JP3030441B2 - Electrophotographic photoreceptor - Google Patents

Description

Description: TECHNICAL FIELD The present invention relates to an electrophotographic photoconductor, and more particularly, to an electrophotographic photoconductor in which a specific compound is contained in a photosensitive layer.

[Conventional technology]

Conventionally, inorganic materials such as selenium, cadmium sulfide, and zinc oxide have been used as photoconductive materials for photoconductors used in electrophotography. Here, the term "electrophotographic method" generally means that a photoconductive photoreceptor is first charged in a dark place, for example, by corona discharge, and then subjected to image exposure to selectively dissipate the charge of only the exposed portion. An electrostatic latent image is obtained, and the latent image portion is developed and visualized with fine particles (toner) composed of a coloring material such as a dye or a pigment and a binder such as a polymer substance to form an image. This is one of the image forming methods used.

The basic characteristics required of the photoreceptor in such an electrophotographic method include (1) being able to be charged to an appropriate potential in a dark place, (2) being less liable to dissipate electric charge in a dark place, and (3). Charges can be quickly dissipated by light irradiation.

By the way, each of the above-mentioned inorganic substances has many advantages and also has various disadvantages. For example, selenium, which is widely used at present, satisfies the above conditions (1) to (3), but the production conditions are difficult, the production cost is high, there is no flexibility, and the selenium is processed into a belt shape. It also has drawbacks in that it is difficult to handle, and is sensitive to heat and mechanical shocks, and requires careful handling. Cadmium sulfide and zinc oxide are used as photoreceptors by dispersing them in a resin as a binder.However, due to mechanical defects such as smoothness, hardness, tensile strength, and abrasion resistance, they are repeatedly used as they are. Can not be used.

In recent years, electrophotographic photoreceptors using various organic substances have been proposed to eliminate the disadvantages of these inorganic substances, and some of them have been put to practical use. For example, poly-N-vinylcarbazole and 2,4,7-trinitrofluorene-9-
Photoreceptor (described in U.S. Pat. No. 3,484,237), a photoreceptor obtained by sensitizing poly-N-vinylcarbazole with a pyrylium salt dye (described in JP-B-48-25658), organic Photoreceptors containing pigment as the main component
No. 37543), a photoreceptor containing a eutectic complex composed of a dye and a resin as a main component (described in JP-A-47-10735), and a photoreceptor obtained by dye-sensitizing a triphenylamine compound ( U.S. Pat. No. 3,180,730), a photoreceptor using an amine derivative as a charge transporting material (Japanese Patent Laid-Open No. 57-195254), and a photoreceptor using poly-N-vinylcarbazole and an amine derivative as a charge transporting material (Japanese Patent No. -1155), a photoreceptor using a benzidine compound as a photoconductive material among polyfunctional tertiary amine compounds (US Pat. No. 3,265,
496, JP-B-39-11546 and JP-A-53-27033). Although these photoreceptors have excellent properties and are considered to be of high practical value, in electrophotography, considering various requirements for photoreceptors, these requirements are still insufficient. In fact, it is not possible to obtain anything satisfying the above conditions.

On the other hand, as diaminopyrene-based compounds, N, N, N ',
An electrophotographic photoreceptor using an N'-tetraphenyl-1,6-diaminopyrene compound is disclosed in JP-A-55-144250. However, the above compound is hardly soluble in the adhesive resin solution, and in order to form a good photosensitive layer satisfying various conditions required for the photoreceptor in the electrophotography,
It is difficult.

[Problems to be solved by the invention]

SUMMARY OF THE INVENTION It is an object of the present invention to provide a photoreceptor capable of solving the above-mentioned various disadvantages of the conventional photoreceptor and sufficiently satisfying the conditions required in electrophotography. It is a further object of the present invention to provide an electrophotographic photoreceptor which is easy to manufacture, relatively inexpensive, and has excellent durability.

[Means for solving the problem]

According to the present invention, the following general formula (I) is provided on a conductive support.
A photosensitive layer containing at least one of the diaminopyrene compounds represented by the formula (1) as an active ingredient.

