JP3130513U - High pressure gas cartridge - Google Patents

High pressure gas cartridge Download PDF

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JP3130513U
JP3130513U JP2007000154U JP2007000154U JP3130513U JP 3130513 U JP3130513 U JP 3130513U JP 2007000154 U JP2007000154 U JP 2007000154U JP 2007000154 U JP2007000154 U JP 2007000154U JP 3130513 U JP3130513 U JP 3130513U
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pressure gas
sealing plate
gas cartridge
tin
gas
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敏夫 入江
清隆 伊藤
重徳 酒井
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Asahi Seisakusho Co Ltd
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Abstract

【課題】長期間に亘って封板の腐食が生じない高圧ガスカートリッジ、特に内容積が10〜500ml程度の小型高圧ガスカートリッジを提供する。
【解決手段】高圧ガスカートリッジを容器本体にティンフリー鋼板またはニッケルめっき鋼板の何れかから選ばれた封板3を装着する。この場合において、封板の厚さを0.2〜0.6mm、降伏強度を200〜500MPaの範囲に取ることができる。
【選択図】図1
A high-pressure gas cartridge that does not cause corrosion of a sealing plate over a long period of time, particularly a small high-pressure gas cartridge having an internal volume of about 10 to 500 ml.
A high pressure gas cartridge is mounted on a container body with a sealing plate 3 selected from a tin-free steel plate or a nickel-plated steel plate. In this case, the sealing plate can have a thickness of 0.2 to 0.6 mm and a yield strength of 200 to 500 MPa.
[Selection] Figure 1

Description

本考案は、高圧ガスカートリッジ、特に内容積が500ml以下の小型の高圧ガスカートリッジに関する。   The present invention relates to a high-pressure gas cartridge, and more particularly to a small high-pressure gas cartridge having an internal volume of 500 ml or less.

高圧ガスカートリッジ、特に内容積が500ml以下の小型の高圧ガスカートリッジは、種々の用途に利用される。例えば、炭酸ガスを封入した高圧ガスカートリッジは炭酸水の製造装置、生ビール用サーバー等の食品押出し用装置、ライフジャケット、加圧式消火器、コンピューターやカメラなどの精密機器の除塵用ブロワー、水槽内の水草育成用の炭酸ガス供給源として利用されている。また、酸素ガスを封入したカートリッジは、火災の際の有毒ガス吸入防止用器具や酸素欠乏対策器具に利用されるほか、心臓病などの携帯酸素吸入器の酸素供給源として利用されている。このような高圧ガスカートリッジには、その性質上、長期間に亘りガス漏れ等を生ずることなく、正常なガス圧を保持することが求められる。   A high-pressure gas cartridge, particularly a small high-pressure gas cartridge having an internal volume of 500 ml or less, is used for various applications. For example, high-pressure gas cartridges filled with carbon dioxide gas are used for carbonated water production equipment, food extrusion equipment such as draft beer servers, life jackets, pressurized fire extinguishers, dust blowers for precision equipment such as computers and cameras, and water tanks. It is used as a carbon dioxide supply source for aquatic plants. In addition, the cartridge in which oxygen gas is sealed is used as an oxygen supply source for portable oxygen inhalers such as heart disease as well as a device for preventing toxic gas inhalation and an oxygen deficiency countermeasure device in the event of a fire. Such a high-pressure gas cartridge is required to maintain a normal gas pressure without causing a gas leak or the like over a long period of time due to its nature.

かかる高圧ガスカートリッジは、一般に、厚さ約2mm程度の超深絞り冷間圧延鋼板を有底の円筒体にプレス成形した後、開口部近傍を誘導加熱により軟化して口金部の成形加工を行い、ついで必要に応じてねじ切りを行った後、潤滑油の脱脂を行い、得られた口金部付きの有底円筒体に炭酸ガス、窒素ガス等のガスを封入しながら封板の溶着を行い、最後に外面に防錆用亜鉛めっき等の防錆処理を施して製造される。これら一連の工程により高圧ガスカートリッジが長期間に亘って保管されるときの本体および封板の腐食が防止されるようになっている。なお、これら高圧ガスカートリッジは、一般に、10〜500ml程度の内容積を有する。   In general, such a high-pressure gas cartridge is formed by pressing an ultra-deep-drawn cold-rolled steel sheet having a thickness of about 2 mm into a bottomed cylindrical body, and then softening the vicinity of the opening by induction heating to form the die part. Then, after threading as necessary, the lubricating oil is degreased, and the sealing plate is welded while carbon dioxide gas, nitrogen gas or the like is sealed in the obtained bottomed cylindrical body with the base part. Finally, the outer surface is manufactured by subjecting it to rust prevention treatment such as galvanization for rust prevention. The series of steps prevents corrosion of the main body and the sealing plate when the high-pressure gas cartridge is stored for a long period of time. These high-pressure gas cartridges generally have an internal volume of about 10 to 500 ml.

