JP3048314B2 - Printing method of silk fabric by sublimation heat transfer - Google Patents
Printing method of silk fabric by sublimation heat transferInfo
- Publication number
- JP3048314B2 JP3048314B2 JP7077035A JP7703595A JP3048314B2 JP 3048314 B2 JP3048314 B2 JP 3048314B2 JP 7077035 A JP7077035 A JP 7077035A JP 7703595 A JP7703595 A JP 7703595A JP 3048314 B2 JP3048314 B2 JP 3048314B2
- Authority
- JP
- Japan
- Prior art keywords
- silk fabric
- heat transfer
- resin
- sublimation heat
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Printing Methods (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、昇華性染料で印刷した
紙（転写紙）を用いて、熱転写によって画像を絹織物に
プリント加工する方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of printing an image on silk fabric by thermal transfer using paper (transfer paper) printed with a sublimable dye.
【０００２】[0002]
【従来の技術】昇華性染料を含むインクで画像を印刷し
た転写紙を重ねて加熱することにより、紙上の画像を繊
維に転写プリントする方法は周知である。本法は、スク
リーン版等の捺染型を必要とせず、容易にプリント画像
が得られる点に特長がある。2. Description of the Related Art It is well known that an image on paper is transferred and printed on a fiber by superposing and heating transfer paper on which an image is printed with an ink containing a sublimable dye. This method has a feature in that a printed image can be easily obtained without requiring a printing die such as a screen plate.
【０００３】本法の繊維分野における用途は、発色性に
限界があるためにポリエステル繊維のプリント加工に限
られている。しかし、工程が簡易で用水も不要なため、
従来からこれをポリエステル以外の繊維に応用すること
が試しみられている。The application of this method in the field of fibers is limited to the printing of polyester fibers due to the limited color development. However, since the process is simple and no water is required,
There have been attempts to apply this to fibers other than polyester.
【０００４】絹織物のプリント加工に応用するものとし
ては、合成樹脂やグラフト重合によって絹を事前に加工
する方法が知られている。しかし、これらの方法で得ら
れる染色物は、前者で風合いの低下、発色の不鮮明さ、
後者では染色斑の発生、染色堅牢度の低下などの問題が
ある。更に後者では、加工設備が新規に必要であること
などの困難を伴う。また、生地表面を樹脂フィルムで覆
い、これに転写する方法も知られているが、風合いが重
視される絹織物に用いることは困難である。このため、
これらの技術は何れも絹織物のプリント加工用には普及
してないのが現況である。[0004] As a method applied to printing of silk fabric, a method of processing silk in advance by a synthetic resin or graft polymerization is known. However, the dyed products obtained by these methods have the following disadvantages: reduced texture, unclear color development,
The latter has problems such as the occurrence of stained spots and a decrease in color fastness. Further, the latter involves difficulties such as the necessity of a new processing facility. Further, a method of covering the cloth surface with a resin film and transferring the cloth to the resin film is also known, but it is difficult to use the cloth for a silk fabric where texture is important. For this reason,
At present, none of these techniques is widely used for printing silk fabrics.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、このような
所与の問題を解決して、かつ同時に撥水撥油性を付与し
た絹織物のプリント加工物を提供することを目的とす
る。SUMMARY OF THE INVENTION An object of the present invention is to solve such a given problem and at the same time to provide a print of silk fabric having water and oil repellency.
