JP3168715B2 - Composite material, method for producing composite material, and method for producing molded composite material - Google Patents

Composite material, method for producing composite material, and method for producing molded composite material

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Publication number
JP3168715B2
JP3168715B2 JP21196992A JP21196992A JP3168715B2 JP 3168715 B2 JP3168715 B2 JP 3168715B2 JP 21196992 A JP21196992 A JP 21196992A JP 21196992 A JP21196992 A JP 21196992A JP 3168715 B2 JP3168715 B2 JP 3168715B2
Authority
JP
Japan
Prior art keywords
plate
aluminum
composite material
aluminum alloy
pressing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP21196992A
Other languages
Japanese (ja)
Other versions
JPH0615465A (en
Inventor
憲一郎 柴田
利之 八田
文雄 松山
昌宏 宮本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP21196992A priority Critical patent/JP3168715B2/en
Priority to TW082105174A priority patent/TW286299B/zh
Priority to KR1019930011926A priority patent/KR100269824B1/en
Priority to DE69320881T priority patent/DE69320881T2/en
Priority to EP93110350A priority patent/EP0577069B1/en
Publication of JPH0615465A publication Critical patent/JPH0615465A/en
Priority to US08/450,396 priority patent/US5485950A/en
Application granted granted Critical
Publication of JP3168715B2 publication Critical patent/JP3168715B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本願発明は,複合材,複合材の製
造方法及び複合材成形物の製造方法に関する,詳しくは
例えば調理器具特に電磁加熱式調理器具に用いられる器
物(ただしこれらに限定されるものではない)に有効な
複合材,複合材の製造方法及び複合材成形物の製造方法
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composite material, a method for producing a composite material and a method for producing a composite material molded article, and more particularly to, for example, a cooking utensil, particularly an appliance used in an electromagnetic heating type cooking utensil. The present invention relates to a composite material, a method for producing a composite material, and a method for producing a composite material.

【0002】[0002]

【従来の技術】従来,電磁加熱式調理器具に用いられる
器物,例えば炊飯器内釜は,発熱を受け持つ鉄,ステン
レス等の磁性金属板と導熱を受け持つアルミニウムやア
ルミニウム合金板の複合板材を基材とし,これを後者の
板を内側として深絞り等プレス成形加工して製造する
(内釜内面には炊飯のこびりつき防止のため弗素樹脂の
コーティングを一般には施す)。
2. Description of the Related Art Conventionally, utensils used for electromagnetic heating type cooking utensils, for example, rice cooker inner pots, are made of a base plate made of a magnetic metal plate such as iron or stainless steel which generates heat and an aluminum or aluminum alloy plate which conducts heat. It is manufactured by press-forming such as deep drawing with the latter plate as the inner side (the inner surface of the inner pot is generally coated with a fluororesin to prevent sticking of cooked rice).

【0003】この基材たる複合板材は従来,ロール圧延
によって磁性金属板とアルミニウムまたはアルミニウム
合金板をクラッド(複合化)する方法による材料が用い
られていた(例えば特公昭54−3468号,特公昭5
4−9985号参照)。
Conventionally, the composite plate material as the base material has been a material obtained by cladding (compositing) a magnetic metal plate and an aluminum or aluminum alloy plate by roll rolling (for example, Japanese Patent Publication No. 54-3468, Japanese Patent Publication No. 5
4-9985).

【0004】ロール圧延によるクラッドは多量生産に適
する。しかしロール圧延で作られていたので,アルミニ
ウムまたはアルミニウム合金を圧縮して接合するため板
厚のばらつきが大きく,このためクラッド板をプレス成
形する過程でわれが生じたり,しわが生じる場合が多
く,加工に大きな問題があった。さらに,異物の付着,
きず等が発生しやすく表面研摩が必要等の問題,あるい
は部分的にクラッドの接合強度が弱いものがあり,プレ
ス加工で剥離する等の問題があった。
[0004] The cladding by roll rolling is suitable for mass production. However, since it was made by roll rolling, the aluminum or aluminum alloy was compressed and joined, resulting in large variations in plate thickness. This often caused cracks and wrinkles in the press forming process of the clad plate. There was a big problem in processing. In addition, adhesion of foreign matter,
There are problems such as the necessity of surface polishing or the like because cracks and the like are likely to occur, or the problem that the bonding strength of the clad is partially low and peeled off by press working.

【0005】[0005]

【発明が解決しようとする課題】上記に鑑み,本願発明
は,複合板材の品質を向上させ成形加工上の不良率の低
減を計り,望ましくは更に量産性を高めることを目的と
している。
SUMMARY OF THE INVENTION In view of the above, it is an object of the present invention to improve the quality of a composite plate material, reduce a defective rate in molding, and desirably further increase mass productivity.

【0006】[0006]

【課題を解決するための手段】 本願発明の1つは,鉄,ステンレス等の磁性金属板
とアルミニウムまたはアルミニウム合金板とを熱間一軸
加圧(Axial Hot Pressing)法によ
って接合したことを特徴とする複合材である。
Means for Solving the Problems One of the inventions of the present application is characterized in that a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate are joined by a hot uniaxial pressing (Axial Hot Pressing) method. Composite material.

【0007】 又本願の他の1つの発明は,鉄,ステ
ンレス等の磁性金属板とアルミニウムまたはアルミニウ
ム合金板とを熱間一軸加圧(Axial Hot Pr
essing)法によって接合することを特徴とする複
合材の製造方法である。
Another invention of the present application relates to a method of hot uniaxial pressing of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate (Axial Hot Pr).
(Essing) method.

【0008】 更にまた本願の他の1つの発明は,
鉄,ステンレス等の磁性金属板とアルミニウムまたはア
ルミニウム合金板とを熱間一軸加圧(Axial Ho
t Pressing)法によって接合し,この複合板
材をプレス成形加工,及び/または,打ち抜き,切断加
工することを特徴とする複合材成形物の製造方法であ
る。
[0008] Still another invention of the present application is:
Hot uniaxial pressing of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate (Axial Ho)
(t Pressing) method, and the composite plate material is press-formed and / or punched and cut.

【0009】なお本願の発明の実施の態様として少なく
とも下記が含まれる。 (イ)鉄,ステンレス等の磁性金属板とアルミニウムま
たはアルミニウム合金板との各々の素材板を,中間層を
介在する事なく直接に,熱間一軸加圧(Axial H
ot Pressing)法によって接合することを特
徴とする上記本願のの発明の複合材の製造方法。
[0009] Embodiments of the present invention include at least the following. (A) Direct hot uniaxial pressing (Axial H) of each material plate of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate without intervening an intermediate layer.
The method of manufacturing a composite material according to the invention of the present application, wherein the composite material is joined by an ot pressing method.

【0010】(ロ) 鉄,ステンレス等の磁性金属板と
アルミニウムまたはアルミニウム合金板との各々/また
は片方の素材板の表面に,当該素材板の融点の中間のま
たは同等の融点を有する金属層を形成した後,熱間一軸
加圧(Axial Hot Pressing)法によ
って接合することを特徴とする上記本願のの発明の複
合材の製造方法。
(B) A metal layer having a melting point intermediate or equivalent to the melting point of the material plate is formed on the surface of each and / or one of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate. The method for producing a composite material according to the invention of the present application, wherein the composite material is joined by hot uniaxial pressing (Axial Hot Pressing) after being formed.

【0011】(ハ)鉄,ステンレス等の磁性金属板とア
ルミニウムまたはアルミニウム合金板との各々/または
片方の素材板の表面に,当該素材板の熱膨脹係数の中間
のまたは同等の熱膨脹係数を有する金属層を形成した
後,熱間一軸加圧(AxialHot Pressin
g)法によって接合することを特徴とする上記本願の
の発明の複合材の製造方法。
(C) a metal having an intermediate or equivalent thermal expansion coefficient between the thermal expansion coefficients of the magnetic metal plate such as iron or stainless steel and the aluminum or aluminum alloy plate and / or one of the material plates; After forming the layer, hot uniaxial pressing (AxialHot Pressin)
g) a method for producing a composite material according to the present invention, wherein the composite material is joined by a method g).

