JP3161346B2 - Titanium carbonitride-based cermet throw-away cutting inserts with excellent wear and chipping resistance - Google Patents

Titanium carbonitride-based cermet throw-away cutting inserts with excellent wear and chipping resistance

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Publication number
JP3161346B2
JP3161346B2 JP30605896A JP30605896A JP3161346B2 JP 3161346 B2 JP3161346 B2 JP 3161346B2 JP 30605896 A JP30605896 A JP 30605896A JP 30605896 A JP30605896 A JP 30605896A JP 3161346 B2 JP3161346 B2 JP 3161346B2
Authority
JP
Japan
Prior art keywords
cutting
hardness
flank
excellent wear
cutting edge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP30605896A
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Japanese (ja)
Other versions
JPH10146702A (en
Inventor
隆史 藤澤
清一郎 中村
久史 辻崎
勝尚 野中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
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Mitsubishi Materials Corp
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Priority to JP30605896A priority Critical patent/JP3161346B2/en
Publication of JPH10146702A publication Critical patent/JPH10146702A/en
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Publication of JP3161346B2 publication Critical patent/JP3161346B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、切刃の逃げ面と
すくい面が交わる切刃稜線部(以下、単に切刃稜線部と
云う)と、逃げ面およびすくい面における硬さが相異
し、これによってすぐれた耐摩耗性と耐チッピング性を
具備するようになる炭窒化チタン基サーメット製スロー
アウエイ型切削チップ(以下、単に切削チップと云う)
に関するものである。
BACKGROUND OF THE INVENTION The present invention relates to a cutting edge ridge where a flank and a rake face of a cutting edge intersect (hereinafter simply referred to as a cutting edge ridge), and the flank and the rake face have different hardnesses. , A slow-way type cutting tip made of titanium carbonitride-based cermet which has excellent wear resistance and chipping resistance (hereinafter simply referred to as cutting tip).
It is about.

【0002】[0002]

