JP3111373B2 - Foam interior material and method for producing the same - Google Patents
Foam interior material and method for producing the sameInfo
- Publication number
- JP3111373B2 JP3111373B2 JP06181987A JP18198794A JP3111373B2 JP 3111373 B2 JP3111373 B2 JP 3111373B2 JP 06181987 A JP06181987 A JP 06181987A JP 18198794 A JP18198794 A JP 18198794A JP 3111373 B2 JP3111373 B2 JP 3111373B2
- Authority
- JP
- Japan
- Prior art keywords
- chloride resin
- polyvinyl chloride
- foamed
- printed
- resin paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Laminated Bodies (AREA)
- Finishing Walls (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、立体感があり且つ表面
強度が強い、防汚機能の高い発泡内装材を提供するもの
である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention provides a foamed interior material having a three-dimensional effect, a high surface strength and a high antifouling function.
【0002】[0002]
【従来の技術】壁紙等の発泡内装材は、一般に裏打難燃
紙の上にポリ塩化ビニル樹脂層を設け、該ポリ塩化ビニ
ル樹脂層の表面にグラビア印刷したり、エンボスを施し
て立体感を持たせたり、或いは該ポリ塩化ビニル樹脂層
の表面に発泡ポリ塩化ビニル樹脂塗料を模様状に適用し
て発泡させたものなどが実用化されている。2. Description of the Related Art In general, a foamed interior material such as wallpaper is provided with a polyvinyl chloride resin layer on a backing flame-retardant paper, and the surface of the polyvinyl chloride resin layer is gravure printed or embossed to give a three-dimensional appearance. Practical use has been made, for example, in which the surface of the polyvinyl chloride resin layer is foamed by applying a foamed polyvinyl chloride resin paint in a pattern.
【0003】[0003]
【発明が解決しようとする課題】これらの壁紙の製法の
うち、発泡ポリ塩化ビニル樹脂塗料を模様状に適用して
発泡させたものは、ソフト感などの特徴から広く使われ
ているが、発泡ポリ塩化ビニル樹脂層が表面にある為、
表面強度が弱くて擦り傷や打ち傷等がつき易く、又汚れ
易く、一旦汚れた場合にこれを拭き取ることは殆ど不可
能であった。Among these methods for producing wallpaper, those produced by applying a foamed polyvinyl chloride resin paint in a pattern form and foaming are widely used because of their softness and other characteristics. Because the polyvinyl chloride resin layer is on the surface,
The surface strength is weak, so that scratches and bruises are liable to be made, and it is easy to get dirty. It is almost impossible to wipe off the soil once it gets dirty.
【0004】表面層である発泡ポリ塩化ビニル樹脂層の
強度を上げ、且つ汚れを防止する為に、表面層である発
泡ポリ塩化ビニル樹脂層の表面全面を、熱可塑性合成樹
脂からなるフィルム層で覆うことにより解決する方法が
考えられる。しかしこれは、凹凸模様が付いたポリ塩化
ビニル樹脂の発泡層の表面を、熱可塑性合成樹脂からな
るフィルム層でラミネートして覆うことは、ポリ塩化ビ
ニル樹脂の発泡層の凹凸模様がある為に、熱可塑性合成
樹脂からなるフィルム層と、覆われるポリ塩化ビニル樹
脂の表面全体の密着は得られない。これは発泡層の表面
が凹凸状態となっており、発泡した凸部が接着しても凹
部が接着しないで残される為に、外観上も使用出来ない
状態となる丈で無く、当然のことながら剥離し易くなる
という欠点があった。In order to increase the strength of the foamed polyvinyl chloride resin layer as the surface layer and to prevent contamination, the entire surface of the foamed polyvinyl chloride resin layer as the surface layer is coated with a film layer made of a thermoplastic synthetic resin. A possible solution is to cover it. However, this is because the surface of the polyvinyl chloride resin foam layer with the uneven pattern is laminated and covered with a film layer made of thermoplastic synthetic resin because the uneven pattern of the polyvinyl chloride resin foam layer is present. In addition, adhesion between the film layer made of a thermoplastic synthetic resin and the entire surface of the polyvinyl chloride resin to be covered cannot be obtained. This is because the surface of the foam layer is uneven, and even if the foamed protrusions adhere, the recesses do not adhere and are left unattached, so it is not in a state where it can not be used in appearance, and it is natural There was a drawback that peeling was easy.
