JP3088229B2 - Hair cosmetics - Google Patents

Hair cosmetics

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Publication number
JP3088229B2
JP3088229B2 JP05347849A JP34784993A JP3088229B2 JP 3088229 B2 JP3088229 B2 JP 3088229B2 JP 05347849 A JP05347849 A JP 05347849A JP 34784993 A JP34784993 A JP 34784993A JP 3088229 B2 JP3088229 B2 JP 3088229B2
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JP
Japan
Prior art keywords
hair
present
polyoxyalkylene
set holding
holding power
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP05347849A
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Japanese (ja)
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JPH07187966A (en
Inventor
直史 山本
Original Assignee
鐘紡株式会社
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Priority to JP05347849A priority Critical patent/JP3088229B2/en
Publication of JPH07187966A publication Critical patent/JPH07187966A/en
Application granted granted Critical
Publication of JP3088229B2 publication Critical patent/JP3088229B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Compositions Of Macromolecular Compounds (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は毛髪に対し、べたつか
ず、セット保持力に優れ、毛髪をゴワゴワした違和感の
無い自然なしなやかな髪に仕上げ、艶の良さを与える毛
髪化粧料に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic composition which imparts good luster to hair by giving the hair a non-greasy property, an excellent set holding power, a natural supple hair with no discomfort, and a good shine.

【0002】[0002]

【従来の技術】従来、毛髪化粧料には毛髪にしなやかさ
や艶を与える目的でシリコン油、エステル油、炭化水素
油などの油分を、可溶化、乳化、溶解して用いられてい
る。特にシリコン油は、表面張力が低く毛髪へのなじみ
に優れ、良い艶が得られるため、近年多用されている。
2. Description of the Related Art Conventionally, hair cosmetics have been used by solubilizing, emulsifying and dissolving oil components such as silicone oil, ester oil and hydrocarbon oil for the purpose of giving hair suppleness and luster. In particular, silicone oil has been widely used in recent years because it has a low surface tension, is excellent in conformity to hair, and has good luster.

【0003】しかしながら、シリコン油に代表される油
分では、油分のもつ限界があり多量に用いたり、消費者
が長い間使用したりすると、毛髪にきしみ感が増したり
脂ぎるといった欠点があった。
[0003] However, the oil represented by silicone oil has a limitation that the oil has a limit, and when used in a large amount or when used for a long time by a consumer, there is a disadvantage that the hair becomes more squeaky and greasy.

【0004】又、しなやかさを付与する目的でカチオン
界面活性剤も多用されているが、望ましい艶を与えるも
のではなく、多量に配合すると安全性上も好ましくない
という欠点があった。
[0004] In addition, cationic surfactants are often used for the purpose of imparting flexibility, but they do not impart desirable luster and have a drawback that if they are incorporated in a large amount, safety is not preferred.

【0005】毛髪をセットする整髪料には、種々の高分
子化合物があり、中でも高分子化合物として両性高分子
化合物が用いられている。
[0005] There are various high molecular compounds in hair styling products for setting hair, and among them, amphoteric high molecular compounds are used as high molecular compounds.

【0006】両性高分子化合物は良好なセット保持力を
示すが、艶が無く、セット後にゴワつきがある。乾燥の
際及び高湿度下ではべたつくという欠点もある。
[0006] The amphoteric polymer compound exhibits good set holding power, but has no luster and has a rough finish after setting. There is also the disadvantage of stickiness during drying and under high humidity.

【0007】さらに、カチオン化シリコンと両性高分子
を組み合わせた毛髪化粧料(特開平2−111711号
公報),及び水飴とポリオキシプロピレンブチルエーテ
ルを組み合わせた毛髪化粧料(特開平4−283508
号公報)が提案されているが、前者はセット保持力を低
下させるものであり、後者は毛髪へしなやかさを付与す
るものの、べたつきがあり、満足のゆくものではなかっ
た。
Further, hair cosmetics comprising a combination of cationized silicone and an amphoteric polymer (JP-A-2-111711) and hair cosmetics comprising a combination of starch syrup and polyoxypropylene butyl ether (JP-A-4-283508)
Japanese Patent Application Laid-Open No. H10-27983 has been proposed, but the former reduces the set holding power, and the latter imparts suppleness to the hair, but is sticky and unsatisfactory.