【従来の技術】従来、一般に例えば特開平3−3250
2号公報などに記載されるように、結合相形成成分とし
てCoおよび/またはNiを3〜20重量%含有し、か
つ内部が1400〜1800のビッカース硬さを有し、
切刃の逃げ面、切刃稜線部、およびすくい面にかけての
表面部に、最高表面硬さがビッカース硬さで2400〜
2800の均一な硬さ分布をもった表面硬化層を形成し
てなる切削チップが知られており、また、これが例えば
鋼などの連続切削や断続切削に用いられていることも知
られている。さらに、上記切削チップが、以下の条件、
すなわち、 (a)焼結温度への昇温速度:1〜3℃/sec、 (b)室温から1200〜1350℃への昇温雰囲気:
0.1torr以下の真空、 (c)1200〜1350℃から焼結温度である148
0〜1560℃への昇温雰囲気:5〜30torrの窒
素雰囲気、 (d)上記焼結温度での保持時間および雰囲気:60〜
90分および5〜30torrの窒素雰囲気、 (e)冷却:0.1torr以下の真空雰囲気で炉冷、 以上(a)〜(e)の条件を満足する条件で、所定の配
合組成を有する圧粉体を焼結することによって製造され
ることも知られている。
2. Description of the Related Art Conventionally, generally, for example, JP-A-3-3250
No. 2, as described in JP-B-2, etc., containing 3 to 20% by weight of Co and / or Ni as a binder phase forming component, and having a Vickers hardness of 1400 to 1800 inside,
The maximum surface hardness is 2400 Vickers hardness on the flank of the cutting edge, the cutting edge ridge, and the surface over the rake face.
A cutting tip formed with a surface hardened layer having a uniform hardness distribution of 2800 is known, and it is also known that the cutting tip is used for continuous cutting or interrupted cutting of, for example, steel. Further, the cutting tip, the following conditions,
(A) Heating rate to sintering temperature: 1 to 3 ° C / sec; (b) Heating atmosphere from room temperature to 1200 to 1350 ° C:
A vacuum of 0.1 torr or less, (c) a sintering temperature of 1200 to 1350 ° C.
Temperature rising atmosphere to 0 to 1560 ° C: nitrogen atmosphere of 5 to 30 torr, (d) Holding time and atmosphere at the above sintering temperature: 60 to
(E) Cooling: furnace cooling in a vacuum atmosphere of 0.1 torr or less, under a condition satisfying the above conditions (a) to (e), a compact having a predetermined compounding composition It is also known to be manufactured by sintering a body.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
に対する省力化および省エネ化の要求は強く、これに伴
い切削加工は高速化の傾向にあるが、上記の表面硬化層
の硬さ分布に変化のない従来切削チップにおいては、こ
れを連続切削や断続切削を高速で行う場合に用いると、
切刃の逃げ面およびすくい面にチッピングが発生し易
く、このため比較的短時間で使用寿命に至るのが現状で
ある。
On the other hand, in recent years, there has been a strong demand for labor saving and energy saving for cutting work, and the cutting work has tended to be accelerated accordingly. In conventional cutting inserts that do not change, if this is used when performing continuous cutting or intermittent cutting at high speed,
Chipping is likely to occur on the flank and rake face of the cutting blade, and at present the service life is reached in a relatively short time.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の表面部に表面硬化層を形
成した従来切削チップに着目し、これのすぐれた耐摩耗
性を保持した状態で、耐チッピング性向上をはかるべく
研究を行った結果、結合相形成成分であるCoおよび/
またはNiの含有量を7〜17重量%と特定した上で、
上記の従来切削チップの焼結条件である(a)〜(e)
の条件のうちの(e)条件の冷却雰囲気を1〜5tor
rの窒素雰囲気とした条件で焼結を行なうと、焼結後の
切削チップの表面部には、切刃稜線部が従来切削チップ
の表面硬化層に比して相対的に高い硬さのビッカース硬
さ(Hv)で2600〜3000の最高表面硬さを示
し、一方逃げ面およびすくい面はこれより相対的に低い
Hv:1800〜2200の最高表面硬さを示す表面硬
化層が形成されるようになり、このような表面硬化層の
形成された切削チップは、これを高速連続切削および高
速断続切削に用いても相対的に高い硬さを有する切刃稜
線部によってすぐれた耐摩耗性が確保され、かつ相対的
に硬さの低い逃げ面およびすくい面によってチッピング
の発生も抑制され、すぐれた切削性能を長期に亘って発
揮するという研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
From the above viewpoint, we focused on the conventional cutting insert with a surface hardened layer formed on the above surface part, and conducted research to improve chipping resistance while maintaining excellent wear resistance. , Co as a binder phase forming component and / or
Or, after specifying the content of Ni as 7 to 17% by weight,
The conditions for sintering the above-mentioned conventional cutting tips are (a) to (e).
The cooling atmosphere of the condition (e) of the conditions (1) to (5)
When sintering is performed under a nitrogen atmosphere of r, the cutting edge after sintering has a Vickers cutting edge with a relatively higher hardness than the surface hardened layer of the conventional cutting tip. The flank face and the rake face exhibit a relatively low Hv: a surface hardened layer exhibiting a maximum surface hardness of 1800 to 2200, which has a maximum surface hardness of 2600 to 3000 in terms of hardness (Hv). The cutting edge with such a hardened layer ensures excellent wear resistance due to the relatively high hardness of the cutting edge ridge even when used for high-speed continuous cutting and high-speed interrupted cutting. In addition, the occurrence of chipping was suppressed by the flank and rake face having relatively low hardness, and a research result that excellent cutting performance was exhibited over a long period of time was obtained.

【0005】この発明は、上記の研究結果に基づいてな
されたものであって、結合相形成成分としてCoおよび
/またはNiを7〜17重量%含有し、かつ内部がH
v:1400〜1800の硬さを有する切削チップの表
面部に、切刃稜線部における最高表面硬さがHv:26
00〜3000を示し、逃げ面およびすくい面における
最高表面硬さがHv:1800〜2200を示す表面硬
化層を形成してなる、すぐれた耐摩耗性と耐チッピング
性を有する切削チップに特徴を有するものである。
The present invention has been made on the basis of the above-mentioned research results, and contains 7 to 17% by weight of Co and / or Ni as a binder phase forming component and has an H inside.
v: On the surface of the cutting tip having a hardness of 1400 to 1800, the maximum surface hardness at the cutting edge ridge is Hv: 26.
It has a feature of a cutting tip having excellent wear resistance and chipping resistance, which is formed by forming a surface hardened layer having a maximum surface hardness of Hv: 1800 to 2200 on the flank and the rake face. Things.