【0005】また上記欠点を解消する方法として、凹凸
模様が付いたポリ塩化ビニル樹脂の発泡層の表面に、ペ
ーストゾルを用いたコーティングを施して凹凸面に密着
した表面塗膜層を設けることは可能であるが、この場合
にはペーストゾル中に含まれる可塑剤の影響で、汚れ防
止効果が得られない。本発明はこれらの欠点を解消した
ものである。As a method for solving the above-mentioned drawbacks, it is not possible to apply a coating using a paste sol to the surface of a foamed layer of a polyvinyl chloride resin having a concavo-convex pattern to provide a surface coating layer in close contact with the concavo-convex surface. Although it is possible, in this case, the effect of preventing contamination cannot be obtained due to the influence of the plasticizer contained in the paste sol. The present invention has solved these disadvantages.
【0006】[0006]
【課題を解決するための手段】本発明者等は種々検討の
結果、裏打難燃紙の上にポリ塩化ビニル樹脂ベース層を
設けた基材の上に、ポリ塩化ビニル樹脂の発泡層をロー
タリースクリーン法等により模様状に設けた後、熱可塑
性合成樹脂からなるフィルムの貼り合わせ面を該ポリ塩
化ビニル樹脂発泡層が発泡しない様な温度で溶融して、
未発泡の状態である為に表面凹凸の少ないポリ塩化ビニ
ル樹脂発泡層と貼り合わせるか、若しくは接着剤を用い
て未発泡で表面凹凸の少ないポリ塩化ビニル樹脂発泡層
の表面に熱可塑性合成樹脂からなるフィルムを貼り合わ
せて後、該未発泡のポリ塩化ビニル樹脂発泡層を発泡さ
せる方法にによってこれらの問題が解決出来ることを見
出したものである。As a result of various studies, the present inventors have found that a foamed layer of a polyvinyl chloride resin is formed on a base material having a polyvinyl chloride resin base layer on a backing flame-retardant paper. After being provided in a pattern by a screen method or the like, the bonding surface of the film made of a thermoplastic synthetic resin is melted at such a temperature that the polyvinyl chloride resin foam layer does not foam,
Since it is in an unfoamed state, it is bonded to the polyvinyl chloride resin foam layer with less surface irregularities, or the surface of the non-foamed polyvinyl chloride resin foam layer with less surface irregularities is made of thermoplastic synthetic resin using an adhesive. It has been found that these problems can be solved by a method of foaming the unfoamed polyvinyl chloride resin foam layer after laminating a film.
【0007】又本発明に用いる基材は必ずしも表面が平
滑である必要は無く、深い凹凸模様のエンボス等が施さ
れているもの等を除けば、エンボス入りのものであって
も本発明の方法は適用出来る。更に裏打難燃紙そのもの
が使用できることは勿論、裏打難燃紙に塩化ビニル樹脂
層等の発泡塩化ビニル樹脂と接着性の良い熱可塑性樹脂
によるベース層を設けたり、このベース層に軽いエンボ
スを施したり、印刷等による模様付けをしたものであっ
ても良い。然し、より確実に表面塗膜層を発泡する凹凸
面に密着して設ける為には、フィルムのラミネート加工
前の下地表面が平滑性が高いほうが好ましいことは言う
までもない。従って、ベースに印刷等による模様付けを
したものに、発泡層が発泡しない条件であれば、ロール
掛け等のプレーンエンボス加工を施して表面を平滑にす
ることは、発泡層と表面塗膜層の間に気泡を噛んだまま
になり、次工程で発泡した時にエアが巻き込まれて浮い
た部分が出来る状態を防止し得るので有効である。The substrate used in the present invention does not necessarily have to have a smooth surface, and even if it is embossed, the method of the present invention can be applied to the substrate except that the substrate is embossed with a deep uneven pattern. Is applicable. In addition to the fact that the backing flame-retardant paper itself can be used, the base flame-retardant paper may be provided with a base layer made of a thermoplastic resin with good adhesive properties to the foamed vinyl chloride resin such as a vinyl chloride resin layer, or this base layer may be embossed lightly. Or may be patterned by printing or the like. However, in order to more reliably provide the surface coating layer in close contact with the foamed uneven surface, it is needless to say that the smoothness of the underlayer surface before laminating the film is preferable. Therefore, if the base is patterned by printing or the like, and the foamed layer does not foam, it is necessary to apply a plain embossing process such as rolling to smooth the surface, and to form a smooth surface between the foamed layer and the surface coating layer. This is effective because air bubbles are left between the air bubbles and air bubbles are formed in the next step, thereby preventing a floating portion from being formed.
