JP3103042U - Analgesic plaster - Google Patents

Abstract

[PROBLEMS] When applied to an affected part of the body as an analgesic plaster, the body temperature rises by 0.5 to 1 ° C. to promote blood circulation, and emits electrons, and the plus electrons in the body become ± 0, leaving neck and shoulder stiffness. Immediately remove back pain, neuralgia, etc.
SOLUTION: A fine powder of inorganic germanium of high purity is mixed with a binder, coated on a sheet base material 2 to form a germanium-containing layer 14, and is further bonded to the germanium-containing layer in an appropriate planar shape. The layer 16 is formed. For example, a fine powder of inorganic germanium having a purity of 99.999% or more is mixed with a polyurethane resin as a germanium-containing layer.
[Selection diagram] Fig. 1

Description

  The present invention relates to an analgesic plaster made of high-purity inorganic germanium. When attached to an affected part of the body, the body temperature rises by 0.5 to 1 ° C. to promote blood circulation, and emits electrons to generate positive electrons in the body. The present invention relates to an analgesic plaster capable of quickly removing neck and shoulder stiffness, low back pain, neuralgia, etc. when the value becomes ± 0.

  Modern people are busy with work, housekeeping, studying, etc., and daily fatigue accumulates. Many people complain of stiff shoulders, lower back pain, muscle fatigue, etc. on a daily basis. Many anti-inflammatory analgesic plasters are commercially available to relieve this pain. This anti-inflammatory analgesic plaster often contains a skin irritant as an anti-inflammatory analgesic, and l-menthol and dl-camphor have a local irritating effect, and may cause eczema, rash, etc., and methyl salicylate is Due to the property of being easily absorbed from the skin, it is easy to get rash when applied for a long time at the same location. In addition, if the adhesive strength of the plaster is too strong, the skin may become red at the time of peeling.Therefore, an antihistamine is added to the anti-inflammatory analgesic agent, or mechanical ventilation is performed on the plaster base material to improve air permeability. May be granted.

  This anti-inflammatory analgesic plaster requires less mechanical irritation at the time of peeling and requires less adhesive substance to remain on the skin after peeling. Spreading sticky substance with drug. This anti-inflammatory analgesic plaster is applied over a wide area other than the required affected area, and if the application is applied for a long time, not only rash-prone persons but also ordinary persons cannot escape itching or redness. In order to reduce this, for example, in Japanese Patent Application Laid-Open No. 2000-169366, in a sheet-like raster in which an external preparation containing an anti-inflammatory analgesic is spread on the upper surface of the support, only the substantially central portion of the spread external preparation is affected. The thick embossed portion is raised in a range suitable for being mounted in accordance with the above. Japanese Patent Application Laid-Open No. H11-263724 discloses a thermal plaster containing a drug holding piece containing a tincura capsici or the like which gives a warm feeling corresponding to an applied portion inside a peripheral edge of a support having an adhesive layer formed thereon. And the planar shape of the medicine holding piece is determined to be a rectangle.

In an analgesic plaster, if the medicine is heaped up in the center of the sheet material or a rectangular medicine holding piece is held inside the support with an adhesive layer formed around it, it will reduce rash and redness caused by these medicines Although it can be done, it cannot be completely avoided, and the effect of the treatment is not enough. On the other hand, the use of sheet-like germanium instead of these agents is disclosed in Japanese Patent Application Laid-Open No. 58-1465 or Japanese Patent No. 2572520. The generation of germanium ions from germanium semiconductors harmonizes bioelectric currents, relieves muscle tension, releases blood congestion, improves blood circulation, and causes side effects such as rash, redness, and inflammation during use. There is no.
JP 2000-169366 A JP-A-11-263724 JP-A-58-1465 Japanese Patent No. 2572520

  The skin abutment piece disclosed in Japanese Patent Application Laid-Open No. 58-1465 is formed by mixing germanium particles and metal particles into a sheet, and is a hard plate, so that it can be fixed to the body with a bandage or bandage. Uncomfortable feeling cannot be avoided and contact with the skin surface is not good. The germanium particles have a problem that the purity is not so high because they are mixed with other metal particles, and the action of relieving body stiffness and pain is not sufficient. The semiconductor therapeutic agent disclosed in Japanese Patent No. 2572520 specifies a germanium semiconductor thin film or powder as an example of a p-type semiconductor, and forms the p-type semiconductor thin film on the surface of a molded body such as plastic. When forming a thin film on the surface of a hard molded product, this semiconductor therapeutic agent cannot avoid the discomfort during use if it is fixed to the body with an adhesive bandage or the like as described above. When kneading germanium powder with a commercially available lotion or the like, aluminum or the like is added, so that the purity is not so high, and it is easy to dissipate from the body.