【0006】なお、この発明の切削チップの表面硬化層
における硬さ分布は、結合相形成成分であるCoおよび
/またはNiの含有量を7〜17重量%に特定した上
で、上記の通り従来切削チップの焼結条件である(a)
〜(e)の条件のうちの(e)条件の冷却雰囲気を1〜
5torrの窒素雰囲気とした条件で焼結を行なうこと
により調整される、すなわち、Coおよび/またはNi
の含有量を前記範囲内で低くし、かつ前記(e)条件に
おける窒素雰囲気の圧力を前記範囲内で高くするほど切
刃稜線部と逃げ面およびすくい面の硬さは高くなり、反
対にCoおよび/またはNiの含有量を前記範囲内で高
くし、かつ窒素雰囲気の圧力を低くするほど前記硬さは
低くなるものであり、したがって前記結合相形成成分の
含有量が17重量%を越え、かつ前記窒素雰囲気が1t
orr未満になると、切刃稜線部の最高表面硬さがH
v:2600未満、逃げ面およびすくい面の最高表面硬
さがHv:1800未満となってしまい、所望のすぐれ
た耐摩耗性を確保することができなくなり、一方前記結
合相形成成分の含有量が7重量%未満にして前記窒素雰
囲気が5torrを越えると、切刃稜線部の最高表面硬
さがHv:3000を越え、かつ逃げ面およびすくい面
の最高表面硬さがHv:2200を越えるようになっ
て、切刃にチッピングが発生し易くなるという理由によ
り表面硬化層の硬さ分布を上記の通りに定めたのであ
る。
The hardness distribution in the hardened surface layer of the cutting tip according to the present invention is determined by specifying the content of Co and / or Ni, which is a binder phase forming component, at 7 to 17% by weight, as described above. (A)
The cooling atmosphere of the condition (e) among the conditions (e)
It is adjusted by sintering under the condition of a nitrogen atmosphere of 5 torr, that is, Co and / or Ni
The lower the content of Ni in the above range and the higher the pressure of the nitrogen atmosphere in the above condition (e) in the above range, the higher the hardness of the ridge portion of the cutting edge, the flank face and the rake face, and conversely, Co And / or the higher the Ni content within the above range and the lower the pressure of the nitrogen atmosphere, the lower the hardness. Therefore, the content of the binder phase forming component exceeds 17% by weight, And the nitrogen atmosphere is 1t
If it is less than orr, the maximum surface hardness of the ridge of the cutting edge is H
v: less than 2600, the maximum surface hardness of the flank and rake face is less than Hv: 1800, and it becomes impossible to secure desired excellent wear resistance. On the other hand, the content of the binder phase forming component is reduced. When the nitrogen atmosphere exceeds 5 torr with less than 7% by weight, the maximum surface hardness of the cutting edge ridge portion exceeds Hv: 3000, and the maximum surface hardness of the flank and rake surface exceeds Hv: 2200. Thus, the hardness distribution of the hardened surface layer was determined as described above because chipping easily occurred on the cutting blade.

【0007】[0007]