(In the formula, R ¹ and R ² represent a substituted or unsubstituted alkyl group or aryl group, which may be the same or different, except for a 1,6-diamino compound.) The diaminopyrene compound represented by the general formula (I) contained in the layer is, for example, R ¹ =
In the case of R ² the following formula (II) Is reacted with a halide represented by the general formula (III) X-R ¹ (or R ² ) (III) (R ¹ , R ² is the same as above, X represents a halogen) Or the general formula (IV) A dihalogen pyrene derivative represented by the formula: It is easily produced by reacting an amine derivative represented by

In the general formula (I), when R ¹ and R ² are an aryl group, specific examples thereof include a non-condensed carbocyclic aromatic group such as a phenyl group, a biphenyl group and a terphenyl group, and a condensed polycyclic hydrocarbon Groups.

In this case, as the condensed polycyclic hydrocarbon group, those having preferably 18 or less carbon atoms forming a ring, for example, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group,
Heptalenyl group, biphenylenyl group, as-indacenyl group, fluorenyl group, S-indacenyl group, acenaphthylenyl group, preyadenyl group, acenaphthenyl group, phenalenyl group, phenanthryl group, anthryl group, fluoranthenyl group, acephenanthrenyl group, Examples include an aceanthrenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, and a naphthacenyl group.

In addition, the aromatic hydrocarbon groups include those having the following substituents.

(1) halogen atom, cyano group, nitro group (2) alkyl group, preferably C ₂ -C _12, especially C ₁ -C
_8, more preferably a linear or branched alkyl group of C ₁ -C _4, these alkyl groups may further hydrofluoric element,
A hydroxyl group, a cyano group, C ₁ -C ₄ alkoxy group, a phenyl group or a halogen atom, C ₁ alkyl or C ₁ -C ₄ in -C ₄
May contain a phenyl group substituted with an alkoxy group. Specifically, methyl, ethyl, n-propyl, i-propyl, t-butyl, s-butyl, n
-Butyl group, i-butyl group, trifluoromethyl group, 2
-Hydroxyethyl group, 2-cyanoethyl group, 2-ethoxyethyl group, 2-methoxyethyl group, benzyl group, 4
-Chlorobenzyl group, 4-methylbenzyl group, 4-methoxybenzyl group, 4-phenylbenzyl group and the like.

(3) alkoxy group (-OR ₁ ); R ₁ represents an alkyl group defined in (2). Specifically, methoxy, ethoxy, n-propoxy, i-propoxy, t-butoxy, n-butoxy, s-butoxy, i-butoxy, 2-hydroxyethoxy, 2-cyano Ethoxy group, benzyloxy group, 4-methylbenzyloxy group,
A trifluoromethoxy group.

(4) Aryloxy group: Examples of the aryl group include a phenyl group and a naphthyl group. It may contain an alkoxy group having C ₁ -C _4, alkyl group, or a halogen atom C ₁ -C ₄ as a substituent. Specifically, a phenoquino group,
Examples thereof include a 1-naphthyloxy group, a 2-naphthyloxy group, a 4-methylphenoxy group, a 4-methoxyphenoxy group, a 4-chlorophenoxy group, and a 6-methyl-2-naphthyloxy group.

(5) Alkyl mercapto group (-SR ₁ ); R ₁ represents an alkyl group defined in (2). Specifically, a methylthio group,
Examples include an ethylthio group, a phenylthio group, and a p-methylphenylthio group.

(6) (Wherein R ₂ and R ₃ each independently represent a hydrogen atom, an alkyl group or an aryl group as defined in (2), and examples of the aryl group include a phenyl group, a biphenylyl group and a naphthyl group; these alkoxy groups C ₁ -C _4,
Alkyl C ₁ -C _4, or a halogen atom may be contained as a substituent. R ₂ and R ₃ may together form a ring.
Further, a ring may be formed together with a carbon atom on the aryl group. Specifically, amino, diethylamino, N-methyl-N-phenylamino, N, N-diphenylamino, N, N-di (p-tolyl) amino, dibenzylamino, piperidino , A morpholino group, a urolidyl group and the like.

(7) An alkylenedioxy group or an alkylenedithio group such as a methylenedioxy group or a methylenedithio group.

Specific examples of the alkyl group in which R ¹ or R ² is the same as the alkyl group described in the above section (2), for example, can be given.

Hereinafter, typical examples of the diaminopyrene compound represented by the general formula (I) are shown.