  On the other hand, bracelets, necklaces, rings and the like exist as products containing germanium of relatively high purity. Germanium bracelets have the advantage of longer lasting effects compared to magnet bracelets, but bracelets and necklaces have less contact with the skin of the body when used and fully enjoy the beneficial effects of germanium. I hate it. Germanium rings have a limited area of contact even if they are completely in contact with the skin of the body, and can only enjoy the effect locally.If there is a problem with the usability of the ring, the only way to remove it is to take measures Absent.

  SUMMARY OF THE INVENTION The present invention has been proposed to improve the above-mentioned problems with an analgesic plaster containing a germanium product, and provides an analgesic plaster having high-purity inorganic germanium, which is a p-type semiconductor having a good therapeutic effect. It is an object. Another object of the present invention is to provide an analgesic plaster that can be easily attached to an affected part of a body with a flexible material and that can quickly remove neck and shoulder stiffness, back pain, neuralgia and the like.

  The analgesic plaster according to the present invention is obtained by mixing a high-purity inorganic germanium fine powder with a binder, coating it on a sheet substrate to form a germanium-containing layer, and further forming an appropriate planar shape on the germanium-containing layer. Is formed. In other words, a fine powder of inorganic germanium having a purity of 99% or more is mixed with a polyurethane resin, coated on a sheet substrate to form a germanium-containing layer, and then an appropriate flat surface is formed on the germanium-containing layer. Is to form a shaped adhesive layer.

  More specifically, the analgesic plaster of the present invention prepares a sheet substrate having a reflective layer composed of aluminum powder and a binder on a fabric, and then mixes a fine powder of inorganic germanium having a purity of 99% or more with the binder. Then, a germanium-containing layer is formed by coating on the reflection layer of the sheet base material, and an adhesive layer having an appropriate planar shape is formed on the germanium-containing layer. In other words, a sheet substrate having a reflective layer made of aluminum powder and a polyurethane resin is prepared on a nylon cloth, and then fine powder of high-purity inorganic germanium is mixed with the polyurethane resin to form a sheet substrate. This is to form a germanium-containing layer by coating on the reflective layer, and to further form an adhesive layer having an appropriate planar shape on the germanium-containing layer.

  As an actual product, the analgesic plaster of the present invention forms a reflective layer made of aluminum powder and polyurethane resin on nylon cloth, and forms a pattern layer containing polyurethane resin on nylon cloth. To prepare a sheet base material. Then, a fine powder of inorganic germanium having a purity of 99.999% or more is mixed with a polyurethane resin, coated on a reflective layer of a sheet substrate to form a germanium-containing layer, and a rubber-based layer is formed on the germanium-containing layer. An adhesive layer having an appropriate planar shape made of an adhesive or an acrylic adhesive is formed.

Germanium is an element having an atomic number of 32 and an atomic weight of 72.59 that does not change in the air and has a metal-like appearance, but is not a metal but an intrinsic semiconductor, and is therefore described as inorganic germanium in this specification. Germanium is extracted as a tetrachloride GeCl ₄ from an ore such as germane or Rhenie ore, purified by distillation and then hydrolyzed, and the generated dioxide GeO ₂ is reduced with hydrogen. When this is refined by a zone melting method, a high-purity simple substance having an off-white diamond structure is obtained. Germanium has a melting point of 937.4 ° C., a boiling point of 2830 ° C., a density of 5.32 g / cm ³ (25 ° C.), an electron mobility of 3900 cm ² / V · s, a hole mobility of 1900 cm ² / V · s, and a magnetic susceptibility of −0. .106 × 10 ⁻⁶ cm ³ / g, thermal conductivity 59.9 W / m · K, and becomes GeO ₂ dioxide at high temperature.