【０００６】[0006]
【課題を解決するための手段】本発明は上記の如き課題
を解決するために開発したものであって、フェノールー
（エチレングリコール）ｎ−グリシジルエーテル成分か
らなる水溶性エポキシ化合物にメラミン樹脂とフッ素樹
脂エマルジョンとを配合してなる樹脂液を設け、該樹脂
液を絹織物に含浸した後に昇華熱転写により転写紙から
画像をプリント加工することを特徴とする昇華熱転写に
よる絹織物のプリント加工方法であり、その目的を達成
するために絹織物に昇華熱転写のプリントを可能にする
性能を付与し、かつその昇華熱転写を行なう前に前記配
合からなる樹脂液を絹織物に含浸させてから乾燥するこ
とによって得られる。DISCLOSURE OF THE INVENTION The present invention has been developed to solve the above-mentioned problems, and comprises a water-soluble epoxy compound comprising a phenol- (ethylene glycol) n-glycidyl ether component, a melamine resin and a fluororesin. A method of printing a silk fabric by sublimation heat transfer, which comprises providing a resin solution prepared by blending an emulsion with the emulsion and impregnating the silk solution with the resin solution and then printing an image from a transfer paper by sublimation heat transfer. In order to achieve the object, a silk fabric is provided with a performance capable of performing sublimation heat transfer printing, and before the sublimation heat transfer is performed, the silk fabric is impregnated with a resin solution having the above-described composition and then dried. Can be
【０００７】本発明で使用される樹脂液は、フェノール
ー（エチレングリコール）ｎ−グリシジルエーテル成分
からなる水溶性エポキシ化合物にメラミン樹脂とフッ素
樹脂エマルジョンとを配合してなるものが用いられてい
る。As the resin liquid used in the present invention, a resin liquid obtained by mixing a melamine resin and a fluororesin emulsion with a water-soluble epoxy compound comprising a phenol- (ethylene glycol) n-glycidyl ether component is used.
【０００８】水溶性エポキシ化合物成分としては、フェ
ノール誘導体で絹と化学的に反応する性質のある化１に
示す、フェノール−（エチレンオキサイド）ｎ−グリシ
ジルエーテルが適している。他のエポキシ化合物では、
転写した絹織物の染料濃度や色相における鮮明さが充分
ではない。また多官能性のエポキシ樹脂では、織物が硬
くなって風合いが低下するためである。As a water-soluble epoxy compound component, phenol- ( ethylene oxide ) n-glycidyl ether shown in Chemical formula 1 having a property of chemically reacting with silk with a phenol derivative is suitable. In other epoxy compounds,
The sharpness in the dye concentration and hue of the transferred silk fabric is not sufficient. In addition, in the case of a polyfunctional epoxy resin, the fabric becomes hard and the texture is reduced.
【０００９】[0009]
【化１】 Embedded image
【００１０】化１の化合物フェノール−（エチレンオキ
サイド）ｎ−グリシジンエーテルは、エチレンオキサイ
ド部分が付加モル数ｎの異なるものが可能である。本発
明は化合物の付加モル数を限定するものではなく、ｎ＝
５程度のものであれば何れも用途に適するものである。The compound of the formula 1 phenol- ( ethylene oxide
Side ) n-glycidin ether is ethylene oxide
The moieties having different addition mole numbers n are possible. The present invention does not limit the number of added moles of the compound.
Any of about 5 is suitable for use.
【００１１】メラミン樹脂及びフッ素樹脂エマルジョン
には、繊維の樹脂加工に通常使用されているものを用い
ることができる。メラミン樹脂の反応触媒としては、樹
脂エマルジョンを安定した状態に保てるアミン系触媒を
添加することが望ましい。As the melamine resin and the fluorine resin emulsion, those usually used for resin processing of fibers can be used. As a reaction catalyst for the melamine resin, it is desirable to add an amine catalyst that can keep the resin emulsion in a stable state.
【００１２】昇華熱転写した画像の色濃度を高めるため
には、少量のポリアルキレンオキシド化合物（例えばポ
リプロピレングリコールやポリエチレングリコールな
ど）を助剤として樹脂液に添加することが効果的であ
る。特にポリエチレングリコールは、熱転写時の絹の黄
変を低減する効果が認められる。In order to increase the color density of an image transferred by sublimation heat transfer, it is effective to add a small amount of a polyalkylene oxide compound (for example, polypropylene glycol or polyethylene glycol) to a resin solution as an auxiliary. Particularly, polyethylene glycol has an effect of reducing yellowing of silk during thermal transfer.
【００１３】樹脂液を絹織物に含浸する方法は、浸漬し
た後にマングルによって絞るのが一般的であるが、スプ
レーや泡を利用した加工も可能である。含浸したのちの
乾燥は、１００°Ｃ、２〜３分程度の条件でよい。The method of impregnating a silk fabric with a resin solution is generally to squeeze with a mangle after immersion, but processing using spray or foam is also possible. Drying after impregnation may be performed at 100 ° C. for about 2 to 3 minutes.
