JP3113114B2 - Water based nail polish - Google Patents

Water based nail polish

Info

Publication number
JP3113114B2
JP3113114B2 JP05022117A JP2211793A JP3113114B2 JP 3113114 B2 JP3113114 B2 JP 3113114B2 JP 05022117 A JP05022117 A JP 05022117A JP 2211793 A JP2211793 A JP 2211793A JP 3113114 B2 JP3113114 B2 JP 3113114B2
Authority
JP
Japan
Prior art keywords
pigment
fluorine compound
nail
weight
nail polish
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP05022117A
Other languages
Japanese (ja)
Other versions
JPH06211631A (en
Inventor
昭彦 高津
京子 横山
Original Assignee
鐘紡株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 鐘紡株式会社 filed Critical 鐘紡株式会社
Priority to JP05022117A priority Critical patent/JP3113114B2/en
Publication of JPH06211631A publication Critical patent/JPH06211631A/en
Application granted granted Critical
Publication of JP3113114B2 publication Critical patent/JP3113114B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Cosmetics (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、顔料分散安定性の優れ
た水系美爪料を提供することを目的としている。
BACKGROUND OF THE INVENTION An object of the present invention is to provide a water-based beauty nail preparation having excellent pigment dispersion stability.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】従来よ
り美爪料は酢酸ブチル、酢酸エチル、トルエン等の有機
溶剤を使用したものであり、引火性があると共に塗布時
に溶剤臭を伴うものであった。さらに有機溶剤により爪
の脱脂が生じやすく、爪に対する安全性に問題があっ
た。
2. Description of the Prior Art Conventionally, nail polish has used an organic solvent such as butyl acetate, ethyl acetate, and toluene, and is flammable and has a solvent odor during application. there were. Furthermore, degreasing of the nail is easily caused by the organic solvent, and there is a problem in safety for the nail.

【0003】これに対し、有機溶剤を使用しない美爪料
が種々検討されており、特開昭54−28836号公
報、特公昭55−43445号公報、特公昭61−10
43号公報、特公昭62−61002号公報等により、
ポリマーエマルジョンや水性樹脂を配合した美爪料が提
案されている。
[0003] On the other hand, various types of nail polish which do not use an organic solvent have been studied, for example, JP-A-54-28836, JP-B-55-43445, and JP-B-61-10.
No. 43, Japanese Patent Publication No. Sho 62-61002, etc.
Nail preparations containing a polymer emulsion or an aqueous resin have been proposed.

【0004】しかし、これらはいずれも未処理の無機顔
料を使用しており、無機顔料のもつ親水性および水との
比重差により、顔料はいずれも経日で沈降し、使用前に
振とうしても良く混合せず、所望の色調が塗布されない
という欠点があった。また、これらの公報では無機顔料
を分散させるために活性剤やゲル化剤を使用している
が、これだけでは美爪料として塗布むらを生じることな
く塗布できる1000cp以下の粘度において、経日で
の顔料沈降を完全に防止することが困難であった。
However, all of these use untreated inorganic pigments, and due to the hydrophilicity of the inorganic pigments and the difference in specific gravity with water, all of the pigments settle out over time and are shaken before use. However, they do not mix well, and the desired color tone is not applied. Further, in these publications, an activator or a gelling agent is used to disperse the inorganic pigment. However, with this alone, at a viscosity of 1000 cp or less that can be applied without causing unevenness in application as a nail pill, It was difficult to completely prevent pigment settling.

【0005】また、特開平4−103515号公報では
顔料分散安定性を改良するために多価金属元素の含水酸
化物をカチオンポリマーエマルジョンと共に使用してい
るが、カチオンポリマーエマルジョンのpHが低いた
め、pH7〜9のアクリル系エマルジョンと混合して使
用することが困難であった。
In Japanese Patent Application Laid-Open No. 4-103515, a hydrated oxide of a polyvalent metal element is used together with a cationic polymer emulsion in order to improve the pigment dispersion stability. However, since the pH of the cationic polymer emulsion is low, It was difficult to mix and use with an acrylic emulsion having a pH of 7 to 9.