【発明の実施の形態】つぎに、この発明の切削チップを
実施例により具体的に説明する。原料粉末として、いず
れも0.5〜2μmの範囲内の所定の平均粒径を有する
TiCN[重量比で(以下同じ)、TiC/TiN=5
0/50]粉末、TiN粉末、TaC粉末、NbC粉
末、WC粉末、Mo2 C粉末、VC粉末、ZrC粉末、
Cr32 粉末、(Ti,W,Mo)CN[Ti/W/
Mo=80/10/10、C/N=70/30]粉末、
(Ti,Ta,V)CN[Ti/Ta/V=70/20
/10、C/N=50/50]粉末、(Ti,Ta,N
b)CN[Ti/Ta/Nb=70/15/15、C/
N=60/40]粉末、(Ti,W,Nb)CN[Ti
/W/Nb=80/10/10、C/N=70/30]
粉末、(Ti,Nb,Mo)CN[Ti/Nb/Mo=
60/30/10、C/N=60/40]粉末、(T
i,W)CN[Ti/W=80/20、C/N=70/
30]粉末、Co粉末、およびNi粉末を用意し、これ
ら原料粉末を表1に示される配合組成に配合し、ボール
ミルで24時間湿式混合し、乾燥した後、ton/c
2 の圧力で圧粉体A〜Mをプレス成形し、ついでこれ
ら圧粉体A〜Mを、以下に示す条件、すなわち室温から
1350℃までを0.05torrの真空雰囲気中、
1.5℃/minの昇温速度で昇温し、1350℃に昇
温後、雰囲気を10torrの窒素雰囲気に変えて同じ
昇温速度で1520℃まで昇温し、同じ雰囲気で152
0℃に60分間保持し、最終的にそれぞれ1〜5tor
rの範囲内の所定の窒素雰囲気中で炉冷、の条件で焼結
し、焼結体に0.05mmの丸ホーニングを施すことに
よりISO規格SNMG120408のスローアウエイ
チップ形状をもった本発明切削チップ1〜13をそれぞ
れ製造した。また、比較の目的で、上記の圧粉体A〜M
を用い、これの焼結を、上記の焼結条件のうちの最終工
程である炉冷をいずれも0.05torrの窒素雰囲気
中で行なう以外は同じ条件で従来切削チップ1〜13を
それぞれ製造した。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the cutting insert of the present invention will be described in detail with reference to examples. As a raw material powder, TiCN having a predetermined average particle diameter in the range of 0.5 to 2 μm [weight ratio (the same applies hereinafter), TiC / TiN = 5
0/50] powder, TiN powder, TaC powder, NbC powder, WC powder, Mo 2 C powder, VC powder, ZrC powder,
Cr 3 C 2 powder, (Ti, W, Mo) CN [Ti / W /
Mo = 80/10/10, C / N = 70/30] powder,
(Ti, Ta, V) CN [Ti / Ta / V = 70/20
/ 10, C / N = 50/50] powder, (Ti, Ta, N
b) CN [Ti / Ta / Nb = 70/15/15, C /
N = 60/40] powder, (Ti, W, Nb) CN [Ti
/ W / Nb = 80/10/10, C / N = 70/30]
Powder, (Ti, Nb, Mo) CN [Ti / Nb / Mo =
60/30/10, C / N = 60/40] powder, (T
i, W) CN [Ti / W = 80/20, C / N = 70 /
30] A powder, a Co powder, and a Ni powder are prepared, and these raw material powders are blended in the blending composition shown in Table 1, wet-mixed in a ball mill for 24 hours, dried, and then 1 ton / c.
The green compacts A to M are press-molded at a pressure of m 2 , and then these green compacts A to M are subjected to the following conditions, that is, from room temperature to 1350 ° C. in a vacuum atmosphere of 0.05 torr,
The temperature was raised at a rate of 1.5 ° C./min to 1350 ° C., the atmosphere was changed to a nitrogen atmosphere of 10 torr, the temperature was raised to 1520 ° C. at the same rate, and 152
Hold at 0 ° C. for 60 minutes, and finally 1 to 5 torr
r, sintering in a predetermined nitrogen atmosphere within a predetermined nitrogen atmosphere under furnace cooling conditions, and performing a 0.05 mm round honing on the sintered body to obtain a cutting insert of the present invention having a throw-away insert shape according to ISO standard SNMG120408. 1 to 13 were manufactured respectively. Further, for the purpose of comparison, the above-mentioned green compacts A to M
The conventional cutting tips 1 to 13 were manufactured under the same conditions except that the sintering was performed in a nitrogen atmosphere of 0.05 torr, which was the final step of the above sintering conditions. .