  Semiconductors such as inorganic germanium include a p-type semiconductor and an n-type semiconductor, and germanium is an electron-deficient p-type semiconductor. When a p-type semiconductor is brought into contact with human skin, blood flow is increased by thermography and measurement using a laser speckle blood flow meter, causing pain-causing substances and fatigue substances remaining in the capillaries to be removed.・ Stiff shoulder, neuralgia and muscle pain can be eliminated. When a p-type semiconductor is applied to the skin, a therapeutic effect is generally observed in about 80% of the total sample of the p-type semiconductor. The higher the purity of inorganic germanium as a semiconductor therapeutic agent, the more remarkable the therapeutic effect on muscle pain and the like is recognized. If the purity is 99% or more, more preferably 99.999% or more, it will be painful by sticking. No side effects occur.

  The inorganic germanium is used in the form of, for example, a fine powder of 5 μm or less, and this fine powder is uniformly and sufficiently kneaded with a binder made of a polyurethane resin, an acrylic resin latex or a soft resin equivalent thereto. The fine powder of inorganic germanium is added in an amount of 5 to 10% by weight based on the binder resin solution. Referring to the drawings, the germanium-containing layer 14 (FIG. 1) is partially or entirely coated on the reflective layer 8 of the sheet substrate 2 by a silk screen method or a roll coater method, and has a thickness of 10 to 10. It may be 40 μm. This resin solution may be any of resin latex, resin emulsion, resin suspension, hydrophilic copolymer, chemically reactive water-soluble resin, etc., as long as fine powder of inorganic germanium can be uniformly kneaded.

  Regarding the germanium-containing layer 14, the binder is preferably a polyurethane resin. Polyurethane-based resins are, for example, heat-crosslinkable or cross-linkable with time, and generally have low density, so that germanium has better ion permeability than other resins. Polyurethane-based resins are excellent in elongation, abrasion resistance, rebound resilience, and compressive fatigue strength, and cause little delamination or cracking when applied to an affected part.

  The adhesive layer 16 is, for example, selected from a pressure-sensitive adhesive suitable for the material of the sheet substrate 2 and, in order to impart high flexibility, the adhesive layer 16 is usually made of a rubber-based adhesive or an acrylic resin, The thickness is reduced to improve the ion permeability of germanium. In particular, if the sheet substrate 2 is a highly stretchable fiber product, it is preferable that the adhesive layer 16 be made of an acrylic resin because the adhesive strength is large and there is no rash. The thickness of the adhesive layer 16 is determined according to the surface shape of the material to be transferred, and is generally 20 to 200 μm.

  If the adhesive layer 16 does not peel off due to perspiration and can be repeatedly adhered, the adhesive layer is, for example, adhered to a rubber-based adhesive in the presence of a water-insoluble water-absorbent resin powder and moisture. A water-soluble polymer powder having properties is dispersed. In the adhesive layer 16, the rubber-based adhesive is composed of a rubber-adhesive component such as natural rubber, isoprene-based rubber, isobutylene-based rubber, styrene copolymer-based rubber, silicon-based rubber, or acrylic rubber, and petroleum resin, rosin, hydrogenated rosin. , An ester gum, a terpene resin, a styrene resin, an isoprene resin and the like, and a plasticizer such as petrolatum, lanolin and liquid paraffin. The water-absorbent resin powder has an average particle diameter of 1 to 100 μm, such as a starch-polyacrylate graft copolymer, a crosslinked polyacrylate, an acrylate-vinyl alcohol copolymer, and a crosslinked isobutylene-maleate copolymer. It is. The water-soluble polymer powder is polyacrylic acid, polyacrylate, polyacrylamide, polyethylene oxide, polyethylene imine, polyvinyl alcohol, polyvinyl pyrrolidone, or the like, and provides an adhesive layer having high water absorption.