【0012】(ニ)素材板の表面に形成する金属層の材
質が,Cu,Al,Ni,Agのいずれかまたは,これ
らの合金であることを特徴とする上記第2の発明の
(ロ)または(ハ)記載の複合材の製造方法。
(D) The material of the metal layer formed on the surface of the material plate is any one of Cu, Al, Ni and Ag or an alloy thereof. Or (c) a method for producing a composite material.

【0013】(ホ)素材板の表面に金属層を形成する方
法が,めっき,蒸着,イオン蒸着,溶融金属浸漬のいず
れかであり,金属層が薄膜又は厚膜状であることを特徴
とする,上記(ロ)または(ハ)記載の複合材の製造方
法。
(E) The method of forming the metal layer on the surface of the material plate is any one of plating, vapor deposition, ion vapor deposition, and immersion in molten metal, and the metal layer is in the form of a thin film or a thick film. , A method for producing a composite material as described in (b) or (c) above.

【0014】(ヘ)予め,鉄,ステンレス等の磁性金属
板に,薄板状の金属層を同時圧延法によりクラッド化し
た素材板を用いる事を特徴とする,上記(ロ)または
(ハ)記載の複合材の製造方法。
(F) The material described in (b) or (c) above, characterized in that a material plate in which a thin metal layer is clad by a simultaneous rolling method on a magnetic metal plate such as iron or stainless steel is used in advance. Of manufacturing composite materials.

【0015】(ト)鉄,ステンレス等の磁性金属板とア
ルミニウムまたはアルミニウム合金板との各々/または
片方の素材板の表面の面粗度を,サンドブラスト等の方
法で,粗くする事を特徴とする,上記(イ),(ロ)ま
たは(ハ)記載の複合材の製造方法。
(G) The surface roughness of each of one and / or one of a magnetic metal plate such as iron and stainless steel and an aluminum or aluminum alloy plate is roughened by a method such as sandblasting. , A method for producing a composite material according to (a), (b) or (c).

【0016】(チ)磁性金属板とアルミニウムまたはア
ルミニウム合金板とを熱間一軸加圧(Axial Ho
t Pressing)法によって接合した後,複合板
材をプレス成形加工,及び/または,打ち抜き,切断加
工する前に,アルミニウムまたはアルミニウム合金板の
表面に弗素樹脂を被覆することを特徴とする上記本願の
の発明の複合材成形物の製造方法。
(H) A magnetic metal plate and an aluminum or aluminum alloy plate are hot uniaxially pressed (Axial Ho).
t Pressing), and before the composite plate is pressed and / or punched and cut, the surface of the aluminum or aluminum alloy plate is coated with a fluororesin. A method for producing the composite material molded article of the invention.

【0017】(リ)一枚の磁性金属板と一枚のアルミニ
ウムまたはアルミニウム合金板を単位組とし,この単位
組の複数を,磁性金属,アルミニウムまたはアルミニウ
ム合金の何れよりも融点の高い分離材を介在させて積み
重ねて,熱間一軸加圧(Axial Hot Pres
sing)法によって接合することを特徴とする上記本
願のの発明の複合材の製造方法。
(1) One magnetic metal plate and one aluminum or aluminum alloy plate are taken as a unit set, and a plurality of the unit sets are made of a separating material having a higher melting point than any of the magnetic metal, aluminum and aluminum alloy. Stacked with intervening, hot uniaxial pressing (Axial Hot Pres
(sing) method, the method for producing a composite material according to the present invention.

【0018】(ヌ)片面に金属層を形成した,一枚の磁
性金属板と一枚のアルミニウムまたはアルミニウム合金
板を単位組とし,この単位組の複数を分離材を介在させ
ることなく積み重ねて,熱間一軸加圧(Axial H
ot Pressing)法によって接合することを特
徴とする上記(ロ)または(ハ)記載の複合材の製造方
法。
(G) One magnetic metal plate and one aluminum or aluminum alloy plate each having a metal layer formed on one surface are made into a unit set, and a plurality of these unit sets are stacked without interposing a separating material. Hot uniaxial pressing (Axial H
(b) or (c), wherein the composite material is joined by an ot pressing method.

【0019】(ル)複合材成形物の用途が電磁調理式器
具であることを特徴とする上記本願のの発明の複合材
成形物の製造方法。
(1) The method of manufacturing a composite material according to the invention of the present application, wherein the use of the composite material is an electromagnetic cooking appliance.

【0020】(オ)熱間一軸加圧(Axial Hot
Pressing)の温度が300℃以上600℃以
下であることを特徴とする上記本願の,またはの
発明の複合材,複合材の製造方法または複合材成形物の
製造方法。
(E) Axial hot pressing (Axial Hot)
(Pressing) temperature of 300 ° C. or more and 600 ° C. or less, the method for producing a composite material, a composite material, or a composite material molded product according to the above or the present invention.

【0021】(ワ)熱間一軸加圧(Axial Hot
Pressing)の圧力が,200Kg/cm
上1000kg/cm以下であることを特徴とする上
記本願の,またはの発明の複合材,複合材の製造
方法または複合材成形物の製造方法。
(W) Hot uniaxial pressing (Axial Hot)
(Pressing) is 200 kg / cm 2 or more and 1000 kg / cm 2 or less, the method for producing a composite material, a composite material, or a composite material molded product according to the present invention or the present invention.

【0022】(カ)熱間一軸加圧(Axial Hot
Pressing)の加圧時間が,10分以上3時間
以下であることを特徴とする上記本願の,または
の発明の複合材,複合材の製造方法または複合材成形物
の製造方法。
(F) Axial hot pressing (Axial Hot)
Pressing time is 10 minutes or more and 3 hours or less. The method for producing a composite material, a composite material, or a composite material molded article according to the above or the present invention, wherein

【0023】(ヨ)熱間一軸加圧(Axial Hot
Pressing)の雰囲気が,減圧または10
orr以下の真空であることを特徴とする上記本願の
,またはの発明の複合材,複合材の製造方法また
は複合材成形物の製造方法。
(A) Axial hot pressing (Axial Hot)
Pressing) atmosphere is reduced pressure or 10 1 t
The method of manufacturing a composite material, a composite material, or a composite material molded article according to the above or the present invention, wherein the vacuum is equal to or less than orr.

【0024】(タ)中間層を介在する事なく直接に,熱
間一軸加圧(Axial Hot Pressing)
により接合する場合の,望ましい条件は,温度が450
℃以上600℃以下,圧力が400Kg/cm以上,
時間が30分以上であることを特徴とする上記(イ)記
載の複合材の製造方法。
(T) Axial hot pressing directly without an intermediate layer
In the case of joining by the method, the preferable condition is that the temperature is 450
℃ to 600 ° C, pressure 400 kg / cm 2 or more,
The method for producing a composite material according to the above (A), wherein the time is 30 minutes or more.

【0025】(レ)熱間一軸加圧(Axial Hot
Pressing)法により温度が300℃以上45
0℃以下,圧力が250Kg/cm以上,時間が30
分以上で接合することを特徴とする上記(ロ),(ハ)
記載の複合材の製造方法。
(D) Axial hot pressing (Axial Hot)
Pressing) the temperature is 300 ° C or more and 45
0 ° C or less, pressure 250 kg / cm 2 or more, time 30 minutes
(B), (c), characterized in that the bonding is performed in more than one minute.
A method for producing the composite material according to the above.

【0026】(ソ)素材板の表面に金属層をめっき法に
より形成させ,熱間一軸加圧(Axial Hot P
ressing)により膜厚は5μm以上,20μm以
下に接合することを特徴とする上記(ロ),(ハ)記載
の複合材成形物の製造方法。
(S) A metal layer is formed on the surface of a material plate by plating, and hot uniaxial pressing (Axial Hot P
The method for manufacturing a composite material molded product according to the above (b) or (c), wherein the bonding is performed so that the film thickness is 5 μm or more and 20 μm or less by pressing.