【0006】さらに、特開平4−103516号公報で
はポリマーエマルジョンと顔料を共に粉砕して顔料を微
粒子化することにより美爪料の外観、光沢を改良する方
法が記載されているが、本発明者が追試した限りでは経
日での顔料沈降を完全に防止することが困難であった。
Further, Japanese Patent Application Laid-Open No. 4-103516 discloses a method for improving the appearance and gloss of a nail polisher by pulverizing a polymer emulsion and a pigment together to make the pigment finer. However, it was difficult to completely prevent sedimentation of the pigment over time as long as the additional test was conducted.

【0007】一方、特開平4−208213号公報では
フルオロアルキル基を有する化合物で表面処理した粉体
を含有した美爪料が記載されているが、これは有機溶剤
を使用した美爪料の分散安定性に関するものであった。
On the other hand, Japanese Unexamined Patent Publication (Kokai) No. 4-208213 discloses a nail polish containing a powder surface-treated with a compound having a fluoroalkyl group. This is a dispersion of the nail polish using an organic solvent. It was about stability.

【0008】[0008]

【課題を解決するための手段】本発明者はかかる問題を
鑑みて鋭意研究の結果、無機顔料の表面にフッ素化合物
を被覆させたフッ素化合物処理顔料、およびポリオキシ
エチレン系ノニオン界面活性剤を配合することによっ
て、アクリル系樹脂エマルジョンを配合した水系美爪料
に安定に無機顔料を配合できることを見出だした。
Means for Solving the Problems In view of the above problems, the present inventors have made intensive studies and have found that a fluorine compound-treated pigment in which the surface of an inorganic pigment is coated with a fluorine compound, and a polyoxyethylene-based nonionic surfactant are blended. By doing so, it has been found that an inorganic pigment can be stably compounded in a water-based nail pill containing an acrylic resin emulsion.

【0009】またアクリル系樹脂エマルジョンとして一
般式(I)で表されるアルコキシシラン不飽和単量体を
共重合させた共重合体エマルジョンを使用すればさらに
顔料の分散安定性が増加することを見出だした。
It is also found that the use of a copolymer emulsion obtained by copolymerizing an alkoxysilane unsaturated monomer represented by the general formula (I) as an acrylic resin emulsion further increases the pigment dispersion stability. I started.

【0010】すなわち本発明は、無機顔料の表面に、少
なくともフッ素化合物を母体顔料に対し0.1〜10.
0重量%被覆させたフッ素化合物処理顔料10.0重量
%以下、ポリオキシエチレン系ノニオン界面活性剤0.
01〜10.0重量%、アクリル系樹脂エマルジョンを
固形分として5.0〜40.0重量%を配合することに
より、顔料分散安定性の優れた水系美爪料を提供するも
のである。
That is, according to the present invention, at least a fluorine compound is added to the surface of the inorganic pigment in an amount of 0.1 to 10.
0% by weight or less, coated with a fluorine compound-treated pigment 10.0% by weight or less, polyoxyethylene nonionic surfactant 0.1%
An aqueous nail polish having excellent pigment dispersion stability is provided by blending 0.01 to 10.0% by weight and 5.0 to 40.0% by weight of an acrylic resin emulsion as a solid content.

【0011】以下、本発明の構成について詳述する。本
発明に使用されるフッ素化合物処理顔料の母体となる無
機顔料は化粧料に配合される無機顔料であれば全て母体
として使用することができ、酸化チタン、ベンガラ、黄
酸化鉄、黒酸化鉄、グンジョウ、コンジョウ、酸化クロ
ム、水酸化クロム、タルク、マイカ、雲母チタン、酸化
鉄処理雲母チタン、コンジョウ処理雲母チタン、カルミ
ン処理雲母チタン、硫酸バリウム、およびこれらの複合
体等があげられる。
Hereinafter, the configuration of the present invention will be described in detail. The inorganic pigment serving as a base of the fluorine compound-treated pigment used in the present invention can be used as a base as long as it is an inorganic pigment blended in a cosmetic, and titanium oxide, red iron oxide, yellow iron oxide, black iron oxide, Gunjo, konjo, chromium oxide, chromium hydroxide, talc, mica, titanium mica, iron oxide-treated mica titanium, konjo-treated mica titanium, carmine-treated mica titanium, barium sulfate, and composites thereof.