【0008】この結果得られた各種の切削チップについ
て、表面を研磨した状態で、逃げ面およびすくい面のビ
ッカース硬さ(荷重:300g)をそれぞれ任意箇所1
0箇所について測定し、また切刃稜線部は正確な表面硬
さの測定ができないので、任意箇所10箇所の研磨断面
におけるホーニング面から0.05mm内側の位置のビ
ッカース硬さ(荷重:300g)を測定して表面硬さと
し、これから最高表面硬さを選び出し、この結果を表
2、3に内部硬さ(Hv)とともに示した。また、本発
明切削チップ1〜13および従来切削チップ1〜13に
ついて、 被削材:JIS・S45Cの長さ方向等間隔4本縦溝入
り丸棒、 切削速度:300m/min、 送り:0.2mm/rev、 切込実:1.5mm、 切削時間:10分、 の条件で鋼の高速断続切削試験を行ない、切刃の逃げ面
摩耗幅を測定した。これらの測定結果を表2、3に示し
た。
[0008] With respect to the various cutting chips obtained as a result, the Vickers hardness (load: 300 g) of the flank and the rake face (load: 300 g) was determined for each one of the polished surfaces while the surface was polished.
Since the surface hardness cannot be measured accurately at the ridge of the cutting edge, the Vickers hardness (load: 300 g) at a position 0.05 mm inward from the honing surface in the polished cross section at 10 arbitrary points is measured. The surface hardness was measured to determine the maximum surface hardness. The results were shown in Tables 2 and 3 together with the internal hardness (Hv). In addition, for the cutting tips 1 to 13 of the present invention and the conventional cutting tips 1 to 13, work material: JIS S45C, a round bar with four longitudinal grooves at regular intervals in the longitudinal direction, cutting speed: 300 m / min, feed: 0. A high-speed intermittent cutting test of steel was performed under the conditions of 2 mm / rev, actual cutting depth: 1.5 mm, cutting time: 10 minutes, and the flank wear width of the cutting edge was measured. Tables 2 and 3 show the measurement results.

【0009】[0009]

【表1】 [Table 1]

【0010】[0010]

【表2】 [Table 2]

【0011】[0011]

【表3】 [Table 3]

【0012】[0012]

【発明の効果】表2、3に示される結果から、本発明切
削チップ1〜13は、いずれもこれを構成する表面硬化
層における相対的に高い硬さの切刃稜線部と、相対的に
硬さの低い逃げ面およびすくい面によって、すぐれた耐
摩耗性と耐チッピング性を具備するようになることか
ら、苛酷な条件での切削となる鋼の高速断続切削でもチ
ッピングの発生なく、すぐれた切削性能を示すのに対し
て、表面硬化層に相対的硬さ変化のない従来切削チップ
1〜13においては、いずれも表面硬化層における逃げ
面およびすくい面の有する高硬度によって比較的短時間
でチッピングが発生し、使用寿命に至ることが明らかで
ある。上述のように、この発明の切削チップは、これを
構成する表面硬化層の切刃稜線部の有するHv:260
0〜3000の最高表面硬さによってすぐれた耐摩耗性
が確保され、かつ最高表面硬さがHv:1800〜22
00の相対的に硬さのひくい逃げ面およびすくい面によ
ってすぐれた耐チッピング性を有するようになるので、
例えば鋼の高速連続切削は勿論のこと、高速断続切削に
おいても切刃にチッピングの発生なく、長期に亘ってす
ぐれた切削性能を発揮するのである。
From the results shown in Tables 2 and 3, all of the cutting tips 1 to 13 of the present invention have relatively high cutting edge ridges in the surface hardened layer constituting the cutting tips. The flank and rake surfaces with low hardness provide excellent wear resistance and chipping resistance, so that chipping does not occur even in high-speed interrupted cutting of steel, which is cutting under severe conditions. In contrast to the cutting performance, in the conventional cutting tips 1 to 13 in which the surface hardened layer does not change in relative hardness, in a relatively short time due to the high hardness of the flank and rake face in the surface hardened layer. It is evident that chipping occurs and extends the service life. As described above, the cutting tip of the present invention has Hv: 260 of the cutting edge ridge portion of the surface hardened layer constituting the cutting tip.
Excellent wear resistance is ensured by the maximum surface hardness of 0 to 3000, and the maximum surface hardness is Hv: 1800 to 22
Since the relatively hard flank and rake face of 00 have excellent chipping resistance,
For example, not only in high-speed continuous cutting of steel but also in high-speed intermittent cutting, chipping does not occur on the cutting edge, and excellent cutting performance is exhibited over a long period of time.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 辻崎 久史 茨城県結城郡石下町大字古間木1511番地 三菱マテリアル株式会社 筑波製作所 内 (72)発明者 野中 勝尚 茨城県結城郡石下町大字古間木1511番地 三菱マテリアル株式会社 筑波製作所 内 (56)参考文献 特開 平3−32502(JP,A) 特開 平2−15139(JP,A) 特開 昭63−57732(JP,A) (58)調査した分野(Int.Cl.7,DB名) B23B 27/14 C22C 29/04 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Hisashi Tsujizaki 1511 Furamagi, Ishishita-cho, Yuki-gun, Ibaraki Prefecture Inside the Tsukuba Works, Mitsubishi Materials Corporation (72) Inventor Katsuhisa Nonaka 1511 Furimagi, Ishishita-cho, Yuki-gun, Ibaraki Prefecture Address Mitsubishi Materials Corporation Tsukuba Works (56) References JP-A-3-32502 (JP, A) JP-A-2-15139 (JP, A) JP-A-63-57732 (JP, A) (58) Survey Field (Int. Cl. 7 , DB name) B23B 27/14 C22C 29/04