【0027】(ツ)分離材の厚さが3mm以下であるこ
とを特徴とする上記(リ)記載の複合材の製造方法。
(T) The method for producing a composite material according to (I) above, wherein the thickness of the separating material is 3 mm or less.

【0028】(ネ)分離材がシート状または,薄板状ま
たは,編物,布状または,粉末状であることを特徴とす
る上記(リ)記載の複合材の製造方法。
(F) The method for producing a composite material as described in (i) above, wherein the separating material is in the form of a sheet, a thin plate, a knit, a cloth, or a powder.

【0029】(ナ)分離材の材質がMo(モリブデン)
または,W(タングステン)または,アルマイトまた
は,カーボンまたは,セラミック(アルミナ,ジルコニ
ア,窒化珪素)であることを特徴とする上記(リ)記載
の複合材の製造方法。
(4) The material of the separating material is Mo (molybdenum)
Alternatively, the method for producing a composite material according to the above (1), wherein the composite material is W (tungsten), alumite, carbon, or ceramic (alumina, zirconia, silicon nitride).

【0030】(ラ)熱間一軸加圧(Axial Hot
Pressing)の加圧用型材質が,鉄系合金また
は,セラミックまたは,カーボンであることを特徴とす
る上記本願の,またはの発明の複合材,複合材の
製造方法または複合材成形物の製造方法。
(A) Hot uniaxial pressing (Axial Hot)
Pressing mold material is an iron-based alloy, ceramic, or carbon. The method for producing a composite material, a composite material, or a composite material molded article according to the above or the present invention, wherein the method is a method for producing a composite material.

【0031】(ム)接合強度が,幅5mmの複合板の引
き離し強度で,3Kg以上であることを特徴とする上記
本願の,またはの発明の複合材,複合材の製造方
法または複合材成形物の製造方法。
(G) The composite material, the method for producing a composite material, or the composite material molded article according to the above or the present invention, wherein the joining strength is 3 kg or more as a peeling strength of the composite plate having a width of 5 mm. Manufacturing method.

【0032】(ウ)磁性金属板がフェライト系ステンレ
ス板であることを特徴とする上記(ル)記載の複合材成
形物の製造方法。
(C) The method for producing a composite material molded article according to the above (l), wherein the magnetic metal plate is a ferritic stainless steel plate.

【0033】(イ)アルミニウム合金板がMg−Mn系
アルミニウム合金板であることを特徴とする上記(ル)
記載の複合材成形物の製造方法。
(A) The aluminum alloy plate is a Mg-Mn based aluminum alloy plate.
A method for producing the composite material described in the above.

【0034】(ノ)複合材成形物がアルミニウムまたは
アルミニウム合金の磁性金属側でない表面に弗素樹脂被
覆を有するものであることを特徴とする上記(ル)記載
の複合材成形物の製造方法。
(V) The method for producing a composite material according to the above (1), wherein the composite material has a fluorine resin coating on the surface of the aluminum or aluminum alloy other than the magnetic metal side.

【0035】以下に本願発明を詳細に説明する。Hereinafter, the present invention will be described in detail.

【作用】本願発明に於いて,例えば電磁加熱式調理器具
では鉄,ステンレス等の磁性金属板は,器物の外側とな
る材質であって,誘導加熱の発熱層となる。
According to the present invention, for example, in an electromagnetic heating type cooking utensil, a magnetic metal plate such as iron or stainless steel is a material that is the outside of the vessel and serves as a heating layer for induction heating.

【0036】又,アルミニウムまたはアルミニウム合金
板は,器物の内側となる材質であって,発熱層の熱を拡
散する良好な熱伝導層となる。
Further, the aluminum or aluminum alloy plate is a material which is used as the inside of the object and serves as a good heat conductive layer for diffusing the heat of the heat generating layer.

【0037】アルミニウムまたはアルミニウム合金の磁
性金属板と反対の器物の内面は例えば炊飯のこびりつき
等の防止のため弗素樹脂が被覆されることがある。弗素
樹脂の種類や被覆方法については既に多く技術が公開さ
れている(例えば特開平3−57184号参照)。
The inner surface of the object opposite to the aluminum or aluminum alloy magnetic metal plate may be coated with a fluororesin, for example, to prevent sticking during cooking. Many techniques have been disclosed for the types and coating methods of fluororesins (see, for example, Japanese Patent Application Laid-Open No. 3-57184).

【0038】本願出願人は,熱間等方向加圧法による磁
性金属板とアルミニウムまたはアルミニウム合金板との
接合方法を提案した(特願平3−343870号(特開
平5−116244号公報))が,本願発明は前記課題
に併せ,これの欠点をも解消するものである。
The applicant of the present application has proposed a method of joining a magnetic metal plate and an aluminum or aluminum alloy plate by a hot isodirectional pressing method (Japanese Patent Application No. 3-343870 (Japanese Patent Application Laid-Open No. 5-116244)). The present invention is intended to solve the above-mentioned problems and also to solve the disadvantages.

【0039】即ち熱間等方向加圧とは,加熱機構を内蔵
した高圧容器を使用し,超高圧の不活性ガス(主にAr
ガス)雰囲気中で高圧加熱する。これにより被処理体に
高温加熱と,ガス圧力による等方向圧力の相乗効果を与
え,被処理体を構成する材料に塑性加工や構成成分の拡
散などの現象を与える処理である。
That is, the hot isodirectional pressurization is performed by using a high-pressure container having a built-in heating mechanism and using an ultra-high pressure inert gas (mainly Ar gas).
Gas) High pressure heating in atmosphere. This is a process that gives a synergistic effect of high-temperature heating and isotropic pressure due to gas pressure to the object to be processed, and gives phenomena such as plastic working and diffusion of constituent components to the material constituting the object to be processed.

【0040】この熱間等方向加圧法による長所は,従来
この種複合板材の分野に於いて採用されていたロール圧
延によらず,この熱間等方向加圧法によりクラッド板材
を得ること,しかも拡散金属層を介在させることなく直
接鉄,ステンレス等の磁性金属板とアルミニウムまたは
アルミニウム合金板をクラッドすることを最大の特徴と
していた。
The advantage of the hot isostatic pressing method is that a clad sheet material can be obtained by the hot isodirectional pressing method without using the roll rolling conventionally used in the field of the composite sheet material, and the diffusion is achieved. The greatest feature is that a magnetic metal plate such as iron or stainless steel is directly clad with an aluminum or aluminum alloy plate without any intervening metal layer.

【0041】しかし,この熱間等方向加圧法による欠点
として,高圧ガスを用いるため設備の運転費用が高価,
また,使い捨ての金属カプセルが必要で,カプセルへの
真空封入やカプセルの除去にかなりの手間がかかりコス
トアップの要因になる,点があった。
However, the disadvantage of this hot isostatic pressurization method is that the operation cost of the equipment is high because high-pressure gas is used,
In addition, a disposable metal capsule is required, and it takes a considerable amount of time to vacuum-enclose the capsule and remove the capsule, resulting in an increase in cost.