【0012】これらの母体顔料に被覆するフッ素化合物
は、たとえばパーフルオロアルキルリン酸エステル類、
パーフルオロアルキルリン酸塩類、パーフルオロアルキ
ルシラン類、パーフルオロポリエーテル類、パーフルオ
ロアルキル基を有する樹脂、四フッ化エチレン樹脂、パ
ーフルオロアルコール、パーフルオロエポキシ化合物、
パーフルオロ硫酸塩、パーフルオロカルボン酸塩、パー
フルオロアルキル基を含有するオルガノシロキサン、あ
るいはこれらの誘導体等の変性フッ素化合物の類から選
ばれる。
Fluorine compounds coated on these base pigments include, for example, perfluoroalkyl phosphates,
Perfluoroalkyl phosphates, perfluoroalkylsilanes, perfluoropolyethers, resins having a perfluoroalkyl group, ethylene tetrafluoride resin, perfluoroalcohol, perfluoroepoxy compound,
It is selected from modified fluorine compounds such as perfluorosulfates, perfluorocarboxylates, organosiloxanes containing a perfluoroalkyl group, and derivatives thereof.

【0013】被覆方法はたとえばフッ素化合物をベンゼ
ン、トルエン等の有機溶媒に加熱溶解し、その中に母体
とする顔料を加えた後攪拌し、溶媒を除去した後乾燥し
て処理する方法や、母体とする顔料に水を加えてスラリ
ー状態とすると共に、フルオロアルキル基を有する化合
物に水を加えて攪拌しエマルジョン状態にして徐々に両
者を混合し、これを酸性とした後常温または高温静置等
によりエマルジョンを破壊して母体顔料の表面にフルオ
ロアルキル基を有する化合物を被覆させた後、濾過、乾
燥して処理する方法等の公知の方法で行うものである。
The coating method is, for example, a method of heating and dissolving a fluorine compound in an organic solvent such as benzene or toluene, adding a pigment as a base material thereto, stirring the mixture, removing the solvent, and then drying and treating. Water is added to the pigment to be made into a slurry state, and water is added to the compound having a fluoroalkyl group, and the mixture is stirred to form an emulsion state, and the two are gradually mixed. And then coating the compound having a fluoroalkyl group on the surface of the parent pigment, followed by filtration, drying, and treatment to carry out the treatment.

【0014】もちろん他の油剤を被覆した後にフッ素化
合物をさらに結合させても、他の油剤と共に被覆処理し
ても良く、結果として顔料表面にフッ素化合物もしくは
フッ素化合物誘導体が被覆された顔料であれば本発明の
フッ素化合物処理顔料として全て使用できる。前述した
フッ素化合物の被覆量は母体顔料に対し、0.1〜1
0.0重量%である。被覆量が0.1重量%以下では無
機顔料の分散安定性が乏しく、また10.0重量%以上
では美爪料の粘度が増加し、塗布時にムラを生じるため
好ましくない。もちろんこれらのフッ素化合物は2種以
上を併用しても良い。
Of course, the fluorine compound may be further bound after coating the other oil agent, or may be coated with the other oil agent. As a result, if the pigment surface is coated with a fluorine compound or a fluorine compound derivative, All can be used as the fluorine compound-treated pigment of the present invention. The coating amount of the fluorine compound is 0.1 to 1 with respect to the base pigment.
0.0% by weight. When the coating amount is 0.1% by weight or less, the dispersion stability of the inorganic pigment is poor, and when the coating amount is 10.0% by weight or more, the viscosity of the nail polish increases, which is not preferable because unevenness occurs during application. Of course, two or more of these fluorine compounds may be used in combination.