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】結合相形成成分としてCoおよび/または
Niを7〜17重量%含有し、かつ内部が1400〜1
800のビッカース硬さを有する炭窒化チタン基サーメ
ット製スローアウエイ型切削チップの表面部に、切刃の
逃げ面とすくい面が交わる切刃稜線部における最高表面
硬さがビッカース硬さで2600〜3000を示し、逃
げ面およびすくい面における最高表面硬さがビッカース
硬さで1800〜2200を示す表面硬化層を形成した
ことを特徴とする、すぐれた耐摩耗性と耐チッピング性
を有する炭窒化チタン基サーメット製スローアウエイ型
切削チップ。
The present invention contains 7 to 17% by weight of Co and / or Ni as a binder phase-forming component, and has an interior of 1400 to 1%.
The maximum surface hardness at the cutting edge ridge line where the flank of the cutting edge and the rake face intersect with the surface of a titanium carbonitride-based cermet throw-away type cutting tip having a Vickers hardness of 800 is 2600 to 3000 Vickers hardness. And a surface hardened layer having a Vickers hardness of 1800 to 2200 as the maximum surface hardness at the flank and rake faces, and having excellent wear resistance and chipping resistance. Cermet throwaway cutting insert.
JP30605896A 1996-11-18 1996-11-18 Titanium carbonitride-based cermet throw-away cutting inserts with excellent wear and chipping resistance Expired - Fee Related JP3161346B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30605896A JP3161346B2 (en) 1996-11-18 1996-11-18 Titanium carbonitride-based cermet throw-away cutting inserts with excellent wear and chipping resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30605896A JP3161346B2 (en) 1996-11-18 1996-11-18 Titanium carbonitride-based cermet throw-away cutting inserts with excellent wear and chipping resistance

Publications (2)

Publication Number Publication Date
JPH10146702A JPH10146702A (en) 1998-06-02
JP3161346B2 true JP3161346B2 (en) 2001-04-25

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE519832C2 (en) * 1999-05-03 2003-04-15 Sandvik Ab Titanium-based carbonitride alloy with binder phase of cobalt for easy finishing
SE519834C2 (en) * 1999-05-03 2003-04-15 Sandvik Ab Titanium-based carbonitride alloy with binder phase of cobalt for tough machining
JP4969533B2 (en) * 2008-08-25 2012-07-04 京セラ株式会社 Ti-based cermet
JP2014094163A (en) 2012-11-09 2014-05-22 3M Innovative Properties Co Cutter blades

Also Published As

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JPH10146702A (en) 1998-06-02

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