【0008】[0008]
【作用】本発明に用いる材料は、特殊なものを用いる必
要は全く無く、覆いに用いる熱可塑性合成樹脂フィルム
の材質も、アクリル樹脂、ポリ塩化ビニル、エチレン−
酢酸ビニル共重合体ケン化物等の防汚機能及び表面強度
のある適当なものを選んで用いることができる。未発泡
で表面凹凸が殆どないポリ塩化ビニル樹脂発泡層に熱可
塑性合成樹脂からなるフィルムをラミネートしてフィル
ム層を密着させた後、ポリ塩化ビニル樹脂発泡層を発泡
させることにより、凹凸感のある防汚機能を有する発泡
内装材を得ることに成功したものである。There is no need to use any special material for the present invention, and the material of the thermoplastic synthetic resin film used for the covering may be acrylic resin, polyvinyl chloride, ethylene-
A suitable material having an antifouling function and surface strength such as a saponified vinyl acetate copolymer can be selected and used. After laminating a film made of a thermoplastic synthetic resin on a non-foamed polyvinyl chloride resin foam layer with almost no surface irregularities and closely attaching the film layer, foaming the polyvinyl chloride resin foam layer gives a feeling of unevenness. It succeeded in obtaining a foam interior material having an antifouling function.
【0009】[0009]
【実施例1】壁紙用の原紙(坪量75g/m2 の難燃
紙)に 塗料として PVC(重合度900) 100
重量部 DOP 55重量部 発泡剤(ADCA系) 4重量部 安定剤(Ba-Zn 複合系) 2重量部 充填剤(炭酸カルシウム) 20重量部 着色剤 適量 からなる配合のものを用いて、ロータリースクリーンに
て織物無地柄を印刷塗布(付着量250g/m2 )した
後、温度160°Cにて発泡を抑えて乾燥させてから、
ウレタン系接着剤を10g/m2 塗布したエチレン−酢
酸ビニル共重合体ケン化物フィルム(商品名エバール1
5μ厚)を160°C、1.5Kg/cm2 圧にて表面
に接着した。後、温度200°Cにて塗布した発泡塩化
ビニル塗料を2分間加熱発泡して、表面全体がエバール
フィルムにて完全に密着状態で覆われた発泡壁紙を得
た。Example 1 Base paper for wallpaper (flame-retardant paper having a basis weight of 75 g / m 2 ) as a paint PVC (degree of polymerization 900) 100
Parts by weight DOP 55 parts by weight Blowing agent (ADCA type) 4 parts by weight Stabilizer (Ba-Zn composite type) 2 parts by weight Filler (calcium carbonate) 20 parts by weight Coloring agent After printing and applying a plain woven pattern at 250 g / m 2 , the foam is dried at a temperature of 160 ° C. while suppressing foaming.
A saponified ethylene-vinyl acetate copolymer film coated with a urethane-based adhesive at 10 g / m 2 (trade name: EVAL 1)
(5 μm thick) was adhered to the surface at 160 ° C. and a pressure of 1.5 kg / cm 2 . Thereafter, the foamed vinyl chloride paint applied at a temperature of 200 ° C. was heated and foamed for 2 minutes to obtain a foamed wallpaper whose entire surface was completely covered with an EVAL film.
