JP3044516B2 - Metal plate molding method - Google Patents
Metal plate molding methodInfo
- Publication number
- JP3044516B2 JP3044516B2 JP5140831A JP14083193A JP3044516B2 JP 3044516 B2 JP3044516 B2 JP 3044516B2 JP 5140831 A JP5140831 A JP 5140831A JP 14083193 A JP14083193 A JP 14083193A JP 3044516 B2 JP3044516 B2 JP 3044516B2
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- metal plate
- film
- mold
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は自動車、エレクトロニク
ス製品の金属装飾板等を成型するのに使用して好適な薄
い金属板を成型する金属板の成型方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of forming a thin metal plate suitable for forming a metal decorative plate of an automobile or an electronic product.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】一般
に、絞り加工による自動車、エレクトロニクス製品の金
属装飾板を製造するのに図3に示す如く行っていた。2. Description of the Related Art Generally, as shown in FIG. 3, a metal decorative plate for automobiles and electronic products is manufactured by drawing.
【0003】図3Aにおいて、1は絞り加工しようとす
る厚さが例えば0.1mmのステンレススチールより成
る金属板を示し、先ず図3Aに示す如くこの金属板1の
一方の面に例えば厚さ25μmのポリエチレンテレフタ
レート(東レ社製S10)の剥離フィルム2の一面上に
エチレン酢酸ビニール共重合体系接着剤3を被着した接
着剤シートを被着すると共にこの金属板1の他方の面に
プロテクトフィルムとして粘着剤付可撓性フィルム(セ
キスイ化学社製#623E厚さ75μm)4を積層す
る。In FIG. 3A, reference numeral 1 denotes a metal plate made of stainless steel having a thickness of, for example, 0.1 mm to be drawn. First, as shown in FIG. 3A, one surface of the metal plate 1 has a thickness of, for example, 25 μm. An adhesive sheet having an ethylene-vinyl acetate copolymer adhesive 3 is adhered on one surface of a release film 2 of polyethylene terephthalate (S10 manufactured by Toray Industries, Inc.) and a protective film is formed on the other surface of the metal plate 1. A flexible film with an adhesive (# 623E manufactured by Sekisui Chemical Co., Ltd., thickness 75 μm) 4 is laminated.
【0004】次に図3Bに示す如く雄型5a及び雌型5
bより成る金型により外形抜き及び絞り加工を同時に行
う。[0004] Next, as shown in FIG.
The outer shape punching and drawing are performed at the same time using the mold composed of b.
【0005】その後図3Cに示す如く剥離フィルム2を
剥離し、この金属板1の接着剤3側に図3Dに示す如く
例えばABS樹脂の成型体6をホットプレス機にて接着
し、プロテクトフィルム4を剥離した。Thereafter, as shown in FIG. 3C, the release film 2 is peeled off, and a molded body 6 of, for example, an ABS resin is adhered to the adhesive 3 side of the metal plate 1 by a hot press as shown in FIG. Was peeled off.
【0006】斯る図3の製造方法においては剥離フィル
ム2を付着したまま金型5a,5bにより外形抜き及び
絞り加工するので、この金属装飾板のエッジがシャープ
に出ない不都合があると共にこの剥離フィルム2に発生
したしわが金属装飾板の表面に出る不都合があった。In the manufacturing method shown in FIG. 3, since the outer shape is drawn and drawn by the dies 5a and 5b while the release film 2 is adhered, there is a disadvantage that the edge of the metal decorative plate does not come out sharply and this release is performed. There was a problem that wrinkles generated in the film 2 appeared on the surface of the metal decorative plate.
【0007】この為図3の製造方法において金属板1に
接着剤シートを被着した後に、この剥離フィルム2を剥
離し、その後、金型5a,5bにより外形抜き及び絞り
加工を同時に行うことが考えられるが、この場合接着剤
3の接着面は平滑であり、金型5aへの付着があり、連
続打抜き加工ができない不都合がある。For this reason, in the manufacturing method of FIG. 3, after the adhesive sheet is adhered to the metal plate 1, the release film 2 is peeled off, and then the outer shape punching and drawing are performed simultaneously by the dies 5a and 5b. However, in this case, the bonding surface of the adhesive 3 is smooth and adheres to the mold 5a, so that there is a disadvantage that continuous punching cannot be performed.