【0015】また本発明に使用されるポリオキシエチレ
ン系ノニオン界面活性剤としてはポリオキシエチレンソ
ルビタン脂肪酸エステル、ポリオキシエチレングリセリ
ン脂肪酸エステル、ポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンアルキルフェニルエーテル、ポ
リオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒ
マシ油等の類から選ばれる。
The polyoxyethylene nonionic surfactant used in the present invention includes polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, and polyoxyethylene. It is selected from castor oil, polyoxyethylene hydrogenated castor oil and the like.

【0016】また本発明に使用されるアクリル系樹脂エ
マルジョンは、少なくともアクリル酸、メタクリル酸あ
るいはそれらのアルキルエステルまたは誘導体の類から
えらばれるモノマーを含む共重合体の水性エマルジョン
であり、共重合させる他のモノマーは特に限定されず、
スチレン、酢酸ビニル等を共重合させても良い。
The acrylic resin emulsion used in the present invention is an aqueous emulsion of a copolymer containing at least a monomer selected from the group consisting of acrylic acid, methacrylic acid and their alkyl esters or derivatives. The monomer of is not particularly limited,
Styrene, vinyl acetate and the like may be copolymerized.

【0017】アクリル酸、メタクリル酸あるいはそれら
のアルキルエステルまたは誘導体の類からえらばれるモ
ノマーとしてはアクリル酸、メタクリル酸、アクリル酸
エチル、メタクリル酸メチル、アクリル酸オクチル、ア
クリロニトリル、アクリルアミド等があげられ、なかで
も一般式(I)で表されるアルコキシシランを含むアク
リル酸、メタクリル酸の誘導体を共重合させたエマルジ
ョンが顔料分散安定性および化粧持ちの良さの点で好ま
しく、たとえばアクリロキシトリメトキシシラン、メタ
クリロキシトリメトキシシラン、アクリロキシトリエト
キシシラン、メタクリロキシトリエトキシシラン、アク
リロキシトリエトキシメトキシシラン、メタクリロキシ
トリエトキシメトキシシラン、メタクリロキシエチルト
リメトキシシラン、メタクリロキシエチルトリエトキシ
シラン、メタクリロキシプロピルトリメトキシシラン、
メタクリロキシプロピルトリエトキシシラン等があげら
れる。
The monomers selected from the group consisting of acrylic acid, methacrylic acid and their alkyl esters or derivatives include acrylic acid, methacrylic acid, ethyl acrylate, methyl methacrylate, octyl acrylate, acrylonitrile, acrylamide and the like. However, an emulsion obtained by copolymerizing a derivative of acrylic acid or methacrylic acid containing an alkoxysilane represented by the general formula (I) is preferable in terms of pigment dispersion stability and cosmetic durability. For example, acryloxytrimethoxysilane and methacrylic acid are preferred. Roxytrimethoxysilane, acryloxytriethoxysilane, methacryloxytriethoxysilane, acryloxytriethoxymethoxysilane, methacryloxytriethoxymethoxysilane, methacryloxyethyltrimethoxysilane Methacryloxyethyl triethoxysilane, methacryloxypropyl trimethoxysilane,
Methacryloxypropyltriethoxysilane and the like can be mentioned.

【0018】本発明に使用されるフッ素化合物処理顔料
の配合量は好ましくは0.1〜10.0重量%以下であ
り、美爪料の色調に応じて増減される。10.0重量%
以上では美爪料の粘度が増加し、塗布時にムラを生じる
ために好ましくない。
The compounding amount of the fluorine compound-treated pigment used in the present invention is preferably 0.1 to 10.0% by weight or less, and may be increased or decreased according to the color tone of the nail polish. 10.0% by weight
The above is not preferable because the viscosity of the nail enamel increases and unevenness occurs during application.