【0008】[0008]

【発明が解決しようとする課題及び課題を解決するため
の手段】本発明者は、このような状況に鑑み、毛髪に対
し、べたつかず、セット保持力に優れ、毛髪をゴワゴワ
した違和感の無い自然でしなやかな髪に仕上げ、艶の良
さを与える毛髪化粧料を提供することを目的として鋭意
検討の結果、ポリオキシアルキレン変性シリコンと両性
高分子と水飴とを配合することを特徴とする毛髪化粧料
がこれらのすべてを満足することを見出し、本発明を完
成した。すなわち、本発明の請求項1は、ポリオキシア
ルキレン変性シリコンと両性高分子と水飴とを配合する
ことを特徴とする毛髪化粧料である。また、本発明の請
求項2は、請求項1において、ポリオキシアルキレン変
性シリコン(A)+両性高分子(B)と水飴(C)との
重量比〔(A)+(B)〕/(C)〕が0.0075〜
200であることを特徴とする毛髪化粧料である。
SUMMARY OF THE INVENTION In view of such circumstances, the inventor of the present invention has made the hair non-sticky, has excellent set holding power, and has a natural feeling of uncomfortable hair. As a result of intensive investigations with the aim of providing a hair cosmetic that gives a supple hair and gives good gloss, a hair cosmetic characterized by blending polyoxyalkylene-modified silicone, amphoteric polymer and starch syrup Found that all these were satisfied, and completed the present invention. That is, claim 1 of the present invention is a hair cosmetic comprising a mixture of polyoxyalkylene-modified silicone, amphoteric polymer and starch syrup. Further, claim 2 of the present invention is the method according to claim 1, wherein the weight ratio of the polyoxyalkylene-modified silicon (A) + amphoteric polymer (B) and starch syrup (C) [(A) + (B)] / ( C)] is 0.0075 or more
It is a hair cosmetic characterized by being 200.

【0009】本発明で用いられるポリオキシアルキレン
変性シリコンは、ポリオキシエチレン変性シリコン、ポ
リオキシプロピレン変性シリコン、ポリオキシエチレン
−ポリオキシプロピレン変性シリコンであり、これらの
ポリオキシアルキレン鎖がシリコン鎖にペンダント状に
付いているもの、ジメチルシロキサンとポリオキシアル
キレン鎖が直鎖状に交互に重合しているもの、さらにこ
れらペンダント状と直鎖状の混合系のものが挙げられ
る。ポリオキシアルキレン変性シリコンの中で、ポリオ
キシエチレン−ポリオキシプロピレン変性シリコンの方
が、ポリオキシエチレン変性シリコンだけのものよりも
艶の良さ、セット保持力の低下が少ないという点でやや
優れている。
The polyoxyalkylene-modified silicon used in the present invention is polyoxyethylene-modified silicon, polyoxypropylene-modified silicon, or polyoxyethylene-polyoxypropylene-modified silicon, and these polyoxyalkylene chains are pendant to the silicon chains. And dimethylsiloxane and polyoxyalkylene chains alternately polymerized in a linear manner, and further, pendant and linear mixed systems of these. Among the polyoxyalkylene-modified silicons, the polyoxyethylene-polyoxypropylene-modified silicon is slightly better than the polyoxyethylene-modified silicon alone in terms of glossiness and less reduction in set holding power. .

【0010】本発明で用いられる両性高分子化合物とし
てアクリル系両性樹脂が挙げられ、具体例としてN−メ
タクリロイルエチルN,N−ジメチルアンモニウム・α
−N−メチルカルボキシベタイン・メタクリル酸ブチル
共重合体及びオクチルアクリルアミドブチルアミノエチ
ルメタクリレート(メタ)アクリル酸/メタアクリル酸
エステル共重合体等が挙げられ、前者はユカフォーマー
AM−75W(三菱油化株式会社製)として、後者はA
mphomer(National Starch 社製)として購入
することができる。
The amphoteric polymer compound used in the present invention includes an acrylic amphoteric resin. Specific examples include N-methacryloylethyl N, N-dimethylammonium.α
-N-methylcarboxybetaine / butyl methacrylate copolymer and octylacrylamidobutylaminoethyl methacrylate (meth) acrylic acid / methacrylic acid ester copolymer; the former is Yuka Former AM-75W (Mitsubishi Yuka Corporation) The latter is A
It can be purchased as mphomer (manufactured by National Starch).