【0042】本発明では,上記の熱間等方向加圧法に代
り,熱間一軸加圧(Axial Hot Pressi
ng)法により,磁性金属板とアルミニウムまたはアル
ミニウム合金板とを接合するものである。さて,熱間一
軸加圧(Axial Hot Pressing)法自
体は公知である。本法は,従来はセラミックス等の粉末
原料を高密度に焼結するため,臼と杵よりなる型内に原
料粉末を入れ,加熱炉と油圧プレスを備えた装置で温度
と一軸圧力を同時に加えるものである。本発明では従
来,粉末原料が入る部分に,素材板(磁性金属板とアル
ミニウムまたはアルミニウム合金板)と分離材を多層に
積層して入れ,これを熱間一軸加圧(Axial Ho
t Pressing)し,接合する。図2はこれの概
略を示し,図中11は素材板と分離材の積層部,12は
炉体,13はヒーター,14は型(臼),15は型
(杵),16は油圧装置,17は真空ポンプ,18は熱
電対,19は断熱材である。
In the present invention, instead of the above-mentioned hot isostatic pressing method, hot uniaxial pressing (Axial Hot Pressing) is used.
The magnetic metal plate and the aluminum or aluminum alloy plate are joined by the ng) method. Axial hot pressing is itself known. Conventionally, in order to sinter powder materials such as ceramics at a high density, this method puts the material powder in a mold consisting of a die and a punch, and simultaneously applies temperature and uniaxial pressure using a device equipped with a heating furnace and a hydraulic press. Things. In the present invention, a material plate (a magnetic metal plate and an aluminum or aluminum alloy plate) and a separating material are laminated in multiple layers in a portion where a powder raw material enters, and this is subjected to hot uniaxial pressing (Axial Ho).
t Pressing) and joining. FIG. 2 schematically shows this, in which 11 is a laminated portion of the material plate and the separating material, 12 is a furnace body, 13 is a heater, 14 is a mold (die), 15 is a mold (punch), 16 is a hydraulic device, 17 is a vacuum pump, 18 is a thermocouple, and 19 is a heat insulating material.

【0043】本,熱間一軸加圧(Axial Hot
Pressing)法によれば,高圧ガスを用いない
為,設備費,設備運転費が安価であり,また,カプセル
は不要で,型は繰り返し使用できる長所がある。コンプ
レッサーによる,ガス加圧に比べ,油圧ポンプによる加
圧,減圧は迅速で,サイクルタイムも短くする事ができ
る。この簡便な熱間一軸加圧法によっても,接合金属間
または,中間層金属を介した拡散が起こり,実用的に充
分な接合強度が得られる事を見いだしたものである。ま
た,板厚の減少は殆どなく,従って板厚のばらつきが極
めて小さく,また異物の付着,きず等の発生がない。更
にまた接合も部分的に極端に弱い部分もなく従来以上に
強く,プレス加工にも耐えることを本願発明者らは見い
出した。
Axial Hot Press (Axial Hot Press)
According to the pressing method, since high-pressure gas is not used, equipment costs and equipment operation costs are low, and capsules are unnecessary, and the mold can be used repeatedly. The pressurization and decompression by the hydraulic pump are quicker than the gas pressurization by the compressor, and the cycle time can be shortened. It has been found that even with this simple hot uniaxial pressing method, diffusion occurs between bonding metals or via an intermediate layer metal, and practically sufficient bonding strength can be obtained. Further, there is almost no decrease in the thickness of the plate, so that the variation in the thickness of the plate is extremely small, and there is no occurrence of adhesion of foreign matter and flaws. In addition, the present inventors have found that the bonding is stronger than before without any extremely weak portions, and that it can withstand press working.

【0044】熱間一軸加圧(Axial Hot Pr
essing)法の雰囲気としては,大気中,非酸化性
ガス中(Ar,N,He,CO等)でも可能ではあ
るが,接合界面へのガス分子の介在を低減し,接合金属
同志の拡散を促進する為には,減圧または10tor
r以下の真空雰囲気が望ましい。真空度は,高真空であ
るほど望ましいが,経済的には,ロータリーポンプ等で
容易に得られる,10torr程度の真空度でも充分
実用的な接着強度が得られる事が判った。
Hot uniaxial pressing (Axial Hot Pr)
Although the atmosphere of the essing) method can be used in the air or in a non-oxidizing gas (Ar, N 2 , He, CO 2, etc.), the interposition of gas molecules at the bonding interface is reduced, and the bonding metal Reduce pressure or 10 1 torr to promote diffusion
A vacuum atmosphere of r or less is desirable. It is found that the degree of vacuum is preferably as high as possible, but economically, a sufficiently practical adhesive strength can be obtained even with a degree of vacuum of about 10 2 torr, which can be easily obtained with a rotary pump or the like.

【0045】熱間一軸加圧(Axial Hot Pr
essing)法の温度条件としては,300℃以上6
00℃以下が望ましい。300℃未満では,接合すべき
金属間または,中間層の金属原子の原子拡散が不十分と
なり,充分な接合力が得られない。また600℃,を越
える温度では,アルミニウムまたはアルミニウム合金板
が結晶粒成長を起こす結果,強度低下及び,絞り加工工
程での肌あれ等の問題を起こすので,好ましくない。
Hot uniaxial pressing (Axial Hot Pr)
The temperature condition of the essing) method is 300 ° C. or more and 6
It is desirably 00 ° C or less. If the temperature is lower than 300 ° C., the diffusion of metal atoms between the metals to be bonded or the metal atoms in the intermediate layer becomes insufficient, and a sufficient bonding force cannot be obtained. On the other hand, if the temperature exceeds 600 ° C., the aluminum or aluminum alloy plate undergoes crystal grain growth, which causes problems such as a decrease in strength and a rough surface in the drawing process.

【0046】中間層を介在する事なく直接に,熱間一軸
加圧(Axial Hot Pressing)法によ
り接合する場合の望ましい条件は,温度が450℃以上
600℃以下,圧力が400Kg/cm以上,時間が
30分以上である。Al原子とFe,Ni,Cr原子の
相互拡散に適当な温度はやや高温,圧力は高圧側が適当
である。これは,アルミニウムまたはアルミニウム合金
と磁性金属板の表面酸化物層を介しての拡散が必要な為
と推察される。
Desirable conditions when joining directly by an axial hot pressing method without an intermediate layer are as follows: a temperature of 450 ° C. or more and 600 ° C. or less, a pressure of 400 kg / cm 2 or more, The time is 30 minutes or more. The temperature suitable for the interdiffusion between Al atoms and Fe, Ni, Cr atoms is slightly higher, and the pressure is preferably higher. This is presumed to be due to the need to diffuse aluminum or aluminum alloy through the surface oxide layer of the magnetic metal plate.

【0047】Cu,Ni,Al等の金属を中間層として
介在させて,熱間一軸加圧(Axial Hot Pr
essing)法により接合する場合の望ましい条件
は,温度が300℃以上450℃以下,圧力が250K
g/cm以上,時間が30分以上である。Cu,N
i,Al等の金属をめっき等の方法で,素材金属表面に
形成してから,熱間一軸加圧を行った場合,比較的低
温,低圧側でも,中間層が磁性金属板とアルミニウムま
たはアルミニウム合金板の双方に拡散し,継ぎの役割を
果たす為と推察される。温度が高すぎる場合,中間層が
拡散し過ぎて消滅し,接合強度が低下するものと推察さ
れる。また,脆性の金属間化合物の生成も望ましくな
い。
A metal such as Cu, Ni, Al or the like is interposed as an intermediate layer, and hot uniaxial pressing (Axial Hot Pr) is performed.
Desirable conditions for joining by the essing) method are a temperature of 300 ° C. to 450 ° C. and a pressure of 250K.
g / cm 2 or more and time is 30 minutes or more. Cu, N
When a metal such as i, Al or the like is formed on the surface of a material metal by plating or the like and then hot uniaxial pressing is performed, the intermediate layer is formed of a magnetic metal plate and aluminum or aluminum even at a relatively low temperature and a low pressure side. It is presumed that it diffuses into both alloy sheets and plays a role of joint. If the temperature is too high, it is assumed that the intermediate layer is excessively diffused and disappears, and the bonding strength is reduced. Also, the formation of brittle intermetallic compounds is undesirable.