【0019】また本発明に使用されるポリオキシエチレ
ン系ノニオン界面活性剤の配合量は好ましくは0.01
〜10.0重量%であり、フッ素化合物処理顔料の配合
量に応じて増減させる。0.01重量%以下では顔料の
分散安定性が乏しく、また10.0重量%以上では美爪
料の粘度が増加し、塗布時にムラを生じるだけでなく化
粧持ちも悪くなる傾向にある。
The compounding amount of the polyoxyethylene nonionic surfactant used in the present invention is preferably 0.01.
110.0% by weight, which is increased or decreased according to the blending amount of the fluorine compound-treated pigment. When the content is 0.01% by weight or less, the dispersion stability of the pigment is poor. When the content is 10.0% by weight or more, the viscosity of the nail polishes increases, and not only unevenness occurs at the time of application, but also the long-lasting makeup tends to deteriorate.

【0020】また本発明に使用されるアクリル系樹脂エ
マルジョンの配合量は好ましくは固形分として5.0〜
40.0重量%であり、5.0重量%以下では美爪料の
被膜形成効果に乏しく、化粧持ちに優れた美爪料となら
ず、また40.0重量%以上では美爪料の粘度が増加
し、塗布時にムラを生じる傾向にあるために好ましくな
い。このアクリル系樹脂エマルジョンは2種以上のアク
リル系樹脂エマルジョンを配合してもさしつかえない。
The amount of the acrylic resin emulsion used in the present invention is preferably from 5.0 to 5.0 as a solid content.
When the content is 40.0% by weight or less, the effect of forming a film of the nail enamel is poor when the content is less than 5.0% by weight. Is increased, and unevenness tends to occur during coating, which is not preferable. This acrylic resin emulsion may contain two or more acrylic resin emulsions.

【0021】本発明の美爪料中には上記必須成分以外に
他の顔料や色素、染料を配合することもできる。タール
系色素はそのまま使用しても比較的安定に分散するが、
もちろん必要に応じてフッ素化合物処理して配合しても
良い。また必要に応じ、ポリオキシエチレン系ノニオン
界面活性剤以外の界面活性剤、可塑剤、粘度調整剤(ゲ
ル化剤)、防腐剤、香料等を適宜配合することができ
る。
The nail polish of the present invention may contain other pigments, pigments and dyes in addition to the above essential components. Tar pigments are relatively stable even when used as is,
Of course, if necessary, it may be blended by treating with a fluorine compound. If necessary, a surfactant other than the polyoxyethylene-based nonionic surfactant, a plasticizer, a viscosity modifier (gelling agent), a preservative, a fragrance, and the like can be appropriately compounded.

【0022】[0022]

【実施例】以下、実施例によって本発明の効果を更に詳
しく説明する。表1〜9の組成により、各々の実施例お
よび比較例の美爪料を調整した。ここで表中の数値は全
て重量%である。この美爪料は色素や顔料を界面活性剤
と共にローラーミルにて粉砕練混し、その後アクリル系
樹脂エマルジョンおよびその他の成分と約60℃にて均
一に混合した後、室温まで冷却して製造した。また、必
要に応じ減圧脱泡をおこない美爪料中に含まれた空気を
除去した。
EXAMPLES Hereinafter, the effects of the present invention will be described in more detail with reference to examples. According to the compositions of Tables 1 to 9, the nail polish of each Example and Comparative Example was adjusted. Here, all numerical values in the table are% by weight. This nail polish was manufactured by pulverizing and mixing a pigment and a pigment together with a surfactant in a roller mill, then uniformly mixing with an acrylic resin emulsion and other components at about 60 ° C., and then cooling to room temperature. . In addition, defoaming was performed under reduced pressure as needed to remove air contained in the nail preparation.

【0023】[0023]

【表1】 [Table 1]

【0024】[0024]

【表2】 [Table 2]

【0025】[0025]

【表3】 [Table 3]

【0026】[0026]

【表4】 [Table 4]

【0027】[0027]

【表5】 [Table 5]

【0028】[0028]

【表6】 [Table 6]

【0029】[0029]

【表7】 [Table 7]

【0030】[0030]

【表8】 [Table 8]

【0031】[0031]

【表9】 [Table 9]