【0011】本発明で用いられる水飴は、デンプンを希
酸(鉱酸又はシュウ酸)又は酵素(アミラーゼ)で加水
分解して作られる。
The starch syrup used in the present invention is produced by hydrolyzing starch with a dilute acid (mineral acid or oxalic acid) or an enzyme (amylase).

【0012】本発明のポリオキシアルキレン変性シリコ
ンと両性高分子との総配合量(A)+(B)は、毛髪化
粧料全量中、1〜20重量%が好ましく、更に好ましく
は2〜6重量%である。2重量%未満及び6重量%を超
える場合、本発明を満足するものではあるが、セット保
持力及び仕上がりの点で必ずしも十分ではない。
The total amount (A) + (B) of the polyoxyalkylene-modified silicone of the present invention and the amphoteric polymer is preferably 1 to 20% by weight, more preferably 2 to 6% by weight, based on the total amount of the hair cosmetic. %. When the content is less than 2% by weight or more than 6% by weight, the present invention is satisfied, but is not always sufficient in terms of set holding power and finish.

【0013】本発明のポリオキシアルキレン変性シリコ
ン(A)+両性高分子(B)と水飴(C)との重量比
〔(A)+(B)〕/(C)は0.0075〜200の
範囲が好ましく、さらに好ましくは0.02〜50の範
囲である。0.0075未満及び200を超えるときは
本発明を満足するものではあるが、セット保持力及び仕
上がりの点で必ずしも十分ではない。
The weight ratio [(A) + (B)] / (C) of the polyoxyalkylene-modified silicone (A) + amphoteric polymer (B) and starch syrup (C) of the present invention is 0.0075 to 200. It is preferably in the range, more preferably in the range of 0.02 to 50. When the ratio is less than 0.0075 or more than 200, the present invention is satisfied, but the set holding power and the finish are not always sufficient.

【0014】本発明の毛髪化粧料には上記の必須構成成
分に加えて、目的に応じて本発明の効果を損わない範囲
で、アルコール類、油剤、界面活性剤、着色剤、増粘
剤、金属封鎖剤、紫外線吸収剤、酸化防止剤、防腐剤、
清涼剤、香料、pH調整剤、植物抽出エキス、損傷毛修
復剤、生薬、その他の添加剤などを適宜配合しても良
い。
In the hair cosmetic composition of the present invention, in addition to the above-mentioned essential components, alcohols, oils, surfactants, coloring agents, thickeners, as long as the effects of the present invention are not impaired depending on the purpose. , Sequestering agents, ultraviolet absorbers, antioxidants, preservatives,
A cooling agent, a fragrance, a pH adjuster, a plant extract, a damaged hair repair agent, a crude drug, other additives, and the like may be appropriately compounded.

【0015】[0015]

【実施例】以下に実施例、比較例を挙げて本発明を説明
する。本発明は、これらにより限定されるものではな
い。
The present invention will be described below with reference to examples and comparative examples. The present invention is not limited by these.

【0016】実施例1〜8、比較例1〜4においてセッ
トローションを調製し、毛髪化粧料のセット保持力及び
実用テストの評価を以下の通り実施した。なお、以下の
表に示す組成物の配合量は、それぞれ重量%で示す。
Set lotions were prepared in Examples 1 to 8 and Comparative Examples 1 to 4, and the set retention of hair cosmetics and the evaluation of practical tests were evaluated as follows. In addition, the compounding quantity of the composition shown in the following tables is each shown by weight%.

【0017】(1)セット保持力 長さ15cm、重さ1.0gの毛束に毛髪化粧料の試料
0.5gを均等に塗布し、直径2cmのロッドに巻き、
45℃の高温室内に6時間放置して完全に乾燥させた。
乾燥後、ロッドをはずして、毛束のみかけの長さ(L)
を測定し、次いで温度25℃、湿度90%の恒温恒湿室
に毛束を吊し、30分後に取り出し、再び毛束のみかけ
の長さ(L0 )を測定した。
(1) Set holding power A hair cosmetic sample having a length of 15 cm and a weight of 1.0 g is uniformly coated with 0.5 g of a hair cosmetic sample and wound around a 2 cm diameter rod.
It was left in a high-temperature room at 45 ° C. for 6 hours to be completely dried.
After drying, remove the rod and the apparent length of the hair bundle (L)
Then, the hair bundle was hung in a thermo-hygrostat at a temperature of 25 ° C. and a humidity of 90%, taken out after 30 minutes, and the apparent length (L 0 ) of the hair bundle was measured again.