  The adhesive layer 16 may be formed entirely on the germanium-containing layer 14 and cut into a desired shape together with release paper (not shown) when the analgesic plaster 1 is used. As shown in FIG. 4, the adhesive layer 16 may be determined in advance in a planar shape such as (1) rectangular, (2) circular, (3) turtle-shape, or (4) elliptical, depending on the sticking place or the like. . In this case, it is preferable that the adhesive layer 16 is an acrylic resin having a large adhesive force and little rash.

  Further, as shown in FIG. 5, the adhesive layer 16 may be formed on a part of the plane of the germanium-containing layer 14, and it is possible to remove the germanium-containing layer only on the plane where the adhesive layer 16 exists. Examples of the adhesive layer include planar shapes such as (1) an annular shape, (2) a rectangular annular shape, (3) a small round shape at the center, and a rectangle at four corners. In this case, since the germanium-containing layer 14 is in direct contact with the affected part, it can be expected that the therapeutic effect of high-purity inorganic germanium will be more effective.

  The analgesic plaster according to the present invention, when affixed to an affected part of the body, causes a lot of pains, such as neck and shoulder stiffness, neuralgia, whiplash, fifty shoulder, lower back pain, waist, knee pain, foot pain, sprain, sciatica, Excellent treatment for rheumatoid arthritis, tinnitus, hearing loss, hemophilia, etc. In this analgesic plaster, germanium ions are effectively generated from the germanium-containing layer, instantaneously harmonizing the disturbed bioelectric current to relieve muscle tension, release blood congestion, improve blood circulation and improve body stiffness. It relieves pain and pain, and does not cause side effects such as rash, redness, and inflammation when used.

  The analgesic plaster of the present invention is also highly safe because high-purity inorganic germanium has obtained medical device approval from the Ministry of Health, Labor and Welfare. The higher the purity of germanium in this analgesic plaster, the more effective it is. If the purity is 99.999% or more, the destruction of muscle cells due to active oxygen harmful to the human body can be surely suppressed. There are no side effects such as onset.

  The analgesic plaster of the present invention is a flexible and thin sheet material having a thickness of about 0.5 to 1.0 mm. This analgesic plaster is thin and flexible, so there is almost no sense of incongruity when applied, and it expands and contracts according to the movement of the body, so it is hard to peel off when used, and it is possible to perform meals, gymnastics and other work with it attached It is.

  Next, the present invention will be described based on embodiments, but the present invention is not limited to the embodiments. FIG. 1 shows an example of an analgesic plaster 1 according to the present invention.

  The sheet substrate 2 of the analgesic plaster 1 is composed of a front surface material 3 (FIG. 2) and a back surface material 5 (FIG. 3). As shown in FIG. 2, the surface material 3 has a silver reflective layer 8 formed by kneading an aluminum powder and a polyurethane resin on a thin nylon cloth 7. Further, as shown in FIG. 3, a pattern layer 12 containing a polyurethane-based resin is formed on a thin nylon cloth 10 on the back surface member 5, and further, appropriate characters and figures are printed. The pattern layer 12 is usually white by adding a white pigment such as titanium oxide, and further prints appropriate characters and figures on the surface thereof.

  The fabrics 7, 10 are usually the same thin nylon fabric. The reflection layer 8 and the pattern layer 12 are thinly attached to the nylon cloths 7 and 10 to a thickness of about 10 to 50 μm by a silk screen method or a roll coater method. It is preferable to add an appropriate amount of a thermoplastic polyamide resin to the reflective layer 8 and the pattern layer 12 in order to increase the gripping force with the fabrics 7 and 10.

  The sheet substrate 2 is entirely bonded with nylon fabrics 7 and 10 with a double-sided adhesive tape (not shown) or the like, and integrated through a pair of rollers. The germanium-containing layer 14 is manufactured by sufficiently kneading 8% by weight of inorganic germanium fine powder having a purity of 99.999% and 92% by weight of a polyurethane resin latex. The germanium-containing layer 14 is entirely coated on the reflective layer 8 of the sheet substrate 2 by a silk screen method. The thickness of the germanium-containing layer 14 is about 10 μm.

  An adhesive layer 16 having an appropriate planar shape is further provided on the germanium-containing layer 14 so that the analgesic plaster 1 can be attached to the body. The adhesive layer 16 is made of, for example, an acrylic resin mainly composed of an acrylic ester of an aliphatic alcohol having 2 to 12 carbon atoms, and has a large adhesive force and does not rash during use. The thickness of the adhesive layer 16 is determined according to the surface shape of the material to be transferred, and the thickness is preferably 50 to 80 μm.