しかしながら、製造・出荷時に正常なガス圧を有し、かつガス漏れのない高圧ガスカートリッジであっても、時間の経過とともに僅かずつガス漏れによる機能低下を生ずるものがあり、長期間保管後の使用に当たって十分な信頼性を確保するのが困難な場合がある。このような時間経過によるガス漏れは、特に封板部分での腐食進行に起因するものが多いことが知られている。   However, even high-pressure gas cartridges that have normal gas pressure at the time of manufacture and shipment, and that do not leak gas, may gradually deteriorate in function due to gas leakage over time. In some cases, it may be difficult to ensure sufficient reliability. It is known that such gas leakage due to the passage of time is often caused by the progress of corrosion particularly in the sealing plate portion.

例えば、加圧式消火器に内蔵されている高圧ガスカートリッジは、消火器内に組み込んだ状態で、例えば家庭内で長期間に亘って保管すると、時間の経過とともに僅かずつガス漏れによる機能低下を生ずるものがあり、緊急時の使用に備えて十分な信頼性を確保するのが困難な場合があることも指摘されている。   For example, when a high-pressure gas cartridge built in a pressurized fire extinguisher is stored in a fire extinguisher for a long period of time, for example, in a home, the function is gradually deteriorated due to gas leakage over time. Some have pointed out that it may be difficult to ensure sufficient reliability for emergency use.

かかる問題を解決するための手段として、特許文献1には、消火薬剤押し出し用の加圧ガスを内蔵した消火器であって、該消火器の一部には、容器内のガスが漏出した際に漏出ガスと接触して発色又は変色することによりガス漏れを表示する手段を備えてなる加圧式消火器が提案されている。   As means for solving such a problem, Patent Document 1 discloses a fire extinguisher containing a pressurized gas for extinguishing a fire extinguishing agent, and when a gas in a container leaks into a part of the fire extinguisher. There has been proposed a pressurized fire extinguisher comprising means for displaying gas leakage by developing or changing color in contact with leakage gas.

特許文献1に記載の手段は、適正な管理が行われれば、一定の効果を収めることが予測される。しかしながら、かかる手段は、長期間の保存において封板の腐食等によるガス漏れのあることを前提としており、漏れを防止するための抜本的対策になっていない。特に、一般家庭などのように必ずしも管理が確実に行われず、消火器が放置されるような場合には、先に述べた封板の腐食等によるガス漏れのため、緊急時に消火能力が不足するという問題を生ずる危険性がある。また、かかるガス漏れにより消火液が消火器から漏出して家庭内の消火器保管場所、例えば床やカーペットなどを汚染するおそれもある。   The means described in Patent Document 1 is expected to have a certain effect if proper management is performed. However, such means are based on the premise that there is gas leakage due to corrosion of the sealing plate during long-term storage, and are not a radical measure for preventing leakage. In particular, when a fire extinguisher is left uncontrolled, such as in a general home, the fire extinguishing capability is insufficient in an emergency due to gas leakage due to corrosion of the sealing plate described above. There is a risk of causing problems. Moreover, there is a possibility that the fire extinguishing liquid may leak from the fire extinguisher due to such gas leakage and contaminate a fire extinguisher storage place such as a floor or a carpet in the home.