【0018】セット保持力を次式にて求めた。 セット保持力(%)=〔(15−L0 )÷(15−
L)〕×100 したがって、この値が100に近いほどセット保持力が
強いことを示す。
The set holding force was determined by the following equation. Set holding force (%) = [(15−L 0 ) ÷ (15−
L)] × 100 Therefore, the closer this value is to 100, the stronger the set holding force.

【0019】評価基準は、以下の通りである。 ◎:非常に良好 セット保持力80%以上 ○:良好 セット保持力50%以上、80%未満 △:やや悪い セット保持力30%以上、50%未満 ×:悪い セット保持力30%未満The evaluation criteria are as follows. ◎: Very good set holding power of 80% or more ○: Good Set holding power of 50% or more and less than 80% Δ: Slightly bad Set holding power of 30% or more and less than 50% ×: Poor set holding power of less than 30%

【0020】(2)実用テスト 20名の被験者によって、毛髪化粧料の試料を使用し、
整髪を実施した。その後、被験者本人が、べたつきの無
さ、しなやかさ、艶について官能評価した。
(2) Practical test A sample of hair cosmetics was used by 20 subjects,
Hairdressing was performed. Thereafter, the subject himself performed a sensory evaluation of non-stickiness, suppleness, and gloss.

【0021】評価基準は、以下の通りである。 ◎:非常に良好 ○:良好 △:やや悪い ×:悪いThe evaluation criteria are as follows. ◎: Very good ○: Good △: Somewhat bad ×: Bad

【0022】実施例、比較例で使用したポリオキシアル
キレン変性シリコンは、SILWET L−7002、
SILWET L−7604(日本ユニカ−株式会社)
を使用した。
The polyoxyalkylene-modified silicon used in Examples and Comparative Examples was SILWET L-7002,
SILWET L-7604 (Nihon Unicar Co., Ltd.)
It was used.

【0023】又、使用した両性高分子化合物は、ユカフ
ォーマーAM−75W(三菱油化株式会社)を使用し
た。評価結果を表1に示す。
The amphoteric polymer compound used was Yuka Former AM-75W (Mitsubishi Yuka Co., Ltd.). Table 1 shows the evaluation results.

【0024】[0024]

【表1】 [Table 1]

【0025】表1より明らかなように、本発明の成分を
用いた実施例1〜8の毛髪化粧料はいずれも優れた性能
を示していた。
As is clear from Table 1, the hair cosmetics of Examples 1 to 8 using the components of the present invention exhibited excellent performance.

【0026】一方、必須成分のいずれかを欠いた比較例
1〜4では、セット力あるいは艶、しなやかさ、べとつ
きの無さの面で劣っており、本発明の目的を達成できな
かった。
On the other hand, Comparative Examples 1 to 4 lacking any of the essential components were inferior in terms of setting power, gloss, suppleness and non-stickiness, and could not achieve the object of the present invention.

【0027】実施例9 泡沫状化粧料 下記組成を調製して得た原液90%に対してLPG10
%を加え、泡沫状化粧料を調製した。
Example 9 Foamed Cosmetic LPG 10 based on 90% of a stock solution obtained by preparing the following composition
% To prepare a foamy cosmetic.

【0028】 (原液組成) (1)ポリオキシアルキレン変性シリコン(20E.O./15P.O.) 0.3(%) (SILWETL−7002 日本ユニカー株式会社) (2)両性高分子 2.0 (ユカフォーマーAM−75W 三菱油化株式会社) (3)水飴 1.0 (4)ポリオキシエチレン硬化ヒマシ油(60E.O.) 1.0 (5)ジプロピレングリコール 2.0 (6)エタノール 20.0 (7)防腐剤 適量 (8)精製水 残部 この泡沫状化粧料を使用すると、毛髪に対し、べたつか
ず、セット保持力に優れ、毛髪をゴワゴワした違和感の
無い自然なしなやかな髪に仕上げ、艶の良さが得られ
た。
(Composition of stock solution) (1) Polyoxyalkylene-modified silicon (20EO / 15PO) 0.3 (%) (SILWETL-7002 Nippon Unicar Co., Ltd.) (2) Amphoteric polymer 2.0 (Yuka Former AM-75W Mitsubishi Yuka Co., Ltd.) (3) Mizuame 1.0 (4) Polyoxyethylene hydrogenated castor oil (60E.O.) 1.0 (5) Dipropylene glycol 2.0 (6) Ethanol 20 0.0 (7) Preservatives Appropriate amount (8) Purified water Remaining When this foamy cosmetic is used, the hair is non-greasy, has excellent set holding power, and gives a natural and supple hair that is smooth and does not feel uncomfortable. , Good gloss was obtained.