  As another adhesive layer, 30 parts of a styrene copolymer rubber, 15 parts of polyisobutylene, and 25 parts of liquid paraffin are mixed and dissolved in an appropriate amount of n-hexane, and starch-polyacrylate grafting is performed on the obtained adhesive solution. 10 parts of the copolymer may be dispersed. This dispersion is applied on the germanium-containing layer 14 by a silk screen method, and is appropriately heated to volatilize n-hexane to form an adhesive layer. This adhesive layer usually has a thickness of 50 to 80 μm.

  The adhesive layer 16 is formed over the entire surface of the germanium-containing layer 14 or, as shown in FIG. 4, has a predetermined shape such as (1) rectangular, (2) circular, (3) turtle-shaped, or (4) elliptical. Is determined in the plane shape. Further, as shown in FIG. 5, the adhesive layer 16 may be formed on a part of the germanium-containing layer 14, for example, (1) an annular shape, (2) a rectangular annular shape, and (3) a small round shape at the center. , May be defined as partial rectangles (not shown) at the four corners.

  The analgesic plaster 1 is a soft and thin sheet material having a silver surface and a thickness of 0.5 to 1.0 mm. When release paper (not shown) is peeled off from the analgesic plaster 1 and attached to an affected part of the body, inorganic germanium having a purity of 99.999% or more exerts an excellent therapeutic effect on many pains. Since the analgesic plaster 1 is thin and flexible, there is little unpleasant sensation when it is attached, and a meal or other work can be carried out with the application. Moreover, the analgesic plaster 1 is hard to be peeled off at the time of use, and can be more firmly adhered when fixed with a bandage or bandage.

FIG. 3 is an enlarged cross-sectional view illustrating the analgesic plaster according to the present invention. It is an expanded sectional view showing the surface material of a sheet substrate. It is an expanded sectional view showing the back material of a sheet substrate. It is a schematic plan view which illustrates the planar shape of an analgesic plaster. It is a schematic plan view which illustrates another planar shape of an analgesic plaster.

Explanation of reference numerals

DESCRIPTION OF SYMBOLS 1 Analgesic plaster 2 Sheet base material 8 Reflective layer 12 Pattern layer 14 Germanium containing layer 16 Adhesive layer

Claims (5)

  An analgesic plaster in which a high-purity inorganic germanium fine powder is mixed with a binder, coated on a sheet substrate to form a germanium-containing layer, and further, on the germanium-containing layer, to form an appropriate planar adhesive layer. .   A fine powder of inorganic germanium having a purity of 99% or more is mixed with a polyurethane resin, coated on a sheet substrate to form a germanium-containing layer, and an appropriate planar adhesive layer is further formed on the germanium-containing layer. An analgesic plaster that forms.   A sheet substrate having a reflective layer composed of an aluminum powder and a binder is prepared on the fabric, and fine powder of inorganic germanium having a purity of 99% or more is mixed with the binder, and coated on the reflective layer of the sheet substrate. An analgesic plaster comprising a germanium-containing layer, and an appropriate planar adhesive layer formed on the germanium-containing layer.   Prepare a sheet substrate having a reflective layer consisting of aluminum powder and polyurethane resin on nylon fabric, then mix fine powder of high-purity inorganic germanium with polyurethane resin, and place it on the reflective layer of the sheet substrate. An analgesic plaster which is coated to form a germanium-containing layer and further forms an appropriate planar adhesive layer on the germanium-containing layer. A reflective layer consisting of aluminum powder and polyurethane resin is formed on the nylon fabric, and a pattern layer containing the polyurethane resin is formed on the nylon fabric. Then, a fine powder of inorganic germanium having a purity of 99.999% or more is mixed with a polyurethane resin, coated on a reflective layer of a sheet substrate to form a germanium-containing layer, and further on the germanium-containing layer. An analgesic plaster that forms an appropriate planar adhesive layer made of a rubber-based adhesive or an acrylic adhesive.

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