【0010】[0010]
【実施例2】壁紙用の原紙(坪量75g/m2 の難燃
紙)に PVC(重合度1200) 100重量部 DOP 60重量部 発泡剤(ADCA系) 2重量部 安定剤(Ba-Zn 複合系) 2重量部 充填剤(炭酸カルシウム) 50重量部 着色剤(二酸化チタン) 10重量部 からなる配合の塗料を150g/m2 塗布乾燥してべー
ス層とし、深さ0.3mmのエンボスを施した後、 PVC(重合度900) 100重量部 DOP 55重量部 発泡剤(ADCA系) 4重量部 安定剤(Ba-Zn 複合系) 2重量部 充填剤(炭酸カルシウム) 40重量部 着色剤(二酸化チタン) 適量 からなる配合の塗料を織物無地柄のロータリースクリー
ンにて付着量が120g/m2 になるように塗布した
後、温度170°Cにて発泡を抑えて加熱後、直ちにプ
レーンロールにてアクリルフィルム(厚さ30μ)を圧
力2Kg/cm2 にて発泡性塩化ビニル樹脂塗料塗布面
に圧着した。後、温度200°Cにて塗布した発泡塩化
ビニル塗料を2分間加熱発泡して表面全体がアクリルフ
ィルムにて完全に密着状態で覆われた発泡壁紙を得た。Example 2 Base paper for wallpaper (flame-retardant paper having a basis weight of 75 g / m 2 ) 100 parts by weight of PVC (polymerization degree 1200) DOP 60 parts by weight Blowing agent (ADCA type) 2 parts by weight Stabilizer (Ba-Zn) (Composite system) 2 parts by weight Filler (calcium carbonate) 50 parts by weight Coloring agent (titanium dioxide) 10 parts by weight A paint having a composition of 150 g / m 2 is applied and dried to form a base layer having a depth of 0.3 mm. After embossing, PVC (degree of polymerization: 900) 100 parts by weight DOP 55 parts by weight Blowing agent (ADCA type) 4 parts by weight Stabilizer (Ba-Zn composite type) 2 parts by weight Filler (calcium carbonate) 40 parts by weight Coloring Agent (titanium dioxide) An appropriate amount of paint is applied on a rotary screen with a plain woven fabric so that the amount of adhesion becomes 120 g / m 2 , and then heated at a temperature of 170 ° C. to suppress foaming, and then immediately To roll An acrylic film (thickness: 30 μm) was pressed against the foamed vinyl chloride resin paint-coated surface at a pressure of 2 kg / cm 2 . Thereafter, the foamed vinyl chloride paint applied at a temperature of 200 ° C. was heated and foamed for 2 minutes to obtain a foamed wallpaper whose entire surface was completely covered with an acrylic film.
【0011】[0011]
【実施例3,4】実施例1.2に於いて、発泡性塩化ビ
ニル層を設けた後に160℃、1.5Kg/cm2の条件でプ
レーンロール掛けして表面を平滑にする以外は、実施例
1.2と同様にして、フィルムで完全に密着状態になる
様に覆われた発泡壁紙を得た。Examples 3 and 4 In Example 1.2, except that a foaming vinyl chloride layer was provided and then a plain roll was applied under the conditions of 160 ° C. and 1.5 kg / cm 2 to smooth the surface. In the same manner as in Example 1.2, a foamed wallpaper covered with a film so as to be completely adhered was obtained.
【0012】[0012]
【比較例1〜2】実施例1及び2に於いて、ロータリー
スクリーンにて塗布した発泡塩化ビニル樹脂を200°
Cで2分間加熱しただけで、フィルムラミネートをして
いない発泡壁紙を得た。Comparative Examples 1 and 2 In Examples 1 and 2, the foamed vinyl chloride resin applied by a rotary screen was set at 200 °
By heating at C for 2 minutes, a foamed wallpaper without film lamination was obtained.
【0013】以上の実施例及び比較例につき性能評価を
したところ下記の通りであった。 実施例1 実施例2 実施例3 実施例4 耐汚染性(マジックインキ) ◎ ○ ◎ ○ 〃 (コーヒー) ◎ ◎ ◎ ◎ 〃 (クレヨン) ◎ ◎ ◎ ◎ 表面強度(摩擦回数 200回) ○ ○ ○ ○ 〃 (摩擦回数 500回) ○ ○ ○ ○ 〃 (摩擦回数1000回) ○ ○〜△ ○ ○〜△ エア噛み込み(浮き) ○ ○ ◎ ◎ 比較例1 比較例2 耐汚染性(マジックインキ) × × 〃 (コーヒー) △ △ 〃 (クレヨン) △〜× △〜× 表面強度(摩擦回数 200回) △ △ 〃 (摩擦回数 500回) △〜× △〜× 〃 (摩擦回数1000回) × × 耐汚染の評価方法は、 耐汚染性(マジックインキ):表面を油性のマジックイ
ンキにて汚染して24時間経過後、ベンジンを染み込ま
せた布で拭き取った結果。 耐汚染性(コーヒー) 表面にコーヒーをこぼし24時間経過後、湿布にて拭き
取った結果。 耐汚染性(クレヨン) 表面を赤色のクレヨンにて汚染して24時間経過後、ベ
ンジンを染み込ませた布で拭き取った結果。判定基準
は、 × 殆ど吹き取れない。 △ 少し
拭き取れる。 ○ 僅かに後が残る。 ◎ 異常
無し。 エア噛み込み(浮き)の評価方法は、発泡後の浮き(エ
ア噛み込み状態を目視にて観察した。判定結果の表現
は、 ◎ 全くエア噛み込みの徴候も見られない。 ○ エア噛み込みの徴候らしきものはみられるが、実質
的にエア噛み込みは無い。 △ 僅かにエア噛み込みが発生。 表面強度の評価方法は、JIS−L−0823による表