【0029】実施例10 ヘアースプレー 下記組成を調製して得た原液60%に対してジメチルエ
ーテル40%を加え、ヘアースプレーを調製した。
Example 10 Hair spray A hair spray was prepared by adding 40% of dimethyl ether to 60% of a stock solution obtained by preparing the following composition.

【0030】 (原液組成) (1)ポリオキシアルキレン変性シリコン(20E.O./15P.O.) 1.0(%) (SILWETL−7002 日本ユニカー株式会社) (2)両性高分子 5.0 (ユカフォーマーAM−75W 三菱油化株式会社) (3)水飴 0.3 (4)グリセリン 1.0 (5)エタノール 40.0 (6)紫外線吸収剤 適量 (7)精製水 残部(Composition of stock solution) (1) Polyoxyalkylene-modified silicon (20EO / 15PO) 1.0 (%) (SILWETL-7002 Nippon Unicar Co., Ltd.) (2) Amphoteric polymer 5.0 (Yuka Former AM-75W Mitsubishi Yuka Co., Ltd.) (3) Ginger syrup 0.3 (4) Glycerin 1.0 (5) Ethanol 40.0 (6) Appropriate amount of ultraviolet absorber (7) Purified water balance

【0031】このヘアースプレーを使用すると、毛髪に
対し、べたつかず、セット保持力に優れ、毛髪をゴワゴ
ワした違和感の無い自然でしなやかな髪に仕上げ、艶の
良さが得られた。
When this hair spray was used, the hair was non-greasy, had excellent set holding power, was finished with a natural and supple hair with no discomfort, and had good luster.

【0032】[0032]

【発明の効果】以上記載のごとく、本発明は、毛髪に対
し、べたつかず、セット保持力に優れ、毛髪をゴワゴワ
した違和感の無い自然でしなやかな髪に仕上げ、艶の良
さを与える毛髪化粧料を提供することができる。
Industrial Applicability As described above, the present invention provides a hair cosmetic which gives a non-greasy, excellent set holding power to hair, gives natural and supple hair with a feeling of unpleasantness, and gives a good luster to the hair. Can be provided.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) A61K 7/00 - 7/50 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7/ 00-7/50

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 ポリオキシアルキレン変性シリコンと両
性高分子と水飴とを配合することを特徴とする毛髪化粧
料。
1. A hair cosmetic comprising a polyoxyalkylene-modified silicone, an amphoteric polymer and starch syrup.
【請求項2】 ポリオキシアルキレン変性シリコン
(A)+両性高分子(B)と、水飴(C)との重量比
〔(A)+(B)〕/(C)が、0.0075〜200
であることを特徴とする請求項1記載の毛髪化粧料。
2. The weight ratio [(A) + (B)] / (C) of polyoxyalkylene-modified silicone (A) + amphoteric polymer (B) and starch syrup (C) is 0.0075 to 200.
The hair cosmetic according to claim 1, wherein
JP05347849A 1993-12-24 1993-12-24 Hair cosmetics Expired - Lifetime JP3088229B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP05347849A JP3088229B2 (en) 1993-12-24 1993-12-24 Hair cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP05347849A JP3088229B2 (en) 1993-12-24 1993-12-24 Hair cosmetics

Publications (2)

Publication Number Publication Date
JPH07187966A JPH07187966A (en) 1995-07-25
JP3088229B2 true JP3088229B2 (en) 2000-09-18

Family

ID=18393021

Family Applications (1)

Application Number Title Priority Date Filing Date
JP05347849A Expired - Lifetime JP3088229B2 (en) 1993-12-24 1993-12-24 Hair cosmetics

Country Status (1)

Country Link
JP (1) JP3088229B2 (en)

Also Published As

Publication number Publication date
JPH07187966A (en) 1995-07-25

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