【0008】またこの絞りが大きい場合には、この絞っ
た部分の金属板1の面に縞状の模様が発生し、外観不良
となる不都合がある。If the aperture is large, a striped pattern is generated on the surface of the metal plate 1 at the narrowed portion, and there is a disadvantage that the appearance is poor.
【0009】そこで、更にこの接着剤3として金型5a
に対し滑り性の良い、硬い接着剤を使用することが考え
られるが、この滑り性の良い硬い接着剤はポリオレフィ
ンのようなプラスチックには接着しにくい不都合があ
り、またこの接着物に対し低温における衝撃性に接着力
が劣る不都合があった。Therefore, a mold 5a is further used as the adhesive 3.
It is conceivable to use a hard adhesive with good slipperiness, but this hard adhesive with good slipperiness has a disadvantage that it is difficult to adhere to plastics such as polyolefin, and this adhesive has a disadvantage at low temperatures. There was a disadvantage that the adhesive strength was inferior to the impact strength.
【0010】本発明は斯る点に鑑み、上述不都合を改善
するようにした金属板の成型方法及び接着剤シートを提
案することを目的とする。[0010] In view of the above, an object of the present invention is to propose a metal plate molding method and an adhesive sheet which are designed to solve the above-mentioned disadvantages.
【0011】[0011]
【課題を解決するための手段】本発明金属板の成型方法
は例えば図2に示す如く、マット処理したフィルム2a
の面に接着剤3を被着した接着剤シートを金属板1の一
方の面に被着し、この金属板1の他方の面に粘着剤付可
撓性フィルム4を積層する工程(図2A)と、このマッ
ト処理したフィルム2aを剥離する工程(図2B)と、
この金属板1の接着剤3面が一方の金型5aに当たり、
この金属板1の可撓性フィルム4面が他方の金型5bに
当たるように金型内に装着し、絞り加工と同時に外形抜
きを工程とを有するものである。The method of molding a metal plate according to the present invention is, for example, as shown in FIG.
A step of attaching an adhesive sheet having an adhesive 3 attached to one surface of a metal plate 1 and laminating a flexible film 4 with an adhesive on the other surface of the metal plate 1 (FIG. 2A) ) And a step of peeling off the matted film 2a (FIG. 2B);
The surface of the adhesive 3 of the metal plate 1 hits one mold 5a,
The metal plate 1 is mounted in a mold so that the surface of the flexible film 4 of the metal plate 1 comes into contact with the other mold 5b.
【0012】[0012]
【0013】[0013]
【作用】本発明によれば金属板1の一方の面に接着した
接着剤シートはマット処理したフィルム2aの面に接着
剤3を被着したものであるので、フィルム2aを剥離し
た接着剤3の金型5aに対向する面には、このマット処
理に応じた無数の微細な凹凸があり、この金型5a,5
bにより外形抜き及び絞り加工を同時に行ったときに、
この接着剤3の金型5aへの付着もなく、金型に対する
滑り性も良好であり、絞り加工がシャープに仕上がり、
金属板表面の外観が非常にきれいであった。According to the present invention, the adhesive sheet adhered to one surface of the metal plate 1 is obtained by applying the adhesive 3 to the surface of the matted film 2a, so that the adhesive 3 The surface facing the mold 5a has countless fine irregularities corresponding to the matting process.
When the outline punching and drawing are performed simultaneously by b,
There is no adhesion of the adhesive 3 to the mold 5a, the slipperiness with respect to the mold is good, and the drawing process is finished sharply.
The appearance of the metal plate surface was very clean.
【0014】[0014]
【実施例】以下図1、図2を参照して本発明金属板の成
型方法の実施例につき説明しよう。この図1、図2にお
いて図3に対応する部分には同一符号を付して示す。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of a method for forming a metal plate according to the present invention will be described below with reference to FIGS. 1 and 2, parts corresponding to those in FIG. 3 are denoted by the same reference numerals.