【0048】熱間一軸加圧(Axial Hot Pr
essing)法の圧力条件としては,上記の通り,条
件によっては変動はするが,200Kg/cm以上,
1000Kg/cm未満が適当な範囲といえる。低圧
力で充分な拡散を起こす為には,非経済的な時間を要す
るものであり,過剰な高圧力は,非経済的な設備と,ア
ルミニウムまたはアルミニウム合金板の不必要な変形
(薄肉化)をもたらし,脱型を困難にするものである。
Axial hot pressing (Axial Hot Pr)
As described above, the pressure condition of the essing) method fluctuates depending on the condition, but is 200 kg / cm 2 or more.
An appropriate range is less than 1000 kg / cm 2 . It takes uneconomical time to achieve sufficient diffusion at low pressure, and excessive high pressure can cause uneconomical equipment and unnecessary deformation of aluminum or aluminum alloy plate (thinning). And make demolding difficult.

【0049】本,熱間一軸加圧(Axial Hot
Pressing)法による接合の特徴は,中間層の無
し,有りに関わらず,条件を最適化すれば,実用的な接
合強度が得られる点にある。中間層は,接合条件を低
温,低圧側にシフトすると共に,最適条件下では,大幅
に高い接合強度が得られる利点がある。この点で,中間
層の材質の選定は,重要である。
Axial Hot Press (Axial Hot Press)
The feature of the joining by the pressing method is that a practical joining strength can be obtained by optimizing the conditions regardless of the presence or absence of the intermediate layer. The intermediate layer has the advantage that the joining conditions can be shifted to lower temperatures and lower pressures, and that under the optimal conditions, a significantly higher joining strength can be obtained. In this regard, the selection of the material of the intermediate layer is important.

【0050】中間層の材質を種々検討した結果,Cu,
Ni,Al,Ag等が適当であることが判った。本来,
これらの金属の磁性金属板またはアルミニウムまたはア
ルミニウム合金板との拡散係数の値は,文献等でも十分
には明らかになっていない。しかし,これらの金属の融
点はいずれも,磁性金属板とアルミニウムまたはアルミ
ニウム合金の中間(同等を含む)の融点を有しているこ
とが明らかである。(ここで,同等とは,磁性金属板上
にアルミニウムまたはアルミニウム合金層を形成してか
ら接合することを意味する。以下同様。)
As a result of various studies on the material of the intermediate layer, Cu,
Ni, Al, Ag, etc. were found to be suitable. Originally,
The values of the diffusion coefficients of these metals with a magnetic metal plate or an aluminum or aluminum alloy plate are not sufficiently clarified even in literatures. However, it is clear that the melting points of these metals all have intermediate (including equivalent) melting points between the magnetic metal plate and aluminum or aluminum alloy. (Here, "equivalent" means that an aluminum or aluminum alloy layer is formed on a magnetic metal plate before joining. The same applies hereinafter.)

【0051】中間層の熱膨張係数の観点での整合も重要
である。磁性金属板とアルミニウムまたはアルミニウム
合金とは,熱膨張係数の差が大きく,倍近い差がある。
従って,高温で接合していても,冷却時に界面で応力が
発生し,剥離しやすい傾向にある。上記の中間層の金属
は,いずれも,磁性金属板とアルミニウムまたはアルミ
ニウム合金との中間(同等を含む)の熱膨張係数を有し
ており,これらが界面に介在することが,界面の応力を
緩和し,熱一軸加圧法における接合強度を向上している
ことが推定される。
Matching in terms of the coefficient of thermal expansion of the intermediate layer is also important. The difference in the coefficient of thermal expansion between the magnetic metal plate and aluminum or aluminum alloy is large and nearly double.
Therefore, even when joined at a high temperature, stress is generated at the interface at the time of cooling, and there is a tendency for peeling to occur. Each of the above metals in the intermediate layer has a thermal expansion coefficient intermediate (including equivalent) between the magnetic metal plate and aluminum or aluminum alloy, and the presence of these at the interface reduces the stress at the interface. It is presumed that the bonding was relaxed and the bonding strength in the hot uniaxial pressing method was improved.

【0052】素材板の表面に,予め中間層の金属層を形
成する方法としては,湿式法(めっき,ペースト塗布
等),乾式法(真空蒸着,イオン蒸着,スパッタリング
等)の他,溶射,溶融金属浸漬等で可能である。めっき
法ではCu,Ni,Ag等の金属を比較的安価に,数μ
mから数十μmの厚さの被膜を形成することができる。
また,真空蒸着,イオン蒸着等の乾式法では,純度,密
着性の良いAl,Cu,Ni,Ag等の金属膜(数μm
から数十μmの厚さ)を,無公害で形成することができ
る。また,溶射,溶融金属浸漬等のように,溶融金属を
表面に付着させる事によっても,比較的厚肉の被膜を形
成できる。
The method of forming the intermediate metal layer on the surface of the material plate in advance includes a wet method (plating, paste application, etc.), a dry method (vacuum vapor deposition, ion vapor deposition, sputtering, etc.), thermal spraying, and melting. It is possible by metal immersion or the like. In the plating method, metals such as Cu, Ni, and Ag are relatively inexpensively reduced to several μm.
A film having a thickness of m to several tens μm can be formed.
In a dry method such as vacuum evaporation or ion evaporation, a metal film (several μm) of Al, Cu, Ni, Ag, etc. having good purity and adhesion is used.
To several tens of μm) can be formed without pollution. A relatively thick coating can also be formed by attaching a molten metal to the surface, such as by spraying or immersing the molten metal.

【0053】上記のいずれの方法によって,中間層の金
属層を形成する場合でも,素材板の被膜形成面を,不純
物の汚染などが無いように予め充分に洗浄等の手段でク
リーニングすることが,密着性の向上に有効である。め
っき処理の場合は,予め表面の酸化物を除去する工程を
入れる事が望ましい。蒸着の場合も,グロー放電等の手
段で表面を予め洗浄することが良い。
In any case of forming the intermediate metal layer by any of the above methods, it is necessary to sufficiently clean the surface of the material plate on which the film is to be formed by cleaning or the like in advance so as not to contaminate impurities. It is effective for improving the adhesion. In the case of plating, it is desirable to include a step of removing oxides on the surface in advance. Also in the case of vapor deposition, the surface is preferably cleaned in advance by means such as glow discharge.

【0054】さらに,磁性金属板とアルミニウムまたは
アルミニウム合金板との各々/または片方の素材板の表
面の面粗度をサンドブラスト等の手段で粗くすること
が,中間層の密着性の向上および,中間層を形成しない
直接接合の場合でも,接合強度向上に有効である。これ
は,表面の清浄効果と共に,中間層及び/または接合相
手材の熱間一軸加圧(Axial Hot Press
ing)時の食い込み効果と考えられる。
Furthermore, the surface roughness of the surface of each of the magnetic metal plate and the aluminum or aluminum alloy plate and / or one of the material plates can be made rough by means such as sandblasting to improve the adhesion of the intermediate layer and improve the intermediate layer. Even in the case of direct bonding without forming a layer, it is effective for improving the bonding strength. This is because, together with the cleaning effect of the surface, the hot pressing of the intermediate layer and / or the joining partner is performed by an axial hot press.
ing).

【0055】上記の様に,中間層の被膜を素材板表面に
形成する方法の他に,予め,鉄,ステンレス等の磁性金
属板に,中間層となるべき薄板状の金属層を同時圧延法
によりクラッド化した素材板を用いても良い。例えば,
Cu/ステンレスなどの同時圧延法によるクラッド材
は,市販されており,これを円板状に打ち抜いたものを
素材板として使用すれば,めっき,蒸着などをせずに,
そのまま熱間一軸加圧にかけることができる。
As described above, in addition to the method of forming the coating of the intermediate layer on the surface of the raw material plate, a thin metal layer to be used as the intermediate layer is previously formed on a magnetic metal plate such as iron or stainless steel by the simultaneous rolling method. May be used. For example,
A clad material made of a simultaneous rolling method such as Cu / stainless steel is commercially available. If a material obtained by punching the material into a disk shape is used as a material plate, plating and vapor deposition can be performed without plating.
It can be subjected to hot uniaxial pressing as it is.