上記の諸問題を解決するための手段として封板の素材をめっき鋼板とすることが考えられる。しかしながら、封板の腐食防止の目的で例えば錫めっき鋼板を用いた場合は、口金部付きの有底円筒体に封板を抵抗溶接するとき、めっき成分の錫が溶接電極の金属銅と合金を形成し、めっきのない薄鋼板の場合は400点以上電極面の研磨後溶接できるのに対し、30点くらい溶接すると電極が錫めっき板と溶着して離れなくなってしまうので電極の研磨しなければならない。   As a means for solving the above problems, it is conceivable to use a plated steel plate as the sealing plate material. However, for example, when a tin-plated steel sheet is used for the purpose of preventing corrosion of the sealing plate, when the sealing plate is resistance-welded to the bottomed cylindrical body with the base, the plating component tin is bonded to the metal copper and alloy of the welding electrode. In the case of a thin steel plate that is formed and not plated, it can be welded after polishing the electrode surface of 400 points or more, whereas if it is welded about 30 points, the electrode will not be separated from the tin plating plate, so the electrode must be polished. Don't be.

この現象は飲料缶の缶胴を溶接して作成する溶接缶の製造の際に経験され、例えば特許文献2に示すような対策が講じられている。すなわち、錫めっき板同士を溶接する際には円盤状の電極と錫めっき板との間に銅線を介挿し、溶接後は表面が合金化した胴線を捨て、常に未合金の新鮮な銅線を介挿するのである。   This phenomenon is experienced during the manufacture of a welded can made by welding a can body of a beverage can. For example, a countermeasure as shown in Patent Document 2 is taken. That is, when welding tin-plated plates, a copper wire is inserted between the disc-shaped electrode and the tin-plated plate, and after welding, the body-lined body wire is discarded, and unalloyed fresh copper is always used. A line is inserted.

特開2000−202057号公報Japanese Patent Laid-Open No. 2000-202057 特公昭54−4684号公報Japanese Patent Publication No.54-4684

しかしながら、特許文献2に記載の手段は、工程が煩雑でありかつ設備費も大きく、小型のカートリッジの封板の接合に適用するのは経済的ではない。そのため、前述の小型ガスカートリッジの封板には、めっきの施されていない、いわゆる無処理の冷延鋼板が用いられており、封板部の耐食性向上に関して抜本的対策が講じられていないのが現状である。   However, the means described in Patent Document 2 has a complicated process and a large equipment cost, and it is not economical to apply it to the joining of a sealing plate of a small cartridge. Therefore, the sealing plate of the above-mentioned small gas cartridge uses a so-called untreated cold-rolled steel plate that is not plated, and no drastic measures have been taken to improve the corrosion resistance of the sealing plate portion. Currently.

本考案は、長期間に亘って封板の腐食が生じない高圧ガスカートリッジ、特に内容積が10〜500ml程度の小型高圧ガスカートリッジを提供することを目的とする。   An object of the present invention is to provide a high-pressure gas cartridge that does not cause corrosion of the sealing plate over a long period of time, particularly a small high-pressure gas cartridge having an internal volume of about 10 to 500 ml.

本考案者は、封板材料として多種類のめっき鋼板を試験し、ティンフリー鋼板およびニッケルめっき鋼板が従来の封板の溶接工程に対する適合性を有し、また、これを封板材料として用いた高圧ガスカートリッジが優れた耐食性を有していることを発見して本考案を完成するに至った。   The present inventor has tested various types of plated steel sheets as sealing plate materials, and tin-free steel plates and nickel-plated steel plates have compatibility with conventional sealing plate welding processes, and these were used as sealing plate materials. The inventors discovered that the high-pressure gas cartridge has excellent corrosion resistance and completed the present invention.

本考案の高圧ガスカートリッジは、鋼製の容器本体にティンフリー鋼板及びニッケルめっき鋼板の何れかから選ばれた封板を装着してなるものである。上記考案において、封板は厚さ:、0.2〜0.6mm、降伏強度:200〜500MPaの範囲にあるものとするのが好ましい。   The high-pressure gas cartridge of the present invention is formed by mounting a sealing plate selected from a tin-free steel plate and a nickel-plated steel plate on a steel container body. In the above device, the sealing plate preferably has a thickness of 0.2 to 0.6 mm and a yield strength of 200 to 500 MPa.