The photoreceptor of the present invention comprises one or more of the above diaminopyrene compounds in the photosensitive layer 2 (2 ′, 2 ″, 2 or 2).
1), 2 and 3, depending on the application of these diaminopyrene compounds.
It can be used as shown in FIG. 4, FIG. 4 or FIG.

The photoreceptor in FIG. 1 has a conductive support 1 on which a photosensitive layer 2 composed of a diaminopyrene compound, a sensitizing dye and a binder (binder resin) is provided. The diaminopyrene compound here acts as a photoconductive substance, and the generation and transfer of charge carriers required for light decay are performed via the diaminopyrene compound. However, since the diaminopyrene compound has almost no absorption in the visible region of light, it is necessary to sensitize by adding a sensitizing dye having absorption in the visible region for the purpose of forming an image with visible light. is there.

The photosensitive member shown in FIG. 2 has a photosensitive layer 2 'in which a charge generating substance 3 is dispersed in a charge transporting medium 4 comprising a diaminopyrene compound and a binder on a conductive support 1. . The diaminopyrene compound here forms a charge transport medium together with a binder (or a binder and a plasticizer), while the charge generating substance 3 (a charge generating substance such as an inorganic or organic pigment) generates a charge carrier. . In this case, the charge transport medium 4 is mainly responsible for receiving and transporting charge carriers generated by the charge generating substance 3. In this photoreceptor, the basic condition is that the charge generation substance and the diaminopyrene compound do not overlap in the absorption wavelength region mainly in the visible region. This is because it is necessary to transmit light to the surface of the charge generating material 3 in order to efficiently generate charge carriers in the charge generating material 3. The diaminopyrene compound represented by the general formula (I) has almost no absorption in the visible region, and generally absorbs light in the visible region, and is particularly effective when combined with the charge generation material 3 which generates a charge carrier. The feature is that it works as

The photosensitive member in FIG. 3 is provided with a photosensitive layer 2 ″ comprising a laminate of a charge generation layer 5 mainly composed of a charge generation substance 3 and a charge transport layer 4 containing a diaminopyrene compound on a conductive support 1. In this photoreceptor, the light transmitted through the charge transport layer 4 reaches the charge generation layer 5, where charge carriers are generated, while the charge transport layer 4 injects the charge carriers. Receiving and transporting the carrier, the generation of charge carriers required for light attenuation is performed by the charge generating substance 3,
The charge carrier is transported in the charge transport layer 4 (where the diaminopyrene compound mainly works). Such a mechanism is the same as that described for the photosensitive member shown in FIG.

The photoreceptor in FIG. 4 is obtained by reversing the stacking order of the charge generation layer 5 and the charge transport layer 4 containing the diaminopyrene compound in FIG. 3, and the mechanism for generating and transporting the charge carriers is described above. You can do the same as In this case, a protective layer 6 can be provided on the charge generation layer 5 as shown in FIG. 5 in consideration of mechanical strength.

In order to actually prepare the photoreceptor of the present invention, if the photoreceptor shown in FIG. 1 is used, one or two or more diaminopyrene compounds are dissolved in a solution in which a binder is dissolved, and further sensitized to this. A photosensitive layer 2 may be formed by preparing a liquid to which a pigment is added, coating the liquid on the conductive support 1 and drying the liquid.

The thickness of the photosensitive layer is 3 to 50 µm, preferably 5 to 20 µm. The amount of the olefin compound in the photosensitive layer 2 is
It is 30 to 70% by weight, preferably about 50% by weight, and the amount of the sensitizing dye in the photosensitive layer 2 is 0.1 to 5% by weight, preferably 0.5 to 3% by weight. Sensitizing infections include Brilliant Green, Victoria Blue B, Methyl Violet, Crystal Violet, Acid Violet
Triarylmethane dyes such as 6B, rhodamine B, rhodamine 6G, rhodamine G extra, eosin S, erythrosine, rose bengal, xanthene dyes such as fluorescein, thiazine dyes such as methylene blue, cyanine dyes such as cyanine, 2, 6-diphenyl-4- (N, N-dimethylaminophenyl) thiapyrylium perchlorate, benzopyrylium salt (JP-B-48-25
No. 658) and pyrylium dyes. It should be noted that even if these sensitizing charges are used alone,
More than one species may be used in combination.