【0056】更に熱間一軸加圧(Axial Hot
Pressing)法による接合を,安価に効率的な多
量生産に適合させる方法として,本願発明者らは,以下
の方法が有効である事を見出した。
Further, hot uniaxial pressing (Axial Hot)
The present inventors have found that the following method is effective as a method for adapting the joining by the pressing method to inexpensive and efficient mass production.

【0057】即ち熱間一軸加圧法によって接合するに際
し,一枚の磁性金属板と一枚のアルミニウムまたはアル
ミニウム合金板を単位の組とし,この単位の組の複数
を,磁性金属,アルミニウムまたはアルミニウム合金の
何れよりも融点の高い分離材を介在させて,所定の型内
に積み重ねて熱間一軸加圧を行う。融点が高い事は,即
ち,前述の通り,拡散係数の小さい材料であることを意
味する。拡散係数が小さいと同時に熱間一軸加圧されて
も,磁性金属,アルミニウムまたはアルミニウム合金の
何れとも反応せず,分離材として有効に働く。
That is, when joining by the hot uniaxial pressing method, one magnetic metal plate and one aluminum or aluminum alloy plate are used as a set of units, and a plurality of these sets of units are used as a magnetic metal, aluminum or aluminum alloy. Are stacked in a predetermined mold and subjected to hot uniaxial pressing with a separating material having a higher melting point than any one of the above. A high melting point means that the material has a low diffusion coefficient as described above. Even when the diffusion coefficient is small and hot uniaxial pressing is performed, it does not react with any of the magnetic metal, aluminum or aluminum alloy, and works effectively as a separating material.

【0058】上記によれば,分離材の存在により単位の
組の複数が単位の組毎にクラッドされて取り出すことが
出来る。
According to the above, a plurality of sets of units can be clad and taken out for each set of units due to the presence of the separating material.

【0059】なお分離材としては,例えばアルミナ等の
セラミックシート,カーボンシート等の如きシート状の
もの,又例えばガラスクロス等の如き編物,布状のも
の,或いは粉体状のもの等が採用できる。また,分離材
の材質がMo(モリブデン)または,W(タングステ
ン)または,アルマイトまたは,カーボンまたは,セラ
ミック(アルミナ,ジルコニア,窒化珪素)であっても
分離材として有効である。
As the separating material, for example, a sheet-like material such as a ceramic sheet of alumina or the like, a carbon sheet or the like, a knitted material such as a glass cloth or the like, a cloth-like material, or a powder-like material can be used. . Even if the material of the separating material is Mo (molybdenum), W (tungsten), alumite, carbon, or ceramic (alumina, zirconia, silicon nitride), it is effective as a separating material.

【0060】分離材の厚さ3mm以下で,できるだけ薄
く,耐久性に富む事が必要である。厚肉の分離材は,熱
間一軸加圧の際,型内に積層される素材板の枚数を低減
させる結果になり,経済的に望ましくない。また,あま
りに薄くあるいは低強度の材質は,使い捨てになり,経
済的に望ましくない。
It is necessary that the thickness of the separating material is 3 mm or less, as thin as possible, and high in durability. Thick separators are not economically desirable because they result in a reduction in the number of blanks stacked in the mold during hot uniaxial pressing. Also, materials that are too thin or of low strength are disposable and are not economically desirable.

【0061】なお,片面に中間金属層を形成した素材板
を用いる場合は,中間金属層を内側に包む様に一枚の磁
性金属板と一枚のアルミニウムまたはアルミニウム合金
板を単位の組として積層することができる。この場合,
比較的低温側(300〜400℃)で熱間一軸加圧する
と分離材を使用しなくても,単位の組の複数が単位の組
毎にクラッドされて取り出すことができる。
When a material plate having an intermediate metal layer formed on one side is used, one magnetic metal plate and one aluminum or aluminum alloy plate are laminated as a unit so as to enclose the intermediate metal layer inside. can do. in this case,
When hot uniaxial pressing is performed at a relatively low temperature side (300 to 400 ° C.), a plurality of unit sets can be clad and taken out for each unit set without using a separating material.

【0062】熱間一軸加圧(Axial Hot Pr
essing)の加圧用型の臼は,型内部に積み重ねた
素材板と分離材が,加圧時にずれてくずれないように,
ガイドの役割を果たす。一方上下の杵は,油圧シリンダ
ーの高圧を素材板に伝達するので,高温高圧に耐える材
料が要求される。例えば鉄系耐熱合金または,セラミッ
クまたは,カーボンなどが適当である。
Axial hot pressing (Axial Hot Pr)
The dies of the pressing mold of essing) are designed so that the material plate and the separating material stacked inside the
Serve as a guide. On the other hand, since the upper and lower punches transmit the high pressure of the hydraulic cylinder to the material plate, a material that can withstand high temperature and high pressure is required. For example, an iron-based heat-resistant alloy, ceramic, or carbon is suitable.

【0063】熱間一軸加圧(Axial Hot Pr
essing)法の接合強度は,用途及び要求特性によ
り最適条件を選定することができるが,一般に電磁加熱
式調理器具で後工程で深絞り加工が必要な場合は,幅5
mmの複合板の引き剥し強度で,3Kg以上であること
が,剥離などの問題が起こりにくい最低限の強度である
事が確認された。
Axial hot pressing (Axial Hot Pr)
For the joining strength of the essing) method, optimum conditions can be selected according to the application and required characteristics. However, in general, when deep drawing is required in a post-process of an electromagnetic heating cooker, a width of 5 mm is required.
It was confirmed that the peel strength of the composite board having a thickness of 3 kg or more was the minimum strength at which problems such as peeling did not easily occur.

【0064】なお本願発明に於いて,磁性金属板にフェ
ライト系ステンレス板を用いれば,電磁誘導加熱方式で
の発熱が可能となり,電磁加熱式のジャー炊飯器内釜あ
るいは電磁調理器具用器物として用いることが出来る。
In the present invention, when a ferritic stainless steel plate is used as the magnetic metal plate, heat can be generated by an electromagnetic induction heating method, and the magnetic metal plate is used as an inner pot of an electromagnetically heated jar rice cooker or an electromagnetic cooking utensil. I can do it.

【0065】又本願発明に於いて,アルミニウム合金板
にAg−Mn系アルミニウム合金板を用いれば,耐食性
にすぐれた器物を得ることができる。
In the present invention, if an Ag-Mn-based aluminum alloy plate is used as the aluminum alloy plate, a vessel having excellent corrosion resistance can be obtained.

【0066】[0066]

【実施例】以下に本願発明を実施例を以て説明する。図
1は本願発明の実施例を説明するための簡略縦断正面図
である。図中1は鉄,ステンレス等の磁性金属板,2は
アルミニウムまたははアルミニウム合金板,3は磁性金
属,アルミニウム,アルミニウム合金の何れよりも融点
の高い分離材,4は熱間一軸加圧(Axial Hot
Pressing)用の型の臼,杵を示す。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below with reference to embodiments. FIG. 1 is a simplified vertical sectional front view for explaining an embodiment of the present invention. In the figure, 1 is a magnetic metal plate such as iron or stainless steel, 2 is an aluminum or aluminum alloy plate, 3 is a separating material having a melting point higher than any of magnetic metal, aluminum and aluminum alloy, and 4 is hot uniaxial pressing (Axial) Hot
Pressing die and punch are shown.

【0067】実施例1 アルミニウム2としては材質JIS3004系アルミ合
金MG−110(住友軽金属製)(Mg0.6〜0.8
Mn0.9〜1.1%を含む),サイズ1.5mm厚,
425mmΦのサークル板を用い,ステンレス1として
は0.5mm厚,425mmΦ。のSUS430サーク
ル板を用いた。これらをアルカリによって表面洗浄した
後10枚ずつ交互に積層した。複合板材の単位となる一
枚のアルミニウム板と一枚のステンレス板の組の間には
カーボン薄板3を分離材として用いた。
Example 1 Aluminum 2 was made of JIS 3004 aluminum alloy MG-110 (manufactured by Sumitomo Light Metal) (Mg 0.6 to 0.8).
Mn 0.9-1.1%), size 1.5mm thick,
A circle plate of 425 mmφ is used, and the stainless steel 1 has a thickness of 0.5 mm and 425 mmφ. SUS430 circle plate was used. After washing the surface with alkali, 10 sheets were alternately laminated. A carbon thin plate 3 was used as a separating material between a set of one aluminum plate and one stainless plate as a unit of the composite plate material.