【0015】本例においては、金属板1の一方の面に被
着する接着剤シートとして、図1に示す如きものを用意
した。図1において、2aは例えば厚さが25μmのポ
リエチレンテレフタレートの剥離用のフィルムを示し、
このフィルム2aの片面2bにサンドマット処理即ち無
数の微細な凹凸を形成する。In this embodiment, an adhesive sheet to be adhered to one surface of the metal plate 1 was prepared as shown in FIG. In FIG. 1, 2a indicates a film for peeling polyethylene terephthalate having a thickness of, for example, 25 μm,
A sand mat treatment is performed on one surface 2b of the film 2a, that is, countless fine irregularities are formed.
【0016】この場合マット深度としては1μm〜10
μm(Rmax ) の範囲が良好である。このマット深度が
10μm以上としたときには後述する接着剤3の剥離が
重くなる不都合がある。また、このフィルム2aの厚さ
が薄い25μm程度の場合は引張り強さ、伸び等の機械
的強度が低下するため、このマット深度は1.0μm〜
4.0μmが好ましい。このマット処理したポリエチレ
ンテレフタレートとしては帝人社製PS−25が使用で
きる。本例に使用した25μm厚のポリエチレンテレフ
タレートのフィルム2aのマット深度は表面の粗さ計
(kosakalabolatory Ltd型式SP
−11、AS−3H、RA−60A)にて測定したとこ
ろRa=0.27μm、Rmax =3.31μmであっ
た。ここでRaは中心線平均粗さ、Rmax は最大高さで
ある。In this case, the mat depth is 1 μm to 10 μm.
The range of μm (Rmax) is good. When the mat depth is set to 10 μm or more, there is a disadvantage that the peeling of the adhesive 3 described later becomes heavy. When the thickness of the film 2a is as thin as about 25 μm, the mechanical strength such as tensile strength and elongation is reduced.
4.0 μm is preferred. As this matted polyethylene terephthalate, Teijin PS-25 can be used. The mat depth of the polyethylene terephthalate film 2a having a thickness of 25 μm used in this example was measured using a surface roughness meter (kosakalabory Ltd Model SP
-11, AS-3H, RA-60A), Ra = 0.27 μm and Rmax = 3.31 μm. Here, Ra is the center line average roughness, and Rmax is the maximum height.
【0017】本例においては、この剥離用のフィルム2
aのマット処理面2b上に図1に示す如く、厚さ40μ
m〜50μmのエチレン酢酸ビニール共重合体系接着剤
3を押出機のTダイで押出しラミネートする。In the present embodiment, the release film 2
a on the matted surface 2b of FIG.
An ethylene vinyl acetate copolymer adhesive 3 of m to 50 μm is extruded and laminated with a T-die of an extruder.
【0018】本例においてはこのエチレン酢酸ビニール
共重合体系接着剤として、 エチレン酢酸ビニール共重合体‥‥50重量部 (エバフレックスEV360:三井デュポンポリケミカ
ル社製) スチレン・ブタジエンラバー ‥‥20重量部 (TR−KX−65:シェル化学社製) 石油樹脂 ‥‥30重量部 (アルコンM100:荒川化学工業社製) 酸化防止剤 ‥‥0.5重量部 (アンテージDBH:川口化学工業社製) を組成とする接着原料をタンブラーにてドライブレンド
し、押出し成型機にて、170℃の温度で溶融混練し、
ひも状に押出された接着剤を水槽を通して冷却し、ペレ
タイザーにてカットし、ペレット状の接着剤を作成し、
このペレット状の接着剤を、70℃のオーブン中で1〜
2時間乾燥し、この乾燥したペレット状の接着剤を再び
押出し機にて170℃の温度でTダイよりフィルム状
(厚さ40μm〜50μm)に押し出し、この厚さ40
μm〜50μmのフィルム状の接着剤3をただちに(1
00℃以下に冷却しないうちに)、この剥離用のフィル
ム2aのマット処理面2bにラミネート(ニップ圧1.