In order to produce the photoreceptor shown in FIG. 2, fine particles of the charge generating substance 3 are dispersed in a solution in which one or two or more diaminopyrene compounds and a binder are dissolved, and this is electrically conductively supported. What is necessary is just to apply it on the body 1 and dry it to form a dry layer 2 '.

The thickness of the photosensitive layer 2 'is 3 to 50 .mu.m, preferably 5 to 20 .mu.m.
m is appropriate. The amount of the diaminopyrene compound in the photosensitive layer 2 'is 10 to 95% by weight, preferably 30 to 90% by weight, and the amount of the charge generating substance 3 in the photosensitive layer 2' is 0.
It is 1 to 50% by weight, preferably 1 to 20% by weight. Examples of the charge generating substance 3 include inorganic pigments such as selenium, selenium-tellurium, cadmium sulfide, cadmium sulphide-selenium, and α-silicon. Examples of the organic pigments include CI Pigment Blue 25 (color index CI 21180) and CI Pigment Red 41. (CI 21200), CI Acid Red 52 (CI 45100), CI Basic Red 3
(CI45210), an azo pigment having a carbazole skeleton (described in JP-A-53-95033), an azo pigment having a distyrylbenzene skeleton (JP-A-53-133445), and an azo pigment having a triphenylamine skeleton (JP-A-53-1323
No. 47), an azo pigment having a dibenzothiophene skeleton (described in JP-A-54-21728), an azo pigment having an oxadiazole skeleton (described in JP-A-54-12742), a fluorenone skeleton Azo pigments having
54-22834), an azo pigment having a bisstilbene skeleton (described in JP-A-54-17733), and an azo pigment having a distyryloxadiazole skeleton (described in JP-A-54-17733).
Azo pigments having a distyrylcarbazole skeleton (described in JP-A-54-14967), for example, C.I. Pigment Blue 16 (CI7
Phthalocyanine-based pigments such as C.I.
Indigo pigments such as 73030), Argo Scarlet B
(Manufactured by Bayer AG) and perylene pigments such as Indance Scarlet R (manufactured by Bayer AG).
These charge generating substances may be used alone or in combination of two or more.

Further, to prepare the photoreceptor shown in FIG. 3, a charge generating substance is vacuum-deposited on the conductive support 1 or more, or
If necessary, a dispersion liquid in which the fine particles 3 of the charge generating substance are dispersed in a suitable solvent in which a binder is dissolved is applied and dried, and if necessary, the surface is finished by a method such as buffing, and the film thickness is adjusted. To form the charge generation layer 5,
A solution in which one or more diaminopyrene compounds and a binder are dissolved is applied thereon and dried to form the charge transport layer 4. Here, the charge generation material used for forming the charge generation layer 5 is the same as that described in the description of the photosensitive layer 2 '.

The thickness of the charge generation layer 5 is 5 μm or less, preferably 2 μm.
The thickness of the charge transport layer 4 is 3 to 50 μm, preferably 5 to 20 μm. In the type in which the charge generation layer 5 has the fine particles 3 of the charge generation layer material dispersed in a binder, the ratio of the fine particles 3 of the charge generation material to the charge generation layer 5 is preferably 10 to 95% by weight. Is about 50 to 90% by weight. The amount of the compound in the charge transport layer 4 is 10%.
9595% by weight, preferably 30-90% by weight. In order to prepare the photoreceptor shown in FIG. 4, a solution in which a diaminopyrene compound and a binder are dissolved is applied onto the conductive support 1,
After drying to form the charge transport layer 4, a dispersion of fine particles of the charge generation layer material dispersed in a solvent in which a binder is dissolved, if necessary, is applied on the charge transport layer by a method such as spray coating. The charge generation layer 5 may be formed by drying. The amount ratio of the charge generation layer or the charge transport layer is the same as that described in FIG. By forming a protective layer 6 on the charge generating layer 5 of the photoreceptor thus obtained by spraying an appropriate resin solution or the like, the photoreceptor shown in FIG. 5 can be prepared. As the resin used here, a binder described later can be used.