本考案により製造される高圧ガスカートリッジは長期間に亘って封板の腐食を生じない。   The high-pressure gas cartridge manufactured according to the present invention does not cause corrosion of the sealing plate over a long period of time.

以下、本考案をその代表的な適用対象である消火器用の高圧ガスカートリッジを例にとって説明する。本考案に係る高圧ガスカートリッジ11は、図1に示すように、本体、すなわち、有底の円筒部1と該円筒体の頭部を絞り込んで成形された口部2と本体の口部2の開口部を封止する封板3からなる。口部2には、加圧式消火器内に固定するためのねじ切部4が設けられているのが一般的である。また、その内部には、用途に応じてガス体が所定の圧力で充填されている。消火器用の場合、ガス体の種類は、炭酸ガスとするのが一般的である。そのサイズは直径:25〜40mm、高さ(口部を含む):110〜140mm、内容積:30〜100ml程度である。   Hereinafter, the present invention will be described by taking as an example a high-pressure gas cartridge for a fire extinguisher which is a typical application target thereof. As shown in FIG. 1, a high-pressure gas cartridge 11 according to the present invention comprises a main body, that is, a bottomed cylindrical portion 1, a mouth portion 2 formed by narrowing the head of the cylindrical body, and a mouth portion 2 of the main body. It consists of a sealing plate 3 that seals the opening. The mouth 2 is generally provided with a threaded portion 4 for fixing in a pressurized fire extinguisher. Further, the gas body is filled with a predetermined pressure in accordance with the use. In the case of a fire extinguisher, the type of gas body is generally carbon dioxide. The size is about 25 to 40 mm in diameter, about 110 to 140 mm in height (including the mouth), and about 30 to 100 ml in internal volume.

かかる高圧ガスカートリッジ11の製造工程は、鋼板などの素材の有底円筒体へのプレス成形、口部の誘導加熱による軟化、必要に応じて行われるねじ切り、潤滑油の脱脂及び消火器用ガス(窒素等の高圧ガス又は液化ガス、例えば液化炭酸ガス)の封入並びに封板の溶着の各工程をこの順に行って製造される。   The manufacturing process of the high-pressure gas cartridge 11 includes press molding of a material such as a steel plate into a bottomed cylindrical body, softening of the mouth by induction heating, threading performed as necessary, degreasing of lubricating oil, and gas for a fire extinguisher (nitrogen The high pressure gas such as liquefied gas such as liquefied carbon dioxide) and the sealing plate welding process are performed in this order.

有底円筒体への成形は、通常のように、プレス油を使用してプレス成形により行われる。得られた有底円筒体には、高圧ガスカートリッジの口部に当たる部分を成形するために開口端近傍を軟化するための口部誘導加熱が施され、続いて口部先端加工が行われる。このように成形された高圧ガスカートリッジ用の有底円筒体口部には、必要に応じてねじ切り加工が行われた後、前記プレス成形やねじ切り作業に用いられた油分が内外面同時脱脂され、乾燥される。続いてこのように成形され、ねじ切り加工の行われた有底円筒体の開口部から消火器用ガス、たとえば、液化炭酸ガスの充填が行われると同時に抵抗溶接による封板の封着が行われる。   The molding into the bottomed cylindrical body is performed by press molding using press oil as usual. The obtained bottomed cylindrical body is subjected to mouth induction heating for softening the vicinity of the opening end in order to form a portion corresponding to the mouth portion of the high-pressure gas cartridge, and then the mouth tip processing is performed. The bottomed cylindrical mouth portion for the high-pressure gas cartridge formed in this way is subjected to threading as necessary, and then the oil used in the press molding and threading operation is simultaneously degreased on the inner and outer surfaces, Dried. Subsequently, a fire extinguisher gas, for example, liquefied carbon dioxide gas, is filled from the opening of the bottomed cylindrical body thus formed and threaded, and at the same time, the sealing plate is sealed by resistance welding.