0〜3.0kg/cm)する。In this example, as the ethylene-vinyl acetate copolymer-based adhesive, ethylene-vinyl acetate copolymer 重量 50 parts by weight (Evaflex EV360: manufactured by DuPont-Mitsui Polychemical Co., Ltd.) Styrene butadiene rubber ‥‥ 20 parts by weight (TR-KX-65: Shell Chemical Co., Ltd.) Petroleum resin ‥‥ 30 parts by weight (Alcon M100: Arakawa Chemical Co., Ltd.) Antioxidant ‥‥ 0.5 parts by weight (Antage DBH: Kawaguchi Chemical Co., Ltd.) The adhesive raw material having the composition is dry-blended with a tumbler, and melt-kneaded at a temperature of 170 ° C. with an extruder,
Cool the adhesive extruded into a string through a water tank, cut it with a pelletizer, create a pellet-shaped adhesive,
This pellet-shaped adhesive is placed in an oven at 70 ° C.
After drying for 2 hours, the dried pellet-shaped adhesive was again extruded into a film (thickness: 40 μm to 50 μm) from a T-die at a temperature of 170 ° C. by an extruder.
Immediately apply the adhesive 3 in the form of a film having a thickness of 50 μm to 50 μm (1
Before cooling to below 00 ° C.), lamination (nip pressure 1.
0-3.0 kg / cm).
【0019】次に、図2を参照して、上述の接着剤シー
トを使用した金属板の成型方法につき説明する。Next, a method for molding a metal plate using the above-mentioned adhesive sheet will be described with reference to FIG.
【0020】本例においては、先ず図2Aに示す如く、
絞り加工しようとする厚さが例えば0.1mmのステン
レススチールより成る金属板1の一方の面に上述の如き
剥離用のフィルム2aのマット処理面2bに接着剤3を
ラミネートした接着剤シートの接着剤3の面を加熱ロー
ルにて、160℃,3kg/cm,1m/分の条件で被
着すると共にこの金属板1の他方の面にプロテクトフィ
ルムとして粘着剤付可撓性フィルム(セキスイ化学社製
#623E厚さ75μm)を積層する。In this example, first, as shown in FIG.
Adhesion of an adhesive sheet obtained by laminating an adhesive 3 on one side of a metal plate 1 made of stainless steel and having a thickness of, for example, 0.1 mm to be drawn, on a matted surface 2b of a peeling film 2a as described above. The surface of the agent 3 is applied with a heating roll at 160 ° C., 3 kg / cm, 1 m / min, and a flexible film with an adhesive (Sekisui Chemical Co., Ltd.) is formed on the other surface of the metal plate 1 as a protective film. # 623E (thickness: 75 μm).
【0021】次に図2Bに示す如く、このマット処理し
た剥離用のフィルム2aを剥離する。この場合接着剤3
の剥離用のフィルム2aの剥離面は剥離用のフィルム2
aのマット処理に対応した無数の微細の凹凸が形成され
たものとなる。Next, as shown in FIG. 2B, the release film 2a subjected to the mat treatment is released. In this case adhesive 3
The release surface of the release film 2a is the release film 2
Innumerable fine irregularities corresponding to the matting process a are formed.
【0022】次に図2C,Dに示す如く、この金属板1
の接着剤3面が一方の金型である雄型5aに当たり、こ
の金属板1の可撓性フィルム4面が他方の金型である雌
型5bに当たるように金型5a,5b内に装着し、絞り
加工及び外形抜きを同時に行う。Next, as shown in FIGS.
Are mounted in the molds 5a and 5b such that the adhesive 3 surface of the metal plate 1 contacts the male mold 5a as one mold and the flexible film 4 surface of the metal plate 1 contacts the female mold 5b as the other mold. , Drawing and outline punching are performed simultaneously.
【0023】この場合、剥離用のフィルム2aを剥離し
た接着剤3の雄型5aに対向する面にはマット処理に応
じた無数の微細な凹凸があり、この金型5a,5bによ
り絞り加工及び外形抜きを同時に行ったときに、この接
着剤3の雄型5aへの付着もなく、この雄型5aに対す
る滑り性も良好であった。In this case, the surface of the adhesive 3 from which the peeling film 2a has been peeled, which faces the male mold 5a, has a myriad of fine irregularities corresponding to the matting process. When the outer shape was simultaneously removed, the adhesive 3 did not adhere to the male mold 5a, and the slipperiness with respect to the male mold 5a was good.