In the production of any of these photoconductors, a metal plate or metal foil of aluminum or the like, a plastic film on which a metal such as aluminum is vapor-deposited, or a paper subjected to a conductive treatment is used for the conductive support 1. Examples of the binder include condensation resins such as polyamide, polyurethane, polyester, epoxy resin, polyketone, and polycarbonate; and vinyl polymers such as polyvinyl ketone, polystyrene, poly-N-vinylcarbazole, and polyacrylamide. All insulating and adhesive resins can be used. If necessary, a plasticizer is added to the binder. Examples of such a plasticizer include halogenated paraffin, polychlorinated biphenyl, dimethylnaphthalene, and dibutylphthalate.

Further, the photosensitive member obtained as described above may be provided with an adhesive layer or a barrier layer between the conductive support and the photosensitive layer, if necessary. Materials used for these layers include polyamide, nitrocellulose, and aluminum oxide, and the film thickness is preferably 1 μm or less.

To make a copy using the photoreceptor of the present invention, the photosensitive surface is charged, exposed, then developed, if necessary,
Transfer to paper etc. The photoconductor of the present invention has high sensitivity,
In addition, it has excellent advantages such as high flexibility.

〔Example〕

Hereinafter, the present invention will be described with reference to examples. In the following examples, all parts are parts by weight.

[Synthesis of Compound of General Formula (I)]

(Synthesis example of compound No. 25) 0.70 g of 1,8-diaminopyrene, 20.9 of 4-iodotoluene
3 g, potassium carbonate 2.49 g and copper powder 0.19 g were stirred at 209 ° C. for 5 hours while azeotropically dehydrating under a nitrogen stream. After allowing to cool to room temperature, the mixture was filtered through celite, chloroform was added to the filtrate, the chloroform layer was washed with water, dried over magnesium sulfate, and further concentrated under reduced pressure to obtain a dark brown oil. This was treated with a silica gel column [eluent: toluene / n-hexane (1: 3) mixed solvent] and recrystallized from an ethanol / N, N-dimethylformamide mixed solvent to obtain yellow-green needle crystals. The crystals were stirred under reflux in ethanol, filtered,
0.92 g (yield 51.7%) of N, N, N ', N'-tetrakis (4-methylphenyl) -1,8-diaminopyrene (compound No. 25) represented by the following formula of yellowish green powder was obtained. . The melting point was 280 ° C or higher.

Elemental analysis values were as follows, as C ₄₄ H ₃₆ N ₂ .

C% H% N% Actual value 89.10 6.05 4.60 Calculated value 89.15 6.12 4.73 Other diaminopyrene compounds were synthesized in the same manner as described above.

Example 1 76 parts of Diane blue (C.I. Pigment Blue 25, CI 21180), 1260 parts of a 2% tetrahydrofuran solution of a polyester resin (Vylon 200, manufactured by Toyobo Co., Ltd.) and 3700 parts of tetrahydrofuran were milled in a ball mill as charge generating substances. After mixing, the obtained dispersion was applied on an aluminum surface of a conductive support made of a polyester base on which aluminum was deposited by using a doctor blade, and was naturally dried to form a charge generating layer having a thickness of about 1 μm.

On the other hand, as the charge transport material, a solution was prepared by mixing and dissolving 2 parts of the diaminopyrene compound of Compound Specific Example No. 4, 2 parts of a polycarbonate resin (Panlite K1300, manufactured by Teijin Limited) and 16 parts of tetrahydrofuran. Is applied on the charge generation layer using a doctor blade,
After drying at 120 ° C. for 5 minutes to form a charge transport layer having a thickness of about 20 μm, photoconductor No. 1 was prepared.

Examples 2 to 33 Photoconductors Nos. 2 to 33 were produced in exactly the same manner as in Example 1 except that the charge generating substance and the charge transporting substance (diaminopyrene compound) were changed to those shown in Table 1.

Example 34 Selenium was vacuum-deposited to a thickness of about 1 μm on an aluminum plate having a thickness of about 300 μm to form a charge generation layer. Next, 2 parts of a diaminopyrene compound of Compound No. 4 and a polyester resin (Polyester Adhesive 4900 manufactured by DuPont)
0) 3 parts and 45 parts of tetrahydrofuran were mixed and dissolved to form a charge transport layer forming solution, which was applied on the above-mentioned charge generation layer (selenium vapor deposition layer) using a doctor blade, air-dried, and then depressurized. The resultant was dried underneath to form a charge transport layer having a thickness of about 10 μm, thereby obtaining a photoreceptor No. 34 of the present invention.