【0032】次いで実施例および比較例の美爪料の顔料
分散安定性試験を実施し、その結果を表10に記載し
た。顔料分散安定性試験は5℃、30℃、45℃の各恒
温槽にて静置状態における経日変化を観察し、4段階
(◎:一ケ月間顔料沈降なし、○:2週間で顔料沈降、
△:1週間で顔料沈降、×:3日以内で顔料沈降)で評
価した。
Next, the pigment dispersion stability test of the nail polishes of Examples and Comparative Examples was carried out, and the results are shown in Table 10. The pigment dispersion stability test was carried out by observing the daily change in the stationary state in each of the constant temperature baths at 5 ° C., 30 ° C., and 45 ° C. ,
Δ: pigment sedimentation in 1 week, ×: pigment sedimentation in 3 days or less).

【0033】[0033]

【表10】 [Table 10]

【0034】また、実施例および比較例の美爪料の実用
特性試験を実施し、その結果を表11〜12に記載し
た。実用特性試験は、20名の女性パネラーに美爪料を
爪に塗布し、その使用品質(塗り易さ、色むら、乾燥速
度、光沢、仕上がり、化粧持ち)を5段階評価(5:良
い、4:やや良い、3:ふつう、2:やや悪い、1:悪
い)で集計し、その平均値を4段階(◎:4以上、○:
3〜4、△:2〜3、×:2以下)で評価した。
Further, practical property tests of the nail polishes of Examples and Comparative Examples were conducted, and the results are shown in Tables 11 to 12. In the practical characteristics test, a nail polish was applied to the nails of 20 female panelists, and the quality of use (ease of application, uneven color, drying speed, gloss, finish, makeup durability) was evaluated on a five-point scale (5: good, 4: Slightly good, 3: Normal, 2: Slightly bad, 1: Poor, and averaged in 4 steps (A: 4 or more, O:
3-4, Δ: 2-3, ×: 2 or less).

【0035】[0035]

【表11】 [Table 11]

【0036】[0036]

【表12】 [Table 12]

【0037】表10より、実施例はいずれも比較例に比
べて顔料分散安定性に優れていることが明らかである。
From Table 10, it is clear that all of the examples are more excellent in pigment dispersion stability than the comparative examples.

【0038】また表11〜12より、実施例はいずれも
比較例に比べて実用特性においても同等もしくはそれ以
上の評価を有していることが明らかである。
From Tables 11 to 12, it is clear that all of the examples have equal or higher evaluations in practical characteristics than the comparative examples.

【0039】[0039]

【発明の効果】本発明の水系美爪料は、顔料分散安定性
に優れた効果を有するものである。
The water-based nail polishes of the present invention have excellent pigment dispersion stability.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) A61K 7/043 A61K 7/00 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7/043 A61K 7/00

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 無機顔料の表面に、フッ素化合物を母体
顔料に対し0.1〜10.0重量%被覆させたフッ素化
合物処理顔料、ポリオキシエチレン系ノニオン界面活性
剤、アクリル系樹脂エマルジョンを含有することを特徴
とする水系美爪料。
1. An inorganic pigment containing a fluorine compound-treated pigment obtained by coating a fluorine compound at 0.1 to 10.0% by weight with respect to a base pigment, a polyoxyethylene nonionic surfactant, and an acrylic resin emulsion on the surface of the inorganic pigment. A water-based beautiful nail material characterized by doing.
【請求項2】 アクリル系樹脂エマルジョンが、少なく
とも下記一般式(I)で表されるアルコキシシラン不飽
和単量体の一種以上を共重合してなる共重合体エマルジ
ョンである請求項1記載の水系美爪料。 【化1】
2. The aqueous system according to claim 1, wherein the acrylic resin emulsion is a copolymer emulsion obtained by copolymerizing at least one kind of an alkoxysilane unsaturated monomer represented by the following general formula (I). Beauty nails. Embedded image
JP05022117A 1993-01-13 1993-01-13 Water based nail polish Expired - Fee Related JP3113114B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP05022117A JP3113114B2 (en) 1993-01-13 1993-01-13 Water based nail polish

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP05022117A JP3113114B2 (en) 1993-01-13 1993-01-13 Water based nail polish