【0068】これをセットとしてカーボン製の型の臼に
入れ,杵を入れて,型全体を熱間一軸加圧(Axial
Hot Pressing)装置の真空炉にセットし
た。真空炉を5×10の真空度に真空引きしながら,
炉を500℃に昇温し,500kg/cmの圧力を油
圧装置を作動させて加圧し,2時間保持した後,減圧,
降温した。この様にして,アルミ/ステンレス貼合わせ
板を得た。
This is put into a set of a die made of carbon as a set, a punch is put therein, and the whole die is subjected to hot uniaxial pressing (Axial).
(Hot Pressing) apparatus. While evacuating the vacuum furnace to a degree of vacuum of 5 × 10 2 ,
The temperature of the furnace was raised to 500 ° C., a pressure of 500 kg / cm 2 was increased by operating a hydraulic device, and the pressure was maintained for 2 hours.
The temperature has dropped. Thus, an aluminum / stainless steel laminated plate was obtained.

【0069】これのアルミ/ステンレス接合強度は5m
m幅で3〜7kgで,従来の圧延によるクラッド材の様
に,部分的に接合強度の著しく低い箇所は無く,均一で
安定した接合強度を示した。また一枚の板厚(t)は
2.0mmで接合による板厚変化は各々みられなかっ
た。又異物の付着,きずの発生もなかった。
The aluminum / stainless steel joint strength is 5 m.
With a width of 3 to 7 kg and a width of 3 to 7 kg, unlike the clad material obtained by the conventional rolling, there was no portion where the joining strength was extremely low, and uniform and stable joining strength was exhibited. The thickness (t) of one sheet was 2.0 mm, and no change in the thickness due to joining was observed. Also, there was no adhesion of foreign matter and no flaw.

【0070】これのアルミ面をNacl水溶液中20ク
ーロン/cmの電気量で電解エッチングを施し,表面
に微細な凹凸を設け,この面に弗素樹脂分散液を塗布
し,焼き付けた。この被覆板を油圧プレスで,深さ14
6mm,内径221mmの炊飯ジャー内釜形状に加工
し,本願発明の器物を得た。器物にはわれ,しわ等の発
生がなかった。
The aluminum surface was subjected to electrolytic etching in an aqueous NaCl solution with an electric quantity of 20 coulombs / cm 2 to provide fine irregularities on the surface, and a fluororesin dispersion was applied to the surface and baked. This covering plate is pressed with a hydraulic press to a depth of 14
It was processed into a rice cooker inner pot shape having a diameter of 6 mm and an inner diameter of 221 mm to obtain a vessel of the present invention. There were no wrinkles, etc., on the objects.

【0071】実施例2〜35 実施例1と全く同様にして,素材板に,各種表面処理を
行ったあと,あるいは,熱間一軸加圧(Axial H
ot Pressing)の温度,圧力,時間条件を変
化させた場合の接合強度と深絞り性を評価した結果を,
表1,2,3,及び4の実施例2以下に示す。同時に,
充分な接合強度の得られない,若干の比較例も表4に示
した。
Examples 2 to 35 In the same manner as in Example 1, the material plate was subjected to various surface treatments, or was subjected to hot uniaxial pressing (Axial H).
The results of evaluating the bonding strength and deep drawability when changing the temperature, pressure, and time conditions of the
The results are shown in Tables 1, 2, 3, and 4 below in Example 2. at the same time,
Table 4 also shows some comparative examples in which sufficient bonding strength could not be obtained.

【0072】[0072]

【表1】 [Table 1]

【0073】[0073]

【表2】 [Table 2]

【0074】[0074]

【表3】 [Table 3]

【0075】[0075]

【表4】 [Table 4]

【0076】以上本願発明を主として電磁加熱式調理器
具用器物について説明したが,本願発明はこれらに決し
て限定されるものではなく,ひろく複合材成形物の製造
に適用できる。
Although the invention of the present application has been mainly described with reference to the electromagnetic heating type cooking utensil, the invention of the present application is by no means limited to these, and can be widely applied to the production of composite material molded products.

【0077】[0077]

【発明の効果】以上説明したように本願発明によると,
プレス成形加工した器物のわれ,しわ,複合板材の剥離
等の発生がなく,不良率が極めて少なくなる。又分離材
を用いて基材となる複数組を同時に熱間一軸加圧すると
きは多量生産が出来コストの低減が可能となる。
As described above, according to the present invention,
There is no occurrence of cracks, wrinkles, peeling of the composite plate, etc. of the press-formed product, and the defect rate is extremely reduced. Further, when a plurality of sets serving as a base material are simultaneously subjected to hot uniaxial pressing by using a separating material, mass production can be performed and cost can be reduced.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本願発明の実施例を説明する図で,基材の複数
組を同時に製造する場合の要部の簡略縦断正面図であ
る。
FIG. 1 is a view for explaining an embodiment of the present invention, and is a simplified vertical sectional front view of a main part when a plurality of sets of base materials are simultaneously manufactured.

【図2】熱間一軸加圧(Axial Hot Pres
sing)法の概略図である。
FIG. 2 Axial Hot Pres
(sing) method.

【符号の説明】[Explanation of symbols]

1 鉄,ステンレス等の磁性金属 2 アルミニウム又はアルミニウム合金板 3 分離材 4 型(臼) 5 型(杵) Reference Signs List 1 magnetic metal such as iron and stainless steel 2 aluminum or aluminum alloy plate 3 separating material 4 type (die) 5 type (punch)

───────────────────────────────────────────────────── フロントページの続き (72)発明者 宮本 昌宏 大阪府泉南郡熊取町大字野田950番地 住友電気工業株式会社 熊取製作所内 (56)参考文献 特開 平5−77353(JP,A) (58)調査した分野(Int.Cl.7,DB名) B23K 20/00 A47J 27/00 A47J 36/02 B32B 15/01 WPI/L(QUESTEL)──────────────────────────────────────────────────続 き Continuation of the front page (72) Inventor Masahiro Miyamoto 950 Noda, Kazatori-cho, Sennan-gun, Osaka Prefecture Sumitomo Electric Industries, Ltd. Kumatori Works (56) References JP-A-5-77353 (JP, A) (58) ) Field surveyed (Int. Cl. 7 , DB name) B23K 20/00 A47J 27/00 A47J 36/02 B32B 15/01 WPI / L (QUESTEL)

