5 for adjusting the concentration of the reference gas is, for example, a mass flow meter provided in each of two gas flow paths as disclosed in Japanese Patent Publication No. 59-41126, and is separated from both gas flow paths. The two gas flow paths are merged and connected to the comparison gas line 2, and the concentration of the standard gas diluted by the zero gas, that is, the reference gas at that time is provided. A device configured to convert the concentration and output a signal to the indicator 21 is used.
【００１７】なお、本発明はセルの数を上記実施例のも
のに限定するものではなく、単一のセルに対して基準ガ
スとサンプルガスとを一定周期かつ一定量交互に送給す
る流体変調方式にも本発明を適用できることはいうまで
もない。The present invention is not limited to the number of cells in the above-described embodiment, but is a fluid modulation system in which a reference gas and a sample gas are alternately supplied to a single cell at a constant period and a constant amount. Needless to say, the present invention can be applied to a system.
【００１８】上述のように、基準ガスの濃度をサンプル
ガスの濃度と一致させる測定方法では、いわゆるフルス
ケールなる概念そのものが存在せず、ガス分析計20の測
定可能範囲とは関係なく、基準ガス調整手段５の能力に
より測定範囲が決定され、ガス分析計20のフルスケール
の拡大という技術的課題が存在しなくなるという利点が
あり、変動幅の大きいＣＯ2 濃度の測定にはまことに好
適である。As described above, in the measuring method for matching the concentration of the reference gas with the concentration of the sample gas, there is no concept of a so-called full scale, and the reference gas is independent of the measurable range of the gas analyzer 20. The measurement range is determined by the capability of the adjusting means 5, and there is an advantage that the technical problem of expanding the full scale of the gas analyzer 20 does not exist, which is particularly suitable for the measurement of the CO 2 concentration having a large fluctuation range.
【００１９】また、ガス分析計20のスパンドリフトその
ものがなく、その測定値への影響がなくなり指示安定性
が向上する。Further, there is no span drift itself of the gas analyzer 20, and there is no influence on the measured value, so that the indication stability is improved.
【００２０】さらに、両セル９，10内のガス濃度を一致
させるため、気圧変化や温度変化があっても、ガス密度
の変化に起因する測定値への影響もなくなり測定値の信
頼性が向上する。Further, since the gas concentrations in the cells 9 and 10 are made to match, even if there is a change in air pressure or a change in temperature, the change in gas density does not affect the measured value, and the reliability of the measured value is improved. I do.
【００２１】[0021]
【発明の効果】以上説明したように、本発明の方法によ
れば、ガス分析計からの検出出力がゼロとなるように基
準ガスの濃度を調整し、その基準ガスの濃度を以てサン
プルガスの濃度とするので、フルスケールを拡大しなく
てもよく、変動幅の大きいＣＯ2 濃度の測定に好適とな
る。As described above, according to the method of the present invention, the concentration of the reference gas is adjusted so that the detection output from the gas analyzer becomes zero, and the concentration of the sample gas is adjusted based on the concentration of the reference gas. Therefore, it is not necessary to enlarge the full scale, which is suitable for measuring the CO 2 concentration having a large fluctuation range.
【００２２】また、ガス分析計のスパンドリフトそのも
のがないので、その測定値への影響がなくなり指示安定
性が向上する。Further, since there is no span drift of the gas analyzer, there is no influence on the measured value and the indication stability is improved.
【００２３】さらに、両セル内のガス濃度を一致させる
ので、気圧変化や温度変化があってもガス密度の変化に
起因する測定値への影響もなくなり測定値の信頼性が向
上する。Further, since the gas concentrations in both cells are made to match, even if there is a pressure change or a temperature change, there is no influence on the measured value due to the change in gas density, and the reliability of the measured value is improved.
【００２４】そして、基準ガスの濃度を可変調整するた
めの基準ガス調整手段として、マスフローメータ等の信
頼性の高い流量制御手段を採用することにより、別途複
雑な回路を設けることなく装置を構成することができ
る。By employing a highly reliable flow control means such as a mass flow meter as a reference gas adjusting means for variably adjusting the concentration of the reference gas, the apparatus can be constructed without providing a separate complicated circuit. be able to.
【図１】本発明の基準ガス濃度調整方式によるガス濃度
測定方法を実施するためのガス濃度測定装置の回路図で
ある。FIG. 1 is a circuit diagram of a gas concentration measuring device for performing a gas concentration measuring method according to a reference gas concentration adjusting method of the present invention.