Publications (2)

Publication Number Publication Date
JPH06211631A JPH06211631A (en) 1994-08-02
JP3113114B2 true JP3113114B2 (en) 2000-11-27

Family

ID=12073948

Family Applications (1)

Application Number Title Priority Date Filing Date
JP05022117A Expired - Fee Related JP3113114B2 (en) 1993-01-13 1993-01-13 Water based nail polish

Country Status (1)

Country Link
JP (1) JP3113114B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05223518A (en) * 1992-02-07 1993-08-31 Nippon Steel Corp Measurement of lining profile of lined container for molten metal, and method and apparatus for detecting penetrating ground metal
JPH0569615U (en) * 1992-02-24 1993-09-21 キーパー株式会社 Bellows product thickness measuring device

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2736260B1 (en) * 1995-07-05 1997-09-26 Dior Christian Parfums STABLE FORMULA OF NAIL VARNISH WITHOUT AROMATIC SOLVENT
KR100328269B1 (en) * 1999-08-28 2002-04-10 서경배 A method for surface-modifying of cosmetic pigment and solid powder containing modified pigment thereof
JP3631927B2 (en) 1999-09-22 2005-03-23 ロレアル Gel composition and its use in cosmetics, etc.
CN1228380C (en) * 2001-03-02 2005-11-23 株式会社资生堂 Aqueous polymer emulsions and cosmetics with use of the same
JP5669398B2 (en) * 2010-01-06 2015-02-12 三菱鉛筆株式会社 Aqueous cosmetics
JP5669399B2 (en) * 2010-01-07 2015-02-12 三菱鉛筆株式会社 Aqueous cosmetics
CN102791244B (en) * 2010-01-06 2015-10-21 三菱铅笔株式会社 Aqueous cosmetic
JP5886020B2 (en) * 2011-12-14 2016-03-16 三菱鉛筆株式会社 Aqueous beauty nail composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05223518A (en) * 1992-02-07 1993-08-31 Nippon Steel Corp Measurement of lining profile of lined container for molten metal, and method and apparatus for detecting penetrating ground metal
JPH0569615U (en) * 1992-02-24 1993-09-21 キーパー株式会社 Bellows product thickness measuring device

Also Published As

Publication number Publication date
JPH06211631A (en) 1994-08-02

Similar Documents

Publication Publication Date Title
JP2704730B2 (en) Cosmetics
JP3113114B2 (en) Water based nail polish
JP2011016734A (en) Cosmetic
JPH11269231A (en) Copolymer for cosmetic
JP2895589B2 (en) Water based nail polish
JPH07173034A (en) Water-based manicure solution
KR101525962B1 (en) Aqueous enamel composition and a method for producing the same
JPH09104833A (en) Pigment subjected to hydrophilic treatment and composition containing the same
JP3525592B2 (en) Aqueous nail polish
JPH02247110A (en) Non-aqueous makeup cosmetic
JP3080803B2 (en) Water based nail polish
KR101848476B1 (en) Conveniently removable aqueous enamel composition and a process for the preparation thereof
JP3484560B2 (en) Solid powder cosmetics
JPH07187951A (en) Makeup cosmetic
JP3229651B2 (en) Cosmetics
JPH08231344A (en) Cosmetic
JPH06239718A (en) Makeup cosmetic
JP3409192B2 (en) Eye makeup cosmetics for eyelashes or eyebrows
JP3364760B2 (en) Lipstick overcoat
JP3639692B2 (en) Aqueous nail polish and manufacturing method thereof
JPH08133928A (en) Powder for make-up and make-up article containing said powder
JP2000234042A (en) Copolymer-containing composition for surface modification
JP3613713B2 (en) Water based cosmetics
JP2686880B2 (en) Cosmetics
JPH038432A (en) Water-in-oil type emulsified composition

Legal Events

Date Code Title Description
S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R371 Transfer withdrawn

Free format text: JAPANESE INTERMEDIATE CODE: R371

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090922

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100922

Year of fee payment: 10

LAPS Cancellation because of no payment of annual fees