本考案においては、前記のように成形・脱脂・乾燥が行われた有底円筒体の開口部から消火器用ガスの充填が行われると同時に抵抗溶接による封板の封着が行われるが、その封着に当たっては、容器本体の開口部から封板が封着されるべき位置からずれるのを防ぐために、図2のように予め切り離し部にスコア11を入れ、かつ、カップ状にプレス成形してなる封板素材10を本体先端部の口部2に被せ、しかる後その底部13と口部2の先端とを、例えば抵抗溶接により溶接したのち、周囲のリング状部14を切り離すことにより行われる。   In the present invention, the gas for the fire extinguisher is filled from the opening of the bottomed cylindrical body that has been molded, degreased and dried as described above, and at the same time, the sealing plate is sealed by resistance welding. In sealing, in order to prevent the sealing plate from shifting from the position where the sealing plate should be sealed from the opening of the container body, a score 11 is put in the separation part in advance as shown in FIG. The sealing plate material 10 is placed on the mouth 2 of the front end of the main body, and then the bottom 13 and the tip of the mouth 2 are welded, for example, by resistance welding, and then the surrounding ring-shaped part 14 is cut off. .

封板材料には、上記加工を行うことができる成形性を有し、かつ、良好な抵抗溶接性を有することが要求される。また、消火器内に長期に亘って内蔵された状態で十分な耐食性を有することが要求される。また、封板として機能するための耐破壊圧力を備え、さらに例えば消火器の内蔵圧力源として用いられる場合には、ハンドル操作による破断容易性を兼ね備えることが要求される。   The sealing plate material is required to have a formability capable of performing the above processing and a good resistance weldability. Moreover, it is requested | required that it should have sufficient corrosion resistance in the state built in the fire extinguisher for a long period of time. Moreover, when it is used as a built-in pressure source of a fire extinguisher, for example, it is required to have breakability easily by a handle operation.

まず、耐食性を満たすために、ティンフリー鋼板又はニッケルめっき鋼板が選択される。これらのめっき鋼板は、高圧ガスカートリッジの長期使用過程における封板の腐食原因となる水分が容器内部に残留しても、発生する炭酸等により封板が腐食しないようにするのに十分な特性を有し、通常のティンフリースチールのほかにクロム水和酸化物の厚さを薄くした無研磨溶溶接鋼板と呼ばれるティンフリースチールも利用できる。なお、ティンフリースチールには、クロム水和酸化物系ティンフリー鋼板のほかに目付量2g/m以下の薄ニッケルめっき鋼板も含まれる。ニッケルめっき鋼板は、薄鋼板に再結晶焼鈍を施した後電気メッキにより製造する方法により製造されたものと、薄鋼板に電気メッキを施したのち再結晶焼鈍を施す方法により製造されたものがあるが、いずれもめっき層の融点が高く、溶接に使用する電極の寿命に影響を与えることなく、本考案の目的に使用できる。なお、防錆機能を有する溶接可能な金属めっきとしては亜鉛めっきが挙げられるが、電極の銅と合金を形成し電極研磨の頻度が増える弊害を有しているのは錫めっきと同じであり、本考案の封板としては不適当である。 First, in order to satisfy the corrosion resistance, a tin-free steel plate or a nickel-plated steel plate is selected. These plated steel sheets have sufficient characteristics to prevent the sealing plate from corroding due to the generated carbon dioxide, etc., even if moisture that causes corrosion of the sealing plate in the long-term use process of the high-pressure gas cartridge remains inside the container. In addition to ordinary tin-free steel, tin-free steel called non-abrasive welded steel sheet in which the thickness of chromium hydrated oxide is reduced can also be used. Tin-free steel includes thin nickel-plated steel sheets having a basis weight of 2 g / m 2 or less in addition to chromium hydrated oxide tin-free steel sheets. There are two types of nickel-plated steel sheets, one manufactured by electroplating after applying recrystallization annealing to a thin steel sheet, and one manufactured by recrystallization annealing after electroplating a thin steel sheet. However, any of them has a high melting point of the plating layer and can be used for the purpose of the present invention without affecting the life of the electrode used for welding. In addition, as a weldable metal plating having a rust prevention function, galvanization can be mentioned, but it is the same as tin plating that has an adverse effect of increasing the frequency of electrode polishing by forming an alloy with copper of the electrode, It is not suitable as a sealing plate of the present invention.