Claims (14)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 鉄,ステンレス等の磁性金属板とアルミ
ニウムまたはアルミニウム合金板とを熱間一軸加圧(A
xial Hot Pressing)法によって接合
したことを特徴とする複合材。
1. A hot uniaxial pressing (A) of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate.
A composite material joined by a xial hot pressing (xial hot pressing) method.
【請求項2】 鉄,ステンレス等の磁性金属板とアルミ
ニウムまたはアルミニウム合金板とを熱間一軸加圧(A
xial Hot Pressing)法によって接合
することを特徴とする複合材の製造方法。
2. A hot uniaxial pressing (A) of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate.
(xial Hot Pressing) method.
【請求項3】 鉄,ステンレス等の磁性金属板とアルミ
ニウムまたはアルミニウム合金板とを熱間一軸加圧(A
xial Hot Pressing)法によって接合
し,この複合板材をプレス成形加工,及び/または,打
ち抜き,切断加工することを特徴とする複合材成形物の
製造方法。
3. A hot uniaxial pressing (A) of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate.
(xial Hot Pressing) method, and the composite plate material is subjected to press molding and / or punching and cutting.
【請求項4】 鉄,ステンレス等の磁性金属板とアルミ
ニウムまたはアルミニウム合金板との各々の素材板を,
中間層を介在する事なく直接に,熱間一軸加圧(Axi
al Hot Pressing)法によって接合する
ことを特徴とする,請求項2記載の複合材の製造方法。
4. A material plate of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate,
Direct hot uniaxial pressing (Axi
3. The method according to claim 2, wherein the bonding is performed by an al hot pressing method.
【請求項5】 鉄,ステンレス等の磁性金属板とアルミ
ニウムまたはアルミニウム合金板との各々/または片方
の素材板の表面に,当該素材板の融点の中間のまたは同
等の融点を有する金属層を形成した後,熱間一軸加圧
(AxialHot Pressing)法によって接
合することを特徴とする,請求項2記載の複合材の製造
方法。
5. A metal layer having a melting point in the middle of or equivalent to the melting point of the material plate formed on a surface of each of a material plate of a magnetic metal plate such as iron or stainless steel and an aluminum or aluminum alloy plate. 3. The method according to claim 2, wherein the bonding is performed by an axial hot pressing method.
【請求項6】 鉄,ステンレス等の磁性金属板とアルミ
ニウムまたはアルミニウム合金板との各々/または片方
の素材板の表面に,当該素材板の熱膨脹係数の中間のま
たは同等の熱膨脹係数を有する金属層を形成した後,熱
間一軸加圧(Axial Hot Pressing)
法によって接合することを特徴とする,請求項2記載の
複合材の製造方法。
6. A metal layer having a thermal expansion coefficient intermediate or equal to the thermal expansion coefficient of a material metal plate such as iron or stainless steel and / or one or more material plates of aluminum or an aluminum alloy plate. After forming, hot uniaxial pressing (Axial Hot Pressing)
3. The method for producing a composite material according to claim 2, wherein the joining is performed by a method.
【請求項7】 素材板の表面に形成する金属層の材質
が,Cu,Al,Ni,Agのいずれかまたは,これら
の合金であることを特徴とする,請求項5または6記載
の複合材の製造方法。
7. The composite material according to claim 5, wherein the material of the metal layer formed on the surface of the material plate is one of Cu, Al, Ni, and Ag, or an alloy thereof. Manufacturing method.
【請求項8】 素材板の表面に金属層を形成する方法
が,めっき,蒸着,イオン蒸着,溶融金属浸漬のいずれ
かであり,金属層が薄膜又は厚膜状であることを特徴と
する,請求項5または6記載の複合材の製造方法。
8. A method for forming a metal layer on the surface of a material plate by plating, vapor deposition, ion vapor deposition, or immersion in molten metal, wherein the metal layer is in a thin film or thick film state. A method for producing a composite material according to claim 5.
【請求項9】 予め,鉄,ステンレス等の磁性金属板
に,薄板状の金属層を同時圧延法によりクラッド化した
素材板を用いる事を特徴とする,請求項5または6記載
の複合材の製造方法。
9. The composite material according to claim 5, wherein a material plate in which a thin metal layer is clad by a simultaneous rolling method on a magnetic metal plate such as iron or stainless steel is used in advance. Production method.
【請求項10】 鉄,ステンレス等の磁性金属板とアル
ミニウムまたはアルミニウム合金板との各々/または片
方の素材板の表面の面粗度を,サンドブラスト等の方法
で,粗くする事を特徴とする,請求項4,5または6記
載の複合材の製造方法。
10. The surface roughness of each of one and / or one of a magnetic metal plate such as iron and stainless steel and an aluminum or aluminum alloy plate is roughened by sandblasting or the like. A method for producing a composite material according to claim 4, 5 or 6.
【請求項11】 磁性金属板とアルミニウムまたはアル
ミニウム合金板とを熱間一軸加圧(Axial Hot
Pressing)法によって接合した後,複合板材
をプレス成形加工,及び/または,打ち抜き,切断加工
する前に,アルミニウムまたはアルミニウム合金板の表
面に弗素樹脂を被覆することを特徴とする請求項3記載
の複合材成形物の製造方法。
11. An axial hot pressing of a magnetic metal plate and an aluminum or aluminum alloy plate.
The surface of the aluminum or aluminum alloy plate is coated with a fluororesin before the composite plate is pressed and / or punched or cut after joining by a pressing method. A method of manufacturing a composite material.
【請求項12】 一枚の磁性金属板と一枚のアルミニウ
ムまたはアルミニウム合金板を単位組とし,この単位組
の複数を,磁性金属,アルミニウムまたはアルミニウム
合金の何れよりも融点の高い分離材を介在させて積み重
ねて,熱間一軸加圧(Axial Hot Press
ing)法によって接合することを特徴とする請求項2
記載の複合材の製造方法。
12. A unit set of one magnetic metal plate and one aluminum or aluminum alloy plate, and a plurality of the unit sets are interposed with a separating material having a higher melting point than any of the magnetic metal, aluminum and aluminum alloy. Axial Hot Press (Axial Hot Press)
3. The method according to claim 2, wherein the bonding is performed by an ing method.
A method for producing the composite material according to the above.
【請求項13】 片面に金属層を形成した,一枚の磁性
金属板と一枚のアルミニウムまたはアルミニウム合金板
を単位組とし,この単位組の複数を分離材を介在させる
ことなく積み重ねて,熱間一軸加圧(Axial Ho
t Pressing)法によって接合することを特徴
とする請求項5または6記載の複合材の製造方法。
13. A unit set of one magnetic metal plate and one aluminum or aluminum alloy plate having a metal layer formed on one side, and a plurality of the unit sets are stacked without interposing a separating material, Uniaxial pressurization (Axial Ho
7. The method for producing a composite material according to claim 5, wherein the joining is performed by a (t Pressing) method.
【請求項14】 複合材成形物の用途が電磁加熱式調理
器具であることを特徴とする請求項3記載の複合材成形
物の製造方法。
14. The method of manufacturing a composite material according to claim 3, wherein the use of the composite material is an electromagnetically heated cooking appliance.
JP21196992A 1992-06-29 1992-06-29 Composite material, method for producing composite material, and method for producing molded composite material Expired - Fee Related JP3168715B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP21196992A JP3168715B2 (en) 1992-06-29 1992-06-29 Composite material, method for producing composite material, and method for producing molded composite material
TW082105174A TW286299B (en) 1992-06-29 1993-06-29
KR1019930011926A KR100269824B1 (en) 1992-06-29 1993-06-29 Process for producing composite material , and for producing composite material molding
DE69320881T DE69320881T2 (en) 1992-06-29 1993-06-29 Method for producing a composite material and a molded part from the composite material
EP93110350A EP0577069B1 (en) 1992-06-29 1993-06-29 Process for producing composite material and composite molding from the composite material
US08/450,396 US5485950A (en) 1992-06-29 1995-05-25 Composite material, process for producing composite material, and process for producing composite material molding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21196992A JP3168715B2 (en) 1992-06-29 1992-06-29 Composite material, method for producing composite material, and method for producing molded composite material

Publications (2)

Publication Number Publication Date
JPH0615465A JPH0615465A (en) 1994-01-25
JP3168715B2 true JP3168715B2 (en) 2001-05-21

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ID=16614713

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Country Link
JP (1) JP3168715B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08339884A (en) * 1995-06-12 1996-12-24 Matsushita Electric Ind Co Ltd Heated cooking utensil for electromagnetic induction heating cooking device and manufacture thereof
JP3724955B2 (en) * 1997-08-29 2005-12-07 住友電気工業株式会社 Battery case for secondary battery
JP4666901B2 (en) * 2003-10-31 2011-04-06 学校法人日本大学 Laser welding method and laser welding apparatus
CN1299898C (en) * 2005-05-11 2007-02-14 李一明 Method and equipment for manufacturing composite plate
JP7065478B2 (en) * 2017-11-01 2022-05-12 株式会社小松精機工作所 Metal sheet metal joining device

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