【００１４】樹脂液を含浸して乾燥した絹織物を、転写
紙と重ねて１９０°Ｃ、７０秒間の熱処理を行う。転写
紙には、市販の通常のポリエステル繊維用のものを利用
することができる。熱処理によって、転写紙上の昇華性
染料が絹織物に移行し、画像が転写されるとともに、同
時に樹脂の反応によって画像が定着される。１９０°Ｃ
以上の温度条件では、画像の転写は促進されるが絹の黄
変が急速に進むために適当とはいえない。The silk fabric impregnated with the resin solution and dried is superposed on the transfer paper and heat-treated at 190 ° C. for 70 seconds. As the transfer paper, commercially available paper for ordinary polyester fibers can be used. By the heat treatment, the sublimable dye on the transfer paper is transferred to the silk fabric, and the image is transferred, and at the same time, the image is fixed by the reaction of the resin. 190 ° C
Under the above temperature conditions, the transfer of the image is accelerated, but the yellowing of the silk proceeds rapidly, which is not appropriate.
【００１５】熱処理した絹織物は、界面活性剤溶液によ
るソーピング処理で未定着の樹脂及び染料を除去して、
乾燥することで繊維製品として利用することができる。The heat-treated silk fabric is subjected to a soaping treatment with a surfactant solution to remove unfixed resin and dye,
It can be used as a fiber product by drying.
【００１６】[0016]
【実施例】下記の組成に調製した樹脂液に絹織物（羽二
重）を浸漬したのち、織物重量に等しい液量までマング
ルで絞り、乾燥してから１００°Ｃ、３分の熱処理を行
った。 フェノール−（エチレンオキサイド）５−グリシジルエーテル １０部 Ｄｅｎａｃｏｌ ＥＸ−１４５、ナガセ化成工業（株） 変性メラミン樹脂 ４部 Ｕｎｉｋａ ｒｅｓｉｎ Ｆ−３８、ユニオン化学工業（株） フッ素樹脂エマルジョン ３部 Ｓｕｍｉｆｌｕｏｉｌ ＥＭ−２０１、住友化学工業（株） アミン系反応触媒 ２部 Ｕｎｉｋａ ｃａｔａｌｙｓｔ ３−Ｐ、ユニオン化学工業（株） ポリエチレングリコール（ＰＥＧ ３００） ２部 試薬１級、純正化学（株） 全量を水で１００に調整する。EXAMPLE A silk fabric (Habuta) was immersed in a resin solution having the following composition, squeezed with a mangle to a liquid amount equal to the weight of the fabric, dried, and then heat-treated at 100 ° C. for 3 minutes. Was. Phenol- (ethylene oxide) 5-glycidyl ether 10 parts Denacol EX-145, Nagase Kasei Kogyo Co., Ltd. Modified melamine resin 4 parts Unika resin F-38, Union Chemical Industry Co., Ltd. Fluororesin emulsion 3 parts Sumfluoil EM-201, Sumitomo Chemical Co., Ltd. Amine-based reaction catalyst 2 parts UNIKA CATALYST 3-P, Union Chemical Co., Ltd. Polyethylene glycol (PEG 300) 2 parts Reagent 1st grade, Junsei Chemical Co., Ltd. The total amount is adjusted to 100 with water.
【００１７】樹脂液を含浸した絹織物に、三原色及び黒
色にベタ印刷した転写紙を用いて、熱処理機で１９０°
Ｃ、７０秒間の加熱処理をすることにより転写プリント
をおこなった。転写した絹織物は、非イオン性界面活性
剤０．１％溶液で５０°Ｃ、１０分間のソーピング処理
を行ったのち、乾燥した。The silk cloth impregnated with the resin solution is transferred to a heat treatment machine at 190 ° C. using transfer paper solid-printed in three primary colors and black.
C, transfer printing was performed by performing a heat treatment for 70 seconds. The transferred silk fabric was subjected to a soaping treatment at 50 ° C. for 10 minutes with a 0.1% solution of a nonionic surfactant, and then dried.
【００１８】ポリエステル繊維を用いて同様の転写プリ
ントを行い、絹織物と色相や色濃度を比較したところ、
共に全く同等であった。また、絹織物の感触、風合いも
極めてソフトで、同時に水及び油によって汚れない性質
が得られた。染色堅牢度も表１に示したように良好であ
り、特にドライクリーニングに対して優れている。The same transfer printing was performed using polyester fiber, and the hue and color density were compared with those of silk fabric.