Example 35 A perylene pigment in place of selenium To form a charge generation layer (thickness is about 0.6 μm), and a diaminopyrene compound N as a charge transport material.
Photoconductor No. 35 was prepared in the same manner as in Example 34 except that o.4 was used.

Example 36 A mixture of 1 part of Diane Blue (same as that used in Example 1) and 158 parts of tetrahydrofuran was pulverized and mixed in a ball mill, and then mixed with 12 parts of a diaminopyrene compound of Compound No. 4, polyester 18 parts of resin (Polyester Adhesive 49000 manufactured by DuPont) is added, and a photosensitive layer forming liquid obtained by further mixing is applied on an aluminum-evaporated polyester film using a doctor blade,
After drying at 100 ° C. for 3 minutes to form a photosensitive layer having a thickness of about 16 μm, Photoconductor No. 36 of the present invention was prepared.

Example 37 The charge transport layer coating solution used in Example 1 was coated on a polyester film substrate on which aluminum was vapor-deposited with a blade in the same manner as in Example 1, and then dried to a thickness of about 20 μm.
Was formed. Bisazo pigment (P-2) 13.5
Parts, 5.4 parts of polyvinyl butyral (trade name: XYHL Union Carbide Plastics Co., Ltd.), 680 parts of THF and 1020 parts of ethyl cellosolve were pulverized and mixed in a ball mill, and then 1700 parts of ethyl cellosolve were added and mixed by stirring. A working liquid was obtained. This coating solution was spray-coated on the charge transport layer and dried at 100 ° C. for 10 minutes to form a charge generation layer having a thickness of about 0.2 μm. Further, a methanol / polyamide resin (trade name: CM-8000, manufactured by Toray Co., Ltd.)
An n-butanol solution was spray-coated and dried at 120 ° C. for 30 minutes to form a protective layer having a thickness of about 0.5 μm.
It was created.

The photoreceptors Nos. 1 to 37 thus produced were charged by performing a −6 KV or +6 KV corona discharge for 20 seconds using a commercially available electrostatic copying paper tester (SP428, manufactured by KK Kawaguchi Electric Works). Leave for 20 seconds in a dark place, then the surface potential Vp
o (volt), then illuminate the surface of the photoreceptor with a tungsten lamp so that the illuminance is 4.5 lux, and calculate the time (second) until the surface potential becomes 1/2 of Vpo. E1 / 2 (looks-seconds) was calculated. Table 2 shows the results.

Also, after charging each of the above photoreceptors using a commercially available electrophotographic copying machine, irradiating light through the original drawing to form an electrostatic latent image, and developing using a dry developer, the obtained The transferred image (toner image) was electrostatically transferred onto plain paper and fixed, and a clear transferred image was obtained. Similarly, when a wet type developer was used as the developer, a clear transfer image was obtained.

[Effects] The photoreceptor of the present invention is not only excellent in photosensitive characteristics but also has high strength against heat and mechanical shock and can be manufactured at low cost.

[Brief description of the drawings]

1 to 5 are cross-sectional views of the electrophotographic photosensitive member according to the present invention, which are enlarged in the thickness direction. DESCRIPTION OF SYMBOLS 1 ... Conductive support, 2,2 ', 2 ", 2,2' ... Photosensitive layer 3 ... Charge generating substance, 4 ... Charge transport medium or charge transport layer 5 ... Charge generating layer, 6 ... … Protective layer

──────────────────────────────────────────────────続 き Continuation of front page (56) References JP-A-55-144250 (JP, A) JP-A-4-20573 (JP, A) JP-A-4-36264 (JP, A) JP-A-63-1988 210943 (JP, A) JP-A-64-19049 (JP, A) JP-A-1-217357 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) G03G 5/00 C09B 57 / 00 C07C 211/61 CA (STN) REGISTRY (STN)

Claims (1)

(57) [Claims] An electrophotographic photosensitive member comprising a conductive support and a photosensitive layer containing at least one diaminopyrene compound represented by the following general formula (I) as an active ingredient. (In the formula, R ¹ and R ² represent a substituted or unsubstituted alkyl group or aryl group, which may be the same or different, except for a 1,6-diaminopyrene compound.)