【0024】またこの場合は剥離用のフィルム2aを剥
がしているので絞り加工がシャープに仕上がり、金属板
1の表面の外観が非常にきれいであった。In this case, since the peeling film 2a was peeled off, the drawing process was finished sharply, and the appearance of the surface of the metal plate 1 was very beautiful.
【0025】その後図2Eに示す如く、この金属板1の
接着剤3側に例えばABS樹脂の成型体6に150℃,
3kg/cm2 ,10秒間の条件でホットプレス機にて
接着し、金属装飾板を得た。プロテクトフィルムである
粘着剤付可撓性フィルム4は必要に応じて剥離する。Then, as shown in FIG. 2E, a molded body 6 made of, for example, an ABS resin is applied on the adhesive 3 side of the metal plate 1 at 150 ° C.
Bonding was performed with a hot press under the conditions of 3 kg / cm 2 and 10 seconds to obtain a metal decorative plate. The flexible film with adhesive 4 which is a protection film is peeled off as necessary.
【0026】本例によれば薄い例えば0.1mmの厚さ
のステンレススチール板1の一方の面に接着した接着剤
シートはマット処理した剥離用のフィルム2aの面に接
着剤3を被着したものであるので、この剥離用のフィル
ム2aを剥離した接着剤3の金型5aに対向する面には
マット処理に応じた無数の微細な凹凸があり、この金型
5a,5bにより外形抜き及び絞り加工を同時に行った
ときに、この接着剤3の金型5aへの付着もなく、金型
5aに対する滑り性も良好である利益がある。According to the present embodiment, the adhesive sheet adhered to one surface of the thin stainless steel plate 1 having a thickness of, for example, 0.1 mm has the adhesive 3 adhered to the surface of the matting peeling film 2a. Therefore, the surface of the adhesive 3 from which the release film 2a has been peeled has a myriad of fine irregularities corresponding to the matting process on the surface facing the mold 5a. When the drawing process is performed at the same time, there is an advantage that the adhesive 3 does not adhere to the mold 5a and the sliding property with respect to the mold 5a is good.
【0027】また本例によれば剥離用のフィルム2aを
剥離した後に金型5a,5bで外形抜き及び絞り加工を
するので、絞り加工がシャープに仕上がり、また金属板
表面の外観が非常にきれいである利益がある。Further, according to this embodiment, since the outer shape is removed and drawn by the dies 5a and 5b after the peeling film 2a is peeled, the drawing is finished sharply and the appearance of the metal plate surface is very beautiful. There are benefits.
【0028】尚上述実施例においては剥離用のフィルム
2a上に被着する接着剤3の厚さを40μm〜50μm
と述べたが、この接着剤3の厚さとして20μm〜12
0μmで良い。この接着剤3の厚さが120μm以上で
は絞り加工のエッジのシャープ性が劣り、また20μm
以下では接着力が不足する不都合がある。In the above embodiment, the thickness of the adhesive 3 to be applied on the release film 2a is set to 40 μm to 50 μm.
However, the thickness of the adhesive 3 is 20 μm to 12 μm.
It may be 0 μm. When the thickness of the adhesive 3 is 120 μm or more, the sharpness of the edge of the drawing process is poor, and
Below, there is a disadvantage that the adhesive strength is insufficient.
【0029】また、本発明は上述実施例に限らず本発明
の要旨を逸脱することなく、その他種々の構成が採り得
ることは勿論である。Further, the present invention is not limited to the above-described embodiment, and it goes without saying that various other configurations can be adopted without departing from the gist of the present invention.
【0030】[0030]
【発明の効果】本発明によれば金型により外形抜き及び
絞り加工を行ったときに、接着剤の金型への付着がな
く、また金型に対する滑り性も良好である利益がある。According to the present invention, there is an advantage that the adhesive does not adhere to the mold and the sliding property with respect to the mold is good when the outer shape is drawn and drawn by the mold.
【0031】また本発明によれば剥離用のフィルムを剥
離した後に金型で外形抜き及び絞り加工をするので、こ
の絞り加工がシャープに仕上がり、また金属板表面の外
観が非常にきれいである利益がある。According to the present invention, since the outer shape is removed and drawn by a die after the release film is peeled off, the drawing is finished sharply and the appearance of the metal plate surface is very clean. There is.