封板として要求される耐破壊圧力及び消火器のハンドル操作による破断容易性を兼備するためには、封板材料の降伏強度を200〜500MPa、好ましくは250〜430MPa、厚さを0.20〜0.60mmとするのがよい。降伏強度が200MPa未満の場合は、上記厚さの範囲においてプレス成形性および耐破壊圧力が不足し、500MPa超の場合はプレス成形性およびハンドル操作による破断容易性が不十分になる。なお、封板の厚さは、薄すぎては降伏強度を上げても耐破壊圧力を具備させることが困難になる場合があり、また、厚すぎては破断容易性の欠ける場合が生ずる場合があり、さらに、封板を溶接する際の生産上、管理上の安定性を考慮して定められたものである。   In order to combine the fracture pressure required for the sealing plate and the ease of breaking by the handle operation of the fire extinguisher, the yield strength of the sealing plate material is 200 to 500 MPa, preferably 250 to 430 MPa, and the thickness is 0.20 to 0.20. It is good to set it as 0.60 mm. When the yield strength is less than 200 MPa, the press formability and the fracture pressure are insufficient in the above thickness range, and when it exceeds 500 MPa, the press formability and the ease of breakage due to handle operation become insufficient. In addition, if the thickness of the sealing plate is too thin, it may be difficult to provide a fracture resistance even if the yield strength is increased, and if it is too thick, it may be difficult to break. Furthermore, it is determined in consideration of production and management stability when welding the sealing plate.

このような諸条件を満たすものとして、市販の缶用鋼板のうち硬度がT2からT5の鋼板が適している。特に、T3CAとT4CA、あるいはその中間のものが好ましい。なお、上記T3CAとは、ロックウエル硬度にしたがって、49±3のT1から70±3のT6までの7段階に分類した缶用鋼板のうち、硬度がT3に相当し、最終的に連続焼鈍により硬度調整されたものをいう。T4CAについても同様である。   Of those commercially available steel plates for cans, steel plates having a hardness of T2 to T5 are suitable. In particular, T3CA and T4CA, or an intermediate product thereof is preferable. The T3CA is a steel plate for cans classified into 7 stages from T1 of 49 ± 3 to T6 of 70 ± 3 according to Rockwell hardness. The hardness corresponds to T3, and the hardness is finally obtained by continuous annealing. It is adjusted. The same applies to T4CA.

以上、本発明を消火器の高圧ガスカートリッジに適用する場合に説明したが、本発明による高圧ガスカートリッジは、たとえば、飲料水容器内に組み込み、その押し出し用の容器内内蔵高圧ガスカートリッジとしても利用できる。   As described above, the present invention has been described when applied to a high-pressure gas cartridge of a fire extinguisher. However, the high-pressure gas cartridge according to the present invention is incorporated into a drinking water container and used as an internal high-pressure gas cartridge for extrusion. it can.

本考案に係る高圧ガスカートリッジの構造を示す概念図である。It is a conceptual diagram which shows the structure of the high pressure gas cartridge which concerns on this invention. 封板の取付け要領を示す説明図である。It is explanatory drawing which shows the attachment point of a sealing board.

符号の説明Explanation of symbols

1:有底の円筒部
2:口部
3:封板
4:ねじ切部
10:封板素材
11:スコア
13:底部
14:リング状部
1: Bottomed cylindrical part
2: Mouth
3: Seal plate
4: Threaded part
10: Seal plate material
11: Score
13: Bottom
14: Ring-shaped part

Claims (2)

鋼製の容器本体にティンフリー鋼板及びニッケルめっき鋼板の何れかから選ばれた封板を装着してなることを特徴とする高圧ガスカートリッジ。   A high-pressure gas cartridge comprising a steel container body and a sealing plate selected from a tin-free steel plate and a nickel-plated steel plate. 封板が厚さ:0.2〜0.6mm、降伏強度:200〜500MPaの範囲にあることを特徴とする請求項1記載の高圧ガスカートリッジ。   The high-pressure gas cartridge according to claim 1, wherein the sealing plate has a thickness of 0.2 to 0.6 mm and a yield strength of 200 to 500 MPa.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014520113A (en) * 2011-06-10 2014-08-21 ゲノ エルエルシー Nitric oxide (NO) pressurized container

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014520113A (en) * 2011-06-10 2014-08-21 ゲノ エルエルシー Nitric oxide (NO) pressurized container

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