面摩擦堅牢度テストによる。判定結果の表現は、 ○ 異常無し。 △ やや摩耗した。 × 完全に摩耗した。The performance of the above Examples and Comparative Examples was evaluated as follows. Example 1 Example 2 Example 3 Example 4 Stain resistance (magic ink) ◎ ○ ◎ ○ 〃 (coffee) ◎ ◎ ◎ ◎ 〃 (crayon) ◎ ◎ ◎ ◎ Surface strength (200 times of friction) ○ ○ ○ ○ 〃 (Friction frequency 500 times) ○ ○ ○ ○ 〃 (Friction frequency 1000 times) ○ ○ 〜 △ ○ ○ 〜 △ Air entrapment (floating) ○ ○ ◎ ◎ Comparative example 1 Comparative example 2 Stain resistance (magic ink) × × 〃 (coffee) △ △ 〃 (crayon) △ ~ × △ 〜 × Surface strength (200 times of friction) △ △ 〃 (500 times of friction) △ ~ × △ ~ × 〃 (1000 times of friction) × × The method for evaluating stain resistance is as follows: Stain resistance (magic ink): The result of wiping with a cloth impregnated with benzene after 24 hours after the surface was stained with oily magic ink. Stain resistance (coffee) The result of spilling coffee on the surface and wiping with a compress after 24 hours. Stain resistance (crayon) The result of wiping with a cloth impregnated with benzene after 24 hours after the surface was contaminated with red crayon. Judgment criteria: x Hardly blow off. △ Can be wiped off a little. ○ Slightly remains. ◎ No abnormality. The method of evaluating the air entrapment (floating) was as follows: The air entrapment after bubbling (the state of the air entrapment was visually observed. The expression of the judgment result was: ◎ No sign of air entrapment was observed. Although there seems to be a sign, there is practically no air entrapment. △ Slight air entrapment occurs The surface strength is evaluated by a surface friction fastness test according to JIS-L-0823. : ○ No abnormality △ Slightly worn × Completely worn
【0014】[0014]
【発明の効果】以上実施例と比較例からも明らかな通
り、従来の発泡壁紙の特徴を活かした儘欠点であった表
面の傷つき易さなどの強度を改善し、且つ汚れがつきず
らいだけでなく、万一汚した場合にも容易に拭き取りが
可能な、優れた壁紙を提供するものである。As is clear from the above Examples and Comparative Examples, the strength of the conventional foamed wallpaper, such as the surface being easily damaged, was improved while taking advantage of the characteristics of the conventional foamed wallpaper, and the dirt was hardly removed. In addition, the present invention provides an excellent wallpaper that can be easily wiped even if it becomes dirty.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭63−72527(JP,A) 実開 昭58−115334(JP,U) 実開 昭58−21436(JP,U) 特公 昭48−39032(JP,B1) (58)調査した分野(Int.Cl.7,DB名) B32B 1/00 - 35/00 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-63-72527 (JP, A) JP-A 58-115334 (JP, U) JP-A 58-21436 (JP, U) 39032 (JP, B1) (58) Fields investigated (Int. Cl. 7 , DB name) B32B 1/00-35/00
Claims (4)
脂塗料を模様状に印刷若しくは塗布し、印刷若しくは塗
布された発泡ポリ塩化ビニル樹脂塗料が発泡しないよう
な温度で溶融した状態で、熱可塑性合成樹脂からなるフ
ィルムを表面にラミネートした後、該発泡ポリ塩化ビニ
ル樹脂塗料を発泡させることを特徴とする、防汚機能を
有する発泡内装材の製造方法To 1. A top of the backing flame燃紙, foamed polyvinyl chloride resin coating was printed or coated on the pattern shape, printed or coated foamed poly as vinyl chloride resin paint does not foam
A method for producing a foamed interior material having an antifouling function, comprising laminating a film made of a thermoplastic synthetic resin on the surface in a state of being melted at an appropriate temperature, and then foaming the foamed polyvinyl chloride resin paint.