【図1】接着剤シートの例を示す断面図である。FIG. 1 is a cross-sectional view illustrating an example of an adhesive sheet.
【図2】本発明金属板の成型方法の実施例の説明に供す
る断面図である。FIG. 2 is a cross-sectional view for explaining an example of a method for molding a metal plate of the present invention.
【図3】従来の金属板の成型方法の例の説明に供する断
面図である。FIG. 3 is a cross-sectional view for explaining an example of a conventional method for forming a metal plate.
1 金属板 2a フィルム 3 接着剤 4 粘着剤付可撓性フィルム 5a,5b 金型 6 成型体 DESCRIPTION OF SYMBOLS 1 Metal plate 2a Film 3 Adhesive 4 Flexible film with adhesive 5a, 5b Mold 6 Molded object
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 実開 昭55−62543(JP,U) (58)調査した分野(Int.Cl.7,DB名) B21D 22/02,22/20 C09J 7/02 ────────────────────────────────────────────────── ─── Continuation of the front page (56) References Japanese Utility Model Showa 55-62543 (JP, U) (58) Fields investigated (Int. Cl. 7 , DB name) B21D 22 / 02,22 / 20 C09J 7 / 02
Claims (3)
被着した接着剤シートを金属板の一方の面に被着し、該
金属板の他方の面に粘着剤付可撓性フィルムを積層する
工程と、前記マット処理したフィルムを剥離する工程
と、前記金属板の接着剤面が一方の金型に当たり、前記
金属板の可撓性フィルム面が他方の金型に当たるように
金型内に装着し、絞り加工と同時に外形抜きを行う工程
とを有することを特徴とする金属板の成型方法。1. An adhesive sheet in which an adhesive is applied to a surface of a mat-treated film is applied to one surface of a metal plate, and a flexible film with an adhesive is laminated on the other surface of the metal plate. And the step of peeling off the matted film, the adhesive surface of the metal plate hits one mold, the flexible film surface of the metal plate into the mold so as to hit the other mold Mounting and drawing the outer shape simultaneously with the drawing process.
て、 前記接着剤シートのフィルムのマット処理面に20μm
〜120μmの厚さを有する熱可塑性接着層を設けたこ
とを特徴とする金属板の成型方法。2. The method for molding a metal plate according to claim 1, wherein the matte-treated surface of the film of the adhesive sheet has a thickness of 20 μm.
A method for molding a metal plate, comprising: providing a thermoplastic adhesive layer having a thickness of about 120 µm.
て、 前記接着剤シートのマット処理面が1μm〜10μmの
マット深度を有することを特徴とする金属板の成型方
法。3. The method for forming a metal sheet according to claim 2, wherein a mat-treated surface of the adhesive sheet has a mat depth of 1 μm to 10 μm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5140831A JP3044516B2 (en) | 1993-06-11 | 1993-06-11 | Metal plate molding method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5140831A JP3044516B2 (en) | 1993-06-11 | 1993-06-11 | Metal plate molding method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06344043A JPH06344043A (en) | 1994-12-20 |
JP3044516B2 true JP3044516B2 (en) | 2000-05-22 |
Family
ID=15277739
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5140831A Expired - Lifetime JP3044516B2 (en) | 1993-06-11 | 1993-06-11 | Metal plate molding method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3044516B2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5104043B2 (en) * | 2007-05-31 | 2012-12-19 | Jfeスチール株式会社 | Embossing method of metal plate |
CN103930500B (en) * | 2011-11-15 | 2016-08-24 | 三井—杜邦聚合化学株式会社 | Pressure-sensitive adhesive film or sheet material, surface protection film or sheet material and use pressure-sensitive adhesive film or sheet material for the method protecting article surface |
JP6914035B2 (en) | 2016-12-28 | 2021-08-04 | スリーエム イノベイティブ プロパティズ カンパニー | A method for manufacturing a sheet-shaped laminate, a mold for molding the sheet-shaped laminate, and a sheet-shaped laminate. |
-
1993
- 1993-06-11 JP JP5140831A patent/JP3044516B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH06344043A (en) | 1994-12-20 |
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