Both were completely equivalent. In addition, the feel and feel of the silk fabric were extremely soft, and at the same time, the property of not being stained by water and oil was obtained. The color fastness is also good as shown in Table 1, and is particularly excellent for dry cleaning.
【００１９】[0019]
【表１】 [Table 1]
【００２０】[0020]
【発明の効果】本発明による絹織物のプリント加工物
は、風合いや染色堅牢度が良好であり、水や油などの汚
れが付着し難い性質があるため、ネクタイ、ブラウス、
コート地等の洋装品の他、和装着物への用途にも適する
ものである。The printed material of the silk fabric according to the present invention has a good texture and color fastness, and has a property that dirt such as water or oil does not easily adhere.
It is suitable for use not only for Western-fitted items such as coated fabrics, but also for Japanese-style items.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭53−35078（ＪＰ，Ａ) 特開 平３−113083（ＪＰ，Ａ) 特開 平４−82980（ＪＰ，Ａ) 特開 平６−346384（ＪＰ，Ａ) 社団法人高分子学会編、「高分子工学 講座12 化学繊維の染色と加工」、株式 会社地人書館、昭和42年、第417頁 (58)調査した分野(Int.Cl.7，ＤＢ名) D06P 1/52 - 1/58 D06P 3/24 D06P 5/00 114 - 106 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-53-35078 (JP, A) JP-A-3-113083 (JP, A) JP-A-4-82980 (JP, A) JP-A-6-82980 346384 (JP, A) The Society of Polymer Science, edited by “Polymer Engineering Course 12: Dyeing and Processing of Chemical Fiber”, Jinjinshokan Co., Ltd., Showa 42, p. 417 (58) Fields surveyed (Int. . 7, DB name) D06P 1/52 - 1/58 D06P 3/24 D06P 5/00 114 - 106
Claims (1)
−グリシジルエーテル成分からなる水溶性エポキシ化合
物にメラミン樹脂とフッ素樹脂エマルジョンとを配合し
てなる樹脂液を設け、該樹脂液を絹織物に含浸した後に
昇華熱転写により転写紙から画像をプリント加工するこ
とを特徴とする昇華熱転写による絹織物のプリント加工
方法。1. Phenol- (ethylene glycol) n
-Providing a resin solution prepared by mixing a melamine resin and a fluororesin emulsion with a water-soluble epoxy compound comprising a glycidyl ether component, impregnating the resin solution into silk fabric, and then printing an image from transfer paper by sublimation heat transfer. A method of printing silk fabric by sublimation heat transfer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7077035A JP3048314B2 (en) | 1995-02-24 | 1995-02-24 | Printing method of silk fabric by sublimation heat transfer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7077035A JP3048314B2 (en) | 1995-02-24 | 1995-02-24 | Printing method of silk fabric by sublimation heat transfer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08232177A JPH08232177A (en) | 1996-09-10 |
| JP3048314B2 true JP3048314B2 (en) | 2000-06-05 |
Family
ID=13622512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7077035A Expired - Fee Related JP3048314B2 (en) | 1995-02-24 | 1995-02-24 | Printing method of silk fabric by sublimation heat transfer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3048314B2 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5335078A (en) * | 1976-09-13 | 1978-04-01 | Toppan Printing Co Ltd | Printing method |
| JPH062993B2 (en) * | 1989-09-21 | 1994-01-12 | 鐘紡株式会社 | Silk dyeing method |
| JPH0482980A (en) * | 1990-07-24 | 1992-03-16 | Kanebo Ltd | Production of fiber structure of multicolor dyed front and back surfaces |
| JPH06346384A (en) * | 1993-05-31 | 1994-12-20 | Mishina Orimono Kk | Method for dyeing using water repellent treated yarn |
-
1995
- 1995-02-24 JP JP7077035A patent/JP3048314B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| 社団法人高分子学会編、「高分子工学講座１２ 化学繊維の染色と加工」、株式会社地人書館、昭和４２年、第４１７頁 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08232177A (en) | 1996-09-10 |
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