２…基準ガス送給ライン（比較ガスライン）、５…基準
ガス調整手段、９，10…セル、16…検出器、20…ガス分
析計。2: Reference gas supply line (comparison gas line), 5: Reference gas adjusting means, 9, 10, cell, 16: detector, 20: gas analyzer.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 三輪 勝 三重県員弁郡東員町笹尾西３丁目８番地 の26 (72)発明者 熊崎 脩 愛知県名古屋市天白区島田２丁目301号 (72)発明者 石本 秀一 京都府京都市南区吉祥院宮の東町２番地 株式会社堀場製作所内 (72)発明者 三笠 元 京都府京都市南区吉祥院宮の東町２番地 株式会社堀場製作所内 (72)発明者 嘉田 教夫 京都府京都市南区吉祥院宮の東町２番地 株式会社堀場製作所内 (72)発明者 山田 毅 京都府京都市南区吉祥院宮の東町２番地 株式会社堀場製作所内 (56)参考文献 特開 平２−272361（ＪＰ，Ａ) 特開 平１−174943（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) G01N 21/00 - 21/01 G01N 21/17 - 21/61 ＪＩＣＳＴファイル（ＪＯＩＳ)──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Masaru Miwa 3-8-8 Sasao Nishi, Toin-cho, Inaba-gun, Mie Prefecture (72) Inventor Osamu Kumazaki 2-301 Shimada, Tenpaku-ku, Nagoya City, Aichi Prefecture (72) Invention Person Shuichi Ishimoto 2 Higashi-cho, Kichijoin-gu, Minami-ku, Kyoto, Kyoto, Japan (72) Inventor Mikasa Former Mikasa Moto 2 Higashi-cho, Kichijoin-gu, Kyoto, Kyoto, Japan Norio 2 Higashi-cho, Kichijo-in Palace, Minami-ku, Kyoto, Kyoto, Japan (72) Inventor Takeshi Yamada 2 Higashi-cho, Kichijo-in Palace, Minami-ku, Kyoto, Kyoto, Japan (56) References to HORIBA, Ltd. 2-272361 (JP, A) JP-A-1-174943 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) G01N 21/00-21/01 G01N 21/17-21 / 61 JICST Airu (JOIS)
Claims (2)
を一定周期かつ一定量交互に送給して光源から前記セル
に対して赤外線を照射させ、その透過光を検出器で受光
することによりサンプルガスの濃度分析をおこなうよう
にした流体変調・比較測定式のガス分析計を用いたガス
濃度測定方法であって、前記ガス分析計からの検出出力
がゼロとなるように基準ガスの濃度を調整し、その基準
ガスの濃度を以てサンプルガスの濃度となすことを特徴
とする基準ガス濃度調整方式によるガス濃度測定方法。1. A method according to claim 1, wherein a reference gas and a sample gas are alternately supplied to the cell at a fixed period and a fixed amount, and a light source irradiates the cell with infrared rays, and the transmitted light is received by a detector. A gas concentration measurement method using a fluid modulation / comparison measurement type gas analyzer that performs a concentration analysis of a sample gas, wherein a concentration of a reference gas is adjusted so that a detection output from the gas analyzer becomes zero. A gas concentration measuring method using a reference gas concentration adjusting method, wherein the gas concentration is adjusted and the concentration of the reference gas is used as the sample gas concentration.
を一定周期かつ一定量交互に送給して光源から前記セル
に対して赤外線を照射させ、その透過光を検出器で受光
することによりサンプルガスの濃度分析をおこなうよう
にした流体変調・比較測定方式のガス分析計を備えたガ
ス濃度測定装置において、前記ガス分析計からの検出信
号を受信しその検出値がゼロとなるように基準ガスの濃
度を可変調整する基準ガス調整手段が基準ガス送給ライ
ンに設けられ、その基準ガス調整手段で調整した基準ガ
スの濃度を以てサンプルガスの濃度となすことを特徴と
する基準ガス濃度調整方式によるガス濃度測定装置。2. A method according to claim 1, wherein a reference gas and a sample gas are alternately supplied to the cell at a fixed period and a fixed amount, and a light source irradiates the cell with infrared rays, and the transmitted light is received by a detector. In a gas concentration measurement device provided with a gas analyzer of a fluid modulation / comparison measurement method for performing a concentration analysis of a sample gas, a reference is made so that a detection signal from the gas analyzer is received and the detection value becomes zero. A reference gas concentration adjusting method, wherein reference gas adjusting means for variably adjusting the concentration of gas is provided in a reference gas supply line, and the concentration of the reference gas adjusted by the reference gas adjusting means is used as the concentration of the sample gas. Gas concentration measuring device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8969592A JP3172571B2 (en) | 1992-03-13 | 1992-03-13 | Gas concentration measuring method and device using reference gas concentration adjusting method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8969592A JP3172571B2 (en) | 1992-03-13 | 1992-03-13 | Gas concentration measuring method and device using reference gas concentration adjusting method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05256778A JPH05256778A (en) | 1993-10-05 |
| JP3172571B2 true JP3172571B2 (en) | 2001-06-04 |
Family
ID=13977907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8969592A Expired - Fee Related JP3172571B2 (en) | 1992-03-13 | 1992-03-13 | Gas concentration measuring method and device using reference gas concentration adjusting method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3172571B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7025870B2 (en) | 2001-11-30 | 2006-04-11 | Osaka Sanso Kogyo Ltd. | Method for analyzing the oxygen concentration of a gas |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2022204B1 (en) * | 2018-12-13 | 2020-07-03 | Green Vision Holding Bv | METHOD AND APPARATUS FOR DETERMINING THE CONCENTRATION OF A GASEOUS POLLUTION IN A VERY HIGH PURITY PRODUCT GAS |
-
1992
- 1992-03-13 JP JP8969592A patent/JP3172571B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7025870B2 (en) | 2001-11-30 | 2006-04-11 | Osaka Sanso Kogyo Ltd. | Method for analyzing the oxygen concentration of a gas |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05256778A (en) | 1993-10-05 |
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