脂塗料を模様状に印刷若しくは塗布し、印刷若しくは塗
布された発泡ポリ塩化ビニル樹脂塗料が発泡をしないよ
うな温度で溶融した状態で緩く加熱しながらプレスして
平滑にした表面に、熱可塑性性合成樹脂からなるフィル
ムをラミネートした後、該発泡ポリ塩化ビニル樹脂塗料
を発泡させることを特微とする、防汚機能を有する発泡
内装材の製造方法。2. A foamed polyvinyl chloride resin paint is printed or applied on the backing flame-retardant paper in a pattern, so that the printed or applied foamed polyvinyl chloride resin paint does not foam .
After laminating a film made of a thermoplastic synthetic resin on the surface smoothed by pressing while heating loosely in a molten state at such a temperature , the foamed polyvinyl chloride resin paint is characterized by foaming, A method for producing a foamed interior material having an antifouling function.
ス層を設け、該ポリ塩化ビニル樹脂ペース層上に発泡ポ
リ塩化ビニル樹脂塗料を模様状に印刷若しくは塗布し、
印刷若しくは塗布された発泡ポリ塩化ビニル樹脂塗料が
発泡しないような温度で溶融した状態で、熱可塑性合成
樹脂からなるフイルムを表面にラミネートした後、該発
泡ポリ塩化ビニル樹脂塗料を発泡させることを特徴とす
る、防汚機能を有する発泡内装材の製造方法。3. A polyvinyl chloride resin paste layer is provided on a backing flame-retardant paper, and a foamed polyvinyl chloride resin paint is printed or applied on the polyvinyl chloride resin paste layer in a pattern.
After laminating a film made of a thermoplastic synthetic resin on the surface in a state where the printed or applied foamed polyvinyl chloride resin paint is melted at a temperature that does not foam, the foamed polyvinyl chloride resin paint is foamed. A method for producing a foamed interior material having an antifouling function.
ス層を設け、該ポリ塩化ビニル樹脂ペース層上に発泡ポ
リ塩化ビニル樹脂塗料を模様状に印刷若しくは塗布し、
印刷若しくは塗布された発泡ポリ塩化ビニル樹脂塗料が
発泡をしないような温度で溶融した状態で、緩く加熱し
ながらプレスして表面を平滑にした表面に、熱可塑性合
成樹脂からなるフィルムをラミネートした後、該発泡ポ
リ塩化ビニル樹脂塗料を発泡させることを特徴とする、
防汚機能を有する発泡内装林の製造方法。4. A polyvinyl chloride resin paste layer is provided on a backing flame-retardant paper, and a foamed polyvinyl chloride resin paint is printed or applied in a pattern on the polyvinyl chloride resin paste layer,
After laminating a film made of thermoplastic synthetic resin on the surface that has been smoothed by pressing while gently heating in a state where the printed or applied foamed polyvinyl chloride resin paint is melted at a temperature that does not foam Characterized by foaming the foamed polyvinyl chloride resin paint,
A method for producing a foam interior forest having an antifouling function.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP06181987A JP3111373B2 (en) | 1993-08-26 | 1994-07-12 | Foam interior material and method for producing the same |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23221093 | 1993-08-26 | ||
JP5-232210 | 1993-08-26 | ||
JP06181987A JP3111373B2 (en) | 1993-08-26 | 1994-07-12 | Foam interior material and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07112502A JPH07112502A (en) | 1995-05-02 |
JP3111373B2 true JP3111373B2 (en) | 2000-11-20 |
Family
ID=26500955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP06181987A Expired - Fee Related JP3111373B2 (en) | 1993-08-26 | 1994-07-12 | Foam interior material and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3111373B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7128523B2 (en) | 2019-12-17 | 2022-08-31 | 学校法人実践女子学園 | card system |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10305535A (en) * | 1997-05-09 | 1998-11-17 | Nippon Synthetic Chem Ind Co Ltd:The | Laminate |
JP5041720B2 (en) * | 2005-03-30 | 2012-10-03 | 大日本印刷株式会社 | Wall covering decorative sheet and wall covering decorative sheet |
JP6120207B2 (en) * | 2012-11-30 | 2017-04-26 | ダイニック株式会社 | wallpaper |
JP2019142202A (en) * | 2018-02-23 | 2019-08-29 | 大日本印刷株式会社 | Foam laminate sheet |
-
1994
- 1994-07-12 JP JP06181987A patent/JP3111373B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7128523B2 (en) | 2019-12-17 | 2022-08-31 | 学校法人実践女子学園 | card system |
Also Published As
Publication number | Publication date |
---|---|
JPH07112502A (en) | 1995-05-02 |
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